Articles | Volume 16, issue 3
https://doi.org/10.5194/acp-16-1761-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-16-1761-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Hydroxyl radicals from secondary organic aerosol decomposition in water
Haijie Tong
Multiphase Chemistry Department, Max Planck Institute for
Chemistry, Mainz, Germany
Andrea M. Arangio
Multiphase Chemistry Department, Max Planck Institute for
Chemistry, Mainz, Germany
Pascale S. J. Lakey
Multiphase Chemistry Department, Max Planck Institute for
Chemistry, Mainz, Germany
Thomas Berkemeier
Multiphase Chemistry Department, Max Planck Institute for
Chemistry, Mainz, Germany
Fobang Liu
Multiphase Chemistry Department, Max Planck Institute for
Chemistry, Mainz, Germany
Christopher J. Kampf
Multiphase Chemistry Department, Max Planck Institute for
Chemistry, Mainz, Germany
Institute for Inorganic and Analytical Chemistry, Johannes Gutenberg
University Mainz, Mainz, Germany
William H. Brune
Department of Meteorology, Pennsylvania State University, University
Park, PA 16802, USA
Ulrich Pöschl
Multiphase Chemistry Department, Max Planck Institute for
Chemistry, Mainz, Germany
Multiphase Chemistry Department, Max Planck Institute for
Chemistry, Mainz, Germany
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- Isomerization and Degradation of Levoglucosan via the Photo-Fenton Process: Insights from Aqueous-Phase Experiments and Atmospheric Particulate Matter C. Yang et al. 10.1021/acs.est.0c02499
- The maximum carbonyl ratio (MCR) as a new index for the structural classification of secondary organic aerosol components Y. Zhang et al. 10.1002/rcm.9113
- Iron-Facilitated Organic Radical Formation from Secondary Organic Aerosols in Surrogate Lung Fluid J. Wei et al. 10.1021/acs.est.1c04334
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- Atmospheric organic complexation enhanced sulfate formation and iron dissolution on nano α-Fe2O3 K. Li et al. 10.1039/D0EN01220C
- Long-lived and short-lived reactive species produced by a cold atmospheric pressure plasma jet for the inactivation of Pseudomonas aeruginosa and Staphylococcus aureus V. Kondeti et al. 10.1016/j.freeradbiomed.2018.05.083
- Seasonal variation characteristics of hydroxyl radical pollution and its potential formation mechanism during the daytime in Lanzhou G. Wang et al. 10.1016/j.jes.2020.03.045
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Short summary
We provide experimental evidence that terpene and isoprene SOA form substantial amounts of OH radicals upon interaction with liquid water and iron. Our measurements and model results imply that the chemical reactivity of SOA in the atmosphere, particularly in clouds, can be faster than previously thought. Inhalation and deposition of SOA particles in the human respiratory tract may lead to a substantial release of OH radicals in vivo, causing oxidative stress and adverse aerosol health effects.
We provide experimental evidence that terpene and isoprene SOA form substantial amounts of OH...
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