Articles | Volume 16, issue 3
https://doi.org/10.5194/acp-16-1761-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-16-1761-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Hydroxyl radicals from secondary organic aerosol decomposition in water
Haijie Tong
Multiphase Chemistry Department, Max Planck Institute for
Chemistry, Mainz, Germany
Andrea M. Arangio
Multiphase Chemistry Department, Max Planck Institute for
Chemistry, Mainz, Germany
Pascale S. J. Lakey
Multiphase Chemistry Department, Max Planck Institute for
Chemistry, Mainz, Germany
Thomas Berkemeier
Multiphase Chemistry Department, Max Planck Institute for
Chemistry, Mainz, Germany
Fobang Liu
Multiphase Chemistry Department, Max Planck Institute for
Chemistry, Mainz, Germany
Christopher J. Kampf
Multiphase Chemistry Department, Max Planck Institute for
Chemistry, Mainz, Germany
Institute for Inorganic and Analytical Chemistry, Johannes Gutenberg
University Mainz, Mainz, Germany
William H. Brune
Department of Meteorology, Pennsylvania State University, University
Park, PA 16802, USA
Ulrich Pöschl
Multiphase Chemistry Department, Max Planck Institute for
Chemistry, Mainz, Germany
Multiphase Chemistry Department, Max Planck Institute for
Chemistry, Mainz, Germany
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140 citations as recorded by crossref.
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- Prominent Contribution of Hydrogen Peroxide to Intracellular Reactive Oxygen Species Generated upon Exposure to Naphthalene Secondary Organic Aerosols F. Liu et al. 10.1021/acs.estlett.9b00773
- Large differences of highly oxygenated organic molecules (HOMs) and low-volatile species in secondary organic aerosols (SOAs) formed from ozonolysis of β-pinene and limonene D. Liu et al. 10.5194/acp-23-8383-2023
- Photooxidants from brown carbon and other chromophores in illuminated particle extracts R. Kaur et al. 10.5194/acp-19-6579-2019
- Modelling molecular composition of SOA from toluene photo-oxidation at urban and street scales K. Sartelet et al. 10.1039/D4EA00049H
- Light-induced variation in environmentally persistent free radicals and the generation of reactive radical species in humic substances Y. Shi et al. 10.1007/s11783-020-1285-2
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Short summary
We provide experimental evidence that terpene and isoprene SOA form substantial amounts of OH radicals upon interaction with liquid water and iron. Our measurements and model results imply that the chemical reactivity of SOA in the atmosphere, particularly in clouds, can be faster than previously thought. Inhalation and deposition of SOA particles in the human respiratory tract may lead to a substantial release of OH radicals in vivo, causing oxidative stress and adverse aerosol health effects.
We provide experimental evidence that terpene and isoprene SOA form substantial amounts of OH...
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