Articles | Volume 20, issue 13
https://doi.org/10.5194/acp-20-8157-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-20-8157-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
14 Jul 2020
Research article |
| 14 Jul 2020
| 14 Jul 2020
Ice-supersaturated air masses in the northern mid-latitudes from regular in situ observations by passenger aircraft: vertical distribution, seasonality and tropospheric fingerprint
Forschungszentrum Jülich GmbH, Institute of Energy and Climate Research 8 – Troposphere, Jülich, Germany
Patrick Neis
Forschungszentrum Jülich GmbH, Institute of Energy and Climate Research 8 – Troposphere, Jülich, Germany
Institute for Atmospheric Physics, Johannes Gutenberg University, Mainz, Germany
now at: CGI Deutschland B.V. & CO. KG, Frankfurt, Germany
Mihal Rütimann
Forschungszentrum Jülich GmbH, Institute of Energy and Climate Research 8 – Troposphere, Jülich, Germany
Susanne Rohs
Forschungszentrum Jülich GmbH, Institute of Energy and Climate Research 8 – Troposphere, Jülich, Germany
Florian Berkes
Forschungszentrum Jülich GmbH, Institute of Energy and Climate Research 8 – Troposphere, Jülich, Germany
now at: P3 solutions GmbH, Aachen, Germany
Herman G. J. Smit
Forschungszentrum Jülich GmbH, Institute of Energy and Climate Research 8 – Troposphere, Jülich, Germany
Martina Krämer
Forschungszentrum Jülich GmbH, Institute of Energy and Climate Research 7 – Stratosphere, Jülich, Germany
Institute for Atmospheric Physics, Johannes Gutenberg University, Mainz, Germany
Nicole Spelten
Forschungszentrum Jülich GmbH, Institute of Energy and Climate Research 7 – Stratosphere, Jülich, Germany
Peter Spichtinger
Institute for Atmospheric Physics, Johannes Gutenberg University, Mainz, Germany
Philippe Nédélec
CNRS Laboratoire d'Aérologie and Université Paul Sabatier Toulouse III, Toulouse, France
Andreas Wahner
Forschungszentrum Jülich GmbH, Institute of Energy and Climate Research 8 – Troposphere, Jülich, Germany
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This preprint is open for discussion and under review for Atmospheric Chemistry and Physics (ACP).
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Michael Rolletter, Andreas Hofzumahaus, Anna Novelli, Andreas Wahner, and Hendrik Fuchs
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Ziming Wang, Luca Bugliaro, Klaus Gierens, Michaela I. Hegglin, Susanne Rohs, Andreas Petzold, Stefan Kaufmann, and Christiane Voigt
Atmos. Chem. Phys., 25, 2845–2861, https://doi.org/10.5194/acp-25-2845-2025, https://doi.org/10.5194/acp-25-2845-2025, 2025
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Upper-tropospheric relative humidity bias in the ERA5 weather model is corrected by 10 % by an artificial neural network using aircraft in-service humidity data and thermodynamic and dynamical variables. The improved skills of the weather model will advance cirrus research, weather forecasts, and measures for contrail reduction.
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The size and number of cirrus ice crystals is one parameter influencing the still uncertain effect of cirrus clouds on climate. Here, the occurrence of ice particle sizes and concentrations with varying temperature and cloud microphysical thickness is analyzed as well as whether they formed in-situ or were transported upwards as frozen droplets from further below. The analyses are based on a large database of airborne measurements and extensive simulations.
Hendrik Fuchs, Aaron Stainsby, Florian Berg, René Dubus, Michelle Färber, Andreas Hofzumahaus, Frank Holland, Kelvin H. Bates, Steven S. Brown, Matthew M. Coggon, Glenn S. Diskin, Georgios I. Gkatzelis, Christopher M. Jernigan, Jeff Peischl, Michael A. Robinson, Andrew W. Rollins, Nell B. Schafer, Rebecca H. Schwantes, Chelsea E. Stockwell, Patrick R. Veres, Carsten Warneke, Eleanor M. Waxman, Lu Xu, Kristen Zuraski, Andreas Wahner, and Anna Novelli
Atmos. Meas. Tech., 18, 881–895, https://doi.org/10.5194/amt-18-881-2025, https://doi.org/10.5194/amt-18-881-2025, 2025
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Significant improvements have been made to the instruments used to measure OH reactivity, which is equivalent to the sum of air pollutant concentrations. Accurate and precise measurements with a high time resolution have been achieved, allowing use on aircraft, as demonstrated during flights in the USA.
Blaž Gasparini, Rachel Atlas, Aiko Voigt, Martina Krämer, and Peter N. Blossey
EGUsphere, https://doi.org/10.5194/egusphere-2025-203, https://doi.org/10.5194/egusphere-2025-203, 2025
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Tropical cirrus clouds, especially their evolution, are poorly understood, contributing to uncertainty in climate projections. We address this by using novel tracers in a cloud-resolving model to track the life cycle of cirrus clouds, providing insights into cloud formation, ice crystal evolution, and radiative effects. We also improve the model's cloud microphysics with a simple, computationally efficient approach that can be applied to other models.
Nicolas Emig, Annette K. Miltenberger, Peter M. Hoor, and Andreas Petzold
EGUsphere, https://doi.org/10.5194/egusphere-2024-3919, https://doi.org/10.5194/egusphere-2024-3919, 2025
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This study presents in situ observations of cirrus occurrence from aircraft measurements in the extra-tropical transition layer (ExTL) using simultaneous measurements from two platforms. Lagrangian diagnostics based on high-resolution ICON simulations show long residence times of the cirrus in stratospheric air allowing to separate different diabatic processes during transit. The findings suggest that radiative diabatic cloud processes significantly impact the tropopause thermodynamic structure.
Tim Lüttmer, Annette Miltenberger, and Peter Spichtinger
EGUsphere, https://doi.org/10.5194/egusphere-2025-185, https://doi.org/10.5194/egusphere-2025-185, 2025
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We investigate ice formation pathways in a warm conveyor belt case study. We employ a multi-phase microphysics scheme that distinguishes between ice from different nucleation processes. Ice crystals in the cirrus outflow mostly stem from in-situ formation. Hence they were formed directly from the vapor phase. Sedimentational redistribution modulates cirrus properties and leads to a disagreement between cirrus origin classifications based on thermodynamic history and nucleation processes.
Roeland Van Malderen, Anne M. Thompson, Debra E. Kollonige, Ryan M. Stauffer, Herman G. J. Smit, Eliane Maillard Barras, Corinne Vigouroux, Irina Petropavlovskikh, Thierry Leblanc, Valérie Thouret, Pawel Wolff, Peter Effertz, David W. Tarasick, Deniz Poyraz, Gérard Ancellet, Marie-Renée De Backer, Stéphanie Evan, Victoria Flood, Matthias M. Frey, James W. Hannigan, José L. Hernandez, Marco Iarlori, Bryan J. Johnson, Nicholas Jones, Rigel Kivi, Emmanuel Mahieu, Glen McConville, Katrin Müller, Tomoo Nagahama, Justus Notholt, Ankie Piters, Natalia Prats, Richard Querel, Dan Smale, Wolfgang Steinbrecht, Kimberly Strong, and Ralf Sussmann
EGUsphere, https://doi.org/10.5194/egusphere-2024-3736, https://doi.org/10.5194/egusphere-2024-3736, 2025
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Tropospheric ozone is an important greenhouse gas and is an air pollutant. The time variability of tropospheric ozone is mainly driven by anthropogenic emissions. In this paper, we study the distribution and time variability of ozone from harmonized ground-based observations from five different measurement techniques. Our findings will provide clear standard references for atmospheric models and evolving tropospheric ozone satellite data for the 2000–2022 period.
Roeland Van Malderen, Zhou Zang, Kai-Lan Chang, Robin Björklund, Owen R. Cooper, Jane Liu, Eliane Maillard Barras, Corinne Vigouroux, Irina Petropavlovskikh, Thierry Leblanc, Valérie Thouret, Pawel Wolff, Peter Effertz, Audrey Gaudel, David W. Tarasick, Herman G. J. Smit, Anne M. Thompson, Ryan M. Stauffer, Debra E. Kollonige, Deniz Poyraz, Gérard Ancellet, Marie-Renée De Backer, Matthias M. Frey, James W. Hannigan, José L. Hernandez, Bryan J. Johnson, Nicholas Jones, Rigel Kivi, Emmanuel Mahieu, Isamu Morino, Glen McConville, Katrin Müller, Isao Murata, Justus Notholt, Ankie Piters, Maxime Prignon, Richard Querel, Vincenzo Rizi, Dan Smale, Wolfgang Steinbrecht, Kimberly Strong, and Ralf Sussmann
EGUsphere, https://doi.org/10.5194/egusphere-2024-3745, https://doi.org/10.5194/egusphere-2024-3745, 2025
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Tropospheric ozone is an important greenhouse gas and an air pollutant, whose distribution and time variability is mainly governed by anthropogenic emissions and dynamics. In this paper, we assess regional trends of tropospheric ozone column amounts, based on two different approaches of merging or synthesizing ground-based observations and their trends within specific regions. Our findings clearly demonstrate regional trend differences, but also consistently higher pre- than post-COVID trends.
Kevin Wolf, Nicolas Bellouin, Olivier Boucher, Susanne Rohs, and Yun Li
Atmos. Chem. Phys., 25, 157–181, https://doi.org/10.5194/acp-25-157-2025, https://doi.org/10.5194/acp-25-157-2025, 2025
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ERA5 atmospheric reanalysis and airborne in situ observations from IAGOS are compared in terms of the representation of the contrail formation potential and the presence of supersaturation. Differences are traced back to biases in ERA5 relative humidity fields. Those biases are addressed by applying a quantile mapping technique that significantly improved contrail estimation based on post-processed ERA5 data.
Herman G.J. Smit, Torben Galle, Romain Blot, Florian Obersteiner, Philippe Nédélec, Andreas Zahn, Jean-Marc Cousin, Ulrich Bundke, Andreas Petzold, Valerie Thouret, and Hannah Clark
EGUsphere, https://doi.org/10.5194/egusphere-2024-3760, https://doi.org/10.5194/egusphere-2024-3760, 2025
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The two ozone instruments of IAGOS (In-service Aircraft for a Global Observation System) have been compared with the Ozone PhotoMeter (OPM) of the World Calibration Center of Ozone Sondes (WCCOS) in an atmospheric simulation chamber under realistic flight conditions of pressure, temperature, and ozone concentrations. The two IAGOS-instruments showed good agreement with the OPM within 5–6 %. The observed differences are small but systematic and reproducible during the intercomparison.
Thibaut Lebourgeois, Bastien Sauvage, Pawel Wolff, Béatrice Josse, Virginie Marécal, Yasmine Bennouna, Romain Blot, Damien Boulanger, Hannah Clark, Jean-Marc Cousin, Philippe Nedelec, and Valérie Thouret
Atmos. Chem. Phys., 24, 13975–14004, https://doi.org/10.5194/acp-24-13975-2024, https://doi.org/10.5194/acp-24-13975-2024, 2024
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Our study examines intense-carbon-monoxide (CO) pollution events measured by commercial aircraft from the In-service Aircraft for a Global Observing System (IAGOS) research infrastructure. We combine these measurements with the SOFT-IO model to trace the origin of the observed CO. A comprehensive analysis of the geographical origin, source type, seasonal variation, and ozone levels of these pollution events is provided.
Xiao Lu, Yiming Liu, Jiayin Su, Xiang Weng, Tabish Ansari, Yuqiang Zhang, Guowen He, Yuqi Zhu, Haolin Wang, Ganquan Zeng, Jingyu Li, Cheng He, Shuai Li, Teerachai Amnuaylojaroen, Tim Butler, Qi Fan, Shaojia Fan, Grant L. Forster, Meng Gao, Jianlin Hu, Yugo Kanaya, Mohd Talib Latif, Keding Lu, Philippe Nédélec, Peer Nowack, Bastien Sauvage, Xiaobin Xu, Lin Zhang, Ke Li, Ja-Ho Koo, and Tatsuya Nagashima
EGUsphere, https://doi.org/10.5194/egusphere-2024-3702, https://doi.org/10.5194/egusphere-2024-3702, 2024
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This study analyzes summertime ozone trends in East and Southeast Asia derived from a comprehensive observational database spanning from 1995 to 2019, incorporating aircraft observations, ozonesonde data, and measurements from 2500 surface sites. Multiple models are applied to attribute to changes in anthropogenic emissions and climate. The results highlight increases in anthropogenic emission are the primary driver of ozone increases both in the free troposphere and at the surface.
Hassnae Erraji, Philipp Franke, Astrid Lampert, Tobias Schuldt, Ralf Tillmann, Andreas Wahner, and Anne Caroline Lange
Atmos. Chem. Phys., 24, 13913–13934, https://doi.org/10.5194/acp-24-13913-2024, https://doi.org/10.5194/acp-24-13913-2024, 2024
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Four-dimensional variational data assimilation allows for the simultaneous optimisation of initial values and emission rates by using trace-gas profiles from drone observations in a regional air quality model. Assimilated profiles positively impact the representation of air pollutants in the model by improving their vertical distribution and ground-level concentrations. This case study highlights the potential of drone data to enhance air quality analyses including local emission evaluation.
Zhou Zang, Jane Liu, David Tarasick, Omid Moeini, Jianchun Bian, Jinqiang Zhang, Anne M. Thompson, Roeland Van Malderen, Herman G. J. Smit, Ryan M. Stauffer, Bryan J. Johnson, and Debra E. Kollonige
Atmos. Chem. Phys., 24, 13889–13912, https://doi.org/10.5194/acp-24-13889-2024, https://doi.org/10.5194/acp-24-13889-2024, 2024
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The Trajectory-mapped Ozonesonde dataset for the Stratosphere and Troposphere (TOST) provides a global-scale, long-term ozone climatology that is horizontally and vertically resolved. In this study, we improved, updated and validated TOST from 1970 to 2021. Based on this TOST dataset, we characterized global ozone variations spatially in both the troposphere and stratosphere and temporally by season and decade. We also showed a stagnant lower stratospheric ozone variation since the late 1990s.
Rodrigo J. Seguel, Charlie Opazo, Yann Cohen, Owen R. Cooper, Laura Gallardo, Björn-Martin Sinnhuber, Florian Obersteiner, Andreas Zahn, Peter Hoor, and Susanne Rohs
EGUsphere, https://doi.org/10.5194/egusphere-2024-3719, https://doi.org/10.5194/egusphere-2024-3719, 2024
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We explored differences in ozone levels between the Northern and Southern Hemispheres in the Stratosphere-troposphere exchange region. Using unique data from a research aircraft, we found significantly lower ozone levels (with stratospheric character) in the Southern Hemisphere, especially during years of severe ozone depletion. A Sudden Stratospheric Warming event in 2019 increased Southern Hemisphere ozone levels, highlighting the relationship between atmospheric events and ozone distribution.
Florian Berg, Anna Novelli, René Dubus, Andreas Hofzumahaus, Frank Holland, Andreas Wahner, and Hendrik Fuchs
Atmos. Chem. Phys., 24, 13715–13731, https://doi.org/10.5194/acp-24-13715-2024, https://doi.org/10.5194/acp-24-13715-2024, 2024
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This study reports temperature-dependent rate coefficients of the reaction of atmospherically relevant hydrocarbons from biogenic sources (methyl vinyl ketones and monoterpenes) and anthropogenic sources (alkanes and aromatics). Measurements were done at atmospheric conditions (ambient pressure and temperature range) in air.
Alena Kosareva, Stamen Dolaptchiev, Peter Spichtinger, and Ulrich Achatz
Geosci. Model Dev. Discuss., https://doi.org/10.5194/gmd-2024-193, https://doi.org/10.5194/gmd-2024-193, 2024
Revised manuscript under review for GMD
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This study improves how we predict ice formation in clouds by accounting for variable ice sizes and different weather conditions. Using simulations, we developed a more accurate method that works efficiently, making it suitable for application in weather and climate prediction models. The new approach is numerically verified and provides precise predictions of ice formation events and reliable estimates of key parameters.
Gérard Ancellet, Camille Viatte, Anne Boynard, François Ravetta, Jacques Pelon, Cristelle Cailteau-Fischbach, Pascal Genau, Julie Capo, Axel Roy, and Philippe Nédélec
Atmos. Chem. Phys., 24, 12963–12983, https://doi.org/10.5194/acp-24-12963-2024, https://doi.org/10.5194/acp-24-12963-2024, 2024
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Characterization of ozone pollution in urban areas benefited from a measurement campaign in summer 2022 in the Paris region. The analysis is based on 21 d of lidar and aircraft observations. The main objective is an analysis of the sensitivity of ozone pollution to the micrometeorological processes in the urban atmospheric boundary layer and the transport of regional pollution. The paper also discusses to what extent satellite observations can track observed ozone plumes.
Honglei Wang, David W. Tarasick, Jane Liu, Herman G. J. Smit, Roeland Van Malderen, Lijuan Shen, Romain Blot, and Tianliang Zhao
Atmos. Chem. Phys., 24, 11927–11942, https://doi.org/10.5194/acp-24-11927-2024, https://doi.org/10.5194/acp-24-11927-2024, 2024
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In this study, we identify 23 suitable pairs of sites from World Ozone and Ultraviolet Radiation Data Centre (WOUDC) and In-service Aircraft for a Global Observing System (IAGOS) datasets (1995 to 2021), compare the average vertical distributions of tropospheric O3 from ozonesonde and aircraft measurements, and analyze the differences based on ozonesonde type and station–airport distance.
Patrick Peter, Sigrun Matthes, Christine Frömming, Patrick Jöckel, Luca Bugliaro, Andreas Giez, Martina Krämer, and Volker Grewe
EGUsphere, https://doi.org/10.5194/egusphere-2024-2142, https://doi.org/10.5194/egusphere-2024-2142, 2024
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Our study examines how temperature and humidity representations influence contrail (-cirrus) formation criteria. Using various model setups, we identified biases that lead to overestimation of contrail formation areas. By comparing simulations with in-flight and satellite observations, we confirmed that humidity threshold choices greatly affect contrail predictions. These findings can help develop strategies for climate-optimized flight routes, potentially reducing aviation's climate effect.
Daniel Köhler, Philipp Reutter, and Peter Spichtinger
Atmos. Chem. Phys., 24, 10055–10072, https://doi.org/10.5194/acp-24-10055-2024, https://doi.org/10.5194/acp-24-10055-2024, 2024
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In this work, the influence of humidity on the properties of the tropopause is studied. The tropopause is the interface between the troposphere and the stratosphere and represents a barrier for the transport of air masses between the troposphere and the stratosphere. We consider not only the tropopause itself, but also a layer around it called the tropopause inversion layer (TIL). It is shown that the moister the underlying atmosphere is, the more this layer acts as a barrier.
Kuo-Ying Wang, Philippe Nedelec, Valerie Thouret, Hannah Clark, Andreas Wahner, and Andreas Petzold
EGUsphere, https://doi.org/10.5194/egusphere-2024-2414, https://doi.org/10.5194/egusphere-2024-2414, 2024
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We use routine in-service commercial passenger airplanes Airbus A340 and A330 to collect air pollutants in the upper troposphere. The beauty in using commercial airplanes is that these commercial airplanes, like taxi on the ground, keep flying all the time. We find that short-lived air pollutants are very sensitive to ground-level emissions. Effective regulation in ground-level emissions can help to reduce air pollution in the upper troposphere.
Yann Cohen, Didier Hauglustaine, Nicolas Bellouin, Marianne Tronstad Lund, Sigrun Matthes, Agnieszka Skowron, Robin Thor, Ulrich Bundke, Andreas Petzold, Susanne Rohs, Valérie Thouret, Andreas Zahn, and Helmut Ziereis
EGUsphere, https://doi.org/10.5194/egusphere-2024-2208, https://doi.org/10.5194/egusphere-2024-2208, 2024
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The chemical composition of the atmosphere near the tropopause is a key parameter for evaluating the climate impact of subsonic aviation pollutants. This study uses in-situ data on board passenger aircraft to assess the ability of 5 chemistry-climate models to reproduce (bi-)decadal climatologies in ozone, carbon monoxide, water vapour, and reactive nitrogen in this region. The models reproduce well the very distinct ozone seasonality in the upper troposphere and in the lower stratosphere.
Sina Hofer, Klaus Gierens, and Susanne Rohs
Atmos. Chem. Phys., 24, 7911–7925, https://doi.org/10.5194/acp-24-7911-2024, https://doi.org/10.5194/acp-24-7911-2024, 2024
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We try to improve the forecast of ice supersaturation (ISS) and potential persistent contrails using data on dynamical quantities in addition to temperature and relative humidity in a modern kind of regression model. Although the results are improved, they are not good enough for flight routing. The origin of the problem is the strong overlap of probability densities conditioned on cases with and without ice-supersaturated regions (ISSRs) in the important range of 70–100 %.
Arno Keppens, Serena Di Pede, Daan Hubert, Jean-Christopher Lambert, Pepijn Veefkind, Maarten Sneep, Johan De Haan, Mark ter Linden, Thierry Leblanc, Steven Compernolle, Tijl Verhoelst, José Granville, Oindrila Nath, Ann Mari Fjæraa, Ian Boyd, Sander Niemeijer, Roeland Van Malderen, Herman G. J. Smit, Valentin Duflot, Sophie Godin-Beekmann, Bryan J. Johnson, Wolfgang Steinbrecht, David W. Tarasick, Debra E. Kollonige, Ryan M. Stauffer, Anne M. Thompson, Angelika Dehn, and Claus Zehner
Atmos. Meas. Tech., 17, 3969–3993, https://doi.org/10.5194/amt-17-3969-2024, https://doi.org/10.5194/amt-17-3969-2024, 2024
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The Sentinel-5P satellite operated by the European Space Agency has carried the TROPOspheric Monitoring Instrument (TROPOMI) around the Earth since October 2017. This mission also produces atmospheric ozone profile data which are described in detail for May 2018 to April 2023. Independent validation using ground-based reference measurements demonstrates that the operational ozone profile product mostly fully and at least partially complies with all mission requirements.
Roger Teoh, Zebediah Engberg, Ulrich Schumann, Christiane Voigt, Marc Shapiro, Susanne Rohs, and Marc E. J. Stettler
Atmos. Chem. Phys., 24, 6071–6093, https://doi.org/10.5194/acp-24-6071-2024, https://doi.org/10.5194/acp-24-6071-2024, 2024
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The radiative forcing (RF) due to aviation contrails is comparable to that caused by CO2. We estimate that global contrail net RF in 2019 was 62.1 mW m−2. This is ~1/2 the previous best estimate for 2018. Contrail RF varies regionally due to differences in conditions required for persistent contrails. COVID-19 reduced contrail RF by 54% in 2020 relative to 2019. Globally, 2 % of all flights account for 80 % of the annual contrail energy forcing, suggesting a opportunity to mitigate contrail RF.
Sidiki Sanogo, Olivier Boucher, Nicolas Bellouin, Audran Borella, Kevin Wolf, and Susanne Rohs
Atmos. Chem. Phys., 24, 5495–5511, https://doi.org/10.5194/acp-24-5495-2024, https://doi.org/10.5194/acp-24-5495-2024, 2024
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Relative humidity relative to ice (RHi) is a key variable in the formation of cirrus clouds and contrails. This study shows that the properties of the probability density function of RHi differ between the tropics and higher latitudes. In line with RHi and temperature variability, aircraft are likely to produce more contrails with bioethanol and liquid hydrogen as fuel. The impact of this fuel change decreases with decreasing pressure levels but increases from high latitudes to the tropics.
Andreas Petzold, Ulrich Bundke, Anca Hienola, Paolo Laj, Cathrine Lund Myhre, Alex Vermeulen, Angeliki Adamaki, Werner Kutsch, Valerie Thouret, Damien Boulanger, Markus Fiebig, Markus Stocker, Zhiming Zhao, and Ari Asmi
Atmos. Chem. Phys., 24, 5369–5388, https://doi.org/10.5194/acp-24-5369-2024, https://doi.org/10.5194/acp-24-5369-2024, 2024
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Easy and fast access to long-term and high-quality observational data is recognised as fundamental to environmental research and the development of climate forecasting and assessment services. We discuss the potential new directions in atmospheric sciences offered by the atmosphere-centric European research infrastructures ACTRIS, IAGOS, and ICOS, building on their capabilities for standardised provision of data through open access combined with tools and methods of data-intensive science.
Yarê Baker, Sungah Kang, Hui Wang, Rongrong Wu, Jian Xu, Annika Zanders, Quanfu He, Thorsten Hohaus, Till Ziehm, Veronica Geretti, Thomas J. Bannan, Simon P. O'Meara, Aristeidis Voliotis, Mattias Hallquist, Gordon McFiggans, Sören R. Zorn, Andreas Wahner, and Thomas F. Mentel
Atmos. Chem. Phys., 24, 4789–4807, https://doi.org/10.5194/acp-24-4789-2024, https://doi.org/10.5194/acp-24-4789-2024, 2024
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Highly oxygenated organic molecules are important contributors to secondary organic aerosol. Their yield depends on detailed atmospheric chemical composition. One important parameter is the ratio of hydroperoxy radicals to organic peroxy radicals (HO2/RO2), and we show that higher HO2/RO2 ratios lower the secondary organic aerosol yield. This is of importance as laboratory studies are often biased towards organic peroxy radicals.
Ella Gilbert, Jhaswantsing Purseed, Yun Li, Martina Krämer, Beatrice Altamura, and Nicolas Bellouin
EGUsphere, https://doi.org/10.5194/egusphere-2024-821, https://doi.org/10.5194/egusphere-2024-821, 2024
Preprint withdrawn
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We use a simple experiment to explore the non-CO2 impacts of aviation on climate, which are considerably larger than the impact of the sector’s carbon emissions alone. We show that the main effect of our experiments – which intend to mimic the effect of aircraft soot emissions reaching existing high-altitude cirrus clouds – is to extend cloud lifetime, thereby enhancing their effect on climate.
Rongrong Wu, Sören R. Zorn, Sungah Kang, Astrid Kiendler-Scharr, Andreas Wahner, and Thomas F. Mentel
Atmos. Meas. Tech., 17, 1811–1835, https://doi.org/10.5194/amt-17-1811-2024, https://doi.org/10.5194/amt-17-1811-2024, 2024
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Recent advances in high-resolution time-of-flight chemical ionization mass spectrometry (CIMS) enable the detection of highly oxygenated organic molecules, which efficiently contribute to secondary organic aerosol. Here we present an application of fuzzy c-means (FCM) clustering to deconvolve CIMS data. FCM not only reduces the complexity of mass spectrometric data but also the chemical and kinetic information retrieved by clustering gives insights into the chemical processes involved.
Irene Bartolomé García, Odran Sourdeval, Reinhold Spang, and Martina Krämer
Atmos. Chem. Phys., 24, 1699–1716, https://doi.org/10.5194/acp-24-1699-2024, https://doi.org/10.5194/acp-24-1699-2024, 2024
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How many ice crystals of each size are in a cloud is a key parameter for the retrieval of cloud properties. The distribution of ice crystals is obtained from in situ measurements and used to create parameterizations that can be used when analyzing the remote-sensing data. Current parameterizations are based on data sets that do not include reliable measurements of small crystals, but in our study we use a data set that includes very small ice crystals to improve these parameterizations.
Herman G. J. Smit, Deniz Poyraz, Roeland Van Malderen, Anne M. Thompson, David W. Tarasick, Ryan M. Stauffer, Bryan J. Johnson, and Debra E. Kollonige
Atmos. Meas. Tech., 17, 73–112, https://doi.org/10.5194/amt-17-73-2024, https://doi.org/10.5194/amt-17-73-2024, 2024
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This paper revisits fundamentals of ECC ozonesonde measurements to develop and characterize a methodology to correct for the fast and slow time responses using the JOSIE (Jülich Ozone Sonde Intercomparison Experiment) simulation chamber data. Comparing the new corrected ozonesonde profiles to an accurate ozone UV photometer (OPM) as reference allows us to evaluate the time response correction (TRC) method and to determine calibration functions traceable to one reference with 5 % uncertainty.
Yann Cohen, Didier Hauglustaine, Bastien Sauvage, Susanne Rohs, Patrick Konjari, Ulrich Bundke, Andreas Petzold, Valérie Thouret, Andreas Zahn, and Helmut Ziereis
Atmos. Chem. Phys., 23, 14973–15009, https://doi.org/10.5194/acp-23-14973-2023, https://doi.org/10.5194/acp-23-14973-2023, 2023
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The upper troposphere–lower stratosphere (UTLS) is a key region regarding the lower atmospheric composition. This study consists of a comprehensive evaluation of an up-to-date chemistry–climate model in this layer, using regular in situ measurements based on passenger aircraft. For this purpose, a specific software (Interpol-IAGOS) has been updated and made publicly available. The model reproduces the carbon monoxide peaks due to biomass burning over the continental tropics particularly well.
Maria Tsivlidou, Bastien Sauvage, Yasmine Bennouna, Romain Blot, Damien Boulanger, Hannah Clark, Eric Le Flochmoën, Philippe Nédélec, Valérie Thouret, Pawel Wolff, and Brice Barret
Atmos. Chem. Phys., 23, 14039–14063, https://doi.org/10.5194/acp-23-14039-2023, https://doi.org/10.5194/acp-23-14039-2023, 2023
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The tropics are a region where the ozone increase has been most apparent since 1980 and where observations are sparse. Using aircraft, satellite, and model data, we document the characteristics of tropospheric ozone and CO over the whole tropics for the last 2 decades. We explore the origin of the observed CO anomalies and investigate transport processes driving the tropical CO and O3 distribution. Our study highlights the importance of anthropogenic emissions, mostly over the northern tropics.
Francesco Cairo, Martina Krämer, Armin Afchine, Guido Di Donfrancesco, Luca Di Liberto, Sergey Khaykin, Lorenza Lucaferri, Valentin Mitev, Max Port, Christian Rolf, Marcel Snels, Nicole Spelten, Ralf Weigel, and Stephan Borrmann
Atmos. Meas. Tech., 16, 4899–4925, https://doi.org/10.5194/amt-16-4899-2023, https://doi.org/10.5194/amt-16-4899-2023, 2023
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Cirrus clouds have been observed over the Himalayan region between 10 km and the tropopause at 17–18 km. Data from backscattersonde, hygrometers, and particle cloud spectrometers have been compared to assess their consistency. Empirical relationships between optical parameters accessible with remote sensing lidars and cloud microphysical parameters (such as ice water content, particle number and surface area density, and particle aspherical fraction) have been established.
Elena De La Torre Castro, Tina Jurkat-Witschas, Armin Afchine, Volker Grewe, Valerian Hahn, Simon Kirschler, Martina Krämer, Johannes Lucke, Nicole Spelten, Heini Wernli, Martin Zöger, and Christiane Voigt
Atmos. Chem. Phys., 23, 13167–13189, https://doi.org/10.5194/acp-23-13167-2023, https://doi.org/10.5194/acp-23-13167-2023, 2023
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In this study, we show the differences in the microphysical properties between high-latitude (HL) cirrus and mid-latitude (ML) cirrus over the Arctic, North Atlantic, and central Europe during summer. The in situ measurements are combined with backward trajectories to investigate the influence of the region on cloud formation. We show that HL cirrus are characterized by a lower concentration of larger ice crystals when compared to ML cirrus.
Paul Konopka, Christian Rolf, Marc von Hobe, Sergey M. Khaykin, Benjamin Clouser, Elisabeth Moyer, Fabrizio Ravegnani, Francesco D'Amato, Silvia Viciani, Nicole Spelten, Armin Afchine, Martina Krämer, Fred Stroh, and Felix Ploeger
Atmos. Chem. Phys., 23, 12935–12947, https://doi.org/10.5194/acp-23-12935-2023, https://doi.org/10.5194/acp-23-12935-2023, 2023
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We studied water vapor in a critical region of the atmosphere, the Asian summer monsoon anticyclone, using rare in situ observations. Our study shows that extremely high water vapor values observed in the stratosphere within the Asian monsoon anticyclone still undergo significant freeze-drying and that water vapor concentrations set by the Lagrangian dry point are a better proxy for the stratospheric water vapor budget than rare observations of enhanced water mixing ratios.
Jacky Y. S. Pang, Florian Berg, Anna Novelli, Birger Bohn, Michelle Färber, Philip T. M. Carlsson, René Dubus, Georgios I. Gkatzelis, Franz Rohrer, Sergej Wedel, Andreas Wahner, and Hendrik Fuchs
Atmos. Chem. Phys., 23, 12631–12649, https://doi.org/10.5194/acp-23-12631-2023, https://doi.org/10.5194/acp-23-12631-2023, 2023
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In this study, the oxidations of sabinene by OH radicals and ozone were investigated with an atmospheric simulation chamber. Reaction rate coefficients of the OH-oxidation reaction at temperatures between 284 to 340 K were determined for the first time in the laboratory by measuring the OH reactivity. Product yields determined in chamber experiments had good agreement with literature values, but discrepancies were found between experimental yields and expected yields from oxidation mechanisms.
Silke Groß, Tina Jurkat-Witschas, Qiang Li, Martin Wirth, Benedikt Urbanek, Martina Krämer, Ralf Weigel, and Christiane Voigt
Atmos. Chem. Phys., 23, 8369–8381, https://doi.org/10.5194/acp-23-8369-2023, https://doi.org/10.5194/acp-23-8369-2023, 2023
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Aviation-emitted aerosol can have an impact on cirrus clouds. We present optical and microphysical properties of mid-latitude cirrus clouds which were formed under the influence of aviation-emitted aerosol or which were formed under rather pristine conditions. We find that cirrus clouds affected by aviation-emitted aerosol show larger values of the particle linear depolarization ratio, larger mean effective ice particle diameters and decreased ice particle number concentrations.
Patrick Weber, Oliver F. Bischof, Benedikt Fischer, Marcel Berg, Susanne Hering, Steven Spielman, Gregory Lewis, Andreas Petzold, and Ulrich Bundke
Atmos. Meas. Tech., 16, 3505–3514, https://doi.org/10.5194/amt-16-3505-2023, https://doi.org/10.5194/amt-16-3505-2023, 2023
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This study tests the new water condensation particle counter (MAGIC 210-LP) for deployment on passenger aircraft coordinated by the European research infrastructure IAGOS. We conducted a series of laboratory experiments for flight altitude conditions. We demonstrate that this water condensation particle counter model shows excellent agreement with a butanol-based instrument used in parallel and a Faraday cup electrometer as reference instrument at all tested pressure conditions.
Hao Luo, Luc Vereecken, Hongru Shen, Sungah Kang, Iida Pullinen, Mattias Hallquist, Hendrik Fuchs, Andreas Wahner, Astrid Kiendler-Scharr, Thomas F. Mentel, and Defeng Zhao
Atmos. Chem. Phys., 23, 7297–7319, https://doi.org/10.5194/acp-23-7297-2023, https://doi.org/10.5194/acp-23-7297-2023, 2023
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Oxidation of limonene, an element emitted by trees and chemical products, by OH, a daytime oxidant, forms many highly oxygenated organic molecules (HOMs), including C10-20 compounds. HOMs play an important role in new particle formation and growth. HOM formation can be explained by the chemistry of peroxy radicals. We found that a minor branching ratio initial pathway plays an unexpected, significant role. Considering this pathway enables accurate simulations of HOMs and other concentrations.
Patrick Weber, Oliver F. Bischof, Benedikt Fischer, Marcel Berg, Jannik Schmitt, Gerhard Steiner, Lothar Keck, Andreas Petzold, and Ulrich Bundke
Aerosol Research, 1, 1–12, https://doi.org/10.5194/ar-1-1-2023, https://doi.org/10.5194/ar-1-1-2023, 2023
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The aerosol number concentration is essential information for aerosol science. A condensation particle counter (CPC) can robustly provide this information. Butanol is often used as a working fluid in a CPC. We could show that dimethyl sulfoxide (DMSO) behaves equivalently to butanol in terms of the instrument`s counting efficiency, cut-off diameter and concentration linearity. We tested this on different aerosols, including sodium chloride, ammonium sulfate and fresh combustion soot.
Xiaoyi Zhao, Vitali Fioletov, Alberto Redondas, Julian Gröbner, Luca Egli, Franz Zeilinger, Javier López-Solano, Alberto Berjón Arroyo, James Kerr, Eliane Maillard Barras, Herman Smit, Michael Brohart, Reno Sit, Akira Ogyu, Ihab Abboud, and Sum Chi Lee
Atmos. Meas. Tech., 16, 2273–2295, https://doi.org/10.5194/amt-16-2273-2023, https://doi.org/10.5194/amt-16-2273-2023, 2023
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The Brewer ozone spectrophotometer is one of the World Meteorological Organization (WMO) Global Atmosphere Watch (GAW)'s standard ozone monitoring instruments since the 1980s. This work is aimed at obtaining answers to (1) why Brewer primary calibration work can only be performed at certain sites (e.g., Izaña and MLO) and (2) what is needed to assure the equivalence of calibration quality from different sites.
Philip T. M. Carlsson, Luc Vereecken, Anna Novelli, François Bernard, Steven S. Brown, Bellamy Brownwood, Changmin Cho, John N. Crowley, Patrick Dewald, Peter M. Edwards, Nils Friedrich, Juliane L. Fry, Mattias Hallquist, Luisa Hantschke, Thorsten Hohaus, Sungah Kang, Jonathan Liebmann, Alfred W. Mayhew, Thomas Mentel, David Reimer, Franz Rohrer, Justin Shenolikar, Ralf Tillmann, Epameinondas Tsiligiannis, Rongrong Wu, Andreas Wahner, Astrid Kiendler-Scharr, and Hendrik Fuchs
Atmos. Chem. Phys., 23, 3147–3180, https://doi.org/10.5194/acp-23-3147-2023, https://doi.org/10.5194/acp-23-3147-2023, 2023
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The investigation of the night-time oxidation of the most abundant hydrocarbon, isoprene, in chamber experiments shows the importance of reaction pathways leading to epoxy products, which could enhance particle formation, that have so far not been accounted for. The chemical lifetime of organic nitrates from isoprene is long enough for the majority to be further oxidized the next day by daytime oxidants.
Georgios Dekoutsidis, Silke Groß, Martin Wirth, Martina Krämer, and Christian Rolf
Atmos. Chem. Phys., 23, 3103–3117, https://doi.org/10.5194/acp-23-3103-2023, https://doi.org/10.5194/acp-23-3103-2023, 2023
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Cirrus clouds affect Earth's atmosphere, deeming our study important. Here we use water vapor measurements by lidar and study the relative humidity (RHi) within and around midlatitude cirrus clouds. We find high supersaturations in the cloud-free air and within the clouds, especially near the cloud top. We study two cloud types with different formation processes. Finally, we conclude that the shape of the distribution of RHi can be used as an indicator of different cloud evolutionary stages.
Fayçal Lamraoui, Martina Krämer, Armin Afchine, Adam B. Sokol, Sergey Khaykin, Apoorva Pandey, and Zhiming Kuang
Atmos. Chem. Phys., 23, 2393–2419, https://doi.org/10.5194/acp-23-2393-2023, https://doi.org/10.5194/acp-23-2393-2023, 2023
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Cirrus in the tropical tropopause layer (TTL) can play a key role in vertical transport. We investigate the role of different cloud regimes and the associated ice habits in regulating the properties of the TTL. We use high-resolution numerical experiments at the scales of large-eddy simulations (LESs) and aircraft measurements. We found that LES-scale parameterizations that predict ice shape are crucial for an accurate representation of TTL cirrus and thus the associated (de)hydration process.
Yun Li, Christoph Mahnke, Susanne Rohs, Ulrich Bundke, Nicole Spelten, Georgios Dekoutsidis, Silke Groß, Christiane Voigt, Ulrich Schumann, Andreas Petzold, and Martina Krämer
Atmos. Chem. Phys., 23, 2251–2271, https://doi.org/10.5194/acp-23-2251-2023, https://doi.org/10.5194/acp-23-2251-2023, 2023
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The radiative effect of aviation-induced cirrus is closely related to ambient conditions and its microphysical properties. Our study investigated the occurrence of contrail and natural cirrus measured above central Europe in spring 2014. It finds that contrail cirrus appears frequently in the pressure range 200 to 245 hPa and occurs more often in slightly ice-subsaturated environments than expected. Avoiding slightly ice-subsaturated regions by aviation might help mitigate contrail cirrus.
Clément Narbaud, Jean-Daniel Paris, Sophie Wittig, Antoine Berchet, Marielle Saunois, Philippe Nédélec, Boris D. Belan, Mikhail Y. Arshinov, Sergei B. Belan, Denis Davydov, Alexander Fofonov, and Artem Kozlov
Atmos. Chem. Phys., 23, 2293–2314, https://doi.org/10.5194/acp-23-2293-2023, https://doi.org/10.5194/acp-23-2293-2023, 2023
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We measured CH4 and CO2 from aircraft over the Russian Arctic. Analyzing our data with the Lagrangian model FLEXPART, we find a sharp east–west gradient in atmospheric composition. Western Siberia is influenced by strong wetland CH4 emissions, deep CO2 gradient from biospheric uptake, and long-range transport from Europe and North America. Eastern flights document less variability. Over the Arctic Ocean, we find a small influence from marine CH4 emissions compatible with reasonable inventories.
Changmin Cho, Hendrik Fuchs, Andreas Hofzumahaus, Frank Holland, William J. Bloss, Birger Bohn, Hans-Peter Dorn, Marvin Glowania, Thorsten Hohaus, Lu Liu, Paul S. Monks, Doreen Niether, Franz Rohrer, Roberto Sommariva, Zhaofeng Tan, Ralf Tillmann, Astrid Kiendler-Scharr, Andreas Wahner, and Anna Novelli
Atmos. Chem. Phys., 23, 2003–2033, https://doi.org/10.5194/acp-23-2003-2023, https://doi.org/10.5194/acp-23-2003-2023, 2023
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With this study, we investigated the processes leading to the formation, destruction, and recycling of radicals for four seasons in a rural environment. Complete knowledge of their chemistry is needed if we are to predict the formation of secondary pollutants from primary emissions. The results highlight a still incomplete understanding of the paths leading to the formation of the OH radical, which has been observed in several other environments as well and needs to be further investigated.
Andreas Marsing, Ralf Meerkötter, Romy Heller, Stefan Kaufmann, Tina Jurkat-Witschas, Martina Krämer, Christian Rolf, and Christiane Voigt
Atmos. Chem. Phys., 23, 587–609, https://doi.org/10.5194/acp-23-587-2023, https://doi.org/10.5194/acp-23-587-2023, 2023
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We employ highly resolved aircraft measurements of profiles of the ice water content (IWC) in Arctic cirrus clouds in winter and spring, when solar irradiation is low. Using radiation transfer calculations, we assess the cloud radiative effect over different surfaces like snow or ocean. The variability in the IWC of the clouds affects their overall radiative effect and drives internal processes. This helps understand the role of cirrus in a rapidly changing Arctic environment.
Antje Inness, Ilse Aben, Melanie Ades, Tobias Borsdorff, Johannes Flemming, Luke Jones, Jochen Landgraf, Bavo Langerock, Philippe Nedelec, Mark Parrington, and Roberto Ribas
Atmos. Chem. Phys., 22, 14355–14376, https://doi.org/10.5194/acp-22-14355-2022, https://doi.org/10.5194/acp-22-14355-2022, 2022
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The Copernicus Atmosphere Monitoring Service (CAMS) provides daily global air quality forecasts to users worldwide. One of the species of interest is carbon monoxide (CO), an important trace gas in the atmosphere with anthropogenic and natural sources, produced by incomplete combustion, for example, by wildfires. This paper looks at how well CAMS can model CO in the atmosphere and shows that the fields can be improved when blending CO data from the TROPOMI instrument with the CAMS model.
Haolin Wang, Xiao Lu, Daniel J. Jacob, Owen R. Cooper, Kai-Lan Chang, Ke Li, Meng Gao, Yiming Liu, Bosi Sheng, Kai Wu, Tongwen Wu, Jie Zhang, Bastien Sauvage, Philippe Nédélec, Romain Blot, and Shaojia Fan
Atmos. Chem. Phys., 22, 13753–13782, https://doi.org/10.5194/acp-22-13753-2022, https://doi.org/10.5194/acp-22-13753-2022, 2022
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We report significant global tropospheric ozone increases in 1995–2017 based on extensive aircraft and ozonesonde observations. Using GEOS-Chem (Goddard Earth Observing System chemistry model) multi-decadal global simulations, we find that changes in global anthropogenic emissions, in particular the rapid increases in aircraft emissions, contribute significantly to the increases in tropospheric ozone and resulting radiative impact.
Zhaofeng Tan, Hendrik Fuchs, Andreas Hofzumahaus, William J. Bloss, Birger Bohn, Changmin Cho, Thorsten Hohaus, Frank Holland, Chandrakiran Lakshmisha, Lu Liu, Paul S. Monks, Anna Novelli, Doreen Niether, Franz Rohrer, Ralf Tillmann, Thalassa S. E. Valkenburg, Vaishali Vardhan, Astrid Kiendler-Scharr, Andreas Wahner, and Roberto Sommariva
Atmos. Chem. Phys., 22, 13137–13152, https://doi.org/10.5194/acp-22-13137-2022, https://doi.org/10.5194/acp-22-13137-2022, 2022
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During the 2019 JULIAC campaign, ClNO2 was measured at a rural site in Germany in different seasons. The highest ClNO2 level was 1.6 ppbv in September. ClNO2 production was more sensitive to the availability of NO2 than O3. The average ClNO2 production efficiency was up to 18 % in February and September and down to 3 % in December. These numbers are at the high end of the values reported in the literature, indicating the importance of ClNO2 chemistry in rural environments in midwestern Europe.
Yindong Guo, Hongru Shen, Iida Pullinen, Hao Luo, Sungah Kang, Luc Vereecken, Hendrik Fuchs, Mattias Hallquist, Ismail-Hakki Acir, Ralf Tillmann, Franz Rohrer, Jürgen Wildt, Astrid Kiendler-Scharr, Andreas Wahner, Defeng Zhao, and Thomas F. Mentel
Atmos. Chem. Phys., 22, 11323–11346, https://doi.org/10.5194/acp-22-11323-2022, https://doi.org/10.5194/acp-22-11323-2022, 2022
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The oxidation of limonene, a common volatile emitted by trees and chemical products, by NO3, a nighttime oxidant, forms many highly oxygenated organic molecules (HOM), including C10-30 compounds. Most of the HOM are second-generation organic nitrates, in which carbonyl-substituted C10 nitrates accounted for a major fraction. Their formation can be explained by chemistry of peroxy radicals. HOM, especially low-volatile ones, play an important role in nighttime new particle formation and growth.
Clare E. Singer, Benjamin W. Clouser, Sergey M. Khaykin, Martina Krämer, Francesco Cairo, Thomas Peter, Alexey Lykov, Christian Rolf, Nicole Spelten, Armin Afchine, Simone Brunamonti, and Elisabeth J. Moyer
Atmos. Meas. Tech., 15, 4767–4783, https://doi.org/10.5194/amt-15-4767-2022, https://doi.org/10.5194/amt-15-4767-2022, 2022
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In situ measurements of water vapor in the upper troposphere are necessary to study cloud formation and hydration of the stratosphere but challenging due to cold–dry conditions. We compare measurements from three water vapor instruments from the StratoClim campaign in 2017. In clear sky (clouds), point-by-point differences were <1.5±8 % (<1±8 %). This excellent agreement allows detection of fine-scale structures required to understand the impact of convection on stratospheric water vapor.
Boris D. Belan, Gerard Ancellet, Irina S. Andreeva, Pavel N. Antokhin, Viktoria G. Arshinova, Mikhail Y. Arshinov, Yurii S. Balin, Vladimir E. Barsuk, Sergei B. Belan, Dmitry G. Chernov, Denis K. Davydov, Alexander V. Fofonov, Georgii A. Ivlev, Sergei N. Kotel'nikov, Alexander S. Kozlov, Artem V. Kozlov, Katharine Law, Andrey V. Mikhal'chishin, Igor A. Moseikin, Sergei V. Nasonov, Philippe Nédélec, Olesya V. Okhlopkova, Sergei E. Ol'kin, Mikhail V. Panchenko, Jean-Daniel Paris, Iogannes E. Penner, Igor V. Ptashnik, Tatyana M. Rasskazchikova, Irina K. Reznikova, Oleg A. Romanovskii, Alexander S. Safatov, Denis E. Savkin, Denis V. Simonenkov, Tatyana K. Sklyadneva, Gennadii N. Tolmachev, Semyon V. Yakovlev, and Polina N. Zenkova
Atmos. Meas. Tech., 15, 3941–3967, https://doi.org/10.5194/amt-15-3941-2022, https://doi.org/10.5194/amt-15-3941-2022, 2022
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The change of the global climate is most pronounced in the Arctic, where the air temperature increases faster than the global average. This is associated with an increase in the concentration of greenhouse gases in the atmosphere. It is important to study how the air composition in the Arctic changes in the changing climate. Thus this integrated experiment was carried out to measure the composition of the troposphere in the Russian sector of the Arctic from on board the aircraft laboratory.
Jacky Yat Sing Pang, Anna Novelli, Martin Kaminski, Ismail-Hakki Acir, Birger Bohn, Philip T. M. Carlsson, Changmin Cho, Hans-Peter Dorn, Andreas Hofzumahaus, Xin Li, Anna Lutz, Sascha Nehr, David Reimer, Franz Rohrer, Ralf Tillmann, Robert Wegener, Astrid Kiendler-Scharr, Andreas Wahner, and Hendrik Fuchs
Atmos. Chem. Phys., 22, 8497–8527, https://doi.org/10.5194/acp-22-8497-2022, https://doi.org/10.5194/acp-22-8497-2022, 2022
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This study investigates the radical chemical budget during the limonene oxidation at different atmospheric-relevant NO concentrations in chamber experiments under atmospheric conditions. It is found that the model–measurement discrepancies of HO2 and RO2 are very large at low NO concentrations that are typical for forested environments. Possible additional processes impacting HO2 and RO2 concentrations are discussed.
Klaus Gierens, Lena Wilhelm, Sina Hofer, and Susanne Rohs
Atmos. Chem. Phys., 22, 7699–7712, https://doi.org/10.5194/acp-22-7699-2022, https://doi.org/10.5194/acp-22-7699-2022, 2022
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We are interested in the prediction of condensation trails, in particular strong ones. For this we need a good forecast of temperature and humidity in the levels where aircraft cruise. Unfortunately, the humidity forecast is quite difficult for these levels, in particular the ice supersaturation, which is needed for long-lasting contrails. We are thus seeking proxy variables that help distinguish situations where strong contrails can form, for instance the lapse rate.
Patrick Weber, Andreas Petzold, Oliver F. Bischof, Benedikt Fischer, Marcel Berg, Andrew Freedman, Timothy B. Onasch, and Ulrich Bundke
Atmos. Meas. Tech., 15, 3279–3296, https://doi.org/10.5194/amt-15-3279-2022, https://doi.org/10.5194/amt-15-3279-2022, 2022
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In our laboratory closure study, we measured the full set of aerosol optical properties for different light-absorbing aerosols using a set of instruments.
Our key finding is that the extensive and intensive aerosol optical properties obtained agree with data from reference instruments, except the absorption Ångström exponent of externally mixed aerosols. The reported uncertainty in the single-scattering albedo fulfils the defined goals for Global Climate Observing System applications of 10 %.
Gérard Ancellet, Sophie Godin-Beekmann, Herman G. J. Smit, Ryan M. Stauffer, Roeland Van Malderen, Renaud Bodichon, and Andrea Pazmiño
Atmos. Meas. Tech., 15, 3105–3120, https://doi.org/10.5194/amt-15-3105-2022, https://doi.org/10.5194/amt-15-3105-2022, 2022
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The 1991–2021 Observatoire de Haute Provence electrochemical concentration cell (ECC) ozonesonde data have been homogenized according to the recommendations of the Ozonesonde Data Quality Assessment panel. Comparisons with ground-based instruments also measuring ozone at the same station (lidar, surface measurements) and with colocated satellite observations show the benefits of this homogenization. Remaining differences between ECC and other observations in the stratosphere are also discussed.
Dimitris Akritidis, Andrea Pozzer, Johannes Flemming, Antje Inness, Philippe Nédélec, and Prodromos Zanis
Atmos. Chem. Phys., 22, 6275–6289, https://doi.org/10.5194/acp-22-6275-2022, https://doi.org/10.5194/acp-22-6275-2022, 2022
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We perform a process-oriented evaluation of Copernicus Atmosphere Monitoring Service (CAMS) reanalysis (CAMSRA) O3 over Europe using WOUDC (World Ozone and Ultraviolet Radiation Data Centre) ozonesondes and IAGOS (In-service Aircraft for a Global Observing System) aircraft measurements. Chemical data assimilation assists CAMSRA to reproduce the observed O3 increases in the troposphere during the examined folding events, but it mostly results in O3 overestimation in the upper troposphere.
Mireia Papke Chica, Valerian Hahn, Tiziana Braeuer, Elena de la Torre Castro, Florian Ewald, Mathias Gergely, Simon Kirschler, Luca Bugliaro Goggia, Stefanie Knobloch, Martina Kraemer, Johannes Lucke, Johanna Mayer, Raphael Maerkl, Manuel Moser, Laura Tomsche, Tina Jurkat-Witschas, Martin Zoeger, Christian von Savigny, and Christiane Voigt
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2022-255, https://doi.org/10.5194/acp-2022-255, 2022
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The mixed-phase temperature regime in convective clouds challenges our understanding of microphysical and radiative cloud properties. We provide a rare and unique dataset of aircraft in situ measurements in a strong mid-latitude convective system. We find that mechanisms initiating ice nucleation and growth strongly depend on temperature, relative humidity, and vertical velocity and variate within the measured system, resulting in altitude dependent changes of the cloud liquid and ice fraction.
Sergey M. Khaykin, Elizabeth Moyer, Martina Krämer, Benjamin Clouser, Silvia Bucci, Bernard Legras, Alexey Lykov, Armin Afchine, Francesco Cairo, Ivan Formanyuk, Valentin Mitev, Renaud Matthey, Christian Rolf, Clare E. Singer, Nicole Spelten, Vasiliy Volkov, Vladimir Yushkov, and Fred Stroh
Atmos. Chem. Phys., 22, 3169–3189, https://doi.org/10.5194/acp-22-3169-2022, https://doi.org/10.5194/acp-22-3169-2022, 2022
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The Asian monsoon anticyclone is the key contributor to the global annual maximum in lower stratospheric water vapour. We investigate the impact of deep convection on the lower stratospheric water using a unique set of observations aboard the high-altitude M55-Geophysica aircraft deployed in Nepal in summer 2017 within the EU StratoClim project. We find that convective plumes of wet air can persist within the Asian anticyclone for weeks, thereby enhancing the occurrence of high-level clouds.
Martin J. Osborne, Johannes de Leeuw, Claire Witham, Anja Schmidt, Frances Beckett, Nina Kristiansen, Joelle Buxmann, Cameron Saint, Ellsworth J. Welton, Javier Fochesatto, Ana R. Gomes, Ulrich Bundke, Andreas Petzold, Franco Marenco, and Jim Haywood
Atmos. Chem. Phys., 22, 2975–2997, https://doi.org/10.5194/acp-22-2975-2022, https://doi.org/10.5194/acp-22-2975-2022, 2022
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Using the Met Office NAME dispersion model, supported by satellite- and ground-based remote-sensing observations, we describe the dispersion of aerosols from the 2019 Raikoke eruption and the concurrent wildfires in Alberta Canada. We show how the synergy of dispersion modelling and multiple observation sources allowed observers in the London VAAC to arrive at a more complete picture of the aerosol loading at altitudes commonly used by aviation.
Stefan Niebler, Annette Miltenberger, Bertil Schmidt, and Peter Spichtinger
Weather Clim. Dynam., 3, 113–137, https://doi.org/10.5194/wcd-3-113-2022, https://doi.org/10.5194/wcd-3-113-2022, 2022
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We use machine learning to create a network that detects and classifies four types of synoptic-scale weather fronts from ERA5 atmospheric reanalysis data. We present an application of our method, showing its use case in a scientific context. Additionally, our results show that multiple sources of training data are necessary to perform well on different regions, implying differences within those regions. Qualitative evaluation shows that the results are physically plausible.
Dina Khordakova, Christian Rolf, Jens-Uwe Grooß, Rolf Müller, Paul Konopka, Andreas Wieser, Martina Krämer, and Martin Riese
Atmos. Chem. Phys., 22, 1059–1079, https://doi.org/10.5194/acp-22-1059-2022, https://doi.org/10.5194/acp-22-1059-2022, 2022
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Extreme storms transport humidity from the troposphere to the stratosphere. Here it has a strong impact on the climate. With ongoing global warming, we expect more storms and, hence, an enhancement of this effect. A case study was performed in order to measure the impact of the direct injection of water vapor into the lower stratosphere. The measurements displayed a significant transport of water vapor into the lower stratosphere, and this was supported by satellite and reanalysis data.
Manuel Baumgartner, Christian Rolf, Jens-Uwe Grooß, Julia Schneider, Tobias Schorr, Ottmar Möhler, Peter Spichtinger, and Martina Krämer
Atmos. Chem. Phys., 22, 65–91, https://doi.org/10.5194/acp-22-65-2022, https://doi.org/10.5194/acp-22-65-2022, 2022
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An important mechanism for the appearance of ice particles in the upper troposphere at low temperatures is homogeneous nucleation. This process is commonly described by the
Koop line, predicting the humidity at freezing. However, laboratory measurements suggest that the freezing humidities are above the Koop line, motivating the present study to investigate the influence of different physical parameterizations on the homogeneous freezing with the help of a detailed numerical model.
Hannah Clark, Yasmine Bennouna, Maria Tsivlidou, Pawel Wolff, Bastien Sauvage, Brice Barret, Eric Le Flochmoën, Romain Blot, Damien Boulanger, Jean-Marc Cousin, Philippe Nédélec, Andreas Petzold, and Valérie Thouret
Atmos. Chem. Phys., 21, 16237–16256, https://doi.org/10.5194/acp-21-16237-2021, https://doi.org/10.5194/acp-21-16237-2021, 2021
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We examined 27 years of IAGOS (In-service Aircraft for a Global Observing System) profiles at Frankfurt to see if there were unusual features during the spring of 2020 related to COVID-19 lockdowns in Europe. Increased ozone near the surface was partly linked to the reduction in emissions. Carbon monoxide decreased near the surface, but the impact of the lockdowns was offset by polluted air masses from elsewhere. There were small reductions in ozone and carbon monoxide in the free troposphere.
Zhaofeng Tan, Luisa Hantschke, Martin Kaminski, Ismail-Hakki Acir, Birger Bohn, Changmin Cho, Hans-Peter Dorn, Xin Li, Anna Novelli, Sascha Nehr, Franz Rohrer, Ralf Tillmann, Robert Wegener, Andreas Hofzumahaus, Astrid Kiendler-Scharr, Andreas Wahner, and Hendrik Fuchs
Atmos. Chem. Phys., 21, 16067–16091, https://doi.org/10.5194/acp-21-16067-2021, https://doi.org/10.5194/acp-21-16067-2021, 2021
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The photo-oxidation of myrcene, a monoterpene species emitted by plants, was investigated at atmospheric conditions in the outdoor simulation chamber SAPHIR. The chemical structure of myrcene is partly similar to isoprene. Therefore, it can be expected that hydrogen shift reactions could play a role as observed for isoprene. In this work, their potential impact on the regeneration efficiency of hydroxyl radicals is investigated.
Christoph Mahnke, Ralf Weigel, Francesco Cairo, Jean-Paul Vernier, Armin Afchine, Martina Krämer, Valentin Mitev, Renaud Matthey, Silvia Viciani, Francesco D'Amato, Felix Ploeger, Terry Deshler, and Stephan Borrmann
Atmos. Chem. Phys., 21, 15259–15282, https://doi.org/10.5194/acp-21-15259-2021, https://doi.org/10.5194/acp-21-15259-2021, 2021
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In 2017, in situ aerosol measurements were conducted aboard the M55 Geophysica in the Asian monsoon region. The vertical particle mixing ratio profiles show a distinct layer (15–18.5 km), the Asian tropopause aerosol layer (ATAL). The backscatter ratio (BR) was calculated based on the aerosol size distributions and compared with the BRs detected by a backscatter probe and a lidar aboard M55, and by the CALIOP lidar. All four methods show enhanced BRs in the ATAL altitude range (max. at 17.5 km).
Victor Lannuque, Bastien Sauvage, Brice Barret, Hannah Clark, Gilles Athier, Damien Boulanger, Jean-Pierre Cammas, Jean-Marc Cousin, Alain Fontaine, Eric Le Flochmoën, Philippe Nédélec, Hervé Petetin, Isabelle Pfaffenzeller, Susanne Rohs, Herman G. J. Smit, Pawel Wolff, and Valérie Thouret
Atmos. Chem. Phys., 21, 14535–14555, https://doi.org/10.5194/acp-21-14535-2021, https://doi.org/10.5194/acp-21-14535-2021, 2021
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The African intertropical troposphere is one of the world areas where the increase in ozone mixing ratio has been most pronounced since 1980 and where high carbon monoxide mixing ratios are found in altitude. In this article, IAGOS aircraft measurements, IASI satellite instrument observations, and SOFT-IO model products are used to explore the seasonal distribution variations and the origin of ozone and carbon monoxide over the African upper troposphere.
Julia Schneider, Kristina Höhler, Robert Wagner, Harald Saathoff, Martin Schnaiter, Tobias Schorr, Isabelle Steinke, Stefan Benz, Manuel Baumgartner, Christian Rolf, Martina Krämer, Thomas Leisner, and Ottmar Möhler
Atmos. Chem. Phys., 21, 14403–14425, https://doi.org/10.5194/acp-21-14403-2021, https://doi.org/10.5194/acp-21-14403-2021, 2021
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Homogeneous freezing is a relevant mechanism for the formation of cirrus clouds in the upper troposphere. Based on an extensive set of homogeneous freezing experiments at the AIDA chamber with aqueous sulfuric acid aerosol, we provide a new fit line for homogeneous freezing onset conditions of sulfuric acid aerosol focusing on cirrus temperatures. In the atmosphere, homogeneous freezing thresholds have important implications on the cirrus cloud occurrence and related cloud radiative effects.
Ralf Weigel, Christoph Mahnke, Manuel Baumgartner, Martina Krämer, Peter Spichtinger, Nicole Spelten, Armin Afchine, Christian Rolf, Silvia Viciani, Francesco D'Amato, Holger Tost, and Stephan Borrmann
Atmos. Chem. Phys., 21, 13455–13481, https://doi.org/10.5194/acp-21-13455-2021, https://doi.org/10.5194/acp-21-13455-2021, 2021
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In July and August 2017, the StratoClim mission took place in Nepal with eight flights of the M-55 Geophysica at up to 20 km in the Asian monsoon anticyclone. New particle formation (NPF) next to cloud ice was detected in situ by abundant nucleation-mode aerosols (> 6 nm) along with ice particles (> 3 µm). NPF was observed mainly below the tropopause, down to 15 % being non-volatile residues. Observed intra-cloud NPF indicates its importance for the composition in the tropical tropopause layer.
Luisa Hantschke, Anna Novelli, Birger Bohn, Changmin Cho, David Reimer, Franz Rohrer, Ralf Tillmann, Marvin Glowania, Andreas Hofzumahaus, Astrid Kiendler-Scharr, Andreas Wahner, and Hendrik Fuchs
Atmos. Chem. Phys., 21, 12665–12685, https://doi.org/10.5194/acp-21-12665-2021, https://doi.org/10.5194/acp-21-12665-2021, 2021
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The reactions of Δ3-carene with ozone and the hydroxyl radical (OH) and the photolysis and OH reaction of caronaldehyde were investigated in the simulation chamber SAPHIR. Reaction rate constants of these reactions were determined. Caronaldehyde yields of the ozonolysis and OH reaction were determined. The organic nitrate yield of the reaction of Δ3-carene and caronaldehyde-derived peroxy radicals with NO was determined. The ROx budget (ROx = OH+HO2+RO2) was also investigated.
Simon Rosanka, Bruno Franco, Lieven Clarisse, Pierre-François Coheur, Andrea Pozzer, Andreas Wahner, and Domenico Taraborrelli
Atmos. Chem. Phys., 21, 11257–11288, https://doi.org/10.5194/acp-21-11257-2021, https://doi.org/10.5194/acp-21-11257-2021, 2021
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The strong El Niño in 2015 led to a particular dry season in Indonesia and favoured severe peatland fires. The smouldering conditions of these fires and the high carbon content of peat resulted in high volatile organic compound (VOC) emissions. By using a comprehensive atmospheric model, we show that these emissions have a significant impact on the tropospheric composition and oxidation capacity. These emissions are transported into to the lower stratosphere, resulting in a depletion of ozone.
Rongrong Wu, Luc Vereecken, Epameinondas Tsiligiannis, Sungah Kang, Sascha R. Albrecht, Luisa Hantschke, Defeng Zhao, Anna Novelli, Hendrik Fuchs, Ralf Tillmann, Thorsten Hohaus, Philip T. M. Carlsson, Justin Shenolikar, François Bernard, John N. Crowley, Juliane L. Fry, Bellamy Brownwood, Joel A. Thornton, Steven S. Brown, Astrid Kiendler-Scharr, Andreas Wahner, Mattias Hallquist, and Thomas F. Mentel
Atmos. Chem. Phys., 21, 10799–10824, https://doi.org/10.5194/acp-21-10799-2021, https://doi.org/10.5194/acp-21-10799-2021, 2021
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Isoprene is the biogenic volatile organic compound with the largest emissions rates. The nighttime reaction of isoprene with the NO3 radical has a large potential to contribute to SOA. We classified isoprene nitrates into generations and proposed formation pathways. Considering the potential functionalization of the isoprene nitrates we propose that mainly isoprene dimers contribute to SOA formation from the isoprene NO3 reactions with at least a 5 % mass yield.
Simon Rosanka, Rolf Sander, Andreas Wahner, and Domenico Taraborrelli
Geosci. Model Dev., 14, 4103–4115, https://doi.org/10.5194/gmd-14-4103-2021, https://doi.org/10.5194/gmd-14-4103-2021, 2021
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The Jülich Aqueous-phase Mechanism of Organic Chemistry (JAMOC) is developed and implemented into the Module Efficiently Calculating the Chemistry of the Atmosphere (MECCA). JAMOC is an explicit in-cloud oxidation scheme for oxygenated volatile organic compounds (OVOCs), which is suitable for global model applications. Within a box-model study, we show that JAMOC yields reduced gas-phase concentrations of most OVOCs and oxidants, except for nitrogen oxides.
Simon Rosanka, Rolf Sander, Bruno Franco, Catherine Wespes, Andreas Wahner, and Domenico Taraborrelli
Atmos. Chem. Phys., 21, 9909–9930, https://doi.org/10.5194/acp-21-9909-2021, https://doi.org/10.5194/acp-21-9909-2021, 2021
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In-cloud destruction of ozone depends on hydroperoxyl radicals in cloud droplets, where they are produced by oxygenated volatile organic compound (OVOC) oxygenation. Only rudimentary representations of these processes, if any, are currently available in global atmospheric models. By using a comprehensive atmospheric model that includes a complex in-cloud OVOC oxidation scheme, we show that atmospheric oxidants are reduced and models ignoring this process will underpredict clouds as ozone sinks.
Defeng Zhao, Iida Pullinen, Hendrik Fuchs, Stephanie Schrade, Rongrong Wu, Ismail-Hakki Acir, Ralf Tillmann, Franz Rohrer, Jürgen Wildt, Yindong Guo, Astrid Kiendler-Scharr, Andreas Wahner, Sungah Kang, Luc Vereecken, and Thomas F. Mentel
Atmos. Chem. Phys., 21, 9681–9704, https://doi.org/10.5194/acp-21-9681-2021, https://doi.org/10.5194/acp-21-9681-2021, 2021
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The reaction of isoprene, a biogenic volatile organic compound with the globally largest emission rates, with NO3, an nighttime oxidant influenced heavily by anthropogenic emissions, forms a large number of highly oxygenated organic molecules (HOM). These HOM are formed via one or multiple oxidation steps, followed by autoxidation. Their total yield is much higher than that in the daytime oxidation of isoprene. They may play an important role in nighttime organic aerosol formation and growth.
Marvin Glowania, Franz Rohrer, Hans-Peter Dorn, Andreas Hofzumahaus, Frank Holland, Astrid Kiendler-Scharr, Andreas Wahner, and Hendrik Fuchs
Atmos. Meas. Tech., 14, 4239–4253, https://doi.org/10.5194/amt-14-4239-2021, https://doi.org/10.5194/amt-14-4239-2021, 2021
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Three instruments that use different techniques to measure gaseous formaldehyde concentrations were compared in experiments in the atmospheric simulation chamber SAPHIR at Forschungszentrum Jülich. The results demonstrated the need to correct the baseline in measurements by instruments that use the Hantzsch reaction or make use of cavity ring-down spectroscopy. After applying corrections, all three methods gave accurate and precise measurements within their specifications.
Romain Blot, Philippe Nedelec, Damien Boulanger, Pawel Wolff, Bastien Sauvage, Jean-Marc Cousin, Gilles Athier, Andreas Zahn, Florian Obersteiner, Dieter Scharffe, Hervé Petetin, Yasmine Bennouna, Hannah Clark, and Valérie Thouret
Atmos. Meas. Tech., 14, 3935–3951, https://doi.org/10.5194/amt-14-3935-2021, https://doi.org/10.5194/amt-14-3935-2021, 2021
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A lack of information about temporal changes in measurement uncertainties is an area of concern for long-term trend studies of the key compounds which have a direct or indirect impact on climate change. The IAGOS program has measured O3 and CO within the troposphere and lower stratosphere for more than 25 years. In this study, we demonstrated that the IAGOS database can be treated as one continuous program and is therefore appropriate for studies of long-term trends.
Irene Bartolome Garcia, Reinhold Spang, Jörn Ungermann, Sabine Griessbach, Martina Krämer, Michael Höpfner, and Martin Riese
Atmos. Meas. Tech., 14, 3153–3168, https://doi.org/10.5194/amt-14-3153-2021, https://doi.org/10.5194/amt-14-3153-2021, 2021
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Cirrus clouds contribute to the general radiation budget of the Earth. Measuring optically thin clouds is challenging but the IR limb sounder GLORIA possesses the necessary technical characteristics to make it possible. This study analyses data from the WISE campaign obtained with GLORIA. We developed a cloud detection method and derived characteristics of the observed cirrus-like cloud top, cloud bottom or position with respect to the tropopause.
Changmin Cho, Andreas Hofzumahaus, Hendrik Fuchs, Hans-Peter Dorn, Marvin Glowania, Frank Holland, Franz Rohrer, Vaishali Vardhan, Astrid Kiendler-Scharr, Andreas Wahner, and Anna Novelli
Atmos. Meas. Tech., 14, 1851–1877, https://doi.org/10.5194/amt-14-1851-2021, https://doi.org/10.5194/amt-14-1851-2021, 2021
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This study describes the implementation and characterization of the chemical modulation reactor (CMR) used in the laser-induced fluorescence instrument of the Forschungszentrum Jülich. The CMR allows for interference-free OH radical measurement in ambient air. During a field campaign in a rural environment, the observed interference was mostly below the detection limit of the instrument and fully explained by the known ozone interference.
Julia Perim de Faria, Ulrich Bundke, Andrew Freedman, Timothy B. Onasch, and Andreas Petzold
Atmos. Meas. Tech., 14, 1635–1653, https://doi.org/10.5194/amt-14-1635-2021, https://doi.org/10.5194/amt-14-1635-2021, 2021
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An evaluation of the performance and accuracy of a Cavity Attenuated Phase-Shift Single Scattering Albedo Monitor (CAPS PMSSA; Aerodyne Research, Inc.) was conducted in an optical-closure study with proven technologies for aerosol particle optical-property measurements. This study demonstrates that the CAPS PMSSA is a robust and reliable instrument for the direct measurement of the particle scattering and extinction coefficients and thus single-scattering albedo.
Johannes Schneider, Ralf Weigel, Thomas Klimach, Antonis Dragoneas, Oliver Appel, Andreas Hünig, Sergej Molleker, Franziska Köllner, Hans-Christian Clemen, Oliver Eppers, Peter Hoppe, Peter Hoor, Christoph Mahnke, Martina Krämer, Christian Rolf, Jens-Uwe Grooß, Andreas Zahn, Florian Obersteiner, Fabrizio Ravegnani, Alexey Ulanovsky, Hans Schlager, Monika Scheibe, Glenn S. Diskin, Joshua P. DiGangi, John B. Nowak, Martin Zöger, and Stephan Borrmann
Atmos. Chem. Phys., 21, 989–1013, https://doi.org/10.5194/acp-21-989-2021, https://doi.org/10.5194/acp-21-989-2021, 2021
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During five aircraft missions, we detected aerosol particles containing meteoric material in the lower stratosphere. The stratospheric measurements span a latitude range from 15 to 68° N, and we find that at potential temperature levels of more than 40 K above the tropopause; particles containing meteoric material occur at similar abundance fractions across latitudes and seasons. We conclude that meteoric material is efficiently distributed between high and low latitudes by isentropic mixing.
Jörn Ungermann, Irene Bartolome, Sabine Griessbach, Reinhold Spang, Christian Rolf, Martina Krämer, Michael Höpfner, and Martin Riese
Atmos. Meas. Tech., 13, 7025–7045, https://doi.org/10.5194/amt-13-7025-2020, https://doi.org/10.5194/amt-13-7025-2020, 2020
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This study examines the potential of new IR limb imager instruments and tomographic methods for cloud detection purposes. Simple color-ratio-based methods are examined and compared against more involved nonlinear convex optimization. In a second part, 3-D measurements of the airborne limb sounder GLORIA taken during the Wave-driven ISentropic Exchange campaign are used to exemplarily derive the location and extent of small-scale cirrus clouds with high spatial accuracy.
Huan Song, Xiaorui Chen, Keding Lu, Qi Zou, Zhaofeng Tan, Hendrik Fuchs, Alfred Wiedensohler, Daniel R. Moon, Dwayne E. Heard, María-Teresa Baeza-Romero, Mei Zheng, Andreas Wahner, Astrid Kiendler-Scharr, and Yuanhang Zhang
Atmos. Chem. Phys., 20, 15835–15850, https://doi.org/10.5194/acp-20-15835-2020, https://doi.org/10.5194/acp-20-15835-2020, 2020
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Accurate calculation of the HO2 uptake coefficient is one of the key parameters to quantify the co-reduction of both aerosol and ozone pollution. We modelled various lab measurements of γHO2 based on a gas-liquid phase kinetic model and developed a state-of-the-art parameterized equation. Based on a dataset from a comprehensive field campaign in the North China Plain, we proposed that the determination of the heterogeneous uptake process for HO2 should be included in future field campaigns.
Manuel Baumgartner, Ralf Weigel, Allan H. Harvey, Felix Plöger, Ulrich Achatz, and Peter Spichtinger
Atmos. Chem. Phys., 20, 15585–15616, https://doi.org/10.5194/acp-20-15585-2020, https://doi.org/10.5194/acp-20-15585-2020, 2020
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The potential temperature is routinely used in atmospheric science. We review its derivation and suggest a new potential temperature, based on a temperature-dependent parameterization of the dry air's specific heat capacity. Moreover, we compare the new potential temperature to the common one and discuss the differences which become more important at higher altitudes. Finally, we indicate some consequences of using the new potential temperature in typical applications.
Michael Rolletter, Marion Blocquet, Martin Kaminski, Birger Bohn, Hans-Peter Dorn, Andreas Hofzumahaus, Frank Holland, Xin Li, Franz Rohrer, Ralf Tillmann, Robert Wegener, Astrid Kiendler-Scharr, Andreas Wahner, and Hendrik Fuchs
Atmos. Chem. Phys., 20, 13701–13719, https://doi.org/10.5194/acp-20-13701-2020, https://doi.org/10.5194/acp-20-13701-2020, 2020
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The photooxidation of pinonaldehyde is investigated in a chamber study under natural sunlight and low NO conditions with and without an added hydroxyl radical (OH) scavenger. The experimentally determined pinonaldehyde photolysis frequency is faster by a factor of 3.5 than currently used parameterizations in atmospheric models. Yields of degradation products are measured in the presence and absence of OH. Measurements are compared to current atmospheric models and a theory-based mechanism.
Martina Krämer, Christian Rolf, Nicole Spelten, Armin Afchine, David Fahey, Eric Jensen, Sergey Khaykin, Thomas Kuhn, Paul Lawson, Alexey Lykov, Laura L. Pan, Martin Riese, Andrew Rollins, Fred Stroh, Troy Thornberry, Veronika Wolf, Sarah Woods, Peter Spichtinger, Johannes Quaas, and Odran Sourdeval
Atmos. Chem. Phys., 20, 12569–12608, https://doi.org/10.5194/acp-20-12569-2020, https://doi.org/10.5194/acp-20-12569-2020, 2020
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To improve the representations of cirrus clouds in climate predictions, extended knowledge of their properties and geographical distribution is required. This study presents extensive airborne in situ and satellite remote sensing climatologies of cirrus and humidity, which serve as a guide to cirrus clouds. Further, exemplary radiative characteristics of cirrus types and also in situ observations of tropical tropopause layer cirrus and humidity in the Asian monsoon anticyclone are shown.
Holger Vömel, Herman G. J. Smit, David Tarasick, Bryan Johnson, Samuel J. Oltmans, Henry Selkirk, Anne M. Thompson, Ryan M. Stauffer, Jacquelyn C. Witte, Jonathan Davies, Roeland van Malderen, Gary A. Morris, Tatsumi Nakano, and Rene Stübi
Atmos. Meas. Tech., 13, 5667–5680, https://doi.org/10.5194/amt-13-5667-2020, https://doi.org/10.5194/amt-13-5667-2020, 2020
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The time response of electrochemical concentration cell (ECC) ozonesondes points to at least two distinct reaction pathways with time constants of approximately 20 s and 25 min. Properly considering these time constants eliminates the need for a poorly defined "background" and allows reducing ad hoc corrections based on laboratory tests. This reduces the uncertainty of ECC ozonesonde measurements throughout the profile and especially in regions of low ozone and strong gradients of ozone.
David L. Mitchell, John Mejia, Anne Garnier, Yuta Tomii, Martina Krämer, and Farnaz Hosseinpour
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2020-846, https://doi.org/10.5194/acp-2020-846, 2020
Publication in ACP not foreseen
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This may be the first estimate of the radiative contribution of homogeneous ice nucleation in cirrus clouds on a global, regional and seasonal scale. This is achieved by constraining an atmospheric global climate model with measured cirrus cloud properties via satellite remote sensing. The results show that the overall radiative warming contributed by homogeneous ice nucleation at the top of the atmosphere is 2.4 W m-2 outside the ± 30° latitude zone during non-summer months (JJA).
Iida Pullinen, Sebastian Schmitt, Sungah Kang, Mehrnaz Sarrafzadeh, Patrick Schlag, Stefanie Andres, Einhard Kleist, Thomas F. Mentel, Franz Rohrer, Monika Springer, Ralf Tillmann, Jürgen Wildt, Cheng Wu, Defeng Zhao, Andreas Wahner, and Astrid Kiendler-Scharr
Atmos. Chem. Phys., 20, 10125–10147, https://doi.org/10.5194/acp-20-10125-2020, https://doi.org/10.5194/acp-20-10125-2020, 2020
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Biogenic and anthropogenic air masses mix in the atmosphere, bringing plant-emitted monoterpenes and traffic-related nitrogen oxides together. There is debate whether the presence of nitrogen oxides reduces or increases secondary aerosol formation. This is important as secondary aerosols have cooling effects in the climate system but also constitute a health risk in populated areas. We show that the presence of NOx alone should not much affect the mass yields of secondary organic aerosols.
Frank Roux, Hannah Clark, Kuo-Ying Wang, Susanne Rohs, Bastien Sauvage, and Philippe Nédélec
Atmos. Chem. Phys., 20, 3945–3963, https://doi.org/10.5194/acp-20-3945-2020, https://doi.org/10.5194/acp-20-3945-2020, 2020
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Ozone, carbon monoxide and relative humidity were measured by two China Airlines aircraft equipped with IAGOS instruments during the summer of 2016. We examined landing and take-off profiles near Taipei (Taiwan), in the vicinity of three typhoons, in relation to ERA-5 meteorological reanalyses. Upstream of the storms, these data suggest that air is transported downwards from the stratosphere. Downstream, the troposphere is cleaner and moister due to the uplift of marine boundary layer air.
Mattia Righi, Johannes Hendricks, Ulrike Lohmann, Christof Gerhard Beer, Valerian Hahn, Bernd Heinold, Romy Heller, Martina Krämer, Michael Ponater, Christian Rolf, Ina Tegen, and Christiane Voigt
Geosci. Model Dev., 13, 1635–1661, https://doi.org/10.5194/gmd-13-1635-2020, https://doi.org/10.5194/gmd-13-1635-2020, 2020
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A new cloud microphysical scheme is implemented in the global EMAC-MADE3 aerosol model and evaluated. The new scheme features a detailed parameterization for aerosol-driven ice formation in cirrus clouds, accounting for the competition between homogeneous and heterogeneous ice formation processes. The comparison against satellite data and in situ measurements shows that the model performance is in line with similar global coupled models featuring ice cloud parameterizations.
Anna Novelli, Luc Vereecken, Birger Bohn, Hans-Peter Dorn, Georgios I. Gkatzelis, Andreas Hofzumahaus, Frank Holland, David Reimer, Franz Rohrer, Simon Rosanka, Domenico Taraborrelli, Ralf Tillmann, Robert Wegener, Zhujun Yu, Astrid Kiendler-Scharr, Andreas Wahner, and Hendrik Fuchs
Atmos. Chem. Phys., 20, 3333–3355, https://doi.org/10.5194/acp-20-3333-2020, https://doi.org/10.5194/acp-20-3333-2020, 2020
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Experimental evidence from a simulation chamber study shows that the regeneration efficiency of the hydroxyl radical is maintained globally at values higher than 0.5 for a wide range of nitrogen oxide concentrations as a result of isomerizations of peroxy radicals originating from the OH oxidation of isoprene. The available models were tested, and suggestions on how to improve their ability to reproduce the measured radical and oxygenated volatile organic compound concentrations are provided.
Fan Mei, Jian Wang, Jennifer M. Comstock, Ralf Weigel, Martina Krämer, Christoph Mahnke, John E. Shilling, Johannes Schneider, Christiane Schulz, Charles N. Long, Manfred Wendisch, Luiz A. T. Machado, Beat Schmid, Trismono Krisna, Mikhail Pekour, John Hubbe, Andreas Giez, Bernadett Weinzierl, Martin Zoeger, Mira L. Pöhlker, Hans Schlager, Micael A. Cecchini, Meinrat O. Andreae, Scot T. Martin, Suzane S. de Sá, Jiwen Fan, Jason Tomlinson, Stephen Springston, Ulrich Pöschl, Paulo Artaxo, Christopher Pöhlker, Thomas Klimach, Andreas Minikin, Armin Afchine, and Stephan Borrmann
Atmos. Meas. Tech., 13, 661–684, https://doi.org/10.5194/amt-13-661-2020, https://doi.org/10.5194/amt-13-661-2020, 2020
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In 2014, the US DOE G1 aircraft and the German HALO aircraft overflew the Amazon basin to study how aerosols influence cloud cycles under a clean condition and around a tropical megacity. This paper describes how to meaningfully compare similar measurements from two research aircraft and identify the potential measurement issue. We also discuss the uncertainty range for each measurement for further usage in model evaluation and satellite data validation.
Philipp Reutter, Patrick Neis, Susanne Rohs, and Bastien Sauvage
Atmos. Chem. Phys., 20, 787–804, https://doi.org/10.5194/acp-20-787-2020, https://doi.org/10.5194/acp-20-787-2020, 2020
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This study compares in situ measurements of temperature and humidity in the upper troposphere and lower stratosphere with reanalysis data from the ECMWF ERA-Interim data set. It is shown that temperature compares well between both data sets. However, extreme values of relative humidity with respect to ice (RHi) are missing in ERA-Interim, and hence the number and size of ice supersaturated regions differ strongly between both data sets.
Manuel Baumgartner, Max Sagebaum, Nicolas R. Gauger, Peter Spichtinger, and André Brinkmann
Geosci. Model Dev., 12, 5197–5212, https://doi.org/10.5194/gmd-12-5197-2019, https://doi.org/10.5194/gmd-12-5197-2019, 2019
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Numerical models in atmospheric sciences need to include physical processes through parameterizations, which are not explicitly resolved, e.g., the formation of clouds. As a consequence, the parameterizations contain uncertain parameters. We suggest using the technique of algorithmic differentiation (AD) to identify the most uncertain parameters within parameterizations. In this study, we illustrate AD by analyzing a scheme for liquid clouds incorporated into a parcel model framework.
Kuo-Ying Wang, Philippe Nedelec, Hannah Clark, and Neil Harris
Earth Syst. Sci. Data Discuss., https://doi.org/10.5194/essd-2019-156, https://doi.org/10.5194/essd-2019-156, 2019
Revised manuscript not accepted
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Atmospheric dispersion of radioactive materials following the accidents of the 11 March 2011 Fukushima Nuclear Power Plants contain very distinctive characteristics
over the land surface areas and over the oceanic atmosphere. Air dose rates measured over the land surface areas exhibit a combination of the effects from the deposited radioactive materials on the surface and the airborne radioactive materials. Air dose rates measured over the oceanic atmosphere were due to airborne particles.
Keun-Ok Lee, Thibaut Dauhut, Jean-Pierre Chaboureau, Sergey Khaykin, Martina Krämer, and Christian Rolf
Atmos. Chem. Phys., 19, 11803–11820, https://doi.org/10.5194/acp-19-11803-2019, https://doi.org/10.5194/acp-19-11803-2019, 2019
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This study focuses on the hydration patch that was measured during the StratoClim field campaign and the corresponding convective overshoots over the Sichuan Basin. Through analysis using airborne and spaceborne measurements and the numerical simulation using a non-hydrostatic model, we show the key hydration process and pathway of the hydration patch in tropical tropopause layer.
Michael Rolletter, Martin Kaminski, Ismail-Hakki Acir, Birger Bohn, Hans-Peter Dorn, Xin Li, Anna Lutz, Sascha Nehr, Franz Rohrer, Ralf Tillmann, Robert Wegener, Andreas Hofzumahaus, Astrid Kiendler-Scharr, Andreas Wahner, and Hendrik Fuchs
Atmos. Chem. Phys., 19, 11635–11649, https://doi.org/10.5194/acp-19-11635-2019, https://doi.org/10.5194/acp-19-11635-2019, 2019
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Here we present a study of the photooxidation of alpha-pinene, the most abundant monoterpene, by hydroxyl radicals (OH) conducted in the simulation chamber SAPHIR under low NOx and atmospheric alpha-pinene concentrations. Yields of the main degradation products acetone, formaldehyde, and pinonaldehyde were determined and the HOx (OH + HO2) radical budget was investigated. Measurements were used to test current atmospheric models and a theory-based mechanism.
Zhaofeng Tan, Keding Lu, Andreas Hofzumahaus, Hendrik Fuchs, Birger Bohn, Frank Holland, Yuhan Liu, Franz Rohrer, Min Shao, Kang Sun, Yusheng Wu, Limin Zeng, Yinsong Zhang, Qi Zou, Astrid Kiendler-Scharr, Andreas Wahner, and Yuanhang Zhang
Atmos. Chem. Phys., 19, 7129–7150, https://doi.org/10.5194/acp-19-7129-2019, https://doi.org/10.5194/acp-19-7129-2019, 2019
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Atmospheric OH, HO2, and RO2 radicals; OH reactivity; and trace gases measured in the Pearl River Delta in autumn 2014 are used for radical budget analyses. The RO2 budget suggests that unexplained OH reactivity is due to unmeasured volatile organic compounds. The OH budget points to a missing OH source and that of RO2 to a missing RO2 sink at low NO. This could indicate a common, unknown process that converts RO2 to OH without the involvement of NO, which would reduce ozone production by 30 %.
Sabine Robrecht, Bärbel Vogel, Jens-Uwe Grooß, Karen Rosenlof, Troy Thornberry, Andrew Rollins, Martina Krämer, Lance Christensen, and Rolf Müller
Atmos. Chem. Phys., 19, 5805–5833, https://doi.org/10.5194/acp-19-5805-2019, https://doi.org/10.5194/acp-19-5805-2019, 2019
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The potential destruction of stratospheric ozone in the mid-latitudes has been discussed recently. We analysed this ozone loss mechanism and its sensitivities. In a certain temperature range, we found a threshold in water vapour, which has to be exceeded for ozone loss to occur. We show the dependence of this water vapour threshold on temperature, sulfate content and air composition. This study provides a basis to estimate the impact of potential sulphate geoengineering on stratospheric ozone.
Sascha R. Albrecht, Anna Novelli, Andreas Hofzumahaus, Sungah Kang, Yare Baker, Thomas Mentel, Andreas Wahner, and Hendrik Fuchs
Atmos. Meas. Tech., 12, 891–902, https://doi.org/10.5194/amt-12-891-2019, https://doi.org/10.5194/amt-12-891-2019, 2019
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Within this study we demonstrate reliable measurement of hydroperoxy (HO2) radicals via chemical ionisation mass spectrometry. HO2 is detected as an ion cluster with bromide ions, which allows a selective detection. This direct and sensitive measurement provides reliable data of HO2 radical concentrations in the atmosphere as demonstrated in the first application in simulation chamber experiments.
Michael Weger, Bernd Heinold, Christa Engler, Ulrich Schumann, Axel Seifert, Romy Fößig, Christiane Voigt, Holger Baars, Ulrich Blahak, Stephan Borrmann, Corinna Hoose, Stefan Kaufmann, Martina Krämer, Patric Seifert, Fabian Senf, Johannes Schneider, and Ina Tegen
Atmos. Chem. Phys., 18, 17545–17572, https://doi.org/10.5194/acp-18-17545-2018, https://doi.org/10.5194/acp-18-17545-2018, 2018
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The impact of desert dust on cloud formation is investigated for a major Saharan dust event over Europe by interactive regional dust modeling. Dust particles are very efficient ice-nucleating particles promoting the formation of ice crystals in clouds. The simulations show that the observed extensive cirrus development was likely related to the above-average dust load. The interactive dust–cloud feedback in the model significantly improves the agreement with aircraft and satellite observations.
Veronika Wolf, Thomas Kuhn, Mathias Milz, Peter Voelger, Martina Krämer, and Christian Rolf
Atmos. Chem. Phys., 18, 17371–17386, https://doi.org/10.5194/acp-18-17371-2018, https://doi.org/10.5194/acp-18-17371-2018, 2018
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Balloon-borne measurements of microphysical properties of Arctic ice clouds have been performed with an in situ particle imager and been analyzed for the first time with respect to how the ice particles have formed. Ice particle size, shape and number show large variations from cloud to cloud, which cannot be explained with local conditions only, and rather depend on conditions at cloud formation. Taking this into account when parametrizing ice cloud properties may improve retrievals and models.
Hervé Petetin, Bastien Sauvage, Mark Parrington, Hannah Clark, Alain Fontaine, Gilles Athier, Romain Blot, Damien Boulanger, Jean-Marc Cousin, Philippe Nédélec, and Valérie Thouret
Atmos. Chem. Phys., 18, 17277–17306, https://doi.org/10.5194/acp-18-17277-2018, https://doi.org/10.5194/acp-18-17277-2018, 2018
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This study derives a climatology of the impact of biomass burning versus anthropogenic emissions on the strongest CO plumes observed in the troposphere based on a dataset of about 30 000 in situ vertical profiles, combined with Lagrangian simulations coupled to CO emission. Results demonstrate the large contribution of biomass burning to the strongest CO plumes encountered in the troposphere in many locations of the world.
Stefan Kaufmann, Christiane Voigt, Romy Heller, Tina Jurkat-Witschas, Martina Krämer, Christian Rolf, Martin Zöger, Andreas Giez, Bernhard Buchholz, Volker Ebert, Troy Thornberry, and Ulrich Schumann
Atmos. Chem. Phys., 18, 16729–16745, https://doi.org/10.5194/acp-18-16729-2018, https://doi.org/10.5194/acp-18-16729-2018, 2018
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We present an intercomparison of the airborne water vapor measurements during the ML-CIRRUS mission. Although the agreement of the hygrometers significantly improved compared to studies from recent decades, systematic differences remain under specific meteorological conditions. We compare the measurements to model data, where we observe a model wet bias in the lower stratosphere close to the tropopause, likely caused by a blurred humidity gradient in the model tropopause.
Christiane Schulz, Johannes Schneider, Bruna Amorim Holanda, Oliver Appel, Anja Costa, Suzane S. de Sá, Volker Dreiling, Daniel Fütterer, Tina Jurkat-Witschas, Thomas Klimach, Christoph Knote, Martina Krämer, Scot T. Martin, Stephan Mertes, Mira L. Pöhlker, Daniel Sauer, Christiane Voigt, Adrian Walser, Bernadett Weinzierl, Helmut Ziereis, Martin Zöger, Meinrat O. Andreae, Paulo Artaxo, Luiz A. T. Machado, Ulrich Pöschl, Manfred Wendisch, and Stephan Borrmann
Atmos. Chem. Phys., 18, 14979–15001, https://doi.org/10.5194/acp-18-14979-2018, https://doi.org/10.5194/acp-18-14979-2018, 2018
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Aerosol chemical composition measurements in the tropical upper troposphere over the Amazon region show that 78 % of the aerosol in the upper troposphere consists of organic matter. Up to 20 % of the organic aerosol can be attributed to isoprene epoxydiol secondary organic aerosol (IEPOX-SOA). Furthermore, organic nitrates were identified, suggesting a connection to the IEPOX-SOA formation.
Odran Sourdeval, Edward Gryspeerdt, Martina Krämer, Tom Goren, Julien Delanoë, Armin Afchine, Friederike Hemmer, and Johannes Quaas
Atmos. Chem. Phys., 18, 14327–14350, https://doi.org/10.5194/acp-18-14327-2018, https://doi.org/10.5194/acp-18-14327-2018, 2018
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The number concentration of ice crystals (Ni) is a key cloud property that remains very uncertain due to difficulties in determining it using satellites. This lack of global observational constraints limits our ability to constrain this property in models responsible for predicting future climate. This pair of papers fills this gap by showing and analyzing the first rigorously evaluated global climatology of Ni, leading to new information shedding light on the processes that control high clouds.
Edward Gryspeerdt, Odran Sourdeval, Johannes Quaas, Julien Delanoë, Martina Krämer, and Philipp Kühne
Atmos. Chem. Phys., 18, 14351–14370, https://doi.org/10.5194/acp-18-14351-2018, https://doi.org/10.5194/acp-18-14351-2018, 2018
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The concentration of ice crystals in a cloud affects both the properties and the life cycle of the cloud. This work uses a new satellite retrieval to investigate controls on the ice crystal concentration at a global scale. Both temperature and vertical wind speed in a cloud have a strong impact on the concentration of ice crystals. The ice crystal number is also related to the aerosol environment; defining this relation opens up new ways to investigate human impacts on clouds and the climate.
Sara Bacer, Sylvia C. Sullivan, Vlassis A. Karydis, Donifan Barahona, Martina Krämer, Athanasios Nenes, Holger Tost, Alexandra P. Tsimpidi, Jos Lelieveld, and Andrea Pozzer
Geosci. Model Dev., 11, 4021–4041, https://doi.org/10.5194/gmd-11-4021-2018, https://doi.org/10.5194/gmd-11-4021-2018, 2018
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The complexity of ice nucleation mechanisms and aerosol--ice interactions makes their representation still challenging in atmospheric models. We have implemented a comprehensive ice crystal formation parameterization in the global chemistry-climate model EMAC to improve the representation of ice crystal number concentrations. The newly implemented parameterization takes into account processes which were previously neglected by the standard version of the model.
Annette Filges, Christoph Gerbig, Chris W. Rella, John Hoffnagle, Herman Smit, Martina Krämer, Nicole Spelten, Christian Rolf, Zoltán Bozóki, Bernhard Buchholz, and Volker Ebert
Atmos. Meas. Tech., 11, 5279–5297, https://doi.org/10.5194/amt-11-5279-2018, https://doi.org/10.5194/amt-11-5279-2018, 2018
Zhaofeng Tan, Franz Rohrer, Keding Lu, Xuefei Ma, Birger Bohn, Sebastian Broch, Huabin Dong, Hendrik Fuchs, Georgios I. Gkatzelis, Andreas Hofzumahaus, Frank Holland, Xin Li, Ying Liu, Yuhan Liu, Anna Novelli, Min Shao, Haichao Wang, Yusheng Wu, Limin Zeng, Min Hu, Astrid Kiendler-Scharr, Andreas Wahner, and Yuanhang Zhang
Atmos. Chem. Phys., 18, 12391–12411, https://doi.org/10.5194/acp-18-12391-2018, https://doi.org/10.5194/acp-18-12391-2018, 2018
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We present the first wintertime OH, HO2, and RO2 measurements in Beijing, China. OH concentrations are nearly 2-fold larger than those observed in foreign cities during wintertime. The high OH and large OH reactivities indicate photochemical processes can be effective even during wintertime. A box model largely underestimated HO2 and RO2 concentrations during pollution episodes correlated with high NOx, indicating a deficit current chemistry in the high NOx regime.
Anna Novelli, Martin Kaminski, Michael Rolletter, Ismail-Hakki Acir, Birger Bohn, Hans-Peter Dorn, Xin Li, Anna Lutz, Sascha Nehr, Franz Rohrer, Ralf Tillmann, Robert Wegener, Frank Holland, Andreas Hofzumahaus, Astrid Kiendler-Scharr, Andreas Wahner, and Hendrik Fuchs
Atmos. Chem. Phys., 18, 11409–11422, https://doi.org/10.5194/acp-18-11409-2018, https://doi.org/10.5194/acp-18-11409-2018, 2018
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The impact of photooxidation of 2-methyl-3-butene-2-ol (MBO) on the concentration of radical species was studied in the atmospheric simulation chamber SAPHIR. MBO is a volatile organic compound mainly emitted by ponderosa and lodgepole pines which are very abundant in forests in the central-west USA. A very good agreement between measured and modelled radical concentrations and products from the oxidation of MBO was observed in an environment with NO of ~ 200 pptv.
Sören Johansson, Wolfgang Woiwode, Michael Höpfner, Felix Friedl-Vallon, Anne Kleinert, Erik Kretschmer, Thomas Latzko, Johannes Orphal, Peter Preusse, Jörn Ungermann, Michelle L. Santee, Tina Jurkat-Witschas, Andreas Marsing, Christiane Voigt, Andreas Giez, Martina Krämer, Christian Rolf, Andreas Zahn, Andreas Engel, Björn-Martin Sinnhuber, and Hermann Oelhaf
Atmos. Meas. Tech., 11, 4737–4756, https://doi.org/10.5194/amt-11-4737-2018, https://doi.org/10.5194/amt-11-4737-2018, 2018
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We present two-dimensional cross sections of temperature, HNO3, O3, ClONO2, H2O and CFC-12 from measurements of the GLORIA infrared limb imager during the POLSTRACC/GW-LCYCLE/SALSA aircraft campaigns in the Arctic winter 2015/2016. GLORIA sounded the atmosphere between 5 and 14 km with vertical resolutions of 0.4–1 km. Estimated errors are in the range of 1–2 K (temperature) and 10 %–20 % (trace gases). Comparisons to in situ instruments onboard the aircraft and to Aura/MLS are shown.
Armin Afchine, Christian Rolf, Anja Costa, Nicole Spelten, Martin Riese, Bernhard Buchholz, Volker Ebert, Romy Heller, Stefan Kaufmann, Andreas Minikin, Christiane Voigt, Martin Zöger, Jessica Smith, Paul Lawson, Alexey Lykov, Sergey Khaykin, and Martina Krämer
Atmos. Meas. Tech., 11, 4015–4031, https://doi.org/10.5194/amt-11-4015-2018, https://doi.org/10.5194/amt-11-4015-2018, 2018
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The ice water content (IWC) of cirrus clouds is an essential parameter that determines their radiative properties and is thus important for climate simulations. Experimental investigations of IWCs measured on board research aircraft reveal that their accuracy is influenced by the sampling position. IWCs detected at the aircraft roof deviate significantly from wing, side or bottom IWCs. The reasons are deflections of the gas streamlines and ice particle trajectories behind the aircraft cockpit.
Hervé Petetin, Bastien Sauvage, Herman G. J. Smit, François Gheusi, Fabienne Lohou, Romain Blot, Hannah Clark, Gilles Athier, Damien Boulanger, Jean-Marc Cousin, Philippe Nedelec, Patrick Neis, Susanne Rohs, and Valérie Thouret
Atmos. Chem. Phys., 18, 9561–9581, https://doi.org/10.5194/acp-18-9561-2018, https://doi.org/10.5194/acp-18-9561-2018, 2018
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Based on the numerous profiles available since 1994, this paper investigates the vertical stratification of ozone, carbon monoxide and relative humidity in the lower part of the troposphere (planetary boundary layer, lower free troposphere). Such a characterization of the vertical distribution of pollution is notably important for better understanding vertical exchanges and evaluating models on the vertical dimension.
Florian Berkes, Norbert Houben, Ulrich Bundke, Harald Franke, Hans-Werner Pätz, Franz Rohrer, Andreas Wahner, and Andreas Petzold
Atmos. Meas. Tech., 11, 3737–3757, https://doi.org/10.5194/amt-11-3737-2018, https://doi.org/10.5194/amt-11-3737-2018, 2018
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The need for in situ nitrogen oxide measurements on a global scale is crucial to improve the chemistry in global chemistry models and evaluate satellite retrievals. Here we present the characterization of the new IAGOS NOx instrument installed on passenger aircraft, which will provide statistical robust measurements from the surface up to 13 km.
Chance W. Sterling, Bryan J. Johnson, Samuel J. Oltmans, Herman G. J. Smit, Allen F. Jordan, Patrick D. Cullis, Emrys G. Hall, Anne M. Thompson, and Jacquelyn C. Witte
Atmos. Meas. Tech., 11, 3661–3687, https://doi.org/10.5194/amt-11-3661-2018, https://doi.org/10.5194/amt-11-3661-2018, 2018
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The electrochemical concentration cell ozonesonde is a balloon-borne instrument that measures ozone to an altitude of ~30 km. This work summarizes the National Oceanic and Atmospheric Administration's 50+ year, eight-site ozonesonde network history, the processing techniques utilized to account for instrumental changes, and the uncertainty of the measurement. The ozonesonde measurements were compared to satellite measurements and agreed well. This important data set is more useful and robust.
Hendrik Fuchs, Sascha Albrecht, Ismail–Hakki Acir, Birger Bohn, Martin Breitenlechner, Hans-Peter Dorn, Georgios I. Gkatzelis, Andreas Hofzumahaus, Frank Holland, Martin Kaminski, Frank N. Keutsch, Anna Novelli, David Reimer, Franz Rohrer, Ralf Tillmann, Luc Vereecken, Robert Wegener, Alexander Zaytsev, Astrid Kiendler-Scharr, and Andreas Wahner
Atmos. Chem. Phys., 18, 8001–8016, https://doi.org/10.5194/acp-18-8001-2018, https://doi.org/10.5194/acp-18-8001-2018, 2018
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The photooxidation of methyl vinyl ketone MVK, one of the most important products of isoprene that is emitted by plants, was investigated in the atmospheric simulation chamber SAPHIR for conditions found in forested areas. The comparison of measured trace gas time series with model calculations shows a gap in the understanding of radical chemistry in the MVK oxidation scheme. The possibility of unimolecular isomerization reactions were investigated by means of quantum-chemical calculations.
Mingjin Wang, Tong Zhu, Defeng Zhao, Florian Rubach, Andreas Wahner, Astrid Kiendler-Scharr, and Thomas F. Mentel
Atmos. Chem. Phys., 18, 7345–7359, https://doi.org/10.5194/acp-18-7345-2018, https://doi.org/10.5194/acp-18-7345-2018, 2018
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Organic coatings modify hygroscopicity and CCN activation of mineral dust perticles. Small amounts of oleic acid coating (volume fraction (vf) ≤ 4.1 %) decreased the CCN activity of CaCO3 particles, while more oleic acid coating (vf ≥ 14.8 %) increased the CCN activity of CaCO3 particles, while malonic acid coating (vf = 0.4−42 %) even in smallest amounts increased the CCN activity of CaCO3 particles. Our laboratory results should also hold under conditions of the atmosphere.
Yann Cohen, Hervé Petetin, Valérie Thouret, Virginie Marécal, Béatrice Josse, Hannah Clark, Bastien Sauvage, Alain Fontaine, Gilles Athier, Romain Blot, Damien Boulanger, Jean-Marc Cousin, and Philippe Nédélec
Atmos. Chem. Phys., 18, 5415–5453, https://doi.org/10.5194/acp-18-5415-2018, https://doi.org/10.5194/acp-18-5415-2018, 2018
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Measurements of ozone and carbon monoxide were performed during 1994–2013 around the tropopause on board commercial aircraft. Seasonal cycles and trends were calculated above eight well-sampled regions in Northern Hemisphere midlatitudes. CO shows decreasing concentrations over the last 10 years, thus reflecting the impact of the legislation on anthropogenic emissions. Ozone amounts increased over the 20 years in the upper troposphere during different seasons, depending on the longitudes.
Christian Rolf, Bärbel Vogel, Peter Hoor, Armin Afchine, Gebhard Günther, Martina Krämer, Rolf Müller, Stefan Müller, Nicole Spelten, and Martin Riese
Atmos. Chem. Phys., 18, 2973–2983, https://doi.org/10.5194/acp-18-2973-2018, https://doi.org/10.5194/acp-18-2973-2018, 2018
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The Asian monsoon is a pronounced circulation system linked to rapid vertical transport of surface air from India and east Asia in the summer months. We found, based on aircraft measurements, higher concentration of water vapor in the lowermost stratosphere caused by the Asian monsoon. Enrichment of water vapor concentrations in the lowermost stratosphere impacts the radiation budget and thus climate. Understanding those variations in water vapor is important for climate projections.
Manuel Baumgartner and Peter Spichtinger
Atmos. Chem. Phys., 18, 2525–2546, https://doi.org/10.5194/acp-18-2525-2018, https://doi.org/10.5194/acp-18-2525-2018, 2018
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Ice crystals are surrounded by liquid cloud droplets in mixed-phase clouds. The coexistence of ice and water is thermodynamically not stable and the particles will influence their respective growth by condensation. This effect is known as the Wegener–Bergeron–Findeisen process. In current models, the local interactions of the particles are neglected and they can only interact indirectly. This work proposes an approach to include local interactions and discusses some implications.
Defeng Zhao, Sebastian H. Schmitt, Mingjin Wang, Ismail-Hakki Acir, Ralf Tillmann, Zhaofeng Tan, Anna Novelli, Hendrik Fuchs, Iida Pullinen, Robert Wegener, Franz Rohrer, Jürgen Wildt, Astrid Kiendler-Scharr, Andreas Wahner, and Thomas F. Mentel
Atmos. Chem. Phys., 18, 1611–1628, https://doi.org/10.5194/acp-18-1611-2018, https://doi.org/10.5194/acp-18-1611-2018, 2018
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Air pollutants emitted by human activities such as NOx and SO2 can influence the abundance of secondary organic aerosol (SOA) from biogenic volatile organic compounds (VOCs). We found that NOx suppressed new particle formation and SOA mass formation. When both SO2 and NOx are present, the suppressing effect of NOx on SOA mass formation was counteracted by SO2. High NOx changed SOA chemical composition, forming more organic nitrate, because NOx changed radical chemistry during VOC oxidation.
Meinrat O. Andreae, Armin Afchine, Rachel Albrecht, Bruna Amorim Holanda, Paulo Artaxo, Henrique M. J. Barbosa, Stephan Borrmann, Micael A. Cecchini, Anja Costa, Maximilian Dollner, Daniel Fütterer, Emma Järvinen, Tina Jurkat, Thomas Klimach, Tobias Konemann, Christoph Knote, Martina Krämer, Trismono Krisna, Luiz A. T. Machado, Stephan Mertes, Andreas Minikin, Christopher Pöhlker, Mira L. Pöhlker, Ulrich Pöschl, Daniel Rosenfeld, Daniel Sauer, Hans Schlager, Martin Schnaiter, Johannes Schneider, Christiane Schulz, Antonio Spanu, Vinicius B. Sperling, Christiane Voigt, Adrian Walser, Jian Wang, Bernadett Weinzierl, Manfred Wendisch, and Helmut Ziereis
Atmos. Chem. Phys., 18, 921–961, https://doi.org/10.5194/acp-18-921-2018, https://doi.org/10.5194/acp-18-921-2018, 2018
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We made airborne measurements of aerosol particle concentrations and properties over the Amazon Basin. We found extremely high concentrations of very small particles in the region between 8 and 14 km altitude all across the basin, which had been recently formed by gas-to-particle conversion at these altitudes. This makes the upper troposphere a very important source region of atmospheric particles with significant implications for the Earth's climate system.
Micael A. Cecchini, Luiz A. T. Machado, Manfred Wendisch, Anja Costa, Martina Krämer, Meinrat O. Andreae, Armin Afchine, Rachel I. Albrecht, Paulo Artaxo, Stephan Borrmann, Daniel Fütterer, Thomas Klimach, Christoph Mahnke, Scot T. Martin, Andreas Minikin, Sergej Molleker, Lianet H. Pardo, Christopher Pöhlker, Mira L. Pöhlker, Ulrich Pöschl, Daniel Rosenfeld, and Bernadett Weinzierl
Atmos. Chem. Phys., 17, 14727–14746, https://doi.org/10.5194/acp-17-14727-2017, https://doi.org/10.5194/acp-17-14727-2017, 2017
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This study introduces and explores the concept of gamma phase space. This space is able to represent all possible variations in the cloud droplet size distributions (DSDs). The methodology was applied to recent in situ aircraft measurements over the Amazon. It is shown that the phase space is able to represent several processes occurring in the clouds in a simple manner. The consequences for cloud studies, modeling, and the representation of the transition from warm to mixed phase are discussed.
Hendrik Fuchs, Anna Novelli, Michael Rolletter, Andreas Hofzumahaus, Eva Y. Pfannerstill, Stephan Kessel, Achim Edtbauer, Jonathan Williams, Vincent Michoud, Sebastien Dusanter, Nadine Locoge, Nora Zannoni, Valerie Gros, Francois Truong, Roland Sarda-Esteve, Danny R. Cryer, Charlotte A. Brumby, Lisa K. Whalley, Daniel Stone, Paul W. Seakins, Dwayne E. Heard, Coralie Schoemaecker, Marion Blocquet, Sebastien Coudert, Sebastien Batut, Christa Fittschen, Alexander B. Thames, William H. Brune, Cheryl Ernest, Hartwig Harder, Jennifer B. A. Muller, Thomas Elste, Dagmar Kubistin, Stefanie Andres, Birger Bohn, Thorsten Hohaus, Frank Holland, Xin Li, Franz Rohrer, Astrid Kiendler-Scharr, Ralf Tillmann, Robert Wegener, Zhujun Yu, Qi Zou, and Andreas Wahner
Atmos. Meas. Tech., 10, 4023–4053, https://doi.org/10.5194/amt-10-4023-2017, https://doi.org/10.5194/amt-10-4023-2017, 2017
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Hydroxyl radical reactivity (k(OH)) is closely related to processes that lead to the formation of oxidised, secondary pollutants such as ozone and aerosol. In order to compare the performances of instruments measuring k(OH), experiments were conducted in the simulation chamber SAPHIR. Chemical conditions were chosen either to be representative of the atmosphere or to test potential limitations of instruments. Overall, the results show that instruments are capable of measuring k(OH).
Florian Berkes, Patrick Neis, Martin G. Schultz, Ulrich Bundke, Susanne Rohs, Herman G. J. Smit, Andreas Wahner, Paul Konopka, Damien Boulanger, Philippe Nédélec, Valerie Thouret, and Andreas Petzold
Atmos. Chem. Phys., 17, 12495–12508, https://doi.org/10.5194/acp-17-12495-2017, https://doi.org/10.5194/acp-17-12495-2017, 2017
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This study highlights the importance of independent global measurements with high and long-term accuracy to quantify long-term changes, especially in the UTLS region, and to help identify inconsistencies between different data sets of observations and models. Here we investigated temperature trends over different regions within a climate-sensitive area of the atmosphere and demonstrated the value of the IAGOS temperature observations as an anchor point for the evaluation of reanalyses.
Anja Costa, Jessica Meyer, Armin Afchine, Anna Luebke, Gebhard Günther, James R. Dorsey, Martin W. Gallagher, Andre Ehrlich, Manfred Wendisch, Darrel Baumgardner, Heike Wex, and Martina Krämer
Atmos. Chem. Phys., 17, 12219–12238, https://doi.org/10.5194/acp-17-12219-2017, https://doi.org/10.5194/acp-17-12219-2017, 2017
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The paper presents 38 h of in situ cloud spectrometer observations of microphysical cloud properties in the Arctic, midlatitudes and tropics. The clouds are classified via particle concentrations, size distributions, and – as a novelty – small particle aspherical fractions. Cloud-type profiles are given for different temperatures and locations. The results confine regions where different cloud transformation processes occurred and emphasise the importance of small particle shape detection.
Qing Mu, Gerhard Lammel, Christian N. Gencarelli, Ian M. Hedgecock, Ying Chen, Petra Přibylová, Monique Teich, Yuxuan Zhang, Guangjie Zheng, Dominik van Pinxteren, Qiang Zhang, Hartmut Herrmann, Manabu Shiraiwa, Peter Spichtinger, Hang Su, Ulrich Pöschl, and Yafang Cheng
Atmos. Chem. Phys., 17, 12253–12267, https://doi.org/10.5194/acp-17-12253-2017, https://doi.org/10.5194/acp-17-12253-2017, 2017
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Polycyclic aromatic hydrocarbons (PAHs) are hazardous pollutants with the largest emissions in East Asia. The regional WRF-Chem-PAH model has been developed to reflect the state-of-the-art understanding of current PAHs studies with several new or updated features. It is able to reasonably well simulate the concentration levels and particulate mass fractions of PAHs near the sources and at a remote outflow region of East Asia, in high spatial and temporal resolutions.
Marcus Klingebiel, André Ehrlich, Fanny Finger, Timo Röschenthaler, Suad Jakirlić, Matthias Voigt, Stefan Müller, Rolf Maser, Manfred Wendisch, Peter Hoor, Peter Spichtinger, and Stephan Borrmann
Atmos. Meas. Tech., 10, 3485–3498, https://doi.org/10.5194/amt-10-3485-2017, https://doi.org/10.5194/amt-10-3485-2017, 2017
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Microphysical and radiation measurements were collected with the unique AIRcraft TOwed Sensor Shuttle (AIRTOSS) – Learjet tandem platform. It is a combination of a Learjet 35A research aircraft and an instrumented aerodynamic bird, which can be detached from and retracted back to the aircraft during flight.
AIRTOSS and Learjet are equipped with radiative, cloud microphysical, trace gas,
and meteorological instruments to study cirrus clouds.
Evelyn Jäkel, Manfred Wendisch, Trismono C. Krisna, Florian Ewald, Tobias Kölling, Tina Jurkat, Christiane Voigt, Micael A. Cecchini, Luiz A. T. Machado, Armin Afchine, Anja Costa, Martina Krämer, Meinrat O. Andreae, Ulrich Pöschl, Daniel Rosenfeld, and Tianle Yuan
Atmos. Chem. Phys., 17, 9049–9066, https://doi.org/10.5194/acp-17-9049-2017, https://doi.org/10.5194/acp-17-9049-2017, 2017
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Vertical profiles of the cloud particle phase state in tropical deep convective clouds (DCCs) were investigated using airborne imaging spectrometer measurements during the ACRIDICON-CHUVA campaign, which was conducted over the Brazilian rainforest in September 2014. A phase discrimination retrieval was applied to observations of clouds formed in different aerosol conditions. The profiles were compared to in situ and satellite measurements.
Cheng Wu, Iida Pullinen, Stefanie Andres, Astrid Kiendler-Scharr, Einhard Kleist, Andreas Wahner, Jürgen Wildt, and Thomas F. Mentel
Biogeosciences Discuss., https://doi.org/10.5194/bg-2017-260, https://doi.org/10.5194/bg-2017-260, 2017
Manuscript not accepted for further review
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Biogenic volatile organic compounds are important for atmospheric chemistry. We showed by 13CO2 labelling experiments that biosynthesis is not restricted to the presence of light. In particular sesquiterpenes exhibit substantial de novo emissions in darkness with the carbon being delivered from alternative carbon sources. Our findings are of importance for future emissions under conditions of climate change as the response of de novo emissions to stresses differs from that of pool emissions.
Elisa Johanna Spreitzer, Manuel Patrik Marschalik, and Peter Spichtinger
Nonlin. Processes Geophys., 24, 307–328, https://doi.org/10.5194/npg-24-307-2017, https://doi.org/10.5194/npg-24-307-2017, 2017
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We developed a simple analytical model for describing subvisible cirrus clouds qualitatively. Using theory of dynamical systems we found two different states for the long-term behaviour of subvisible cirrus clouds, i.e. an attractor case (stable equilibrium point) and a limit cycle scenario. The transition between the states constitutes a Hopf bifurcation and is determined by environmental conditions such as vertical updraughts and temperature.
Thomas Berkemeier, Markus Ammann, Ulrich K. Krieger, Thomas Peter, Peter Spichtinger, Ulrich Pöschl, Manabu Shiraiwa, and Andrew J. Huisman
Atmos. Chem. Phys., 17, 8021–8029, https://doi.org/10.5194/acp-17-8021-2017, https://doi.org/10.5194/acp-17-8021-2017, 2017
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Kinetic process models are efficient tools used to unravel the mechanisms governing chemical and physical transformation in multiphase atmospheric chemistry. However, determination of kinetic parameters such as reaction rate or diffusion coefficients from multiple data sets is often difficult or ambiguous. This study presents a novel optimization algorithm and framework to determine these parameters in an automated fashion and to gain information about parameter uncertainty and uniqueness.
Terry Deshler, Rene Stübi, Francis J. Schmidlin, Jennifer L. Mercer, Herman G. J. Smit, Bryan J. Johnson, Rigel Kivi, and Bruno Nardi
Atmos. Meas. Tech., 10, 2021–2043, https://doi.org/10.5194/amt-10-2021-2017, https://doi.org/10.5194/amt-10-2021-2017, 2017
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Ozonesondes, small balloon-borne instruments to measure ozone profiles, are used once and lost. Quality control is thus essential. From the mid-1990s to late 2000s differences in manufacturers' (Science Pump and ENSCI) recommended sensor solution concentrations, 1.0 % and 0.5 % potassium iodide, led to some confusion. This paper uses comparison measurements to derive transfer functions to homogenize the measurements made with non-standard combinations of instrument and sensor solution.
Martin Kaminski, Hendrik Fuchs, Ismail-Hakki Acir, Birger Bohn, Theo Brauers, Hans-Peter Dorn, Rolf Häseler, Andreas Hofzumahaus, Xin Li, Anna Lutz, Sascha Nehr, Franz Rohrer, Ralf Tillmann, Luc Vereecken, Robert Wegener, and Andreas Wahner
Atmos. Chem. Phys., 17, 6631–6650, https://doi.org/10.5194/acp-17-6631-2017, https://doi.org/10.5194/acp-17-6631-2017, 2017
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Monoterpenes emitted by trees are among the volatile organic compounds with the highest global emission rates. The atmospheric degradation of the monoterpene β-pinene was investigated in the atmosphere simulation chamber SAPHIR in Jülich under low NOx and atmospheric β-pinene concentrations. While the budget of OH was balanced, both OH and HO2 concentrations were underestimated in the simulation results. These observations suggest the existence of unaccounted sources of HO2.
Tobias Borsdorff, Joost aan de Brugh, Haili Hu, Philippe Nédélec, Ilse Aben, and Jochen Landgraf
Atmos. Meas. Tech., 10, 1769–1782, https://doi.org/10.5194/amt-10-1769-2017, https://doi.org/10.5194/amt-10-1769-2017, 2017
Ulrich Schumann, Christoph Kiemle, Hans Schlager, Ralf Weigel, Stephan Borrmann, Francesco D'Amato, Martina Krämer, Renaud Matthey, Alain Protat, Christiane Voigt, and C. Michael Volk
Atmos. Chem. Phys., 17, 2311–2346, https://doi.org/10.5194/acp-17-2311-2017, https://doi.org/10.5194/acp-17-2311-2017, 2017
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A long-lived (1 h) contrail and overshooting convection were observed in the tropics, near Darwin, Australia. The data are used to study the contrail life cycle at low temperatures and cirrus from deep overturning convection in the lower tropical stratosphere. Airborne in situ, lidar, profiler, radar, and satellite data, as well as a photo, are used to distinguish contrail cirrus from convective cirrus and to study the origin of the observed ice and aerosol, up to 2.3 km above the tropopause.
Zhaofeng Tan, Hendrik Fuchs, Keding Lu, Andreas Hofzumahaus, Birger Bohn, Sebastian Broch, Huabin Dong, Sebastian Gomm, Rolf Häseler, Lingyan He, Frank Holland, Xin Li, Ying Liu, Sihua Lu, Franz Rohrer, Min Shao, Baolin Wang, Ming Wang, Yusheng Wu, Limin Zeng, Yinsong Zhang, Andreas Wahner, and Yuanhang Zhang
Atmos. Chem. Phys., 17, 663–690, https://doi.org/10.5194/acp-17-663-2017, https://doi.org/10.5194/acp-17-663-2017, 2017
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In this study, we performed accurate OH measurements as well as selective HO2 and RO2 measurements at a rural site in North China Plain with state-of-the-art instruments newly developed. We confirmed the previous discovery on the enhancement of the OH in low NOx with which little O3 production was associated, and we found a missing RO2 source in high NOx which promoted higher O3 production. Our results are of vital importance for ozone abatement strategies currently under discussion for China.
Hendrik Fuchs, Zhaofeng Tan, Keding Lu, Birger Bohn, Sebastian Broch, Steven S. Brown, Huabin Dong, Sebastian Gomm, Rolf Häseler, Lingyan He, Andreas Hofzumahaus, Frank Holland, Xin Li, Ying Liu, Sihua Lu, Kyung-Eun Min, Franz Rohrer, Min Shao, Baolin Wang, Ming Wang, Yusheng Wu, Limin Zeng, Yinson Zhang, Andreas Wahner, and Yuanhang Zhang
Atmos. Chem. Phys., 17, 645–661, https://doi.org/10.5194/acp-17-645-2017, https://doi.org/10.5194/acp-17-645-2017, 2017
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OH reactivity was measured during a 1-month long campaign at a rural site in the North China Plain in 2014. OH reactivity measurements are compared to calculations using OH reactant measurements. Good agreement is found indicating that all important OH reactants were measured. In addition, the chemical OH budget is analyzed. In contrast to previous campaigns in China in 2006, no significant imbalance between OH production and destruction is found.
Bernhard Buchholz, Armin Afchine, Alexander Klein, Cornelius Schiller, Martina Krämer, and Volker Ebert
Atmos. Meas. Tech., 10, 35–57, https://doi.org/10.5194/amt-10-35-2017, https://doi.org/10.5194/amt-10-35-2017, 2017
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HAI is a fully autonomous, airborne hygrometer for atmospheric investigations for simultaneous gas-phase/total H2O detection on the HALO aircraft. HAI employs first-principle, direct, tunable diode laser absorption spectroscopy (dTDLAS) for calibration-free, absolute H2O detection. HAI simultaneously measures at 1.4/2.6 µm and in closed-/open-path configuration, covers a H2O range of 1–40 000ppmv at up to 1.4 ms time resolution and achieves precisions of 0.18/0.055 ppmv at 1.4/2.6 µm.
Bärbel Vogel, Gebhard Günther, Rolf Müller, Jens-Uwe Grooß, Armin Afchine, Heiko Bozem, Peter Hoor, Martina Krämer, Stefan Müller, Martin Riese, Christian Rolf, Nicole Spelten, Gabriele P. Stiller, Jörn Ungermann, and Andreas Zahn
Atmos. Chem. Phys., 16, 15301–15325, https://doi.org/10.5194/acp-16-15301-2016, https://doi.org/10.5194/acp-16-15301-2016, 2016
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The identification of transport pathways from the Asian monsoon anticyclone into the lower stratosphere is unclear. Global simulations with the CLaMS model demonstrate that source regions in Asia and in the Pacific Ocean have a significant impact on the chemical composition of the lower stratosphere of the Northern Hemisphere by flooding the extratropical lower stratosphere with young moist air masses. Two main horizontal transport pathways from the Asian monsoon anticyclone are identified.
Hervé Petetin, Valérie Thouret, Alain Fontaine, Bastien Sauvage, Giles Athier, Romain Blot, Damien Boulanger, Jean-Marc Cousin, and Philippe Nédélec
Atmos. Chem. Phys., 16, 15147–15163, https://doi.org/10.5194/acp-16-15147-2016, https://doi.org/10.5194/acp-16-15147-2016, 2016
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Ozone (O3) and carbon monoxide (CO) are two compounds of major importance in the atmosphere. In this paper we investigated their variability and trends at Frankfurt based on the MOZAIC–IAGOS dataset, a unique dataset of about 21 300 vertical profiles recorded by commercial aircraft. The CO concentrations have been decreasing since 2002, while no strong tendency is observed for O3 since 1994. However, the O3 seasonal variations are changing, with the spring maximum occurring earlier and earlier.
Ralf Weigel, Peter Spichtinger, Christoph Mahnke, Marcus Klingebiel, Armin Afchine, Andreas Petzold, Martina Krämer, Anja Costa, Sergej Molleker, Philipp Reutter, Miklós Szakáll, Max Port, Lucas Grulich, Tina Jurkat, Andreas Minikin, and Stephan Borrmann
Atmos. Meas. Tech., 9, 5135–5162, https://doi.org/10.5194/amt-9-5135-2016, https://doi.org/10.5194/amt-9-5135-2016, 2016
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The subject of our study concerns measurements with optical array probes (OAPs) on fast-flying aircraft such as the G550 (HALO or HIAPER). At up to Mach 0.7 the effect of air compression upstream of underwing-mounted instruments and particles' inertia need consideration for determining ambient particle concentrations. Compared to conventional practices the introduced correction procedure eliminates ambiguities and exhibits consistency over flight speeds between 50 and 250 m s−.
Stefan Müller, Peter Hoor, Heiko Bozem, Ellen Gute, Bärbel Vogel, Andreas Zahn, Harald Bönisch, Timo Keber, Martina Krämer, Christian Rolf, Martin Riese, Hans Schlager, and Andreas Engel
Atmos. Chem. Phys., 16, 10573–10589, https://doi.org/10.5194/acp-16-10573-2016, https://doi.org/10.5194/acp-16-10573-2016, 2016
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In situ airborne measurements performed during TACTS/ESMVal 2012 were analysed to investigate the chemical compostion of the upper troposphere and lower stratosphere. N2O, CO and O3 data show an increase in tropospherically affected air masses within the extratropical stratosphere from August to September 2012, which originate from the Asian monsoon region. Thus, the Asian monsoon anticyclone significantly affected the chemical composition of the extratropical stratosphere during summer 2012.
Roeland Van Malderen, Marc A. F. Allaart, Hugo De Backer, Herman G. J. Smit, and Dirk De Muer
Atmos. Meas. Tech., 9, 3793–3816, https://doi.org/10.5194/amt-9-3793-2016, https://doi.org/10.5194/amt-9-3793-2016, 2016
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Thanks to the Montreal Protocol regulations for ozone-depleting substances, the decline of ozone concentrations has been stopped. A remaining major issue today is if the onset of ozone recovery can be detected. Ozonesondes have provided vertical distribution of ozone with high vertical resolution for several decades. In this study, we investigate how different operating procedures at ozonesonde stations and different ozonesonde data correction strategies affect trends in ozone concentrations.
Wolfgang Woiwode, Michael Höpfner, Lei Bi, Michael C. Pitts, Lamont R. Poole, Hermann Oelhaf, Sergej Molleker, Stephan Borrmann, Marcus Klingebiel, Gennady Belyaev, Andreas Ebersoldt, Sabine Griessbach, Jens-Uwe Grooß, Thomas Gulde, Martina Krämer, Guido Maucher, Christof Piesch, Christian Rolf, Christian Sartorius, Reinhold Spang, and Johannes Orphal
Atmos. Chem. Phys., 16, 9505–9532, https://doi.org/10.5194/acp-16-9505-2016, https://doi.org/10.5194/acp-16-9505-2016, 2016
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The analysis of spectral signatures of a polar stratospheric cloud in airborne infrared remote sensing observations in the Arctic in combination with further collocated measurements supports the view that the observed cloud consisted of highly aspherical nitric acid trihydrate particles. A characteristic "shoulder-like" spectral signature may be exploited for identification of large, highly aspherical nitric acid trihydrate particles involved in denitrification of the polar winter stratosphere.
Fanny Finger, Frank Werner, Marcus Klingebiel, André Ehrlich, Evelyn Jäkel, Matthias Voigt, Stephan Borrmann, Peter Spichtinger, and Manfred Wendisch
Atmos. Chem. Phys., 16, 7681–7693, https://doi.org/10.5194/acp-16-7681-2016, https://doi.org/10.5194/acp-16-7681-2016, 2016
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Solar spectra of optical layer properties of cirrus have been derived from the first truly collocated airborne radiation measurements using an aircraft and a towed sensor platform. The measured layer properties differ slightly due to horizontal cirrus inhomogeneities and the influence of low-level water clouds. Applying a 1-D radiative transfer model sensitivity studies were performed. It was found that if a low-level cloud is not considered, the solar cooling of the cirrus is strongly overestimated.
Erika Kienast-Sjögren, Christian Rolf, Patric Seifert, Ulrich K. Krieger, Bei P. Luo, Martina Krämer, and Thomas Peter
Atmos. Chem. Phys., 16, 7605–7621, https://doi.org/10.5194/acp-16-7605-2016, https://doi.org/10.5194/acp-16-7605-2016, 2016
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We present a climatology of mid-latitude cirrus cloud properties based on 13 000 hours of automatically analyzed lidar measurements at three different sites. Jungfraujoch,
situated at 3580 m a.s.l., is found to be ideal to measure high and optically thin
cirrus. We use our retrieved optical properties together with a radiation model and
estimate the radiative forcing by mid-latitude cirrus.
All cirrus clouds detected here have a positive net radiative effect.
Daan Hubert, Jean-Christopher Lambert, Tijl Verhoelst, José Granville, Arno Keppens, Jean-Luc Baray, Adam E. Bourassa, Ugo Cortesi, Doug A. Degenstein, Lucien Froidevaux, Sophie Godin-Beekmann, Karl W. Hoppel, Bryan J. Johnson, Erkki Kyrölä, Thierry Leblanc, Günter Lichtenberg, Marion Marchand, C. Thomas McElroy, Donal Murtagh, Hideaki Nakane, Thierry Portafaix, Richard Querel, James M. Russell III, Jacobo Salvador, Herman G. J. Smit, Kerstin Stebel, Wolfgang Steinbrecht, Kevin B. Strawbridge, René Stübi, Daan P. J. Swart, Ghassan Taha, David W. Tarasick, Anne M. Thompson, Joachim Urban, Joanna A. E. van Gijsel, Roeland Van Malderen, Peter von der Gathen, Kaley A. Walker, Elian Wolfram, and Joseph M. Zawodny
Atmos. Meas. Tech., 9, 2497–2534, https://doi.org/10.5194/amt-9-2497-2016, https://doi.org/10.5194/amt-9-2497-2016, 2016
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A more detailed understanding of satellite O3 profile data records is vital for further progress in O3 research. To this end, we made a comprehensive assessment of 14 limb/occultation profilers using ground-based reference data. The mutual consistency of satellite O3 in terms of bias, short-term variability and decadal stability is generally good over most of the stratosphere. However, we identified some exceptions that impact the quality of recently merged data sets and ozone trend assessments.
Florian Berkes, Peter Hoor, Heiko Bozem, Daniel Kunkel, Michael Sprenger, and Stephan Henne
Atmos. Chem. Phys., 16, 6011–6025, https://doi.org/10.5194/acp-16-6011-2016, https://doi.org/10.5194/acp-16-6011-2016, 2016
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We presented airborne measurements of CO2 and O3 across the entrainment zone over a semi-remote environment in southwestern Germany in late summer 2011 .
For the first time CO2 and O3 were used as tracer to identify mixing through this transport barrier. We demonstrated that the tracer--tracer correlation of CO2 and O3 is a powerful tool to identify entrainment and mixing.
Anna E. Luebke, Armin Afchine, Anja Costa, Jens-Uwe Grooß, Jessica Meyer, Christian Rolf, Nicole Spelten, Linnea M. Avallone, Darrel Baumgardner, and Martina Krämer
Atmos. Chem. Phys., 16, 5793–5809, https://doi.org/10.5194/acp-16-5793-2016, https://doi.org/10.5194/acp-16-5793-2016, 2016
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In this study, we present observational evidence to show that two distinct types of cirrus clouds exist – in situ origin and liquid origin cirrus. These two types differ by their formation mechanism and other properties. Airborne, in-cloud measurements of cloud ice water content (IWC), ice crystal concentration (Nice), and ice crystal size from the 2014 ML-CIRRUS campaign provide cloud samples that have been divided and analyzed according to their origin type.
N. Sobanski, M. J. Tang, J. Thieser, G. Schuster, D. Pöhler, H. Fischer, W. Song, C. Sauvage, J. Williams, J. Fachinger, F. Berkes, P. Hoor, U. Platt, J. Lelieveld, and J. N. Crowley
Atmos. Chem. Phys., 16, 4867–4883, https://doi.org/10.5194/acp-16-4867-2016, https://doi.org/10.5194/acp-16-4867-2016, 2016
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The nitrate radical (NO3) is an important nocturnal oxidant. By measuring NO3, its precursors (nitrogen dioxide and ozone) and several trace gases with which it reacts, we examined the chemical and meteorological factors influencing the lifetime of NO3 at a semi-rural mountain site. Unexpectedly long lifetimes, approaching 1 h, were observed on several nights and were associated with a low-lying residual layer. We discuss the role of other reactions that convert NO2 to NO3.
Hendrik Fuchs, Zhaofeng Tan, Andreas Hofzumahaus, Sebastian Broch, Hans-Peter Dorn, Frank Holland, Christopher Künstler, Sebastian Gomm, Franz Rohrer, Stephanie Schrade, Ralf Tillmann, and Andreas Wahner
Atmos. Meas. Tech., 9, 1431–1447, https://doi.org/10.5194/amt-9-1431-2016, https://doi.org/10.5194/amt-9-1431-2016, 2016
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The hydroxyl radical is the key reactant that controls the chemical transformation of pollutants in the atmosphere. Observations of nighttime radicals concentrations were larger than predicted by models in field campaigns in forested and urban environments. Here, we investigated, if measurements could have been affected by artifacts. No significant interferences were found for atmospheric concentrations of reactants in ozonolysis experiments, but small artificats from nitrate radicals.
T. Hohaus, U. Kuhn, S. Andres, M. Kaminski, F. Rohrer, R. Tillmann, A. Wahner, R. Wegener, Z. Yu, and A. Kiendler-Scharr
Atmos. Meas. Tech., 9, 1247–1259, https://doi.org/10.5194/amt-9-1247-2016, https://doi.org/10.5194/amt-9-1247-2016, 2016
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As an extension of the atmosphere simulation chamber SAPHIR, an environmentally-controlled dynamic (flow-through) plant chamber under SAPHIR (SAPHIR-PLUS) was developed. This facility allows for feeding a natural blend of biogenic trace gases into SAPHIR. PLUS is utilized to characterize the atmospheric chemistry of natural trace gas mixtures at close to ambient concentration levels. In this study, the results of the initial characterization experiments are presented in detail.
Martina Krämer, Christian Rolf, Anna Luebke, Armin Afchine, Nicole Spelten, Anja Costa, Jessica Meyer, Martin Zöger, Jessica Smith, Robert L. Herman, Bernhard Buchholz, Volker Ebert, Darrel Baumgardner, Stephan Borrmann, Marcus Klingebiel, and Linnea Avallone
Atmos. Chem. Phys., 16, 3463–3483, https://doi.org/10.5194/acp-16-3463-2016, https://doi.org/10.5194/acp-16-3463-2016, 2016
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A guide to cirrus clouds is compiled from extensive model simulations and aircraft observations. Two types of cirrus are found: rather thin in situ cirrus that form directly as ice and thicker liquid origin cirrus consisting of uplifted frozen liquid drops. Over Europe, thinner in situ and liquid origin cirrus occur often together with frontal systems, while over the US and the Tropics, thick liquid origin cirrus formed in large convective systems are detected more frequently.
D. F. Zhao, A. Buchholz, B. Kortner, P. Schlag, F. Rubach, H. Fuchs, A. Kiendler-Scharr, R. Tillmann, A. Wahner, Å. K. Watne, M. Hallquist, J. M. Flores, Y. Rudich, K. Kristensen, A. M. K. Hansen, M. Glasius, I. Kourtchev, M. Kalberer, and Th. F. Mentel
Atmos. Chem. Phys., 16, 1105–1121, https://doi.org/10.5194/acp-16-1105-2016, https://doi.org/10.5194/acp-16-1105-2016, 2016
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This study investigated the cloud droplet activation behavior and hygroscopic growth of mixed anthropogenic and biogenic SOA (ABSOA) compared to pure biogenic SOA (BSOA) and pure anthropogenic SOA (ASOA). Cloud droplet activation behaviors of different types of SOA were similar. In contrast, the hygroscopicity of ASOA was higher than BSOA and ABSOA. ASOA components enhanced the hygroscopicity of the ABSOA. Yet this enhancement cannot be described by a linear mixing of pure SOA systems.
D. W. Tarasick, J. Davies, H. G. J. Smit, and S. J. Oltmans
Atmos. Meas. Tech., 9, 195–214, https://doi.org/10.5194/amt-9-195-2016, https://doi.org/10.5194/amt-9-195-2016, 2016
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Changes to measurement methods over Canada's 48-year ozonesonde record have been characterized and corrections applied. An estimate of the altitude-dependent uncertainty is added to each profile. The re-evaluated time series show negative trends in the lower stratosphere of up to 5 % per decade for the period 1966–2013. In the troposphere trends for the 48-year period are generally not significant. This suggests that free tropospheric ozone levels over Canada have not changed in nearly 50 years.
K. Weigel, A. Rozanov, F. Azam, K. Bramstedt, R. Damadeo, K.-U. Eichmann, C. Gebhardt, D. Hurst, M. Kraemer, S. Lossow, W. Read, N. Spelten, G. P. Stiller, K. A. Walker, M. Weber, H. Bovensmann, and J. P. Burrows
Atmos. Meas. Tech., 9, 133–158, https://doi.org/10.5194/amt-9-133-2016, https://doi.org/10.5194/amt-9-133-2016, 2016
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The SCanning Imaging Absorption spectroMeter for Atmospheric CHartographY (SCIAMACHY) aboard the Envisat satellite provided measurements between 2002 and 2012 with different viewing geometries. The limb viewing geometry allows the retrieval of water vapour profiles in the UTLS (upper troposphere and lower stratosphere) from the near-infrared spectral range (1353–1410 nm). Here, we present data version 3.01 and compare it to other water vapour data.
D. Chang, Y. Cheng, P. Reutter, J. Trentmann, S. M. Burrows, P. Spichtinger, S. Nordmann, M. O. Andreae, U. Pöschl, and H. Su
Atmos. Chem. Phys., 15, 10325–10348, https://doi.org/10.5194/acp-15-10325-2015, https://doi.org/10.5194/acp-15-10325-2015, 2015
C. Rolf, A. Afchine, H. Bozem, B. Buchholz, V. Ebert, T. Guggenmoser, P. Hoor, P. Konopka, E. Kretschmer, S. Müller, H. Schlager, N. Spelten, O. Sumińska-Ebersoldt, J. Ungermann, A. Zahn, and M. Krämer
Atmos. Chem. Phys., 15, 9143–9158, https://doi.org/10.5194/acp-15-9143-2015, https://doi.org/10.5194/acp-15-9143-2015, 2015
J. Meyer, C. Rolf, C. Schiller, S. Rohs, N. Spelten, A. Afchine, M. Zöger, N. Sitnikov, T. D. Thornberry, A. W. Rollins, Z. Bozóki, D. Tátrai, V. Ebert, B. Kühnreich, P. Mackrodt, O. Möhler, H. Saathoff, K. H. Rosenlof, and M. Krämer
Atmos. Chem. Phys., 15, 8521–8538, https://doi.org/10.5194/acp-15-8521-2015, https://doi.org/10.5194/acp-15-8521-2015, 2015
W. Woiwode, O. Sumińska-Ebersoldt, H. Oelhaf, M. Höpfner, G. V. Belyaev, A. Ebersoldt, F. Friedl-Vallon, J.-U. Grooß, T. Gulde, M. Kaufmann, A. Kleinert, M. Krämer, E. Kretschmer, T. Kulessa, G. Maucher, T. Neubert, C. Piesch, P. Preusse, M. Riese, H. Rongen, C. Sartorius, G. Schardt, A. Schönfeld, D. Schuettemeyer, M. K. Sha, F. Stroh, J. Ungermann, C. M. Volk, and J. Orphal
Atmos. Meas. Tech., 8, 2509–2520, https://doi.org/10.5194/amt-8-2509-2015, https://doi.org/10.5194/amt-8-2509-2015, 2015
T. F. Mentel, M. Springer, M. Ehn, E. Kleist, I. Pullinen, T. Kurtén, M. Rissanen, A. Wahner, and J. Wildt
Atmos. Chem. Phys., 15, 6745–6765, https://doi.org/10.5194/acp-15-6745-2015, https://doi.org/10.5194/acp-15-6745-2015, 2015
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We studied a series of cycloalkenes and methyl-substituted alkenes in order to elucidate the structural pre-requisites and chemical pathways to the recently discovered class of highly oxidized molecules ELVOC (Ehn et al., Nature, 2014). ELVOC may totally change the view on (parts of) the mechanism of SOA formation. We present results which support recent observations of H shifts from C-H to peroxy radicals, highlighting the pivotal role of peroxyradicals in organic atmospheric chemistry.
J. Ungermann, J. Blank, M. Dick, A. Ebersoldt, F. Friedl-Vallon, A. Giez, T. Guggenmoser, M. Höpfner, T. Jurkat, M. Kaufmann, S. Kaufmann, A. Kleinert, M. Krämer, T. Latzko, H. Oelhaf, F. Olchewski, P. Preusse, C. Rolf, J. Schillings, O. Suminska-Ebersoldt, V. Tan, N. Thomas, C. Voigt, A. Zahn, M. Zöger, and M. Riese
Atmos. Meas. Tech., 8, 2473–2489, https://doi.org/10.5194/amt-8-2473-2015, https://doi.org/10.5194/amt-8-2473-2015, 2015
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The GLORIA sounder is an airborne infrared limb-imager combining a two-dimensional infrared detector with a Fourier transform spectrometer. It was operated aboard the new German Gulfstream G550 research aircraft HALO during the TACTS and ESMVAL campaigns in summer 2012. This paper describes the retrieval of temperature, as well as H2O, HNO3, and O3 cross sections from GLORIA dynamics mode spectra. A high correlation is achieved between the remote sensing and the in situ trace gas measurements.
P. Neis, H. G. J. Smit, M. Krämer, N. Spelten, and A. Petzold
Atmos. Meas. Tech., 8, 1233–1243, https://doi.org/10.5194/amt-8-1233-2015, https://doi.org/10.5194/amt-8-1233-2015, 2015
J. Kaiser, G. M. Wolfe, B. Bohn, S. Broch, H. Fuchs, L. N. Ganzeveld, S. Gomm, R. Häseler, A. Hofzumahaus, F. Holland, J. Jäger, X. Li, I. Lohse, K. Lu, A. S. H. Prévôt, F. Rohrer, R. Wegener, R. Wolf, T. F. Mentel, A. Kiendler-Scharr, A. Wahner, and F. N. Keutsch
Atmos. Chem. Phys., 15, 1289–1298, https://doi.org/10.5194/acp-15-1289-2015, https://doi.org/10.5194/acp-15-1289-2015, 2015
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Using measurements acquired from a Zeppelin airship during the PEGASOS 2012 campaign, we show that VOC oxidation alone cannot account for the formaldehyde concentrations observed in the morning over rural Italy. Vertical profiles suggest a ground-level source of HCHO. Incorporating this additional HCHO source into a photochemical model increases calculated O3 production by as much as 12%.
D. F. Zhao, M. Kaminski, P. Schlag, H. Fuchs, I.-H. Acir, B. Bohn, R. Häseler, A. Kiendler-Scharr, F. Rohrer, R. Tillmann, M. J. Wang, R. Wegener, J. Wildt, A. Wahner, and Th. F. Mentel
Atmos. Chem. Phys., 15, 991–1012, https://doi.org/10.5194/acp-15-991-2015, https://doi.org/10.5194/acp-15-991-2015, 2015
C. Wu, I. Pullinen, S. Andres, G. Carriero, S. Fares, H. Goldbach, L. Hacker, T. Kasal, A. Kiendler-Scharr, E. Kleist, E. Paoletti, A. Wahner, J. Wildt, and Th. F. Mentel
Biogeosciences, 12, 177–191, https://doi.org/10.5194/bg-12-177-2015, https://doi.org/10.5194/bg-12-177-2015, 2015
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Impacts of soil moisture on de novo monoterpene emissions from several tree species were studied. Mild drought slightly increased MT emissions, but with further progressing drought the emissions decreased to almost zero. Increases of MT emissions were explainable by increases of leaf temperature due to lowered transpirational cooling. The decrease of emissions observed when soil moisture fell below certain thresholds was parameterized, allowing considering impacts of soil moisture in models.
D. Tátrai, Z. Bozóki, H. Smit, C. Rolf, N. Spelten, M. Krämer, A. Filges, C. Gerbig, G. Gulyás, and G. Szabó
Atmos. Meas. Tech., 8, 33–42, https://doi.org/10.5194/amt-8-33-2015, https://doi.org/10.5194/amt-8-33-2015, 2015
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Airborne hygrometry is very important in climate research, and the interest in knowing not only water vapor concentration but (cirrus) cloud content as well is increasing. The authors provide a photoacoustic spectroscopy-based dual-channel hygrometer system that can be a good solution for such measurements. The instrument was proven to operate properly from ground level up to the lower stratosphere, giving the possibility even for cirrus cloud studies.
H. G. J. Smit, S. Rohs, P. Neis, D. Boulanger, M. Krämer, A. Wahner, and A. Petzold
Atmos. Chem. Phys., 14, 13241–13255, https://doi.org/10.5194/acp-14-13241-2014, https://doi.org/10.5194/acp-14-13241-2014, 2014
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Long-term water vapour measurements from the MOZAIC programme are a unique source for upper troposphere humidity data. However, due to an error in the calibration procedure, RH data from MOZAIC were biased towards higher values for the period starting in year 2000. Here we report the procedures followed to reanalyse the calibrations and to reprocess the entire MOZAIC RH data. This study serves as the reference publication for the reanalysed MOZAIC RH data base for the period 1994 to 2009.
R. Pommrich, R. Müller, J.-U. Grooß, P. Konopka, F. Ploeger, B. Vogel, M. Tao, C. M. Hoppe, G. Günther, N. Spelten, L. Hoffmann, H.-C. Pumphrey, S. Viciani, F. D'Amato, C. M. Volk, P. Hoor, H. Schlager, and M. Riese
Geosci. Model Dev., 7, 2895–2916, https://doi.org/10.5194/gmd-7-2895-2014, https://doi.org/10.5194/gmd-7-2895-2014, 2014
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A version of the chemical transport model CLaMS is presented, which features a simplified (numerically inexpensive) chemistry scheme. The model results using this version of CLaMS show a good representation of anomaly fields of CO, CH4, N2O, and CFC-11 in the lower stratosphere. CO measurements of three instruments (COLD, HAGAR, and Falcon-CO) in the lower tropical stratosphere (during the campaign TROCCINOX in 2005) have been compared and show a good agreement within the error bars.
B. Vogel, G. Günther, R. Müller, J.-U. Grooß, P. Hoor, M. Krämer, S. Müller, A. Zahn, and M. Riese
Atmos. Chem. Phys., 14, 12745–12762, https://doi.org/10.5194/acp-14-12745-2014, https://doi.org/10.5194/acp-14-12745-2014, 2014
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Enhanced tropospheric trace gases (e.g. pollutants) were measured in situ in
the lowermost stratosphere over Northern Europe on 26 September 2012
during the TACTS aircraft campaign. We found that the combination of rapid uplift by a typhoon and eastward eddy shedding from the Asian monsoon anticyclone is a novel fast transport pathway
that may carry boundary emissions from Southeast
Asia/western Pacific within approximately 5 weeks to the lowermost
stratosphere in Northern Europe.
X. Li, F. Rohrer, T. Brauers, A. Hofzumahaus, K. Lu, M. Shao, Y. H. Zhang, and A. Wahner
Atmos. Chem. Phys., 14, 12291–12305, https://doi.org/10.5194/acp-14-12291-2014, https://doi.org/10.5194/acp-14-12291-2014, 2014
A. Kunz, N. Spelten, P. Konopka, R. Müller, R. M. Forbes, and H. Wernli
Atmos. Chem. Phys., 14, 10803–10822, https://doi.org/10.5194/acp-14-10803-2014, https://doi.org/10.5194/acp-14-10803-2014, 2014
S. Molleker, S. Borrmann, H. Schlager, B. Luo, W. Frey, M. Klingebiel, R. Weigel, M. Ebert, V. Mitev, R. Matthey, W. Woiwode, H. Oelhaf, A. Dörnbrack, G. Stratmann, J.-U. Grooß, G. Günther, B. Vogel, R. Müller, M. Krämer, J. Meyer, and F. Cairo
Atmos. Chem. Phys., 14, 10785–10801, https://doi.org/10.5194/acp-14-10785-2014, https://doi.org/10.5194/acp-14-10785-2014, 2014
D. W. Fahey, R.-S. Gao, O. Möhler, H. Saathoff, C. Schiller, V. Ebert, M. Krämer, T. Peter, N. Amarouche, L. M. Avallone, R. Bauer, Z. Bozóki, L. E. Christensen, S. M. Davis, G. Durry, C. Dyroff, R. L. Herman, S. Hunsmann, S. M. Khaykin, P. Mackrodt, J. Meyer, J. B. Smith, N. Spelten, R. F. Troy, H. Vömel, S. Wagner, and F. G. Wienhold
Atmos. Meas. Tech., 7, 3177–3213, https://doi.org/10.5194/amt-7-3177-2014, https://doi.org/10.5194/amt-7-3177-2014, 2014
H. Fuchs, I.-H. Acir, B. Bohn, T. Brauers, H.-P. Dorn, R. Häseler, A. Hofzumahaus, F. Holland, M. Kaminski, X. Li, K. Lu, A. Lutz, S. Nehr, F. Rohrer, R. Tillmann, R. Wegener, and A. Wahner
Atmos. Chem. Phys., 14, 7895–7908, https://doi.org/10.5194/acp-14-7895-2014, https://doi.org/10.5194/acp-14-7895-2014, 2014
A. Cirisan, B. P. Luo, I. Engel, F. G. Wienhold, M. Sprenger, U. K. Krieger, U. Weers, G. Romanens, G. Levrat, P. Jeannet, D. Ruffieux, R. Philipona, B. Calpini, P. Spichtinger, and T. Peter
Atmos. Chem. Phys., 14, 7341–7365, https://doi.org/10.5194/acp-14-7341-2014, https://doi.org/10.5194/acp-14-7341-2014, 2014
H. Joos, P. Spichtinger, P. Reutter, and F. Fusina
Atmos. Chem. Phys., 14, 6835–6852, https://doi.org/10.5194/acp-14-6835-2014, https://doi.org/10.5194/acp-14-6835-2014, 2014
S. Nehr, B. Bohn, H.-P. Dorn, H. Fuchs, R. Häseler, A. Hofzumahaus, X. Li, F. Rohrer, R. Tillmann, and A. Wahner
Atmos. Chem. Phys., 14, 6941–6952, https://doi.org/10.5194/acp-14-6941-2014, https://doi.org/10.5194/acp-14-6941-2014, 2014
J. Tian, N. Riemer, M. West, L. Pfaffenberger, H. Schlager, and A. Petzold
Atmos. Chem. Phys., 14, 5327–5347, https://doi.org/10.5194/acp-14-5327-2014, https://doi.org/10.5194/acp-14-5327-2014, 2014
K. D. Lu, F. Rohrer, F. Holland, H. Fuchs, T. Brauers, A. Oebel, R. Dlugi, M. Hu, X. Li, S. R. Lou, M. Shao, T. Zhu, A. Wahner, Y. H. Zhang, and A. Hofzumahaus
Atmos. Chem. Phys., 14, 4979–4999, https://doi.org/10.5194/acp-14-4979-2014, https://doi.org/10.5194/acp-14-4979-2014, 2014
B. Hassler, I. Petropavlovskikh, J. Staehelin, T. August, P. K. Bhartia, C. Clerbaux, D. Degenstein, M. De Mazière, B. M. Dinelli, A. Dudhia, G. Dufour, S. M. Frith, L. Froidevaux, S. Godin-Beekmann, J. Granville, N. R. P. Harris, K. Hoppel, D. Hubert, Y. Kasai, M. J. Kurylo, E. Kyrölä, J.-C. Lambert, P. F. Levelt, C. T. McElroy, R. D. McPeters, R. Munro, H. Nakajima, A. Parrish, P. Raspollini, E. E. Remsberg, K. H. Rosenlof, A. Rozanov, T. Sano, Y. Sasano, M. Shiotani, H. G. J. Smit, G. Stiller, J. Tamminen, D. W. Tarasick, J. Urban, R. J. van der A, J. P. Veefkind, C. Vigouroux, T. von Clarmann, C. von Savigny, K. A. Walker, M. Weber, J. Wild, and J. M. Zawodny
Atmos. Meas. Tech., 7, 1395–1427, https://doi.org/10.5194/amt-7-1395-2014, https://doi.org/10.5194/amt-7-1395-2014, 2014
G. W. Mann, K. S. Carslaw, C. L. Reddington, K. J. Pringle, M. Schulz, A. Asmi, D. V. Spracklen, D. A. Ridley, M. T. Woodhouse, L. A. Lee, K. Zhang, S. J. Ghan, R. C. Easter, X. Liu, P. Stier, Y. H. Lee, P. J. Adams, H. Tost, J. Lelieveld, S. E. Bauer, K. Tsigaridis, T. P. C. van Noije, A. Strunk, E. Vignati, N. Bellouin, M. Dalvi, C. E. Johnson, T. Bergman, H. Kokkola, K. von Salzen, F. Yu, G. Luo, A. Petzold, J. Heintzenberg, A. Clarke, J. A. Ogren, J. Gras, U. Baltensperger, U. Kaminski, S. G. Jennings, C. D. O'Dowd, R. M. Harrison, D. C. S. Beddows, M. Kulmala, Y. Viisanen, V. Ulevicius, N. Mihalopoulos, V. Zdimal, M. Fiebig, H.-C. Hansson, E. Swietlicki, and J. S. Henzing
Atmos. Chem. Phys., 14, 4679–4713, https://doi.org/10.5194/acp-14-4679-2014, https://doi.org/10.5194/acp-14-4679-2014, 2014
J. Wildt, T. F. Mentel, A. Kiendler-Scharr, T. Hoffmann, S. Andres, M. Ehn, E. Kleist, P. Müsgen, F. Rohrer, Y. Rudich, M. Springer, R. Tillmann, and A. Wahner
Atmos. Chem. Phys., 14, 2789–2804, https://doi.org/10.5194/acp-14-2789-2014, https://doi.org/10.5194/acp-14-2789-2014, 2014
J. C. Corbin, B. Sierau, M. Gysel, M. Laborde, A. Keller, J. Kim, A. Petzold, T. B. Onasch, U. Lohmann, and A. A. Mensah
Atmos. Chem. Phys., 14, 2591–2603, https://doi.org/10.5194/acp-14-2591-2014, https://doi.org/10.5194/acp-14-2591-2014, 2014
P. Jeßberger, C. Voigt, U. Schumann, I. Sölch, H. Schlager, S. Kaufmann, A. Petzold, D. Schäuble, and J.-F. Gayet
Atmos. Chem. Phys., 13, 11965–11984, https://doi.org/10.5194/acp-13-11965-2013, https://doi.org/10.5194/acp-13-11965-2013, 2013
S. M. Khaykin, I. Engel, H. Vömel, I. M. Formanyuk, R. Kivi, L. I. Korshunov, M. Krämer, A. D. Lykov, S. Meier, T. Naebert, M. C. Pitts, M. L. Santee, N. Spelten, F. G. Wienhold, V. A. Yushkov, and T. Peter
Atmos. Chem. Phys., 13, 11503–11517, https://doi.org/10.5194/acp-13-11503-2013, https://doi.org/10.5194/acp-13-11503-2013, 2013
R. M. Varma, S. M. Ball, T. Brauers, H.-P. Dorn, U. Heitmann, R. L. Jones, U. Platt, D. Pöhler, A. A. Ruth, A. J. L. Shillings, J. Thieser, A. Wahner, and D. S. Venables
Atmos. Meas. Tech., 6, 3115–3130, https://doi.org/10.5194/amt-6-3115-2013, https://doi.org/10.5194/amt-6-3115-2013, 2013
P. Spichtinger and M. Krämer
Atmos. Chem. Phys., 13, 9801–9818, https://doi.org/10.5194/acp-13-9801-2013, https://doi.org/10.5194/acp-13-9801-2013, 2013
M. von Hobe, S. Bekki, S. Borrmann, F. Cairo, F. D'Amato, G. Di Donfrancesco, A. Dörnbrack, A. Ebersoldt, M. Ebert, C. Emde, I. Engel, M. Ern, W. Frey, S. Genco, S. Griessbach, J.-U. Grooß, T. Gulde, G. Günther, E. Hösen, L. Hoffmann, V. Homonnai, C. R. Hoyle, I. S. A. Isaksen, D. R. Jackson, I. M. Jánosi, R. L. Jones, K. Kandler, C. Kalicinsky, A. Keil, S. M. Khaykin, F. Khosrawi, R. Kivi, J. Kuttippurath, J. C. Laube, F. Lefèvre, R. Lehmann, S. Ludmann, B. P. Luo, M. Marchand, J. Meyer, V. Mitev, S. Molleker, R. Müller, H. Oelhaf, F. Olschewski, Y. Orsolini, T. Peter, K. Pfeilsticker, C. Piesch, M. C. Pitts, L. R. Poole, F. D. Pope, F. Ravegnani, M. Rex, M. Riese, T. Röckmann, B. Rognerud, A. Roiger, C. Rolf, M. L. Santee, M. Scheibe, C. Schiller, H. Schlager, M. Siciliani de Cumis, N. Sitnikov, O. A. Søvde, R. Spang, N. Spelten, F. Stordal, O. Sumińska-Ebersoldt, A. Ulanovski, J. Ungermann, S. Viciani, C. M. Volk, M. vom Scheidt, P. von der Gathen, K. Walker, T. Wegner, R. Weigel, S. Weinbruch, G. Wetzel, F. G. Wienhold, I. Wohltmann, W. Woiwode, I. A. K. Young, V. Yushkov, B. Zobrist, and F. Stroh
Atmos. Chem. Phys., 13, 9233–9268, https://doi.org/10.5194/acp-13-9233-2013, https://doi.org/10.5194/acp-13-9233-2013, 2013
E. Kienast-Sjögren, P. Spichtinger, and K. Gierens
Atmos. Chem. Phys., 13, 9021–9037, https://doi.org/10.5194/acp-13-9021-2013, https://doi.org/10.5194/acp-13-9021-2013, 2013
Th. F. Mentel, E. Kleist, S. Andres, M. Dal Maso, T. Hohaus, A. Kiendler-Scharr, Y. Rudich, M. Springer, R. Tillmann, R. Uerlings, A. Wahner, and J. Wildt
Atmos. Chem. Phys., 13, 8755–8770, https://doi.org/10.5194/acp-13-8755-2013, https://doi.org/10.5194/acp-13-8755-2013, 2013
A. Petzold, J. A. Ogren, M. Fiebig, P. Laj, S.-M. Li, U. Baltensperger, T. Holzer-Popp, S. Kinne, G. Pappalardo, N. Sugimoto, C. Wehrli, A. Wiedensohler, and X.-Y. Zhang
Atmos. Chem. Phys., 13, 8365–8379, https://doi.org/10.5194/acp-13-8365-2013, https://doi.org/10.5194/acp-13-8365-2013, 2013
A. E. Luebke, L. M. Avallone, C. Schiller, J. Meyer, C. Rolf, and M. Krämer
Atmos. Chem. Phys., 13, 6447–6459, https://doi.org/10.5194/acp-13-6447-2013, https://doi.org/10.5194/acp-13-6447-2013, 2013
Y. P. Li, H. Elbern, K. D. Lu, E. Friese, A. Kiendler-Scharr, Th. F. Mentel, X. S. Wang, A. Wahner, and Y. H. Zhang
Atmos. Chem. Phys., 13, 6289–6304, https://doi.org/10.5194/acp-13-6289-2013, https://doi.org/10.5194/acp-13-6289-2013, 2013
G. Wetzel, H. Oelhaf, G. Berthet, A. Bracher, C. Cornacchia, D. G. Feist, H. Fischer, A. Fix, M. Iarlori, A. Kleinert, A. Lengel, M. Milz, L. Mona, S. C. Müller, J. Ovarlez, G. Pappalardo, C. Piccolo, P. Raspollini, J.-B. Renard, V. Rizi, S. Rohs, C. Schiller, G. Stiller, M. Weber, and G. Zhang
Atmos. Chem. Phys., 13, 5791–5811, https://doi.org/10.5194/acp-13-5791-2013, https://doi.org/10.5194/acp-13-5791-2013, 2013
A. Petzold, T. Onasch, P. Kebabian, and A. Freedman
Atmos. Meas. Tech., 6, 1141–1151, https://doi.org/10.5194/amt-6-1141-2013, https://doi.org/10.5194/amt-6-1141-2013, 2013
H.-P. Dorn, R. L. Apodaca, S. M. Ball, T. Brauers, S. S. Brown, J. N. Crowley, W. P. Dubé, H. Fuchs, R. Häseler, U. Heitmann, R. L. Jones, A. Kiendler-Scharr, I. Labazan, J. M. Langridge, J. Meinen, T. F. Mentel, U. Platt, D. Pöhler, F. Rohrer, A. A. Ruth, E. Schlosser, G. Schuster, A. J. L. Shillings, W. R. Simpson, J. Thieser, R. Tillmann, R. Varma, D. S. Venables, and A. Wahner
Atmos. Meas. Tech., 6, 1111–1140, https://doi.org/10.5194/amt-6-1111-2013, https://doi.org/10.5194/amt-6-1111-2013, 2013
E. U. Emanuelsson, M. Hallquist, K. Kristensen, M. Glasius, B. Bohn, H. Fuchs, B. Kammer, A. Kiendler-Scharr, S. Nehr, F. Rubach, R. Tillmann, A. Wahner, H.-C. Wu, and Th. F. Mentel
Atmos. Chem. Phys., 13, 2837–2855, https://doi.org/10.5194/acp-13-2837-2013, https://doi.org/10.5194/acp-13-2837-2013, 2013
S. Groß, M. Esselborn, B. Weinzierl, M. Wirth, A. Fix, and A. Petzold
Atmos. Chem. Phys., 13, 2487–2505, https://doi.org/10.5194/acp-13-2487-2013, https://doi.org/10.5194/acp-13-2487-2013, 2013
R. Weller, A. Minikin, A. Petzold, D. Wagenbach, and G. König-Langlo
Atmos. Chem. Phys., 13, 1579–1590, https://doi.org/10.5194/acp-13-1579-2013, https://doi.org/10.5194/acp-13-1579-2013, 2013
M. Gysel, M. Laborde, A. A. Mensah, J. C. Corbin, A. Keller, J. Kim, A. Petzold, and B. Sierau
Atmos. Meas. Tech., 5, 3099–3107, https://doi.org/10.5194/amt-5-3099-2012, https://doi.org/10.5194/amt-5-3099-2012, 2012
T. Hamburger, G. McMeeking, A. Minikin, A. Petzold, H. Coe, and R. Krejci
Atmos. Chem. Phys., 12, 11533–11554, https://doi.org/10.5194/acp-12-11533-2012, https://doi.org/10.5194/acp-12-11533-2012, 2012
Related subject area
Subject: Clouds and Precipitation | Research Activity: Field Measurements | Altitude Range: Troposphere | Science Focus: Physics (physical properties and processes)
Characterization of fog microphysics and their relationships with visibility at a mountain site in China
Hunting for gravity waves in non-orographic winter storms using 3+ years of regional surface air pressure network and radar observations
Theoretical framework for measuring cloud effective supersaturation fluctuations with an advanced optical system
Investigating the role of typhoon-induced waves and stratospheric hydration in the formation of tropopause cirrus clouds observed during the 2017 Asian monsoon
How does riming influence the observed spatial variability of ice water in mixed-phase clouds?
In-cloud characteristics observed in US Northeast and Midwest non-orographic winter storms with implications for ice particle mass growth and residence time
Microphysical view of the development and ice production of mid-latitude stratiform clouds with embedded convection during an extratropical cyclone
Measurement Report: A survey of meteorological and cloud properties during ACTIVATE's postfrontal flights and their suitability for Lagrangian case studies
Clouds and precipitation in the initial phase of marine cold-air outbreaks as observed by airborne remote sensing
Light scattering and microphysical properties of atmospheric bullet rosette ice crystals
Quantified ice-nucleating ability of AgI-containing seeding particles in natural clouds
Estimating the snow density using collocated Parsivel and Micro-Rain Radar measurements: a preliminary study from ICE-POP 2017/2018
Technical note: On the ice microphysics of isolated thunderstorms and non-thunderstorms in southern China – a radar polarimetric perspective
Distinctive aerosol–cloud–precipitation interactions in marine boundary layer clouds from the ACE-ENA and SOCRATES aircraft field campaigns
Aerosol Indirect Effects on Cirrus Clouds Based on Global-Scale Airborne Observations and Machine Learning Models
Drivers of droplet formation in east Mediterranean orographic clouds
Observability of moisture transport divergence in Arctic atmospheric rivers by dropsondes
Elucidating the boundary layer turbulence dissipation rate using high-resolution measurements from a radar wind profiler network over the Tibetan Plateau
Environmental controls on isolated convection during the Amazonian wet season
Isotopic composition of convective rainfall in the inland tropics of Brazil
Measurement report: Cloud and environmental properties associated with aggregated shallow marine cumulus and cumulus congestus
Vertical Profiles of Liquid Water Content in fog layers during the SOFOG3D experiment
Lifecycle of updrafts and mass flux in isolated deep convection over the Amazon rainforest: insights from cell tracking
Thermodynamic and cloud evolution in a cold-air outbreak during HALO-(AC)3: quasi-Lagrangian observations compared to the ERA5 and CARRA reanalyses
Powering aircraft with 100 % sustainable aviation fuel reduces ice crystals in contrails
Supercooled liquid water clouds observed over Dome C, Antarctica: temperature sensitivity and cloud radiative forcing
Role of thermodynamic and turbulence processes on the fog life cycle during SOFOG3D experiment
Characterizing the near-global cloud vertical structures over land using high-resolution radiosonde measurements
Differences in microphysical properties of cirrus at high and mid-latitudes
Sub-cloud rain evaporation in the North Atlantic winter trade winds derived by pairing isotopic data with a bin-resolved microphysical model
Overview and statistical analysis of boundary layer clouds and precipitation over the western North Atlantic Ocean
A set of methods to evaluate the below-cloud evaporation effect on local precipitation isotopic composition: a case study for Xi'an, China
Earth-system-model evaluation of cloud and precipitation occurrence for supercooled and warm clouds over the Southern Ocean's Macquarie Island
Pollution slightly enhances atmospheric cooling by low-level clouds in tropical West Africa
Investigating an indirect aviation effect on mid-latitude cirrus clouds – linking lidar-derived optical properties to in situ measurements
Investigating the vertical extent and short-wave radiative effects of the ice phase in Arctic summertime low-level clouds
Microphysical and thermodynamic phase analyses of Arctic low-level clouds measured above the sea ice and the open ocean in spring and summer
Aircraft observations of gravity wave activity and turbulence in the tropical tropopause layer: prevalence, influence on cirrus clouds, and comparison with global storm-resolving models
Influence of air mass origin on microphysical properties of low-level clouds in a subarctic environment
Sensitivity of convectively driven tropical tropopause cirrus properties to ice habits in high-resolution simulations
Upper-tropospheric slightly ice-subsaturated regions: frequency of occurrence and statistical evidence for the appearance of contrail cirrus
Examination of aerosol indirect effects during cirrus cloud evolution
In situ microphysics observations of intense pyroconvection from a large wildfire
Conditions favorable for secondary ice production in Arctic mixed-phase clouds
Interaction between cloud–radiation, atmospheric dynamics and thermodynamics based on observational data from GoAmazon 2014/15 and a cloud-resolving model
Snowfall in Northern Finland derives mostly from ice clouds
Observation of secondary ice production in clouds at low temperatures
In situ and satellite-based estimates of cloud properties and aerosol–cloud interactions over the southeast Atlantic Ocean
Ice fog observed at cirrus temperatures at Dome C, Antarctic Plateau
Life cycle of stratocumulus clouds over 1 year at the coast of the Atacama Desert
Quan Liu, Xiaojing Shen, Junying Sun, Yangmei Zhang, Bing Qi, Qianli Ma, Lujie Han, Honghui Xu, Xinyao Hu, Jiayuan Lu, Shuo Liu, Aoyuan Yu, Linlin Liang, Qian Gao, Hong Wang, Huizheng Che, and Xiaoye Zhang
Atmos. Chem. Phys., 25, 3253–3267, https://doi.org/10.5194/acp-25-3253-2025, https://doi.org/10.5194/acp-25-3253-2025, 2025
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Through simultaneous measurements of aerosol particles and fog droplets, the evolution of droplets size distribution during the eight observed fog events was investigated. The results showed that the concentration and size distribution of pre-fog aerosol had significant impacts on fog microphysical characteristics. The extinction of fog interstitial particles played an important role in visibility degradation for light fogs, especially in polluted regions.
Luke R. Allen, Sandra E. Yuter, Matthew A. Miller, and Laura M. Tomkins
Atmos. Chem. Phys., 25, 1765–1790, https://doi.org/10.5194/acp-25-1765-2025, https://doi.org/10.5194/acp-25-1765-2025, 2025
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Atmospheric gravity waves (GWs) are air oscillations in which buoyancy is the restoring force, and they may enhance precipitation under certain conditions. We used 3+ seasons of pressure data to identify GWs with wavelengths ≤ 170 km in the Toronto and New York metropolitan areas in the context of snow storms. We found only six GW events during snow storms, suggesting that GWs on those scales are uncommon at the two locations during snow storms and, thus, do not often enhance snowfall.
Ye Kuang, Jiangchuan Tao, Hanbing Xu, Li Liu, Pengfei Liu, Wanyun Xu, Weiqi Xu, Yele Sun, and Chunsheng Zhao
Atmos. Chem. Phys., 25, 1163–1174, https://doi.org/10.5194/acp-25-1163-2025, https://doi.org/10.5194/acp-25-1163-2025, 2025
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This study presents a novel optical framework to measure supersaturation, a fundamental parameter in cloud physics, by observing the scattering properties of particles that have or have not grown into cloud droplets. The technique offers high-resolution measurements, capturing essential fluctuations in supersaturation necessary for understanding cloud physics.
Amit Kumar Pandit, Jean-Paul Vernier, Thomas Duncan Fairlie, Kristopher M. Bedka, Melody A. Avery, Harish Gadhavi, Madineni Venkat Ratnam, Sanjeev Dwivedi, Kasimahanthi Amar Jyothi, Frank G. Wienhold, Holger Vömel, Hongyu Liu, Bo Zhang, Buduru Suneel Kumar, Tra Dinh, and Achuthan Jayaraman
Atmos. Chem. Phys., 24, 14209–14238, https://doi.org/10.5194/acp-24-14209-2024, https://doi.org/10.5194/acp-24-14209-2024, 2024
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This study investigates the formation mechanism of a tropopause cirrus cloud layer observed at extremely cold temperatures over Hyderabad in India during the 2017 Asian summer monsoon using balloon-borne sensors. Ice crystals smaller than 50 µm were found in this optically thin cirrus cloud layer. Combined analysis of back trajectories, satellite, and model data revealed that the formation of this layer was influenced by waves and stratospheric hydration induced by typhoon Hato.
Nina Maherndl, Manuel Moser, Imke Schirmacher, Aaron Bansemer, Johannes Lucke, Christiane Voigt, and Maximilian Maahn
Atmos. Chem. Phys., 24, 13935–13960, https://doi.org/10.5194/acp-24-13935-2024, https://doi.org/10.5194/acp-24-13935-2024, 2024
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It is not clear why ice crystals in clouds occur in clusters. Here, airborne measurements of clouds in mid-latitudes and high latitudes are used to study the spatial variability of ice. Further, we investigate the influence of riming, which occurs when liquid droplets freeze onto ice crystals. We find that riming enhances the occurrence of ice clusters. In the Arctic, riming leads to ice clustering at spatial scales of 3–5 km. This is due to updrafts and not higher amounts of liquid water.
Luke R. Allen, Sandra E. Yuter, Declan M. Crowe, Matthew A. Miller, and K. Lee Thornhill
EGUsphere, https://doi.org/10.5194/egusphere-2024-3808, https://doi.org/10.5194/egusphere-2024-3808, 2024
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We analyzed in-cloud characteristics using in situ measurements from 42 research flights across two field campaigns into non-orographic, non-lake effect winter storms. Much of the storm volume contains weak vertical motions (a few cm s-1), and most updrafts ≥ 0.5 m s-1 are small (< 1 km). Within 2 km of cloud radar echo top, stronger vertical motions and conditions for ice particle growth are more common. This implies the importance of cloud-top generating cells for production of snow particles.
Yuanmou Du, Dantong Liu, Delong Zhao, Mengyu Huang, Ping Tian, Dian Wen, Wei Xiao, Wei Zhou, Hui He, Baiwan Pan, Dongfei Zuo, Xiange Liu, Yingying Jing, Rong Zhang, Jiujiang Sheng, Fei Wang, Yu Huang, Yunbo Chen, and Deping Ding
Atmos. Chem. Phys., 24, 13429–13444, https://doi.org/10.5194/acp-24-13429-2024, https://doi.org/10.5194/acp-24-13429-2024, 2024
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By conducting in situ measurements, we investigated ice production processes in stratiform clouds with embedded convection over the North China Plain. The results show that the ice number concentration is strongly related to the distance to the cloud top, and the level with a larger distance to the cloud top has more graupel falling from upper levels, which promotes collision and coalescence between graupel and droplets and enhances secondary ice production.
Florian Tornow, Ann Fridlind, George Tselioudis, Brian Cairns, Andrew Ackerman, Seethala Chellappan, David Painemal, Paquita Zuidema, Christiane Voigt, Simon Kirschler, and Armin Sorooshian
EGUsphere, https://doi.org/10.5194/egusphere-2024-3462, https://doi.org/10.5194/egusphere-2024-3462, 2024
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The recent NASA campaign ACTIVATE (Aerosol Cloud meTeorology Interactions oVer the western ATlantic Experiment) performed 71 tandem flights in mid-latitude marine cold-air outbreaks off the US Eastern seaboard. We provide meteorological and cloud transition stage context, allowing us to identify days that are most suitable for Lagrangian modeling and analysis. Surveyed cloud properties show signatures of cloud microphysical processes, such as cloud-top entrainment and secondary ice formation.
Imke Schirmacher, Sabrina Schnitt, Marcus Klingebiel, Nina Maherndl, Benjamin Kirbus, André Ehrlich, Mario Mech, and Susanne Crewell
Atmos. Chem. Phys., 24, 12823–12842, https://doi.org/10.5194/acp-24-12823-2024, https://doi.org/10.5194/acp-24-12823-2024, 2024
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During Arctic marine cold-air outbreaks, cold air flows from sea ice over open water. Roll circulations evolve, forming cloud streets. We investigate the initial circulation and cloud development using high-resolution airborne measurements. We compute the distance an air mass traveled over water (fetch) from back trajectories. Cloud streets form at 15 km fetch, cloud cover strongly increases at around 20 km, and precipitation forms at around 30 km.
Shawn Wendell Wagner, Martin Schnaiter, Guanglang Xu, Franziska Nehlert, and Emma Järvinen
EGUsphere, https://doi.org/10.5194/egusphere-2024-3316, https://doi.org/10.5194/egusphere-2024-3316, 2024
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Understanding the interaction between cirrus clouds and solar radiation is critical for modeling the Earth’s climate. A common crystal type found in cirrus clouds is the bullet rosette. Here, atmospheric bullet rosettes measured from jet aircraft are analyzed for their morphological and radiative properties. Atmospheric bullet rosettes are found to be more morphologically complex than previously assumed. This complexity has a significant impact on their radiative properties.
Anna J. Miller, Christopher Fuchs, Fabiola Ramelli, Huiying Zhang, Nadja Omanovic, Robert Spirig, Claudia Marcolli, Zamin A. Kanji, Ulrike Lohmann, and Jan Henneberger
EGUsphere, https://doi.org/10.5194/egusphere-2024-3230, https://doi.org/10.5194/egusphere-2024-3230, 2024
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We analyzed the ability of silver iodide particles to form ice crystals in naturally-occurring liquid clouds below 0 °C and found that ≈0.1−1 % of particles nucleate ice, with a negative dependence on temperature. Contextualizing our results with previous laboratory studies, we help to bridge the gap between laboratory and field experiments and which also helps to inform future cloud seeding projects.
Wei-Yu Chang, Yung-Chuan Yang, Chen-Yu Hung, Kwonil Kim, Gyuwon Lee, and Ali Tokay
Atmos. Chem. Phys., 24, 11955–11979, https://doi.org/10.5194/acp-24-11955-2024, https://doi.org/10.5194/acp-24-11955-2024, 2024
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Snow density is derived by collocated Micro-Rain Radar (MRR) and Parsivel (ICE-POP 2017/2018). We apply the particle size distribution from Parsivel to a T-matrix backscattering simulation and compare with ZHH from MRR. Bulk density and bulk water fractions are derived from comparing simulated and calculated ZHH. Retrieved bulk density is validated by comparing snowfall rate measurements from Pluvio and the Precipitation Imaging Package. Snowfall rate consistency confirms the algorithm.
Chuanhong Zhao, Yijun Zhang, Dong Zheng, Haoran Li, Sai Du, Xueyan Peng, Xiantong Liu, Pengguo Zhao, Jiafeng Zheng, and Juan Shi
Atmos. Chem. Phys., 24, 11637–11651, https://doi.org/10.5194/acp-24-11637-2024, https://doi.org/10.5194/acp-24-11637-2024, 2024
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Understanding lightning activity is important for meteorology and atmospheric chemistry. However, the occurrence of lightning activity in clouds is uncertain. In this study, we quantified the difference between isolated thunderstorms and non-thunderstorms. We showed that lightning activity was more likely to occur with more graupel volume and/or riming. A deeper ZDR column was associated with lightning occurrence. This information can aid in a deeper understanding of lighting physics.
Xiaojian Zheng, Xiquan Dong, Baike Xi, Timothy Logan, and Yuan Wang
Atmos. Chem. Phys., 24, 10323–10347, https://doi.org/10.5194/acp-24-10323-2024, https://doi.org/10.5194/acp-24-10323-2024, 2024
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The marine boundary layer aerosol–cloud interactions (ACIs) are examined using in situ measurements from two aircraft campaigns over the eastern North Atlantic (ACE-ENA) and Southern Ocean (SOCRATES). The SOCRATES clouds have more and smaller cloud droplets. The ACE-ENA clouds exhibit stronger drizzle formation and growth. Results found distinctive aerosol–cloud interactions for two campaigns. The drizzle processes significantly alter sub-cloud aerosol budgets and impact the ACI assessments.
Derek Ngo, Minghui Diao, Ryan J. Patnaude, Sarah Woods, and Glenn Diskin
EGUsphere, https://doi.org/10.5194/egusphere-2024-2122, https://doi.org/10.5194/egusphere-2024-2122, 2024
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Key controlling factors of cirrus clouds were individually quantified using machine learning models, based on global-scale in-situ observations compiled from 12 flight campaigns at 67° S – 87° N. Relative humidity shows much larger effects on cirrus occurrences than vertical velocity. Aerosol indirect effects are seen from both large and small aerosols, which affect predictions of cirrus occurrences. Large aerosols significantly improve predictions of ice water content but not small aerosols.
Romanos Foskinis, Ghislain Motos, Maria I. Gini, Olga Zografou, Kunfeng Gao, Stergios Vratolis, Konstantinos Granakis, Ville Vakkari, Kalliopi Violaki, Andreas Aktypis, Christos Kaltsonoudis, Zongbo Shi, Mika Komppula, Spyros N. Pandis, Konstantinos Eleftheriadis, Alexandros Papayannis, and Athanasios Nenes
Atmos. Chem. Phys., 24, 9827–9842, https://doi.org/10.5194/acp-24-9827-2024, https://doi.org/10.5194/acp-24-9827-2024, 2024
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Analysis of modeling, in situ, and remote sensing measurements reveals the microphysical state of orographic clouds and their response to aerosol from the boundary layer and free troposphere. We show that cloud response to aerosol is robust, as predicted supersaturation and cloud droplet number levels agree with those determined from in-cloud measurements. The ability to determine if clouds are velocity- or aerosol-limited allows for novel model constraints and remote sensing products.
Henning Dorff, Heike Konow, Vera Schemann, and Felix Ament
Atmos. Chem. Phys., 24, 8771–8795, https://doi.org/10.5194/acp-24-8771-2024, https://doi.org/10.5194/acp-24-8771-2024, 2024
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Using synthetic dropsondes, we assess how discrete spatial sampling and temporal evolution during flight affect the accuracy of real sonde-based moisture transport divergence in Arctic atmospheric rivers (ARs). Non-instantaneous sampling during temporal AR evolution deteriorates the divergence values more than spatial undersampling. Moisture advection is the dominating factor but most sensitive to the sampling method. We suggest a minimum of seven sondes to resolve the AR divergence components.
Deli Meng, Jianping Guo, Xiaoran Guo, Yinjun Wang, Ning Li, Yuping Sun, Zhen Zhang, Na Tang, Haoran Li, Fan Zhang, Bing Tong, Hui Xu, and Tianmeng Chen
Atmos. Chem. Phys., 24, 8703–8720, https://doi.org/10.5194/acp-24-8703-2024, https://doi.org/10.5194/acp-24-8703-2024, 2024
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The turbulence in the planetary boundary layer (PBL) over the Tibetan Plateau (TP) remains unclear. Here we elucidate the vertical profile of and temporal variation in the turbulence dissipation rate in the PBL over the TP based on a radar wind profiler (RWP) network. To the best of our knowledge, this is the first time that the turbulence profile over the whole TP has been revealed. Furthermore, the possible mechanisms of clouds acting on the PBL turbulence structure are investigated.
Leandro Alex Moreira Viscardi, Giuseppe Torri, David K. Adams, and Henrique de Melo Jorge Barbosa
Atmos. Chem. Phys., 24, 8529–8548, https://doi.org/10.5194/acp-24-8529-2024, https://doi.org/10.5194/acp-24-8529-2024, 2024
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We evaluate the environmental conditions that control how clouds grow from fair weather cumulus into severe thunderstorms during the Amazonian wet season. Days with rain clouds begin with more moisture in the air and have strong convergence in the afternoon, while precipitation intensity increases with large-scale vertical velocity, moisture, and low-level wind. These results contribute to understanding how clouds form over the rainforest.
Vinicius dos Santos, Didier Gastmans, Ana María Durán-Quesada, Ricardo Sánchez-Murillo, Kazimierz Rozanski, Oliver Kracht, and Demilson de Assis Quintão
Atmos. Chem. Phys., 24, 6663–6680, https://doi.org/10.5194/acp-24-6663-2024, https://doi.org/10.5194/acp-24-6663-2024, 2024
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We present novel findings on convective rainfall, summer rain in the late afternoon, by coupling water stable isotopes, micro rain radar, and satellite data. We found the tallest clouds in the afternoon and much smaller clouds at night, resulting in differences in day–night ratios in water stable isotopes. We sampled rain and meteorological variables every 5–10 min, allowing us to evaluate the development of convective rainfall, contributing to knowledge of rainfall related to extreme events.
Ewan Crosbie, Luke D. Ziemba, Michael A. Shook, Taylor Shingler, Johnathan W. Hair, Armin Sorooshian, Richard A. Ferrare, Brian Cairns, Yonghoon Choi, Joshua DiGangi, Glenn S. Diskin, Chris Hostetler, Simon Kirschler, Richard H. Moore, David Painemal, Claire Robinson, Shane T. Seaman, K. Lee Thornhill, Christiane Voigt, and Edward Winstead
Atmos. Chem. Phys., 24, 6123–6152, https://doi.org/10.5194/acp-24-6123-2024, https://doi.org/10.5194/acp-24-6123-2024, 2024
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Marine clouds are found to clump together in regions or lines, readily discernible from satellite images of the ocean. While clustering is also a feature of deep storm clouds, we focus on smaller cloud systems associated with fair weather and brief localized showers. Two aircraft sampled the region around these shallow systems: one incorporated measurements taken within, adjacent to, and below the clouds, while the other provided a survey from above using remote sensing techniques.
Théophane Costabloz, Frédéric Burnet, Christine Lac, Pauline Martinet, Julien Delanoë, Susana Jorquera, and Maroua Fathalli
EGUsphere, https://doi.org/10.5194/egusphere-2024-1344, https://doi.org/10.5194/egusphere-2024-1344, 2024
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This study documents vertical profiles of liquid water content (LWC) in fogs from in situ measurements collected during the SOFOG3D field campaign in 2019–2020. The analysis of 140 vertical profiles reveals a reverse trend in LWC, maximum values at ground decreasing with height, during stable conditions in optically thin fogs, evolving towards quasi-adiabatic characteristics when fogs become thick. These results offer new perspectives for better constraining fog numerical simulations.
Siddhant Gupta, Dié Wang, Scott E. Giangrande, Thiago S. Biscaro, and Michael P. Jensen
Atmos. Chem. Phys., 24, 4487–4510, https://doi.org/10.5194/acp-24-4487-2024, https://doi.org/10.5194/acp-24-4487-2024, 2024
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We examine the lifecycle of isolated deep convective clouds (DCCs) in the Amazon rainforest. Weather radar echoes from the DCCs are tracked to evaluate their lifecycle. The DCC size and intensity increase, reach a peak, and then decrease over the DCC lifetime. Vertical profiles of air motion and mass transport from different seasons are examined to understand the transport of energy and momentum within DCC cores and to address the deficiencies in simulating DCCs using weather and climate models.
Benjamin Kirbus, Imke Schirmacher, Marcus Klingebiel, Michael Schäfer, André Ehrlich, Nils Slättberg, Johannes Lucke, Manuel Moser, Hanno Müller, and Manfred Wendisch
Atmos. Chem. Phys., 24, 3883–3904, https://doi.org/10.5194/acp-24-3883-2024, https://doi.org/10.5194/acp-24-3883-2024, 2024
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A research aircraft is used to track the changes in air temperature, moisture, and cloud properties for air that moves from cold Arctic sea ice onto warmer oceanic waters. The measurements are compared to two reanalysis models named ERA5 and CARRA. The biggest differences are found for air temperature over the sea ice and moisture over the ocean. CARRA data are more accurate than ERA5 because they better simulate the sea ice, the transition from sea ice to open ocean, and the forming clouds.
Raphael Satoru Märkl, Christiane Voigt, Daniel Sauer, Rebecca Katharina Dischl, Stefan Kaufmann, Theresa Harlaß, Valerian Hahn, Anke Roiger, Cornelius Weiß-Rehm, Ulrike Burkhardt, Ulrich Schumann, Andreas Marsing, Monika Scheibe, Andreas Dörnbrack, Charles Renard, Maxime Gauthier, Peter Swann, Paul Madden, Darren Luff, Reetu Sallinen, Tobias Schripp, and Patrick Le Clercq
Atmos. Chem. Phys., 24, 3813–3837, https://doi.org/10.5194/acp-24-3813-2024, https://doi.org/10.5194/acp-24-3813-2024, 2024
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In situ measurements of contrails from a large passenger aircraft burning 100 % sustainable aviation fuel (SAF) show a 56 % reduction in contrail ice crystal numbers compared to conventional Jet A-1. Results from a climate model initialized with the observations suggest a significant decrease in radiative forcing from contrails. Our study confirms that future increased use of low aromatic SAF can reduce the climate impact from aviation.
Philippe Ricaud, Massimo Del Guasta, Angelo Lupi, Romain Roehrig, Eric Bazile, Pierre Durand, Jean-Luc Attié, Alessia Nicosia, and Paolo Grigioni
Atmos. Chem. Phys., 24, 613–630, https://doi.org/10.5194/acp-24-613-2024, https://doi.org/10.5194/acp-24-613-2024, 2024
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Clouds affect the Earth's climate in ways that depend on the type of cloud (solid/liquid water). From observations at Concordia (Antarctica), we show that in supercooled liquid water (liquid water for temperatures below 0°C) clouds (SLWCs), temperature and SLWC radiative forcing increase with liquid water (up to 70 W m−2). We extrapolated that the maximum SLWC radiative forcing can reach 40 W m−2 over the Antarctic Peninsula, highlighting the importance of SLWCs for global climate prediction.
Cheikh Dione, Martial Haeffelin, Frédéric Burnet, Christine Lac, Guylaine Canut, Julien Delanoë, Jean-Charles Dupont, Susana Jorquera, Pauline Martinet, Jean-François Ribaud, and Felipe Toledo
Atmos. Chem. Phys., 23, 15711–15731, https://doi.org/10.5194/acp-23-15711-2023, https://doi.org/10.5194/acp-23-15711-2023, 2023
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This paper documents the role of thermodynamics and turbulence in the fog life cycle over southwestern France. It is based on a unique dataset collected during the SOFOG3D field campaign in autumn and winter 2019–2020. The paper gives a threshold for turbulence driving the different phases of the fog life cycle and the role of advection in the night-time dissipation of fog. The results can be operationalised to nowcast fog and improve short-range forecasts in numerical weather prediction models.
Hui Xu, Jianping Guo, Bing Tong, Jinqiang Zhang, Tianmeng Chen, Xiaoran Guo, Jian Zhang, and Wenqing Chen
Atmos. Chem. Phys., 23, 15011–15038, https://doi.org/10.5194/acp-23-15011-2023, https://doi.org/10.5194/acp-23-15011-2023, 2023
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The radiative effect of cloud remains one of the largest uncertain factors in climate change, largely due to the lack of cloud vertical structure (CVS) observations. The study presents the first near-global CVS climatology using high-vertical-resolution soundings. Single-layer cloud mainly occurs over arid regions. As the number of cloud layers increases, clouds tend to have lower bases and thinner layer thicknesses. The occurrence frequency of cloud exhibits a pronounced seasonal diurnal cycle.
Elena De La Torre Castro, Tina Jurkat-Witschas, Armin Afchine, Volker Grewe, Valerian Hahn, Simon Kirschler, Martina Krämer, Johannes Lucke, Nicole Spelten, Heini Wernli, Martin Zöger, and Christiane Voigt
Atmos. Chem. Phys., 23, 13167–13189, https://doi.org/10.5194/acp-23-13167-2023, https://doi.org/10.5194/acp-23-13167-2023, 2023
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In this study, we show the differences in the microphysical properties between high-latitude (HL) cirrus and mid-latitude (ML) cirrus over the Arctic, North Atlantic, and central Europe during summer. The in situ measurements are combined with backward trajectories to investigate the influence of the region on cloud formation. We show that HL cirrus are characterized by a lower concentration of larger ice crystals when compared to ML cirrus.
Mampi Sarkar, Adriana Bailey, Peter Blossey, Simon P. de Szoeke, David Noone, Estefanía Quiñones Meléndez, Mason D. Leandro, and Patrick Y. Chuang
Atmos. Chem. Phys., 23, 12671–12690, https://doi.org/10.5194/acp-23-12671-2023, https://doi.org/10.5194/acp-23-12671-2023, 2023
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We study rain evaporation characteristics below shallow cumulus clouds over the North Atlantic Ocean by pairing isotope observations with a microphysical model. The modeled fraction of rain mass that evaporates below the cloud strongly depends on the raindrop size and distribution width. Moreover, the higher the rain mass fraction evaporated, the greater the change in deuterium excess. In this way, rain evaporation could be studied independently using only isotope and microphysical observations.
Simon Kirschler, Christiane Voigt, Bruce E. Anderson, Gao Chen, Ewan C. Crosbie, Richard A. Ferrare, Valerian Hahn, Johnathan W. Hair, Stefan Kaufmann, Richard H. Moore, David Painemal, Claire E. Robinson, Kevin J. Sanchez, Amy J. Scarino, Taylor J. Shingler, Michael A. Shook, Kenneth L. Thornhill, Edward L. Winstead, Luke D. Ziemba, and Armin Sorooshian
Atmos. Chem. Phys., 23, 10731–10750, https://doi.org/10.5194/acp-23-10731-2023, https://doi.org/10.5194/acp-23-10731-2023, 2023
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In this study we present an overview of liquid and mixed-phase clouds and precipitation in the marine boundary layer over the western North Atlantic Ocean. We compare microphysical properties of pure liquid clouds to mixed-phase clouds and show that the initiation of the ice phase in mixed-phase clouds promotes precipitation. The observational data presented in this study are well suited for investigating the processes that give rise to liquid and mixed-phase clouds, ice, and precipitation.
Meng Xing, Weiguo Liu, Jing Hu, and Zheng Wang
Atmos. Chem. Phys., 23, 9123–9136, https://doi.org/10.5194/acp-23-9123-2023, https://doi.org/10.5194/acp-23-9123-2023, 2023
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The below-cloud evaporation effect (BCE) on precipitation largely impacts the final isotopic composition. However, determining the BCE effect remains poorly constrained. Our work used a ΔdΔδ diagram to differentiate the below-cloud processes. Moreover, by comparing two different computing methods, we considered that both methods are suitable for evaluation the BCE, except for snowfall events. Overall, our work compiled a set of effective methods to evaluate the BCE effect.
McKenna W. Stanford, Ann M. Fridlind, Israel Silber, Andrew S. Ackerman, Greg Cesana, Johannes Mülmenstädt, Alain Protat, Simon Alexander, and Adrian McDonald
Atmos. Chem. Phys., 23, 9037–9069, https://doi.org/10.5194/acp-23-9037-2023, https://doi.org/10.5194/acp-23-9037-2023, 2023
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Clouds play an important role in the Earth’s climate system as they modulate the amount of radiation that either reaches the surface or is reflected back to space. This study demonstrates an approach to robustly evaluate surface-based observations against a large-scale model. We find that the large-scale model precipitates too infrequently relative to observations, contrary to literature documentation suggesting otherwise based on satellite measurements.
Valerian Hahn, Ralf Meerkötter, Christiane Voigt, Sonja Gisinger, Daniel Sauer, Valéry Catoire, Volker Dreiling, Hugh Coe, Cyrille Flamant, Stefan Kaufmann, Jonas Kleine, Peter Knippertz, Manuel Moser, Philip Rosenberg, Hans Schlager, Alfons Schwarzenboeck, and Jonathan Taylor
Atmos. Chem. Phys., 23, 8515–8530, https://doi.org/10.5194/acp-23-8515-2023, https://doi.org/10.5194/acp-23-8515-2023, 2023
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During the DACCIWA campaign in West Africa, we found a 35 % increase in the cloud droplet concentration that formed in a polluted compared with a less polluted environment and a decrease of 17 % in effective droplet diameter. Radiative transfer simulations, based on the measured cloud properties, reveal that these low-level polluted clouds radiate only 2.6 % more energy back to space, compared with a less polluted cloud. The corresponding additional decrease in temperature is rather small.
Silke Groß, Tina Jurkat-Witschas, Qiang Li, Martin Wirth, Benedikt Urbanek, Martina Krämer, Ralf Weigel, and Christiane Voigt
Atmos. Chem. Phys., 23, 8369–8381, https://doi.org/10.5194/acp-23-8369-2023, https://doi.org/10.5194/acp-23-8369-2023, 2023
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Aviation-emitted aerosol can have an impact on cirrus clouds. We present optical and microphysical properties of mid-latitude cirrus clouds which were formed under the influence of aviation-emitted aerosol or which were formed under rather pristine conditions. We find that cirrus clouds affected by aviation-emitted aerosol show larger values of the particle linear depolarization ratio, larger mean effective ice particle diameters and decreased ice particle number concentrations.
Emma Järvinen, Franziska Nehlert, Guanglang Xu, Fritz Waitz, Guillaume Mioche, Regis Dupuy, Olivier Jourdan, and Martin Schnaiter
Atmos. Chem. Phys., 23, 7611–7633, https://doi.org/10.5194/acp-23-7611-2023, https://doi.org/10.5194/acp-23-7611-2023, 2023
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The Arctic is warming faster than other regions. Arctic low-level mixed-phase clouds, where ice crystals and liquid droplets co-exist, are thought to have an important role in Arctic warming. Here we show airborne measurements of vertical distribution of liquid and ice particles and their relative abundance. Ice particles are found in relative warm clouds, which can be explained by multiplication of existing ice crystals. However, the role of ice particles in redistributing sun light is minimal.
Manuel Moser, Christiane Voigt, Tina Jurkat-Witschas, Valerian Hahn, Guillaume Mioche, Olivier Jourdan, Régis Dupuy, Christophe Gourbeyre, Alfons Schwarzenboeck, Johannes Lucke, Yvonne Boose, Mario Mech, Stephan Borrmann, André Ehrlich, Andreas Herber, Christof Lüpkes, and Manfred Wendisch
Atmos. Chem. Phys., 23, 7257–7280, https://doi.org/10.5194/acp-23-7257-2023, https://doi.org/10.5194/acp-23-7257-2023, 2023
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This study provides a comprehensive microphysical and thermodynamic phase analysis of low-level clouds in the northern Fram Strait, above the sea ice and the open ocean, during spring and summer. Using airborne in situ cloud data, we show that the properties of Arctic low-level clouds vary significantly with seasonal meteorological situations and surface conditions. The observations presented in this study can help one to assess the role of clouds in the Arctic climate system.
Rachel Atlas and Christopher S. Bretherton
Atmos. Chem. Phys., 23, 4009–4030, https://doi.org/10.5194/acp-23-4009-2023, https://doi.org/10.5194/acp-23-4009-2023, 2023
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The tropical tropopause layer exists between the troposphere and the stratosphere in the tropics. Very thin cirrus clouds cool Earth's surface by scrubbing water vapor (a greenhouse gas) out of air parcels as they ascend through the tropical tropopause layer on their way to the stratosphere. We show observational evidence from aircraft that small-scale (< 100 km) gravity waves and turbulence increase the amount of ice in these clouds and may allow them to remove more water vapor from the air.
Konstantinos Matthaios Doulgeris, Ville Vakkari, Ewan J. O'Connor, Veli-Matti Kerminen, Heikki Lihavainen, and David Brus
Atmos. Chem. Phys., 23, 2483–2498, https://doi.org/10.5194/acp-23-2483-2023, https://doi.org/10.5194/acp-23-2483-2023, 2023
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We investigated how different long-range-transported air masses can affect the microphysical properties of low-level clouds in a clean subarctic environment. A connection was revealed. Higher values of cloud droplet number concentrations were related to continental air masses, whereas the lowest values of number concentrations were related to marine air masses. These were characterized by larger cloud droplets. Clouds in all regions were sensitive to increases in cloud number concentration.
Fayçal Lamraoui, Martina Krämer, Armin Afchine, Adam B. Sokol, Sergey Khaykin, Apoorva Pandey, and Zhiming Kuang
Atmos. Chem. Phys., 23, 2393–2419, https://doi.org/10.5194/acp-23-2393-2023, https://doi.org/10.5194/acp-23-2393-2023, 2023
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Cirrus in the tropical tropopause layer (TTL) can play a key role in vertical transport. We investigate the role of different cloud regimes and the associated ice habits in regulating the properties of the TTL. We use high-resolution numerical experiments at the scales of large-eddy simulations (LESs) and aircraft measurements. We found that LES-scale parameterizations that predict ice shape are crucial for an accurate representation of TTL cirrus and thus the associated (de)hydration process.
Yun Li, Christoph Mahnke, Susanne Rohs, Ulrich Bundke, Nicole Spelten, Georgios Dekoutsidis, Silke Groß, Christiane Voigt, Ulrich Schumann, Andreas Petzold, and Martina Krämer
Atmos. Chem. Phys., 23, 2251–2271, https://doi.org/10.5194/acp-23-2251-2023, https://doi.org/10.5194/acp-23-2251-2023, 2023
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The radiative effect of aviation-induced cirrus is closely related to ambient conditions and its microphysical properties. Our study investigated the occurrence of contrail and natural cirrus measured above central Europe in spring 2014. It finds that contrail cirrus appears frequently in the pressure range 200 to 245 hPa and occurs more often in slightly ice-subsaturated environments than expected. Avoiding slightly ice-subsaturated regions by aviation might help mitigate contrail cirrus.
Flor Vanessa Maciel, Minghui Diao, and Ryan Patnaude
Atmos. Chem. Phys., 23, 1103–1129, https://doi.org/10.5194/acp-23-1103-2023, https://doi.org/10.5194/acp-23-1103-2023, 2023
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Aerosol indirect effects on cirrus clouds are investigated during cirrus evolution, using global-scale in situ observations and climate model simulations. As cirrus evolves, the mechanisms to form ice crystals also change with time. Both small and large aerosols are found to affect cirrus properties. Southern Hemisphere cirrus appears to be more sensitive to additional aerosols. The climate model underestimates ice crystal mass, likely due to biases of relative humidity and vertical velocity.
David E. Kingsmill, Jeffrey R. French, and Neil P. Lareau
Atmos. Chem. Phys., 23, 1–21, https://doi.org/10.5194/acp-23-1-2023, https://doi.org/10.5194/acp-23-1-2023, 2023
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This study uses in situ aircraft measurements to characterize the size and shape distributions of 10 µm to 6 mm diameter particles observed during six penetrations of wildfire-induced pyroconvection. Particles sampled in one penetration of a smoke plume are most likely pyrometeors composed of ash. The other penetrations are through pyrocumulus clouds where particle composition is most likely a combination of hydrometeors (ice particles) and pyrometeors (ash).
Julie Thérèse Pasquier, Jan Henneberger, Fabiola Ramelli, Annika Lauber, Robert Oscar David, Jörg Wieder, Tim Carlsen, Rosa Gierens, Marion Maturilli, and Ulrike Lohmann
Atmos. Chem. Phys., 22, 15579–15601, https://doi.org/10.5194/acp-22-15579-2022, https://doi.org/10.5194/acp-22-15579-2022, 2022
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It is important to understand how ice crystals and cloud droplets form in clouds, as their concentrations and sizes determine the exact radiative properties of the clouds. Normally, ice crystals form from aerosols, but we found evidence for the formation of additional ice crystals from the original ones over a large temperature range within Arctic clouds. In particular, additional ice crystals were formed during collisions of several ice crystals or during the freezing of large cloud droplets.
Layrson J. M. Gonçalves, Simone M. S. C. Coelho, Paulo Y. Kubota, and Dayana C. Souza
Atmos. Chem. Phys., 22, 15509–15526, https://doi.org/10.5194/acp-22-15509-2022, https://doi.org/10.5194/acp-22-15509-2022, 2022
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This research aims to study the environmental conditions that are favorable and not favorable to cloud formation, in this case specifically for the Amazon region. The results found in this research will be used to improve the representation of clouds in numerical models that are used in weather and climate prediction. In general, it is expected that with better knowledge regarding the cloud–radiation interaction, it is possible to make a better forecast of weather and climate.
Claudia Mignani, Lukas Zimmermann, Rigel Kivi, Alexis Berne, and Franz Conen
Atmos. Chem. Phys., 22, 13551–13568, https://doi.org/10.5194/acp-22-13551-2022, https://doi.org/10.5194/acp-22-13551-2022, 2022
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We determined over the course of 8 winter months the phase of clouds associated with snowfall in Northern Finland using radiosondes and observations of ice particle habits at ground level. We found that precipitating clouds were extending from near ground to at least 2.7 km altitude and approximately three-quarters of them were likely glaciated. Possible moisture sources and ice formation processes are discussed.
Alexei Korolev, Paul J. DeMott, Ivan Heckman, Mengistu Wolde, Earle Williams, David J. Smalley, and Michael F. Donovan
Atmos. Chem. Phys., 22, 13103–13113, https://doi.org/10.5194/acp-22-13103-2022, https://doi.org/10.5194/acp-22-13103-2022, 2022
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The present study provides the first explicit in situ observation of secondary ice production at temperatures as low as −27 °C, which is well outside the range of the Hallett–Mossop process (−3 to −8 °C). This observation expands our knowledge of the temperature range of initiation of secondary ice in clouds. The obtained results are intended to stimulate laboratory and theoretical studies to develop physically based parameterizations for weather prediction and climate models.
Siddhant Gupta, Greg M. McFarquhar, Joseph R. O'Brien, Michael R. Poellot, David J. Delene, Ian Chang, Lan Gao, Feng Xu, and Jens Redemann
Atmos. Chem. Phys., 22, 12923–12943, https://doi.org/10.5194/acp-22-12923-2022, https://doi.org/10.5194/acp-22-12923-2022, 2022
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The ability of NASA’s Terra and Aqua satellites to retrieve cloud properties and estimate the changes in cloud properties due to aerosol–cloud interactions (ACI) was examined. There was good agreement between satellite retrievals and in situ measurements over the southeast Atlantic Ocean. This suggests that, combined with information on aerosol properties, satellite retrievals of cloud properties can be used to study ACI over larger domains and longer timescales in the absence of in situ data.
Étienne Vignon, Lea Raillard, Christophe Genthon, Massimo Del Guasta, Andrew J. Heymsfield, Jean-Baptiste Madeleine, and Alexis Berne
Atmos. Chem. Phys., 22, 12857–12872, https://doi.org/10.5194/acp-22-12857-2022, https://doi.org/10.5194/acp-22-12857-2022, 2022
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The near-surface atmosphere over the Antarctic Plateau is cold and pristine and resembles to a certain extent the high troposphere where cirrus clouds form. In this study, we use innovative humidity measurements at Concordia Station to study the formation of ice fogs at temperatures <−40°C. We provide observational evidence that ice fogs can form through the homogeneous freezing of solution aerosols, a common nucleation pathway for cirrus clouds.
Jan H. Schween, Camilo del Rio, Juan-Luis García, Pablo Osses, Sarah Westbrook, and Ulrich Löhnert
Atmos. Chem. Phys., 22, 12241–12267, https://doi.org/10.5194/acp-22-12241-2022, https://doi.org/10.5194/acp-22-12241-2022, 2022
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Marine stratocumulus clouds of the eastern Pacific play an essential role in the Earth's climate. These clouds form the major source of water to parts of the extreme dry Atacama Desert at the northern coast of Chile. For the first time these clouds are observed over a whole year with three remote sensing instruments. It is shown how these clouds are influenced by the land–sea wind system and the distribution of ocean temperatures.
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Short summary
The first analysis of 15 years of global-scale water vapour and relative humidity observations by passenger aircraft in the MOZAIC and IAGOS programmes resolves detailed features of water vapour and ice-supersaturated air in the mid-latitude tropopause. Key results provide in-depth insight into seasonal and regional variability and chemical signatures of ice-supersaturated air masses, including trend analyses, and show a close link to cirrus clouds and their highly important effects on climate.
The first analysis of 15 years of global-scale water vapour and relative humidity observations...
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