Articles | Volume 16, issue 17
https://doi.org/10.5194/acp-16-10879-2016
https://doi.org/10.5194/acp-16-10879-2016
Research article
 | 
01 Sep 2016
Research article |  | 01 Sep 2016

Size-resolved aerosol composition at an urban and a rural site in the Po Valley in summertime: implications for secondary aerosol formation

Silvia Sandrini, Dominik van Pinxteren, Lara Giulianelli, Hartmut Herrmann, Laurent Poulain, Maria Cristina Facchini, Stefania Gilardoni, Matteo Rinaldi, Marco Paglione, Barbara J. Turpin, Francesca Pollini, Silvia Bucci, Nicola Zanca, and Stefano Decesari

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Cited articles

Bertram, T. H., Thornton, J. A., Riedel, T. P., Middlebrook, A. M., Bahreini, R., Bates, T. S., Quinn, P. K., and Coffman, D. J.: Direct observations of N2O5 reactivity on ambient aerosol particles, Geophys. Res. Lett., 36, L19803, https://doi.org/10.1029/2009gl040248, 2009.
Bucci, S., Cairo, F., Cristofanelli, P., Decesari, S., Groess, J., and Fierli, F.: Transport regimes analysis over the Po Valley during summer 2012: impacts on Planetary Boundary Layer variability and aerosol content, in preparation, 2016.
Carbone, C., Decesari, S., Mircea, M., Giulianelli, L., Finessi, E., Rinaldi, M., Fuzzi, S., Marinoni, A., Duchi, R., Perrino, C., Sargolini, T., Varde, M., Sprovieri, F., Gobbi, G. P., Angelini, F., and Facchini, M. C.: Size-resolved aerosol chemical composition over the Italian Peninsula during typical summer and winter conditions, Atmos. Environ., 44, 5269–5278, 2010.
Clegg, S. L., Brimblecombe, P., and Wexler, A. S.: Thermodynamic model of the system H+-NH4+-SO42−-NO3-H2O at tropospheric temperatures, J. Phys. Chem. A, 102, 2137–2154, 1998.
Crosier, J., Allan, J. D., Coe, H., Bower, K. N., Formenti, P., and Williams, P. I.: Chemical composition of summertime aerosol in the Po Valley (Italy), northern Adriatic and Black Sea, Q. J. Roy. Meteor. Soc., 133, 61–75, 2007.
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This paper deals with impactor measurements performed in the summer 2012 during the EU project PEGASOS campaign in the Po Valley, at an urban and a rural site. The paper tries to disentangle the effects of weather anomalies (temporal and spatial) from those of diverse emissions (NH3) and chemical processes on the formation of secondary aerosols in the region, with special focus on nocturnal ammonium nitrate formation and its implications (aqueous formation of secondary organic aerosol).
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