Articles | Volume 23, issue 9
https://doi.org/10.5194/acp-23-5279-2023
https://doi.org/10.5194/acp-23-5279-2023
Research article
 | 
11 May 2023
Research article |  | 11 May 2023

Revealing the sources and sinks of negative cluster ions in an urban environment through quantitative analysis

Rujing Yin, Xiaoxiao Li, Chao Yan, Runlong Cai, Ying Zhou, Juha Kangasluoma, Nina Sarnela, Janne Lampilahti, Tuukka Petäjä, Veli-Matti Kerminen, Federico Bianchi, Markku Kulmala, and Jingkun Jiang

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Cited articles

Arnold, F. and Viggiano, A. A.: Combined mass spectrometric composition measurements of positive and negative ions in the lower ionosphere – I. Positive ions, Planet. Space Sci., 30, 1295–1305, https://doi.org/10.1016/0032-0633(82)90103-9, 1982. 
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Bates, D. R.: Recombination of Small Ions in the Troposphere and Lower Stratosphere, Planet. Space Sci., 30, 1275–1282, https://doi.org/10.1016/0032-0633(82)90101-5, 1982. 
Baumgaertner, A. J., Thayer, J. P., Neely III, R. R., and Lucas, G.: Toward a comprehensive global electric circuit model: Atmospheric conductivity and its variability in CESM1(WACCM) model simulations, J. Geophys. Res.-Atmos., 118, 9221–9232, https://doi.org/10.1002/jgrd.50725, 2013. 
Beck, L. J., Schobesberger, S., Sipilä, M., Kerminen, V. M., and Kulmala, M.: Estimation of sulfuric acid concentration using ambient ion composition and concentration data obtained with atmospheric pressure interface time-of-flight ion mass spectrometer, Atmos. Meas. Tech., 15, 1957–1965, https://doi.org/10.5194/amt-15-1957-2022, 2022. 
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Atmospheric cluster ions are important constituents in the atmosphere. However, the quantitative research on their compositions is still limited, especially in urban environments. Here we demonstrate the feasibility of an in situ quantification method of cluster ions measured by a high-resolution mass spectrometer and reveal their governing factors, sources, and sinks in urban Beijing through quantitative analysis of cluster ions, reagent ions, neutral molecules, and condensation sink.
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