Articles | Volume 14, issue 16
https://doi.org/10.5194/acp-14-8323-2014
https://doi.org/10.5194/acp-14-8323-2014
Research article
 | Highlight paper
 | 
20 Aug 2014
Research article | Highlight paper |  | 20 Aug 2014

Molecular corridors and kinetic regimes in the multiphase chemical evolution of secondary organic aerosol

M. Shiraiwa, T. Berkemeier, K. A. Schilling-Fahnestock, J. H. Seinfeld, and U. Pöschl

Related authors

Surprisingly Robust Photochemistry in Subarctic Particles During Winter: Evidence from Photooxidants
Laura Marie Dahler Heinlein, Junwei He, Michael Oluwatoyin Sunday, Fangzhou Guo, James Campbell, Allison Moon, Sukriti Kapur, Ting Fang, Kasey Edwards, Meeta Cesler-Maloney, Alyssa J. Burns, Jack Dibb, William Simpson, Manabu Shiraiwa, Becky Alexander, Jingqiu Mao, James H. Flynn III, Jochen Stutz, and Cort Anastasio
EGUsphere, https://doi.org/10.5194/egusphere-2025-824,https://doi.org/10.5194/egusphere-2025-824, 2025
This preprint is open for discussion and under review for Atmospheric Chemistry and Physics (ACP).
Short summary
Heterogeneous reaction kinetics influencing benzo(a)pyrene global atmospheric distribution and related lifetime lung cancer risk
Mega Octaviani, Benjamin A. Musa Bandowe, Qing Mu, Jake Wilson, Holger Tost, Hang Su, Yafang Cheng, Manabu Shiraiwa, Ulrich Pöschl, Thomas Berkemeier, and Gerhard Lammel
EGUsphere, https://doi.org/10.5194/egusphere-2025-186,https://doi.org/10.5194/egusphere-2025-186, 2025
This preprint is open for discussion and under review for Atmospheric Chemistry and Physics (ACP).
Short summary
Hydrogen Peroxide Photoformation in Particulate Matter and its Contribution to S(IV) Oxidation During Winter in Fairbanks, Alaska
Michael Oluwatoyin Sunday, Laura Marie Dahler Heinlein, Junwei He, Allison Moon, Sukriti Kapur, Ting Fang, Kasey C. Edwards, Fangzhou Guo, Jack Dibb, James H. Flynn III, Becky Alexander, Manabu Shiraiwa, and Cort Anastasio
EGUsphere, https://doi.org/10.5194/egusphere-2024-3272,https://doi.org/10.5194/egusphere-2024-3272, 2024
Short summary
Secondary organic aerosols derived from intermediate-volatility n-alkanes adopt low-viscous phase state
Tommaso Galeazzo, Bernard Aumont, Marie Camredon, Richard Valorso, Yong B. Lim, Paul J. Ziemann, and Manabu Shiraiwa
Atmos. Chem. Phys., 24, 5549–5565, https://doi.org/10.5194/acp-24-5549-2024,https://doi.org/10.5194/acp-24-5549-2024, 2024
Short summary
Simulated phase state and viscosity of secondary organic aerosols over China
Zhiqiang Zhang, Ying Li, Haiyan Ran, Junling An, Yu Qu, Wei Zhou, Weiqi Xu, Weiwei Hu, Hongbin Xie, Zifa Wang, Yele Sun, and Manabu Shiraiwa
Atmos. Chem. Phys., 24, 4809–4826, https://doi.org/10.5194/acp-24-4809-2024,https://doi.org/10.5194/acp-24-4809-2024, 2024
Short summary

Related subject area

Subject: Aerosols | Research Activity: Laboratory Studies | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
Boosting aerosol surface effects: strongly enhanced cooperative surface propensity of atmospherically relevant organic molecular ions in aqueous solution
Harmanjot Kaur, Stephan Thürmer, Shirin Gholami, Bruno Credidio, Florian Trinter, Debora Vasconcelos, Ricardo Marinho, Joel Pinheiro, Hendrik Bluhm, Arnaldo Naves de Brito, Gunnar Öhrwall, Bernd Winter, and Olle Björneholm
Atmos. Chem. Phys., 25, 3503–3518, https://doi.org/10.5194/acp-25-3503-2025,https://doi.org/10.5194/acp-25-3503-2025, 2025
Short summary
The lifetimes and potential change in planetary albedo owing to the oxidation of thin surfactant organic films extracted from atmospheric aerosol by hydroxyl (OH) radicals at the air–water interface of particles
Rosalie H. Shepherd, Martin D. King, Andrew D. Ward, Edward J. Stuckey, Rebecca J. L. Welbourn, Neil Brough, Adam Milsom, Christian Pfrang, and Thomas Arnold
Atmos. Chem. Phys., 25, 2569–2588, https://doi.org/10.5194/acp-25-2569-2025,https://doi.org/10.5194/acp-25-2569-2025, 2025
Short summary
Exometabolomic exploration of culturable airborne microorganisms from an urban atmosphere
Rui Jin, Wei Hu, Peimin Duan, Ming Sheng, Dandan Liu, Ziye Huang, Mutong Niu, Libin Wu, Junjun Deng, and Pingqing Fu
Atmos. Chem. Phys., 25, 1805–1829, https://doi.org/10.5194/acp-25-1805-2025,https://doi.org/10.5194/acp-25-1805-2025, 2025
Short summary
Measurement Report: Changes in ammonia emissions since the 18th century in south-eastern Europe inferred from an Elbrus (Caucasus, Russia) ice-core record
Michel Legrand, Mstislav Vorobyev, Daria Bokuchava, Stanislav Kutuzov, Andreas Plach, Andreas Stohl, Alexandra Khairedinova, Vladimir Mikhalenko, Maria Vinogradova, Sabine Eckhardt, and Susanne Preunkert
Atmos. Chem. Phys., 25, 1385–1399, https://doi.org/10.5194/acp-25-1385-2025,https://doi.org/10.5194/acp-25-1385-2025, 2025
Short summary
Atmospheric oxidation of 1,3-butadiene: influence of seed aerosol acidity and relative humidity on SOA composition and the production of air toxic compounds
Mohammed Jaoui, Klara Nestorowicz, Krzysztof J. Rudzinski, Michael Lewandowski, Tadeusz E. Kleindienst, Julio Torres, Ewa Bulska, Witold Danikiewicz, and Rafal Szmigielski
Atmos. Chem. Phys., 25, 1401–1432, https://doi.org/10.5194/acp-25-1401-2025,https://doi.org/10.5194/acp-25-1401-2025, 2025
Short summary

Cited articles

Abramson, E., Imre, D., Beranek, J., Wilson, J. M., and Zelenyuk, A.: Experimental determination of chemical diffusion within secondary organic aerosol particles, Phys. Chem. Chem. Phys., 15, 2983–2991, 2013.
Berkemeier, T., Huisman, A. J., Ammann, M., Shiraiwa, M., Koop, T., and Pöschl, U.: Kinetic regimes and limiting cases of gas uptake and heterogeneous reactions in atmospheric aerosols and clouds: a general classification scheme, Atmos. Chem. Phys., 13, 6663–6686, https://doi.org/10.5194/acp-13-6663-2013, 2013.
Bertram, A. K., Ivanov, A. V., Hunter, M., Molina, L. T., and Molina, M. J.: The reaction probability of OH on organic surfaces of tropospheric interest, J. Phys. Chem. A, 105, 9415–9421, 2001.
Bilde, M., Svenningsson, B., Monster, J., and Rosenorn, T.: Even-odd alternation of evaporation rates and vapor pressures of C3-C9 dicarboxylic acid aerosols, Environ. Sci. Technol., 37, 1371–1378, 2003.
Bird, R. B., Stewart, W. E., and Lightfoot, E. N.: Transport Phenomena, 2nd edition, John Wiley & Sons, Inc., New York, 2007.
Download
Share
Altmetrics
Final-revised paper
Preprint