Articles | Volume 25, issue 3
https://doi.org/10.5194/acp-25-1883-2025
https://doi.org/10.5194/acp-25-1883-2025
Research article
 | 
12 Feb 2025
Research article |  | 12 Feb 2025

Quantifying primary oxidation products in the OH-initiated reaction of benzyl alcohol

Reina S. Buenconsejo, Sophia M. Charan, John H. Seinfeld, and Paul O. Wennberg

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Cited articles

Allen, H. M., Crounse, J. D., Bates, K. H., Teng, A. P., Krawiec-Thayer, M. P., Rivera-Rios, J. C., Keutsch, F. N., St. Clair, J. M., Hanisco, T. F., Møller, K. H., Kjaergaard, H. G., and Wennberg, P. O.: Kinetics and Product Yields of the OH Initiated Oxidation of Hydroxymethyl Hydroperoxide, J. Phys. Chem. A, 122, 6292–6302, https://doi.org/10.1021/acs.jpca.8b04577, 2018. a
Atkinson, R., Aschmann, S. M., Carter, W. P., Winer, A. M., and Pitts, J. N.: Alkyl nitrate formation from the NO-air photooxidations of C2-C8 n-alkanes, J. Phys. Chem., 86, 7, https://doi.org/10.1021/j100220a022, 1982. a
Baltaretu, C. O., Lichtman, E. I., Hadler, A. B., and Elrod, M. J.: Primary atmospheric oxidation mechanism for toluene, J. Phys. Chem. A, 113, 221–230, https://doi.org/10.1021/jp806841t, 2009. a, b
Bernard, F., Magneron, I., Eyglunent, G., Daële, V., Wallington, T. J., Hurley, M. D., and Mellouki, A.: Atmospheric chemistry of benzyl alcohol: kinetics and mechanism of reaction with OH radicals, Environ. Sci. Technol., 47, 3182–3189, https://doi.org/10.1021/es304600z, 2013. a, b, c, d, e, f, g, h, i, j, k, l, m
Bloss, C., Wagner, V., Jenkin, M. E., Volkamer, R., Bloss, W. J., Lee, J. D., Heard, D. E., Wirtz, K., Martin-Reviejo, M., Rea, G., Wenger, J. C., and Pilling, M. J.: Development of a detailed chemical mechanism (MCMv3.1) for the atmospheric oxidation of aromatic hydrocarbons, Atmos. Chem. Phys., 5, 641–664, https://doi.org/10.5194/acp-5-641-2005, 2005. a, b
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Short summary
We look at the atmospheric chemistry of a volatile chemical product (VCP), benzyl alcohol. Benzyl alcohol and other VCPs may play a significant role in the formation of urban smog. By better understanding the chemistry of VCPs like benzyl alcohol, we may better understand observed data and how VCPs affect air quality. We identify products formed from benzyl alcohol chemistry and use this chemistry to understand how benzyl alcohol forms a key component of smog, secondary organic aerosol.
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