Articles | Volume 17, issue 21
https://doi.org/10.5194/acp-17-13139-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-17-13139-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
07 Nov 2017
Research article |
| 07 Nov 2017
| 07 Nov 2017
Impacts of Mt Pinatubo volcanic aerosol on the tropical stratosphere in chemistry–climate model simulations using CCMI and CMIP6 stratospheric aerosol data
Laura E. Revell
CORRESPONDING AUTHOR
Bodeker Scientific, Christchurch, New Zealand
Institute for Atmospheric and Climate Science, ETH Zurich, Zurich, Switzerland
Andrea Stenke
Institute for Atmospheric and Climate Science, ETH Zurich, Zurich, Switzerland
Beiping Luo
Institute for Atmospheric and Climate Science, ETH Zurich, Zurich, Switzerland
Stefanie Kremser
Bodeker Scientific, Alexandra, New Zealand
Eugene Rozanov
Institute for Atmospheric and Climate Science, ETH Zurich, Zurich, Switzerland
Physical-Meteorological Observatory/World Radiation Center, Davos, Switzerland
Timofei Sukhodolov
Physical-Meteorological Observatory/World Radiation Center, Davos, Switzerland
Thomas Peter
Institute for Atmospheric and Climate Science, ETH Zurich, Zurich, Switzerland
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Dongqi Lin, Jiawei Zhang, Basit Khan, Marwan Katurji, and Laura E. Revell
Geosci. Model Dev., 17, 815–845, https://doi.org/10.5194/gmd-17-815-2024, https://doi.org/10.5194/gmd-17-815-2024, 2024
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Jan Clemens, Bärbel Vogel, Lars Hoffmann, Sabine Griessbach, Nicole Thomas, Suvarna Fadnavis, Rolf Müller, Thomas Peter, and Felix Ploeger
Atmos. Chem. Phys., 24, 763–787, https://doi.org/10.5194/acp-24-763-2024, https://doi.org/10.5194/acp-24-763-2024, 2024
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Rolf Müller, Ulrich Pöschl, Thomas Koop, Thomas Peter, and Ken Carslaw
Atmos. Chem. Phys., 23, 15445–15453, https://doi.org/10.5194/acp-23-15445-2023, https://doi.org/10.5194/acp-23-15445-2023, 2023
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Yaowei Li, Corey Pedersen, John Dykema, Jean-Paul Vernier, Sandro Vattioni, Amit Kumar Pandit, Andrea Stenke, Elizabeth Asher, Troy Thornberry, Michael A. Todt, Thao Paul Bui, Jonathan Dean-Day, and Frank N. Keutsch
Atmos. Chem. Phys., 23, 15351–15364, https://doi.org/10.5194/acp-23-15351-2023, https://doi.org/10.5194/acp-23-15351-2023, 2023
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Yusuf A. Bhatti, Laura E. Revell, Alex J. Schuddeboom, Adrian J. McDonald, Alex T. Archibald, Jonny Williams, Abhijith U. Venugopal, Catherine Hardacre, and Erik Behrens
Atmos. Chem. Phys., 23, 15181–15196, https://doi.org/10.5194/acp-23-15181-2023, https://doi.org/10.5194/acp-23-15181-2023, 2023
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Ben A. Cala, Scott Archer-Nicholls, James Weber, N. Luke Abraham, Paul T. Griffiths, Lorrie Jacob, Y. Matthew Shin, Laura E. Revell, Matthew Woodhouse, and Alexander T. Archibald
Atmos. Chem. Phys., 23, 14735–14760, https://doi.org/10.5194/acp-23-14735-2023, https://doi.org/10.5194/acp-23-14735-2023, 2023
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Dongqi Lin, Marwan Katurji, Laura E. Revell, Basit Khan, and Andrew Sturman
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Franziska Zilker, Timofei Sukhodolov, Gabriel Chiodo, Marina Friedel, Tatiana Egorova, Eugene Rozanov, Jan Sedlacek, Svenja Seeber, and Thomas Peter
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Gabriel Chiodo, Marina Friedel, Svenja Seeber, Daniela Domeisen, Andrea Stenke, Timofei Sukhodolov, and Franziska Zilker
Atmos. Chem. Phys., 23, 10451–10472, https://doi.org/10.5194/acp-23-10451-2023, https://doi.org/10.5194/acp-23-10451-2023, 2023
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Stratospheric ozone protects the biosphere from harmful UV radiation. Anthropogenic activity has led to a reduction in the ozone layer in the recent past, but thanks to the implementation of the Montreal Protocol, the ozone layer is projected to recover. In this study, we show that projected future changes in Arctic ozone abundances during springtime will influence stratospheric climate and thereby actively modulate large-scale circulation changes in the Northern Hemisphere.
Marina Friedel, Gabriel Chiodo, Timofei Sukhodolov, James Keeble, Thomas Peter, Svenja Seeber, Andrea Stenke, Hideharu Akiyoshi, Eugene Rozanov, David Plummer, Patrick Jöckel, Guang Zeng, Olaf Morgenstern, and Béatrice Josse
Atmos. Chem. Phys., 23, 10235–10254, https://doi.org/10.5194/acp-23-10235-2023, https://doi.org/10.5194/acp-23-10235-2023, 2023
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Previously, it has been suggested that springtime Arctic ozone depletion might worsen in the coming decades due to climate change, which might counteract the effect of reduced ozone-depleting substances. Here, we show with different chemistry–climate models that springtime Arctic ozone depletion will likely decrease in the future. Further, we explain why models show a large spread in the projected development of Arctic ozone depletion and use the model spread to constrain future projections.
Tatiana Egorova, Jan Sedlacek, Timofei Sukhodolov, Arseniy Karagodin-Doyennel, Franziska Zilker, and Eugene Rozanov
Atmos. Chem. Phys., 23, 5135–5147, https://doi.org/10.5194/acp-23-5135-2023, https://doi.org/10.5194/acp-23-5135-2023, 2023
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This paper describes the climate and atmosphere benefits of the Montreal Protocol, simulated with the state-of-the-art Earth system model SOCOLv4.0. We have added to and confirmed the previous studies by showing that without the Montreal Protocol by the end of the 21st century there would be a dramatic reduction in the ozone layer as well as substantial perturbation of the essential climate variables in the troposphere caused by the warming from increasing ozone-depleting substances.
Anand Kumar, Kristian Klumpp, Chen Barak, Giora Rytwo, Michael Plötze, Thomas Peter, and Claudia Marcolli
Atmos. Chem. Phys., 23, 4881–4902, https://doi.org/10.5194/acp-23-4881-2023, https://doi.org/10.5194/acp-23-4881-2023, 2023
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Smectites are a major class of clay minerals that are ice nucleation (IN) active. They form platelets that swell or even delaminate in water by intercalation of water between their layers. We hypothesize that at least three smectite layers need to be stacked together to host a critical ice embryo on clay mineral edges and that the larger the surface edge area is, the higher the freezing temperature. Edge sites on such clay particles play a crucial role in imparting IN ability to such particles.
Arseniy Karagodin-Doyennel, Eugene Rozanov, Timofei Sukhodolov, Tatiana Egorova, Jan Sedlacek, and Thomas Peter
Atmos. Chem. Phys., 23, 4801–4817, https://doi.org/10.5194/acp-23-4801-2023, https://doi.org/10.5194/acp-23-4801-2023, 2023
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The future ozone evolution in SOCOLv4 simulations under SSP2-4.5 and SSP5-8.5 scenarios has been assessed for the period 2015–2099 and subperiods using the DLM approach. The SOCOLv4 projects a decline in tropospheric ozone in the 2030s in SSP2-4.5 and in the 2060s in SSP5-8.5. The stratospheric ozone increase is ~3 times higher in SSP5-8.5, confirming the important role of GHGs in ozone evolution. We also showed that tropospheric ozone strongly impacts the total column in the tropics.
Andrey V. Koval, Olga N. Toptunova, Maxim A. Motsakov, Ksenia A. Didenko, Tatiana S. Ermakova, Nikolai M. Gavrilov, and Eugene V. Rozanov
Atmos. Chem. Phys., 23, 4105–4114, https://doi.org/10.5194/acp-23-4105-2023, https://doi.org/10.5194/acp-23-4105-2023, 2023
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Periodic changes in all hydrodynamic parameters are constantly observed in the atmosphere. The amplitude of these fluctuations increases with height due to a decrease in the atmospheric density. In the upper layers of the atmosphere, waves are the dominant form of motion. We use a model of the general circulation of the atmosphere to study the contribution to the formation of the dynamic and temperature regimes of the middle and upper atmosphere made by different global-scale atmospheric waves.
Kristian Klumpp, Claudia Marcolli, Ana Alonso-Hellweg, Christopher H. Dreimol, and Thomas Peter
Atmos. Chem. Phys., 23, 1579–1598, https://doi.org/10.5194/acp-23-1579-2023, https://doi.org/10.5194/acp-23-1579-2023, 2023
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The prerequisites of a particle surface for efficient ice nucleation are still poorly understood. This study compares the ice nucleation activity of two chemically identical but morphologically different minerals (kaolinite and halloysite). We observe, on average, not only higher ice nucleation activities for halloysite than kaolinite but also higher diversity between individual samples. We identify the particle edges as being the most likely site for ice nucleation.
Ilaria Quaglia, Claudia Timmreck, Ulrike Niemeier, Daniele Visioni, Giovanni Pitari, Christina Brodowsky, Christoph Brühl, Sandip S. Dhomse, Henning Franke, Anton Laakso, Graham W. Mann, Eugene Rozanov, and Timofei Sukhodolov
Atmos. Chem. Phys., 23, 921–948, https://doi.org/10.5194/acp-23-921-2023, https://doi.org/10.5194/acp-23-921-2023, 2023
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The last very large explosive volcanic eruption we have measurements for is the eruption of Mt. Pinatubo in 1991. It is therefore often used as a benchmark for climate models' ability to reproduce these kinds of events. Here, we compare available measurements with the results from multiple experiments conducted with climate models interactively simulating the aerosol cloud formation.
Arseniy Karagodin-Doyennel, Eugene Rozanov, Timofei Sukhodolov, Tatiana Egorova, Jan Sedlacek, William Ball, and Thomas Peter
Atmos. Chem. Phys., 22, 15333–15350, https://doi.org/10.5194/acp-22-15333-2022, https://doi.org/10.5194/acp-22-15333-2022, 2022
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Applying the dynamic linear model, we confirm near-global ozone recovery (55°N–55°S) in the mesosphere, upper and middle stratosphere, and a steady increase in the troposphere. We also show that modern chemistry–climate models (CCMs) like SOCOLv4 may reproduce the observed trend distribution of lower stratospheric ozone, despite exhibiting a lower magnitude and statistical significance. The obtained ozone trend pattern in SOCOLv4 is generally consistent with observations and reanalysis datasets.
Nikou Hamzehpour, Claudia Marcolli, Sara Pashai, Kristian Klumpp, and Thomas Peter
Atmos. Chem. Phys., 22, 14905–14930, https://doi.org/10.5194/acp-22-14905-2022, https://doi.org/10.5194/acp-22-14905-2022, 2022
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Playa surfaces in Iran that emerged through Lake Urmia (LU) desiccation have become a relevant dust source of regional relevance. Here, we identify highly erodible LU playa surfaces and determine their physicochemical properties and mineralogical composition and perform emulsion-freezing experiments with them. We find high ice nucleation activities (up to 250 K) that correlate positively with organic matter and clay content and negatively with pH, salinity, K-feldspars, and quartz.
Nikou Hamzehpour, Claudia Marcolli, Kristian Klumpp, Debora Thöny, and Thomas Peter
Atmos. Chem. Phys., 22, 14931–14956, https://doi.org/10.5194/acp-22-14931-2022, https://doi.org/10.5194/acp-22-14931-2022, 2022
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Dust aerosols from dried lakebeds contain mineral particles, as well as soluble salts and (bio-)organic compounds. Here, we investigate ice nucleation (IN) activity of dust samples from Lake Urmia playa, Iran. We find high IN activity of the untreated samples that decreases after organic matter removal but increases after removing soluble salts and carbonates, evidencing inhibiting effects of soluble salts and carbonates on the IN activity of organic matter and minerals, especially microcline.
Marina Friedel, Gabriel Chiodo, Andrea Stenke, Daniela I. V. Domeisen, and Thomas Peter
Atmos. Chem. Phys., 22, 13997–14017, https://doi.org/10.5194/acp-22-13997-2022, https://doi.org/10.5194/acp-22-13997-2022, 2022
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In spring, winds the Arctic stratosphere change direction – an event called final stratospheric warming (FSW). Here, we examine whether the interannual variability in Arctic stratospheric ozone impacts the timing of the FSW. We find that Arctic ozone shifts the FSW to earlier and later dates in years with high and low ozone via the absorption of UV light. The modulation of the FSW by ozone has consequences for surface climate in ozone-rich years, which may result in better seasonal predictions.
Clare E. Singer, Benjamin W. Clouser, Sergey M. Khaykin, Martina Krämer, Francesco Cairo, Thomas Peter, Alexey Lykov, Christian Rolf, Nicole Spelten, Armin Afchine, Simone Brunamonti, and Elisabeth J. Moyer
Atmos. Meas. Tech., 15, 4767–4783, https://doi.org/10.5194/amt-15-4767-2022, https://doi.org/10.5194/amt-15-4767-2022, 2022
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In situ measurements of water vapor in the upper troposphere are necessary to study cloud formation and hydration of the stratosphere but challenging due to cold–dry conditions. We compare measurements from three water vapor instruments from the StratoClim campaign in 2017. In clear sky (clouds), point-by-point differences were <1.5±8 % (<1±8 %). This excellent agreement allows detection of fine-scale structures required to understand the impact of convection on stratospheric water vapor.
Alex R. Aves, Laura E. Revell, Sally Gaw, Helena Ruffell, Alex Schuddeboom, Ngaire E. Wotherspoon, Michelle LaRue, and Adrian J. McDonald
The Cryosphere, 16, 2127–2145, https://doi.org/10.5194/tc-16-2127-2022, https://doi.org/10.5194/tc-16-2127-2022, 2022
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This study confirms the presence of microplastics in Antarctic snow, highlighting the extent of plastic pollution globally. Fresh snow was collected from Ross Island, Antarctica, and subsequent analysis identified an average of 29 microplastic particles per litre of melted snow. The most likely source of these airborne microplastics is local scientific research stations; however, modelling shows their origin could have been up to 6000 km away.
Irina Mironova, Miriam Sinnhuber, Galina Bazilevskaya, Mark Clilverd, Bernd Funke, Vladimir Makhmutov, Eugene Rozanov, Michelle L. Santee, Timofei Sukhodolov, and Thomas Ulich
Atmos. Chem. Phys., 22, 6703–6716, https://doi.org/10.5194/acp-22-6703-2022, https://doi.org/10.5194/acp-22-6703-2022, 2022
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From balloon measurements, we detected unprecedented, extremely powerful, electron precipitation over the middle latitudes. The robustness of this event is confirmed by satellite observations of electron fluxes and chemical composition, as well as by ground-based observations of the radio signal propagation. The applied chemistry–climate model shows the almost complete destruction of ozone in the mesosphere over the region where high-energy electrons were observed.
Kristian Klumpp, Claudia Marcolli, and Thomas Peter
Atmos. Chem. Phys., 22, 3655–3673, https://doi.org/10.5194/acp-22-3655-2022, https://doi.org/10.5194/acp-22-3655-2022, 2022
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Surface interactions with solutes can significantly alter the ice nucleation activity of mineral dust. Past studies revealed the sensitivity of microcline, one of the most ice-active types of dust in the atmosphere, to inorganic solutes. This study focuses on the interaction of microcline with bio-organic substances and the resulting effects on its ice nucleation activity. We observe strongly hampered ice nucleation activity due to the presence of carboxylic and amino acids but not for polyols.
Debra K. Weisenstein, Daniele Visioni, Henning Franke, Ulrike Niemeier, Sandro Vattioni, Gabriel Chiodo, Thomas Peter, and David W. Keith
Atmos. Chem. Phys., 22, 2955–2973, https://doi.org/10.5194/acp-22-2955-2022, https://doi.org/10.5194/acp-22-2955-2022, 2022
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This paper explores a potential method of geoengineering that could be used to slow the rate of change of climate over decadal scales. We use three climate models to explore how injections of accumulation-mode sulfuric acid aerosol change the large-scale stratospheric particle size distribution and radiative forcing response for the chosen scenarios. Radiative forcing per unit sulfur injected and relative to the change in aerosol burden is larger with particulate than with SO2 injections.
Kseniia Golubenko, Eugene Rozanov, Gennady Kovaltsov, Ari-Pekka Leppänen, Timofei Sukhodolov, and Ilya Usoskin
Geosci. Model Dev., 14, 7605–7620, https://doi.org/10.5194/gmd-14-7605-2021, https://doi.org/10.5194/gmd-14-7605-2021, 2021
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A new full 3-D time-dependent model, based on SOCOL-AERv2, of beryllium atmospheric production, transport, and deposition has been developed and validated using directly measured data. The model is recommended to be used in studies related to, e.g., atmospheric dynamical patterns, extreme solar particle storms, long-term solar activity reconstruction from cosmogenic proxy data, and solar–terrestrial relations.
Arseniy Karagodin-Doyennel, Eugene Rozanov, Timofei Sukhodolov, Tatiana Egorova, Alfonso Saiz-Lopez, Carlos A. Cuevas, Rafael P. Fernandez, Tomás Sherwen, Rainer Volkamer, Theodore K. Koenig, Tanguy Giroud, and Thomas Peter
Geosci. Model Dev., 14, 6623–6645, https://doi.org/10.5194/gmd-14-6623-2021, https://doi.org/10.5194/gmd-14-6623-2021, 2021
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Here, we present the iodine chemistry module in the SOCOL-AERv2 model. The obtained iodine distribution demonstrated a good agreement when validated against other simulations and available observations. We also estimated the iodine influence on ozone in the case of present-day iodine emissions, the sensitivity of ozone to doubled iodine emissions, and when considering only organic or inorganic iodine sources. The new model can be used as a tool for further studies of iodine effects on ozone.
Brian Nathan, Stefanie Kremser, Sara Mikaloff-Fletcher, Greg Bodeker, Leroy Bird, Ethan Dale, Dongqi Lin, Gustavo Olivares, and Elizabeth Somervell
Atmos. Chem. Phys., 21, 14089–14108, https://doi.org/10.5194/acp-21-14089-2021, https://doi.org/10.5194/acp-21-14089-2021, 2021
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The MAPM project showcases a method to improve estimates of PM2.5 emissions through an advanced statistical technique that is still new to the aerosol community. Using Christchurch, NZ, as a test bed, measurements from a field campaign in winter 2019 are incorporated into this new approach. An overestimation from local inventory estimates is identified. This technique may be exported to other urban areas in need.
Timofei Sukhodolov, Tatiana Egorova, Andrea Stenke, William T. Ball, Christina Brodowsky, Gabriel Chiodo, Aryeh Feinberg, Marina Friedel, Arseniy Karagodin-Doyennel, Thomas Peter, Jan Sedlacek, Sandro Vattioni, and Eugene Rozanov
Geosci. Model Dev., 14, 5525–5560, https://doi.org/10.5194/gmd-14-5525-2021, https://doi.org/10.5194/gmd-14-5525-2021, 2021
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This paper features the new atmosphere–ocean–aerosol–chemistry–climate model SOCOLv4.0 and its validation. The model performance is evaluated against reanalysis products and observations of atmospheric circulation and trace gas distribution, with a focus on stratospheric processes. Although we identified some problems to be addressed in further model upgrades, we demonstrated that SOCOLv4.0 is already well suited for studies related to chemistry–climate–aerosol interactions.
Greg E. Bodeker, Jan Nitzbon, Jordis S. Tradowsky, Stefanie Kremser, Alexander Schwertheim, and Jared Lewis
Earth Syst. Sci. Data, 13, 3885–3906, https://doi.org/10.5194/essd-13-3885-2021, https://doi.org/10.5194/essd-13-3885-2021, 2021
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Ozone in Earth's atmosphere has undergone significant changes since first measured systematically from space in the late 1970s. The purpose of the paper is to present a new, spatially filled, global total column ozone climate data record spanning from October 1978 to December 2016. The database is compiled from measurements from 17 different satellite-based instruments where offsets and drifts between the instruments have been corrected using ground-based measurements.
Ralf Weigel, Christoph Mahnke, Manuel Baumgartner, Antonis Dragoneas, Bärbel Vogel, Felix Ploeger, Silvia Viciani, Francesco D'Amato, Silvia Bucci, Bernard Legras, Beiping Luo, and Stephan Borrmann
Atmos. Chem. Phys., 21, 11689–11722, https://doi.org/10.5194/acp-21-11689-2021, https://doi.org/10.5194/acp-21-11689-2021, 2021
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In July and August 2017, eight StratoClim mission flights of the Geophysica reached up to 20 km in the Asian monsoon anticyclone. New particle formation (NPF) was identified in situ by abundant nucleation-mode aerosols (6–15 nm in diameter) with mixing ratios of up to 50 000 mg−1. NPF occurred most frequently at 12–16 km with fractions of non-volatile residues of down to 15 %. Abundance and productivity of observed NPF indicate its ability to promote the Asian tropopause aerosol layer.
Stefanie Kremser, Mike Harvey, Peter Kuma, Sean Hartery, Alexia Saint-Macary, John McGregor, Alex Schuddeboom, Marc von Hobe, Sinikka T. Lennartz, Alex Geddes, Richard Querel, Adrian McDonald, Maija Peltola, Karine Sellegri, Israel Silber, Cliff S. Law, Connor J. Flynn, Andrew Marriner, Thomas C. J. Hill, Paul J. DeMott, Carson C. Hume, Graeme Plank, Geoffrey Graham, and Simon Parsons
Earth Syst. Sci. Data, 13, 3115–3153, https://doi.org/10.5194/essd-13-3115-2021, https://doi.org/10.5194/essd-13-3115-2021, 2021
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Aerosol–cloud interactions over the Southern Ocean are poorly understood and remain a major source of uncertainty in climate models. This study presents ship-borne measurements, collected during a 6-week voyage into the Southern Ocean in 2018, that are an important supplement to satellite-based measurements. For example, these measurements include data on low-level clouds and aerosol composition in the marine boundary layer, which can be used in climate model evaluation efforts.
Michael Weimer, Jennifer Buchmüller, Lars Hoffmann, Ole Kirner, Beiping Luo, Roland Ruhnke, Michael Steiner, Ines Tritscher, and Peter Braesicke
Atmos. Chem. Phys., 21, 9515–9543, https://doi.org/10.5194/acp-21-9515-2021, https://doi.org/10.5194/acp-21-9515-2021, 2021
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We show that we are able to directly simulate polar stratospheric clouds formed locally in a mountain wave and represent their effect on the ozone chemistry with the global atmospheric chemistry model ICON-ART. Thus, we show the first simulations that close the gap between directly resolved mountain-wave-induced polar stratospheric clouds and their representation at coarse global resolutions.
Ethan R. Dale, Stefanie Kremser, Jordis S. Tradowsky, Greg E. Bodeker, Leroy J. Bird, Gustavo Olivares, Guy Coulson, Elizabeth Somervell, Woodrow Pattinson, Jonathan Barte, Jan-Niklas Schmidt, Nariefa Abrahim, Adrian J. McDonald, and Peter Kuma
Earth Syst. Sci. Data, 13, 2053–2075, https://doi.org/10.5194/essd-13-2053-2021, https://doi.org/10.5194/essd-13-2053-2021, 2021
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MAPM is a project whose goal is to develop a method to infer particulate matter (PM) emissions maps from PM concentration measurements. In support of MAPM, we conducted a winter field campaign in New Zealand. In addition to two types of instruments measuring PM, an array of other meteorological sensors were deployed, measuring temperature and wind speed as well as probing the vertical structure of the lower atmosphere. In this article, we present the measurements taken during this campaign.
Dongqi Lin, Basit Khan, Marwan Katurji, Leroy Bird, Ricardo Faria, and Laura E. Revell
Geosci. Model Dev., 14, 2503–2524, https://doi.org/10.5194/gmd-14-2503-2021, https://doi.org/10.5194/gmd-14-2503-2021, 2021
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We present an open-source toolbox WRF4PALM, which enables weather dynamics simulation within urban landscapes. WRF4PALM passes meteorological information from the popular Weather Research and Forecasting (WRF) model to the turbulence-resolving PALM model system 6.0. WRF4PALM can potentially extend the use of WRF and PALM with realistic boundary conditions to any part of the world. WRF4PALM will help study air pollution dispersion, wind energy prospecting, and high-impact wind forecasting.
Greg E. Bodeker and Stefanie Kremser
Atmos. Chem. Phys., 21, 5289–5300, https://doi.org/10.5194/acp-21-5289-2021, https://doi.org/10.5194/acp-21-5289-2021, 2021
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This paper presents measures of the severity of the Antarctic ozone hole covering the period 1979 to 2019. The paper shows that while the severity of Antarctic ozone depletion grew rapidly through the last two decades of the 20th century, the severity declined thereafter and faster than expected from declines in stratospheric concentrations of the chlorine- and bromine-containing chemical compounds that destroy ozone.
Margot Clyne, Jean-Francois Lamarque, Michael J. Mills, Myriam Khodri, William Ball, Slimane Bekki, Sandip S. Dhomse, Nicolas Lebas, Graham Mann, Lauren Marshall, Ulrike Niemeier, Virginie Poulain, Alan Robock, Eugene Rozanov, Anja Schmidt, Andrea Stenke, Timofei Sukhodolov, Claudia Timmreck, Matthew Toohey, Fiona Tummon, Davide Zanchettin, Yunqian Zhu, and Owen B. Toon
Atmos. Chem. Phys., 21, 3317–3343, https://doi.org/10.5194/acp-21-3317-2021, https://doi.org/10.5194/acp-21-3317-2021, 2021
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This study finds how and why five state-of-the-art global climate models with interactive stratospheric aerosols differ when simulating the aftermath of large volcanic injections as part of the Model Intercomparison Project on the climatic response to Volcanic forcing (VolMIP). We identify and explain the consequences of significant disparities in the underlying physics and chemistry currently in some of the models, which are problems likely not unique to the models participating in this study.
Manuel Graf, Philipp Scheidegger, André Kupferschmid, Herbert Looser, Thomas Peter, Ruud Dirksen, Lukas Emmenegger, and Béla Tuzson
Atmos. Meas. Tech., 14, 1365–1378, https://doi.org/10.5194/amt-14-1365-2021, https://doi.org/10.5194/amt-14-1365-2021, 2021
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Water vapor is the most important natural greenhouse gas. The accurate and frequent measurement of its abundance, especially in the upper troposphere and lower stratosphere (UTLS), is technically challenging. We developed and characterized a mid-IR absorption spectrometer for highly accurate water vapor measurements in the UTLS. The instrument is sufficiently small and lightweight (3.9 kg) to be carried by meteorological balloons, which enables frequent and cost-effective soundings.
Michael Steiner, Beiping Luo, Thomas Peter, Michael C. Pitts, and Andrea Stenke
Geosci. Model Dev., 14, 935–959, https://doi.org/10.5194/gmd-14-935-2021, https://doi.org/10.5194/gmd-14-935-2021, 2021
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We evaluate polar stratospheric clouds (PSCs) as simulated by the chemistry–climate model (CCM) SOCOLv3.1 in comparison with measurements by the CALIPSO satellite. A cold bias results in an overestimated PSC area and mountain-wave ice is underestimated, but we find overall good temporal and spatial agreement of PSC occurrence and composition. This work confirms previous studies indicating that simplified PSC schemes may also achieve good approximations of the fundamental properties of PSCs.
Teresa Jorge, Simone Brunamonti, Yann Poltera, Frank G. Wienhold, Bei P. Luo, Peter Oelsner, Sreeharsha Hanumanthu, Bhupendra B. Singh, Susanne Körner, Ruud Dirksen, Manish Naja, Suvarna Fadnavis, and Thomas Peter
Atmos. Meas. Tech., 14, 239–268, https://doi.org/10.5194/amt-14-239-2021, https://doi.org/10.5194/amt-14-239-2021, 2021
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Balloon-borne frost point hygrometers are crucial for the monitoring of water vapour in the upper troposphere and lower stratosphere. We found that when traversing a mixed-phase cloud with big supercooled droplets, the intake tube of the instrument collects on its inner surface a high percentage of these droplets. The newly formed ice layer will sublimate at higher levels and contaminate the measurement. The balloon is also a source of contamination, but only at higher levels during the ascent.
Jing Dou, Peter A. Alpert, Pablo Corral Arroyo, Beiping Luo, Frederic Schneider, Jacinta Xto, Thomas Huthwelker, Camelia N. Borca, Katja D. Henzler, Jörg Raabe, Benjamin Watts, Hartmut Herrmann, Thomas Peter, Markus Ammann, and Ulrich K. Krieger
Atmos. Chem. Phys., 21, 315–338, https://doi.org/10.5194/acp-21-315-2021, https://doi.org/10.5194/acp-21-315-2021, 2021
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Photochemistry of iron(III) complexes plays an important role in aerosol aging, especially in the lower troposphere. Ensuing radical chemistry leads to decarboxylation, and the production of peroxides, and oxygenated volatile compounds, resulting in particle mass loss due to release of the volatile products to the gas phase. We investigated kinetic transport limitations due to high particle viscosity under low relative humidity conditions. For quantification a numerical model was developed.
Arseniy Karagodin-Doyennel, Eugene Rozanov, Ales Kuchar, William Ball, Pavle Arsenovic, Ellis Remsberg, Patrick Jöckel, Markus Kunze, David A. Plummer, Andrea Stenke, Daniel Marsh, Doug Kinnison, and Thomas Peter
Atmos. Chem. Phys., 21, 201–216, https://doi.org/10.5194/acp-21-201-2021, https://doi.org/10.5194/acp-21-201-2021, 2021
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The solar signal in the mesospheric H2O and CO was extracted from the CCMI-1 model simulations and satellite observations using multiple linear regression (MLR) analysis. MLR analysis shows a pronounced and statistically robust solar signal in both H2O and CO. The model results show a general agreement with observations reproducing a negative/positive solar signal in H2O/CO. The pattern of the solar signal varies among the considered models, reflecting some differences in the model setup.
Cited articles
Anet, J. G., Rozanov, E. V., Muthers, S., Peter, T., Brönnimann, S., Arfeuille, F., Beer, J., Shapiro, A. I., Raible, C. C., Steinhilber, F., and Schmutz, W. K.: Impact of a potential 21st century “grand solar minimum” on surface temperatures and stratospheric ozone, Geophys. Res. Lett., 40, 4420–4425, https://doi.org/10.1002/grl.50806, 2013.
Aquila, V., Oman, L. D., Stolarski, R., Douglass, A. R., and Newman, P. A.: The response of ozone and nitrogen dioxide to the eruption of Mt. Pinatubo at southern and northern midlatitudes, J. Atmos. Sci., 70, 894–900, https://doi.org/10.1175/jas-d-12-0143.1, 2013.
Arfeuille, F., Luo, B. P., Heckendorn, P., Weisenstein, D., Sheng, J. X., Rozanov, E., Schraner, M., Brönnimann, S., Thomason, L. W., and Peter, T.: Modeling the stratospheric warming following the Mt. Pinatubo eruption: Uncertainties in aerosol extinctions, Atmos. Chem. Phys., 13, 11221–11234, https://doi.org/10.5194/acp-13-11221-2013, 2013.
Arfeuille, F., Weisenstein, D., Mack, H., Rozanov, E., Peter, T., and Brönnimann, S.: Volcanic forcing for climate modeling: a new microphysics-based data set covering years 1600–present, Clim. Past, 10, 359–375, https://doi.org/10.5194/cp-10-359-2014, 2014.
Bauman, J. J., Russell, P. B., Geller, M. A., and Hamill, P.: A stratospheric aerosol climatology from SAGE II and CLAES measurements: 1. Methodology, J. Geophys. Res., 108, 4382, https://doi.org/10.1029/2002JD002992, 2003a.
Bauman, J. J., Russell, P. B., Geller, M. A., and Hamill, P.: A stratospheric aerosol climatology from SAGE II and CLAES measurements: 2. Results and comparisons, 1984–1999, J. Geophys. Res., 108, 4383, https://doi.org/10.1029/2002JD002993, 2003b.
Bingen, C., Fussen, D., and Vanhellemont, F.: A global climatology of stratospheric aerosol size distribution parameters derived from SAGE II data over the period 1984–2000: 1. Methodology and climatological observations, J. Geophys. Res., 109, D06201, https://doi.org/10.1029/2003JD003518, 2004a.
Bingen, C., Fussen, D., and Vanhellemont, F.: A global climatology of stratospheric aerosol size distribution parameters derived from SAGE II data over the period 1984–2000: 2. Reference data, J. Geophys. Res., 109, D06202, https://doi.org/10.1029/2003JD003511, 2004b.
Bohren, C. F. and Huffman, D. R.: Absorption and Scattering of Light by Small Particles, Wiley-VCH, Berlin, 1, 381–428, https://doi.org/10.1002/9783527618156, 2007.
Boucher, O., Randall, D., Artaxo, P., Bretherton, C., Feingold, G., Forster, P., Kerminen, V.-M., Kondo, Y., Liao, H., Lohmann, U., Rasch, P., Satheesh, S. K., Sherwood, S., Stevens, B., and Zhang, X. Y.: Clouds and Aerosols, in: Climate Change 2013: The Physical Science Basis, Contribution of Working Group I to the Fifth Assessment Report of the Intergovernmental Panel on Climate Change, edited by: Stocker, T. F., Qin, D., Plattner, G.-K., Tignor, M., Allen, S. K., Boschung, J., Nauels, A., Xia, Y., Bex, V., and Midgley, P. M., Cambridge University Press, Cambridge, United Kingdom and New York, NY, USA, 2013.
Cagnazzo, C., Manzini, E., Giorgetta, M. A., de F. Forster, P. M., and Morcrette, J.-J.: Impact of an improved radiation scheme in the MAECHAM5 General Circulation Model, Atmos. Chem. Phys., 7, 2503–2515, https://doi.org/10.5194/acp-7-2503-2007, 2007.
Carslaw, K. S., Peter, T., and Clegg, S. L.: Modeling the composition of liquid stratospheric aerosols, Rev. Geophys., 35, 125–154, https://doi.org/10.1029/97RG00078, 1997.
Davis, S. M., Rosenlof, K. H., Hassler, B., Hurst, D. F., Read, W. G., Vömel, H., Selkirk, H., Fujiwara, M., and Damadeo, R.: The Stratospheric Water and Ozone Satellite Homogenized (SWOOSH) database: a long-term database for climate studies, Earth Syst. Sci. Data, 8, 461–490, https://doi.org/10.5194/essd-8-461-2016, 2016.
Dee, D. P., Uppala, S. M., Simmons, A. J., Berrisford, P., Poli, P., Kobayashi, S., Andrae, U., Balmaseda, M.A., Balsamo, G., Bauer, P., Bechtold, P., Beljaars, A. C. M., van de Berg, L., Bidlot, J., Bormann, N., Delsol, C., Dragani, R., Fuentes, M., Geer, A. J., Haimberger, L., Healy, S. B., Hersbach, H., Hólm, E. V., Isaksen, L., Kallberg, P., Köhler, M., Matricardi, M., McNally, A. P., Monge-Sanz, B. M., Morcrette, J.-J., Park, B.-K., Peubey, C., de Rosnay, P., Tavolato, C., Thépaut, J.-N., and Vitart, F.: The ERA-Interim reanalysis: configuration and performance of the data assimilation system, Q. J. R. Meteorol. Soc., 137, 553–597, https://doi.org/10.1002/qj.828, 2011.
Deshler, T., Hervig, M. E., Hofmann, D. J., Rosen, J. M., and Liley, J. B.: Thirty years of in situ stratospheric aerosol size distribution measurements from Laramie, Wyoming (41° N), using balloon-borne instruments, J. Geophys. Res.-Atmos., 108, 4167, https://doi.org/10.1029/2002JD002541, 2003.
Dhomse, S. S., Chipperfield, M. P., Feng, W., Hossaini, R., Mann, G. W., and Santee, M. L.: Revisiting the hemispheric asymmetry in midlatitude ozone changes following the Mount Pinatubo eruption: A 3-D model study, Geophys. Res. Lett., 42, 3038–3047, https://doi.org/10.1002/2015GL063052, 2015.
Driscoll, S., Bozzo, A., Gray, L. J., Robock, A., and Stenchikov, G.: Coupled Model Intercomparison Project 5 (CMIP5) simulations of climate following volcanic eruptions, J. Geophys. Res., 117, D17105, https://doi.org/10.1029/2012JD017607, 2012.
ETH-PMOD: Swiss Federal Institute of Technology Zurich and the Physical-Meteorology Observatory Davos, Data, Part of the Chemistry-Climate Model Initiative (CCMI-1) Project Database, NCAS British Atmospheric Data Centre, available at: http://catalogue.ceda.ac.uk/uuid/1005d2c25d14483aa66a5f4a7f50fcf0 (last access: 20 April 2017), 2015.
Eyring, V., Bony, S., Meehl, G. A., Senior, C. A., Stevens, B., Stouffer, R. J., and Taylor, K. E.: Overview of the Coupled Model Intercomparison Project Phase 6 (CMIP6) experimental design and organization, Geosci. Model Dev., 9, 1937–1958, https://doi.org/10.5194/gmd-9-1937-2016, 2016.
Fouquart, Y. and Bonnel, B.: Computations of solar heating of the Earth's atmosphere – A new parameterization, Beitr. Phys. Atmos., 53, 35–62, 1980.
Giorgetta, M. A.: Der Einfluss der quasi-zweijährigen Oszillation: Modellrechnungen mit ECHAM4, Max-Planck-Institut für Meteorologie, Hamburg, Examensarbeit Nr. 40, MPI-Report 218, 1996.
Guillet, S., Corona, C., Stoffel, M., Khodri, M., Lavigne, F., Ortega, P., Eckert, N., Sielenou, P. D., Daux, V., Churakova (Sidorova), O. V., Davi, N., Edouard, J.-L., Zhang, Y., Luckman, B. H., Myglan, V. S., Guiot, J., Beniston, M., Masson-Delmotte, V., and Oppenheimer, C.: Climate response to the Samalas volcanic eruption in 1257 revealed by proxy records, Nat. Geosci., 10, 123–138, https://doi.org/10.1038/ngeo2875, 2017.
Kinnison, D. E., Grant, K. E., Connell, P. S., Rotman, D. A., and Wuebbles, D. J.: The chemical and radiative effects of the Mount Pinatubo eruption, J. Geophys. Res.-Atmos., 99, 25705–25731, https://doi.org/10.1029/94JD02318, 1994.
Kovilakam, M. and Deshler, T.: On the accuracy of stratospheric aerosol extinction derived from in situ size distribution measurements and surface area density derived from remote SAGE II and HALOE extinction measurements, J. Geophys. Res.-Atmos., 120, 8426–8447, https://doi.org/10.1002/2015JD023303, 2015.
Kremser, S., Thomason, L. W., von Hobe, M., Hermann, M., Deshler, T., Timmreck, C., Toohey, M., Stenke, A., Schwarz, J. P., Weigel, R., Fueglistaler, S., Prata, F. J., Vernier, J.-P., Schlager, H., Barnes, J. E., Antuña-Marrero, J.-C., Fairlie, D., Palm, M., Mahieu, E., Notholt, J., Rex, M., Bingen, C., Vanhellemont, F., Bourassa, A., Plane, J. M. C., Klocke, D., Carn, S. A., Clarisse, L., Trickl, T., Neely, R., James, A. D., Rieger, L., Wilson, J. C., and Meland, B.: Stratospheric aerosol–Observations, processes, and impact on climate, Rev. Geophys., 54, 278–335, https://doi.org/10.1002/2015RG000511, 2016.
Kuchar, A., Ball, W. T., Rozanov, E. V., Stenke, A., Revell, L., Miksovsky, J., Pisoft, P., and Peter T.: On the aliasing of the solar cycle in the lower stratospheric tropical temperature, J. Geophys. Res.-Atmos., 122, 907–9093, doi:10.1002/2017JD026948, 2017.
Kuchar, A. and Revell, L.: SOCOLv3 model data for “On the aliasing of the solar cycle in the lower-stratospheric tropical temperature” and “Chemistry-climate model simulations of the Mt. Pinatubo eruption using CCMI and CMIP6 stratospheric aerosol data sets”, https://doi.org/10.17632/khrhbw6wn5.1, 2017.
Labitzke, K. and McCormick, M. P.: Stratospheric temperature increases due to Pinatubo aerosols, Geophys. Res. Lett., 19, 207–210, https://doi.org/10.1029/91GL02940, 1992.
Lamarque, J.-F., Bond, T. C., Eyring, V., Granier, C., Heil, A., Klimont, Z., Lee, D., Liousse, C., Mieville, A., Owen, B., Schultz, M. G., Shindell, D., Smith, S. J., Stehfest, E., Van Aardenne, J., Cooper, O. R., Kainuma, M., Mahowald, N., McConnell, J. R., Naik, V., Riahi, K., and van Vuuren, D. P.: Historical (1850–2000) gridded anthropogenic and biomass burning emissions of reactive gases and aerosols: methodology and application, Atmos. Chem. Phys., 10, 7017–7039, https://doi.org/10.5194/acp-10-7017-2010, 2010.
Löffler, M., Brinkob, S., and Jöckel, P.: Impact of major volcanic eruptions on stratospheric water vapour, Atmos. Chem. Phys., 16, 6547–6562, https://doi.org/10.5194/acp-16-6547-2016, 2016.
Luo, B.: Stratospheric aerosol data for use in CCMI models, available at: ftp://iacftp.ethz.ch/pub_read/luo/ccmi/ (last access: 20 April 2017), 2013.
Mancini, E., Matthes, K., Blume, C., Bodeker, G., Cagnazzo, C., Calvo, N., Charlton-Perrez, A., Douglass, A., Fogli, P. G., Gray, L., Kim, J., Kodera, K., Kunze, M., Pena-Ortiz, C., Randel, B., Reichler, T., Stenchikov, G., Timmreck, C., Toohey, M., and Yoden, S.: Natural Variability of Stratospheric Ozone, in: SPARC Report on the Evaluation of Chemistry-Climate Models, edited by: Eyring, V., Shepherd, T. G., and Waugh, D. W., SPARC Report No. 5, WCRP-132, WMO/TD-No. 1526, available at: http://www.sparc-climate.org/publications/sparc-reports/sparc-report-no5/ (last access: 6 April 2017), 2010.
Masui, T., Matsumoto, K. Hijioka, Y., Kinoshita, T., Nozawa, T., Ishiwatari, S., Kato, E., Shukla, P. R., Yamagata, Y., and Kainuma, M.: An emission pathway for stabilization at 6 Wm−2 radiative forcing, Climatic Change, 109, 59–76, https://doi.org/10.1007/s10584-011-0150-5, 2011.
Meehl, G. A., Washington, W. M., Arblaster, J. M., Hu, A., Teng, H., Kay, J. E., Gettelman, A., Lawrence, D. M., Sanderson, B. M., and Strand, W. G.: Climate change projections in CESM1(CAM5) compared to CCSM4, J. Clim., 26, 6287–6308, https://doi.org/10.1175/JCLI-D-12-00572.1, 2013.
Mills, M. J., Schmidt, A., Easter, R., Solomon, S., Kinnison, D. E., Ghan, S. J., Neely, R. R., Marsh, D. R., Conley, A., Bardeen, C. G., and Gettelman, A.: Global volcanic aerosol properties derived from emissions, 1990–2014, using CESM1(WACCM), J. Geophys. Res.-Atmos., 121, 2232–2348, https://doi.org/10.1002/2015JD02490, 2016.
Mlawer, E. J., Taubman, S. J., Brown, P. D., Iacono, M. J., and Clough, S. A.: Radiative transfer for inhomogeneous atmospheres: RRTM, a validated correlated-k model for the longwave, J. Geophys. Res.-Atmos., 102, 16663–16682, https://doi.org/10.1029/97JD00237, 1997.
Morgenstern, O., Hegglin, M. I., Rozanov, E., O'Connor, F. M., Abraham, N. L., Akiyoshi, H., Archibald, A. T., Bekki, S., Butchart, N., Chipperfield, M. P., Deushi, M., Dhomse, S. S., Garcia, R. R., Hardiman, S. C., Horowitz, L. W., Jöckel, P., Josse, B., Kinnison, D., Lin, M., Mancini, E., Manyin, M. E., Marchand, M., Marécal, V., Michou, M., Oman, L. D., Pitari, G., Plummer, D. A., Revell, L. E., Saint-Martin, D., Schofield, R., Stenke, A., Stone, K., Sudo, K., Tanaka, T. Y., Tilmes, S., Yamashita, Y., Yoshida, K., and Zeng, G.: Review of the global models used within phase 1 of the Chemistry-Climate Model Initiative (CCMI), Geosci. Model Dev., 10, 639–671, https://doi.org/10.5194/gmd-10-639-2017, 2017.
Muthers, S., Arfeuille, F., Raible, C. C., and Rozanov, E.: The impacts of volcanic aerosol on stratospheric ozone and the Northern Hemisphere polar vortex: separating radiative-dynamical changes from direct effects due to enhanced aerosol heterogeneous chemistry, Atmos. Chem. Phys., 15, 11461–11476, https://doi.org/10.5194/acp-15-11461-2015, 2015.
Pitari, G. and Rizi, V.: An estimate of the chemical and radiative perturbation of stratospheric ozone following the eruption of Mt. Pinatubo, J. Atmos. Sci., 50, 3260–3276, https://doi.org/10.1175/1520-0469(1993)050<3260:aeotca>2.0.co;2, 1993.
Pitari, G., Aquila, V., Kravitz, B., Robock, A., Watanabe, S., Cionni, I., Luca, N. D., Genova, G. D., Mancini, E., and Tilmes, S.: Stratospheric ozone response to sulfate geoengineering: Results from the Geoengineering Model Intercomparison Project (GeoMIP), J. Geophys. Res.-Atmos., 119, 2629–2653, https://doi.org/10.1002/2013JD020566, 2014.
Randel, W. J., Wu, F., Russell, J. M., Waters, J. W., and Froidevaux, L.: Ozone and temperature changes in the stratosphere following the eruption of Mount Pinatubo, J. Geophys. Res.-Atmos., 100, 16753–16764, https://doi.org/10.1029/95JD01001, 1995.
Rayner, N. A., Parker, D. E., Horton, E. B., Folland, C. K., Alexander, L. V., Rowell, D. P., Kent, E. C., and Kaplan, A.: Global analyses of sea surface temperature, sea ice, and night marine air temperature since the late nineteenth century, J. Geophys. Res., 108, 4407, https://doi.org/10.1029/2002JD002670, 2003.
Revell, L. E., Bodeker, G. E., Smale, D., Lehmann, R., Huck, P. E., Williamson, B. E., Rozanov, E., and Struthers, H.: The effectiveness of N2O in depleting stratospheric ozone, Geophys. Res. Lett., 39, L15806, https://doi.org/10.1029/2012GL052143, 2012.
Revell, L. E., Tummon, F., Stenke, A., Sukhodolov, T., Coulon, A., Rozanov, E., Garny, H., Grewe, V., and Peter, T.: Drivers of the tropospheric ozone budget throughout the 21st century under the medium-high climate scenario RCP 6.0, Atmos. Chem. Phys., 15, 5887–5902, https://doi.org/10.5194/acp-15-5887-2015, 2015.
Revell, L. E., Stenke, A., Rozanov, E., Ball, W., Lossow, S., and Peter, T.: The role of methane in projections of 21st century stratospheric water vapour, Atmos. Chem. Phys., 16, 13067–13080, https://doi.org/10.5194/acp-16-13067-2016, 2016.
Riahi, K., Rao, S., Krey, V., Cho, C., Chirkov, V., Fischer, G., Kindermann, G., Nakicenovic, N., and Rafaj, P.: RCP 8.5-A scenario of comparatively high greenhouse gas emissions, Climatic Change, 109, 33–57, https://doi.org/10.1007/s10584-011-0149-y, 2011.
Rienecker, M. M., Suarez, M. J., Gelaro, R., Todling, R., Bacmeister, J., Liu, E., Bosilovich, M. G., Schubert, S.D., Takacs, L., Kim, G.-K., Bloom, S., Chen, J., Collins, D., Conaty, A., da Silva, A., Gu, W., Joiner, J., Koster, R. D., Lucchesi, R., Molod, A., Owens, T., Pawson, S., Pegion, P., Redder, C. R., Reichle, R., Robertson, F. R., Ruddick, A. G., Sienkiewicz, M., and Woollen, J.: MERRA: NASA's Modern-Era Retrospective Analysis for Research and Applications, J. Clim., 24, 3624–3648, https://doi.org/10.1175/jcli-d-11-00015.1, 2011.
Robock, A. and Mao, J.: The volcanic signal in surface temperature observations, J. Clim., 8, 1086–1103, https://doi.org/10.1175/1520-0442(1995)008<1086:tvsist>2.0.co;2, 1995.
Robock, A.: Volcanic eruptions and climate, Rev. Geophys., 38, 191–219, https://doi.org/10.1029/1998RG000054, 2000.
Rodriguez, J. M., Ko, M. K. W., and Sze, N. D.: Role of heterogeneous conversion of N2O5 on sulphate aerosols in global ozone losses, Nature, 352, 134–137, https://doi.org/10.1038/352134a0, 1991.
Rosenfield, J. E., Considine, D. B., Meade, P. E., Bacmeister, J. T., Jackman, C. H., and Schoeberl, M. R.: Stratospheric effects of Mount Pinatubo aerosol studied with a coupled two-dimensional model, J. Geophys. Res.-Atmos., 102, 3649–3670, https://doi.org/10.1029/96JD03820, 1997.
Rozanov, E., Schlesinger, M. E., Andronova, N. G., Yang, F., Malyshev, S. L., Zubov, V. A., Egorova, T. A., and Li, B.: Climate/chemistry effects of the Pinatubo volcanic eruption simulated by the UIUC stratosphere/troposphere GCM with interactive photochemistry, J. Geophys. Res., 107, 4594, https://doi.org/10.1029/2001JD000974, 2002.
Solomon, S., Daniel, J. S., Neely, R. R., Vernier, J.-P., Dutton, E. G., and Thomason, L. W.: The persistently variable “background” stratospheric aerosol layer and global climate change, Science, 333, 866–870, https://doi.org/10.1126/science.1206027, 2011.
Son, S.-W., Gerber, E. P., Perlwitz, J., Polvani, L. M., Gillett, N. P., Seo, K.-H., Eyring, V., Shepherd, T. G., Waugh, D., Akiyoshi, H., Austin, J., Baumgaertner, A., Bekki, S., Braesicke, P., Brühl, C., Butchart, N., Chipperfield, M. P., Cugnet, D., Dameris, M., Dhomse, S., Frith, S., Garny, H., Garcia, R., Hardiman, S. C., Jöckel, P., Lamarque, J. F., Mancini, E., Marchand, M., Michou, M., Nakamura, T., Morgenstern, O., Pitari, G., Plummer, D. A., Pyle, J., Rozanov, E., Scinocca, J. F., Shibata, K., Smale, D., Teyssédre, H., Tian, W., and Yamashita, Y.: Impact of stratospheric ozone on Southern Hemisphere circulation change: A multimodel assessment, J. Geophys. Res., 115, D00M07, https://doi.org/10.1029/2010JD014271, 2010.
Stenke, A., Schraner, M., Rozanov, E., Egorova, T., Luo, B., and Peter, T.: The SOCOL version 3.0 chemistry-climate model: description, evaluation, and implications from an advanced transport algorithm, Geosci. Model Dev., 6, 1407–1427, https://doi.org/10.5194/gmd-6-1407-2013, 2013.
Thomason, L. W., Ernest, N., Millán, L., Rieger, L., Bourassa, A., Vernier, J.-P., Manney, G., Luo, B., Arfeuille, F., and Peter, T.: A global, space-based stratospheric aerosol climatology: 1979 to 2016, Earth Syst. Sci. Data Discuss., https://doi.org/10.5194/essd-2017-91, in review, 2017.
Tie, X. and Brasseur, G.: The response of stratospheric ozone to volcanic eruptions: Sensitivity to atmospheric chlorine loading, Geophys. Res. Lett., 22, 3035–3038, https://doi.org/10.1029/95GL03057, 1995.
World Meteorological Organization: Scientific Assessment of Ozone Depletion: 2010, WMO Global Ozone Research and Monitoring Project – Report No. 52, Geneva, Switzerland, 2011.
Zanchettin, D., Khodri, M., Timmreck, C., Toohey, M., Schmidt, A., Gerber, E. P., Hegerl, G., Robock, A., Pausata, F. S. R., Ball, W. T., Bauer, S. E., Bekki, S., Dhomse, S. S., LeGrande, A. N., Mann, G. W., Marshall, L., Mills, M., Marchand, M., Niemeier, U., Poulain, V., Rozanov, E., Rubino, A., Stenke, A., Tsigaridis, K., and Tummon, F.: The Model Intercomparison Project on the climatic response to Volcanic forcing (VolMIP): experimental design and forcing input data for CMIP6, Geosci. Model Dev., 9, 2701–2719, https://doi.org/10.5194/gmd-9-2701-2016, 2016.
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Short summary
Compiling stratospheric aerosol data sets after a major volcanic eruption is difficult as the stratosphere becomes too optically opaque for satellite instruments to measure accurately. We performed ensemble chemistry–climate model simulations with two stratospheric aerosol data sets compiled for two international modelling activities and compared the simulated volcanic aerosol-induced effects from the 1991 Mt Pinatubo eruption on tropical stratospheric temperature and ozone with observations.
Compiling stratospheric aerosol data sets after a major volcanic eruption is difficult as the...
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