Articles | Volume 16, issue 7
https://doi.org/10.5194/acp-16-4631-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-16-4631-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
13 Apr 2016
Research article |
| 13 Apr 2016
Hotspot of glyoxal over the Pearl River delta seen from the OMI satellite instrument: implications for emissions of aromatic hydrocarbons
Christopher Chan Miller
CORRESPONDING AUTHOR
Department of Earth and Planetary Science, Harvard University, Cambridge MA, USA
Daniel J. Jacob
Department of Earth and Planetary Science, Harvard University, Cambridge MA, USA
School of Engineering and Applied Sciences, Harvard University, Cambridge MA, USA
Gonzalo González Abad
Harvard-Smithsonian Center for Astrophysics, Cambridge MA, USA
Kelly Chance
Harvard-Smithsonian Center for Astrophysics, Cambridge MA, USA
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Atmos. Meas. Tech., 15, 3721–3745, https://doi.org/10.5194/amt-15-3721-2022, https://doi.org/10.5194/amt-15-3721-2022, 2022
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Christopher Chan Miller, Sébastien Roche, Jonas S. Wilzewski, Xiong Liu, Kelly Chance, Amir H. Souri, Eamon Conway, Bingkun Luo, Jenna Samra, Jacob Hawthorne, Kang Sun, Carly Staebell, Apisada Chulakadabba, Maryann Sargent, Joshua S. Benmergui, Jonathan E. Franklin, Bruce C. Daube, Yang Li, Joshua L. Laughner, Bianca C. Baier, Ritesh Gautam, Mark Omara, and Steven C. Wofsy
Atmos. Meas. Tech., 17, 5429–5454, https://doi.org/10.5194/amt-17-5429-2024, https://doi.org/10.5194/amt-17-5429-2024, 2024
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Yujin J. Oak, Daniel J. Jacob, Nicholas Balasus, Laura H. Yang, Heesung Chong, Junsung Park, Hanlim Lee, Gitaek T. Lee, Eunjo S. Ha, Rokjin J. Park, Hyeong-Ahn Kwon, and Jhoon Kim
Atmos. Meas. Tech., 17, 5147–5159, https://doi.org/10.5194/amt-17-5147-2024, https://doi.org/10.5194/amt-17-5147-2024, 2024
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Haipeng Lin, Louisa K. Emmons, Elizabeth W. Lundgren, Laura Hyesung Yang, Xu Feng, Ruijun Dang, Shixian Zhai, Yunxiao Tang, Makoto M. Kelp, Nadia K. Colombi, Sebastian D. Eastham, Thibaud M. Fritz, and Daniel J. Jacob
Atmos. Chem. Phys., 24, 8607–8624, https://doi.org/10.5194/acp-24-8607-2024, https://doi.org/10.5194/acp-24-8607-2024, 2024
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Elise Penn, Daniel J. Jacob, Zichong Chen, James D. East, Melissa P. Sulprizio, Lori Bruhwiler, Joannes D. Maasakkers, Hannah Nesser, Zhen Qu, Yuzhong Zhang, and John Worden
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The hydroxyl radical (OH), destroys many air pollutants, including methane. Global mean OH cannot be directly measured, so it is inferred with the methyl chloroform (MCF) proxy. MCF is decreasing, and a replacement is needed. We use satellite observations of methane in two spectral ranges as a proxy for OH instead. We find shortwave infrared observations can characterize yearly OH and its seasonality, but not the latitudinal distribution. Thermal infrared observations add little information.
Amir H. Souri, Gonzalo González Abad, Glenn M. Wolfe, Tijl Verhoelst, Corinne Vigouroux, Gaia Pinardi, Steven Compernolle, Bavo Langerock, Bryan N. Duncan, and Matthew S. Johnson
EGUsphere, https://doi.org/10.5194/egusphere-2024-1947, https://doi.org/10.5194/egusphere-2024-1947, 2024
This preprint is open for discussion and under review for Atmospheric Chemistry and Physics (ACP).
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We establish a simple yet robust relationship between ozone production rates and several geophysical parameters obtained from several intensive atmospheric composition campaigns. We have shown that satellite remote sensing data can effectively constrain these parameters, enabling us to produce the first global maps of ozone production rates with unprecedented resolution.
Sarah E. Hancock, Daniel Jacob, Zichong Chen, Hannah Nesser, Aaron Davitt, Daniel J. Varon, Melissa P. Sulprizio, Nicholas Balasus, Lucas A. Estrada, James D. East, Elise Penn, Cynthia A. Randles, John Worden, Ilse Aben, Robert J. Parker, and Joannes D. Maasakkers
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Laura Hyesung Yang, Daniel J. Jacob, Ruijun Dang, Yujin J. Oak, Haipeng Lin, Jhoon Kim, Shixian Zhai, Nadia K. Colombi, Drew C. Pendergrass, Ellie Beaudry, Viral Shah, Xu Feng, Robert M. Yantosca, Heesung Chong, Junsung Park, Hanlim Lee, Won-Jin Lee, Soontae Kim, Eunhye Kim, Katherine R. Travis, James H. Crawford, and Hong Liao
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Tianlang Zhao, Jingqiu Mao, Zolal Ayazpour, Gonzalo González Abad, Caroline R. Nowlan, and Yiqi Zheng
Atmos. Chem. Phys., 24, 6105–6121, https://doi.org/10.5194/acp-24-6105-2024, https://doi.org/10.5194/acp-24-6105-2024, 2024
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Drew C. Pendergrass, Daniel J. Jacob, Yujin J. Oak, Jeewoo Lee, Minseok Kim, Jhoon Kim, Seoyoung Lee, Shixian Zhai, Hitoshi Irie, and Hong Liao
Earth Syst. Sci. Data Discuss., https://doi.org/10.5194/essd-2024-172, https://doi.org/10.5194/essd-2024-172, 2024
Preprint withdrawn
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Fine particles suspended in the atmosphere are a major form of air pollution and an important public health burden. However, measurements of particulate matter are sparse in space and in places like East Asia monitors are established after regulatory policies to improve pollution have changed. In this paper, we use machine learning to fill in the gaps. We train an algorithm to predict pollution at the surface from the atmosphere’s opacity, then produce high resolution maps of data without gaps.
Heesung Chong, Gonzalo González Abad, Caroline R. Nowlan, Christopher Chan Miller, Alfonso Saiz-Lopez, Rafael P. Fernandez, Hyeong-Ahn Kwon, Zolal Ayazpour, Huiqun Wang, Amir H. Souri, Xiong Liu, Kelly Chance, Ewan O'Sullivan, Jhoon Kim, Ja-Ho Koo, William R. Simpson, François Hendrick, Richard Querel, Glen Jaross, Colin Seftor, and Raid M. Suleiman
Atmos. Meas. Tech., 17, 2873–2916, https://doi.org/10.5194/amt-17-2873-2024, https://doi.org/10.5194/amt-17-2873-2024, 2024
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We present a new bromine monoxide (BrO) product derived using radiances measured from OMPS-NM on board the Suomi-NPP satellite. This product provides nearly a decade of global stratospheric and tropospheric column retrievals, a feature that is currently rare in publicly accessible datasets. Both stratospheric and tropospheric columns from OMPS-NM demonstrate robust performance, exhibiting good agreement with ground-based observations collected at three stations (Lauder, Utqiagvik, and Harestua).
Jin Liao, Glenn M. Wolfe, Alex E. Kotsakis, Julie M. Nicely, Jason M. St. Clair, Thomas F. Hanisco, Gonzalo Gonzalez Abad, Caroline R. Nowlan, Zolal Ayazpour, Isabelle De Smedt, Eric C. Apel, and Rebecca S. Hornbrook
Atmos. Meas. Tech. Discuss., https://doi.org/10.5194/amt-2024-72, https://doi.org/10.5194/amt-2024-72, 2024
Revised manuscript accepted for AMT
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Validation of satellite HCHO over the remote marine regions is relatively few and modeled HCHO in these regions is usually added as a global satellite HCHO background. This paper intercompares three satellite HCHO retrievals and validates them against in situ observations from the NASA ATom mission. All retrievals are correlated with ATom integrated columns over remote oceans, with OMI SAO (v004) showing the best agreement. A persistent low bias is found in all retrievals at high latitudes.
Jack H. Bruno, Dylan Jervis, Daniel J. Varon, and Daniel J. Jacob
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Methane is a potent greenhouse gas and a current high-priority target for short- to mid-term climate change mitigation. Detection of individual methane emitters from space has become possible in recent years, and the volume of data for this task has been rapidly growing, outpacing processing capabilities. We introduce an automated approach, U-Plume, which can detect and quantify emissions from individual methane sources in high-spatial-resolution satellite data.
Hannah Nesser, Daniel J. Jacob, Joannes D. Maasakkers, Alba Lorente, Zichong Chen, Xiao Lu, Lu Shen, Zhen Qu, Melissa P. Sulprizio, Margaux Winter, Shuang Ma, A. Anthony Bloom, John R. Worden, Robert N. Stavins, and Cynthia A. Randles
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Juseon Bak, Xiong Liu, Kai Yang, Gonzalo Gonzalez Abad, Ewan O'Sullivan, Kelly Chance, and Cheol-Hee Kim
Atmos. Meas. Tech., 17, 1891–1911, https://doi.org/10.5194/amt-17-1891-2024, https://doi.org/10.5194/amt-17-1891-2024, 2024
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The new version (V2) of the OMI ozone profile product is introduced to improve retrieval quality and long-term consistency of tropospheric ozone by incorporating the recent collection 4 OMI L1b spectral products and refining radiometric correction, forward model calculation, and a priori ozone data.
Sebastian D. Eastham, Guillaume P. Chossière, Raymond L. Speth, Daniel J. Jacob, and Steven R. H. Barrett
Atmos. Chem. Phys., 24, 2687–2703, https://doi.org/10.5194/acp-24-2687-2024, https://doi.org/10.5194/acp-24-2687-2024, 2024
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Emissions from aircraft are known to cause air quality impacts worldwide, but the scale and mechanisms of this impact are not well understood. This work uses high-resolution computational modeling of the atmosphere to show that air pollution changes from aviation are mostly the result of emissions during cruise (high-altitude) operations, that these impacts are related to how much non-aviation pollution is present, and that prior regional assessments have underestimated these impacts.
Eamon K. Conway, Amir H. Souri, Joshua Benmergui, Kang Sun, Xiong Liu, Carly Staebell, Christopher Chan Miller, Jonathan Franklin, Jenna Samra, Jonas Wilzewski, Sebastien Roche, Bingkun Luo, Apisada Chulakadabba, Maryann Sargent, Jacob Hohl, Bruce Daube, Iouli Gordon, Kelly Chance, and Steven Wofsy
Atmos. Meas. Tech., 17, 1347–1362, https://doi.org/10.5194/amt-17-1347-2024, https://doi.org/10.5194/amt-17-1347-2024, 2024
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The work presented here describes the processes required to convert raw sensor data for the MethaneAIR instrument to geometrically calibrated data. Each algorithm is described in detail. MethaneAIR is the airborne simulator for MethaneSAT, a new satellite under development by MethaneSAT LLC, a subsidiary of the EDF. MethaneSAT's goals are to precisely map over 80 % of the production sources of methane emissions from oil and gas fields across the globe to a high degree of accuracy.
Kelvin H. Bates, Mathew J. Evans, Barron H. Henderson, and Daniel J. Jacob
Geosci. Model Dev., 17, 1511–1524, https://doi.org/10.5194/gmd-17-1511-2024, https://doi.org/10.5194/gmd-17-1511-2024, 2024
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Accurate representation of rates and products of chemical reactions in atmospheric models is crucial for simulating concentrations of pollutants and climate forcers. We update the widely used GEOS-Chem atmospheric chemistry model with reaction parameters from recent compilations of experimental data and demonstrate the implications for key atmospheric chemical species. The updates decrease tropospheric CO mixing ratios and increase stratospheric nitrogen oxide mixing ratios, among other changes.
Apisada Chulakadabba, Maryann Sargent, Thomas Lauvaux, Joshua S. Benmergui, Jonathan E. Franklin, Christopher Chan Miller, Jonas S. Wilzewski, Sébastien Roche, Eamon Conway, Amir H. Souri, Kang Sun, Bingkun Luo, Jacob Hawthrone, Jenna Samra, Bruce C. Daube, Xiong Liu, Kelly Chance, Yang Li, Ritesh Gautam, Mark Omara, Jeff S. Rutherford, Evan D. Sherwin, Adam Brandt, and Steven C. Wofsy
Atmos. Meas. Tech., 16, 5771–5785, https://doi.org/10.5194/amt-16-5771-2023, https://doi.org/10.5194/amt-16-5771-2023, 2023
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We show that MethaneAIR, a precursor to the MethaneSAT satellite, demonstrates accurate point source quantification during controlled release experiments and regional observations in 2021 and 2022. Results from our two independent quantification methods suggest the accuracy of our sensor and algorithms is better than 25 % for sources emitting 200 kg h−1 or more. Insights from these measurements help establish the capabilities of MethaneSAT and MethaneAIR.
Mark Omara, Ritesh Gautam, Madeleine A. O'Brien, Anthony Himmelberger, Alex Franco, Kelsey Meisenhelder, Grace Hauser, David R. Lyon, Apisada Chulakadabba, Christopher Chan Miller, Jonathan Franklin, Steven C. Wofsy, and Steven P. Hamburg
Earth Syst. Sci. Data, 15, 3761–3790, https://doi.org/10.5194/essd-15-3761-2023, https://doi.org/10.5194/essd-15-3761-2023, 2023
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We acquire, integrate, and analyze ~ 6 million geospatial oil and gas infrastructure data records based on information available in the public domain and develop an open-access global database including all the major oil and gas facility types that are important sources of methane emissions. This work helps fulfill a crucial geospatial data need, in support of the assessment, attribution, and mitigation of global oil and gas methane emissions at high resolution.
Drew C. Pendergrass, Daniel J. Jacob, Hannah Nesser, Daniel J. Varon, Melissa Sulprizio, Kazuyuki Miyazaki, and Kevin W. Bowman
Geosci. Model Dev., 16, 4793–4810, https://doi.org/10.5194/gmd-16-4793-2023, https://doi.org/10.5194/gmd-16-4793-2023, 2023
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We have built a tool called CHEEREIO that allows scientists to use observations of pollutants or gases in the atmosphere, such as from satellites or surface stations, to update supercomputer models that simulate the Earth. CHEEREIO uses the difference between the model simulations of the atmosphere and real-world observations to come up with a good guess for the actual composition of our atmosphere, the true emissions of various pollutants, and whatever else they may want to study.
Nicholas Balasus, Daniel J. Jacob, Alba Lorente, Joannes D. Maasakkers, Robert J. Parker, Hartmut Boesch, Zichong Chen, Makoto M. Kelp, Hannah Nesser, and Daniel J. Varon
Atmos. Meas. Tech., 16, 3787–3807, https://doi.org/10.5194/amt-16-3787-2023, https://doi.org/10.5194/amt-16-3787-2023, 2023
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We use machine learning to remove biases in TROPOMI satellite observations of atmospheric methane, with GOSAT observations serving as a reference. We find that the TROPOMI biases relative to GOSAT are related to the presence of aerosols and clouds, the surface brightness, and the specific detector that makes the observation aboard TROPOMI. The resulting blended TROPOMI+GOSAT product is more reliable for quantifying methane emissions.
Daniel J. Varon, Daniel J. Jacob, Benjamin Hmiel, Ritesh Gautam, David R. Lyon, Mark Omara, Melissa Sulprizio, Lu Shen, Drew Pendergrass, Hannah Nesser, Zhen Qu, Zachary R. Barkley, Natasha L. Miles, Scott J. Richardson, Kenneth J. Davis, Sudhanshu Pandey, Xiao Lu, Alba Lorente, Tobias Borsdorff, Joannes D. Maasakkers, and Ilse Aben
Atmos. Chem. Phys., 23, 7503–7520, https://doi.org/10.5194/acp-23-7503-2023, https://doi.org/10.5194/acp-23-7503-2023, 2023
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We use TROPOMI satellite observations to quantify weekly methane emissions from the US Permian oil and gas basin from May 2018 to October 2020. We find that Permian emissions are highly variable, with diverse economic and activity drivers. The most important drivers during our study period were new well development and natural gas price. Permian methane intensity averaged 4.6 % and decreased by 1 % per year.
Huiqun Wang, Gonzalo González Abad, Chris Chan Miller, Hyeong-Ahn Kwon, Caroline R. Nowlan, Zolal Ayazpour, Heesung Chong, Xiong Liu, Kelly Chance, Ewan O'Sullivan, Kang Sun, Robert Spurr, and Robert J. Hargreaves
Atmos. Meas. Tech. Discuss., https://doi.org/10.5194/amt-2023-66, https://doi.org/10.5194/amt-2023-66, 2023
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A pipeline for retrieving Total Column Water Vapor from satellite blue spectra is developed. New constraints are considered. Water-leaving radiance is important over the oceans. Results agree with reference datasets well under clear conditions. Due to high sensitivity to clouds, strict data filtering criteria are required. All-sky retrievals can be corrected using machine learning. GPS stations’ representation errors follow a power law relationship with grid resolutions.
Ruijun Dang, Daniel J. Jacob, Viral Shah, Sebastian D. Eastham, Thibaud M. Fritz, Loretta J. Mickley, Tianjia Liu, Yi Wang, and Jun Wang
Atmos. Chem. Phys., 23, 6271–6284, https://doi.org/10.5194/acp-23-6271-2023, https://doi.org/10.5194/acp-23-6271-2023, 2023
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We use the GEOS-Chem model to better understand the magnitude and trend in free tropospheric NO2 over the contiguous US. Model underestimate of background NO2 is largely corrected by considering aerosol nitrate photolysis. Increase in aircraft emissions affects satellite retrievals by altering the NO2 shape factor, and this effect is expected to increase in future. We show the importance of properly accounting for the free tropospheric background in interpreting NO2 observations from space.
Zichong Chen, Daniel J. Jacob, Ritesh Gautam, Mark Omara, Robert N. Stavins, Robert C. Stowe, Hannah Nesser, Melissa P. Sulprizio, Alba Lorente, Daniel J. Varon, Xiao Lu, Lu Shen, Zhen Qu, Drew C. Pendergrass, and Sarah Hancock
Atmos. Chem. Phys., 23, 5945–5967, https://doi.org/10.5194/acp-23-5945-2023, https://doi.org/10.5194/acp-23-5945-2023, 2023
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We quantify methane emissions from individual countries in the Middle East and North Africa by inverse analysis of 2019 TROPOMI satellite observations of atmospheric methane. We show that the ability to simply relate oil/gas emissions to activity metrics is compromised by stochastic nature of local infrastructure and management practices. We find that the industry target for oil/gas methane intensity is achievable through associated gas capture, modern infrastructure, and centralized operations.
Shixian Zhai, Daniel J. Jacob, Drew C. Pendergrass, Nadia K. Colombi, Viral Shah, Laura Hyesung Yang, Qiang Zhang, Shuxiao Wang, Hwajin Kim, Yele Sun, Jin-Soo Choi, Jin-Soo Park, Gan Luo, Fangqun Yu, Jung-Hun Woo, Younha Kim, Jack E. Dibb, Taehyoung Lee, Jin-Seok Han, Bruce E. Anderson, Ke Li, and Hong Liao
Atmos. Chem. Phys., 23, 4271–4281, https://doi.org/10.5194/acp-23-4271-2023, https://doi.org/10.5194/acp-23-4271-2023, 2023
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Anthropogenic fugitive dust in East Asia not only causes severe coarse particulate matter air pollution problems, but also affects fine particulate nitrate. Due to emission control efforts, coarse PM decreased steadily. We find that the decrease of coarse PM is a major driver for a lack of decrease of fine particulate nitrate, as it allows more nitric acid to form fine particulate nitrate. The continuing decrease of coarse PM requires more stringent ammonia and nitrogen oxides emission controls.
Nadia K. Colombi, Daniel J. Jacob, Laura Hyesung Yang, Shixian Zhai, Viral Shah, Stuart K. Grange, Robert M. Yantosca, Soontae Kim, and Hong Liao
Atmos. Chem. Phys., 23, 4031–4044, https://doi.org/10.5194/acp-23-4031-2023, https://doi.org/10.5194/acp-23-4031-2023, 2023
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Surface ozone, detrimental to human and ecosystem health, is very high and increasing in South Korea. Using a global model of the atmosphere, we found that emissions from South Korea and China contribute equally to the high ozone observed. We found that in the absence of all anthropogenic emissions over East Asia, ozone is still very high, implying that the air quality standard in South Korea is not practically achievable unless this background external to East Asia can be decreased.
Laura Hyesung Yang, Daniel J. Jacob, Nadia K. Colombi, Shixian Zhai, Kelvin H. Bates, Viral Shah, Ellie Beaudry, Robert M. Yantosca, Haipeng Lin, Jared F. Brewer, Heesung Chong, Katherine R. Travis, James H. Crawford, Lok N. Lamsal, Ja-Ho Koo, and Jhoon Kim
Atmos. Chem. Phys., 23, 2465–2481, https://doi.org/10.5194/acp-23-2465-2023, https://doi.org/10.5194/acp-23-2465-2023, 2023
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A geostationary satellite can now provide hourly NO2 vertical columns, and obtaining the NO2 vertical columns from space relies on NO2 vertical distribution from the chemical transport model (CTM). In this work, we update the CTM to better represent the chemistry environment so that the CTM can accurately provide NO2 vertical distribution. We also find that the changes in NO2 vertical distribution driven by a change in mixing depth play an important role in the NO2 column's diurnal variation.
Amir H. Souri, Matthew S. Johnson, Glenn M. Wolfe, James H. Crawford, Alan Fried, Armin Wisthaler, William H. Brune, Donald R. Blake, Andrew J. Weinheimer, Tijl Verhoelst, Steven Compernolle, Gaia Pinardi, Corinne Vigouroux, Bavo Langerock, Sungyeon Choi, Lok Lamsal, Lei Zhu, Shuai Sun, Ronald C. Cohen, Kyung-Eun Min, Changmin Cho, Sajeev Philip, Xiong Liu, and Kelly Chance
Atmos. Chem. Phys., 23, 1963–1986, https://doi.org/10.5194/acp-23-1963-2023, https://doi.org/10.5194/acp-23-1963-2023, 2023
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We have rigorously characterized different sources of error in satellite-based HCHO / NO2 tropospheric columns, a widely used metric for diagnosing near-surface ozone sensitivity. Specifically, the errors were categorized/quantified into (i) an inherent chemistry error, (ii) the decoupled relationship between columns and the near-surface concentration, (iii) the spatial representativeness error of ground satellite pixels, and (iv) the satellite retrieval errors.
Viral Shah, Daniel J. Jacob, Ruijun Dang, Lok N. Lamsal, Sarah A. Strode, Stephen D. Steenrod, K. Folkert Boersma, Sebastian D. Eastham, Thibaud M. Fritz, Chelsea Thompson, Jeff Peischl, Ilann Bourgeois, Ilana B. Pollack, Benjamin A. Nault, Ronald C. Cohen, Pedro Campuzano-Jost, Jose L. Jimenez, Simone T. Andersen, Lucy J. Carpenter, Tomás Sherwen, and Mat J. Evans
Atmos. Chem. Phys., 23, 1227–1257, https://doi.org/10.5194/acp-23-1227-2023, https://doi.org/10.5194/acp-23-1227-2023, 2023
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NOx in the free troposphere (above 2 km) affects global tropospheric chemistry and the retrieval and interpretation of satellite NO2 measurements. We evaluate free tropospheric NOx in global atmospheric chemistry models and find that recycling NOx from its reservoirs over the oceans is faster than that simulated in the models, resulting in increases in simulated tropospheric ozone and OH. Over the U.S., free tropospheric NO2 contributes the majority of the tropospheric NO2 column in summer.
Randall V. Martin, Sebastian D. Eastham, Liam Bindle, Elizabeth W. Lundgren, Thomas L. Clune, Christoph A. Keller, William Downs, Dandan Zhang, Robert A. Lucchesi, Melissa P. Sulprizio, Robert M. Yantosca, Yanshun Li, Lucas Estrada, William M. Putman, Benjamin M. Auer, Atanas L. Trayanov, Steven Pawson, and Daniel J. Jacob
Geosci. Model Dev., 15, 8731–8748, https://doi.org/10.5194/gmd-15-8731-2022, https://doi.org/10.5194/gmd-15-8731-2022, 2022
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Atmospheric chemistry models must be able to operate both online as components of Earth system models and offline as standalone models. The widely used GEOS-Chem model operates both online and offline, but the classic offline version is not suitable for massively parallel simulations. We describe a new generation of the offline high-performance GEOS-Chem (GCHP) that enables high-resolution simulations on thousands of cores, including on the cloud, with improved access, performance, and accuracy.
Thibaud M. Fritz, Sebastian D. Eastham, Louisa K. Emmons, Haipeng Lin, Elizabeth W. Lundgren, Steve Goldhaber, Steven R. H. Barrett, and Daniel J. Jacob
Geosci. Model Dev., 15, 8669–8704, https://doi.org/10.5194/gmd-15-8669-2022, https://doi.org/10.5194/gmd-15-8669-2022, 2022
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We bring the state-of-the-science chemistry module GEOS-Chem into the Community Earth System Model (CESM). We show that some known differences between results from GEOS-Chem and CESM's CAM-chem chemistry module may be due to the configuration of model meteorology rather than inherent differences in the model chemistry. This is a significant step towards a truly modular Earth system model and allows two strong but currently separate research communities to benefit from each other's advances.
Haolin Wang, Xiao Lu, Daniel J. Jacob, Owen R. Cooper, Kai-Lan Chang, Ke Li, Meng Gao, Yiming Liu, Bosi Sheng, Kai Wu, Tongwen Wu, Jie Zhang, Bastien Sauvage, Philippe Nédélec, Romain Blot, and Shaojia Fan
Atmos. Chem. Phys., 22, 13753–13782, https://doi.org/10.5194/acp-22-13753-2022, https://doi.org/10.5194/acp-22-13753-2022, 2022
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We report significant global tropospheric ozone increases in 1995–2017 based on extensive aircraft and ozonesonde observations. Using GEOS-Chem (Goddard Earth Observing System chemistry model) multi-decadal global simulations, we find that changes in global anthropogenic emissions, in particular the rapid increases in aircraft emissions, contribute significantly to the increases in tropospheric ozone and resulting radiative impact.
Lu Shen, Ritesh Gautam, Mark Omara, Daniel Zavala-Araiza, Joannes D. Maasakkers, Tia R. Scarpelli, Alba Lorente, David Lyon, Jianxiong Sheng, Daniel J. Varon, Hannah Nesser, Zhen Qu, Xiao Lu, Melissa P. Sulprizio, Steven P. Hamburg, and Daniel J. Jacob
Atmos. Chem. Phys., 22, 11203–11215, https://doi.org/10.5194/acp-22-11203-2022, https://doi.org/10.5194/acp-22-11203-2022, 2022
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We use 22 months of TROPOMI satellite observations to quantity methane emissions from the oil (O) and natural gas (G) sector in the US and Canada at the scale of both individual basins as well as country-wide aggregates. We find that O/G-related methane emissions are underestimated in these inventories by 80 % for the US and 40 % for Canada, and 70 % of the underestimate in the US is from five O/G basins, including Permian, Haynesville, Anadarko, Eagle Ford, and Barnett.
Zichong Chen, Daniel J. Jacob, Hannah Nesser, Melissa P. Sulprizio, Alba Lorente, Daniel J. Varon, Xiao Lu, Lu Shen, Zhen Qu, Elise Penn, and Xueying Yu
Atmos. Chem. Phys., 22, 10809–10826, https://doi.org/10.5194/acp-22-10809-2022, https://doi.org/10.5194/acp-22-10809-2022, 2022
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We quantify methane emissions in China and contributions from different sectors by inverse analysis of 2019 TROPOMI satellite observations of atmospheric methane. We find that anthropogenic methane emissions for China are underestimated in the national inventory. Our estimate of emissions indicates a small life-cycle loss rate, implying net climate benefits from the current
coal-to-gasenergy transition in China. However, this small loss rate can be misleading given China's high gas imports.
Daniel J. Jacob, Daniel J. Varon, Daniel H. Cusworth, Philip E. Dennison, Christian Frankenberg, Ritesh Gautam, Luis Guanter, John Kelley, Jason McKeever, Lesley E. Ott, Benjamin Poulter, Zhen Qu, Andrew K. Thorpe, John R. Worden, and Riley M. Duren
Atmos. Chem. Phys., 22, 9617–9646, https://doi.org/10.5194/acp-22-9617-2022, https://doi.org/10.5194/acp-22-9617-2022, 2022
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We review the capability of satellite observations of atmospheric methane to quantify methane emissions on all scales. We cover retrieval methods, precision requirements, inverse methods for inferring emissions, source detection thresholds, and observations of system completeness. We show that current instruments already enable quantification of regional and national emissions including contributions from large point sources. Coverage and resolution will increase significantly in coming years.
Daniel J. Varon, Daniel J. Jacob, Melissa Sulprizio, Lucas A. Estrada, William B. Downs, Lu Shen, Sarah E. Hancock, Hannah Nesser, Zhen Qu, Elise Penn, Zichong Chen, Xiao Lu, Alba Lorente, Ashutosh Tewari, and Cynthia A. Randles
Geosci. Model Dev., 15, 5787–5805, https://doi.org/10.5194/gmd-15-5787-2022, https://doi.org/10.5194/gmd-15-5787-2022, 2022
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Reducing atmospheric methane emissions is critical to slow near-term climate change. Globally surveying satellite instruments like the TROPOspheric Monitoring Instrument (TROPOMI) have unique capabilities for monitoring atmospheric methane around the world. Here we present a user-friendly cloud-computing tool that enables researchers and stakeholders to quantify methane emissions across user-selected regions of interest using TROPOMI satellite observations.
Kang Sun, Mahdi Yousefi, Christopher Chan Miller, Kelly Chance, Gonzalo González Abad, Iouli E. Gordon, Xiong Liu, Ewan O'Sullivan, Christopher E. Sioris, and Steven C. Wofsy
Atmos. Meas. Tech., 15, 3721–3745, https://doi.org/10.5194/amt-15-3721-2022, https://doi.org/10.5194/amt-15-3721-2022, 2022
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This study of upper atmospheric airglow from oxygen is motivated by the need to measure oxygen simultaneously with methane and CO2 in satellite remote sensing. We provide an accurate understanding of the spatial, temporal, and spectral distribution of airglow emissions, which will help in the satellite remote sensing of greenhouse gases and constraining the chemical and physical processes in the upper atmosphere.
Tianlang Zhao, Jingqiu Mao, William R. Simpson, Isabelle De Smedt, Lei Zhu, Thomas F. Hanisco, Glenn M. Wolfe, Jason M. St. Clair, Gonzalo González Abad, Caroline R. Nowlan, Barbara Barletta, Simone Meinardi, Donald R. Blake, Eric C. Apel, and Rebecca S. Hornbrook
Atmos. Chem. Phys., 22, 7163–7178, https://doi.org/10.5194/acp-22-7163-2022, https://doi.org/10.5194/acp-22-7163-2022, 2022
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Monitoring formaldehyde (HCHO) can help us understand Arctic vegetation change. Here, we compare satellite data and model and show that Alaska summertime HCHO is largely dominated by a background from methane oxidation during mild wildfire years and is dominated by wildfire (largely from direct emission of fire) during strong fire years. Consequently, it is challenging to use satellite HCHO to study vegetation change in the Arctic region.
John R. Worden, Daniel H. Cusworth, Zhen Qu, Yi Yin, Yuzhong Zhang, A. Anthony Bloom, Shuang Ma, Brendan K. Byrne, Tia Scarpelli, Joannes D. Maasakkers, David Crisp, Riley Duren, and Daniel J. Jacob
Atmos. Chem. Phys., 22, 6811–6841, https://doi.org/10.5194/acp-22-6811-2022, https://doi.org/10.5194/acp-22-6811-2022, 2022
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This paper is intended to accomplish two goals: 1) describe a new algorithm by which remotely sensed measurements of methane or other tracers can be used to not just quantify methane fluxes, but also attribute these fluxes to specific sources and regions and characterize their uncertainties, and 2) use this new algorithm to provide methane emissions by sector and country in support of the global stock take.
Tia R. Scarpelli, Daniel J. Jacob, Shayna Grossman, Xiao Lu, Zhen Qu, Melissa P. Sulprizio, Yuzhong Zhang, Frances Reuland, Deborah Gordon, and John R. Worden
Atmos. Chem. Phys., 22, 3235–3249, https://doi.org/10.5194/acp-22-3235-2022, https://doi.org/10.5194/acp-22-3235-2022, 2022
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We present a spatially explicit version of the national inventories of oil, gas, and coal methane emissions as submitted by individual countries to the United Nations Framework Convention on Climate Change (UNFCCC) in 2021. We then use atmospheric modeling to compare our inventory emissions to atmospheric methane observations with the goal of identifying potential under- and overestimates of oil–gas methane emissions in the national inventories.
Drew C. Pendergrass, Shixian Zhai, Jhoon Kim, Ja-Ho Koo, Seoyoung Lee, Minah Bae, Soontae Kim, Hong Liao, and Daniel J. Jacob
Atmos. Meas. Tech., 15, 1075–1091, https://doi.org/10.5194/amt-15-1075-2022, https://doi.org/10.5194/amt-15-1075-2022, 2022
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This paper uses a machine learning algorithm to infer high-resolution maps of particulate air quality in eastern China, Japan, and the Korean peninsula, using data from a geostationary satellite along with meteorology. We then perform an extensive evaluation of this inferred air quality and use it to diagnose trends in the region. We hope this paper and the associated data will be valuable to other scientists interested in epidemiology, air quality, remote sensing, and machine learning.
Lu Shen, Daniel J. Jacob, Mauricio Santillana, Kelvin Bates, Jiawei Zhuang, and Wei Chen
Geosci. Model Dev., 15, 1677–1687, https://doi.org/10.5194/gmd-15-1677-2022, https://doi.org/10.5194/gmd-15-1677-2022, 2022
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The high computational cost of chemical integration is a long-standing limitation in global atmospheric chemistry models. Here we present an adaptive and efficient algorithm that can reduce the computational time of atmospheric chemistry by 50 % and maintain the error below 2 % for important species, inspired by machine learning clustering techniques and traditional asymptotic analysis ideas.
Xiao Lu, Daniel J. Jacob, Haolin Wang, Joannes D. Maasakkers, Yuzhong Zhang, Tia R. Scarpelli, Lu Shen, Zhen Qu, Melissa P. Sulprizio, Hannah Nesser, A. Anthony Bloom, Shuang Ma, John R. Worden, Shaojia Fan, Robert J. Parker, Hartmut Boesch, Ritesh Gautam, Deborah Gordon, Michael D. Moran, Frances Reuland, Claudia A. Octaviano Villasana, and Arlyn Andrews
Atmos. Chem. Phys., 22, 395–418, https://doi.org/10.5194/acp-22-395-2022, https://doi.org/10.5194/acp-22-395-2022, 2022
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We evaluate methane emissions and trends for 2010–2017 in the gridded national emission inventories for the United States, Canada, and Mexico by inversion of in situ and satellite methane observations. We find that anthropogenic methane emissions for all three countries are underestimated in the national inventories, largely driven by oil emissions. Anthropogenic methane emissions in the US peak in 2014, in contrast to the report of a steadily decreasing trend over 2010–2017 from the US EPA.
Amir H. Souri, Kelly Chance, Kang Sun, Xiong Liu, and Matthew S. Johnson
Atmos. Meas. Tech., 15, 41–59, https://doi.org/10.5194/amt-15-41-2022, https://doi.org/10.5194/amt-15-41-2022, 2022
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The central component of satellite and model validation is pointwise measurements. A point is an element of space, whereas satellite (model) pixels represent an averaged area. These two datasets are inherently different. We leveraged some geostatistical tools to transform discrete points to gridded data with quantified uncertainty, comparable to satellite footprint (and response functions). This in part alleviated some complications concerning point–pixel comparisons.
Kelvin H. Bates, Daniel J. Jacob, Ke Li, Peter D. Ivatt, Mat J. Evans, Yingying Yan, and Jintai Lin
Atmos. Chem. Phys., 21, 18351–18374, https://doi.org/10.5194/acp-21-18351-2021, https://doi.org/10.5194/acp-21-18351-2021, 2021
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Simple aromatic compounds (benzene, toluene, xylene) have complex gas-phase chemistry that is inconsistently represented in atmospheric models. We compile recent experimental and theoretical insights to develop a new mechanism for gas-phase aromatic oxidation that is sufficiently compact for use in multiscale models. We compare our new mechanism to chamber experiments and other mechanisms, and implement it in a global model to quantify the impacts of aromatic oxidation on tropospheric chemistry.
Amir H. Souri, Kelly Chance, Juseon Bak, Caroline R. Nowlan, Gonzalo González Abad, Yeonjin Jung, David C. Wong, Jingqiu Mao, and Xiong Liu
Atmos. Chem. Phys., 21, 18227–18245, https://doi.org/10.5194/acp-21-18227-2021, https://doi.org/10.5194/acp-21-18227-2021, 2021
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The global pandemic is believed to have an impact on emissions of air pollutants such as nitrogen dioxide (NO2) and formaldehyde (HCHO). This study quantifies the changes in the amount of NOx and VOC emissions via state-of-the-art inverse modeling technique using satellite observations during the lockdown 2020 with respect to a baseline over Europe, which in turn, it permits unraveling atmospheric processes being responsible for ozone formation in a less cloudy month.
Sabour Baray, Daniel J. Jacob, Joannes D. Maasakkers, Jian-Xiong Sheng, Melissa P. Sulprizio, Dylan B. A. Jones, A. Anthony Bloom, and Robert McLaren
Atmos. Chem. Phys., 21, 18101–18121, https://doi.org/10.5194/acp-21-18101-2021, https://doi.org/10.5194/acp-21-18101-2021, 2021
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We use 2010–2015 surface and satellite observations to disentangle methane from anthropogenic and natural sources in Canada. Using a chemical transport model (GEOS-Chem), the mismatch between modelled and observed methane concentrations can be used to infer emissions according to Bayesian statistics. Compared to prior knowledge, we show higher anthropogenic emissions attributed to energy and/or agriculture in Western Canada and lower natural emissions from Boreal wetlands.
Shixian Zhai, Daniel J. Jacob, Jared F. Brewer, Ke Li, Jonathan M. Moch, Jhoon Kim, Seoyoung Lee, Hyunkwang Lim, Hyun Chul Lee, Su Keun Kuk, Rokjin J. Park, Jaein I. Jeong, Xuan Wang, Pengfei Liu, Gan Luo, Fangqun Yu, Jun Meng, Randall V. Martin, Katherine R. Travis, Johnathan W. Hair, Bruce E. Anderson, Jack E. Dibb, Jose L. Jimenez, Pedro Campuzano-Jost, Benjamin A. Nault, Jung-Hun Woo, Younha Kim, Qiang Zhang, and Hong Liao
Atmos. Chem. Phys., 21, 16775–16791, https://doi.org/10.5194/acp-21-16775-2021, https://doi.org/10.5194/acp-21-16775-2021, 2021
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Geostationary satellite aerosol optical depth (AOD) has tremendous potential for monitoring surface fine particulate matter (PM2.5). Our study explored the physical relationship between AOD and PM2.5 by integrating data from surface networks, aircraft, and satellites with the GEOS-Chem chemical transport model. We quantitatively showed that accurate simulation of aerosol size distributions, boundary layer depths, relative humidity, coarse particles, and diurnal variations in PM2.5 are essential.
Liam Bindle, Randall V. Martin, Matthew J. Cooper, Elizabeth W. Lundgren, Sebastian D. Eastham, Benjamin M. Auer, Thomas L. Clune, Hongjian Weng, Jintai Lin, Lee T. Murray, Jun Meng, Christoph A. Keller, William M. Putman, Steven Pawson, and Daniel J. Jacob
Geosci. Model Dev., 14, 5977–5997, https://doi.org/10.5194/gmd-14-5977-2021, https://doi.org/10.5194/gmd-14-5977-2021, 2021
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Atmospheric chemistry models like GEOS-Chem are versatile tools widely used in air pollution and climate studies. The simulations used in such studies can be very computationally demanding, and thus it is useful if the model can simulate a specific geographic region at a higher resolution than the rest of the globe. Here, we implement, test, and demonstrate a new variable-resolution capability in GEOS-Chem that is suitable for simulations conducted on supercomputers.
Zhen Qu, Daniel J. Jacob, Lu Shen, Xiao Lu, Yuzhong Zhang, Tia R. Scarpelli, Hannah Nesser, Melissa P. Sulprizio, Joannes D. Maasakkers, A. Anthony Bloom, John R. Worden, Robert J. Parker, and Alba L. Delgado
Atmos. Chem. Phys., 21, 14159–14175, https://doi.org/10.5194/acp-21-14159-2021, https://doi.org/10.5194/acp-21-14159-2021, 2021
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The recent launch of TROPOMI offers an unprecedented opportunity to quantify the methane budget from a top-down perspective. We use TROPOMI and the more mature GOSAT methane observations to estimate methane emissions and get consistent global budgets. However, TROPOMI shows biases over regions where surface albedo is small and provides less information for the coarse-resolution inversion due to the larger error correlations and spatial variations in the number of observations.
Xuan Wang, Daniel J. Jacob, William Downs, Shuting Zhai, Lei Zhu, Viral Shah, Christopher D. Holmes, Tomás Sherwen, Becky Alexander, Mathew J. Evans, Sebastian D. Eastham, J. Andrew Neuman, Patrick R. Veres, Theodore K. Koenig, Rainer Volkamer, L. Gregory Huey, Thomas J. Bannan, Carl J. Percival, Ben H. Lee, and Joel A. Thornton
Atmos. Chem. Phys., 21, 13973–13996, https://doi.org/10.5194/acp-21-13973-2021, https://doi.org/10.5194/acp-21-13973-2021, 2021
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Halogen radicals have a broad range of implications for tropospheric chemistry, air quality, and climate. We present a new mechanistic description and comprehensive simulation of tropospheric halogens in a global 3-D model and compare the model results with surface and aircraft measurements. We find that halogen chemistry decreases the global tropospheric burden of ozone by 11 %, NOx by 6 %, and OH by 4 %.
Haipeng Lin, Daniel J. Jacob, Elizabeth W. Lundgren, Melissa P. Sulprizio, Christoph A. Keller, Thibaud M. Fritz, Sebastian D. Eastham, Louisa K. Emmons, Patrick C. Campbell, Barry Baker, Rick D. Saylor, and Raffaele Montuoro
Geosci. Model Dev., 14, 5487–5506, https://doi.org/10.5194/gmd-14-5487-2021, https://doi.org/10.5194/gmd-14-5487-2021, 2021
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Emissions are a central component of atmospheric chemistry models. The Harmonized Emissions Component (HEMCO) is a software component for computing emissions from a user-selected ensemble of emission inventories and algorithms. It allows users to select, add, and scale emissions from different sources through a configuration file with no change to the model source code. We demonstrate the implementation of HEMCO in several models, all sharing the same HEMCO core code and database library.
Yi Yin, Frederic Chevallier, Philippe Ciais, Philippe Bousquet, Marielle Saunois, Bo Zheng, John Worden, A. Anthony Bloom, Robert J. Parker, Daniel J. Jacob, Edward J. Dlugokencky, and Christian Frankenberg
Atmos. Chem. Phys., 21, 12631–12647, https://doi.org/10.5194/acp-21-12631-2021, https://doi.org/10.5194/acp-21-12631-2021, 2021
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The growth of methane, the second-most important anthropogenic greenhouse gas after carbon dioxide, has been accelerating in recent years. Using an ensemble of multi-tracer atmospheric inversions constrained by surface or satellite observations, we show that global methane emissions increased by nearly 1 % per year from 2010–2017, with leading contributions from the tropics and East Asia.
Hannah Nesser, Daniel J. Jacob, Joannes D. Maasakkers, Tia R. Scarpelli, Melissa P. Sulprizio, Yuzhong Zhang, and Chris H. Rycroft
Atmos. Meas. Tech., 14, 5521–5534, https://doi.org/10.5194/amt-14-5521-2021, https://doi.org/10.5194/amt-14-5521-2021, 2021
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Analytical inversions of satellite observations of atmospheric composition can improve emissions estimates and quantify errors but are computationally expensive at high resolutions. We propose two methods to decrease this cost. The methods reproduce a high-resolution inversion at a quarter of the cost. The reduced-dimension method creates a multiscale grid. The reduced-rank method solves the inversion where information content is highest.
Xu Feng, Haipeng Lin, Tzung-May Fu, Melissa P. Sulprizio, Jiawei Zhuang, Daniel J. Jacob, Heng Tian, Yaping Ma, Lijuan Zhang, Xiaolin Wang, Qi Chen, and Zhiwei Han
Geosci. Model Dev., 14, 3741–3768, https://doi.org/10.5194/gmd-14-3741-2021, https://doi.org/10.5194/gmd-14-3741-2021, 2021
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WRF-GC is an online coupling of the WRF meteorological model and GEOS-Chem chemical transport model for regional atmospheric chemistry and air quality modeling. In WRF-GC v2.0, we implemented the aerosol–radiation interactions and aerosol–cloud interactions, as well as the capability to nest multiple domains for high-resolution simulations based on the modular framework of WRF-GC v1.0. This allows the GEOS-Chem users to investigate the meteorology–atmospheric chemistry interactions.
Carly Staebell, Kang Sun, Jenna Samra, Jonathan Franklin, Christopher Chan Miller, Xiong Liu, Eamon Conway, Kelly Chance, Scott Milligan, and Steven Wofsy
Atmos. Meas. Tech., 14, 3737–3753, https://doi.org/10.5194/amt-14-3737-2021, https://doi.org/10.5194/amt-14-3737-2021, 2021
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Given the high global warming potential of CH4, the identification and subsequent reduction of anthropogenic CH4 emissions presents a significant opportunity for climate change mitigation. Satellites are an integral piece of this puzzle, providing data to quantify emissions at a variety of spatial scales. This work presents the spectral calibration of MethaneAIR, the airborne instrument used as a test bed for the forthcoming MethaneSAT satellite.
David R. Lyon, Benjamin Hmiel, Ritesh Gautam, Mark Omara, Katherine A. Roberts, Zachary R. Barkley, Kenneth J. Davis, Natasha L. Miles, Vanessa C. Monteiro, Scott J. Richardson, Stephen Conley, Mackenzie L. Smith, Daniel J. Jacob, Lu Shen, Daniel J. Varon, Aijun Deng, Xander Rudelis, Nikhil Sharma, Kyle T. Story, Adam R. Brandt, Mary Kang, Eric A. Kort, Anthony J. Marchese, and Steven P. Hamburg
Atmos. Chem. Phys., 21, 6605–6626, https://doi.org/10.5194/acp-21-6605-2021, https://doi.org/10.5194/acp-21-6605-2021, 2021
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The Permian Basin (USA) is the world’s largest oil field. We use tower- and aircraft-based approaches to measure how methane emissions in the Permian Basin changed throughout 2020. In early 2020, 3.3 % of the region’s gas was emitted; then in spring 2020, the loss rate temporarily dropped to 1.9 % as oil price crashed. We find this short-term reduction to be a result of reduced well development, less gas flaring, and fewer abnormal events despite minimal reductions in oil and gas production.
Daniel J. Varon, Dylan Jervis, Jason McKeever, Ian Spence, David Gains, and Daniel J. Jacob
Atmos. Meas. Tech., 14, 2771–2785, https://doi.org/10.5194/amt-14-2771-2021, https://doi.org/10.5194/amt-14-2771-2021, 2021
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Satellites can detect methane emissions by measuring sunlight reflected from the Earth's surface and atmosphere. Here we show that the European Space Agency's Sentinel-2 twin satellites can be used to monitor anomalously large methane point sources around the world, with global coverage every 2–5 days and 20 m spatial resolution. We demonstrate this previously unreported capability through high-frequency Sentinel-2 monitoring of two strong methane point sources in Algeria and Turkmenistan.
Juseon Bak, Xiong Liu, Robert Spurr, Kai Yang, Caroline R. Nowlan, Christopher Chan Miller, Gonzalo Gonzalez Abad, and Kelly Chance
Atmos. Meas. Tech., 14, 2659–2672, https://doi.org/10.5194/amt-14-2659-2021, https://doi.org/10.5194/amt-14-2659-2021, 2021
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We apply a principal component analysis (PCA)-based approach combined with lookup tables (LUTs) of corrections to accelerate the VLIDORT radiative transfer (RT) model used in the retrieval of ozone profiles from backscattered ultraviolet (UV) measurements by the Ozone Monitoring Instrument (OMI).
Xiao Lu, Daniel J. Jacob, Yuzhong Zhang, Joannes D. Maasakkers, Melissa P. Sulprizio, Lu Shen, Zhen Qu, Tia R. Scarpelli, Hannah Nesser, Robert M. Yantosca, Jianxiong Sheng, Arlyn Andrews, Robert J. Parker, Hartmut Boesch, A. Anthony Bloom, and Shuang Ma
Atmos. Chem. Phys., 21, 4637–4657, https://doi.org/10.5194/acp-21-4637-2021, https://doi.org/10.5194/acp-21-4637-2021, 2021
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We use an analytical solution to the Bayesian inverse problem to quantitatively compare and combine the information from satellite and in situ observations, and to estimate global methane budget and their trends over the 2010–2017 period. We find that satellite and in situ observations are to a large extent complementary in the inversion for estimating global methane budget, and reveal consistent corrections of regional anthropogenic and wetland methane emissions relative to the prior inventory.
Joannes D. Maasakkers, Daniel J. Jacob, Melissa P. Sulprizio, Tia R. Scarpelli, Hannah Nesser, Jianxiong Sheng, Yuzhong Zhang, Xiao Lu, A. Anthony Bloom, Kevin W. Bowman, John R. Worden, and Robert J. Parker
Atmos. Chem. Phys., 21, 4339–4356, https://doi.org/10.5194/acp-21-4339-2021, https://doi.org/10.5194/acp-21-4339-2021, 2021
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We use 2010–2015 GOSAT satellite observations of atmospheric methane over North America in a high-resolution inversion to estimate methane emissions. We find general consistency with the gridded EPA inventory but higher oil and gas production emissions, with oil production emissions twice as large as in the latest EPA Greenhouse Gas Inventory. We find lower wetland emissions than predicted by WetCHARTs and a small increasing trend in the eastern US, apparently related to unconventional oil/gas.
Yuzhong Zhang, Daniel J. Jacob, Xiao Lu, Joannes D. Maasakkers, Tia R. Scarpelli, Jian-Xiong Sheng, Lu Shen, Zhen Qu, Melissa P. Sulprizio, Jinfeng Chang, A. Anthony Bloom, Shuang Ma, John Worden, Robert J. Parker, and Hartmut Boesch
Atmos. Chem. Phys., 21, 3643–3666, https://doi.org/10.5194/acp-21-3643-2021, https://doi.org/10.5194/acp-21-3643-2021, 2021
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We use 2010–2018 satellite observations of atmospheric methane to interpret the factors controlling atmospheric methane and its accelerating increase during the period. The 2010–2018 increase in global methane emissions is driven by tropical and boreal wetlands and tropical livestock (South Asia, Africa, Brazil), with an insignificant positive trend in emissions from the fossil fuel sector. The peak methane growth rates in 2014–2015 are also contributed by low OH and high fire emissions.
Susan S. Kulawik, John R. Worden, Vivienne H. Payne, Dejian Fu, Steven C. Wofsy, Kathryn McKain, Colm Sweeney, Bruce C. Daube Jr., Alan Lipton, Igor Polonsky, Yuguang He, Karen E. Cady-Pereira, Edward J. Dlugokencky, Daniel J. Jacob, and Yi Yin
Atmos. Meas. Tech., 14, 335–354, https://doi.org/10.5194/amt-14-335-2021, https://doi.org/10.5194/amt-14-335-2021, 2021
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This paper shows comparisons of a new single-footprint methane product from the AIRS satellite to aircraft-based observations. We show that this AIRS methane product provides useful information to study seasonal and global methane trends of this important greenhouse gas.
Junfeng Wang, Jianhuai Ye, Dantong Liu, Yangzhou Wu, Jian Zhao, Weiqi Xu, Conghui Xie, Fuzhen Shen, Jie Zhang, Paul E. Ohno, Yiming Qin, Xiuyong Zhao, Scot T. Martin, Alex K. Y. Lee, Pingqing Fu, Daniel J. Jacob, Qi Zhang, Yele Sun, Mindong Chen, and Xinlei Ge
Atmos. Chem. Phys., 20, 14091–14102, https://doi.org/10.5194/acp-20-14091-2020, https://doi.org/10.5194/acp-20-14091-2020, 2020
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We compared the organics in total submicron matter and those coated on BC cores during summertime in Beijing and found large differences between them. Traffic-related OA was associated significantly with BC, while cooking-related OA did not coat BC. In addition, a factor likely originated from primary biomass burning OA was only identified in BC-containing particles. Such a unique BBOA requires further field and laboratory studies to verify its presence and elucidate its properties and impacts.
Laura M. Judd, Jassim A. Al-Saadi, James J. Szykman, Lukas C. Valin, Scott J. Janz, Matthew G. Kowalewski, Henk J. Eskes, J. Pepijn Veefkind, Alexander Cede, Moritz Mueller, Manuel Gebetsberger, Robert Swap, R. Bradley Pierce, Caroline R. Nowlan, Gonzalo González Abad, Amin Nehrir, and David Williams
Atmos. Meas. Tech., 13, 6113–6140, https://doi.org/10.5194/amt-13-6113-2020, https://doi.org/10.5194/amt-13-6113-2020, 2020
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This paper evaluates Sentinel-5P TROPOMI v1.2 NO2 tropospheric columns over New York City using data from airborne mapping spectrometers and a network of ground-based spectrometers (Pandora) collected in 2018. These evaluations consider impacts due to cloud parameters, a priori profile assumptions, and spatial and temporal variability. Overall, TROPOMI tropospheric NO2 columns appear to have a low bias in this region.
Juseon Bak, Xiong Liu, Manfred Birk, Georg Wagner, Iouli E. Gordon, and Kelly Chance
Atmos. Meas. Tech., 13, 5845–5854, https://doi.org/10.5194/amt-13-5845-2020, https://doi.org/10.5194/amt-13-5845-2020, 2020
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This paper evaluates different sets of high-resolution ozone absorption cross-section data for use in atmospheric ozone profile measurements in the Hartley and Huggins bands with a particular focus on BDM 1995 (Daumont et al. 1992; Brion et al., 1993; Malicet et al., 1995) currently used in our retrievals and a new laboratory dataset by Birk and Wagner (BW) (2018).
Lei Zhu, Gonzalo González Abad, Caroline R. Nowlan, Christopher Chan Miller, Kelly Chance, Eric C. Apel, Joshua P. DiGangi, Alan Fried, Thomas F. Hanisco, Rebecca S. Hornbrook, Lu Hu, Jennifer Kaiser, Frank N. Keutsch, Wade Permar, Jason M. St. Clair, and Glenn M. Wolfe
Atmos. Chem. Phys., 20, 12329–12345, https://doi.org/10.5194/acp-20-12329-2020, https://doi.org/10.5194/acp-20-12329-2020, 2020
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We develop a validation platform for satellite HCHO retrievals using in situ observations from 12 aircraft campaigns. The platform offers an alternative way to quickly assess systematic biases in HCHO satellite products over large domains and long periods, facilitating optimization of retrieval settings and the minimization of retrieval biases. Application to the NASA operational HCHO product indicates that relative biases range from −44.5 % to +112.1 % depending on locations and seasons.
Viral Shah, Daniel J. Jacob, Jonathan M. Moch, Xuan Wang, and Shixian Zhai
Atmos. Chem. Phys., 20, 12223–12245, https://doi.org/10.5194/acp-20-12223-2020, https://doi.org/10.5194/acp-20-12223-2020, 2020
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Cloud water pH affects atmospheric chemistry, and acid rain damages ecosystems. We use model simulations along with observations to present a global view of cloud water and precipitation pH. Sulfuric acid, nitric acid, and ammonia control the pH in the northern midlatitudes, but carboxylic acids and dust cations are important in the tropics and subtropics. The acid inputs to many nitrogen-saturated ecosystems are high enough to cause acidification, with ammonium as the main acidifying species.
Ke Li, Daniel J. Jacob, Lu Shen, Xiao Lu, Isabelle De Smedt, and Hong Liao
Atmos. Chem. Phys., 20, 11423–11433, https://doi.org/10.5194/acp-20-11423-2020, https://doi.org/10.5194/acp-20-11423-2020, 2020
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Surface summer ozone increased in China from 2013 to 2019 despite new governmental efforts targeting ozone pollution. We find that the ozone increase is mostly due to anthropogenic drivers, although meteorology also plays a role. Further analysis for the North China Plain shows that PM2.5 continued to decrease through 2019, while emissions of volatile organic compounds (VOCs) stayed flat. This could explain the anthropogenic increase in ozone, as PM2.5 scavenges the radical precursors of ozone.
Xiao Lu, Lin Zhang, Tongwen Wu, Michael S. Long, Jun Wang, Daniel J. Jacob, Fang Zhang, Jie Zhang, Sebastian D. Eastham, Lu Hu, Lei Zhu, Xiong Liu, and Min Wei
Geosci. Model Dev., 13, 3817–3838, https://doi.org/10.5194/gmd-13-3817-2020, https://doi.org/10.5194/gmd-13-3817-2020, 2020
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This study presents the development and evaluation of a new climate chemistry model, BCC-GEOS-Chem v1.0, which couples the GEOS-Chem chemical transport model as an atmospheric chemistry component in the Beijing Climate Center atmospheric general circulation model. A 3-year (2012–2014) simulation of BCC-GEOS-Chem v1.0 shows that the model captures well the spatiotemporal distributions of tropospheric ozone, other gaseous pollutants, and aerosols.
Eamon K. Conway, Iouli E. Gordon, Jonathan Tennyson, Oleg L. Polyansky, Sergei N. Yurchenko, and Kelly Chance
Atmos. Chem. Phys., 20, 10015–10027, https://doi.org/10.5194/acp-20-10015-2020, https://doi.org/10.5194/acp-20-10015-2020, 2020
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Water vapour has a complex spectrum and absorbs from the microwave to the near-UV where it dissociates. There is limited knowledge of the absorption features in the near-UV, and there is a large disagreement for the available models and experiments. We created a new ab initio model that is in good agreement with observation at 363 nm. At lower wavelengths, our calculations suggest that the latest experiments overestimate absorption. This has implications for trace gas retrievals in the near-UV.
Amir H. Souri, Caroline R. Nowlan, Gonzalo González Abad, Lei Zhu, Donald R. Blake, Alan Fried, Andrew J. Weinheimer, Armin Wisthaler, Jung-Hun Woo, Qiang Zhang, Christopher E. Chan Miller, Xiong Liu, and Kelly Chance
Atmos. Chem. Phys., 20, 9837–9854, https://doi.org/10.5194/acp-20-9837-2020, https://doi.org/10.5194/acp-20-9837-2020, 2020
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For the first time, we provide a joint nonlinear optimal estimate of NOx and NMVOC emissions during the KORUS-AQ campaign by simultaneously incorporating SAO's new product of HCHO columns from OMPS and OMI tropospheric NO2 columns into a regional model. Results demonstrate a promising improvement in the performance of the model in terms of HCHO and NO2 concentrations, which in turn enables us to quantify the impact of the emission changes on different pathways of ozone formation and loss.
Haipeng Lin, Xu Feng, Tzung-May Fu, Heng Tian, Yaping Ma, Lijuan Zhang, Daniel J. Jacob, Robert M. Yantosca, Melissa P. Sulprizio, Elizabeth W. Lundgren, Jiawei Zhuang, Qiang Zhang, Xiao Lu, Lin Zhang, Lu Shen, Jianping Guo, Sebastian D. Eastham, and Christoph A. Keller
Geosci. Model Dev., 13, 3241–3265, https://doi.org/10.5194/gmd-13-3241-2020, https://doi.org/10.5194/gmd-13-3241-2020, 2020
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Online coupling of meteorology and chemistry models often presents maintenance issues with hard-wired coding. We present WRF-GC, an one-way online coupling of the WRF meteorological model and GEOS-Chem atmospheric chemistry model for regional atmospheric chemistry and air quality modeling. Our coupling structure allows future versions of either parent model to be immediately integrated into WRF-GC. The WRF-GC model was able to well reproduce regional PM2.5 with greater computational efficiency.
Lu Shen, Daniel J. Jacob, Mauricio Santillana, Xuan Wang, and Wei Chen
Geosci. Model Dev., 13, 2475–2486, https://doi.org/10.5194/gmd-13-2475-2020, https://doi.org/10.5194/gmd-13-2475-2020, 2020
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Chemical mechanisms in air quality models tend to get more complicated with time, reflecting both increasing knowledge and the need for greater scope. This objectively improves the models but increases the computational burden. In this work, we present an approach that can reduce the computational cost of chemical integration by 30–40 % while maintaining an accuracy better than 1 %. It retains the complexity of the full mechanism where it is needed and preserves full diagnostic information.
Tia R. Scarpelli, Daniel J. Jacob, Joannes D. Maasakkers, Melissa P. Sulprizio, Jian-Xiong Sheng, Kelly Rose, Lucy Romeo, John R. Worden, and Greet Janssens-Maenhout
Earth Syst. Sci. Data, 12, 563–575, https://doi.org/10.5194/essd-12-563-2020, https://doi.org/10.5194/essd-12-563-2020, 2020
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Methane, a potent greenhouse gas, is emitted through the exploitation of oil, gas, and coal resources, and many efforts to reduce emissions have targeted these sources. We have created a global inventory of oil, gas, and coal methane emissions based on country reporting to the United Nations. The inventory can be used along with satellite observations of methane to better understand the contribution of these sources to global emissions and to identify potential biases in emissions reporting.
Viral Shah, Daniel J. Jacob, Ke Li, Rachel F. Silvern, Shixian Zhai, Mengyao Liu, Jintai Lin, and Qiang Zhang
Atmos. Chem. Phys., 20, 1483–1495, https://doi.org/10.5194/acp-20-1483-2020, https://doi.org/10.5194/acp-20-1483-2020, 2020
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We analyze 15 years of satellite observations of nitrogen dioxide (NO2) and use an atmospheric chemistry model to understand the seasonal changes and trends in nitrogen oxides (NOx) over China. We show that the seasonal changes in NO2 occur due to changes in the NOx oxidation lifetime. We find that Chinese NOx emissions peaked in 2011 and had decreased by about 25 % by 2018. But the decrease in NO2 in winter was larger, likely because of a simultaneous decrease in the NOx oxidation lifetime.
Daniel H. Cusworth, Daniel J. Jacob, Daniel J. Varon, Christopher Chan Miller, Xiong Liu, Kelly Chance, Andrew K. Thorpe, Riley M. Duren, Charles E. Miller, David R. Thompson, Christian Frankenberg, Luis Guanter, and Cynthia A. Randles
Atmos. Meas. Tech., 12, 5655–5668, https://doi.org/10.5194/amt-12-5655-2019, https://doi.org/10.5194/amt-12-5655-2019, 2019
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We examine the potential for global detection of methane plumes from individual point sources with the new generation of spaceborne imaging spectrometers scheduled for launch in 2019–2025. We perform methane retrievals on simulated scenes with varying surfaces and atmospheric methane concentrations. Our results suggest that imaging spectrometers in space could play a transformative role in the future for quantifying methane emissions from point sources on a global scale.
Juseon Bak, Kang-Hyeon Baek, Jae-Hwan Kim, Xiong Liu, Jhoon Kim, and Kelly Chance
Atmos. Meas. Tech., 12, 5201–5215, https://doi.org/10.5194/amt-12-5201-2019, https://doi.org/10.5194/amt-12-5201-2019, 2019
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GEMS will be launched in late 2019 on board the GeoKOMPSAT (Geostationary Korea Multi-Purpose Satellite) to measure O3, NO2, SO2, H2CO, CHOCHO, and aerosols in East Asia. To support the development of the GEMS ozone profile algorithm, we perform the cross-evaluation of simulated GEMS ozone profile retrievals based on optimal estimation and ozonesonde measurements within the GEMS domain.
Huiqun Wang, Amir Hossein Souri, Gonzalo González Abad, Xiong Liu, and Kelly Chance
Atmos. Meas. Tech., 12, 5183–5199, https://doi.org/10.5194/amt-12-5183-2019, https://doi.org/10.5194/amt-12-5183-2019, 2019
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Total column water vapor (TCWV) is retrieved from the spectra obtained by the Ozone Monitoring Instrument (OMI). Data filtering criteria are recommended. The OMI data generally compare well with reference datasets over both land and the oceans. The data are useful for a variety of applications spanning a range of spatial and temporal scales, such as atmospheric rivers, corn sweat and El Niño.
Shixian Zhai, Daniel J. Jacob, Xuan Wang, Lu Shen, Ke Li, Yuzhong Zhang, Ke Gui, Tianliang Zhao, and Hong Liao
Atmos. Chem. Phys., 19, 11031–11041, https://doi.org/10.5194/acp-19-11031-2019, https://doi.org/10.5194/acp-19-11031-2019, 2019
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Observed annual mean PM2.5 decreased by 30–50 % in China from 2013–2018. However, meteorologically PM2.5 variability complicates trend attribution. We used a stepwise multiple linear regression model to quantitatively separate contributions from anthropogenic emissions and meteorology. Results show that 88 % of the PM2.5 decrease across China is attributable to anthropogenic emission changes, and 12 % is attributable to meteorology.
Katherine R. Travis and Daniel J. Jacob
Geosci. Model Dev., 12, 3641–3648, https://doi.org/10.5194/gmd-12-3641-2019, https://doi.org/10.5194/gmd-12-3641-2019, 2019
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Models of ozone air pollution are often evaluated with the policy metric set by the EPA of the maximum daily 8 h average ozone concentration. These models may be used in policy settings to evaluate air quality regulations. However, most models have difficulty simulating how ozone varies over the course of the day, and thus the use of this metric in model evaluation is problematic. Improved representation of mixed layer dynamics and ozone loss to the surface is needed to resolve this issue.
Kelvin H. Bates and Daniel J. Jacob
Atmos. Chem. Phys., 19, 9613–9640, https://doi.org/10.5194/acp-19-9613-2019, https://doi.org/10.5194/acp-19-9613-2019, 2019
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Isoprene is a highly reactive chemical released to the atmosphere by plants. Its gas-phase reactions and interactions with chemicals released by human activity have far-reaching atmospheric consequences, contributing to ozone and particulate pollution and prolonging the lifetime of methane, a potent greenhouse gas. We use global simulations with a new isoprene reaction scheme to quantify those effects and to show how recently discovered aspects of isoprene chemistry play out on a global scale.
Rachel F. Silvern, Daniel J. Jacob, Loretta J. Mickley, Melissa P. Sulprizio, Katherine R. Travis, Eloise A. Marais, Ronald C. Cohen, Joshua L. Laughner, Sungyeon Choi, Joanna Joiner, and Lok N. Lamsal
Atmos. Chem. Phys., 19, 8863–8878, https://doi.org/10.5194/acp-19-8863-2019, https://doi.org/10.5194/acp-19-8863-2019, 2019
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The US EPA reports a steady decrease in nitrogen oxide (NOx) emissions from fuel combustion over the 2005–2017 period, while satellite observations show a leveling off after 2009, suggesting emission reductions and related air quality gains have halted. We show the sustained decrease in NOx emissions is in fact consistent with observed trends in surface NO2 and ozone concentrations and that the flattening of the satellite trend reflects a growing influence from the non-anthropogenic background.
Juseon Bak, Xiong Liu, Kang Sun, Kelly Chance, and Jae-Hwan Kim
Atmos. Meas. Tech., 12, 3777–3788, https://doi.org/10.5194/amt-12-3777-2019, https://doi.org/10.5194/amt-12-3777-2019, 2019
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This work improves OMI ozone profile retrievals by accounting for spectral fit residuals caused by slit function errors as a pseudo absorber in the optimal-estimation-based spectral fitting process.
Hyeong-Ahn Kwon, Rokjin J. Park, Gonzalo González Abad, Kelly Chance, Thomas P. Kurosu, Jhoon Kim, Isabelle De Smedt, Michel Van Roozendael, Enno Peters, and John Burrows
Atmos. Meas. Tech., 12, 3551–3571, https://doi.org/10.5194/amt-12-3551-2019, https://doi.org/10.5194/amt-12-3551-2019, 2019
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The Geostationary Environment Monitoring Spectrometer (GEMS) will be launched by South Korea in 2019, and it will measure radiances ranging from 300 to 500 nm every hour with a fine spatial resolution of 7 km x 8 km over Seoul in South Korea to monitor column concentrations of air pollutants including O3, NO2, SO2, and HCHO, as well as aerosol optical properties. This paper describes a GEMS formaldehyde retrieval algorithm including a number of sensitivity tests for algorithm evaluation.
Joannes D. Maasakkers, Daniel J. Jacob, Melissa P. Sulprizio, Tia R. Scarpelli, Hannah Nesser, Jian-Xiong Sheng, Yuzhong Zhang, Monica Hersher, A. Anthony Bloom, Kevin W. Bowman, John R. Worden, Greet Janssens-Maenhout, and Robert J. Parker
Atmos. Chem. Phys., 19, 7859–7881, https://doi.org/10.5194/acp-19-7859-2019, https://doi.org/10.5194/acp-19-7859-2019, 2019
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We use 2010–2015 satellite observations of atmospheric methane to improve estimates of methane emissions and their trends, as well as the concentration and trend of tropospheric OH (hydroxyl radical, methane's main sink). We find overestimates of Chinese coal and Middle East oil/gas emissions in the prior estimate. The 2010–2015 growth in methane is attributed to an increase in emissions from India, China, and areas with large tropical wetlands. The contribution from OH is small in comparison.
Lu Shen, Daniel J. Jacob, Xiong Liu, Guanyu Huang, Ke Li, Hong Liao, and Tao Wang
Atmos. Chem. Phys., 19, 6551–6560, https://doi.org/10.5194/acp-19-6551-2019, https://doi.org/10.5194/acp-19-6551-2019, 2019
Lei Zhu, Daniel J. Jacob, Sebastian D. Eastham, Melissa P. Sulprizio, Xuan Wang, Tomás Sherwen, Mat J. Evans, Qianjie Chen, Becky Alexander, Theodore K. Koenig, Rainer Volkamer, L. Gregory Huey, Michael Le Breton, Thomas J. Bannan, and Carl J. Percival
Atmos. Chem. Phys., 19, 6497–6507, https://doi.org/10.5194/acp-19-6497-2019, https://doi.org/10.5194/acp-19-6497-2019, 2019
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We quantify the effect of sea salt aerosol on tropospheric bromine chemistry with a new mechanistic description of the halogen chemistry in a global atmospheric chemistry model. For the first time, we are able to reproduce the observed levels of bromide activation from the sea salt aerosol in a manner consistent with bromine oxide radical measured from various platforms. Sea salt aerosol plays a far more complex role in global tropospheric chemistry than previously recognized.
Raid M. Suleiman, Kelly Chance, Xiong Liu, Gonzalo González Abad, Thomas P. Kurosu, Francois Hendrick, and Nicolas Theys
Atmos. Meas. Tech., 12, 2067–2084, https://doi.org/10.5194/amt-12-2067-2019, https://doi.org/10.5194/amt-12-2067-2019, 2019
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This paper presents the retrieval algorithm for the operational OMBRO data product and shows comparisons with correlative measurements and retrieval results. We highlight the physics of the retrieval. We compare the OMBRO products with other satellite and in situ measurements of BrO and illustrate the quality of the product on a global scale. We study OMBRO enhancements in volcanic plumes and over salt lakes. We also discuss the shortcomings and future updates of the OMBRO product.
Xuan Wang, Daniel J. Jacob, Sebastian D. Eastham, Melissa P. Sulprizio, Lei Zhu, Qianjie Chen, Becky Alexander, Tomás Sherwen, Mathew J. Evans, Ben H. Lee, Jessica D. Haskins, Felipe D. Lopez-Hilfiker, Joel A. Thornton, Gregory L. Huey, and Hong Liao
Atmos. Chem. Phys., 19, 3981–4003, https://doi.org/10.5194/acp-19-3981-2019, https://doi.org/10.5194/acp-19-3981-2019, 2019
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Chlorine radicals have a broad range of implications for tropospheric chemistry, air quality, and climate. We present a comprehensive simulation of tropospheric chlorine in a global 3-D model, which includes explicit accounting of chloride mobilization from sea salt aerosol. We find the chlorine chemistry contributes 1.0 % of the global oxidation of methane and decreases global burdens of tropospheric ozone by 7 % and OH by 3 % through the associated bromine radical chemistry.
Jin Liao, Thomas F. Hanisco, Glenn M. Wolfe, Jason St. Clair, Jose L. Jimenez, Pedro Campuzano-Jost, Benjamin A. Nault, Alan Fried, Eloise A. Marais, Gonzalo Gonzalez Abad, Kelly Chance, Hiren T. Jethva, Thomas B. Ryerson, Carsten Warneke, and Armin Wisthaler
Atmos. Chem. Phys., 19, 2765–2785, https://doi.org/10.5194/acp-19-2765-2019, https://doi.org/10.5194/acp-19-2765-2019, 2019
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Organic aerosol (OA) intimately links natural and anthropogenic emissions with air quality and climate. Direct OA measurements from space are currently not possible. This paper describes a new method to estimate OA by combining satellite HCHO and in situ OA and HCHO. The OA estimate is validated with the ground network. This new method has a potential for mapping observation-based global OA estimate.
Shaojie Song, Meng Gao, Weiqi Xu, Yele Sun, Douglas R. Worsnop, John T. Jayne, Yuzhong Zhang, Lei Zhu, Mei Li, Zhen Zhou, Chunlei Cheng, Yibing Lv, Ying Wang, Wei Peng, Xiaobin Xu, Nan Lin, Yuxuan Wang, Shuxiao Wang, J. William Munger, Daniel J. Jacob, and Michael B. McElroy
Atmos. Chem. Phys., 19, 1357–1371, https://doi.org/10.5194/acp-19-1357-2019, https://doi.org/10.5194/acp-19-1357-2019, 2019
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Chemistry responsible for sulfate production in northern China winter haze remains mysterious. We propose a potentially key pathway through the reaction of formaldehyde and sulfur dioxide that has not been accounted for in previous studies. The special atmospheric conditions favor the formation and existence of their complex, hydroxymethanesulfonate (HMS).
Kang Sun, Lei Zhu, Karen Cady-Pereira, Christopher Chan Miller, Kelly Chance, Lieven Clarisse, Pierre-François Coheur, Gonzalo González Abad, Guanyu Huang, Xiong Liu, Martin Van Damme, Kai Yang, and Mark Zondlo
Atmos. Meas. Tech., 11, 6679–6701, https://doi.org/10.5194/amt-11-6679-2018, https://doi.org/10.5194/amt-11-6679-2018, 2018
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An agile, physics-based approach is developed to oversample irregular satellite observations to a high-resolution common grid. Instead of assuming each sounding as a point or a polygon as in previous methods, the proposed physical oversampling represents soundings as distributions of sensitivity on the ground. This sensitivity distribution can be determined by the spatial response function of each satellite sensor, parameterized as generalized 2-D super Gaussian functions.
Lu Shen, Daniel J. Jacob, Loretta J. Mickley, Yuxuan Wang, and Qiang Zhang
Atmos. Chem. Phys., 18, 17489–17496, https://doi.org/10.5194/acp-18-17489-2018, https://doi.org/10.5194/acp-18-17489-2018, 2018
Eloise A. Marais, Daniel J. Jacob, Sungyeon Choi, Joanna Joiner, Maria Belmonte-Rivas, Ronald C. Cohen, Steffen Beirle, Lee T. Murray, Luke D. Schiferl, Viral Shah, and Lyatt Jaeglé
Atmos. Chem. Phys., 18, 17017–17027, https://doi.org/10.5194/acp-18-17017-2018, https://doi.org/10.5194/acp-18-17017-2018, 2018
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We intercompare two new products of global upper tropospheric nitrogen dioxide (NO2) retrieved from the Ozone Monitoring Instrument (OMI). We evaluate these products with aircraft observations from NASA DC8 aircraft campaigns and interpret the useful information these products can provide about nitrogen oxides (NOx) in the global upper troposphere using the GEOS-Chem chemical transport model.
Jian-Xiong Sheng, Daniel J. Jacob, Joannes D. Maasakkers, Yuzhong Zhang, and Melissa P. Sulprizio
Atmos. Meas. Tech., 11, 6379–6388, https://doi.org/10.5194/amt-11-6379-2018, https://doi.org/10.5194/amt-11-6379-2018, 2018
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We conduct Observing System Simulation Experiments to compare the ability of future satellite measurements of atmospheric methane columns for constraining methane emissions at the 25 km scale. We find that the geostationary instruments can do much better than TROPOMI and are less sensitive to cloud cover. GeoCARB observing twice a day would provide 70 % of the information from the nominal GEO-CAPE mission considered by NASA in response to the Decadal Survey of the US National Research Council.
Daniel H. Cusworth, Daniel J. Jacob, Jian-Xiong Sheng, Joshua Benmergui, Alexander J. Turner, Jeremy Brandman, Laurent White, and Cynthia A. Randles
Atmos. Chem. Phys., 18, 16885–16896, https://doi.org/10.5194/acp-18-16885-2018, https://doi.org/10.5194/acp-18-16885-2018, 2018
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Methane emissions from oil/gas fields originate from a large number of small and densely clustered point sources. We examine the potential of recently launched or planned satellites to locate these high-mode emitters through measurements of atmospheric methane. We find that the recently launched TROPOMI and the planned GeoCARB instruments are successful at locating high-emitting sources for fields of 20-50 emitters within the 50 × 50 km2 geographic domain but are unsuccessful for denser fields.
Lu Hu, Christoph A. Keller, Michael S. Long, Tomás Sherwen, Benjamin Auer, Arlindo Da Silva, Jon E. Nielsen, Steven Pawson, Matthew A. Thompson, Atanas L. Trayanov, Katherine R. Travis, Stuart K. Grange, Mat J. Evans, and Daniel J. Jacob
Geosci. Model Dev., 11, 4603–4620, https://doi.org/10.5194/gmd-11-4603-2018, https://doi.org/10.5194/gmd-11-4603-2018, 2018
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We present a full-year online global simulation of tropospheric chemistry at 12.5 km resolution. To the best of our knowledge, such a resolution in a state-of-the-science global simulation of tropospheric chemistry is unprecedented. This simulation will serve as the Nature Run for observing system simulation experiments to support the future geostationary satellite constellation for tropospheric chemistry, and can also be used for various air quality applications.
Yuzhong Zhang, Daniel J. Jacob, Joannes D. Maasakkers, Melissa P. Sulprizio, Jian-Xiong Sheng, Ritesh Gautam, and John Worden
Atmos. Chem. Phys., 18, 15959–15973, https://doi.org/10.5194/acp-18-15959-2018, https://doi.org/10.5194/acp-18-15959-2018, 2018
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We assess the potential of using satellite observations of atmospheric methane to monitor global mean tropospheric OH concentration, a key parameter for the oxidizing power of the atmosphere.
Caroline R. Nowlan, Xiong Liu, Scott J. Janz, Matthew G. Kowalewski, Kelly Chance, Melanie B. Follette-Cook, Alan Fried, Gonzalo González Abad, Jay R. Herman, Laura M. Judd, Hyeong-Ahn Kwon, Christopher P. Loughner, Kenneth E. Pickering, Dirk Richter, Elena Spinei, James Walega, Petter Weibring, and Andrew J. Weinheimer
Atmos. Meas. Tech., 11, 5941–5964, https://doi.org/10.5194/amt-11-5941-2018, https://doi.org/10.5194/amt-11-5941-2018, 2018
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The GEO-CAPE Airborne Simulator (GCAS) was developed in support of future air quality and ocean color geostationary satellite missions. GCAS flew in its first field campaign on NASA's King Air B-200 aircraft during DISCOVER-AQ Texas in 2013. In this paper, we determine nitrogen dioxide and formaldehyde columns over Houston from the GCAS air quality sensor and compare those results with measurements made from ground-based Pandora spectrometers and in situ airborne instruments.
Hansen Cao, Tzung-May Fu, Lin Zhang, Daven K. Henze, Christopher Chan Miller, Christophe Lerot, Gonzalo González Abad, Isabelle De Smedt, Qiang Zhang, Michel van Roozendael, François Hendrick, Kelly Chance, Jie Li, Junyu Zheng, and Yuanhong Zhao
Atmos. Chem. Phys., 18, 15017–15046, https://doi.org/10.5194/acp-18-15017-2018, https://doi.org/10.5194/acp-18-15017-2018, 2018
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Our top-down estimates for annual total Chinese NMVOC emissions was 30.7 to 49.5 Tg y−1, including 16.4 to 23.6 Tg y−1 from anthropogenic sources, 12.2 to 22.8 Tg y−1 from biogenic sources, and 2.08 to 3.13 Tg y−1 from biomass burning. Our four inversions consistently showed that the emissions of Chinese anthropogenic NMVOC precursors of glyoxal were larger than the a priori estimates. The glyoxal and formaldehyde constraints helped distinguish the NMVOC species from different sources.
Daniel J. Varon, Daniel J. Jacob, Jason McKeever, Dylan Jervis, Berke O. A. Durak, Yan Xia, and Yi Huang
Atmos. Meas. Tech., 11, 5673–5686, https://doi.org/10.5194/amt-11-5673-2018, https://doi.org/10.5194/amt-11-5673-2018, 2018
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Methane is a powerful greenhouse gas emitted from numerous human activities. Space-based observation of point sources would be a cost-effective monitoring solution, but the resolution of most current and planned methane-observing satellites is too coarse to resolve individual emitters. We simulate fine-resolution (50 m) satellite observations of methane plumes as would be measured by GHGSat (to be launched in 2019) and show that such data can usefully quantify large methane point sources.
Jian-Xiong Sheng, Daniel J. Jacob, Alexander J. Turner, Joannes D. Maasakkers, Joshua Benmergui, A. Anthony Bloom, Claudia Arndt, Ritesh Gautam, Daniel Zavala-Araiza, Hartmut Boesch, and Robert J. Parker
Atmos. Chem. Phys., 18, 12257–12267, https://doi.org/10.5194/acp-18-12257-2018, https://doi.org/10.5194/acp-18-12257-2018, 2018
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Analysis of 7 years (2010–2016) of GOSAT methane trends over Canada, the contiguous US, and Mexico suggests that US methane emissions increased by 2.5 ± 1.4 % a−1 over the 7-year period, with contributions from both oil–gas systems and livestock in the Midwest. Mexican emissions show a decrease that can be attributed to a decreasing cattle population. Canadian emissions show year-to-year variability driven by wetland emissions and correlated with wetland areal extent.
Sebastian D. Eastham, Michael S. Long, Christoph A. Keller, Elizabeth Lundgren, Robert M. Yantosca, Jiawei Zhuang, Chi Li, Colin J. Lee, Matthew Yannetti, Benjamin M. Auer, Thomas L. Clune, Jules Kouatchou, William M. Putman, Matthew A. Thompson, Atanas L. Trayanov, Andrea M. Molod, Randall V. Martin, and Daniel J. Jacob
Geosci. Model Dev., 11, 2941–2953, https://doi.org/10.5194/gmd-11-2941-2018, https://doi.org/10.5194/gmd-11-2941-2018, 2018
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Global atmospheric chemical transport models are crucial tools in atmospheric science, used to address problems ranging from climate change to acid rain. GEOS-Chem High Performance (GCHP) is a new implementation of the widely used GEOS-Chem model, designed for massively parallel architectures. GCHP v11-02c is shown to be highly scalable from 6 to over 500 cores, enabling the routine simulation of global atmospheric chemistry from the surface to the stratopause at resolutions of ~50 km or finer.
Alexander J. Turner, Daniel J. Jacob, Joshua Benmergui, Jeremy Brandman, Laurent White, and Cynthia A. Randles
Atmos. Chem. Phys., 18, 8265–8278, https://doi.org/10.5194/acp-18-8265-2018, https://doi.org/10.5194/acp-18-8265-2018, 2018
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We conduct a 1-week WRF-STILT simulation to generate methane column footprints at 1.3 km spatial resolution and hourly temporal resolution over the Barnett Shale. We find that a week of TROPOMI observations should provide regional (~30 km) information on temporally invariant sources and GeoCARB should provide information on temporally invariant sources at 2–7 km spatial resolution. An instrument precision better than 6 ppb is an important threshold for achieving fine resolution of emissions.
Jian-Xiong Sheng, Daniel J. Jacob, Alexander J. Turner, Joannes D. Maasakkers, Melissa P. Sulprizio, A. Anthony Bloom, Arlyn E. Andrews, and Debra Wunch
Atmos. Chem. Phys., 18, 6483–6491, https://doi.org/10.5194/acp-18-6483-2018, https://doi.org/10.5194/acp-18-6483-2018, 2018
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We use observations of boundary layer methane from the SEAC4RS aircraft campaign over the Southeast US to estimate methane emissions in that region. Our results suggest that the EPA inventory is regionally unbiased but there are large local biases, suggesting variable emission factors. Our results also suggest that the choice of landcover map is the dominant source of error for wetland emission estimates.
Jiawei Zhuang, Daniel J. Jacob, and Sebastian D. Eastham
Atmos. Chem. Phys., 18, 6039–6055, https://doi.org/10.5194/acp-18-6039-2018, https://doi.org/10.5194/acp-18-6039-2018, 2018
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Our work explains why current model simulations are unable to capture the intercontinental influences of pollution plumes that are often observed over some regions like California. Due to inadequate vertical grid resolution in these models, the plumes get diffused too rapidly during intercontinental transport. Increasing the vertical grid resolution greatly improves the simulation of plumes and considerably increases the estimate of local surface pollution influence.
Pieternel F. Levelt, Joanna Joiner, Johanna Tamminen, J. Pepijn Veefkind, Pawan K. Bhartia, Deborah C. Stein Zweers, Bryan N. Duncan, David G. Streets, Henk Eskes, Ronald van der A, Chris McLinden, Vitali Fioletov, Simon Carn, Jos de Laat, Matthew DeLand, Sergey Marchenko, Richard McPeters, Jerald Ziemke, Dejian Fu, Xiong Liu, Kenneth Pickering, Arnoud Apituley, Gonzalo González Abad, Antti Arola, Folkert Boersma, Christopher Chan Miller, Kelly Chance, Martin de Graaf, Janne Hakkarainen, Seppo Hassinen, Iolanda Ialongo, Quintus Kleipool, Nickolay Krotkov, Can Li, Lok Lamsal, Paul Newman, Caroline Nowlan, Raid Suleiman, Lieuwe Gijsbert Tilstra, Omar Torres, Huiqun Wang, and Krzysztof Wargan
Atmos. Chem. Phys., 18, 5699–5745, https://doi.org/10.5194/acp-18-5699-2018, https://doi.org/10.5194/acp-18-5699-2018, 2018
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The aim of this paper is to highlight the many successes of the Ozone Monitoring Instrument (OMI) spanning more than 13 years. Data from OMI have been used in a wide range of applications. Due to its unprecedented spatial resolution, in combination with daily global coverage, OMI plays a unique role in measuring trace gases important for the ozone layer, air quality, and climate change. OMI data continue to be used for new research and applications.
Jennifer Kaiser, Daniel J. Jacob, Lei Zhu, Katherine R. Travis, Jenny A. Fisher, Gonzalo González Abad, Lin Zhang, Xuesong Zhang, Alan Fried, John D. Crounse, Jason M. St. Clair, and Armin Wisthaler
Atmos. Chem. Phys., 18, 5483–5497, https://doi.org/10.5194/acp-18-5483-2018, https://doi.org/10.5194/acp-18-5483-2018, 2018
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Isoprene emissions from vegetation have a large effect on atmospheric chemistry and air quality. Here we use the adjoint of GEOS-Chem in an inversion of OMI formaldehyde observations to produce top-down estimates of isoprene emissions in the southeast US during the summer of 2013. We find that MEGAN v2.1 is biased high on average by 40 %. Our downward correction of isoprene emissions leads to a small reduction in modeled surface O3 and decreases the contribution of isoprene to organic aerosol.
Karen Yu, Christoph A. Keller, Daniel J. Jacob, Andrea M. Molod, Sebastian D. Eastham, and Michael S. Long
Geosci. Model Dev., 11, 305–319, https://doi.org/10.5194/gmd-11-305-2018, https://doi.org/10.5194/gmd-11-305-2018, 2018
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Global simulations of atmospheric chemistry are generally conducted with off-line chemical transport models (CTMs) driven by archived meteorological data from general circulation models (GCMs). The off-line approach has the advantages of simplicity and expediency, but it is unable to reproduce the GCM transport exactly. We investigate the cascade of errors associated with the off-line approach using the GEOS-5 GCM and GEOS-Chem CTM and discuss improvements in the use of archived meteorology.
Guanyu Huang, Xiong Liu, Kelly Chance, Kai Yang, and Zhaonan Cai
Atmos. Meas. Tech., 11, 17–32, https://doi.org/10.5194/amt-11-17-2018, https://doi.org/10.5194/amt-11-17-2018, 2018
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In this paper, we focus on the validation of OMI ozone (PROFOZ) product in the stratosphere using MLS ozone observations. This paper, with its companion paper focusing on the validation in the troposphere by using global ozonesonde observations, provides us with a comprehensive understanding of the data quality of OMI PROFOZ product and impacts of the “row anomaly”.
Theodore K. Koenig, Rainer Volkamer, Sunil Baidar, Barbara Dix, Siyuan Wang, Daniel C. Anderson, Ross J. Salawitch, Pamela A. Wales, Carlos A. Cuevas, Rafael P. Fernandez, Alfonso Saiz-Lopez, Mathew J. Evans, Tomás Sherwen, Daniel J. Jacob, Johan Schmidt, Douglas Kinnison, Jean-François Lamarque, Eric C. Apel, James C. Bresch, Teresa Campos, Frank M. Flocke, Samuel R. Hall, Shawn B. Honomichl, Rebecca Hornbrook, Jørgen B. Jensen, Richard Lueb, Denise D. Montzka, Laura L. Pan, J. Michael Reeves, Sue M. Schauffler, Kirk Ullmann, Andrew J. Weinheimer, Elliot L. Atlas, Valeria Donets, Maria A. Navarro, Daniel Riemer, Nicola J. Blake, Dexian Chen, L. Gregory Huey, David J. Tanner, Thomas F. Hanisco, and Glenn M. Wolfe
Atmos. Chem. Phys., 17, 15245–15270, https://doi.org/10.5194/acp-17-15245-2017, https://doi.org/10.5194/acp-17-15245-2017, 2017
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Tropospheric inorganic bromine (BrO and Bry) shows a C-shaped profile over the tropical western Pacific Ocean, and supports previous speculation that marine convection is a source for inorganic bromine from sea salt to the upper troposphere. The Bry profile in the tropical tropopause layer (TTL) is complex, suggesting that the total Bry budget in the TTL is not closed without considering aerosol bromide. The implications for atmospheric composition and bromine sources are discussed.
Juseon Bak, Xiong Liu, Jae-Hwan Kim, David P. Haffner, Kelly Chance, Kai Yang, and Kang Sun
Atmos. Meas. Tech., 10, 4373–4388, https://doi.org/10.5194/amt-10-4373-2017, https://doi.org/10.5194/amt-10-4373-2017, 2017
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This paper verifies and corrects the Ozone Mapping and Profiler Suite (OMPS) nadir mapper (NM) level 1B v2.0 measurements to retrieve reliable ozone profile and tropospheric ozone using an optimal estimation inversion with the fitting window of 302.5–340 nm. We apply "soft calibration" and "common mode correction" to OMPS radiances to eliminate systematic errors in the fitting residuals and derive random-noise measurement errors accounting for both OMPS radiances and forward model calculation.
Kang Sun, Xiong Liu, Guanyu Huang, Gonzalo González Abad, Zhaonan Cai, Kelly Chance, and Kai Yang
Atmos. Meas. Tech., 10, 3677–3695, https://doi.org/10.5194/amt-10-3677-2017, https://doi.org/10.5194/amt-10-3677-2017, 2017
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This study derives on-orbit slit functions from the OMI irradiance spectra. The results differ from the widely used preflight slit functions. The on-orbit changes of OMI slit functions are insignificant over time after accounting for the solar activity. Applying the derived on-orbit slit functions to ozone-profile retrieval shows substantial improvements over the preflight slit functions based on comparisons with ozonesonde validations.
Katherine R. Travis, Daniel J. Jacob, Christoph A. Keller, Shi Kuang, Jintai Lin, Michael J. Newchurch, and Anne M. Thompson
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2017-596, https://doi.org/10.5194/acp-2017-596, 2017
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Models severely overestimate surface ozone in the Southeast US during summertime which has implications for the design of air quality regulations. We use a model (GEOS-Chem) to interpret ozone observations from a suite of observations taken during August–September 2013. The model is unbiased relative to observations below 1 km but is biased high at the surface. We attribute this bias to model representation error, an underestimate in low-cloud, and insufficient treatment of vertical mixing.
Christopher Chan Miller, Daniel J. Jacob, Eloise A. Marais, Karen Yu, Katherine R. Travis, Patrick S. Kim, Jenny A. Fisher, Lei Zhu, Glenn M. Wolfe, Thomas F. Hanisco, Frank N. Keutsch, Jennifer Kaiser, Kyung-Eun Min, Steven S. Brown, Rebecca A. Washenfelder, Gonzalo González Abad, and Kelly Chance
Atmos. Chem. Phys., 17, 8725–8738, https://doi.org/10.5194/acp-17-8725-2017, https://doi.org/10.5194/acp-17-8725-2017, 2017
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The use of satellite glyoxal observations for estimating isoprene emissions has been limited by knowledge of the glyoxal yield from isoprene. We use SENEX aircraft observations over the southeast US to evaluate glyoxal yields from isoprene in a 3-D atmospheric model. The SENEX observations support a pathway for glyoxal formation in pristine regions that we propose here, which may have implications for improving isoprene emissions estimates from upcoming high-resolution geostationary satellites.
Guanyu Huang, Xiong Liu, Kelly Chance, Kai Yang, Pawan K. Bhartia, Zhaonan Cai, Marc Allaart, Gérard Ancellet, Bertrand Calpini, Gerrie J. R. Coetzee, Emilio Cuevas-Agulló, Manuel Cupeiro, Hugo De Backer, Manvendra K. Dubey, Henry E. Fuelberg, Masatomo Fujiwara, Sophie Godin-Beekmann, Tristan J. Hall, Bryan Johnson, Everette Joseph, Rigel Kivi, Bogumil Kois, Ninong Komala, Gert König-Langlo, Giovanni Laneve, Thierry Leblanc, Marion Marchand, Kenneth R. Minschwaner, Gary Morris, Michael J. Newchurch, Shin-Ya Ogino, Nozomu Ohkawara, Ankie J. M. Piters, Françoise Posny, Richard Querel, Rinus Scheele, Frank J. Schmidlin, Russell C. Schnell, Otto Schrems, Henry Selkirk, Masato Shiotani, Pavla Skrivánková, René Stübi, Ghassan Taha, David W. Tarasick, Anne M. Thompson, Valérie Thouret, Matthew B. Tully, Roeland Van Malderen, Holger Vömel, Peter von der Gathen, Jacquelyn C. Witte, and Margarita Yela
Atmos. Meas. Tech., 10, 2455–2475, https://doi.org/10.5194/amt-10-2455-2017, https://doi.org/10.5194/amt-10-2455-2017, 2017
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It is essential to understand the data quality of +10-year OMI ozone product and impacts of the “row anomaly” (RA). We validate the OMI Ozone Profile (PROFOZ) product from Oct 2004 to Dec 2014 against ozonesonde observations globally. Generally, OMI has good agreement with ozonesondes. The spatiotemporal variation of retrieval performance suggests the need to improve OMI’s radiometric calibration especially during the post-RA period to maintain the long-term stability.
A. Anthony Bloom, Kevin W. Bowman, Meemong Lee, Alexander J. Turner, Ronny Schroeder, John R. Worden, Richard Weidner, Kyle C. McDonald, and Daniel J. Jacob
Geosci. Model Dev., 10, 2141–2156, https://doi.org/10.5194/gmd-10-2141-2017, https://doi.org/10.5194/gmd-10-2141-2017, 2017
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Wetland emissions are a principal source of uncertainty in the global atmospheric methane budget due to poor knowledge of wetland processes. We construct a wetland methane emission and uncertainty dataset for use in global atmospheric methane models. Our wetland model ensemble is based on static wetland maps, satellite-derived inundation and carbon cycle models. The ensemble performs favourably against regional flux estimates and atmospheric methane measurements relative to previous studies.
Hannah M. Horowitz, Daniel J. Jacob, Yanxu Zhang, Theodore S. Dibble, Franz Slemr, Helen M. Amos, Johan A. Schmidt, Elizabeth S. Corbitt, Eloïse A. Marais, and Elsie M. Sunderland
Atmos. Chem. Phys., 17, 6353–6371, https://doi.org/10.5194/acp-17-6353-2017, https://doi.org/10.5194/acp-17-6353-2017, 2017
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Mercury is a toxic, global pollutant released to the air from human activities like coal burning. Chemical reactions in air determine how far mercury is transported before it is deposited to the environment, where it may be converted to a form that accumulates in fish. We use a 3-D atmospheric model to evaluate a new set of chemical reactions and its effects on mercury deposition. We find it is consistent with observations and leads to increased deposition to oceans, especially in the tropics.
Rachel F. Silvern, Daniel J. Jacob, Patrick S. Kim, Eloise A. Marais, Jay R. Turner, Pedro Campuzano-Jost, and Jose L. Jimenez
Atmos. Chem. Phys., 17, 5107–5118, https://doi.org/10.5194/acp-17-5107-2017, https://doi.org/10.5194/acp-17-5107-2017, 2017
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We identify a fundamental discrepancy between thermodynamic equilibrium theory and observations of inorganic aerosol composition in the eastern US in summer that shows low ammonium sulfate aerosol ratios. In addition, from 2003 to 2013, while SO2 emissions have declined due to US emission controls, aerosols have become more acidic in the southeastern US. To explain these observations, we suggest that the large and increasing source of organic aerosol may be affecting thermodynamic equilibrium.
Michael P. Barkley, Gonzalo González Abad, Thomas P. Kurosu, Robert Spurr, Sara Torbatian, and Christophe Lerot
Atmos. Chem. Phys., 17, 4687–4709, https://doi.org/10.5194/acp-17-4687-2017, https://doi.org/10.5194/acp-17-4687-2017, 2017
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Using Ozone Monitoring Instrument (OMI) trace gas vertical column observations of NO2, HCHO, SO2, and CHOCHO, we have conducted a robust and detailed time series analysis to assess changes in local air quality for over 1000 locations (focussing on urban, oil refinery, oil port, and power plant targets) over the Middle East for 2005–2014. We find that for many locations in the Middle East, OMI observes a degradation in air quality during this time period.
Hyeong-Ahn Kwon, Rokjin J. Park, Jaein I. Jeong, Seungun Lee, Gonzalo González Abad, Thomas P. Kurosu, Paul I. Palmer, and Kelly Chance
Atmos. Chem. Phys., 17, 4673–4686, https://doi.org/10.5194/acp-17-4673-2017, https://doi.org/10.5194/acp-17-4673-2017, 2017
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A geostationary satellite can measure daytime hourly HCHO columns. Atmospheric conditions such as synoptic meteorology and the presence of other gases and aerosols may affect HCHO measurements. We examine the effects of their temporal variation on the HCHO measurement of a geostationary satellite in East Asia. We find that the hourly variation of other species could be important. Especially the inclusion of hourly aerosol variation in the retrieval could lead to improving HCHO measurements.
Kang Sun, Xiong Liu, Caroline R. Nowlan, Zhaonan Cai, Kelly Chance, Christian Frankenberg, Richard A. M. Lee, Randy Pollock, Robert Rosenberg, and David Crisp
Atmos. Meas. Tech., 10, 939–953, https://doi.org/10.5194/amt-10-939-2017, https://doi.org/10.5194/amt-10-939-2017, 2017
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Accurately characterizing the instrument line shape (ILS) of the Orbiting Carbon Observatory-2 (OCO-2) is challenging and highly important due to its high spectral resolution and requirement for retrieval accuracy. Measured ILS during preflight experiments has been used in the OCO-2 CO2 retrieval. This study derives the on-orbit ILS of OCO-2 using its solar measurements and answers the questions whether on-orbit ILS has changed compared to preflight and whether it varies during the mission.
Sebastian D. Eastham and Daniel J. Jacob
Atmos. Chem. Phys., 17, 2543–2553, https://doi.org/10.5194/acp-17-2543-2017, https://doi.org/10.5194/acp-17-2543-2017, 2017
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Intercontinental atmospheric transport can disrupt local chemistry and cause air quality issues thousands of kilometers from the source, complicating correct attribution of air quality exceedances. This transport occurs in long, thin plumes which current-generation models consistently fail to reproduce. Our study investigates the cause of this failure, finding that greater vertical resolution than is currently available is required to reliably resolve the plumes and their effects.
Daniel J. Jacob, Alexander J. Turner, Joannes D. Maasakkers, Jianxiong Sheng, Kang Sun, Xiong Liu, Kelly Chance, Ilse Aben, Jason McKeever, and Christian Frankenberg
Atmos. Chem. Phys., 16, 14371–14396, https://doi.org/10.5194/acp-16-14371-2016, https://doi.org/10.5194/acp-16-14371-2016, 2016
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Methane is a greenhouse gas emitted by a range of natural and anthropogenic sources. Atmospheric methane has been measured continuously from space since 2003, and new instruments are planned to launch in the near future that will greatly expand the capabilities of space-based observations. We review the value of current, future, and proposed satellite observations to better quantify methane emissions from the global scale down to the scale of point sources.
Katherine R. Travis, Daniel J. Jacob, Jenny A. Fisher, Patrick S. Kim, Eloise A. Marais, Lei Zhu, Karen Yu, Christopher C. Miller, Robert M. Yantosca, Melissa P. Sulprizio, Anne M. Thompson, Paul O. Wennberg, John D. Crounse, Jason M. St. Clair, Ronald C. Cohen, Joshua L. Laughner, Jack E. Dibb, Samuel R. Hall, Kirk Ullmann, Glenn M. Wolfe, Illana B. Pollack, Jeff Peischl, Jonathan A. Neuman, and Xianliang Zhou
Atmos. Chem. Phys., 16, 13561–13577, https://doi.org/10.5194/acp-16-13561-2016, https://doi.org/10.5194/acp-16-13561-2016, 2016
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Ground-level ozone pollution in the Southeast US involves complex chemistry driven by anthropogenic emissions of nitrogen oxides (NOx) and biogenic emissions of isoprene. We find that US NOx emissions are overestimated nationally by as much as 50 % and that reducing model emissions by this amount results in good agreement with SEAC4RS aircraft measurements in August and September 2013. Observations of nitrate wet deposition fluxes and satellite NO2 columns further support this result.
Lei Zhu, Daniel J. Jacob, Patrick S. Kim, Jenny A. Fisher, Karen Yu, Katherine R. Travis, Loretta J. Mickley, Robert M. Yantosca, Melissa P. Sulprizio, Isabelle De Smedt, Gonzalo González Abad, Kelly Chance, Can Li, Richard Ferrare, Alan Fried, Johnathan W. Hair, Thomas F. Hanisco, Dirk Richter, Amy Jo Scarino, James Walega, Petter Weibring, and Glenn M. Wolfe
Atmos. Chem. Phys., 16, 13477–13490, https://doi.org/10.5194/acp-16-13477-2016, https://doi.org/10.5194/acp-16-13477-2016, 2016
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HCHO column data are widely used as a proxy for VOCs emissions, but validation of the data has been extremely limited. We use accurate aircraft observations to validate and intercompare 6 HCHO retrievals with GEOS-Chem as the intercomparison platform. Retrievals are interconsistent in spatial variability over the SE US and in daily variability, but are biased low by 20–51 %. Our work supports the use of HCHO column as a quantitative proxy for isoprene emission after correction of the low bias.
Tomás Sherwen, Johan A. Schmidt, Mat J. Evans, Lucy J. Carpenter, Katja Großmann, Sebastian D. Eastham, Daniel J. Jacob, Barbara Dix, Theodore K. Koenig, Roman Sinreich, Ivan Ortega, Rainer Volkamer, Alfonso Saiz-Lopez, Cristina Prados-Roman, Anoop S. Mahajan, and Carlos Ordóñez
Atmos. Chem. Phys., 16, 12239–12271, https://doi.org/10.5194/acp-16-12239-2016, https://doi.org/10.5194/acp-16-12239-2016, 2016
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We present a simulation of tropospheric Cl, Br, I chemistry within the GEOS-Chem CTM. We find a decrease in tropospheric ozone burden of 18.6 % and a 8.2 % decrease in global mean OH concentrations. Cl oxidation of some VOCs range from 15 to 27 % of the total loss. Bromine plays a small role in oxidising oVOCs. Surface ozone, ozone sondes, and methane lifetime are in general improved by the inclusion of halogens. We argue that simulated bromine and chlorine represent a lower limit.
Huiqun Wang, Gonzalo Gonzalez Abad, Xiong Liu, and Kelly Chance
Atmos. Chem. Phys., 16, 11379–11393, https://doi.org/10.5194/acp-16-11379-2016, https://doi.org/10.5194/acp-16-11379-2016, 2016
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Water vapor is highly important. The OMI total column water vapor product retrieved using SAO's version 1.0 algorithm agrees well with other reference products over the land but has a low bias over the ocean. The updated OMI water vapor product retrieved using SAO's version 2.1 algorithm largely eliminates the low bias over the ocean, improving the land/ocean consistency and the overall data quality. This dataset can benefit a variety of scientific studies and practical applications.
Juseon Bak, Xiong Liu, Jae H. Kim, Matthew T. Deland, and Kelly Chance
Atmos. Meas. Tech., 9, 4521–4531, https://doi.org/10.5194/amt-9-4521-2016, https://doi.org/10.5194/amt-9-4521-2016, 2016
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The main focus of this paper is improving an error of OMI nadir ozone profile retrievals due to the presence of polar mesospheric clouds (PMCs), consisting of small light-scattering particles at an altitude of 80–85 km. This error is shown to be systematic bias from ~ −2 at 2 hPa to ~ −20 % at 0.5 hPa and significantly correlated with brightness of PMCs. We reduce this interference of PMCs on ozone retrievals by including the PMC optical depth in the forward-model calculation and retrieval.
Gonzalo González Abad, Alexander Vasilkov, Colin Seftor, Xiong Liu, and Kelly Chance
Atmos. Meas. Tech., 9, 2797–2812, https://doi.org/10.5194/amt-9-2797-2016, https://doi.org/10.5194/amt-9-2797-2016, 2016
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The multi-spectral possibilities of the OMPS Nadir Mapper instrument are exploited here to perform formaldehyde retrievals. Orbiting the Earth at 824 km, OMPS observes the atmosphere in a time frame similar to instruments belonging to NASA's A-Train constellation, 01:30. We show that OMPS is well suited to measure formaldehyde despite its spectral resolution of 1nm. The comparison of OMPS retrievals with OMI products show good temporal correlation.
Caroline R. Nowlan, Xiong Liu, James W. Leitch, Kelly Chance, Gonzalo González Abad, Cheng Liu, Peter Zoogman, Joshua Cole, Thomas Delker, William Good, Frank Murcray, Lyle Ruppert, Daniel Soo, Melanie B. Follette-Cook, Scott J. Janz, Matthew G. Kowalewski, Christopher P. Loughner, Kenneth E. Pickering, Jay R. Herman, Melinda R. Beaver, Russell W. Long, James J. Szykman, Laura M. Judd, Paul Kelley, Winston T. Luke, Xinrong Ren, and Jassim A. Al-Saadi
Atmos. Meas. Tech., 9, 2647–2668, https://doi.org/10.5194/amt-9-2647-2016, https://doi.org/10.5194/amt-9-2647-2016, 2016
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The Geostationary Trace gas and Aerosol Sensor Optimization (GeoTASO) instrument is a remote sensing airborne instrument developed in support of future air quality satellite missions that will operate from geostationary orbit. GeoTASO flew in its first intensive field campaign during the DISCOVER-AQ 2013 Earth Venture Mission over Houston, Texas. This paper introduces the instrument and data analysis, and presents GeoTASO's first observations of NO2 at 250 m x 250 m spatial resolution.
Jenny A. Fisher, Daniel J. Jacob, Katherine R. Travis, Patrick S. Kim, Eloise A. Marais, Christopher Chan Miller, Karen Yu, Lei Zhu, Robert M. Yantosca, Melissa P. Sulprizio, Jingqiu Mao, Paul O. Wennberg, John D. Crounse, Alex P. Teng, Tran B. Nguyen, Jason M. St. Clair, Ronald C. Cohen, Paul Romer, Benjamin A. Nault, Paul J. Wooldridge, Jose L. Jimenez, Pedro Campuzano-Jost, Douglas A. Day, Weiwei Hu, Paul B. Shepson, Fulizi Xiong, Donald R. Blake, Allen H. Goldstein, Pawel K. Misztal, Thomas F. Hanisco, Glenn M. Wolfe, Thomas B. Ryerson, Armin Wisthaler, and Tomas Mikoviny
Atmos. Chem. Phys., 16, 5969–5991, https://doi.org/10.5194/acp-16-5969-2016, https://doi.org/10.5194/acp-16-5969-2016, 2016
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We use new airborne and ground-based observations from two summer 2013 campaigns in the southeastern US, interpreted with a chemical transport model, to understand the impact of isoprene and monoterpene chemistry on the atmospheric NOx budget via production of organic nitrates (RONO2). We find that a diversity of species contribute to observed RONO2. Our work implies that the NOx sink to RONO2 production is only sensitive to NOx emissions in regions where they are already low.
Karen Yu, Daniel J. Jacob, Jenny A. Fisher, Patrick S. Kim, Eloise A. Marais, Christopher C. Miller, Katherine R. Travis, Lei Zhu, Robert M. Yantosca, Melissa P. Sulprizio, Ron C. Cohen, Jack E. Dibb, Alan Fried, Tomas Mikoviny, Thomas B. Ryerson, Paul O. Wennberg, and Armin Wisthaler
Atmos. Chem. Phys., 16, 4369–4378, https://doi.org/10.5194/acp-16-4369-2016, https://doi.org/10.5194/acp-16-4369-2016, 2016
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Increasing the spatial resolution of a chemical transport model may improve simulations but can be computationally expensive. Using observations from the SEAC4RS aircraft campaign, we find that at higher spatial resolutions, models are better able to simulate the chemical pathways of ozone precursors, but the overall effect on regional mean concentrations is small. This implies that for continental boundary layer applications, coarse resolution models are adequate.
E. A. Marais, D. J. Jacob, J. L. Jimenez, P. Campuzano-Jost, D. A. Day, W. Hu, J. Krechmer, L. Zhu, P. S. Kim, C. C. Miller, J. A. Fisher, K. Travis, K. Yu, T. F. Hanisco, G. M. Wolfe, H. L. Arkinson, H. O. T. Pye, K. D. Froyd, J. Liao, and V. F. McNeill
Atmos. Chem. Phys., 16, 1603–1618, https://doi.org/10.5194/acp-16-1603-2016, https://doi.org/10.5194/acp-16-1603-2016, 2016
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Isoprene secondary organic aerosol (SOA) is a dominant aerosol component in the southeast US, but models routinely underestimate isoprene SOA with traditional schemes based on chamber studies operated under conditions not representative of isoprene-emitting forests. We develop a new irreversible uptake mechanism to reproduce isoprene SOA yields (3.3 %) and composition, and find a factor of 2 co-benefit of SO2 emission controls on reducing sulfate and organic aerosol in the southeast US.
H.-M. Lee, F. Paulot, D. K. Henze, K. Travis, D. J. Jacob, L. H. Pardo, and B. A. Schichtel
Atmos. Chem. Phys., 16, 525–540, https://doi.org/10.5194/acp-16-525-2016, https://doi.org/10.5194/acp-16-525-2016, 2016
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Sources of nitrogen deposition (Ndep) in Federal Class I areas in the US are investigated, identifying unique features in contributions from different species, sectors and locations. Ndep in many parks is impacted by emissions several hundred km away; the role of oxidized vs reduced sources varies regionally. Emissions reductions in the western US most effectively reduce the extent of areas in critical load exceedance, while reductions in the east most effectively reduce exceedance magnitudes.
U. Jeong, J. Kim, C. Ahn, O. Torres, X. Liu, P. K. Bhartia, R. J. D. Spurr, D. Haffner, K. Chance, and B. N. Holben
Atmos. Chem. Phys., 16, 177–193, https://doi.org/10.5194/acp-16-177-2016, https://doi.org/10.5194/acp-16-177-2016, 2016
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An aerosol retrieval and error analysis algorithm using OMI measurements based on an optimal-estimation method was developed in this study. The aerosol retrievals were validated using the DRAGON campaign products. The estimated errors of the retrievals represented the actual biases between retrieval and AERONET measurements well. The retrievals, with their estimated uncertainties, are expected to be valuable for relevant studies, such as trace gas retrieval and data assimilation.
W. Hewson, M. P. Barkley, G. Gonzalez Abad, H. Bösch, T. Kurosu, R. Spurr, and L. G. Tilstra
Atmos. Meas. Tech., 8, 4055–4074, https://doi.org/10.5194/amt-8-4055-2015, https://doi.org/10.5194/amt-8-4055-2015, 2015
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This work presents the air mass factor (AMF) algorithm in use at the University of Leicester, which introduces scene-specific variables into a per-observation full radiative transfer AMF calculation, including increasing spatial resolution of key environmental parameter databases, input variable area weighting, instrument-specific scattering weight calculation, and inclusion of an ozone vertical profile climatology.
J. Bak, X. Liu, J. H. Kim, M. T. Deland, and K. Chance
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acpd-15-25907-2015, https://doi.org/10.5194/acpd-15-25907-2015, 2015
Revised manuscript not accepted
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This work demonstrated the interference of tenuous PMCs on OMI ozone profile retrievals above 6hPa. The presence of PMCs leads to the systematic biases of -2% at 2hPa and -20% at 0.5hPa in OMI retrievals, which are significantly correlated with brightness of PMCs. We perform simultaneous retrievals of PMC optical depth with ozone using optimal estimation technique, to reduce the interference on ozone profile retrievals. As a result, the negative OMI biases are reduced to within ±10%.
P. S. Kim, D. J. Jacob, J. A. Fisher, K. Travis, K. Yu, L. Zhu, R. M. Yantosca, M. P. Sulprizio, J. L. Jimenez, P. Campuzano-Jost, K. D. Froyd, J. Liao, J. W. Hair, M. A. Fenn, C. F. Butler, N. L. Wagner, T. D. Gordon, A. Welti, P. O. Wennberg, J. D. Crounse, J. M. St. Clair, A. P. Teng, D. B. Millet, J. P. Schwarz, M. Z. Markovic, and A. E. Perring
Atmos. Chem. Phys., 15, 10411–10433, https://doi.org/10.5194/acp-15-10411-2015, https://doi.org/10.5194/acp-15-10411-2015, 2015
S. Hayashida, X. Liu, A. Ono, K. Yang, and K. Chance
Atmos. Chem. Phys., 15, 9865–9881, https://doi.org/10.5194/acp-15-9865-2015, https://doi.org/10.5194/acp-15-9865-2015, 2015
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The lower tropospheric ozone distribution maps were first obtained from the recent retrieval products of the Ozone Monitoring Instrument (OMI) onboard the Earth Observing System (EOS) Aura satellite. We found significant enhancement of ozone in the lower troposphere over central and eastern China (CEC), with Shandong Province as its center, and most notable in June in any given year. Similar seasonal variations were observed throughout the 9-year OMI measurement period of 2005 to 2013.
J. Kaiser, G. M. Wolfe, K. E. Min, S. S. Brown, C. C. Miller, D. J. Jacob, J. A. deGouw, M. Graus, T. F. Hanisco, J. Holloway, J. Peischl, I. B. Pollack, T. B. Ryerson, C. Warneke, R. A. Washenfelder, and F. N. Keutsch
Atmos. Chem. Phys., 15, 7571–7583, https://doi.org/10.5194/acp-15-7571-2015, https://doi.org/10.5194/acp-15-7571-2015, 2015
A. J. Turner and D. J. Jacob
Atmos. Chem. Phys., 15, 7039–7048, https://doi.org/10.5194/acp-15-7039-2015, https://doi.org/10.5194/acp-15-7039-2015, 2015
A. J. Turner, D. J. Jacob, K. J. Wecht, J. D. Maasakkers, E. Lundgren, A. E. Andrews, S. C. Biraud, H. Boesch, K. W. Bowman, N. M. Deutscher, M. K. Dubey, D. W. T. Griffith, F. Hase, A. Kuze, J. Notholt, H. Ohyama, R. Parker, V. H. Payne, R. Sussmann, C. Sweeney, V. A. Velazco, T. Warneke, P. O. Wennberg, and D. Wunch
Atmos. Chem. Phys., 15, 7049–7069, https://doi.org/10.5194/acp-15-7049-2015, https://doi.org/10.5194/acp-15-7049-2015, 2015
M. S. Long, R. Yantosca, J. E. Nielsen, C. A. Keller, A. da Silva, M. P. Sulprizio, S. Pawson, and D. J. Jacob
Geosci. Model Dev., 8, 595–602, https://doi.org/10.5194/gmd-8-595-2015, https://doi.org/10.5194/gmd-8-595-2015, 2015
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This paper presents results from the modularization of the GEOS-Chem chemical transport model, and its coupling as the chemical operator within the NASA-GMAO GEOS-5 Earth system model (ESM). The key findings are that chemistry within the modular GEOS-Chem system shows consistent, high strong-scaling properties across the range of distributed processors, transport is the limiting component prohibiting efficient scalability, and GEOS-Chem is able to generate suitable chemical results in an ESM.
C. Liu, X. Liu, M. G. Kowalewski, S. J. Janz, G. González Abad, K. E. Pickering, K. Chance, and L. N. Lamsal
Atmos. Meas. Tech., 8, 751–759, https://doi.org/10.5194/amt-8-751-2015, https://doi.org/10.5194/amt-8-751-2015, 2015
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We characterize the wavelengths and slit functions of Airborne Compact Atmospheric Mapper (ACAM) measurements in ~304--500 nm through the cross-correlation technique. It is necessary to account for atmospheric gas absorption and the ring effect. The derived broadened Gaussian slit functions agree very well with laboratory measurements. Trace gas retrieval comparisons demonstrate that the cross-correlation technique can be reliably used to characterize slit functions.
J. Bak, X. Liu, J. H. Kim, K. Chance, and D. P. Haffner
Atmos. Chem. Phys., 15, 667–683, https://doi.org/10.5194/acp-15-667-2015, https://doi.org/10.5194/acp-15-667-2015, 2015
G. González Abad, X. Liu, K. Chance, H. Wang, T. P. Kurosu, and R. Suleiman
Atmos. Meas. Tech., 8, 19–32, https://doi.org/10.5194/amt-8-19-2015, https://doi.org/10.5194/amt-8-19-2015, 2015
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We present and discuss the Smithsonian Astrophysical Observatory (SAO) formaldehyde retrieval algorithm for the Ozone Monitoring Instrument (OMI), which is the operational retrieval for NASA OMI H2CO.
C. Chan Miller, G. Gonzalez Abad, H. Wang, X. Liu, T. Kurosu, D. J. Jacob, and K. Chance
Atmos. Meas. Tech., 7, 3891–3907, https://doi.org/10.5194/amt-7-3891-2014, https://doi.org/10.5194/amt-7-3891-2014, 2014
K. J. Wecht, D. J. Jacob, M. P. Sulprizio, G. W. Santoni, S. C. Wofsy, R. Parker, H. Bösch, and J. Worden
Atmos. Chem. Phys., 14, 8173–8184, https://doi.org/10.5194/acp-14-8173-2014, https://doi.org/10.5194/acp-14-8173-2014, 2014
E. A. Marais, D. J. Jacob, A. Guenther, K. Chance, T. P. Kurosu, J. G. Murphy, C. E. Reeves, and H. O. T. Pye
Atmos. Chem. Phys., 14, 7693–7703, https://doi.org/10.5194/acp-14-7693-2014, https://doi.org/10.5194/acp-14-7693-2014, 2014
E. Hache, J.-L. Attié, C. Tourneur, P. Ricaud, L. Coret, W. A. Lahoz, L. El Amraoui, B. Josse, P. Hamer, J. Warner, X. Liu, K. Chance, M. Höpfner, R. Spurr, V. Natraj, S. Kulawik, A. Eldering, and J. Orphal
Atmos. Meas. Tech., 7, 2185–2201, https://doi.org/10.5194/amt-7-2185-2014, https://doi.org/10.5194/amt-7-2185-2014, 2014
C. A. Keller, M. S. Long, R. M. Yantosca, A. M. Da Silva, S. Pawson, and D. J. Jacob
Geosci. Model Dev., 7, 1409–1417, https://doi.org/10.5194/gmd-7-1409-2014, https://doi.org/10.5194/gmd-7-1409-2014, 2014
H. Wang, X. Liu, K. Chance, G. González Abad, and C. Chan Miller
Atmos. Meas. Tech., 7, 1901–1913, https://doi.org/10.5194/amt-7-1901-2014, https://doi.org/10.5194/amt-7-1901-2014, 2014
P. Zoogman, D. J. Jacob, K. Chance, X. Liu, M. Lin, A. Fiore, and K. Travis
Atmos. Chem. Phys., 14, 6261–6271, https://doi.org/10.5194/acp-14-6261-2014, https://doi.org/10.5194/acp-14-6261-2014, 2014
L. Zhang, D. J. Jacob, X. Yue, N. V. Downey, D. A. Wood, and D. Blewitt
Atmos. Chem. Phys., 14, 5295–5309, https://doi.org/10.5194/acp-14-5295-2014, https://doi.org/10.5194/acp-14-5295-2014, 2014
E. V. Fischer, D. J. Jacob, R. M. Yantosca, M. P. Sulprizio, D. B. Millet, J. Mao, F. Paulot, H. B. Singh, A. Roiger, L. Ries, R.W. Talbot, K. Dzepina, and S. Pandey Deolal
Atmos. Chem. Phys., 14, 2679–2698, https://doi.org/10.5194/acp-14-2679-2014, https://doi.org/10.5194/acp-14-2679-2014, 2014
J. P. Parrella, K. Chance, R. J. Salawitch, T. Canty, M. Dorf, and K. Pfeilsticker
Atmos. Meas. Tech., 6, 2549–2561, https://doi.org/10.5194/amt-6-2549-2013, https://doi.org/10.5194/amt-6-2549-2013, 2013
J. Cuesta, M. Eremenko, X. Liu, G. Dufour, Z. Cai, M. Höpfner, T. von Clarmann, P. Sellitto, G. Foret, B. Gaubert, M. Beekmann, J. Orphal, K. Chance, R. Spurr, and J.-M. Flaud
Atmos. Chem. Phys., 13, 9675–9693, https://doi.org/10.5194/acp-13-9675-2013, https://doi.org/10.5194/acp-13-9675-2013, 2013
P. S. Kim, D. J. Jacob, X. Liu, J. X. Warner, K. Yang, K. Chance, V. Thouret, and P. Nedelec
Atmos. Chem. Phys., 13, 9321–9335, https://doi.org/10.5194/acp-13-9321-2013, https://doi.org/10.5194/acp-13-9321-2013, 2013
J. Bak, X. Liu, J. C. Wei, L. L. Pan, K. Chance, and J. H. Kim
Atmos. Meas. Tech., 6, 2239–2254, https://doi.org/10.5194/amt-6-2239-2013, https://doi.org/10.5194/amt-6-2239-2013, 2013
J. Bak, J. H. Kim, X. Liu, K. Chance, and J. Kim
Atmos. Meas. Tech., 6, 239–249, https://doi.org/10.5194/amt-6-239-2013, https://doi.org/10.5194/amt-6-239-2013, 2013
J. Mao, S. Fan, D. J. Jacob, and K. R. Travis
Atmos. Chem. Phys., 13, 509–519, https://doi.org/10.5194/acp-13-509-2013, https://doi.org/10.5194/acp-13-509-2013, 2013
Related subject area
Subject: Gases | Research Activity: Remote Sensing | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
Satellite-observed relationships between land cover, burned area, and atmospheric composition over the southern Amazon
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Unleashing the Potential of Geostationary Satellite Observations in Air Quality Forecasting Through Artificial Intelligence Techniques
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Quantifying the diurnal variation in atmospheric NO2 from Geostationary Environment Monitoring Spectrometer (GEMS) observations
Global seasonal urban, industrial, and background NO2 estimated from TROPOMI satellite observations
Opinion: Beyond Global Means: Novel Space-Based Approaches to Indirectly Constrain the Concentrations, Trends, and Variations of Tropospheric Hydroxyl Radical (OH)
Ammonia in the upper troposphere–lower stratosphere (UTLS): GLORIA airborne measurements for CAMS model evaluation in the Asian monsoon and in biomass burning plumes above the South Atlantic
A lightweight NO2-to-NOx conversion model for quantifying NOx emissions of point sources from NO2 satellite observations
Towards a sector-specific CO∕CO2 emission ratio: satellite-based observations of CO release from steel production in Germany
Monitoring European anthropogenic NOx emissions from space
Upper tropospheric pollutants observed by MIPAS: geographic and seasonal variations
Comparing space-based to reported carbon monoxide emission estimates for Europe’s iron & steel plants
Vertical profiles of global tropospheric nitrogen dioxide (NO2) obtained by cloud-slicing TROPOMI
Opposite variations of peak and low ozone concentrations in eastern China: Positive effects of NOx control on ozone pollution
Pyrogenic HONO seen from space: insights from global IASI observations
First evaluation of the GEMS formaldehyde product against TROPOMI and ground-based column measurements during the in-orbit test period
High-resolution mapping of nitrogen oxide emissions in large US cities from TROPOMI retrievals of tropospheric nitrogen dioxide columns
Quantifying the tropospheric ozone radiative effect and its temporal evolution in the satellite era
Tropical upper tropospheric trends in ozone and carbon monoxide (2005–2020): observational and model results
A satellite chronology of plumes from the April 2021 eruption of La Soufrière, St Vincent
Investigation of spatial and temporal variability in lower tropospheric ozone from RAL Space UV–Vis satellite products
Two years of satellite-based carbon dioxide emission quantification at the world's largest coal-fired power plants
Tropical tropospheric ozone and carbon monoxide distributions: characteristics, origins, and control factors, as seen by IAGOS and IASI
Investigation of the summer 2018 European ozone air pollution episodes using novel satellite data and modelling
Bridging the spatial gaps of the Ammonia Monitoring Network using satellite ammonia measurements
A roadmap to estimating agricultural ammonia volatilization over Europe using satellite observations and simulation data
Investigation of meteorological conditions and BrO during ozone depletion events in Ny-Ålesund between 2010 and 2021
Quantification of carbon monoxide emissions from African cities using TROPOMI
Nitrogen oxides emissions from selected cities in North America, Europe, and East Asia observed by the TROPOspheric Monitoring Instrument (TROPOMI) before and after the COVID-19 pandemic
Remotely sensed and surface measurement- derived mass-conserving inversion of daily NOx emissions and inferred combustion technologies in energy-rich northern China
Examining TROPOMI formaldehyde to nitrogen dioxide ratios in the Lake Michigan region: implications for ozone exceedances
Impact of different sources of precursors on an ozone pollution outbreak over Europe analysed with IASI+GOME2 multispectral satellite observations and model simulations
Monitoring and quantifying CO2 emissions of isolated power plants from space
Technical note: Constraining the hydroxyl (OH) radical in the tropics with satellite observations of its drivers – first steps toward assessing the feasibility of a global observation strategy
Significant contribution of inland ships to the total NOx emissions along the Yangtze River
Characteristics of interannual variability in space-based XCO2 global observations
Toward a versatile spaceborne architecture for immediate monitoring of the global methane pledge
Methane emissions are predominantly responsible for record-breaking atmospheric methane growth rates in 2020 and 2021
Ground solar absorption observations of total column CO, CO2, CH4, and aerosol optical depth from California's Sequoia Lightning Complex Fire: emission factors and modified combustion efficiency at regional scales
Potential of TROPOMI for understanding spatio-temporal variations in surface NO2 and their dependencies upon land use over the Iberian Peninsula
Mobile MAX-DOAS observations of tropospheric NO2 and HCHO during summer over the Three Rivers' Source region in China
Estimating enhancement ratios of nitrogen dioxide, carbon monoxide and carbon dioxide using satellite observations
Source mechanisms and transport patterns of tropospheric bromine monoxide: findings from long-term multi-axis differential optical absorption spectroscopy measurements at two Antarctic stations
Measurement report: Spatiotemporal variability of peroxy acyl nitrates (PANs) over Mexico City from TES and CrIS satellite measurements
Biomass burning CO, PM and fuel consumption per unit burned area estimates derived across Africa using geostationary SEVIRI fire radiative power and Sentinel-5P CO data
Characterization of errors in satellite-based HCHO ∕ NO2 tropospheric column ratios with respect to chemistry, column-to-PBL translation, spatial representation, and retrieval uncertainties
Emma Sands, Richard J. Pope, Ruth M. Doherty, Fiona M. O'Connor, Chris Wilson, and Hugh Pumphrey
Atmos. Chem. Phys., 24, 11081–11102, https://doi.org/10.5194/acp-24-11081-2024, https://doi.org/10.5194/acp-24-11081-2024, 2024
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Changes in vegetation alongside biomass burning impact regional atmospheric composition and air quality. Using satellite remote sensing, we find a clear linear relationship between forest cover and isoprene and a pronounced non-linear relationship between burned area and nitrogen dioxide in the southern Amazon, a region of substantial deforestation. These quantified relationships can be used for model evaluation and further exploration of biosphere-atmosphere interactions in Earth System Models.
Jieying Ding, Ronald van der A, Henk Eskes, Enrico Dammers, Mark Shephard, Roy Wichink Kruit, Marc Guevara, and Leonor Tarrason
Atmos. Chem. Phys., 24, 10583–10599, https://doi.org/10.5194/acp-24-10583-2024, https://doi.org/10.5194/acp-24-10583-2024, 2024
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Here we applied the existing Daily Emissions Constrained by Satellite Observations (DECSO) inversion algorithm to NH3 observations from the CrIS satellite instrument to estimate NH3 emissions. As NH3 in the atmosphere is influenced by NOx, we implemented DECSO to estimate NOx and NH3 emissions simultaneously. The emissions are derived over Europe for 2020 at a spatial resolution of 0.2° using daily observations from CrIS and TROPOMI. Results are compared to bottom-up emission inventories.
Matthew S. Johnson, Sajeev Philip, Scott Meech, Rajesh Kumar, Meytar Sorek-Hamer, Yoichi P. Shiga, and Jia Jung
Atmos. Chem. Phys., 24, 10363–10384, https://doi.org/10.5194/acp-24-10363-2024, https://doi.org/10.5194/acp-24-10363-2024, 2024
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Satellites, like the Ozone Monitoring Instrument (OMI), retrieve proxy species of ozone (O3) formation (formaldehyde and nitrogen dioxide) and the ratios (FNRs) which can define O3 production sensitivity regimes. Here we investigate trends of OMI FNRs from 2005 to 2021, and they have increased in major cities, suggesting a transition from radical- to NOx-limited regimes. OMI also observed the impact of reduced emissions during the 2020 COVID-19 lockdown that resulted in increased FNRs.
Audrey Gaudel, Ilann Bourgeois, Meng Li, Kai-Lan Chang, Jerald Ziemke, Bastien Sauvage, Ryan M. Stauffer, Anne M. Thompson, Debra E. Kollonige, Nadia Smith, Daan Hubert, Arno Keppens, Juan Cuesta, Klaus-Peter Heue, Pepijn Veefkind, Kenneth Aikin, Jeff Peischl, Chelsea R. Thompson, Thomas B. Ryerson, Gregory J. Frost, Brian C. McDonald, and Owen R. Cooper
Atmos. Chem. Phys., 24, 9975–10000, https://doi.org/10.5194/acp-24-9975-2024, https://doi.org/10.5194/acp-24-9975-2024, 2024
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The study examines tropical tropospheric ozone changes. In situ data from 1994–2019 display increased ozone, notably over India, Southeast Asia, and Malaysia and Indonesia. Sparse in situ data limit trend detection for the 15-year period. In situ and satellite data, with limited sampling, struggle to consistently detect trends. Continuous observations are vital over the tropical Pacific Ocean, Indian Ocean, western Africa, and South Asia for accurate ozone trend estimation in these regions.
Naveed Ahmad, Changqing Lin, Alexis K. H. Lau, Jhoon Kim, Tianshu Zhang, Fangqun Yu, Chengcai Li, Ying Li, Jimmy C. H. Fung, and Xiang Qian Lao
Atmos. Chem. Phys., 24, 9645–9665, https://doi.org/10.5194/acp-24-9645-2024, https://doi.org/10.5194/acp-24-9645-2024, 2024
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This study developed a nested machine learning model to convert the GEMS NO2 column measurements into ground-level concentrations across China. The model directly incorporates the NO2 mixing height (NMH) into the methodological framework. The study underscores the importance of considering NMH when estimating ground-level NO2 from satellite column measurements and highlights the significant advantages of new-generation geostationary satellites in air quality monitoring.
Chengxin Zhang, Xinhan Niu, Hongyu Wu, Zhipeng Ding, Ka Lok Chan, Jhoon Kim, Thomas Wagner, and Cheng Liu
EGUsphere, https://doi.org/10.5194/egusphere-2024-2620, https://doi.org/10.5194/egusphere-2024-2620, 2024
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This research utilizes hourly air pollution observations from the world’s first geostationary satellite to develop a spatiotemporal neural network model for full-coverage surface NO2 pollution prediction over the next 24 hours, achieving outstanding forecasting performance and efficacy. These results highlight the profound impact of geostationary satellite observations in advancing air quality forecasting models, thereby contributing to future models for health exposure to air pollution.
Richard J. Pope, Fiona M. O'Connor, Mohit Dalvi, Brian J. Kerridge, Richard Siddans, Barry G. Latter, Brice Barret, Eric Le Flochmoen, Anne Boynard, Martyn P. Chipperfield, Wuhu Feng, Matilda A. Pimlott, Sandip S. Dhomse, Christian Retscher, Catherine Wespes, and Richard Rigby
Atmos. Chem. Phys., 24, 9177–9195, https://doi.org/10.5194/acp-24-9177-2024, https://doi.org/10.5194/acp-24-9177-2024, 2024
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Ozone is a potent air pollutant in the lower troposphere, with adverse impacts on human health. Satellite records of tropospheric ozone currently show large-scale inconsistencies in long-term trends. Our detailed study of the potential factors (e.g. satellite errors, where the satellite can observe ozone) potentially driving these inconsistencies found that, in North America, Europe, and East Asia, the underlying trends are typically small with large uncertainties.
David P. Edwards, Sara Martínez-Alonso, Duseong S. Jo, Ivan Ortega, Louisa K. Emmons, John J. Orlando, Helen M. Worden, Jhoon Kim, Hanlim Lee, Junsung Park, and Hyunkee Hong
Atmos. Chem. Phys., 24, 8943–8961, https://doi.org/10.5194/acp-24-8943-2024, https://doi.org/10.5194/acp-24-8943-2024, 2024
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Until recently, satellite observations of atmospheric pollutants at any location could only be obtained once a day. New geostationary satellites stare at a region of the Earth to make hourly measurements, and the Geostationary Environment Monitoring Spectrometer is the first looking at Asia. These data and model simulations show how the change seen for one important pollutant that determines air quality depends on a combination of pollution emissions, atmospheric chemistry, and meteorology.
Vitali Fioletov, Chris A. McLinden, Debora Griffin, Xiaoyi Zhao, and Henk Eskes
EGUsphere, https://doi.org/10.5194/egusphere-2024-1991, https://doi.org/10.5194/egusphere-2024-1991, 2024
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Satellite data were used to estimate urban per capita emissions for 261 major cities worldwide. Three components in tropospheric NO2 data: background NO2, NO2 from urban sources, and from industrial point sources were isolated and then each of these components was analyzed separately. The largest per capita emissions were found at the Middle East and the smallest were in India and South Africa. Urban weekend emissions are 20 %–50 % less than workday emissions for all regions except China.
Bryan Duncan, Daniel Anderson, Arlene Fiore, Joanna Joiner, Nickolay Krotkov, Can Li, Dylan Millet, Julie Nicely, Luke Oman, Jason St. Clair, Joshua Shutter, Amir Souri, Sarah Strode, Brad Weir, Glenn Wolfe, Helen Worden, and Qindan Zhu
EGUsphere, https://doi.org/10.5194/egusphere-2024-2331, https://doi.org/10.5194/egusphere-2024-2331, 2024
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Trace gases emitted to or formed within the atmosphere may be chemically or physically removed from the atmosphere. One trace gas, the hydroxyl radical (OH), is responsible for initiating the chemical removal of many trace gases, including some climate gases. Despite its importance, scientists have not been able to adequately measure OH. In this opinion piece, we discuss promising new methods to indirectly constrain OH using satellite data of trace gases that control the abundance of OH.
Sören Johansson, Michael Höpfner, Felix Friedl-Vallon, Norbert Glatthor, Thomas Gulde, Vincent Huijnen, Anne Kleinert, Erik Kretschmer, Guido Maucher, Tom Neubert, Hans Nordmeyer, Christof Piesch, Peter Preusse, Martin Riese, Björn-Martin Sinnhuber, Jörn Ungermann, Gerald Wetzel, and Wolfgang Woiwode
Atmos. Chem. Phys., 24, 8125–8138, https://doi.org/10.5194/acp-24-8125-2024, https://doi.org/10.5194/acp-24-8125-2024, 2024
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We present airborne infrared limb sounding GLORIA measurements of ammonia (NH3) in the upper troposphere of air masses within the Asian monsoon and of those connected with biomass burning. Comparing CAMS (Copernicus Atmosphere Monitoring Service) model data, we find that the model reproduces the measured enhanced NH3 within the Asian monsoon well but not that within biomass burning plumes, where no enhanced NH3 is measured in the upper troposphere but considerable amounts are simulated by CAMS.
Sandro Meier, Erik F. M. Koene, Maarten Krol, Dominik Brunner, Alexander Damm, and Gerrit Kuhlmann
Atmos. Chem. Phys., 24, 7667–7686, https://doi.org/10.5194/acp-24-7667-2024, https://doi.org/10.5194/acp-24-7667-2024, 2024
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Nitrogen oxides (NOx = NO + NO2) are important air pollutants. This study addresses the challenge of accurately estimating NOx emissions from NO2 satellite observations. We develop a realistic model to convert NO2 to NOx by using simulated plumes from various power plants. We apply the model to satellite NO2 observations, significantly reducing biases in estimated NOx emissions. The study highlights the potential for a consistent, high-resolution estimation of NOx emissions using satellite data.
Oliver Schneising, Michael Buchwitz, Maximilian Reuter, Michael Weimer, Heinrich Bovensmann, John P. Burrows, and Hartmut Bösch
Atmos. Chem. Phys., 24, 7609–7621, https://doi.org/10.5194/acp-24-7609-2024, https://doi.org/10.5194/acp-24-7609-2024, 2024
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Large quantities of CO and CO2 are emitted during conventional steel production. As satellite-based estimates of CO2 emissions at the facility level are challenging, co-emitted CO can indicate the carbon footprint of steel plants. We estimate CO emissions for German steelworks and use CO2 emissions from emissions trading data to derive a sector-specific CO/CO2 emission ratio for the steel industry; it is a prerequisite to use CO as a proxy for CO2 emissions from similar steel production sites.
Ronald J. van der A, Jieying Ding, and Henk Eskes
Atmos. Chem. Phys., 24, 7523–7534, https://doi.org/10.5194/acp-24-7523-2024, https://doi.org/10.5194/acp-24-7523-2024, 2024
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Using observations of the Sentinel-5P satellite and the latest version of the inversion algorithm DECSO, anthropogenic NOx emissions are derived for Europe for the years 2019–2022 with a spatial resolution of 0.2°. The results are compared with European emissions of the Copernicus Atmosphere Monitoring Service.
Norbert Glatthor, Gabriele P. Stiller, Thomas von Clarmann, Bernd Funke, Sylvia Kellmann, and Andrea Linden
EGUsphere, https://doi.org/10.5194/egusphere-2024-1793, https://doi.org/10.5194/egusphere-2024-1793, 2024
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We present global upper tropospheric distributions of the pollutants HCN, CO, C2H2, C2H6, PAN and HCOOH, observed by MIPAS/Envisat between 2002 and 2012. This common view allows conclusions on the sources of the different pollutants, like, e.g., biomass burning, anthropogenic sources or biogenic release. For this purpose we compare their VMR distributions and additionally perform global correlation and regression analyses.
Gijs Leguijt, Joannes D. Maasakkers, Hugo A. C. Denier van der Gon, Arjo J. Segers, Tobias Borsdorff, Ivar R. van der Velde, and Ilse Aben
EGUsphere, https://doi.org/10.5194/egusphere-2024-1561, https://doi.org/10.5194/egusphere-2024-1561, 2024
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The production of steel coincides with large emissions of greenhouse gases and air pollutants including carbon monoxide. European facilities are required to report their emissions, which are estimated using a variety of methods. We evaluate these estimates using carbon monoxide concentrations measured using a satellite. We find generally good agreement between our values and those reported but also identify some uncertainties, showing that satellites can provide insights on these emissions.
Rebekah P. Horner, Eloise A. Marais, Nana Wei, Robert G. Ryan, and Viral Shah
EGUsphere, https://doi.org/10.5194/egusphere-2024-1541, https://doi.org/10.5194/egusphere-2024-1541, 2024
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Nitrogen oxides (NOx ≡ NO + NO2) affect tropospheric ozone and the hydroxyl radical, influencing climate and atmospheric oxidation. To address the lack of routine observations of NOx, we cloud-slice satellite observations of NO2 to derive a new dataset of global vertical profiles of NO2. We evaluate our data against in-situ aircraft observations and use our data to critique contemporary knowledge of tropospheric NOx as simulated with the GEOS-Chem model.
Zhuang Wang, Chune Shi, Hao Zhang, Xianguang Ji, Yizhi Zhu, Congzi Xia, Xiaoyun Sun, Xinfeng Lin, Shaowei Yan, Suyao Wang, Yuan Zhou, Chengzhi Xing, Yujia Chen, and Cheng Liu
EGUsphere, https://doi.org/10.5194/egusphere-2024-341, https://doi.org/10.5194/egusphere-2024-341, 2024
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This study attempts to explain the surface ozone background, typical, and peak trends in eastern China by combining a large amount of ground–based and satellite observations, and found substantial reductions in nitrogen oxides emissions have diametrically opposed effects on peak (decreasing) and low (increasing) ozone concentrations.
Bruno Franco, Lieven Clarisse, Nicolas Theys, Juliette Hadji-Lazaro, Cathy Clerbaux, and Pierre Coheur
Atmos. Chem. Phys., 24, 4973–5007, https://doi.org/10.5194/acp-24-4973-2024, https://doi.org/10.5194/acp-24-4973-2024, 2024
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Using IASI global infrared measurements, we retrieve nitrous acid (HONO) in fire plumes from space. We detect large enhancements of pyrogenic HONO worldwide, especially from intense wildfires at Northern Hemisphere mid- and high latitudes. Predominance of IASI nighttime over daytime measurements sheds light on HONO's extended lifetime and secondary formation during long-range transport in smoke plumes. Our findings deepen the understanding of atmospheric HONO, crucial for air quality assessment.
Gitaek T. Lee, Rokjin J. Park, Hyeong-Ahn Kwon, Eunjo S. Ha, Sieun D. Lee, Seunga Shin, Myoung-Hwan Ahn, Mina Kang, Yong-Sang Choi, Gyuyeon Kim, Dong-Won Lee, Deok-Rae Kim, Hyunkee Hong, Bavo Langerock, Corinne Vigouroux, Christophe Lerot, Francois Hendrick, Gaia Pinardi, Isabelle De Smedt, Michel Van Roozendael, Pucai Wang, Heesung Chong, Yeseul Cho, and Jhoon Kim
Atmos. Chem. Phys., 24, 4733–4749, https://doi.org/10.5194/acp-24-4733-2024, https://doi.org/10.5194/acp-24-4733-2024, 2024
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This study evaluates the Geostationary Environment Monitoring Spectrometer (GEMS) HCHO product by comparing its vertical column densities (VCDs) with those of TROPOMI and ground-based observations. Based on some sensitivity tests, obtaining radiance references under clear-sky conditions significantly improves HCHO retrieval quality. GEMS HCHO VCDs captured seasonal and diurnal variations well during the first year of observation, showing consistency with TROPOMI and ground-based observations.
Fei Liu, Steffen Beirle, Joanna Joiner, Sungyeon Choi, Zhining Tao, K. Emma Knowland, Steven J. Smith, Daniel Q. Tong, Siqi Ma, Zachary T. Fasnacht, and Thomas Wagner
Atmos. Chem. Phys., 24, 3717–3728, https://doi.org/10.5194/acp-24-3717-2024, https://doi.org/10.5194/acp-24-3717-2024, 2024
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Using satellite data, we developed a coupled method independent of the chemical transport model to map NOx emissions across US cities. After validating our technique with synthetic data, we charted NOx emissions from 2018–2021 in 39 cities. Our results closely matched EPA estimates but also highlighted some inconsistencies in both magnitude and spatial distribution. This research can help refine strategies for monitoring and managing air quality.
Richard J. Pope, Alexandru Rap, Matilda A. Pimlott, Brice Barret, Eric Le Flochmoen, Brian J. Kerridge, Richard Siddans, Barry G. Latter, Lucy J. Ventress, Anne Boynard, Christian Retscher, Wuhu Feng, Richard Rigby, Sandip S. Dhomse, Catherine Wespes, and Martyn P. Chipperfield
Atmos. Chem. Phys., 24, 3613–3626, https://doi.org/10.5194/acp-24-3613-2024, https://doi.org/10.5194/acp-24-3613-2024, 2024
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Tropospheric ozone is an important short-lived climate forcer which influences the incoming solar short-wave radiation and the outgoing long-wave radiation in the atmosphere (8–15 km) where the balance between the two yields a net positive (i.e. warming) effect at the surface. Overall, we find that the tropospheric ozone radiative effect ranges between 1.21 and 1.26 W m−2 with a negligible trend (2008–2017), suggesting that tropospheric ozone influences on climate have remained stable with time.
Lucien Froidevaux, Douglas E. Kinnison, Benjamin Gaubert, Michael J. Schwartz, Nathaniel J. Livesey, William G. Read, Charles G. Bardeen, Jerry R. Ziemke, and Ryan A. Fuller
EGUsphere, https://doi.org/10.5194/egusphere-2024-525, https://doi.org/10.5194/egusphere-2024-525, 2024
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We compare observed changes in ozone (O3) and carbon monoxide (CO) in the tropical upper troposphere (10–15 km altitude) for 2005–2020 to predictions from model simulations that track the evolution of natural and industrial emissions transported to this region. An increasing trend in measured upper tropospheric O3 is generally well matched by the model trends. We also find that changes in modeled industrial CO surface emissions lead to better model agreement with observed decreasing CO trends.
Isabelle A. Taylor, Roy G. Grainger, Andrew T. Prata, Simon R. Proud, Tamsin A. Mather, and David M. Pyle
Atmos. Chem. Phys., 23, 15209–15234, https://doi.org/10.5194/acp-23-15209-2023, https://doi.org/10.5194/acp-23-15209-2023, 2023
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This study looks at sulfur dioxide (SO2) and ash emissions from the April 2021 eruption of La Soufrière on St Vincent. Using satellite data, 35 eruptive events were identified. Satellite data were used to track SO2 as it was transported around the globe. The majority of SO2 was emitted into the upper troposphere and lower stratosphere. Similarities with the 1979 eruption of La Soufrière highlight the value of studying these eruptions to be better prepared for future eruptions.
Richard J. Pope, Brian J. Kerridge, Richard Siddans, Barry G. Latter, Martyn P. Chipperfield, Wuhu Feng, Matilda A. Pimlott, Sandip S. Dhomse, Christian Retscher, and Richard Rigby
Atmos. Chem. Phys., 23, 14933–14947, https://doi.org/10.5194/acp-23-14933-2023, https://doi.org/10.5194/acp-23-14933-2023, 2023
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Ozone is a potent air pollutant, and we present the first study to investigate long-term changes in lower tropospheric column ozone (LTCO3) from space. We have constructed a merged LTCO3 dataset from GOME-1, SCIAMACHY and OMI between 1996 and 2017. Comparing LTCO3 between the 1996–2000 and 2013–2017 5-year averages, we find significant positive increases in the tropics/sub-tropics, while in the northern mid-latitudes, we find small-scale differences.
Daniel H. Cusworth, Andrew K. Thorpe, Charles E. Miller, Alana K. Ayasse, Ralph Jiorle, Riley M. Duren, Ray Nassar, Jon-Paul Mastrogiacomo, and Robert R. Nelson
Atmos. Chem. Phys., 23, 14577–14591, https://doi.org/10.5194/acp-23-14577-2023, https://doi.org/10.5194/acp-23-14577-2023, 2023
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Carbon dioxide (CO2) emissions from combustion sources are uncertain in many places across the globe. Satellites have the ability to detect and quantify emissions from large CO2 point sources, including coal-fired power plants. In this study, we tasked two satellites to routinely observe CO2 emissions at 30 coal-fired power plants between 2021 and 2022. These results present the largest dataset of space-based CO2 emission estimates to date.
Maria Tsivlidou, Bastien Sauvage, Yasmine Bennouna, Romain Blot, Damien Boulanger, Hannah Clark, Eric Le Flochmoën, Philippe Nédélec, Valérie Thouret, Pawel Wolff, and Brice Barret
Atmos. Chem. Phys., 23, 14039–14063, https://doi.org/10.5194/acp-23-14039-2023, https://doi.org/10.5194/acp-23-14039-2023, 2023
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The tropics are a region where the ozone increase has been most apparent since 1980 and where observations are sparse. Using aircraft, satellite, and model data, we document the characteristics of tropospheric ozone and CO over the whole tropics for the last 2 decades. We explore the origin of the observed CO anomalies and investigate transport processes driving the tropical CO and O3 distribution. Our study highlights the importance of anthropogenic emissions, mostly over the northern tropics.
Richard J. Pope, Brian J. Kerridge, Martyn P. Chipperfield, Richard Siddans, Barry G. Latter, Lucy J. Ventress, Matilda A. Pimlott, Wuhu Feng, Edward Comyn-Platt, Garry D. Hayman, Stephen R. Arnold, and Ailish M. Graham
Atmos. Chem. Phys., 23, 13235–13253, https://doi.org/10.5194/acp-23-13235-2023, https://doi.org/10.5194/acp-23-13235-2023, 2023
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In the summer of 2018, Europe experienced several persistent large-scale ozone (O3) pollution episodes. Satellite tropospheric O3 and surface O3 data recorded substantial enhancements in 2018 relative to other years. Targeted model simulations showed that meteorological processes and emissions controlled the elevated surface O3, while mid-tropospheric O3 enhancements were dominated by stratospheric O3 intrusion and advection of North Atlantic O3-rich air masses into Europe.
Rui Wang, Da Pan, Xuehui Guo, Kang Sun, Lieven Clarisse, Martin Van Damme, Pierre-François Coheur, Cathy Clerbaux, Melissa Puchalski, and Mark A. Zondlo
Atmos. Chem. Phys., 23, 13217–13234, https://doi.org/10.5194/acp-23-13217-2023, https://doi.org/10.5194/acp-23-13217-2023, 2023
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Ammonia (NH3) is a key precursor for fine particulate matter (PM2.5) and a primary form of reactive nitrogen, yet it has sparse ground measurements. We perform the first comprehensive comparison between ground observations and satellite retrievals in the US, demonstrating that satellite NH3 data can help fill spatial gaps in the current ground monitoring networks. Trend analyses using both datasets highlight increasing NH3 trends across the US, including the NH3 hotspots and urban areas.
Rimal Abeed, Camille Viatte, William C. Porter, Nikolaos Evangeliou, Cathy Clerbaux, Lieven Clarisse, Martin Van Damme, Pierre-François Coheur, and Sarah Safieddine
Atmos. Chem. Phys., 23, 12505–12523, https://doi.org/10.5194/acp-23-12505-2023, https://doi.org/10.5194/acp-23-12505-2023, 2023
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Ammonia emissions from agricultural activities will inevitably increase with the rise in population. We use a variety of datasets (satellite, reanalysis, and model simulation) to calculate the first regional map of ammonia emission potential during the start of the growing season in Europe. We then apply our developed method using a climate model to show the effect of the temperature increase on future ammonia columns under two possible climate scenarios.
Bianca Zilker, Andreas Richter, Anne-Marlene Blechschmidt, Peter von der Gathen, Ilias Bougoudis, Sora Seo, Tim Bösch, and John Philip Burrows
Atmos. Chem. Phys., 23, 9787–9814, https://doi.org/10.5194/acp-23-9787-2023, https://doi.org/10.5194/acp-23-9787-2023, 2023
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During Arctic spring, near-surface ozone is depleted by bromine released from salty sea ice and/or snow-covered areas under certain meteorological conditions. To study this ozone depletion and the prevailing meteorological conditions, two ozone data sets from Ny-Ålesund, Svalbard, have been evaluated. We found that during ozone depletion events lower pressure over the Barents Sea and higher pressure in the Icelandic Low area led to a transport of cold polar air from the north to Ny-Ålesund.
Gijs Leguijt, Joannes D. Maasakkers, Hugo A. C. Denier van der Gon, Arjo J. Segers, Tobias Borsdorff, and Ilse Aben
Atmos. Chem. Phys., 23, 8899–8919, https://doi.org/10.5194/acp-23-8899-2023, https://doi.org/10.5194/acp-23-8899-2023, 2023
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We present a fast method to evaluate carbon monoxide emissions from cities in Africa. Carbon monoxide is important for climate change in an indirect way, as it is linked to ozone, methane, and carbon dioxide. Our measurements are made with a satellite that sees the entire globe every single day. This means that we can check from space whether the current knowledge of emission rates is up to date. We make the comparison and show that the emission rates in northern Africa are underestimated.
Chantelle R. Lonsdale and Kang Sun
Atmos. Chem. Phys., 23, 8727–8748, https://doi.org/10.5194/acp-23-8727-2023, https://doi.org/10.5194/acp-23-8727-2023, 2023
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The COVID-19 pandemic, which was caused by the SARS-CoV-2 virus, emerged in 2019, and its still evolving variants have resulted in unprecedented shifts in human activities and anthropogenic emissions into the Earth's atmosphere. We present monthly nitrogen oxide emissions over three major continents from May 2018 to January 2023 to capture variations before and after the COVID-19 pandemic. We focus on a diverse collection of 54 cities to quantify the post-COVID-19 perturbations.
Xiaolu Li, Jason Blake Cohen, Kai Qin, Hong Geng, Xiaohui Wu, Liling Wu, Chengli Yang, Rui Zhang, and Liqin Zhang
Atmos. Chem. Phys., 23, 8001–8019, https://doi.org/10.5194/acp-23-8001-2023, https://doi.org/10.5194/acp-23-8001-2023, 2023
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Remotely sensed NO2 and surface NOx are combined with a mathematical method to estimate daily NOx emissions. The results identify new sources and improve existing estimates. The estimation is driven by three flexible factors: thermodynamics of combustion, chemical loss, and atmospheric transport. The thermodynamic term separates power, iron, and cement from coking, boilers, and aluminum. This work finds three causes for the extremes: emissions, UV radiation, and transport.
Juanito Jerrold Mariano Acdan, Robert Bradley Pierce, Angela F. Dickens, Zachariah Adelman, and Tsengel Nergui
Atmos. Chem. Phys., 23, 7867–7885, https://doi.org/10.5194/acp-23-7867-2023, https://doi.org/10.5194/acp-23-7867-2023, 2023
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Ozone is an air pollutant that is harmful to human health. Near the surface of Earth, ozone is created when other pollutants react in the presence of sunlight. This study uses satellite data to investigate how ozone levels can be decreased in the Lake Michigan region of the United States. Our results indicate that ozone levels can be decreased by decreasing volatile organic compound emissions in urban areas and decreasing nitrogen oxide emissions in the region as a whole.
Sachiko Okamoto, Juan Cuesta, Matthias Beekmann, Gaëlle Dufour, Maxim Eremenko, Kazuyuki Miyazaki, Cathy Boonne, Hiroshi Tanimoto, and Hajime Akimoto
Atmos. Chem. Phys., 23, 7399–7423, https://doi.org/10.5194/acp-23-7399-2023, https://doi.org/10.5194/acp-23-7399-2023, 2023
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We present a detailed analysis of the daily evolution of the lowermost tropospheric ozone documented by IASI+GOME2 multispectral satellite observations and that of its precursors from TCR-2 tropospheric chemistry reanalysis. It reveals that the ozone outbreak across Europe in July 2017 was produced during favorable condition for photochemical production of ozone and was associated with multiple sources of ozone precursors: biogenic, anthropogenic, and biomass burning emissions.
Xiaojuan Lin, Ronald van der A, Jos de Laat, Henk Eskes, Frédéric Chevallier, Philippe Ciais, Zhu Deng, Yuanhao Geng, Xuanren Song, Xiliang Ni, Da Huo, Xinyu Dou, and Zhu Liu
Atmos. Chem. Phys., 23, 6599–6611, https://doi.org/10.5194/acp-23-6599-2023, https://doi.org/10.5194/acp-23-6599-2023, 2023
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Satellite observations provide evidence for CO2 emission signals from isolated power plants. We use these satellite observations to quantify emissions. We found that for power plants with multiple observations, the correlation of estimated and reported emissions is significantly improved compared to a single observation case. This demonstrates that accurate estimation of power plant emissions can be achieved by monitoring from future satellite missions with more frequent observations.
Daniel C. Anderson, Bryan N. Duncan, Julie M. Nicely, Junhua Liu, Sarah A. Strode, and Melanie B. Follette-Cook
Atmos. Chem. Phys., 23, 6319–6338, https://doi.org/10.5194/acp-23-6319-2023, https://doi.org/10.5194/acp-23-6319-2023, 2023
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We describe a methodology that combines machine learning, satellite observations, and 3D chemical model output to infer the abundance of the hydroxyl radical (OH), a chemical that removes many trace gases from the atmosphere. The methodology successfully captures the variability of observed OH, although further observations are needed to evaluate absolute accuracy. Current satellite observations are of sufficient quality to infer OH, but retrieval validation in the remote tropics is needed.
Xiumei Zhang, Ronald van der A, Jieying Ding, Xin Zhang, and Yan Yin
Atmos. Chem. Phys., 23, 5587–5604, https://doi.org/10.5194/acp-23-5587-2023, https://doi.org/10.5194/acp-23-5587-2023, 2023
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We compiled a ship emission inventory based on automatic identification system (AIS) signals in the Jiangsu section of the Yangtze River. This ship emission inventory was compared with Chinese bottom-up inventories and the satellite-derived emissions from TROPOMI. The result shows a consistent spatial distribution, with riverine cities having high NOx emissions. Inland ship emissions of NOx are shown to contribute at least 40 % to air pollution along the river.
Yifan Guan, Gretchen Keppel-Aleks, Scott C. Doney, Christof Petri, Dave Pollard, Debra Wunch, Frank Hase, Hirofumi Ohyama, Isamu Morino, Justus Notholt, Kei Shiomi, Kim Strong, Rigel Kivi, Matthias Buschmann, Nicholas Deutscher, Paul Wennberg, Ralf Sussmann, Voltaire A. Velazco, and Yao Té
Atmos. Chem. Phys., 23, 5355–5372, https://doi.org/10.5194/acp-23-5355-2023, https://doi.org/10.5194/acp-23-5355-2023, 2023
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We characterize spatial–temporal patterns of interannual variability (IAV) in atmospheric CO2 based on NASA’s Orbiting Carbon Observatory-2 (OCO-2). CO2 variation is strongly impacted by climate events, with higher anomalies during El Nino years. We show high correlation in IAV between space-based and ground-based CO2 from long-term sites. Because OCO-2 has near-global coverage, our paper provides a roadmap to study IAV where in situ observation is sparse, such as open oceans and remote lands.
Yuchen Wang, Xvli Guo, Yajie Huo, Mengying Li, Yuqing Pan, Shaocai Yu, Alexander Baklanov, Daniel Rosenfeld, John H. Seinfeld, and Pengfei Li
Atmos. Chem. Phys., 23, 5233–5249, https://doi.org/10.5194/acp-23-5233-2023, https://doi.org/10.5194/acp-23-5233-2023, 2023
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Substantial advances have been made in recent years toward detecting and quantifying methane super-emitters from space. However, such advances have rarely been expanded to measure the global methane pledge because large-scale swaths and high-resolution sampling have not been coordinated. Here we present a versatile spaceborne architecture that can juggle planet-scale and plant-level methane retrievals, challenge official emission reports, and remain relevant for stereoscopic measurements.
Liang Feng, Paul I. Palmer, Robert J. Parker, Mark F. Lunt, and Hartmut Bösch
Atmos. Chem. Phys., 23, 4863–4880, https://doi.org/10.5194/acp-23-4863-2023, https://doi.org/10.5194/acp-23-4863-2023, 2023
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Our understanding of recent changes in atmospheric methane has defied explanation. Since 2007, the atmospheric growth of methane has accelerated to record-breaking values in 2020 and 2021. We use satellite observations of methane to show that (1) increasing emissions over the tropics are mostly responsible for these recent atmospheric changes, and (2) changes in the OH sink during the 2020 Covid-19 lockdown can explain up to 34% of changes in atmospheric methane for that year.
Isis Frausto-Vicencio, Sajjan Heerah, Aaron G. Meyer, Harrison A. Parker, Manvendra Dubey, and Francesca M. Hopkins
Atmos. Chem. Phys., 23, 4521–4543, https://doi.org/10.5194/acp-23-4521-2023, https://doi.org/10.5194/acp-23-4521-2023, 2023
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Wildfires are increasing in the western USA, making it critical to understand the impacts of greenhouse gases and air pollutants on the atmosphere. We used a ground-based remote sensing technique to measure the greenhouse gases and aerosol in the atmosphere. We isolate a large smoke plume from a nearby wildfire and calculate variables to understand the fuel properties and combustion phases. We find that a significant amount of methane is emitted from the 2020 California wildfire season.
Hervé Petetin, Marc Guevara, Steven Compernolle, Dene Bowdalo, Pierre-Antoine Bretonnière, Santiago Enciso, Oriol Jorba, Franco Lopez, Albert Soret, and Carlos Pérez García-Pando
Atmos. Chem. Phys., 23, 3905–3935, https://doi.org/10.5194/acp-23-3905-2023, https://doi.org/10.5194/acp-23-3905-2023, 2023
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This study analyses the potential of the TROPOMI space sensor for monitoring the variability of NO2 pollution over the Iberian Peninsula. A reduction of NO2 levels is observed during the weekend and in summer, especially over most urbanized areas, in agreement with surface observations. An enhancement of NO2 is found during summer with TROPOMI over croplands, potentially related to natural soil NO emissions, which illustrates the outstanding value of TROPOMI for complementing surface networks.
Siyang Cheng, Xinghong Cheng, Jianzhong Ma, Xiangde Xu, Wenqian Zhang, Jinguang Lv, Gang Bai, Bing Chen, Siying Ma, Steffen Ziegler, Sebastian Donner, and Thomas Wagner
Atmos. Chem. Phys., 23, 3655–3677, https://doi.org/10.5194/acp-23-3655-2023, https://doi.org/10.5194/acp-23-3655-2023, 2023
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We made mobile MAX-DOAS measurements in the background atmosphere over the Tibetan Plateau in summer 2021. We retrieved the tropospheric NO2 and HCHO vertical column densities (VCDs) along extended driving routes and found a decreasing trend of the VCDs with altitude. Elevated NO2 VCDs along the driving routes could be attributed to enhanced traffic emissions from the towns crossed. The spatio-temporal distribution of the HCHO VCDs correlated strongly with the surface temperature.
Cameron G. MacDonald, Jon-Paul Mastrogiacomo, Joshua L. Laughner, Jacob K. Hedelius, Ray Nassar, and Debra Wunch
Atmos. Chem. Phys., 23, 3493–3516, https://doi.org/10.5194/acp-23-3493-2023, https://doi.org/10.5194/acp-23-3493-2023, 2023
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We use three satellites measuring carbon dioxide (CO2), carbon monoxide (CO) and nitrogen dioxide (NO2) to calculate atmospheric enhancements of these gases from 27 urban areas. We calculate enhancement ratios between the species and compare those to ratios derived from four globally gridded anthropogenic emission inventories. We find that the global inventories generally underestimate CO emissions in many North American and European cities relative to our observed enhancement ratios.
Udo Frieß, Karin Kreher, Richard Querel, Holger Schmithüsen, Dan Smale, Rolf Weller, and Ulrich Platt
Atmos. Chem. Phys., 23, 3207–3232, https://doi.org/10.5194/acp-23-3207-2023, https://doi.org/10.5194/acp-23-3207-2023, 2023
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Reactive bromine compounds, emitted by the sea ice during polar spring, play an important role in the atmospheric chemistry of the coastal regions of Antarctica. We investigate the sources and impacts of reactive bromine in detail using many years of measurements at two Antarctic sites located at opposite sides of the Antarctic continent. Using a multitude of meteorological observations, we were able to identify the main triggers and source regions for reactive bromine in Antarctica.
Madison J. Shogrin, Vivienne H. Payne, Susan S. Kulawik, Kazuyuki Miyazaki, and Emily V. Fischer
Atmos. Chem. Phys., 23, 2667–2682, https://doi.org/10.5194/acp-23-2667-2023, https://doi.org/10.5194/acp-23-2667-2023, 2023
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We evaluate the spatiotemporal variability of peroxy acyl nitrates (PANs), important photochemical pollutants, over Mexico City using satellite observations. PANs exhibit a seasonal cycle that maximizes in spring. Wildfires contribute to observed interannual variability, and the satellite indicates several areas of frequent outflow. Recent changes in NOx emissions are not accompanied by changes in PANs. This work demonstrates analysis approaches that can be applied to other megacities.
Hannah M. Nguyen, Jiangping He, and Martin J. Wooster
Atmos. Chem. Phys., 23, 2089–2118, https://doi.org/10.5194/acp-23-2089-2023, https://doi.org/10.5194/acp-23-2089-2023, 2023
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This work presents novel advances in the estimation of open biomass burning emissions via the first fully "top-down" approach to exploit satellite-derived observations of fire radiative power and carbon monoxide over Africa. We produce a 16-year record of fire-generated CO emissions and dry matter consumed per unit area for Africa and evaluate these emissions estimates through their use in an atmospheric model, whose simulation output is then compared to independent satellite observations of CO.
Amir H. Souri, Matthew S. Johnson, Glenn M. Wolfe, James H. Crawford, Alan Fried, Armin Wisthaler, William H. Brune, Donald R. Blake, Andrew J. Weinheimer, Tijl Verhoelst, Steven Compernolle, Gaia Pinardi, Corinne Vigouroux, Bavo Langerock, Sungyeon Choi, Lok Lamsal, Lei Zhu, Shuai Sun, Ronald C. Cohen, Kyung-Eun Min, Changmin Cho, Sajeev Philip, Xiong Liu, and Kelly Chance
Atmos. Chem. Phys., 23, 1963–1986, https://doi.org/10.5194/acp-23-1963-2023, https://doi.org/10.5194/acp-23-1963-2023, 2023
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We have rigorously characterized different sources of error in satellite-based HCHO / NO2 tropospheric columns, a widely used metric for diagnosing near-surface ozone sensitivity. Specifically, the errors were categorized/quantified into (i) an inherent chemistry error, (ii) the decoupled relationship between columns and the near-surface concentration, (iii) the spatial representativeness error of ground satellite pixels, and (iv) the satellite retrieval errors.
Cited articles
Alvarado, L. M. A., Richter, A., Vrekoussis, M., Wittrock, F., Hilboll, A., Schreier, S. F., and Burrows, J. P.: An improved glyoxal retrieval from OMI measurements, Atmos. Meas. Tech., 7, 4133–4150, https://doi.org/10.5194/amt-7-4133-2014, 2014.
Barletta, B., Meinardi, S., Sherwood Rowland, F., Chan, C.-Y., Wang, X., Zou, S., Yin Chan, L., and Blake, D. R.: Volatile organic compounds in 43 Chinese cities, Atmos. Environ., 39, 5979–5990, 2005.
Barletta, B., Meinardi, S., Simpson, I. J., Zou, S., Rowland, F. S., and Blake, D. R.: Ambient mixing ratios of nonmethane hydrocarbons (NMHCs) in two major urban centers of the Pearl River Delta (PRD) region: Guangzhou and Dongguan, Atmos. Environ., 42, 4393–4408, https://doi.org/10.1016/j.atmosenv.2008.01.028, 2008.
Beirle, S., Boersma, K. F., Platt, U., Lawrence, M. G., and Wagner, T.: Megacity Emissions and Lifetimes of Nitrogen Oxides Probed from Space, Science, 333, 1737–1739, https://doi.org/10.1126/science.1207824, 2011.
Bey, I., Jacob, D. J., Yantosca, R. M., Logan, J. A., Field, B. D., Fiore, A. M., Li, Q., Liu, H. Y., Mickley, L. J., and Schultz, M. G.: Global modeling of tropospheric chemistry with assimilated meteorology: Model description and evaluation, J. Geophys. Res.-Atmos., 106, 23073–23095, https://doi.org/10.1029/2001JD000807, 2001.
Bloss, C., Wagner, V., Jenkin, M. E., Volkamer, R., Bloss, W. J., Lee, J. D., Heard, D. E., Wirtz, K., Martin-Reviejo, M., Rea, G., Wenger, J. C., and Pilling, M. J.: Development of a detailed chemical mechanism (MCMv3.1) for the atmospheric oxidation of aromatic hydrocarbons, Atmos. Chem. Phys., 5, 641–664, https://doi.org/10.5194/acp-5-641-2005, 2005.
Bucsela, E. J., Krotkov, N. A., Celarier, E. A., Lamsal, L. N., Swartz, W. H., Bhartia, P. K., Boersma, K. F., Veefkind, J. P., Gleason, J. F., and Pickering, K. E.: A new stratospheric and tropospheric NO2 retrieval algorithm for nadir-viewing satellite instruments: applications to OMI, Atmos. Meas. Tech., 6, 2607–2626, https://doi.org/10.5194/amt-6-2607-2013, 2013.
Chan Miller, C., Gonzalez Abad, G., Wang, H., Liu, X., Kurosu, T., Jacob, D. J., and Chance, K.: Glyoxal retrieval from the Ozone Monitoring Instrument, Atmos. Meas. Tech., 7, 3891–3907, https://doi.org/10.5194/amt-7-3891-2014, 2014.
DiGangi, J. P., Henry, S. B., Kammrath, A., Boyle, E. S., Kaser, L., Schnitzhofer, R., Graus, M., Turnipseed, A., Park, J.-H., Weber, R. J., Hornbrook, R. S., Cantrell, C. A., Maudlin III, R. L., Kim, S., Nakashima, Y., Wolfe, G. M., Kajii, Y., Apel, E. C., Goldstein, A. H., Guenther, A., Karl, T., Hansel, A., and Keutsch, F. N.: Observations of glyoxal and formaldehyde as metrics for the anthropogenic impact on rural photochemistry, Atmos. Chem. Phys., 12, 9529–9543, https://doi.org/10.5194/acp-12-9529-2012, 2012.
Fu, T.-M., Jacob, D. J., Wittrock, F., Burrows, J. P., Vrekoussis, M., and Henze, D. K.: Global budgets of atmospheric glyoxal and methylglyoxal, and implications for formation of secondary organic aerosols, J. Geophys. Res., 113, D15303, https://doi.org/10.1029/2007JD009505, 2008.
González Abad, G., Liu, X., Chance, K., Wang, H., Kurosu, T. P., and Suleiman, R.: Updated Smithsonian Astrophysical Observatory Ozone Monitoring Instrument (SAO OMI) formaldehyde retrieval, Atmos. Meas. Tech., 8, 19–32, https://doi.org/10.5194/amt-8-19-2015, 2015.
Granier, C., Bessagnet, B., Bond, T., D'Angiola, A., Denier van der Gon, H., Frost, G., Heil, A., Kaiser, J., Kinne, S., Klimont, Z., Kloster, S., Lamarque, J.-F., Liousse, C., Masui, T., Meleux, F., Mieville, A., Ohara, T., Raut, J.-C., Riahi, K., Schultz, M., Smith, S., Thompson, A., van Aardenne, J., van der Werf, G., and van Vuuren, D.: Evolution of anthropogenic and biomass burning emissions of air pollutants at global and regional scales during the 1980–2010 period, Climate Change, 109, 163–190, https://doi.org/10.1007/s10584-011-0154-1, 2011.
Guangdong Statistical Bureau & Guangdong Survey Office of National Bureau of Statistics: Guangdong Statistical Yearbook, China Statistics Press, 2010.
Hofzumahaus, A., Rohrer, F., Lu, K., Bohn, B., Brauers, T., Chang, C.-C., Fuchs, H., Holland, F., Kita, K., Kondo, Y., Li, X., Lou, S., Shao, M., Zeng, L., Wahner, A., and Zhang, Y.: Amplified Trace Gas Removal in the Troposphere, Science, 324, 1702–1704, https://doi.org/10.1126/science.1164566, 2009.
Jenkin, M. E., Saunders, S. M., and Pilling, M. J.: The tropospheric degradation of volatile organic compounds: a protocol for mechanism development, Atmos. Environ., 31, 81–104, https://doi.org/10.1016/S1352-2310(96)00105-7, 1997.
Jenkin, M. E., Saunders, S. M., Wagner, V., and Pilling, M. J.: Protocol for the development of the Master Chemical Mechanism, MCM v3 (Part B): tropospheric degradation of aromatic volatile organic compounds, Atmos. Chem. Phys., 3, 181–193, https://doi.org/10.5194/acp-3-181-2003, 2003.
Kaiser, J., Wolfe, G. M., Min, K. E., Brown, S. S., Miller, C. C., Jacob, D. J., deGouw, J. A., Graus, M., Hanisco, T. F., Holloway, J., Peischl, J., Pollack, I. B., Ryerson, T. B., Warneke, C., Washenfelder, R. A., and Keutsch, F. N.: Reassessing the ratio of glyoxal to formaldehyde as an indicator of hydrocarbon precursor speciation, Atmos. Chem. Phys., 15, 7571–7583, https://doi.org/10.5194/acp-15-7571-2015, 2015.
Kurokawa, J., Ohara, T., Morikawa, T., Hanayama, S., Janssens-Maenhout, G., Fukui, T., Kawashima, K., and Akimoto, H.: Emissions of air pollutants and greenhouse gases over Asian regions during 2000–2008: Regional Emission inventory in ASia (REAS) version 2, Atmos. Chem. Phys., 13, 11019–11058, https://doi.org/10.5194/acp-13-11019-2013, 2013.
Lai, C.-H., Chang, C.-C., Wang, C.-H., Shao, M., Zhang, Y., and Wang, J.-L.: Emissions of liquefied petroleum gas (LPG) from motor vehicles, Atmos. Environ., 43, 1456–1463, https://doi.org/10.1016/j.atmosenv.2008.11.045, 2009.
Lamsal, L. N., Krotkov, N. A., Celarier, E. A., Swartz, W. H., Pickering, K. E., Bucsela, E. J., Gleason, J. F., Martin, R. V., Philip, S., Irie, H., Cede, A., Herman, J., Weinheimer, A., Szykman, J. J., and Knepp, T. N.: Evaluation of OMI operational standard NO2 column retrievals using in situ and surface-based NO2 observations, Atmos. Chem. Phys., 14, 11587–11609, https://doi.org/10.5194/acp-14-11587-2014, 2014.
Levelt, P., van den Oord, G., Dobber, M., Malkki, A., Visser, H., de Vries, J., Stammes, P., Lundell, J., and Saari, H.: The ozone monitoring instrument, IEEE T. Geosci. Remote., 44, 1093–1101, https://doi.org/10.1109/TGRS.2006.872333, 2006.
Li, N., Fu, T.-M., Cao, J., Lee, S., Huang, X.-F., He, L.-Y., Ho, K.-F., Fu, J. S., and Lam, Y.-F.: Sources of secondary organic aerosols in the Pearl River Delta region in fall: Contributions from the aqueous reactive uptake of dicarbonyls, Atmos. Environ., 76, 200–207, https://doi.org/10.1016/j.atmosenv.2012.12.005, 2013.
Li, X., Rohrer, F., Brauers, T., Hofzumahaus, A., Lu, K., Shao, M., Zhang, Y. H., and Wahner, A.: Modeling of HCHO and CHOCHO at a semi-rural site in southern China during the PRIDE-PRD2006 campaign, Atmos. Chem. Phys., 14, 12291–12305, https://doi.org/10.5194/acp-14-12291-2014, 2014.
Liu, H., Wang, X. M., Pang, J. M., and He, K. B.: Feasibility and difficulties of China's new air quality standard compliance: PRD case of PM2.5 and ozone from 2010 to 2025, Atmos. Chem. Phys., 13, 12013–12027, https://doi.org/10.5194/acp-13-12013-2013, 2013.
Liu, Y., Shao, M., Fu, L., Lu, S., Zeng, L., and Tang, D.: Source profiles of volatile organic compounds (VOCs) measured in China: Part I, Atmos. Environ., 42, 6247–6260, https://doi.org/10.1016/j.atmosenv.2008.01.070, 2008a.
Liu, Y., Shao, M., Lu, S., Chang, C.-C., Wang, J.-L., and Fu, L.: Source apportionment of ambient volatile organic compounds in the Pearl River Delta, China: Part II, Atmos. Environ., 42, 6261–6274, https://doi.org/10.1016/j.atmosenv.2008.02.027, 2008b.
Liu, Z., Wang, Y., Vrekoussis, M., Richter, A., Wittrock, F., Burrows, J. P., Shao, M., Chang, C.-C., Liu, S.-C., Wang, H., and Chen, C.: Exploring the missing source of glyoxal (CHOCHO) over China, Geophys. Res. Lett., 39, L10812, https://doi.org/10.1029/2012GL051645, 2012.
Mao, J., Paulot, F., Jacob, D. J., Cohen, R. C., Crounse, J. D., Wennberg, P. O., Keller, C. A., Hudman, R. C., Barkley, M. P., and Horowitz, L. W.: Ozone and organic nitrates over the eastern United States: Sensitivity to isoprene chemistry, J. Geophys. Res.-Atmos., 118, 11256–11268, https://doi.org/10.1002/jgrd.50817, 2013.
Martin, R. V., Jacob, D. J., Yantosca, R. M., Chin, M., and Ginoux, P.: Global and regional decreases in tropospheric oxidants from photochemical effects of aerosols, J. Geophys. Res.-Atmos., 108, 4097, https://doi.org/10.1029/2002JD002622, 2003.
Neu, J. L., Prather, M. J., and Penner, J. E.: Global atmospheric chemistry: Integrating over fractional cloud cover, J. Geophys. Res.-Atmos., 112, D11306, https://doi.org/10.1029/2006JD008007, 2007.
Nishino, N., Arey, J., and Atkinson, R.: Formation Yields of Glyoxal and Methylglyoxal from the Gas-Phase OH Radical-Initiated Reactions of Toluene, Xylenes, and Trimethylbenzenes as a Function of NO2 Concentration, J. Phys. Chem. A, 114, 10140–10147, https://doi.org/10.1021/jp105112h, 2010.
Palmer, P. I., Abbot, D. S., Fu, T.-M., Jacob, D. J., Chance, K., Kurosu, T. P., Guenther, A., Wiedinmyer, C., Stanton, J. C., Pilling, M. J., Pressley, S. N., Lamb, B., and Sumner, A. L.: Quantifying the seasonal and interannual variability of North American isoprene emissions using satellite observations of the formaldehyde column, J. Geophys. Res.-Atmos., 111, D12315, https://doi.org/10.1029/2005JD006689, 2006.
Schultz, M. G., Backman, L., Balkanski, Y., Bjoerndalsaeter, S., Brand, R., Burrows, J. P., Dalsoeren, S., de Vasconcelos, M., Grodtmann, B., Hauglustaine, D. A., Heil, A., Hoelzemann, J. J., Isaksen, I. S. A., Kaurola, J., Knorr, W., Ladstaetter-Weissenmayer, A., Mota, B., Oom, D., Pacyna, J., Panasiuk, D., Pereira, J. M. C., Pulles, T., Pyle, J., Rast, S., Richter, A., Savage, N., Schnadt, C., Schulz, M., Spessa, A., Staehelin, J., Sundet, J. K., Szopa, S., Thonicke, K., van het Bolscher, M., van Noije, T., van Velthoven, P., Vik, A. F., and Wittrock, F.: REanalysis of the TROpospheric chemical composition over the past 40 years, A long-term global modeling study of tropospheric chemistry funded under the 5th EU framework programme EU-Contract No. EVK2-CT-2002-00170, Tech. rep., TNO, 2007.
Shao, M., Zhang, Y., Zeng, L., Tang, X., Zhang, J., Zhong, L., and Wang, B.: Ground-level ozone in the Pearl River Delta and the roles of {VOC} and NOx in its production, J. Environ. Manage., 90, 512–518, https://doi.org/10.1016/j.jenvman.2007.12.008, 2009.
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Short summary
Volatile organic compounds (VOCs) are important precursors for photochemical smog.
Glyoxal is an organic compound produced in the atmosphere from reactions of larger VOCs. OMI satellite observations of glyoxal show a large hotspot over the Pearl River delta. The hotspot can be explained by industrial paint and solvent emissions of aromatic VOCs. Our work shows OMI observations are consistent with current VOC emissions estimates, whereas previous work has suggested large underestimates.
Volatile organic compounds (VOCs) are important precursors for photochemical smog.
Glyoxal is...
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