Articles | Volume 22, issue 1
https://doi.org/10.5194/acp-22-65-2022
https://doi.org/10.5194/acp-22-65-2022
Research article
 | 
03 Jan 2022
Research article |  | 03 Jan 2022

New investigations on homogeneous ice nucleation: the effects of water activity and water saturation formulations

Manuel Baumgartner, Christian Rolf, Jens-Uwe Grooß, Julia Schneider, Tobias Schorr, Ottmar Möhler, Peter Spichtinger, and Martina Krämer

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Cited articles

Baumgartner, M. and Spichtinger, P.: Homogeneous nucleation from an asymptotic point of view, Theor. Comput. Fluid Dynam., 33, 83–106, https://doi.org/10.1007/s00162-019-00484-0, 2019. a, b
Berkemeier, T., Shiraiwa, M., Pöschl, U., and Koop, T.: Competition between water uptake and ice nucleation by glassy organic aerosol particles, Atmos. Chem. Phys., 14, 12513–12531, https://doi.org/10.5194/acp-14-12513-2014, 2014. a, b
Bullock, G. and Molinero, V.: Low-density liquid water is the mother of ice: on the relation between mesostructure, thermodynamics and ice crystallization in solutions, Faraday Discuss., 167, 371–388, https://doi.org/10.1039/C3FD00085K, 2013. a
Bunz, H., Benz, S., Gensch, I., and Krämer, M.: MAID: a model to simulate UT/LS aerosols and ice clouds, Environ. Res. Lett., 3, 035001, https://doi.org/10.1088/1748-9326/3/3/035001, 2008. a
Carslaw, K. S., Clegg, S. L., and Brimblecombe, P.: A Thermodynamic Model of the System HCl-HNO3-H2SO4-H2O, Including Solubilities of HBr, from <200 to 328 K, J. Phys. Chem., 99, 11557–11574, https://doi.org/10.1021/j100029a039, 1995. a, b, c, d
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An important mechanism for the appearance of ice particles in the upper troposphere at low temperatures is homogeneous nucleation. This process is commonly described by the Koop line, predicting the humidity at freezing. However, laboratory measurements suggest that the freezing humidities are above the Koop line, motivating the present study to investigate the influence of different physical parameterizations on the homogeneous freezing with the help of a detailed numerical model.
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