Articles | Volume 23, issue 12
https://doi.org/10.5194/acp-23-6633-2023
https://doi.org/10.5194/acp-23-6633-2023
Measurement report
 | 
19 Jun 2023
Measurement report |  | 19 Jun 2023

Measurement report: Underestimated reactive organic gases from residential combustion – insights from a near-complete speciation

Yaqin Gao, Hongli Wang, Lingling Yuan, Shengao Jing, Bin Yuan, Guofeng Shen, Liang Zhu, Abigail Koss, Yingjie Li, Qian Wang, Dan Dan Huang, Shuhui Zhu, Shikang Tao, Shengrong Lou, and Cheng Huang

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Revised manuscript not accepted
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Cited articles

Akherati, A., He, Y., Coggon, M. M., Koss, A. R., Hodshire, A. L., Sekimoto, K., Warneke, C., de Gouw, J., Yee, L., Seinfeld, J. H., Onasch, T. B., Herndon, S. C., Knighton, W. B., Cappa, C. D., Kleeman, M. J., Lim, C. Y., Kroll, J. H., Pierce, J. R., and Jathar, S. H.: Oxygenated aromatic compounds are important precursors of secondary organic aerosol in biomass-burning emissions, Environ. Sci. Technol., 54, 8568–8579, https://doi.org/10.1021/acs.est.0c01345, 2020. 
Arnold, S. T., Viggiano, A. A., and Morris, R. A.: Rate constants and product branching fractions for the reactions of H3O+ and NO+ with C2–C12 alkanes, J. Phys. Chem. A, 102, 8881–8887, https://doi.org/10.1021/jp9815457, 1998. 
Batterman, S. A., Zhang, G.-Z., and Baumann, M.: Analysis and stability of aldehydes and terpenes in electropolished canisters, Atmos. Environ., 32, 1647–1655, https://doi.org/10.1016/S1352-2310(97)00417-2, 1998. 
Bruns, E. A., El Haddad, I., Slowik, J. G., Kilic, D., Klein, F., Baltensperger, U., and Prevot, A. S. H.: Identification of significant precursor gases of secondary organic aerosols from residential wood combustion, Sci. Rep.-UK, 6, 27881, https://doi.org/10.1038/srep27881, 2016. 
Bruns, E. A., Slowik, J. G., El Haddad, I., Kilic, D., Klein, F., Dommen, J., Temime-Roussel, B., Marchand, N., Baltensperger, U., and Prévôt, A. S. H.: Characterization of gas-phase organics using proton transfer reaction time-of-flight mass spectrometry: fresh and aged residential wood combustion emissions, Atmos. Chem. Phys., 17, 705–720, https://doi.org/10.5194/acp-17-705-2017, 2017. 
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A near-complete speciation of reactive organic gases from residential combustion was developed to get more insights into their atmospheric effects. Oxygenated species, higher hydrocarbons and nitrogen-containing species played larger roles in these emissions compared with common hydrocarbons. Based on the near-complete speciation, these emissions were largely underestimated, leading to more underestimation of their hydroxyl radical reactivity and secondary organic aerosol formation potential.
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