Articles | Volume 21, issue 20
https://doi.org/10.5194/acp-21-16067-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-21-16067-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
29 Oct 2021
Research article |
| 29 Oct 2021
| 29 Oct 2021
Atmospheric photo-oxidation of myrcene: OH reaction rate constant, gas-phase oxidation products and radical budgets
Zhaofeng Tan
Institute of Energy and Climate Research, Troposphere (IEK-8), Forschungszentrum Jülich GmbH, Jülich, Germany
Luisa Hantschke
Institute of Energy and Climate Research, Troposphere (IEK-8), Forschungszentrum Jülich GmbH, Jülich, Germany
Martin Kaminski
Institute of Energy and Climate Research, Troposphere (IEK-8), Forschungszentrum Jülich GmbH, Jülich, Germany
now at: Department 5 – Method Standardisation, Reference Laboratories, Resistance to
Antibiotics, Federal Office of Consumer Protection and Food Safety, Berlin, Germany
Ismail-Hakki Acir
Institute of Energy and Climate Research, Troposphere (IEK-8), Forschungszentrum Jülich GmbH, Jülich, Germany
now at: Institute of Nutrition and Food Sciences, Food Science, University of Bonn, Bonn, Germany
Birger Bohn
Institute of Energy and Climate Research, Troposphere (IEK-8), Forschungszentrum Jülich GmbH, Jülich, Germany
Changmin Cho
Institute of Energy and Climate Research, Troposphere (IEK-8), Forschungszentrum Jülich GmbH, Jülich, Germany
Hans-Peter Dorn
Institute of Energy and Climate Research, Troposphere (IEK-8), Forschungszentrum Jülich GmbH, Jülich, Germany
Institute of Energy and Climate Research, Troposphere (IEK-8), Forschungszentrum Jülich GmbH, Jülich, Germany
now at: State Key Joint Laboratory of Environmental Simulation and Pollution Control, College of Environmental Sciences and Engineering, Peking University, Beijing, China
Anna Novelli
Institute of Energy and Climate Research, Troposphere (IEK-8), Forschungszentrum Jülich GmbH, Jülich, Germany
Sascha Nehr
Institute of Energy and Climate Research, Troposphere (IEK-8), Forschungszentrum Jülich GmbH, Jülich, Germany
now at: European University of Applied Sciences, Brühl, Germany
Franz Rohrer
Institute of Energy and Climate Research, Troposphere (IEK-8), Forschungszentrum Jülich GmbH, Jülich, Germany
Ralf Tillmann
Institute of Energy and Climate Research, Troposphere (IEK-8), Forschungszentrum Jülich GmbH, Jülich, Germany
Robert Wegener
Institute of Energy and Climate Research, Troposphere (IEK-8), Forschungszentrum Jülich GmbH, Jülich, Germany
Andreas Hofzumahaus
Institute of Energy and Climate Research, Troposphere (IEK-8), Forschungszentrum Jülich GmbH, Jülich, Germany
Astrid Kiendler-Scharr
Institute of Energy and Climate Research, Troposphere (IEK-8), Forschungszentrum Jülich GmbH, Jülich, Germany
Andreas Wahner
Institute of Energy and Climate Research, Troposphere (IEK-8), Forschungszentrum Jülich GmbH, Jülich, Germany
Institute of Energy and Climate Research, Troposphere (IEK-8), Forschungszentrum Jülich GmbH, Jülich, Germany
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Cited
11 citations as recorded by crossref.
- Chemical Composition of Aerosols from the E-Cigarette Vaping of Natural and Synthetic Cannabinoids N. Robertson et al.
- 大气HOx自由基光谱学探测技术进展（特邀） 胡. Hu Renzhi et al.
- Investigation of the limonene photooxidation by OH at different NO concentrations in the atmospheric simulation chamber SAPHIR (Simulation of Atmospheric PHotochemistry In a large Reaction Chamber) J. Pang et al.
- Comparison of isoprene chemical mechanisms under atmospheric night-time conditions in chamber experiments: evidence of hydroperoxy aldehydes and epoxy products from NO3 oxidation P. Carlsson et al.
- Emerging investigator series: secondary organic aerosol formation from photooxidation of acyclic terpenes in an oxidation flow reactor S. Gu et al.
- Distinct Roles of NO2 versus NO and Synergisms with SO2 in Secondary Organic Aerosol Formation from β-Myrcene Photooxidation Y. Zhao et al.
- Handheld Crop Pest Sensor Using Binary Catalyst-Loaded Nano-SnO2 Particles for Oxidative Signal Amplification P. Kumar et al.
- Comparison of oxidation products generated from the reaction of α-pinene with hydroxyl radicals, chlorine atoms, and bromine atoms measured using ammonium adduct chemical ionization mass spectrometry A. Lambe et al.
- Hydroxyl Radical-Initiated Reaction of Nerol: A Pathway to Secondary Pollutants in an Indoor Environment A. Mano Priya & G. El Dib
- Photokinetics of Bimolecular Reactions: Analytically Solvable Rate Laws M. Maafi
- Particle Formation from Photooxidation of αpinene, Limonene, and Myrcene D. Hanson et al.
11 citations as recorded by crossref.
- Chemical Composition of Aerosols from the E-Cigarette Vaping of Natural and Synthetic Cannabinoids N. Robertson et al.
- 大气HOx自由基光谱学探测技术进展（特邀） 胡. Hu Renzhi et al.
- Investigation of the limonene photooxidation by OH at different NO concentrations in the atmospheric simulation chamber SAPHIR (Simulation of Atmospheric PHotochemistry In a large Reaction Chamber) J. Pang et al.
- Comparison of isoprene chemical mechanisms under atmospheric night-time conditions in chamber experiments: evidence of hydroperoxy aldehydes and epoxy products from NO3 oxidation P. Carlsson et al.
- Emerging investigator series: secondary organic aerosol formation from photooxidation of acyclic terpenes in an oxidation flow reactor S. Gu et al.
- Distinct Roles of NO2 versus NO and Synergisms with SO2 in Secondary Organic Aerosol Formation from β-Myrcene Photooxidation Y. Zhao et al.
- Handheld Crop Pest Sensor Using Binary Catalyst-Loaded Nano-SnO2 Particles for Oxidative Signal Amplification P. Kumar et al.
- Comparison of oxidation products generated from the reaction of α-pinene with hydroxyl radicals, chlorine atoms, and bromine atoms measured using ammonium adduct chemical ionization mass spectrometry A. Lambe et al.
- Hydroxyl Radical-Initiated Reaction of Nerol: A Pathway to Secondary Pollutants in an Indoor Environment A. Mano Priya & G. El Dib
- Photokinetics of Bimolecular Reactions: Analytically Solvable Rate Laws M. Maafi
- Particle Formation from Photooxidation of αpinene, Limonene, and Myrcene D. Hanson et al.
Saved (final revised paper)
Latest update: 06 May 2026
Short summary
The photo-oxidation of myrcene, a monoterpene species emitted by plants, was investigated at atmospheric conditions in the outdoor simulation chamber SAPHIR. The chemical structure of myrcene is partly similar to isoprene. Therefore, it can be expected that hydrogen shift reactions could play a role as observed for isoprene. In this work, their potential impact on the regeneration efficiency of hydroxyl radicals is investigated.
The photo-oxidation of myrcene, a monoterpene species emitted by plants, was investigated at...
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