Articles | Volume 18, issue 1
https://doi.org/10.5194/acp-18-327-2018
https://doi.org/10.5194/acp-18-327-2018
Research article
 | 
11 Jan 2018
Research article |  | 11 Jan 2018

Heterogeneous reaction of HO2 with airborne TiO2 particles and its implication for climate change mitigation strategies

Daniel R. Moon, Giorgio S. Taverna, Clara Anduix-Canto, Trevor Ingham, Martyn P. Chipperfield, Paul W. Seakins, Maria-Teresa Baeza-Romero, and Dwayne E. Heard

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Cited articles

Aloisio, S. and Francisco, J. S.: Existence of a hydroperoxy and water (HO2 center dot H2O) radical complex, J. Phys. Chem. A, 102, 1899–1902, https://doi.org/10.1021/jp972173p, 1998. 
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Short summary
One geoengineering mitigation strategy for global temperature rises is to inject particles into the stratosphere to scatter solar radiation back to space. However, the injection of such particles must not perturb ozone. We measured the rate of uptake of HO2 radicals, an important stratospheric intermediate, onto TiO2 particles. Using the atmospheric model TOMCAT, we showed that surface reactions between HO2 and TiO2 would have a negligible effect on stratospheric concentrations of HO2 and ozone.
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