Articles | Volume 21, issue 20
https://doi.org/10.5194/acp-21-16067-2021
https://doi.org/10.5194/acp-21-16067-2021
Research article
 | 
29 Oct 2021
Research article |  | 29 Oct 2021

Atmospheric photo-oxidation of myrcene: OH reaction rate constant, gas-phase oxidation products and radical budgets

Zhaofeng Tan, Luisa Hantschke, Martin Kaminski, Ismail-Hakki Acir, Birger Bohn, Changmin Cho, Hans-Peter Dorn, Xin Li, Anna Novelli, Sascha Nehr, Franz Rohrer, Ralf Tillmann, Robert Wegener, Andreas Hofzumahaus, Astrid Kiendler-Scharr, Andreas Wahner, and Hendrik Fuchs

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Cited articles

Allen, H. M., Crounse, J. D., Bates, K. H., Teng, A. P., Krawiec-Thayer, M. P., Rivera-Rios, J. C., Keutsch, F. N., St. Clair, J. M., Hanisco, T. F., Møller, K. H., Kjaergaard, H. G., and Wennberg, P. O.: Kinetics and product yields of the OH initiated oxidation of hydroxymethyl hydroperoxide, J. Phys. Chem. A, 122, 6292–6302, https://doi.org/10.1021/acs.jpca.8b04577, 2018. a
Aschmann, S. M., Atkinson, R., and Arey, J.: Products of reaction of OH radicals with α-pinene, J. Geophys. Res., 107, ACH 6-1–ACH 6-7, https://doi.org/10.1029/2001JD001098, 2002. a, b
Atkinson, R.: Gase-phase tropospheric chemistry of volatile organic compounds: 1. alkanes and alkenes, J. Phys. Chem. Ref. Data, 26, 217–290, 1997. a
Atkinson, R. and Arey, J.: Atmospheric degradation of volatile organic compounds, Chem. Rev., 103, 4605–4638, https://doi.org/10.1021/cr0206420, 2003. a
Atkinson, R., Aschmann, S. M., and Pitts, J. N.: Rate constants for the gas-phase reactions of the OH radical with a series of monoterpenes at 294±1 K, Int. J. Chem. Kinet., 18, 287–299, https://doi.org/10.1002/kin.550180303, 1986. a, b, c, d, e