Articles | Volume 23, issue 9
https://doi.org/10.5194/acp-23-5279-2023
https://doi.org/10.5194/acp-23-5279-2023
Research article
 | 
11 May 2023
Research article |  | 11 May 2023

Revealing the sources and sinks of negative cluster ions in an urban environment through quantitative analysis

Rujing Yin, Xiaoxiao Li, Chao Yan, Runlong Cai, Ying Zhou, Juha Kangasluoma, Nina Sarnela, Janne Lampilahti, Tuukka Petäjä, Veli-Matti Kerminen, Federico Bianchi, Markku Kulmala, and Jingkun Jiang

Related authors

Elucidating the mechanisms of atmospheric new particle formation in the highly polluted Po Valley, Italy
Jing Cai, Juha Sulo, Yifang Gu, Sebastian Holm, Runlong Cai, Steven Thomas, Almuth Neuberger, Fredrik Mattsson, Marco Paglione, Stefano Decesari, Matteo Rinaldi, Rujing Yin, Diego Aliaga, Wei Huang, Yuanyuan Li, Yvette Gramlich, Giancarlo Ciarelli, Lauriane Quéléver, Nina Sarnela, Katrianne Lehtipalo, Nora Zannoni, Cheng Wu, Wei Nie, Juha Kangasluoma, Claudia Mohr, Markku Kulmala, Qiaozhi Zha, Dominik Stolzenburg, and Federico Bianchi
Atmos. Chem. Phys., 24, 2423–2441, https://doi.org/10.5194/acp-24-2423-2024,https://doi.org/10.5194/acp-24-2423-2024, 2024
Short summary

Related subject area

Subject: Gases | Research Activity: Field Measurements | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
Significant influence of oxygenated volatile organic compounds on atmospheric chemistry: a case study in a typical industrial city in China
Jingwen Dai, Kun Zhang, Yanli Feng, Xin Yi, Rui Li, Jin Xue, Qing Li, Lishu Shi, Jiaqiang Liao, Yanan Yi, Fangting Wang, Liumei Yang, Hui Chen, Ling Huang, Jiani Tan, Yangjun Wang, and Li Li
Atmos. Chem. Phys., 25, 7467–7484, https://doi.org/10.5194/acp-25-7467-2025,https://doi.org/10.5194/acp-25-7467-2025, 2025
Short summary
Global ground-based tropospheric ozone measurements: reference data and individual site trends (2000–2022) from the TOAR-II/HEGIFTOM project
Roeland Van Malderen, Anne M. Thompson, Debra E. Kollonige, Ryan M. Stauffer, Herman G. J. Smit, Eliane Maillard Barras, Corinne Vigouroux, Irina Petropavlovskikh, Thierry Leblanc, Valérie Thouret, Pawel Wolff, Peter Effertz, David W. Tarasick, Deniz Poyraz, Gérard Ancellet, Marie-Renée De Backer, Stéphanie Evan, Victoria Flood, Matthias M. Frey, James W. Hannigan, José L. Hernandez, Marco Iarlori, Bryan J. Johnson, Nicholas Jones, Rigel Kivi, Emmanuel Mahieu, Glen McConville, Katrin Müller, Tomoo Nagahama, Justus Notholt, Ankie Piters, Natalia Prats, Richard Querel, Dan Smale, Wolfgang Steinbrecht, Kimberly Strong, and Ralf Sussmann
Atmos. Chem. Phys., 25, 7187–7225, https://doi.org/10.5194/acp-25-7187-2025,https://doi.org/10.5194/acp-25-7187-2025, 2025
Short summary
Understanding summertime H2O2 chemistry in the North China Plain through observations and modeling studies
Can Ye, Pengfei Liu, Chaoyang Xue, Chenglong Zhang, Zhuobiao Ma, Chengtang Liu, Junfeng Liu, Keding Lu, Yujing Mu, and Yuanhang Zhang
Atmos. Chem. Phys., 25, 6991–7005, https://doi.org/10.5194/acp-25-6991-2025,https://doi.org/10.5194/acp-25-6991-2025, 2025
Short summary
Volatile organic compound sources and impacts in an urban Mediterranean area (Marseille, France)
Marvin Dufresne, Thérèse Salameh, Thierry Leonardis, Grégory Gille, Alexandre Armengaud, and Stéphane Sauvage
Atmos. Chem. Phys., 25, 5977–5999, https://doi.org/10.5194/acp-25-5977-2025,https://doi.org/10.5194/acp-25-5977-2025, 2025
Short summary
Short-lived organic nitrates in a suburban temperate forest: an indication of efficient assimilation of reactive nitrogen by the biosphere?
Simone T. Andersen, Rolf Sander, Patrick Dewald, Laura Wüst, Tobias Seubert, Gunther N. T. E. Türk, Jan Schuladen, Max R. McGillen, Chaoyang Xue, Abdelwahid Mellouki, Alexandre Kukui, Vincent Michoud, Manuela Cirtog, Mathieu Cazaunau, Astrid Bauville, Hichem Bouzidi, Paola Formenti, Cyrielle Denjean, Jean-Claude Etienne, Olivier Garrouste, Christopher Cantrell, Jos Lelieveld, and John N. Crowley
Atmos. Chem. Phys., 25, 5893–5909, https://doi.org/10.5194/acp-25-5893-2025,https://doi.org/10.5194/acp-25-5893-2025, 2025
Short summary

Cited articles

Arnold, F. and Viggiano, A. A.: Combined mass spectrometric composition measurements of positive and negative ions in the lower ionosphere – I. Positive ions, Planet. Space Sci., 30, 1295–1305, https://doi.org/10.1016/0032-0633(82)90103-9, 1982. 
Arnold, F., Böhringer, H., and Henschen, G.: Composition measurements of stratospheric positive ions, Geophys. Res. Lett., 5, 653–656, https://doi.org/10.1029/GL005i008p00653, 1978. 
Bates, D. R.: Recombination of Small Ions in the Troposphere and Lower Stratosphere, Planet. Space Sci., 30, 1275–1282, https://doi.org/10.1016/0032-0633(82)90101-5, 1982. 
Baumgaertner, A. J., Thayer, J. P., Neely III, R. R., and Lucas, G.: Toward a comprehensive global electric circuit model: Atmospheric conductivity and its variability in CESM1(WACCM) model simulations, J. Geophys. Res.-Atmos., 118, 9221–9232, https://doi.org/10.1002/jgrd.50725, 2013. 
Beck, L. J., Schobesberger, S., Sipilä, M., Kerminen, V. M., and Kulmala, M.: Estimation of sulfuric acid concentration using ambient ion composition and concentration data obtained with atmospheric pressure interface time-of-flight ion mass spectrometer, Atmos. Meas. Tech., 15, 1957–1965, https://doi.org/10.5194/amt-15-1957-2022, 2022. 
Download
Short summary
Atmospheric cluster ions are important constituents in the atmosphere. However, the quantitative research on their compositions is still limited, especially in urban environments. Here we demonstrate the feasibility of an in situ quantification method of cluster ions measured by a high-resolution mass spectrometer and reveal their governing factors, sources, and sinks in urban Beijing through quantitative analysis of cluster ions, reagent ions, neutral molecules, and condensation sink.
Share
Altmetrics
Final-revised paper
Preprint