Articles | Volume 22, issue 4
https://doi.org/10.5194/acp-22-2569-2022
https://doi.org/10.5194/acp-22-2569-2022
Research article
 | 
25 Feb 2022
Research article |  | 25 Feb 2022

Long-term fluxes of carbonyl sulfide and their seasonality and interannual variability in a boreal forest

Timo Vesala, Kukka-Maaria Kohonen, Linda M. J. Kooijmans, Arnaud P. Praplan, Lenka Foltýnová, Pasi Kolari, Markku Kulmala, Jaana Bäck, David Nelson, Dan Yakir, Mark Zahniser, and Ivan Mammarella

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Cited articles

Aalto, J., Aalto, P., Keronen, P., Kolari, P., Rantala, P., Taipale, R., Kajos, M., Patokoski, J., Rinne, J., Ruuskanen, T., Leskinen, M., Laakso, H., Levula, J., Pohja, T., Siivola, E., and Kulmala, M.: SMEAR II Hyytiälä forest meteorology, greenhouse gases, air quality and soil (Version 1), University of Helsinki, Institute for Atmospheric and Earth System Research [data set], http://urn.fi/urn:nbn:fi:att:a8e81c0e-2838-4df4-9589-74a4240138f8, 2019. 
Asaf, D., Rotenberg, E., Tatarinov, F., Dicken, U., Montzka, S. A., and Yakir, D.: Ecosystem photosynthesis inferred from measurements of carbonyl sulphide flux, Nat. Geosci., 6, 186–190, https://doi.org/10.1038/ngeo1730, 2013. 
Ball, J. T., Woodrow, I. E., and Berry, J. A.: A model predicting stomatal conductance and its contribution to the control of photosynthesis under different environmental conditions, in: Progress in Photosynthesis Research, edited by: Biggens J., Springer, Dordrecht, the Netherlands, vol. 4, 221–224, https://doi.org/10.1007/978-94-017-0519-6_48, 1987. 
Berry, J., Wolf, A., Campbell, J. E., Baker, I., Blake, N., Blake, D., Denning, A. S., Kawa, S. R., Montzka, S. A., Seibt, U., Stimler, K., Yakir, D., and Zhu, Z.: A coupled model of the global cycles of carbonyl sulfide and CO2: A possible new window on the carbon cycle. J. Geophys. Res.-Biogeo., 118, 842–852, 2013. 
Billesbach, D. P., Berry, J. A., Seibt, U., Maseyk, K., Torn, M. S., Fischer, M. L., Abu-Naser, M., and Campbell, J. E.: Growing season eddy covariance measurements of carbonyl sulfide and CO2 fluxes: COS and CO2 relationships in Southern Great Plains winter wheat, Agr. Forest Meteorol., 184, 48–55, 2014. 
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Carbonyl sulfide (COS) provides new insights into carbon cycle research. We present an easy-to-use flux parameterization and the longest existing time series of forest–atmosphere COS exchange measurements, which allow us to study both seasonal and interannual variability. We observed only uptake of COS by the forest on an annual basis, with 37 % variability between years. Upscaling the boreal COS uptake using a biosphere model indicates a significant missing COS sink at high latitudes.
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