Articles | Volume 17, issue 24
Atmos. Chem. Phys., 17, 15137–15150, 2017
https://doi.org/10.5194/acp-17-15137-2017
Atmos. Chem. Phys., 17, 15137–15150, 2017
https://doi.org/10.5194/acp-17-15137-2017
Research article
21 Dec 2017
Research article | 21 Dec 2017

Temperature-dependent rate coefficients for the reactions of the hydroxyl radical with the atmospheric biogenics isoprene, alpha-pinene and delta-3-carene

Terry J. Dillon et al.

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Cited articles

Atkinson, R., Aschmann, S. M., and Pitts, J. N.: Rate constants for the gas-phase reactions of the OH-radical with a series of monoterpenes at 298 +∕ −  1 K, Int. J. Chem. Kinet., 18, 287–299, https://doi.org/10.1002/kin.550180303, 1986.
Atkinson, R. and Arey, J.: Gas-phase tropospheric chemistry of biogenic volatile organic compounds: a review, Atmos. Environ., 37, S197–S219, https://doi.org/10.1016/s1352-2310(03)00391-1, 2003.
Atkinson, R., Baulch, D. L., Cox, R. A., Crowley, J. N., Hampson, R. F., Hynes, R. G., Jenkin, M. E., Rossi, M. J., Troe, J., and IUPAC Subcommittee: Evaluated kinetic and photochemical data for atmospheric chemistry: Volume II – gas phase reactions of organic species, Atmos. Chem. Phys., 6, 3625–4055, https://doi.org/10.5194/acp-6-3625-2006, 2006a.
Atkinson, R., Baulch, D. L., Cox, R. A., Crowley, J. N., Hampson, R. F., Hynes, R. G., Jenkin, M. E., Rossi, M. J., Troe, J., and IUPAC Subcommittee: Evaluated kinetic and photochemical data for atmospheric chemistry: Volume II – gas phase reactions of organic species, Atmos. Chem. Phys., 6, 3625–4055, https://doi.org/10.5194/acp-6-3625-2006, 2006b.
Back, J., Hari, P., Hakola, H., Juurola, E., and Kulmala, M.: Dynamics of monoterpene emissions in Pinus sylvestris during early spring, Boreal Environ. Res., 10, 409–424, 2005.
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Short summary
A great quantity and variety of organic compounds is released to the atmosphere annually. These compounds greatly impact air chemistry, quality and climate. Laser-based experiments were used to study the atmospheric breakdown of three organics: isoprene, alpha-pinene, and delta-3-carene. Results provided important missing information for low-temperature atmospheric conditions, resolved discrepancies from previous work, and allowed estimation of lifetimes of a few hours for each compound.
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