Articles | Volume 14, issue 23
Atmos. Chem. Phys., 14, 13145–13158, 2014

Special issue: Results from the ice nucleation research unit (INUIT) (ACP/AMT...

Atmos. Chem. Phys., 14, 13145–13158, 2014

Research article 10 Dec 2014

Research article | 10 Dec 2014

A comprehensive parameterization of heterogeneous ice nucleation of dust surrogate: laboratory study with hematite particles and its application to atmospheric models

N. Hiranuma1, M. Paukert1, I. Steinke1, K. Zhang2, G. Kulkarni2, C. Hoose1, M. Schnaiter1, H. Saathoff1, and O. Möhler1 N. Hiranuma et al.
  • 1Institute for Meteorology and Climate Research – Atmospheric Aerosol Research, Karlsruhe Institute of Technology, Karlsruhe, Germany
  • 2Atmospheric Science and Global Change Division, Pacific Northwest National Laboratory, Richland, Washington, USA

Abstract. A new heterogeneous ice nucleation parameterization that covers a wide temperature range (−36 to −78 °C) is presented. Developing and testing such an ice nucleation parameterization, which is constrained through identical experimental conditions, is important to accurately simulate the ice nucleation processes in cirrus clouds. The ice nucleation active surface-site density (ns) of hematite particles, used as a proxy for atmospheric dust particles, were derived from AIDA (Aerosol Interaction and Dynamics in the Atmosphere) cloud chamber measurements under water subsaturated conditions. These conditions were achieved by continuously changing the temperature (T) and relative humidity with respect to ice (RHice) in the chamber. Our measurements showed several different pathways to nucleate ice depending on T and RHice conditions. For instance, almost T-independent freezing was observed at −60 °C < T < −50 °C, where RHice explicitly controlled ice nucleation efficiency, while both T and RHice played roles in other two T regimes: −78 °C < T < −60 °C and −50 °C < T < −36 °C. More specifically, observations at T lower than −60 °C revealed that higher RHice was necessary to maintain a constant ns, whereas T may have played a significant role in ice nucleation at T higher than −50 °C. We implemented the new hematite-derived ns parameterization, which agrees well with previous AIDA measurements of desert dust, into two conceptual cloud models to investigate their sensitivity to the new parameterization in comparison to existing ice nucleation schemes for simulating cirrus cloud properties. Our results show that the new AIDA-based parameterization leads to an order of magnitude higher ice crystal concentrations and to an inhibition of homogeneous nucleation in lower-temperature regions. Our cloud simulation results suggest that atmospheric dust particles that form ice nuclei at lower temperatures, below −36 °C, can potentially have a stronger influence on cloud properties, such as cloud longevity and initiation, compared to previous parameterizations.

Short summary
A new heterogeneous ice nucleation parameterization is developed and implemented in cloud models. The results of our simulations suggest stronger influence of dust particles lifted to the upper troposphere on heterogeneous nucleation and more ice nucleation at temperature and humidity conditions relevant to both mixed-phase and cirrus clouds when compared to the existing parametrical frameworks.
Final-revised paper