Articles | Volume 17, issue 24
https://doi.org/10.5194/acp-17-15137-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-17-15137-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Temperature-dependent rate coefficients for the reactions of the hydroxyl radical with the atmospheric biogenics isoprene, alpha-pinene and delta-3-carene
Department of Air Chemistry, Max Planck Institute for Chemistry,
55128 Mainz, Germany
now at: Wolfson Atmospheric Chemistry
Laboratories, Department of Chemistry, University of York, YO10 5DD, York,
UK
Katrin Dulitz
Department of Air Chemistry, Max Planck Institute for Chemistry,
55128 Mainz, Germany
now at: Physikalisches Institut, University of Freiburg,
Hermann-Herder Str. 3, 79104 Freiburg, Germany
Christoph B. M. Groß
Department of Air Chemistry, Max Planck Institute for Chemistry,
55128 Mainz, Germany
John N. Crowley
Department of Air Chemistry, Max Planck Institute for Chemistry,
55128 Mainz, Germany
Viewed
Total article views: 3,736 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 03 Jul 2017)
| HTML | XML | Total | BibTeX | EndNote | |
|---|---|---|---|---|---|
| 2,209 | 1,381 | 146 | 3,736 | 141 | 185 |
- HTML: 2,209
- PDF: 1,381
- XML: 146
- Total: 3,736
- BibTeX: 141
- EndNote: 185
Total article views: 3,072 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 21 Dec 2017)
| HTML | XML | Total | BibTeX | EndNote | |
|---|---|---|---|---|---|
| 1,859 | 1,078 | 135 | 3,072 | 124 | 167 |
- HTML: 1,859
- PDF: 1,078
- XML: 135
- Total: 3,072
- BibTeX: 124
- EndNote: 167
Total article views: 664 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 03 Jul 2017)
| HTML | XML | Total | BibTeX | EndNote | |
|---|---|---|---|---|---|
| 350 | 303 | 11 | 664 | 17 | 18 |
- HTML: 350
- PDF: 303
- XML: 11
- Total: 664
- BibTeX: 17
- EndNote: 18
Viewed (geographical distribution)
Total article views: 3,736 (including HTML, PDF, and XML)
Thereof 3,720 with geography defined
and 16 with unknown origin.
Total article views: 3,072 (including HTML, PDF, and XML)
Thereof 3,066 with geography defined
and 6 with unknown origin.
Total article views: 664 (including HTML, PDF, and XML)
Thereof 654 with geography defined
and 10 with unknown origin.
| Country | # | Views | % |
|---|
| Country | # | Views | % |
|---|
| Country | # | Views | % |
|---|
| Total: | 0 |
| HTML: | 0 |
| PDF: | 0 |
| XML: | 0 |
- 1
1
| Total: | 0 |
| HTML: | 0 |
| PDF: | 0 |
| XML: | 0 |
- 1
1
| Total: | 0 |
| HTML: | 0 |
| PDF: | 0 |
| XML: | 0 |
- 1
1
Cited
15 citations as recorded by crossref.
- The evolution of carbon oxidation state during secondary organic aerosol formation from individual and mixed organic precursors Y. Shao et al. https://doi.org/10.5194/ar-3-619-2025
- Kinetics of the Reaction of OH with Isoprene over a Wide Range of Temperature and Pressure Including Direct Observation of Equilibrium with the OH Adducts D. Medeiros et al. https://doi.org/10.1021/acs.jpca.8b04829
- Mid-infrared absorption cross sections for two unsaturated hydrocarbons: Allene and isoprene K. Leroux et al. https://doi.org/10.1016/j.jqsrt.2025.109737
- Deep-ultraviolet absorption cross sections of strongly absorbing atmospheric species M. Wang et al. https://doi.org/10.1016/j.jqsrt.2024.109050
- Assessment of Isoprene as a Possible Biosignature Gas in Exoplanets with Anoxic Atmospheres Z. Zhan et al. https://doi.org/10.1089/ast.2019.2146
- Kinetic Investigations of the OH-Initiated Reactions of Methyl Cyclohexene Isomers in the Troposphere: An Experimental and Computational Study G. Madhu & B. Rajakumar https://doi.org/10.1021/acs.jpca.5c03646
- Singlet Oxygen Generation via UV-A, -B, and -C Photoexcitation of Isoprene–Oxygen (C5H8–O2) Encounter Complexes in the Gas Phase A. Pyryaeva et al. https://doi.org/10.1021/acs.jpca.0c07509
- Investigation of the kinetics of conjugated diolefins using UV absorption spectroscopy D. Liu & A. Farooq https://doi.org/10.1016/j.proci.2022.07.071
- Bond lengths and band strengths of non-equivalent C-H bonds of 2-methyl-1,3-butadiene using density functional theory, Fourier transform IR, and cavity ringdown techniques C. Manzanares et al. https://doi.org/10.1016/j.molstruc.2024.139903
- The impact of unimolecular reactions on acyl peroxy radical initiated isoprene oxidation I. Karppinen et al. https://doi.org/10.5194/ar-3-175-2025
- Emerging Nonvalence Anion States of [Isoprene-H·]·H2O Accessed via Detachment of OH–·Isoprene M. Dobulis et al. https://doi.org/10.1021/acs.jpca.0c01250
- Observed versus simulated OH reactivity during KORUS-AQ campaign: Implications for emission inventory and chemical environment in East Asia H. Kim et al. https://doi.org/10.1525/elementa.2022.00030
- Temperature-dependent rate coefficients for the reactions of OH radicals with selected alkanes, aromatic compounds, and monoterpenes F. Berg et al. https://doi.org/10.5194/acp-24-13715-2024
- Atmospheric photooxidation and ozonolysis of Δ3-carene and 3-caronaldehyde: rate constants and product yields L. Hantschke et al. https://doi.org/10.5194/acp-21-12665-2021
- The effect of temperature and relative humidity on secondary organic aerosol formation from ozonolysis of Δ3-carene D. Thomsen et al. https://doi.org/10.1039/D3EA00128H
15 citations as recorded by crossref.
- The evolution of carbon oxidation state during secondary organic aerosol formation from individual and mixed organic precursors Y. Shao et al. https://doi.org/10.5194/ar-3-619-2025
- Kinetics of the Reaction of OH with Isoprene over a Wide Range of Temperature and Pressure Including Direct Observation of Equilibrium with the OH Adducts D. Medeiros et al. https://doi.org/10.1021/acs.jpca.8b04829
- Mid-infrared absorption cross sections for two unsaturated hydrocarbons: Allene and isoprene K. Leroux et al. https://doi.org/10.1016/j.jqsrt.2025.109737
- Deep-ultraviolet absorption cross sections of strongly absorbing atmospheric species M. Wang et al. https://doi.org/10.1016/j.jqsrt.2024.109050
- Assessment of Isoprene as a Possible Biosignature Gas in Exoplanets with Anoxic Atmospheres Z. Zhan et al. https://doi.org/10.1089/ast.2019.2146
- Kinetic Investigations of the OH-Initiated Reactions of Methyl Cyclohexene Isomers in the Troposphere: An Experimental and Computational Study G. Madhu & B. Rajakumar https://doi.org/10.1021/acs.jpca.5c03646
- Singlet Oxygen Generation via UV-A, -B, and -C Photoexcitation of Isoprene–Oxygen (C5H8–O2) Encounter Complexes in the Gas Phase A. Pyryaeva et al. https://doi.org/10.1021/acs.jpca.0c07509
- Investigation of the kinetics of conjugated diolefins using UV absorption spectroscopy D. Liu & A. Farooq https://doi.org/10.1016/j.proci.2022.07.071
- Bond lengths and band strengths of non-equivalent C-H bonds of 2-methyl-1,3-butadiene using density functional theory, Fourier transform IR, and cavity ringdown techniques C. Manzanares et al. https://doi.org/10.1016/j.molstruc.2024.139903
- The impact of unimolecular reactions on acyl peroxy radical initiated isoprene oxidation I. Karppinen et al. https://doi.org/10.5194/ar-3-175-2025
- Emerging Nonvalence Anion States of [Isoprene-H·]·H2O Accessed via Detachment of OH–·Isoprene M. Dobulis et al. https://doi.org/10.1021/acs.jpca.0c01250
- Observed versus simulated OH reactivity during KORUS-AQ campaign: Implications for emission inventory and chemical environment in East Asia H. Kim et al. https://doi.org/10.1525/elementa.2022.00030
- Temperature-dependent rate coefficients for the reactions of OH radicals with selected alkanes, aromatic compounds, and monoterpenes F. Berg et al. https://doi.org/10.5194/acp-24-13715-2024
- Atmospheric photooxidation and ozonolysis of Δ3-carene and 3-caronaldehyde: rate constants and product yields L. Hantschke et al. https://doi.org/10.5194/acp-21-12665-2021
- The effect of temperature and relative humidity on secondary organic aerosol formation from ozonolysis of Δ3-carene D. Thomsen et al. https://doi.org/10.1039/D3EA00128H
Saved (final revised paper)
Latest update: 05 Jun 2026
Short summary
A great quantity and variety of organic compounds is released to the atmosphere annually. These compounds greatly impact air chemistry, quality and climate. Laser-based experiments were used to study the atmospheric breakdown of three organics: isoprene, alpha-pinene, and delta-3-carene. Results provided important missing information for low-temperature atmospheric conditions, resolved discrepancies from previous work, and allowed estimation of lifetimes of a few hours for each compound.
A great quantity and variety of organic compounds is released to the atmosphere annually. These...
Altmetrics
Final-revised paper
Preprint