Articles | Volume 16, issue 3
Atmos. Chem. Phys., 16, 1761–1771, 2016
https://doi.org/10.5194/acp-16-1761-2016
Atmos. Chem. Phys., 16, 1761–1771, 2016
https://doi.org/10.5194/acp-16-1761-2016

Research article 15 Feb 2016

Research article | 15 Feb 2016

Hydroxyl radicals from secondary organic aerosol decomposition in water

Haijie Tong et al.

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Cited articles

Anglada, J. M., Martins-Costa, M., Ruiz-López, M. F., and Francisco, J. S.: Spectroscopic signatures of ozone at the air–water interface and photochemistry implications, P. Natl. Acad. Sci. USA, 111, 11618–11623, 2014.
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Arangio, A. M., Slade, J. H., Berkemeier, T., Pöschl, U., Knopf, D. A., and Shiraiwa, M.: Multiphase Chemical Kinetics of OH Radical Uptake by Molecular Organic Markers of Biomass Burning Aerosols: Humidity and Temperature Dependence, Surface Reaction, and Bulk Diffusion, J. Phys. Chem. A, 119, 4533–4544, 2015.
Badali, K. M., Zhou, S., Aljawhary, D., Antiñolo, M., Chen, W. J., Lok, A., Mungall, E., Wong, J. P. S., Zhao, R., and Abbatt, J. P. D.: Formation of hydroxyl radicals from photolysis of secondary organic aerosol material, Atmos. Chem. Phys., 15, 7831–7840, https://doi.org/10.5194/acp-15-7831-2015, 2015.
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Short summary
We provide experimental evidence that terpene and isoprene SOA form substantial amounts of OH radicals upon interaction with liquid water and iron. Our measurements and model results imply that the chemical reactivity of SOA in the atmosphere, particularly in clouds, can be faster than previously thought. Inhalation and deposition of SOA particles in the human respiratory tract may lead to a substantial release of OH radicals in vivo, causing oxidative stress and adverse aerosol health effects.
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