Articles | Volume 24, issue 12
https://doi.org/10.5194/acp-24-7101-2024
© Author(s) 2024. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-24-7101-2024
© Author(s) 2024. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
20 Jun 2024
Research article |
| 20 Jun 2024
| 20 Jun 2024
Emission characteristics of reactive organic gases (ROGs) from industrial volatile chemical products (VCPs) in the Pearl River Delta (PRD), China
Sihang Wang
College of Environment and Climate, Institute for Environmental and Climate Research, Guangdong–Hong Kong–Macau Joint Laboratory of Collaborative Innovation for Environmental Quality, Jinan University, Guangzhou 511443, China
College of Environment and Climate, Institute for Environmental and Climate Research, Guangdong–Hong Kong–Macau Joint Laboratory of Collaborative Innovation for Environmental Quality, Jinan University, Guangzhou 511443, China
Xianjun He
College of Environment and Climate, Institute for Environmental and Climate Research, Guangdong–Hong Kong–Macau Joint Laboratory of Collaborative Innovation for Environmental Quality, Jinan University, Guangzhou 511443, China
Ru Cui
College of Environment and Climate, Institute for Environmental and Climate Research, Guangdong–Hong Kong–Macau Joint Laboratory of Collaborative Innovation for Environmental Quality, Jinan University, Guangzhou 511443, China
now at: Nanjing Intelligent Environmental Science and Technology Co.Ltd, Nanjing 211800, China
College of Environment and Climate, Institute for Environmental and Climate Research, Guangdong–Hong Kong–Macau Joint Laboratory of Collaborative Innovation for Environmental Quality, Jinan University, Guangzhou 511443, China
Yubin Chen
College of Environment and Climate, Institute for Environmental and Climate Research, Guangdong–Hong Kong–Macau Joint Laboratory of Collaborative Innovation for Environmental Quality, Jinan University, Guangzhou 511443, China
Caihong Wu
College of Environment and Climate, Institute for Environmental and Climate Research, Guangdong–Hong Kong–Macau Joint Laboratory of Collaborative Innovation for Environmental Quality, Jinan University, Guangzhou 511443, China
Chaomin Wang
College of Environment and Climate, Institute for Environmental and Climate Research, Guangdong–Hong Kong–Macau Joint Laboratory of Collaborative Innovation for Environmental Quality, Jinan University, Guangzhou 511443, China
Yibo Huangfu
College of Environment and Climate, Institute for Environmental and Climate Research, Guangdong–Hong Kong–Macau Joint Laboratory of Collaborative Innovation for Environmental Quality, Jinan University, Guangzhou 511443, China
Xiao-Bing Li
College of Environment and Climate, Institute for Environmental and Climate Research, Guangdong–Hong Kong–Macau Joint Laboratory of Collaborative Innovation for Environmental Quality, Jinan University, Guangzhou 511443, China
Boguang Wang
College of Environment and Climate, Institute for Environmental and Climate Research, Guangdong–Hong Kong–Macau Joint Laboratory of Collaborative Innovation for Environmental Quality, Jinan University, Guangzhou 511443, China
Min Shao
College of Environment and Climate, Institute for Environmental and Climate Research, Guangdong–Hong Kong–Macau Joint Laboratory of Collaborative Innovation for Environmental Quality, Jinan University, Guangzhou 511443, China
Related authors
Xiao-Bing Li, Bin Yuan, Yibo Huangfu, Suxia Yang, Xin Song, Jipeng Qi, Xianjun He, Sihang Wang, Yubin Chen, Qing Yang, Yongxin Song, Yuwen Peng, Guiqian Tang, Jian Gao, and Min Shao
EGUsphere, https://doi.org/10.5194/egusphere-2024-2755, https://doi.org/10.5194/egusphere-2024-2755, 2024
This preprint is open for discussion and under review for Atmospheric Chemistry and Physics (ACP).
Short summary
Short summary
Online vertical gradient measurements of volatile organic compounds (VOCs), ozone, and NOx were made based on a 325 m tower in urban Beijing. Vertical changes in concentrations, compositions, key drivers, and environmental impacts of VOCs were analyzed in this study. We find that VOC species display differentiated vertical variation patterns and distinct roles in contributing to photochemical ozone formation with increasing height in the urban planetary boundary layer.
Wenjie Wang, Bin Yuan, Hang Su, Yafang Cheng, Jipeng Qi, Sihang Wang, Wei Song, Xinming Wang, Chaoyang Xue, Chaoqun Ma, Fengxia Bao, Hongli Wang, Shengrong Lou, and Min Shao
Atmos. Chem. Phys., 24, 4017–4027, https://doi.org/10.5194/acp-24-4017-2024, https://doi.org/10.5194/acp-24-4017-2024, 2024
Short summary
Short summary
This study investigates the important role of unmeasured volatile organic compounds (VOCs) in ozone formation. Based on results in a megacity of China, we show that unmeasured VOCs can contribute significantly to ozone fomation and also influence the determination of ozone control strategy. Our results show that these unmeasured VOCs are mainly from human sources.
Yiyu Cai, Chenshuo Ye, Wei Chen, Weiwei Hu, Wei Song, Yuwen Peng, Shan Huang, Jipeng Qi, Sihang Wang, Chaomin Wang, Caihong Wu, Zelong Wang, Baolin Wang, Xiaofeng Huang, Lingyan He, Sasho Gligorovski, Bin Yuan, Min Shao, and Xinming Wang
Atmos. Chem. Phys., 23, 8855–8877, https://doi.org/10.5194/acp-23-8855-2023, https://doi.org/10.5194/acp-23-8855-2023, 2023
Short summary
Short summary
We studied the variability and molecular composition of ambient oxidized organic nitrogen (OON) in both gas and particle phases using a state-of-the-art online mass spectrometer in urban air. Biomass burning and secondary formation were found to be the two major sources of OON. Daytime nitrate radical chemistry for OON formation was more important than previously thought. Our results improved the understanding of the sources and molecular composition of OON in the polluted urban atmosphere.
Yubin Chen, Bin Yuan, Chaomin Wang, Sihang Wang, Xianjun He, Caihong Wu, Xin Song, Yibo Huangfu, Xiao-Bing Li, Yijia Liao, and Min Shao
Atmos. Meas. Tech., 15, 6935–6947, https://doi.org/10.5194/amt-15-6935-2022, https://doi.org/10.5194/amt-15-6935-2022, 2022
Short summary
Short summary
In this study, we demonstrate that selective online measurements of cycloalkanes can be achieved using proton transfer reaction time-of-flight mass spectrometry with NO+ chemical ionization (NO+ PTR-ToF-MS), with fast response and low detection limits. Applications of this method in both urban air and emission sources will be shown.
Haichao Wang, Bin Yuan, E Zheng, Xiaoxiao Zhang, Jie Wang, Keding Lu, Chenshuo Ye, Lei Yang, Shan Huang, Weiwei Hu, Suxia Yang, Yuwen Peng, Jipeng Qi, Sihang Wang, Xianjun He, Yubin Chen, Tiange Li, Wenjie Wang, Yibo Huangfu, Xiaobing Li, Mingfu Cai, Xuemei Wang, and Min Shao
Atmos. Chem. Phys., 22, 14837–14858, https://doi.org/10.5194/acp-22-14837-2022, https://doi.org/10.5194/acp-22-14837-2022, 2022
Short summary
Short summary
We present intensive field measurement of ClNO2 in the Pearl River Delta in 2019. Large variation in the level, formation, and atmospheric impacts of ClNO2 was found in different air masses. ClNO2 formation was limited by the particulate chloride (Cl−) and aerosol surface area. Our results reveal that Cl− originated from various anthropogenic emissions rather than sea sources and show minor contribution to the O3 pollution and photochemistry.
Xiao-Bing Li, Bin Yuan, Sihang Wang, Chunlin Wang, Jing Lan, Zhijie Liu, Yongxin Song, Xianjun He, Yibo Huangfu, Chenglei Pei, Peng Cheng, Suxia Yang, Jipeng Qi, Caihong Wu, Shan Huang, Yingchang You, Ming Chang, Huadan Zheng, Wenda Yang, Xuemei Wang, and Min Shao
Atmos. Chem. Phys., 22, 10567–10587, https://doi.org/10.5194/acp-22-10567-2022, https://doi.org/10.5194/acp-22-10567-2022, 2022
Short summary
Short summary
High-time-resolution measurements of volatile organic compounds (VOCs) were made using an online mass spectrometer at a 600 m tall tower in urban region. Compositions, temporal variations, and sources of VOCs were quantitatively investigated in this study. We find that VOC measurements in urban regions aloft could better characterize source characteristics of anthropogenic emissions. Our results could provide important implications in making future strategies for control of VOCs.
Sihang Wang, Bin Yuan, Caihong Wu, Chaomin Wang, Tiange Li, Xianjun He, Yibo Huangfu, Jipeng Qi, Xiao-Bing Li, Qing'e Sha, Manni Zhu, Shengrong Lou, Hongli Wang, Thomas Karl, Martin Graus, Zibing Yuan, and Min Shao
Atmos. Chem. Phys., 22, 9703–9720, https://doi.org/10.5194/acp-22-9703-2022, https://doi.org/10.5194/acp-22-9703-2022, 2022
Short summary
Short summary
Volatile organic compound (VOC) emissions from vehicles are measured using online mass spectrometers. Differences between gasoline and diesel vehicles are observed with higher emission factors of most oxygenated VOCs (OVOCs) and heavier aromatics from diesel vehicles. A higher aromatics / toluene ratio could provide good indicators to distinguish emissions from both vehicle types. We show that OVOCs account for significant contributions to VOC emissions from vehicles, especially diesel vehicles.
Suxia Yang, Bin Yuan, Yuwen Peng, Shan Huang, Wei Chen, Weiwei Hu, Chenglei Pei, Jun Zhou, David D. Parrish, Wenjie Wang, Xianjun He, Chunlei Cheng, Xiao-Bing Li, Xiaoyun Yang, Yu Song, Haichao Wang, Jipeng Qi, Baolin Wang, Chen Wang, Chaomin Wang, Zelong Wang, Tiange Li, E Zheng, Sihang Wang, Caihong Wu, Mingfu Cai, Chenshuo Ye, Wei Song, Peng Cheng, Duohong Chen, Xinming Wang, Zhanyi Zhang, Xuemei Wang, Junyu Zheng, and Min Shao
Atmos. Chem. Phys., 22, 4539–4556, https://doi.org/10.5194/acp-22-4539-2022, https://doi.org/10.5194/acp-22-4539-2022, 2022
Short summary
Short summary
We use a model constrained using observations to study the formation of nitrate aerosol in and downwind of a representative megacity. We found different contributions of various chemical reactions to ground-level nitrate concentrations between urban and suburban regions. We also show that controlling VOC emissions are effective for decreasing nitrate formation in both urban and regional environments, although VOCs are not direct precursors of nitrate aerosol.
Ye Kuang, Shan Huang, Biao Xue, Biao Luo, Qicong Song, Wei Chen, Weiwei Hu, Wei Li, Pusheng Zhao, Mingfu Cai, Yuwen Peng, Jipeng Qi, Tiange Li, Sihang Wang, Duohong Chen, Dingli Yue, Bin Yuan, and Min Shao
Atmos. Chem. Phys., 21, 10375–10391, https://doi.org/10.5194/acp-21-10375-2021, https://doi.org/10.5194/acp-21-10375-2021, 2021
Short summary
Short summary
We found that organic aerosol factors with identified sources perform much better than oxidation level parameters in characterizing variations in organic aerosol hygroscopicity, and secondary aerosol formations associated with different sources have distinct effects on organic aerosol hygroscopicity. It reveals that source-oriented organic aerosol hygroscopicity investigations might result in more appropriate parameterization approaches in chemical and climate models.
Wenjie Wang, Jipeng Qi, Jun Zhou, Bin Yuan, Yuwen Peng, Sihang Wang, Suxia Yang, Jonathan Williams, Vinayak Sinha, and Min Shao
Atmos. Meas. Tech., 14, 2285–2298, https://doi.org/10.5194/amt-14-2285-2021, https://doi.org/10.5194/amt-14-2285-2021, 2021
Short summary
Short summary
We designed a new reactor for measurements of OH reactivity (i.e., OH radical loss frequency) based on the comparative reactivity method under
high-NOx conditions, such as in cities. We performed a series of laboratory tests to evaluate the new reactor. The new reactor was used in the field and performed well in measuring OH reactivity in air influenced by upwind cities.
Caihong Wu, Chaomin Wang, Sihang Wang, Wenjie Wang, Bin Yuan, Jipeng Qi, Baolin Wang, Hongli Wang, Chen Wang, Wei Song, Xinming Wang, Weiwei Hu, Shengrong Lou, Chenshuo Ye, Yuwen Peng, Zelong Wang, Yibo Huangfu, Yan Xie, Manni Zhu, Junyu Zheng, Xuemei Wang, Bin Jiang, Zhanyi Zhang, and Min Shao
Atmos. Chem. Phys., 20, 14769–14785, https://doi.org/10.5194/acp-20-14769-2020, https://doi.org/10.5194/acp-20-14769-2020, 2020
Short summary
Short summary
Based on measurements from an online mass spectrometer, we quantify volatile organic compound (VOC) concentrations from numerous ions of the mass spectrometer, using information from laboratory-obtained calibration results. We find that most VOC concentrations are from oxygenated VOCs (OVOCs). We further show that these OVOCs also contribute significantly to OH reactivity. Our results suggest the important role of OVOCs in VOC emissions and chemistry in urban air.
Chaomin Wang, Bin Yuan, Caihong Wu, Sihang Wang, Jipeng Qi, Baolin Wang, Zelong Wang, Weiwei Hu, Wei Chen, Chenshuo Ye, Wenjie Wang, Yele Sun, Chen Wang, Shan Huang, Wei Song, Xinming Wang, Suxia Yang, Shenyang Zhang, Wanyun Xu, Nan Ma, Zhanyi Zhang, Bin Jiang, Hang Su, Yafang Cheng, Xuemei Wang, and Min Shao
Atmos. Chem. Phys., 20, 14123–14138, https://doi.org/10.5194/acp-20-14123-2020, https://doi.org/10.5194/acp-20-14123-2020, 2020
Short summary
Short summary
We utilized a novel online mass spectrometry method to measure the total concentration of higher alkanes at each carbon number at two different sites in China, allowing us to take into account SOA contributions from all isomers for higher alkanes. We found that higher alkanes account for significant fractions of SOA formation at the two sites. The contributions are comparable to or even higher than single-ring aromatics, the most-recognized SOA precursors in urban air.
Xiao-Bing Li, Bin Yuan, Yibo Huangfu, Suxia Yang, Xin Song, Jipeng Qi, Xianjun He, Sihang Wang, Yubin Chen, Qing Yang, Yongxin Song, Yuwen Peng, Guiqian Tang, Jian Gao, and Min Shao
EGUsphere, https://doi.org/10.5194/egusphere-2024-2755, https://doi.org/10.5194/egusphere-2024-2755, 2024
This preprint is open for discussion and under review for Atmospheric Chemistry and Physics (ACP).
Short summary
Short summary
Online vertical gradient measurements of volatile organic compounds (VOCs), ozone, and NOx were made based on a 325 m tower in urban Beijing. Vertical changes in concentrations, compositions, key drivers, and environmental impacts of VOCs were analyzed in this study. We find that VOC species display differentiated vertical variation patterns and distinct roles in contributing to photochemical ozone formation with increasing height in the urban planetary boundary layer.
Ye Kuang, Biao Luo, Shan Huang, Junwen Liu, Weiwei Hu, Yuweng Peng, Duohong Chen, Dingli Yue, Wanyun Xu, Bin Yuan, and Min Shao
EGUsphere, https://doi.org/10.5194/egusphere-2024-2654, https://doi.org/10.5194/egusphere-2024-2654, 2024
This preprint is open for discussion and under review for Atmospheric Chemistry and Physics (ACP).
Short summary
Short summary
This research reveals the potential importance of nighttime NO3 radical chemistry and aerosol water in the rapid formation of secondary brown carbon from biomass burning emissions. The findings enhance our understanding of nighttime biomass burning evolution and its implications for climate and regional air quality, especially regarding interactions with aerosol water and water-rich fogs and clouds.
Jun Zhou, Chunsheng Zhang, Aiming Liu, Bin Yuan, Yan Wang, Wenjie Wang, Jie-Ping Zhou, Yixin Hao, Xiao-Bing Li, Xianjun He, Xin Song, Yubin Chen, Suxia Yang, Shuchun Yang, Yanfeng Wu, Bin Jiang, Shan Huang, Junwen Liu, Yuwen Peng, Jipeng Qi, Minhui Deng, Bowen Zhong, Yibo Huangfu, and Min Shao
Atmos. Chem. Phys., 24, 9805–9826, https://doi.org/10.5194/acp-24-9805-2024, https://doi.org/10.5194/acp-24-9805-2024, 2024
Short summary
Short summary
In-depth understanding of the near-ground vertical variability in photochemical ozone (O3) formation is crucial for mitigating O3 pollution. Utilizing a self-built vertical observation system, a direct net photochemical O3 production rate detection system, and an observation-based model, we diagnosed the vertical distributions and formation mechanism of net photochemical O3 production rates and sensitivity in the Pearl River Delta region, one of the most O3-polluted areas in China.
Xianzhong Duan, Ming Chang, Guotong Wu, Suping Situ, Shengjie Zhu, Qi Zhang, Yibo Huangfu, Weiwen Wang, Weihua Chen, Bin Yuan, and Xuemei Wang
Atmos. Meas. Tech., 17, 4065–4079, https://doi.org/10.5194/amt-17-4065-2024, https://doi.org/10.5194/amt-17-4065-2024, 2024
Short summary
Short summary
Accurately estimating biogenic volatile organic compound (BVOC) emissions in forest ecosystems has been challenging. This research presents a framework that utilizes drone-based lidar, photogrammetry, and image recognition technologies to identify plant species and estimate BVOC emissions. The largest cumulative isoprene emissions were found in the Myrtaceae family, while those of monoterpenes were from the Rubiaceae family.
Qing Yang, Xiao-Bing Li, Bin Yuan, Xiaoxiao Zhang, Yibo Huangfu, Lei Yang, Xianjun He, Jipeng Qi, and Min Shao
Atmos. Chem. Phys., 24, 6865–6882, https://doi.org/10.5194/acp-24-6865-2024, https://doi.org/10.5194/acp-24-6865-2024, 2024
Short summary
Short summary
Online vertical gradient measurements of formic and isocyanic acids were made based on a 320 m tower in a megacity. Vertical variations and sources of the two acids were analyzed in this study. We find that formic and isocyanic acids exhibited positive vertical gradients and were mainly contributed by photochemical formations. The formation of formic and isocyanic acids was also significantly enhanced in urban regions aloft.
Mingfu Cai, Chenshuo Ye, Bin Yuan, Shan Huang, E Zheng, Suxia Yang, Zelong Wang, Yi Lin, Tiange Li, Weiwei Hu, Wei Chen, Qicong Song, Wei Li, Yuwen Peng, Baolin Liang, Qibin Sun, Jun Zhao, Duohong Chen, Jiaren Sun, Zhiyong Yang, and Min Shao
EGUsphere, https://doi.org/10.5194/egusphere-2024-887, https://doi.org/10.5194/egusphere-2024-887, 2024
Short summary
Short summary
This study investigated the daytime secondary organic aerosol (SOA) formation in urban plumes. We observed a significant daytime SOA formation through gas-particle partitioning when the site was affected by urban plumes. Box model simulation indicated that urban pollutants (nitrogen oxide and volatile organic compounds) could enhance the oxidizing capacity, while the elevated volatile organic compounds were mainly responsible for promoting daytime SOA formation.
Fangbing Li, Dan Dan Huang, Linhui Tian, Bin Yuan, Wen Tan, Liang Zhu, Penglin Ye, Douglas Worsnop, Ka In Hoi, Kai Meng Mok, and Yong Jie Li
Atmos. Meas. Tech., 17, 2415–2427, https://doi.org/10.5194/amt-17-2415-2024, https://doi.org/10.5194/amt-17-2415-2024, 2024
Short summary
Short summary
The responses of protonated, adduct, and fragmented ions of 21 volatile organic compounds (VOCs) were investigated with varying instrument settings and relative humidity (RH) in a Vocus proton-transfer-reaction mass spectrometer (PTR-MS). The protonated ions of most VOCs studied show < 15 % variation in sensitivity, except for some long-chain aldehydes. The relationship between sensitivity and PTR rate constant is complicated by the influences from ion transmission and protonated ion fraction.
Wenjie Wang, Bin Yuan, Hang Su, Yafang Cheng, Jipeng Qi, Sihang Wang, Wei Song, Xinming Wang, Chaoyang Xue, Chaoqun Ma, Fengxia Bao, Hongli Wang, Shengrong Lou, and Min Shao
Atmos. Chem. Phys., 24, 4017–4027, https://doi.org/10.5194/acp-24-4017-2024, https://doi.org/10.5194/acp-24-4017-2024, 2024
Short summary
Short summary
This study investigates the important role of unmeasured volatile organic compounds (VOCs) in ozone formation. Based on results in a megacity of China, we show that unmeasured VOCs can contribute significantly to ozone fomation and also influence the determination of ozone control strategy. Our results show that these unmeasured VOCs are mainly from human sources.
Tingting Hu, Yu Lin, Run Liu, Yuepeng Xu, Shanshan Ouyang, Boguang Wang, Yuanhang Zhang, and Shaw Chen Liu
Atmos. Chem. Phys., 24, 1607–1626, https://doi.org/10.5194/acp-24-1607-2024, https://doi.org/10.5194/acp-24-1607-2024, 2024
Short summary
Short summary
We hypothesize that the cause of the worsening O3 trends in the Beijing–Tianjin–Hebei region, the Yangtze River Delta, and Pearl River Delta from 2015 to 2020 is attributable to the increased occurrence of meteorological conditions of high solar radiation and a positive temperature anomaly under the influence of West Pacific subtropical high, tropical cyclones, and mid–high-latitude wave activities.
Jiangyong Li, Chunlin Zhang, Wenlong Zhao, Shijie Han, Yu Wang, Hao Wang, and Boguang Wang
Geosci. Model Dev., 16, 6049–6066, https://doi.org/10.5194/gmd-16-6049-2023, https://doi.org/10.5194/gmd-16-6049-2023, 2023
Short summary
Short summary
Photochemical box models, crucial for understanding tropospheric chemistry, face challenges due to slow computational efficiency with large chemical equations. The model introduced in this study, ROMAC, boosts efficiency by up to 96 % using an advanced atmospheric solver and an adaptive optimization algorithm. Moreover, ROMAC exceeds traditional box models in evaluating the impact of physical processes on pollutant concentrations.
Yixin Hao, Jun Zhou, Jie-Ping Zhou, Yan Wang, Suxia Yang, Yibo Huangfu, Xiao-Bing Li, Chunsheng Zhang, Aiming Liu, Yanfeng Wu, Yaqing Zhou, Shuchun Yang, Yuwen Peng, Jipeng Qi, Xianjun He, Xin Song, Yubin Chen, Bin Yuan, and Min Shao
Atmos. Chem. Phys., 23, 9891–9910, https://doi.org/10.5194/acp-23-9891-2023, https://doi.org/10.5194/acp-23-9891-2023, 2023
Short summary
Short summary
By employing an improved net photochemical ozone production rate (NPOPR) detection system based on the dual-channel reaction chamber technique, we measured the net photochemical ozone production rate in the Pearl River Delta in China. The photochemical ozone formation mechanisms in the reaction and reference chambers were investigated using the observation-data-constrained box model, which helped us to validate the NPOPR detection system and understand photochemical ozone formation mechanism.
Yiyu Cai, Chenshuo Ye, Wei Chen, Weiwei Hu, Wei Song, Yuwen Peng, Shan Huang, Jipeng Qi, Sihang Wang, Chaomin Wang, Caihong Wu, Zelong Wang, Baolin Wang, Xiaofeng Huang, Lingyan He, Sasho Gligorovski, Bin Yuan, Min Shao, and Xinming Wang
Atmos. Chem. Phys., 23, 8855–8877, https://doi.org/10.5194/acp-23-8855-2023, https://doi.org/10.5194/acp-23-8855-2023, 2023
Short summary
Short summary
We studied the variability and molecular composition of ambient oxidized organic nitrogen (OON) in both gas and particle phases using a state-of-the-art online mass spectrometer in urban air. Biomass burning and secondary formation were found to be the two major sources of OON. Daytime nitrate radical chemistry for OON formation was more important than previously thought. Our results improved the understanding of the sources and molecular composition of OON in the polluted urban atmosphere.
Kevin J. Nihill, Matthew M. Coggon, Christopher Y. Lim, Abigail R. Koss, Bin Yuan, Jordan E. Krechmer, Kanako Sekimoto, Jose L. Jimenez, Joost de Gouw, Christopher D. Cappa, Colette L. Heald, Carsten Warneke, and Jesse H. Kroll
Atmos. Chem. Phys., 23, 7887–7899, https://doi.org/10.5194/acp-23-7887-2023, https://doi.org/10.5194/acp-23-7887-2023, 2023
Short summary
Short summary
In this work, we collect emissions from controlled burns of biomass fuels that can be found in the western United States into an environmental chamber in order to simulate their oxidation as they pass through the atmosphere. These findings provide a detailed characterization of the composition of the atmosphere downwind of wildfires. In turn, this will help to explore the effects of these changing emissions on downwind populations and will also directly inform atmospheric and climate models.
Yaqin Gao, Hongli Wang, Lingling Yuan, Shengao Jing, Bin Yuan, Guofeng Shen, Liang Zhu, Abigail Koss, Yingjie Li, Qian Wang, Dan Dan Huang, Shuhui Zhu, Shikang Tao, Shengrong Lou, and Cheng Huang
Atmos. Chem. Phys., 23, 6633–6646, https://doi.org/10.5194/acp-23-6633-2023, https://doi.org/10.5194/acp-23-6633-2023, 2023
Short summary
Short summary
A near-complete speciation of reactive organic gases from residential combustion was developed to get more insights into their atmospheric effects. Oxygenated species, higher hydrocarbons and nitrogen-containing species played larger roles in these emissions compared with common hydrocarbons. Based on the near-complete speciation, these emissions were largely underestimated, leading to more underestimation of their hydroxyl radical reactivity and secondary organic aerosol formation potential.
Juan Hong, Min Tang, Qiaoqiao Wang, Nan Ma, Shaowen Zhu, Shaobin Zhang, Xihao Pan, Linhong Xie, Guo Li, Uwe Kuhn, Chao Yan, Jiangchuan Tao, Ye Kuang, Yao He, Wanyun Xu, Runlong Cai, Yaqing Zhou, Zhibin Wang, Guangsheng Zhou, Bin Yuan, Yafang Cheng, and Hang Su
Atmos. Chem. Phys., 23, 5699–5713, https://doi.org/10.5194/acp-23-5699-2023, https://doi.org/10.5194/acp-23-5699-2023, 2023
Short summary
Short summary
A comprehensive investigation of the characteristics of new particle formation (NPF) events was conducted at a rural site on the North China Plain (NCP), China, during the wintertime of 2018 by covering the particle number size distribution down to sub–3 nm. Potential mechanisms for NPF under the current environment were explored, followed by a further discussion on the factors governing the occurrence of NPF at this rural site compared with other regions (e.g., urban areas) in the NCP region.
Tingting Feng, Yingkun Wang, Weiwei Hu, Ming Zhu, Wei Song, Wei Chen, Yanyan Sang, Zheng Fang, Wei Deng, Hua Fang, Xu Yu, Cheng Wu, Bin Yuan, Shan Huang, Min Shao, Xiaofeng Huang, Lingyan He, Young Ro Lee, Lewis Gregory Huey, Francesco Canonaco, Andre S. H. Prevot, and Xinming Wang
Atmos. Chem. Phys., 23, 611–636, https://doi.org/10.5194/acp-23-611-2023, https://doi.org/10.5194/acp-23-611-2023, 2023
Short summary
Short summary
To investigate the impact of aging processes on organic aerosols (OA), we conducted a comprehensive field study at a continental remote site using an on-line mass spectrometer. The results show that OA in the Chinese outflows were strongly influenced by upwind anthropogenic emissions. The aging processes can significantly decrease the OA volatility and result in a varied viscosity of OA under different circumstances, signifying the complex physiochemical properties of OA in aged plumes.
Tingting Hu, Yu Lin, Run Liu, Yuepeng Xu, Boguang Wang, Yuanhang Zhang, and Shaw Chen Liu
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2022-781, https://doi.org/10.5194/acp-2022-781, 2023
Revised manuscript not accepted
Short summary
Short summary
We hypothesize that the cause of the worsening O3 trends in the Beijing-Tianjin-Hebei region, the Yangtze River Delta, and the Pearl River Delta from 2015 to 2020 is attributable to the increased occurrence of meteorological conditions of high solar radiation and positive temperature anomaly under the influence of West Pacific Subtropical High, tropical cyclones as well as mid-high latitude wave activities.
Yubin Chen, Bin Yuan, Chaomin Wang, Sihang Wang, Xianjun He, Caihong Wu, Xin Song, Yibo Huangfu, Xiao-Bing Li, Yijia Liao, and Min Shao
Atmos. Meas. Tech., 15, 6935–6947, https://doi.org/10.5194/amt-15-6935-2022, https://doi.org/10.5194/amt-15-6935-2022, 2022
Short summary
Short summary
In this study, we demonstrate that selective online measurements of cycloalkanes can be achieved using proton transfer reaction time-of-flight mass spectrometry with NO+ chemical ionization (NO+ PTR-ToF-MS), with fast response and low detection limits. Applications of this method in both urban air and emission sources will be shown.
Haichao Wang, Bin Yuan, E Zheng, Xiaoxiao Zhang, Jie Wang, Keding Lu, Chenshuo Ye, Lei Yang, Shan Huang, Weiwei Hu, Suxia Yang, Yuwen Peng, Jipeng Qi, Sihang Wang, Xianjun He, Yubin Chen, Tiange Li, Wenjie Wang, Yibo Huangfu, Xiaobing Li, Mingfu Cai, Xuemei Wang, and Min Shao
Atmos. Chem. Phys., 22, 14837–14858, https://doi.org/10.5194/acp-22-14837-2022, https://doi.org/10.5194/acp-22-14837-2022, 2022
Short summary
Short summary
We present intensive field measurement of ClNO2 in the Pearl River Delta in 2019. Large variation in the level, formation, and atmospheric impacts of ClNO2 was found in different air masses. ClNO2 formation was limited by the particulate chloride (Cl−) and aerosol surface area. Our results reveal that Cl− originated from various anthropogenic emissions rather than sea sources and show minor contribution to the O3 pollution and photochemistry.
Biao Luo, Ye Kuang, Shan Huang, Qicong Song, Weiwei Hu, Wei Li, Yuwen Peng, Duohong Chen, Dingli Yue, Bin Yuan, and Min Shao
Atmos. Chem. Phys., 22, 12401–12415, https://doi.org/10.5194/acp-22-12401-2022, https://doi.org/10.5194/acp-22-12401-2022, 2022
Short summary
Short summary
We performed comprehensive analysis on biomass burning organic aerosol (BBOA) size distributions, as well as mass scattering and absorption efficiencies, with an improved method of on-line quantification of brown carbon absorptions. Both BBOA volume size distribution and retrieved refractive index depend highly on combustion conditions represented by the black carbon content, which has significant implications for BBOA climate effect simulations.
Xiao-Bing Li, Bin Yuan, Sihang Wang, Chunlin Wang, Jing Lan, Zhijie Liu, Yongxin Song, Xianjun He, Yibo Huangfu, Chenglei Pei, Peng Cheng, Suxia Yang, Jipeng Qi, Caihong Wu, Shan Huang, Yingchang You, Ming Chang, Huadan Zheng, Wenda Yang, Xuemei Wang, and Min Shao
Atmos. Chem. Phys., 22, 10567–10587, https://doi.org/10.5194/acp-22-10567-2022, https://doi.org/10.5194/acp-22-10567-2022, 2022
Short summary
Short summary
High-time-resolution measurements of volatile organic compounds (VOCs) were made using an online mass spectrometer at a 600 m tall tower in urban region. Compositions, temporal variations, and sources of VOCs were quantitatively investigated in this study. We find that VOC measurements in urban regions aloft could better characterize source characteristics of anthropogenic emissions. Our results could provide important implications in making future strategies for control of VOCs.
Sihang Wang, Bin Yuan, Caihong Wu, Chaomin Wang, Tiange Li, Xianjun He, Yibo Huangfu, Jipeng Qi, Xiao-Bing Li, Qing'e Sha, Manni Zhu, Shengrong Lou, Hongli Wang, Thomas Karl, Martin Graus, Zibing Yuan, and Min Shao
Atmos. Chem. Phys., 22, 9703–9720, https://doi.org/10.5194/acp-22-9703-2022, https://doi.org/10.5194/acp-22-9703-2022, 2022
Short summary
Short summary
Volatile organic compound (VOC) emissions from vehicles are measured using online mass spectrometers. Differences between gasoline and diesel vehicles are observed with higher emission factors of most oxygenated VOCs (OVOCs) and heavier aromatics from diesel vehicles. A higher aromatics / toluene ratio could provide good indicators to distinguish emissions from both vehicle types. We show that OVOCs account for significant contributions to VOC emissions from vehicles, especially diesel vehicles.
Yihang Yu, Peng Cheng, Huirong Li, Wenda Yang, Baobin Han, Wei Song, Weiwei Hu, Xinming Wang, Bin Yuan, Min Shao, Zhijiong Huang, Zhen Li, Junyu Zheng, Haichao Wang, and Xiaofang Yu
Atmos. Chem. Phys., 22, 8951–8971, https://doi.org/10.5194/acp-22-8951-2022, https://doi.org/10.5194/acp-22-8951-2022, 2022
Short summary
Short summary
We have investigated the budget of HONO at an urban site in Guangzhou. Budget and comprehensive uncertainty analysis suggest that at such locations as ours, HONO direct emissions and NO + OH can become comparable or even surpass other HONO sources that typically receive greater attention and interest, such as the NO2 heterogeneous source and the unknown daytime photolytic source. Our findings emphasize the need to reduce the uncertainties of both conventional and novel HONO sources and sinks.
Qi Zhang, Shiguo Jia, Weihua Chen, Jingying Mao, Liming Yang, Padmaja Krishnan, Sayantan Sarkar, Min Shao, and Xuemei Wang
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2022-394, https://doi.org/10.5194/acp-2022-394, 2022
Revised manuscript not accepted
Short summary
Short summary
We use satellite data in the establishment of methylamines marine biological emission (MBE) inventory for the first time, which considers effects of actual marine environment on methylamines emission fluxes. MBE fluxes of monomethylamine and trimethylamines can be comparable with or even higher than that of terrestrial anthropogenic emissions , while for dimethylamines, the ocean acts as a sink. Wind and Chlorophyll-a were potentially the most important factors affecting MBE fluxes.
Kaixiang Song, Run Liu, Yu Wang, Tao Liu, Liyan Wei, Yanxing Wu, Junyu Zheng, Boguang Wang, and Shaw Chen Liu
Atmos. Chem. Phys., 22, 8403–8416, https://doi.org/10.5194/acp-22-8403-2022, https://doi.org/10.5194/acp-22-8403-2022, 2022
Short summary
Short summary
We developed an observation-based method to investigate the sensitivity of ozone formation to precursors during two elevated ozone episodes observed at 77 stations in Guangdong, China. We found approximately 67 % of the station days exhibit ozone formation sensitivity to NOx, 20 % of the station days are in the transitional regime sensitive to both NOx and volatile organic compounds (VOCs), and only 13 % of the station days are sensitive to VOCs.
Mingfu Cai, Shan Huang, Baoling Liang, Qibin Sun, Li Liu, Bin Yuan, Min Shao, Weiwei Hu, Wei Chen, Qicong Song, Wei Li, Yuwen Peng, Zelong Wang, Duohong Chen, Haobo Tan, Hanbin Xu, Fei Li, Xuejiao Deng, Tao Deng, Jiaren Sun, and Jun Zhao
Atmos. Chem. Phys., 22, 8117–8136, https://doi.org/10.5194/acp-22-8117-2022, https://doi.org/10.5194/acp-22-8117-2022, 2022
Short summary
Short summary
This study investigated the size dependence and diurnal variation in organic aerosol hygroscopicity, volatility, and cloud condensation nuclei (CCN) activity. We found that the physical properties of OA could vary in a large range at different particle sizes and affected the number concentration of CCN (NCCN) at all supersaturations. Our results highlight the importance of evaluating the atmospheric evolution processes of OA at different size ranges and their impact on climate effects.
Li Liu, Ye Kuang, Miaomiao Zhai, Biao Xue, Yao He, Jun Tao, Biao Luo, Wanyun Xu, Jiangchuan Tao, Changqin Yin, Fei Li, Hanbing Xu, Tao Deng, Xuejiao Deng, Haobo Tan, and Min Shao
Atmos. Chem. Phys., 22, 7713–7726, https://doi.org/10.5194/acp-22-7713-2022, https://doi.org/10.5194/acp-22-7713-2022, 2022
Short summary
Short summary
Using simultaneous measurements of a humidified nephelometer system and an aerosol chemical speciation monitor in winter in Guangzhou, the strongest scattering ability of more oxidized oxygenated organic aerosol (MOOA) among aerosol components considering their dry-state scattering ability and water uptake ability was revealed, leading to large impacts of MOOA on visibility degradation. This has important implications for visibility improvement in China and aerosol radiative effect simulation.
Suxia Yang, Bin Yuan, Yuwen Peng, Shan Huang, Wei Chen, Weiwei Hu, Chenglei Pei, Jun Zhou, David D. Parrish, Wenjie Wang, Xianjun He, Chunlei Cheng, Xiao-Bing Li, Xiaoyun Yang, Yu Song, Haichao Wang, Jipeng Qi, Baolin Wang, Chen Wang, Chaomin Wang, Zelong Wang, Tiange Li, E Zheng, Sihang Wang, Caihong Wu, Mingfu Cai, Chenshuo Ye, Wei Song, Peng Cheng, Duohong Chen, Xinming Wang, Zhanyi Zhang, Xuemei Wang, Junyu Zheng, and Min Shao
Atmos. Chem. Phys., 22, 4539–4556, https://doi.org/10.5194/acp-22-4539-2022, https://doi.org/10.5194/acp-22-4539-2022, 2022
Short summary
Short summary
We use a model constrained using observations to study the formation of nitrate aerosol in and downwind of a representative megacity. We found different contributions of various chemical reactions to ground-level nitrate concentrations between urban and suburban regions. We also show that controlling VOC emissions are effective for decreasing nitrate formation in both urban and regional environments, although VOCs are not direct precursors of nitrate aerosol.
Wenjie Wang, Bin Yuan, Yuwen Peng, Hang Su, Yafang Cheng, Suxia Yang, Caihong Wu, Jipeng Qi, Fengxia Bao, Yibo Huangfu, Chaomin Wang, Chenshuo Ye, Zelong Wang, Baolin Wang, Xinming Wang, Wei Song, Weiwei Hu, Peng Cheng, Manni Zhu, Junyu Zheng, and Min Shao
Atmos. Chem. Phys., 22, 4117–4128, https://doi.org/10.5194/acp-22-4117-2022, https://doi.org/10.5194/acp-22-4117-2022, 2022
Short summary
Short summary
From thorough measurements of numerous oxygenated volatile organic compounds, we show that their photodissociation can be important for radical production and ozone formation in the atmosphere. This effect was underestimated in previous studies, as measurements of them were lacking.
Xiajie Yang, Qiaoqiao Wang, Nan Ma, Weiwei Hu, Yang Gao, Zhijiong Huang, Junyu Zheng, Bin Yuan, Ning Yang, Jiangchuan Tao, Juan Hong, Yafang Cheng, and Hang Su
Atmos. Chem. Phys., 22, 3743–3762, https://doi.org/10.5194/acp-22-3743-2022, https://doi.org/10.5194/acp-22-3743-2022, 2022
Short summary
Short summary
We use the GEOS-Chem model with additional anthropogenic and biomass burning chlorine emissions combined with updated parameterizations for N2O5 ＋ Cl chemistry to investigate the impacts of chlorine chemistry on air quality in China. Our study not only significantly improves the model's performance but also demonstrates the importance of non-sea-salt chlorine sources as well as an appropriate parameterization for N2O5 ＋ Cl chemistry to the impact of chlorine chemistry in China.
Ziwei Mo, Ru Cui, Bin Yuan, Huihua Cai, Brian C. McDonald, Meng Li, Junyu Zheng, and Min Shao
Atmos. Chem. Phys., 21, 13655–13666, https://doi.org/10.5194/acp-21-13655-2021, https://doi.org/10.5194/acp-21-13655-2021, 2021
Short summary
Short summary
There is a lack of detailed understanding of NMVOC emissions from the use of volatile chemical products (VCPs) in China. This study used a mass balance method to compile a long-term emission inventory for solvent use (including coatings, adhesives, inks, pesticides, cleaners and personal care products) in China during 2000–2017. The striking growth and recent trend of solvent use NMVOC emissions can give important implications for air quality modeling and NMVOC control strategies in China.
Luolin Wu, Jian Hang, Xuemei Wang, Min Shao, and Cheng Gong
Geosci. Model Dev., 14, 4655–4681, https://doi.org/10.5194/gmd-14-4655-2021, https://doi.org/10.5194/gmd-14-4655-2021, 2021
Short summary
Short summary
In order to investigate street-scale flow and air quality, this study has developed APFoam 1.0 to examine the reactive pollutant formation and dispersion in the urban area. The model has been validated and shows good agreement with wind tunnel experimental data. Model sensitivity cases reveal that vehicle emissions, background concentrations, and wind conditions are the key factors affecting the photochemical reaction process.
Benjamin A. Nault, Duseong S. Jo, Brian C. McDonald, Pedro Campuzano-Jost, Douglas A. Day, Weiwei Hu, Jason C. Schroder, James Allan, Donald R. Blake, Manjula R. Canagaratna, Hugh Coe, Matthew M. Coggon, Peter F. DeCarlo, Glenn S. Diskin, Rachel Dunmore, Frank Flocke, Alan Fried, Jessica B. Gilman, Georgios Gkatzelis, Jacqui F. Hamilton, Thomas F. Hanisco, Patrick L. Hayes, Daven K. Henze, Alma Hodzic, James Hopkins, Min Hu, L. Greggory Huey, B. Thomas Jobson, William C. Kuster, Alastair Lewis, Meng Li, Jin Liao, M. Omar Nawaz, Ilana B. Pollack, Jeffrey Peischl, Bernhard Rappenglück, Claire E. Reeves, Dirk Richter, James M. Roberts, Thomas B. Ryerson, Min Shao, Jacob M. Sommers, James Walega, Carsten Warneke, Petter Weibring, Glenn M. Wolfe, Dominique E. Young, Bin Yuan, Qiang Zhang, Joost A. de Gouw, and Jose L. Jimenez
Atmos. Chem. Phys., 21, 11201–11224, https://doi.org/10.5194/acp-21-11201-2021, https://doi.org/10.5194/acp-21-11201-2021, 2021
Short summary
Short summary
Secondary organic aerosol (SOA) is an important aspect of poor air quality for urban regions around the world, where a large fraction of the population lives. However, there is still large uncertainty in predicting SOA in urban regions. Here, we used data from 11 urban campaigns and show that the variability in SOA production in these regions is predictable and is explained by key emissions. These results are used to estimate the premature mortality associated with SOA in urban regions.
Ye Kuang, Shan Huang, Biao Xue, Biao Luo, Qicong Song, Wei Chen, Weiwei Hu, Wei Li, Pusheng Zhao, Mingfu Cai, Yuwen Peng, Jipeng Qi, Tiange Li, Sihang Wang, Duohong Chen, Dingli Yue, Bin Yuan, and Min Shao
Atmos. Chem. Phys., 21, 10375–10391, https://doi.org/10.5194/acp-21-10375-2021, https://doi.org/10.5194/acp-21-10375-2021, 2021
Short summary
Short summary
We found that organic aerosol factors with identified sources perform much better than oxidation level parameters in characterizing variations in organic aerosol hygroscopicity, and secondary aerosol formations associated with different sources have distinct effects on organic aerosol hygroscopicity. It reveals that source-oriented organic aerosol hygroscopicity investigations might result in more appropriate parameterization approaches in chemical and climate models.
Mingfu Cai, Baoling Liang, Qibin Sun, Li Liu, Bin Yuan, Min Shao, Shan Huang, Yuwen Peng, Zelong Wang, Haobo Tan, Fei Li, Hanbin Xu, Duohong Chen, and Jun Zhao
Atmos. Chem. Phys., 21, 8575–8592, https://doi.org/10.5194/acp-21-8575-2021, https://doi.org/10.5194/acp-21-8575-2021, 2021
Short summary
Short summary
This study investigated the contribution of new particle formation (NPF) events to the number concentration of cloud condensation nuclei (NCCN) and its controlling factors in the Pearl River Delta region. The results show that the surfactant effect can decrease the critical diameter and significantly increase the NCCN during the NPF event. In addition, the growth rate is founded to be the most important controlling factor that affects NCCN for growth of newly-formed particles to the CCN sizes.
Chenshuo Ye, Bin Yuan, Yi Lin, Zelong Wang, Weiwei Hu, Tiange Li, Wei Chen, Caihong Wu, Chaomin Wang, Shan Huang, Jipeng Qi, Baolin Wang, Chen Wang, Wei Song, Xinming Wang, E Zheng, Jordan E. Krechmer, Penglin Ye, Zhanyi Zhang, Xuemei Wang, Douglas R. Worsnop, and Min Shao
Atmos. Chem. Phys., 21, 8455–8478, https://doi.org/10.5194/acp-21-8455-2021, https://doi.org/10.5194/acp-21-8455-2021, 2021
Short summary
Short summary
We performed measurements of gaseous and particulate organic compounds using a state-of-the-art online mass spectrometer in urban air. Using the dataset, we provide a holistic chemical characterization of oxygenated organic compounds in the polluted urban atmosphere, which can serve as a reference for the future field measurements of organic compounds in cities.
Wenjie Wang, Jipeng Qi, Jun Zhou, Bin Yuan, Yuwen Peng, Sihang Wang, Suxia Yang, Jonathan Williams, Vinayak Sinha, and Min Shao
Atmos. Meas. Tech., 14, 2285–2298, https://doi.org/10.5194/amt-14-2285-2021, https://doi.org/10.5194/amt-14-2285-2021, 2021
Short summary
Short summary
We designed a new reactor for measurements of OH reactivity (i.e., OH radical loss frequency) based on the comparative reactivity method under
high-NOx conditions, such as in cities. We performed a series of laboratory tests to evaluate the new reactor. The new reactor was used in the field and performed well in measuring OH reactivity in air influenced by upwind cities.
Wenjie Wang, David D. Parrish, Xin Li, Min Shao, Ying Liu, Ziwei Mo, Sihua Lu, Min Hu, Xin Fang, Yusheng Wu, Limin Zeng, and Yuanhang Zhang
Atmos. Chem. Phys., 20, 15617–15633, https://doi.org/10.5194/acp-20-15617-2020, https://doi.org/10.5194/acp-20-15617-2020, 2020
Short summary
Short summary
During the past decade, China has devoted very substantial resources to improving the environment. These efforts have improved atmospheric particulate matter loading, but ambient ozone levels have continued to increase. In this paper we investigate the causes of the increasing ozone concentrations through analysis of a data set that is, to our knowledge, unique: a 12-year data set including ground-level O3, NOx, and VOC precursors collected at an urban site in Beijing.
Caihong Wu, Chaomin Wang, Sihang Wang, Wenjie Wang, Bin Yuan, Jipeng Qi, Baolin Wang, Hongli Wang, Chen Wang, Wei Song, Xinming Wang, Weiwei Hu, Shengrong Lou, Chenshuo Ye, Yuwen Peng, Zelong Wang, Yibo Huangfu, Yan Xie, Manni Zhu, Junyu Zheng, Xuemei Wang, Bin Jiang, Zhanyi Zhang, and Min Shao
Atmos. Chem. Phys., 20, 14769–14785, https://doi.org/10.5194/acp-20-14769-2020, https://doi.org/10.5194/acp-20-14769-2020, 2020
Short summary
Short summary
Based on measurements from an online mass spectrometer, we quantify volatile organic compound (VOC) concentrations from numerous ions of the mass spectrometer, using information from laboratory-obtained calibration results. We find that most VOC concentrations are from oxygenated VOCs (OVOCs). We further show that these OVOCs also contribute significantly to OH reactivity. Our results suggest the important role of OVOCs in VOC emissions and chemistry in urban air.
Sarah E. Benish, Hao He, Xinrong Ren, Sandra J. Roberts, Ross J. Salawitch, Zhanqing Li, Fei Wang, Yuying Wang, Fang Zhang, Min Shao, Sihua Lu, and Russell R. Dickerson
Atmos. Chem. Phys., 20, 14523–14545, https://doi.org/10.5194/acp-20-14523-2020, https://doi.org/10.5194/acp-20-14523-2020, 2020
Short summary
Short summary
Airborne observations of ozone and related pollutants show smog was pervasive in spring 2016 over Hebei Province, China. We find high amounts of ozone precursors throughout and even above the PBL, continuing to generate ozone at high rates to be potentially transported downwind. Concentrations even in the rural areas of this highly industrialized province promote widespread ozone production, and we show that to improve air quality over Hebei both NOx and VOCs should be targeted.
Chaomin Wang, Bin Yuan, Caihong Wu, Sihang Wang, Jipeng Qi, Baolin Wang, Zelong Wang, Weiwei Hu, Wei Chen, Chenshuo Ye, Wenjie Wang, Yele Sun, Chen Wang, Shan Huang, Wei Song, Xinming Wang, Suxia Yang, Shenyang Zhang, Wanyun Xu, Nan Ma, Zhanyi Zhang, Bin Jiang, Hang Su, Yafang Cheng, Xuemei Wang, and Min Shao
Atmos. Chem. Phys., 20, 14123–14138, https://doi.org/10.5194/acp-20-14123-2020, https://doi.org/10.5194/acp-20-14123-2020, 2020
Short summary
Short summary
We utilized a novel online mass spectrometry method to measure the total concentration of higher alkanes at each carbon number at two different sites in China, allowing us to take into account SOA contributions from all isomers for higher alkanes. We found that higher alkanes account for significant fractions of SOA formation at the two sites. The contributions are comparable to or even higher than single-ring aromatics, the most-recognized SOA precursors in urban air.
Zhenhao Ling, Qianqian Xie, Min Shao, Zhe Wang, Tao Wang, Hai Guo, and Xuemei Wang
Atmos. Chem. Phys., 20, 11451–11467, https://doi.org/10.5194/acp-20-11451-2020, https://doi.org/10.5194/acp-20-11451-2020, 2020
Short summary
Short summary
The observation data from a receptor site in the Pearl River Delta region were analyzed by a photochemical box model with near-explicit chemical mechanisms (i.e., the Master Chemical Mechanism, MCM), improvements with reversible and irreversible heterogeneous processes of glyoxal and methylglyoxal, and the gas-particle partitioning of oxidation products in the present study.
Mingfu Cai, Baoling Liang, Qibin Sun, Shengzhen Zhou, Xiaoyang Chen, Bin Yuan, Min Shao, Haobo Tan, and Jun Zhao
Atmos. Chem. Phys., 20, 9153–9167, https://doi.org/10.5194/acp-20-9153-2020, https://doi.org/10.5194/acp-20-9153-2020, 2020
Short summary
Short summary
Cloud condensation nuclei activity in marine atmosphere affects cloud formation and the solar radiation balance over ocean. We employed advanced instruments to measure aerosol hygroscopicity and chemical composition in the northern South China Sea. Our results show that marine aerosols can be affected by local emissions or pollutants from long-range transport. Our study highlights dynamical variations in particle properties and the impact of long-range transport on this region during summertime.
James M. Roberts, Chelsea E. Stockwell, Robert J. Yokelson, Joost de Gouw, Yong Liu, Vanessa Selimovic, Abigail R. Koss, Kanako Sekimoto, Matthew M. Coggon, Bin Yuan, Kyle J. Zarzana, Steven S. Brown, Cristina Santin, Stefan H. Doerr, and Carsten Warneke
Atmos. Chem. Phys., 20, 8807–8826, https://doi.org/10.5194/acp-20-8807-2020, https://doi.org/10.5194/acp-20-8807-2020, 2020
Short summary
Short summary
We measured total reactive nitrogen, Nr, in lab fires from western North American fuels, along with measurements of individual nitrogen compounds. We measured the amount of N that gets converted to inactive compounds (avg. 70 %), and the amount that is accounted for by individual species (85 % of remaining N). We provide guidelines for how the reactive nitrogen is distributed among individual compounds such as NOx and ammonia. This will help estimates and predictions of wildfire emissions.
Luolin Wu, Ming Chang, Xuemei Wang, Jian Hang, Jinpu Zhang, Liqing Wu, and Min Shao
Geosci. Model Dev., 13, 23–40, https://doi.org/10.5194/gmd-13-23-2020, https://doi.org/10.5194/gmd-13-23-2020, 2020
Short summary
Short summary
We developed the Real-time On-road Emission (ROE v1.0) model to obtain the street-scale on-road hot emissions by using real-time big data for traffic provided by the Gaode Map navigation application. The results are close to other emission inventories. Meanwhile, we applied our results to a street-level air quality model for studying the impact of the national holiday traffic volume change on air quality. The model can be further extended to more districts in China or other countries.
Matthew M. Coggon, Christopher Y. Lim, Abigail R. Koss, Kanako Sekimoto, Bin Yuan, Jessica B. Gilman, David H. Hagan, Vanessa Selimovic, Kyle J. Zarzana, Steven S. Brown, James M. Roberts, Markus Müller, Robert Yokelson, Armin Wisthaler, Jordan E. Krechmer, Jose L. Jimenez, Christopher Cappa, Jesse H. Kroll, Joost de Gouw, and Carsten Warneke
Atmos. Chem. Phys., 19, 14875–14899, https://doi.org/10.5194/acp-19-14875-2019, https://doi.org/10.5194/acp-19-14875-2019, 2019
Short summary
Short summary
Wildfire emissions significantly contribute to adverse air quality; however, the chemical processes that lead to hazardous pollutants, such as ozone, are not fully understood. In this study, we describe laboratory experiments where we simulate the atmospheric chemistry of smoke emitted from a range of biomass fuels. We show that certain understudied compounds, such as furans and phenolic compounds, are significant contributors to pollutants formed as a result of typical atmospheric oxidation.
Yahui Bian, Zhijiong Huang, Jiamin Ou, Zhuangmin Zhong, Yuanqian Xu, Zhiwei Zhang, Xiao Xiao, Xiao Ye, Yuqi Wu, Xiaohong Yin, Cheng Li, Liangfu Chen, Min Shao, and Junyu Zheng
Atmos. Chem. Phys., 19, 11701–11719, https://doi.org/10.5194/acp-19-11701-2019, https://doi.org/10.5194/acp-19-11701-2019, 2019
Short summary
Short summary
During 2006–2015, emissions of SO2, NOx, PM2.5 and PM10 saw an obvious downtrend. However, most emissions still have large reduction potential. On-road mobile sources and solvent use are the two key sources that should receive more effective control measures in GD. Also, controls measures on VOC and NH3 should be weighted since they still increased in 2006–2015. Since most control measures focused on PRD rather than non-PRD in GD, emissions in non-PRD were increasingly important.
Wenjie Wang, Xin Li, Min Shao, Min Hu, Limin Zeng, Yusheng Wu, and Tianyi Tan
Atmos. Chem. Phys., 19, 9413–9429, https://doi.org/10.5194/acp-19-9413-2019, https://doi.org/10.5194/acp-19-9413-2019, 2019
Short summary
Short summary
We quantitatively evaluated the relationship between photolysis frequencies and AOD based on 4 years of observational data in Beijing. This study concludes that the influence of aerosol on photolysis frequencies and thus on the rate of oxidation of VOCs and NOx to ozone is important for determining the atmospheric effects of controlling the precursor emissions of these two important air pollutants (aerosols and ozone).
Xin Chen, Dylan B. Millet, Hanwant B. Singh, Armin Wisthaler, Eric C. Apel, Elliot L. Atlas, Donald R. Blake, Ilann Bourgeois, Steven S. Brown, John D. Crounse, Joost A. de Gouw, Frank M. Flocke, Alan Fried, Brian G. Heikes, Rebecca S. Hornbrook, Tomas Mikoviny, Kyung-Eun Min, Markus Müller, J. Andrew Neuman, Daniel W. O'Sullivan, Jeff Peischl, Gabriele G. Pfister, Dirk Richter, James M. Roberts, Thomas B. Ryerson, Stephen R. Shertz, Chelsea R. Thompson, Victoria Treadaway, Patrick R. Veres, James Walega, Carsten Warneke, Rebecca A. Washenfelder, Petter Weibring, and Bin Yuan
Atmos. Chem. Phys., 19, 9097–9123, https://doi.org/10.5194/acp-19-9097-2019, https://doi.org/10.5194/acp-19-9097-2019, 2019
Short summary
Short summary
Volatile organic compounds (VOCs) affect air quality and modify the lifetimes of other pollutants. We combine a high-resolution 3-D atmospheric model with an ensemble of aircraft observations to perform an integrated analysis of the VOC budget over North America. We find that biogenic emissions provide the main source of VOC reactivity even in most major cities. Our findings point to key gaps in current models related to oxygenated VOCs and to the distribution of VOCs in the free troposphere.
Zhuoran He, Xuemei Wang, Zhenhao Ling, Jun Zhao, Hai Guo, Min Shao, and Zhe Wang
Atmos. Chem. Phys., 19, 8801–8816, https://doi.org/10.5194/acp-19-8801-2019, https://doi.org/10.5194/acp-19-8801-2019, 2019
Short summary
Short summary
In this study, source apportionment of volatile organic compounds (VOCs) and their contributions to photochemical O3 formation were analyzed by the positive matrix factorization model and an observation-based model using data collected at a receptor site in the Pearl River Delta (PRD) region. Furthermore, the policies for controlling VOCs are briefly reviewed. The findings could provide quantitative information for devising appropriate measures against VOCs, NOx and O3 pollution in the PRD.
Liqing Wu, Xuemei Wang, Sihua Lu, Min Shao, and Zhenhao Ling
Atmos. Chem. Phys., 19, 8141–8161, https://doi.org/10.5194/acp-19-8141-2019, https://doi.org/10.5194/acp-19-8141-2019, 2019
Short summary
Short summary
Semi-volatile and intermediate-volatility organic compounds (S–IVOCs) are considered critical precursors of secondary organic aerosol (SOA), which is an important component of fine particulate matter (PM2.5). In this study, an emission inventory of S–IVOCs in the Pearl River Delta (PRD) region was developed for the first time for the year 2010, while the contributions of S–IVOCs to SOA formation was evaluated by the WRF-Chem model.
Zhaofeng Tan, Keding Lu, Andreas Hofzumahaus, Hendrik Fuchs, Birger Bohn, Frank Holland, Yuhan Liu, Franz Rohrer, Min Shao, Kang Sun, Yusheng Wu, Limin Zeng, Yinsong Zhang, Qi Zou, Astrid Kiendler-Scharr, Andreas Wahner, and Yuanhang Zhang
Atmos. Chem. Phys., 19, 7129–7150, https://doi.org/10.5194/acp-19-7129-2019, https://doi.org/10.5194/acp-19-7129-2019, 2019
Short summary
Short summary
Atmospheric OH, HO2, and RO2 radicals; OH reactivity; and trace gases measured in the Pearl River Delta in autumn 2014 are used for radical budget analyses. The RO2 budget suggests that unexplained OH reactivity is due to unmeasured volatile organic compounds. The OH budget points to a missing OH source and that of RO2 to a missing RO2 sink at low NO. This could indicate a common, unknown process that converts RO2 to OH without the involvement of NO, which would reduce ozone production by 30 %.
Guo Li, Yafang Cheng, Uwe Kuhn, Rongjuan Xu, Yudong Yang, Hannah Meusel, Zhibin Wang, Nan Ma, Yusheng Wu, Meng Li, Jonathan Williams, Thorsten Hoffmann, Markus Ammann, Ulrich Pöschl, Min Shao, and Hang Su
Atmos. Chem. Phys., 19, 2209–2232, https://doi.org/10.5194/acp-19-2209-2019, https://doi.org/10.5194/acp-19-2209-2019, 2019
Short summary
Short summary
VOCs play a key role in atmospheric chemistry. Emission and deposition on soil have been suggested as important sources and sinks of atmospheric trace gases. The exchange characteristics and heterogeneous chemistry of VOCs on soil, however, are not well understood. We used a newly designed differential coated-wall flow tube system to investigate the long-term variability of bidirectional air–soil exchange of 13 VOCs at ambient air conditions of an urban background site in Beijing.
Kyle J. Zarzana, Vanessa Selimovic, Abigail R. Koss, Kanako Sekimoto, Matthew M. Coggon, Bin Yuan, William P. Dubé, Robert J. Yokelson, Carsten Warneke, Joost A. de Gouw, James M. Roberts, and Steven S. Brown
Atmos. Chem. Phys., 18, 15451–15470, https://doi.org/10.5194/acp-18-15451-2018, https://doi.org/10.5194/acp-18-15451-2018, 2018
Short summary
Short summary
Emissions of glyoxal and methylglyoxal from fuels common to the western United States were measured using cavity-enhanced spectroscopy, which provides a more selective measurement of those compounds than was previously available. Primary emissions of glyoxal were lower than previously reported and showed variability between the different fuel groups. However, emissions of glyoxal relative to formaldehyde were constant across almost all the fuel groups at 6 %–7 %.
Daocheng Gong, Hao Wang, Shenyang Zhang, Yu Wang, Shaw Chen Liu, Hai Guo, Min Shao, Congrong He, Duohong Chen, Lingyan He, Lei Zhou, Lidia Morawska, Yuanhang Zhang, and Boguang Wang
Atmos. Chem. Phys., 18, 14417–14432, https://doi.org/10.5194/acp-18-14417-2018, https://doi.org/10.5194/acp-18-14417-2018, 2018
Short summary
Short summary
The complex air pollution in the air-polluted Pearl River Delta (PRD) region in southern China has significantly elevated the background atmospheric oxidative capacity of the adjacent forests and subsequently lowered the levels of important biogenic volatile organic compounds, such as isoprene, which probably affect the regional air quality and ecological environment in the long term.
Weiqiang Yang, Yanli Zhang, Xinming Wang, Sheng Li, Ming Zhu, Qingqing Yu, Guanghui Li, Zhonghui Huang, Huina Zhang, Zhenfeng Wu, Wei Song, Jihua Tan, and Min Shao
Atmos. Chem. Phys., 18, 12663–12682, https://doi.org/10.5194/acp-18-12663-2018, https://doi.org/10.5194/acp-18-12663-2018, 2018
Short summary
Short summary
We present observation-based evaluations of the reduction of ambient VOCs under intervention control measures during APEC China 2014 in Beijing and the contributions of emissions from domestic solid fuel burning to ambient VOCs during winter heating. Controlling vehicle exhaust and solvent use was found to be effective in reducing ambient VOCs in non-heating periods, and controlling emissions from residential burning of solid fuels became much more important during winter heating.
Zhaofeng Tan, Franz Rohrer, Keding Lu, Xuefei Ma, Birger Bohn, Sebastian Broch, Huabin Dong, Hendrik Fuchs, Georgios I. Gkatzelis, Andreas Hofzumahaus, Frank Holland, Xin Li, Ying Liu, Yuhan Liu, Anna Novelli, Min Shao, Haichao Wang, Yusheng Wu, Limin Zeng, Min Hu, Astrid Kiendler-Scharr, Andreas Wahner, and Yuanhang Zhang
Atmos. Chem. Phys., 18, 12391–12411, https://doi.org/10.5194/acp-18-12391-2018, https://doi.org/10.5194/acp-18-12391-2018, 2018
Short summary
Short summary
We present the first wintertime OH, HO2, and RO2 measurements in Beijing, China. OH concentrations are nearly 2-fold larger than those observed in foreign cities during wintertime. The high OH and large OH reactivities indicate photochemical processes can be effective even during wintertime. A box model largely underestimated HO2 and RO2 concentrations during pollution episodes correlated with high NOx, indicating a deficit current chemistry in the high NOx regime.
Kanako Sekimoto, Abigail R. Koss, Jessica B. Gilman, Vanessa Selimovic, Matthew M. Coggon, Kyle J. Zarzana, Bin Yuan, Brian M. Lerner, Steven S. Brown, Carsten Warneke, Robert J. Yokelson, James M. Roberts, and Joost de Gouw
Atmos. Chem. Phys., 18, 9263–9281, https://doi.org/10.5194/acp-18-9263-2018, https://doi.org/10.5194/acp-18-9263-2018, 2018
Short summary
Short summary
We found that on average 85 % of the VOC emissions from biomass burning across various fuels representative of the western US (including various coniferous and chaparral fuels) can be explained using only two emission profiles: (i) a high-temperature pyrolysis profile and (ii) a low-temperature pyrolysis profile. The high-temperature profile is quantitatively similar between different fuel types (r2 > 0.84), and likewise for the low-temperature profile.
Zhuofei Du, Min Hu, Jianfei Peng, Wenbin Zhang, Jing Zheng, Fangting Gu, Yanhong Qin, Yudong Yang, Mengren Li, Yusheng Wu, Min Shao, and Shijin Shuai
Atmos. Chem. Phys., 18, 9011–9023, https://doi.org/10.5194/acp-18-9011-2018, https://doi.org/10.5194/acp-18-9011-2018, 2018
Short summary
Short summary
By combining approaches involving chassis dynamometer measurements and environmental chamber simulations, we find that gasoline direct injection (GDI) vehicles contribute more primary aerosol and secondary organic aerosol than port fuel injection (PFI) vehicles. Our results highlight the considerable potential contribution of GDI vehicles to urban air pollution, since the market share of GDI vehicles will dominate over that of PFI vehicles in the future.
Abigail R. Koss, Kanako Sekimoto, Jessica B. Gilman, Vanessa Selimovic, Matthew M. Coggon, Kyle J. Zarzana, Bin Yuan, Brian M. Lerner, Steven S. Brown, Jose L. Jimenez, Jordan Krechmer, James M. Roberts, Carsten Warneke, Robert J. Yokelson, and Joost de Gouw
Atmos. Chem. Phys., 18, 3299–3319, https://doi.org/10.5194/acp-18-3299-2018, https://doi.org/10.5194/acp-18-3299-2018, 2018
Short summary
Short summary
Non-methane organic gases (NMOGs) were detected by proton-transfer-reaction mass spectrometry (PTR-ToF) during an extensive laboratory characterization of wildfire emissions. Identifications for PTR-ToF ion masses are proposed and supported by a combination of techniques. Overall excellent agreement with other instrumentation is shown. Scalable emission factors and ratios are reported for many newly reported reactive species. An analysis of chemical characteristics is presented.
Guo Li, Hang Su, Uwe Kuhn, Hannah Meusel, Markus Ammann, Min Shao, Ulrich Pöschl, and Yafang Cheng
Atmos. Chem. Phys., 18, 2669–2686, https://doi.org/10.5194/acp-18-2669-2018, https://doi.org/10.5194/acp-18-2669-2018, 2018
Short summary
Short summary
Coated-wall flow tube reactors are frequently used to investigate gas uptake and heterogeneous or multiphase reaction kinetics under laminar flow conditions. In previous applications, the effects of coating surface roughness on flow conditions were not well quantified. In this study, a criterion is proposed to eliminate/minimize the potential effects of coating surface roughness on laminar flow in coated-wall flow tube experiments and validate the applications of diffusion correction methods.
Jianfei Peng, Min Hu, Song Guo, Zhuofei Du, Dongjie Shang, Jing Zheng, Jun Zheng, Limin Zeng, Min Shao, Yusheng Wu, Don Collins, and Renyi Zhang
Atmos. Chem. Phys., 17, 10333–10348, https://doi.org/10.5194/acp-17-10333-2017, https://doi.org/10.5194/acp-17-10333-2017, 2017
Short summary
Short summary
Rapid growth of BC particles was observed in Beijing using a new outdoor chamber, with an average growth rate of 26 ± 11 nm h−1. Secondary organic aerosol (SOA) accounted for more than 90 % of the coating mass. The hygroscopic growth factor of BC particles increased to 1.06–1.08 upon ageing. The κ (kappa) values for BC particles were calculated as only 0.035, indicating that initial photochemical ageing of BC particles does not appreciably alter the particle hygroscopicity in Beijing.
Abigail Koss, Bin Yuan, Carsten Warneke, Jessica B. Gilman, Brian M. Lerner, Patrick R. Veres, Jeff Peischl, Scott Eilerman, Rob Wild, Steven S. Brown, Chelsea R. Thompson, Thomas Ryerson, Thomas Hanisco, Glenn M. Wolfe, Jason M. St. Clair, Mitchell Thayer, Frank N. Keutsch, Shane Murphy, and Joost de Gouw
Atmos. Meas. Tech., 10, 2941–2968, https://doi.org/10.5194/amt-10-2941-2017, https://doi.org/10.5194/amt-10-2941-2017, 2017
Short summary
Short summary
Oil and gas extraction activity can cause air quality issues through emission of reactive chemicals. VOCs related to extraction operations in the United States were measured by PTR-ToF-MS from aircraft during the SONGNEX campaign in March–April 2015. The detailed analysis in this work provides a guide to interpreting PTR-ToF measurements in oil- and gas-producing regions, and it includes fundamental observations of VOC speciation and mixing ratios.
Yudong Yang, Min Shao, Stephan Keßel, Yue Li, Keding Lu, Sihua Lu, Jonathan Williams, Yuanhang Zhang, Liming Zeng, Anke C. Nölscher, Yusheng Wu, Xuemei Wang, and Junyu Zheng
Atmos. Chem. Phys., 17, 7127–7142, https://doi.org/10.5194/acp-17-7127-2017, https://doi.org/10.5194/acp-17-7127-2017, 2017
Short summary
Short summary
Total OH reactivity is an important parameter to evaluate understanding of atmospheric chemistry, especially the VOC contribution to air pollution. Measured by comparative reactivity methods, total OH reactivity in Beijing and Heshan revealed significant differences between measured and calculated results, such as missing reactivity, which were related to unmeasured primary or secondary species. This missing reactivity would introduce a 21–30 % underestimation for ozone production efficiency.
Bin Yuan, Matthew M. Coggon, Abigail R. Koss, Carsten Warneke, Scott Eilerman, Jeff Peischl, Kenneth C. Aikin, Thomas B. Ryerson, and Joost A. de Gouw
Atmos. Chem. Phys., 17, 4945–4956, https://doi.org/10.5194/acp-17-4945-2017, https://doi.org/10.5194/acp-17-4945-2017, 2017
Short summary
Short summary
In this study, we measured emissions of volatile organic compounds (VOCs) from concentrated animal feeding operations (CAFOs) using both mobile laboratory and aircraft measurements. We will use this data set to investigate chemical compositions of VOC emissions and sources apportionment for these VOC emissions in different facilities.
Brian M. Lerner, Jessica B. Gilman, Kenneth C. Aikin, Elliot L. Atlas, Paul D. Goldan, Martin Graus, Roger Hendershot, Gabriel A. Isaacman-VanWertz, Abigail Koss, William C. Kuster, Richard A. Lueb, Richard J. McLaughlin, Jeff Peischl, Donna Sueper, Thomas B. Ryerson, Travis W. Tokarek, Carsten Warneke, Bin Yuan, and Joost A. de Gouw
Atmos. Meas. Tech., 10, 291–313, https://doi.org/10.5194/amt-10-291-2017, https://doi.org/10.5194/amt-10-291-2017, 2017
Short summary
Short summary
Whole air sampling followed by analysis by gas chromatography is a common technique for characterization of trace volatile organic compounds in the atmosphere. We describe a new automated gas chromatograph–mass spectrograph which uses a Stirling cooler for sample preconcentration at −165 °C without the need for a cryogen such as liquid nitrogen. We also discuss potential sources of artifacts from our electropolished stainless steel sampling system and present results from two field campaigns.
Zhaofeng Tan, Hendrik Fuchs, Keding Lu, Andreas Hofzumahaus, Birger Bohn, Sebastian Broch, Huabin Dong, Sebastian Gomm, Rolf Häseler, Lingyan He, Frank Holland, Xin Li, Ying Liu, Sihua Lu, Franz Rohrer, Min Shao, Baolin Wang, Ming Wang, Yusheng Wu, Limin Zeng, Yinsong Zhang, Andreas Wahner, and Yuanhang Zhang
Atmos. Chem. Phys., 17, 663–690, https://doi.org/10.5194/acp-17-663-2017, https://doi.org/10.5194/acp-17-663-2017, 2017
Short summary
Short summary
In this study, we performed accurate OH measurements as well as selective HO2 and RO2 measurements at a rural site in North China Plain with state-of-the-art instruments newly developed. We confirmed the previous discovery on the enhancement of the OH in low NOx with which little O3 production was associated, and we found a missing RO2 source in high NOx which promoted higher O3 production. Our results are of vital importance for ozone abatement strategies currently under discussion for China.
Hendrik Fuchs, Zhaofeng Tan, Keding Lu, Birger Bohn, Sebastian Broch, Steven S. Brown, Huabin Dong, Sebastian Gomm, Rolf Häseler, Lingyan He, Andreas Hofzumahaus, Frank Holland, Xin Li, Ying Liu, Sihua Lu, Kyung-Eun Min, Franz Rohrer, Min Shao, Baolin Wang, Ming Wang, Yusheng Wu, Limin Zeng, Yinson Zhang, Andreas Wahner, and Yuanhang Zhang
Atmos. Chem. Phys., 17, 645–661, https://doi.org/10.5194/acp-17-645-2017, https://doi.org/10.5194/acp-17-645-2017, 2017
Short summary
Short summary
OH reactivity was measured during a 1-month long campaign at a rural site in the North China Plain in 2014. OH reactivity measurements are compared to calculations using OH reactant measurements. Good agreement is found indicating that all important OH reactants were measured. In addition, the chemical OH budget is analyzed. In contrast to previous campaigns in China in 2006, no significant imbalance between OH production and destruction is found.
Yee Jun Tham, Zhe Wang, Qinyi Li, Hui Yun, Weihao Wang, Xinfeng Wang, Likun Xue, Keding Lu, Nan Ma, Birger Bohn, Xin Li, Simonas Kecorius, Johannes Größ, Min Shao, Alfred Wiedensohler, Yuanhang Zhang, and Tao Wang
Atmos. Chem. Phys., 16, 14959–14977, https://doi.org/10.5194/acp-16-14959-2016, https://doi.org/10.5194/acp-16-14959-2016, 2016
Short summary
Short summary
This work addresses the unclear global significance of chlorine activation processes in the troposphere. The first high-quality measurement data set of ClNO2 in northern China revealed strong ClNO2 production in the residual layers, and demonstrated its significant effects on radical budget and ozone production. Our findings imply the widespread effects of ClNO2 over the polluted regions of northern China, which may increase photochemical and haze pollution.
Maria Zatko, Joseph Erbland, Joel Savarino, Lei Geng, Lauren Easley, Andrew Schauer, Timothy Bates, Patricia K. Quinn, Bonnie Light, David Morison, Hans D. Osthoff, Seth Lyman, William Neff, Bin Yuan, and Becky Alexander
Atmos. Chem. Phys., 16, 13837–13851, https://doi.org/10.5194/acp-16-13837-2016, https://doi.org/10.5194/acp-16-13837-2016, 2016
Short summary
Short summary
This manuscript presents chemical and optical observations collected in the air and snow during UBWOS2014 in eastern Utah. These observations are used to calculate fluxes of reactive nitrogen associated with snow nitrate photolysis. Snow-sourced reactive nitrogen fluxes are compared to reactive nitrogen emission inventories to find that snow-sourced reactive nitrogen is a minor contributor to the reactive nitrogen budget, and thus wintertime ground-level ozone formation, in the Uintah Basin.
Wei Hu, Min Hu, Wei-Wei Hu, Hongya Niu, Jing Zheng, Yusheng Wu, Wentai Chen, Chen Chen, Lingyu Li, Min Shao, Shaodong Xie, and Yuanhang Zhang
Atmos. Chem. Phys., 16, 13213–13230, https://doi.org/10.5194/acp-16-13213-2016, https://doi.org/10.5194/acp-16-13213-2016, 2016
Short summary
Short summary
An Aerodyne high-resolution time-of-flight AMS was deployed at a suburban site in the Sichuan Basin, southwestern China, under high emission intensity, and unique geographical and adverse meteorological conditions. OA was the most abundant component (36 %) in PM1, characterized by a relatively high oxidation state. The contributions of BBOA and BC to PM1 were high in primary emission episodes, highlighting the critical influence of biomass burning.
Guo Li, Hang Su, Xin Li, Uwe Kuhn, Hannah Meusel, Thorsten Hoffmann, Markus Ammann, Ulrich Pöschl, Min Shao, and Yafang Cheng
Atmos. Chem. Phys., 16, 10299–10311, https://doi.org/10.5194/acp-16-10299-2016, https://doi.org/10.5194/acp-16-10299-2016, 2016
Short summary
Short summary
Indoor and outdoor formaldehyde (HCHO) are both of considerable concern because of its health effects and its role in atmospheric chemistry. The heterogeneous reactions between gaseous HCHO with soils can pose important impact on both HCHO budget and soil ecosystem. Our results confirms that HCHO uptake by soil is a complex process involving both adsorption/desorption and chemical reactions. Soil and soil-derived airborne particles can either act as a source or a sink for HCHO.
Abigail R. Koss, Carsten Warneke, Bin Yuan, Matthew M. Coggon, Patrick R. Veres, and Joost A. de Gouw
Atmos. Meas. Tech., 9, 2909–2925, https://doi.org/10.5194/amt-9-2909-2016, https://doi.org/10.5194/amt-9-2909-2016, 2016
Short summary
Short summary
Using laboratory and field experiments, we have explored how the technique of NO+ chemical ionization mass spectrometry can be used to measure volatile organic compounds (VOCs) in the troposphere. Results include the design and operation of the instrument, an evaluation of the technique’s utility for atmospheric measurement, and a guide for data interpretation. Use of this technique will improve our understanding of VOC chemistry.
Bin Yuan, Abigail Koss, Carsten Warneke, Jessica B. Gilman, Brian M. Lerner, Harald Stark, and Joost A. de Gouw
Atmos. Meas. Tech., 9, 2735–2752, https://doi.org/10.5194/amt-9-2735-2016, https://doi.org/10.5194/amt-9-2735-2016, 2016
Short summary
Short summary
We present the development of a hydronium (H3O+) time of flight chemical ionization mass spectrometer (H3O+ ToF-CIMS). We characterize the humidity dependence of the reagent ions and VOC signals in details. The low mass cutoff issue of RF-only quadrupole leads to unusual humidity dependence of reagent ions. The new H3O+ ToF-CIMS was successfully deployed on the NOAA WP-3D research aircraft for the SONGNEX campaign in 2015 and some initial results from the SONGNEX campaign are presented.
Luping Su, Edward G. Patton, Jordi Vilà-Guerau de Arellano, Alex B. Guenther, Lisa Kaser, Bin Yuan, Fulizi Xiong, Paul B. Shepson, Li Zhang, David O. Miller, William H. Brune, Karsten Baumann, Eric Edgerton, Andrew Weinheimer, Pawel K. Misztal, Jeong-Hoo Park, Allen H. Goldstein, Kate M. Skog, Frank N. Keutsch, and John E. Mak
Atmos. Chem. Phys., 16, 7725–7741, https://doi.org/10.5194/acp-16-7725-2016, https://doi.org/10.5194/acp-16-7725-2016, 2016
Xuekun Fang, Min Shao, Andreas Stohl, Qiang Zhang, Junyu Zheng, Hai Guo, Chen Wang, Ming Wang, Jiamin Ou, Rona L. Thompson, and Ronald G. Prinn
Atmos. Chem. Phys., 16, 3369–3382, https://doi.org/10.5194/acp-16-3369-2016, https://doi.org/10.5194/acp-16-3369-2016, 2016
Short summary
Short summary
This is the first study reporting top-down estimates of benzene and toluene emissions in southern China using atmospheric measurement data from a rural site in the area, an atmospheric transport model and an inverse modeling method. This study shows in detail the temporal and spatial differences between the inversion estimate and four different bottom-up emission inventories (RCP, REAS, MEIC; Yin et al., 2015). We propose that more observations are urgently needed in future.
Bin Yuan, John Liggio, Jeremy Wentzell, Shao-Meng Li, Harald Stark, James M. Roberts, Jessica Gilman, Brian Lerner, Carsten Warneke, Rui Li, Amy Leithead, Hans D. Osthoff, Robert Wild, Steven S. Brown, and Joost A. de Gouw
Atmos. Chem. Phys., 16, 2139–2153, https://doi.org/10.5194/acp-16-2139-2016, https://doi.org/10.5194/acp-16-2139-2016, 2016
Short summary
Short summary
We describe high-resolution measurements of nitrated phenols using a time-of-flight chemical ionization mass spectrometer (ToF-CIMS). Strong diurnal profiles were observed for nitrated phenols, with concentration maxima at night. Box model simulations were able to reproduce the measured nitrated phenols.
Yaning Kang, Mingxu Liu, Yu Song, Xin Huang, Huan Yao, Xuhui Cai, Hongsheng Zhang, Ling Kang, Xuejun Liu, Xiaoyuan Yan, Hong He, Qiang Zhang, Min Shao, and Tong Zhu
Atmos. Chem. Phys., 16, 2043–2058, https://doi.org/10.5194/acp-16-2043-2016, https://doi.org/10.5194/acp-16-2043-2016, 2016
Short summary
Short summary
The multi-year (1980–2012) comprehensive ammonia emissions inventories were compiled for China on 1 km × 1 km grid.
Various realistic parameters (ambient temperature, wind speed, soil acidity, synthetic fertilizer types, etc.) were considered in these inventories to synthetically refine the emission factors of ammonia volatilization according to local agricultural practice.
This paper shows the interannual trend and spatial distribution of ammonia emissions in details over recent decades.
R. J. Wild, P. M. Edwards, T. S. Bates, R. C. Cohen, J. A. de Gouw, W. P. Dubé, J. B. Gilman, J. Holloway, J. Kercher, A. R. Koss, L. Lee, B. M. Lerner, R. McLaren, P. K. Quinn, J. M. Roberts, J. Stutz, J. A. Thornton, P. R. Veres, C. Warneke, E. Williams, C. J. Young, B. Yuan, K. J. Zarzana, and S. S. Brown
Atmos. Chem. Phys., 16, 573–583, https://doi.org/10.5194/acp-16-573-2016, https://doi.org/10.5194/acp-16-573-2016, 2016
Short summary
Short summary
High wintertime ozone levels have been observed in the Uintah Basin, Utah, a sparsely populated rural region with intensive oil and gas operations. The reactive nitrogen budget plays an important role in tropospheric ozone formation, and we find that nighttime chemistry has a large effect on its partitioning. Much of the oxidation of reactive nitrogen during a high-ozone year occurred via heterogeneous uptake onto aerosol at night, keeping NOx at concentrations comparable to a low-ozone year.
B. G. Wang, D. Zhu, Y. Zou, H. Wang, L. Zhou, X. Ouyang, H. F. Shao, and X. J. Deng
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acpd-15-17093-2015, https://doi.org/10.5194/acpd-15-17093-2015, 2015
Revised manuscript has not been submitted
Short summary
Short summary
Photochemical smog has been a major cause of air pollution in Guangzhou, one of megacities in China. This study firstly examined the source of peroxyacetyl nitrate in Guangzhou based on a yearlong data set including PAN, ozone, nitrogen oxides and non-methane hydrocarbons. The results suggest regional air mass transport of pollutants had a major impact on the PAN concentrations in Guangzhou area, which will provide useful information for more effectively managing the air quality of Guangzhou.
Y. Zou, X. J. Deng, D. Zhu, D. C. Gong, H. Wang, F. Li, H. B. Tan, T. Deng, B. R. Mai, X. T. Liu, and B. G. Wang
Atmos. Chem. Phys., 15, 6625–6636, https://doi.org/10.5194/acp-15-6625-2015, https://doi.org/10.5194/acp-15-6625-2015, 2015
A. R. Koss, J. de Gouw, C. Warneke, J. B. Gilman, B. M. Lerner, M. Graus, B. Yuan, P. Edwards, S. S. Brown, R. Wild, J. M. Roberts, T. S. Bates, and P. K. Quinn
Atmos. Chem. Phys., 15, 5727–5741, https://doi.org/10.5194/acp-15-5727-2015, https://doi.org/10.5194/acp-15-5727-2015, 2015
Short summary
Short summary
Extraction of natural gas and oil is associated with a range of possible atmospheric environmental issues. Here we present an analysis of gas-phase hydrocarbon measurements taken in an oil and natural gas extraction area in Utah during a period of high wintertime ozone. We are able to constrain important chemical parameters related to emission sources and rates, hydrocarbon photochemistry, and VOC composition.
Y. Liu, B. Yuan, X. Li, M. Shao, S. Lu, Y. Li, C.-C. Chang, Z. Wang, W. Hu, X. Huang, L. He, L. Zeng, M. Hu, and T. Zhu
Atmos. Chem. Phys., 15, 3045–3062, https://doi.org/10.5194/acp-15-3045-2015, https://doi.org/10.5194/acp-15-3045-2015, 2015
S. Dai, X. Bi, L. Y. Chan, J. He, B. Wang, X. Wang, P. Peng, G. Sheng, and J. Fu
Atmos. Chem. Phys., 15, 3097–3108, https://doi.org/10.5194/acp-15-3097-2015, https://doi.org/10.5194/acp-15-3097-2015, 2015
B. Yuan, P. R. Veres, C. Warneke, J. M. Roberts, J. B. Gilman, A. Koss, P. M. Edwards, M. Graus, W. C. Kuster, S.-M. Li, R. J. Wild, S. S. Brown, W. P. Dubé, B. M. Lerner, E. J. Williams, J. E. Johnson, P. K. Quinn, T. S. Bates, B. Lefer, P. L. Hayes, J. L. Jimenez, R. J. Weber, R. Zamora, B. Ervens, D. B. Millet, B. Rappenglück, and J. A. de Gouw
Atmos. Chem. Phys., 15, 1975–1993, https://doi.org/10.5194/acp-15-1975-2015, https://doi.org/10.5194/acp-15-1975-2015, 2015
Short summary
Short summary
In this work, secondary formation of formic acid at an urban site and a site in an oil and gas production region is studied. We investigated various gas phase formation pathways of formic acid, including those recently proposed, using a box model. The contributions from aerosol-related processes, fog events and air-snow exchange to formic acid are also quantified.
M. Wang, M. Shao, W. Chen, S. Lu, Y. Liu, B. Yuan, Q. Zhang, Q. Zhang, C.-C. Chang, B. Wang, L. Zeng, M. Hu, Y. Yang, and Y. Li
Atmos. Chem. Phys., 15, 1489–1502, https://doi.org/10.5194/acp-15-1489-2015, https://doi.org/10.5194/acp-15-1489-2015, 2015
C. Warneke, P. Veres, S. M. Murphy, J. Soltis, R. A. Field, M. G. Graus, A. Koss, S.-M. Li, R. Li, B. Yuan, J. M. Roberts, and J. A. de Gouw
Atmos. Meas. Tech., 8, 411–420, https://doi.org/10.5194/amt-8-411-2015, https://doi.org/10.5194/amt-8-411-2015, 2015
R. Ahmadov, S. McKeen, M. Trainer, R. Banta, A. Brewer, S. Brown, P. M. Edwards, J. A. de Gouw, G. J. Frost, J. Gilman, D. Helmig, B. Johnson, A. Karion, A. Koss, A. Langford, B. Lerner, J. Olson, S. Oltmans, J. Peischl, G. Pétron, Y. Pichugina, J. M. Roberts, T. Ryerson, R. Schnell, C. Senff, C. Sweeney, C. Thompson, P. R. Veres, C. Warneke, R. Wild, E. J. Williams, B. Yuan, and R. Zamora
Atmos. Chem. Phys., 15, 411–429, https://doi.org/10.5194/acp-15-411-2015, https://doi.org/10.5194/acp-15-411-2015, 2015
Short summary
Short summary
High 2013 wintertime O3 pollution events associated with oil/gas production within the Uinta Basin are studied using a 3D model. It's able quantitatively to reproduce these events using emission estimates of O3 precursors based on ambient measurements (top-down approach), but unable to reproduce them using a recent bottom-up emission inventory for the oil/gas industry. The role of various physical and meteorological processes, chemical species and pathways contributing to high O3 are quantified.
X. Li, F. Rohrer, T. Brauers, A. Hofzumahaus, K. Lu, M. Shao, Y. H. Zhang, and A. Wahner
Atmos. Chem. Phys., 14, 12291–12305, https://doi.org/10.5194/acp-14-12291-2014, https://doi.org/10.5194/acp-14-12291-2014, 2014
Q. Zhang, B. Yuan, M. Shao, X. Wang, S. Lu, K. Lu, M. Wang, L. Chen, C.-C. Chang, and S. C. Liu
Atmos. Chem. Phys., 14, 6089–6101, https://doi.org/10.5194/acp-14-6089-2014, https://doi.org/10.5194/acp-14-6089-2014, 2014
M. Wang, M. Shao, W. Chen, B. Yuan, S. Lu, Q. Zhang, L. Zeng, and Q. Wang
Atmos. Chem. Phys., 14, 5871–5891, https://doi.org/10.5194/acp-14-5871-2014, https://doi.org/10.5194/acp-14-5871-2014, 2014
M. Li, Q. Zhang, D. G. Streets, K. B. He, Y. F. Cheng, L. K. Emmons, H. Huo, S. C. Kang, Z. Lu, M. Shao, H. Su, X. Yu, and Y. Zhang
Atmos. Chem. Phys., 14, 5617–5638, https://doi.org/10.5194/acp-14-5617-2014, https://doi.org/10.5194/acp-14-5617-2014, 2014
K. D. Lu, F. Rohrer, F. Holland, H. Fuchs, T. Brauers, A. Oebel, R. Dlugi, M. Hu, X. Li, S. R. Lou, M. Shao, T. Zhu, A. Wahner, Y. H. Zhang, and A. Hofzumahaus
Atmos. Chem. Phys., 14, 4979–4999, https://doi.org/10.5194/acp-14-4979-2014, https://doi.org/10.5194/acp-14-4979-2014, 2014
W. T. Chen, M. Shao, S. H. Lu, M. Wang, L. M. Zeng, B. Yuan, and Y. Liu
Atmos. Chem. Phys., 14, 3047–3062, https://doi.org/10.5194/acp-14-3047-2014, https://doi.org/10.5194/acp-14-3047-2014, 2014
Z. B. Wang, M. Hu, D. Mogensen, D. L. Yue, J. Zheng, R. Y. Zhang, Y. Liu, B. Yuan, X. Li, M. Shao, L. Zhou, Z. J. Wu, A. Wiedensohler, and M. Boy
Atmos. Chem. Phys., 13, 11157–11167, https://doi.org/10.5194/acp-13-11157-2013, https://doi.org/10.5194/acp-13-11157-2013, 2013
W. W. Hu, M. Hu, B. Yuan, J. L. Jimenez, Q. Tang, J. F. Peng, W. Hu, M. Shao, M. Wang, L. M. Zeng, Y. S. Wu, Z. H. Gong, X. F. Huang, and L. Y. He
Atmos. Chem. Phys., 13, 10095–10112, https://doi.org/10.5194/acp-13-10095-2013, https://doi.org/10.5194/acp-13-10095-2013, 2013
C.-C. Chang, M. Shao, C. C. K. Chou, S.-C. Liu, J.-L. Wang, K.-Z. Lee, C.-H. Lai, T. Zhu, and P.-H. Lin
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acpd-13-25939-2013, https://doi.org/10.5194/acpd-13-25939-2013, 2013
Revised manuscript not accepted
B. Yuan, W. W. Hu, M. Shao, M. Wang, W. T. Chen, S. H. Lu, L. M. Zeng, and M. Hu
Atmos. Chem. Phys., 13, 8815–8832, https://doi.org/10.5194/acp-13-8815-2013, https://doi.org/10.5194/acp-13-8815-2013, 2013
Related subject area
Subject: Gases | Research Activity: Field Measurements | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
Ozone deposition measurements over wheat fields in the North China Plain: variability and related factors of deposition flux and velocity
Consistency evaluation of tropospheric ozone from ozonesonde and IAGOS (In-service Aircraft for a Global Observing System) observations: vertical distribution, ozonesonde types, and station–airport distance
CO2 and CO temporal variability over Mexico City from ground-based total column and surface measurements
Investigating carbonyl compounds above the Amazon rainforest using a proton-transfer-reaction time-of-flight mass spectrometer (PTR-ToF-MS) with NO+ chemical ionization
Measurement report: In-flight and ground-based measurements of nitrogen oxide emissions from latest-generation jet engines and 100 % sustainable aviation fuel
Measurement report: Sources, sinks, and lifetime of NOx in a suburban temperate forest at night
Measurement report: Urban ammonia and amines in Houston, Texas
Biomass-burning sources control ambient particulate matter, but traffic and industrial sources control volatile organic compound (VOC) emissions and secondary-pollutant formation during extreme pollution events in Delhi
Multi-year observations of variable incomplete combustion in the New York megacity
Observations of the vertical distributions of summertime atmospheric pollutants in Nam Co: OH production and source analysis
Measurement report: Elevated atmospheric ammonia may promote particle pH and HONO formation – insights from the COVID-19 pandemic
Measurement report: Vertical and temporal variability in the near-surface ozone production rate and sensitivity in an urban area in the Pearl River Delta region, China
Elevated oxidized mercury in the free troposphere: analytical advances and application at a remote continental mountaintop site
Using observed urban NOx sinks to constrain VOC reactivity and the ozone and radical budget in the Seoul Metropolitan Area
Real-world emission characteristics of VOCs from typical cargo ships and their potential contributions to secondary organic aerosol and O3 under low-sulfur fuel policies
NO3 reactivity during a summer period in a temperate forest below and above the canopy
The role of oceanic ventilation and terrestrial outflow in atmospheric non-methane hydrocarbons over the Chinese marginal seas
Concentration and source changes of nitrous acid (HONO) during the COVID-19 lockdown in Beijing
Characteristics and sources of nonmethane volatile organic compounds (NMVOCs) and O3–NOx–NMVOC relationships in Zhengzhou, China
Seasonal Air Concentration Variability, Gas/Particle Partitioning, Precipitation Scavenging, and Air-Water Equilibrium of Organophosphate Esters in Southern Canada
Measurement report: Surface exchange fluxes of HONO during the growth process of paddy fields in the Huaihe River Basin, China
Characterization of biogenic volatile organic compounds and their oxidation products at a stressed pine forest close to a biogas power plant
On the dynamics of ozone depletion events at Villum Research Station in the High Arctic
Deciphering anthropogenic and biogenic contributions to selected non-methane volatile organic compound emissions in an urban area
Measurement report: Enhanced photochemical formation of formic and isocyanic acids in urban regions aloft – insights from tower-based online gradient measurements
Sources of organic gases and aerosol particles and their roles in nighttime particle growth at a rural forested site in southwest Germany
Surface snow bromide and nitrate at Eureka, Canada, in early spring and implications for polar boundary layer chemistry
Molecular and seasonal characteristics of organic vapors in urban Beijing: insights from Vocus-PTR measurements
Opinion: Strengthening research in the Global South – atmospheric science opportunities in South America and Africa
Analysis of ozone vertical profile day-to-day variability in the lower troposphere during the Paris-2022 ACROSS campaign
Shipping and algae emissions have a major impact on ambient air mixing ratios of non-methane hydrocarbons (NMHCs) and methanethiol on Utö Island in the Baltic Sea
Measurement report: Long-term measurements of ozone concentrations in semi-natural African ecosystems
Contribution of cooking emissions to the urban volatile organic compounds in Las Vegas, NV
Reanalysis of NOAA H2 observations: implications for the H2 budget
A large role of missing volatile organic compound reactivity from anthropogenic emissions in ozone pollution regulation
Measurement report: Insights into the chemical composition and origin of molecular clusters and potential precursor molecules present in the free troposphere over the southern Indian Ocean: observations from the Maïdo Observatory (2150 m a.s.l., Réunion)
Production of oxygenated volatile organic compounds from the ozonolysis of coastal seawater
Comment on “Transport of substantial stratospheric ozone to the surface by a dying typhoon and shallow convection” by Chen et al. (2022)
Observations of cyanogen bromide (BrCN) in the global troposphere and their relation to polar surface O3 destruction
Individual coal mine methane emissions constrained by eddy covariance measurements: low bias and missing sources
The variations of VOCs based on the policy change of Omicron in polluted winter in traffic-hub city, China
Discovery of reactive chlorine, sulphur and nitrogen containing ambient volatile organic compounds in the megacity of Delhi during both clean and extremely polluted seasons
Measurement report: Observations of ground-level ozone concentration gradients perpendicular to the Lake Ontario shoreline
Measurement report: The Palau Atmospheric Observatory and its ozonesonde record – continuous monitoring of tropospheric composition and dynamics in the tropical western Pacific
Quantifying SO2 oxidation pathways to atmospheric sulfate using stable sulfur and oxygen isotopes: laboratory simulation and field observation
Influences of downward transport and photochemistry on surface ozone over East Antarctica during austral summer: in situ observations and model simulations
Iodine oxoacids and their roles in sub-3 nm particle growth in polluted urban environments
Intensive photochemical oxidation in the marine atmosphere: evidence from direct radical measurements
Diurnal variations in oxygen and nitrogen isotopes of atmospheric nitrogen dioxide and nitrate: implications for tracing NOx oxidation pathways and emission sources
Measurement report: Method for evaluating CO2 emissions from a cement plant using atmospheric δ(O2 ∕ N2) and CO2 measurements and its implication for future detection of CO2 capture signals
Xiaoyi Zhang, Wanyun Xu, Weili Lin, Gen Zhang, Jinjian Geng, Li Zhou, Huarong Zhao, Sanxue Ren, Guangsheng Zhou, Jianmin Chen, and Xiaobin Xu
Atmos. Chem. Phys., 24, 12323–12340, https://doi.org/10.5194/acp-24-12323-2024, https://doi.org/10.5194/acp-24-12323-2024, 2024
Short summary
Short summary
Ozone (O3) deposition is a key process that removes surface O3, affecting air quality, ecosystems and climate change. We conducted O3 deposition measurement over a wheat canopy using a newly relaxed eddy accumulation flux system. Large variabilities in O3 deposition were detected, mainly determined by crop growth and modulated by various environmental factors. More O3 deposition observations over different surfaces are needed for exploring deposition mechanisms and model optimization.
Honglei Wang, David W. Tarasick, Jane Liu, Herman G. J. Smit, Roeland Van Malderen, Lijuan Shen, Romain Blot, and Tianliang Zhao
Atmos. Chem. Phys., 24, 11927–11942, https://doi.org/10.5194/acp-24-11927-2024, https://doi.org/10.5194/acp-24-11927-2024, 2024
Short summary
Short summary
In this study, we identify 23 suitable pairs of sites from World Ozone and Ultraviolet Radiation Data Centre (WOUDC) and In-service Aircraft for a Global Observing System (IAGOS) datasets (1995 to 2021), compare the average vertical distributions of tropospheric O3 from ozonesonde and aircraft measurements, and analyze the differences based on ozonesonde type and station–airport distance.
Noémie Taquet, Wolfgang Stremme, María Eugenia González del Castillo, Victor Almanza, Alejandro Bezanilla, Olivier Laurent, Carlos Alberti, Frank Hase, Michel Ramonet, Thomas Lauvaux, Ke Che, and Michel Grutter
Atmos. Chem. Phys., 24, 11823–11848, https://doi.org/10.5194/acp-24-11823-2024, https://doi.org/10.5194/acp-24-11823-2024, 2024
Short summary
Short summary
We characterize the variability in CO and CO2 emissions over Mexico City from long-term time-resolved Fourier transform infrared spectroscopy solar absorption and surface measurements from 2013 to 2021. Using the average intraday CO growth rate from total columns, the average CO / CO2 ratio and TROPOMI data, we estimate the interannual variability in the CO and CO2 anthropogenic emissions of Mexico City, highlighting the effect of an unprecedented drop in activity due to the COVID-19 lockdown.
Akima Ringsdorf, Achim Edtbauer, Bruna Holanda, Christopher Poehlker, Marta O. Sá, Alessandro Araújo, Jürgen Kesselmeier, Jos Lelieveld, and Jonathan Williams
Atmos. Chem. Phys., 24, 11883–11910, https://doi.org/10.5194/acp-24-11883-2024, https://doi.org/10.5194/acp-24-11883-2024, 2024
Short summary
Short summary
We show the average height distribution of separately observed aldehydes and ketones over a day and discuss their rainforest-specific sources and sinks as well as their seasonal changes above the Amazon. Ketones have much longer atmospheric lifetimes than aldehydes and thus different implications for atmospheric chemistry. However, they are commonly observed together, which we overcome by measuring with a NO+ chemical ionization mass spectrometer for the first time in the Amazon rainforest.
Theresa Harlass, Rebecca Dischl, Stefan Kaufmann, Raphael Märkl, Daniel Sauer, Monika Scheibe, Paul Stock, Tiziana Bräuer, Andreas Dörnbrack, Anke Roiger, Hans Schlager, Ulrich Schumann, Magdalena Pühl, Tobias Schripp, Tobias Grein, Linda Bondorf, Charles Renard, Maxime Gauthier, Mark Johnson, Darren Luff, Paul Madden, Peter Swann, Denise Ahrens, Reetu Sallinen, and Christiane Voigt
Atmos. Chem. Phys., 24, 11807–11822, https://doi.org/10.5194/acp-24-11807-2024, https://doi.org/10.5194/acp-24-11807-2024, 2024
Short summary
Short summary
Emissions from aircraft have a direct impact on our climate. Here, we present airborne and ground-based measurement data of nitrogen oxides that were collected in the exhaust of an Airbus aircraft. We study the impact of burning fossil and sustainable aviation fuel on nitrogen oxide emissions at different engine settings related to combustor temperature, pressure and fuel flow. Further, we compare observations with engine emission models.
Simone T. Andersen, Max R. McGillen, Chaoyang Xue, Tobias Seubert, Patrick Dewald, Gunther N. T. E. Türk, Jan Schuladen, Cyrielle Denjean, Jean-Claude Etienne, Olivier Garrouste, Marina Jamar, Sergio Harb, Manuela Cirtog, Vincent Michoud, Mathieu Cazaunau, Antonin Bergé, Christopher Cantrell, Sebastien Dusanter, Bénédicte Picquet-Varrault, Alexandre Kukui, Abdelwahid Mellouki, Lucy J. Carpenter, Jos Lelieveld, and John N. Crowley
Atmos. Chem. Phys., 24, 11603–11618, https://doi.org/10.5194/acp-24-11603-2024, https://doi.org/10.5194/acp-24-11603-2024, 2024
Short summary
Short summary
Using measurements of various trace gases in a suburban forest near Paris in the summer of 2022, we were able to gain insight into the sources and sinks of NOx (NO+NO2) with a special focus on their nighttime chemical and physical loss processes. NO was observed as a result of nighttime soil emissions when O3 levels were strongly depleted by deposition. NO oxidation products were not observed at night, indicating that soil and/or foliar surfaces are an efficient sink of reactive N.
Lee Tiszenkel, James H. Flynn, and Shan-Hu Lee
Atmos. Chem. Phys., 24, 11351–11363, https://doi.org/10.5194/acp-24-11351-2024, https://doi.org/10.5194/acp-24-11351-2024, 2024
Short summary
Short summary
Ammonia and amines are important ingredients for aerosol formation in urban environments, but the measurements of these compounds are extremely challenging. Our observations show that urban ammonia and amines in Houston are emitted from urban sources, and diurnal variations in their concentrations are likely governed by gas-to-particle conversion and emissions.
Arpit Awasthi, Baerbel Sinha, Haseeb Hakkim, Sachin Mishra, Varkrishna Mummidivarapu, Gurmanjot Singh, Sachin D. Ghude, Vijay Kumar Soni, Narendra Nigam, Vinayak Sinha, and Madhavan N. Rajeevan
Atmos. Chem. Phys., 24, 10279–10304, https://doi.org/10.5194/acp-24-10279-2024, https://doi.org/10.5194/acp-24-10279-2024, 2024
Short summary
Short summary
We use 111 volatile organic compounds (VOCs), PM10, and PM2.5 in a positive matrix factorization (PMF) model to resolve 11 pollution sources validated with chemical fingerprints. Crop residue burning and heating account for ~ 50 % of the PM, while traffic and industrial emissions dominate the gas-phase VOC burden and formation potential of secondary organic aerosols (> 60 %). Non-tailpipe emissions from compressed-natural-gas-fuelled commercial vehicles dominate the transport sector's PM burden.
Luke D. Schiferl, Cong Cao, Bronte Dalton, Andrew Hallward-Driemeier, Ricardo Toledo-Crow, and Róisín Commane
Atmos. Chem. Phys., 24, 10129–10142, https://doi.org/10.5194/acp-24-10129-2024, https://doi.org/10.5194/acp-24-10129-2024, 2024
Short summary
Short summary
Carbon monoxide (CO) is an air pollutant and an important indicator of the incomplete combustion of fossil fuels in cities. Using 4 years of winter and spring observations in New York City, we found that both the magnitude and variability of CO from the metropolitan area are greater than expected. Transportation emissions cannot explain the missing and variable CO, which points to energy from buildings as a likely underappreciated source of urban air pollution and greenhouse gas emissions.
Chengzhi Xing, Cheng Liu, Chunxiang Ye, Jingkai Xue, Hongyu Wu, Xiangguang Ji, Jinping Ou, and Qihou Hu
Atmos. Chem. Phys., 24, 10093–10112, https://doi.org/10.5194/acp-24-10093-2024, https://doi.org/10.5194/acp-24-10093-2024, 2024
Short summary
Short summary
We identified the contributions of ozone (O3) and nitrous acid (HONO) to the production rates of hydroxide (OH) in vertical space on the Tibetan Plateau (TP). A new insight was offered: the contributions of HONO and O3 to the production rates of OH on the TP are even greater than in lower-altitudes areas. This study enriches the understanding of vertical distribution of atmospheric components and explains the strong atmospheric oxidation capacity (AOC) on the TP.
Xinyuan Zhang, Lingling Wang, Nan Wang, Shuangliang Ma, Shenbo Wang, Ruiqin Zhang, Dong Zhang, Mingkai Wang, and Hongyu Zhang
Atmos. Chem. Phys., 24, 9885–9898, https://doi.org/10.5194/acp-24-9885-2024, https://doi.org/10.5194/acp-24-9885-2024, 2024
Short summary
Short summary
This study highlights the importance of the redox reaction of NO2 with SO2 based on actual atmospheric observations. The particle pH in future China is expected to rise steadily. Consequently, this reaction could become a significant source of HONO in China. Therefore, it is crucial to coordinate the control of SO2, NOx, and NH3 emissions to avoid a rapid increase in the particle pH.
Jun Zhou, Chunsheng Zhang, Aiming Liu, Bin Yuan, Yan Wang, Wenjie Wang, Jie-Ping Zhou, Yixin Hao, Xiao-Bing Li, Xianjun He, Xin Song, Yubin Chen, Suxia Yang, Shuchun Yang, Yanfeng Wu, Bin Jiang, Shan Huang, Junwen Liu, Yuwen Peng, Jipeng Qi, Minhui Deng, Bowen Zhong, Yibo Huangfu, and Min Shao
Atmos. Chem. Phys., 24, 9805–9826, https://doi.org/10.5194/acp-24-9805-2024, https://doi.org/10.5194/acp-24-9805-2024, 2024
Short summary
Short summary
In-depth understanding of the near-ground vertical variability in photochemical ozone (O3) formation is crucial for mitigating O3 pollution. Utilizing a self-built vertical observation system, a direct net photochemical O3 production rate detection system, and an observation-based model, we diagnosed the vertical distributions and formation mechanism of net photochemical O3 production rates and sensitivity in the Pearl River Delta region, one of the most O3-polluted areas in China.
Eleanor J. Derry, Tyler R. Elgiar, Taylor Y. Wilmot, Nicholas W. Hoch, Noah S. Hirshorn, Peter Weiss-Penzias, Christopher F. Lee, John C. Lin, A. Gannet Hallar, Rainer Volkamer, Seth N. Lyman, and Lynne E. Gratz
Atmos. Chem. Phys., 24, 9615–9643, https://doi.org/10.5194/acp-24-9615-2024, https://doi.org/10.5194/acp-24-9615-2024, 2024
Short summary
Short summary
Mercury (Hg) is a globally distributed neurotoxic pollutant. Atmospheric deposition is the main source of Hg in ecosystems. However, measurement biases hinder understanding of the origins and abundance of the more bioavailable oxidized form. We used an improved, calibrated measurement system to study air mass composition and transport of atmospheric Hg at a remote mountaintop site in the central US. Oxidized Hg originated upwind in the low to middle free troposphere under clean, dry conditions.
Benjamin A. Nault, Katherine R. Travis, James H. Crawford, Donald R. Blake, Pedro Campuzano-Jost, Ronald C. Cohen, Joshua P. DiGangi, Glenn S. Diskin, Samuel R. Hall, L. Gregory Huey, Jose L. Jimenez, Kyung-Eun Min, Young Ro Lee, Isobel J. Simpson, Kirk Ullmann, and Armin Wisthaler
Atmos. Chem. Phys., 24, 9573–9595, https://doi.org/10.5194/acp-24-9573-2024, https://doi.org/10.5194/acp-24-9573-2024, 2024
Short summary
Short summary
Ozone (O3) is a pollutant formed from the reactions of gases emitted from various sources. In urban areas, the density of human activities can increase the O3 formation rate (P(O3)), thus impacting air quality and health. Observations collected over Seoul, South Korea, are used to constrain P(O3). A high local P(O3) was found; however, local P(O3) was partly reduced due to compounds typically ignored. These observations also provide constraints for unmeasured compounds that will impact P(O3).
Fan Zhang, Binyu Xiao, Zeyu Liu, Yan Zhang, Chongguo Tian, Rui Li, Can Wu, Yali Lei, Si Zhang, Xinyi Wan, Yubao Chen, Yong Han, Min Cui, Cheng Huang, Hongli Wang, Yingjun Chen, and Gehui Wang
Atmos. Chem. Phys., 24, 8999–9017, https://doi.org/10.5194/acp-24-8999-2024, https://doi.org/10.5194/acp-24-8999-2024, 2024
Short summary
Short summary
Mandatory use of low-sulfur fuel due to global sulfur limit regulations means large uncertainties in volatile organic compound (VOC) emissions. On-board tests of VOCs from nine cargo ships in China were carried out. Results showed that switching from heavy-fuel oil to diesel increased emission factor VOCs by 48 % on average, enhancing O3 and the secondary organic aerosol formation potential. Thus, implementing a global ultra-low-sulfur oil policy needs to be optimized in the near future.
Patrick Dewald, Tobias Seubert, Simone T. Andersen, Gunther N. T. E. Türk, Jan Schuladen, Max R. McGillen, Cyrielle Denjean, Jean-Claude Etienne, Olivier Garrouste, Marina Jamar, Sergio Harb, Manuela Cirtog, Vincent Michoud, Mathieu Cazaunau, Antonin Bergé, Christopher Cantrell, Sebastien Dusanter, Bénédicte Picquet-Varrault, Alexandre Kukui, Chaoyang Xue, Abdelwahid Mellouki, Jos Lelieveld, and John N. Crowley
Atmos. Chem. Phys., 24, 8983–8997, https://doi.org/10.5194/acp-24-8983-2024, https://doi.org/10.5194/acp-24-8983-2024, 2024
Short summary
Short summary
In the scope of a field campaign in a suburban forest near Paris in the summer of 2022, we measured the reactivity of the nitrate radical NO3 towards biogenic volatile organic compounds (BVOCs; e.g. monoterpenes) mainly below but also above the canopy. NO3 reactivity was the highest during nights with strong temperature inversions and decreased strongly with height. Reactions with BVOCs were the main removal process of NO3 throughout the diel cycle below the canopy.
Jian Wang, Lei Xue, Qianyao Ma, Feng Xu, Gaobin Xu, Shibo Yan, Jiawei Zhang, Jianlong Li, Honghai Zhang, Guiling Zhang, and Zhaohui Chen
Atmos. Chem. Phys., 24, 8721–8736, https://doi.org/10.5194/acp-24-8721-2024, https://doi.org/10.5194/acp-24-8721-2024, 2024
Short summary
Short summary
This study investigated the distribution and sources of non-methane hydrocarbons (NMHCs) in the lower atmosphere over the marginal seas of China. NMHCs, a subset of volatile organic compounds (VOCs), play a crucial role in atmospheric chemistry. Derived from systematic atmospheric sampling in coastal cities and marginal sea regions, this study offers valuable insights into the interaction between land and sea in shaping offshore atmospheric NMHCs.
Yusheng Zhang, Feixue Zheng, Zemin Feng, Chaofan Lian, Weigang Wang, Xiaolong Fan, Wei Ma, Zhuohui Lin, Chang Li, Gen Zhang, Chao Yan, Ying Zhang, Veli-Matti Kerminen, Federico Bianch, Tuukka Petäjä, Juha Kangasluoma, Markku Kulmala, and Yongchun Liu
Atmos. Chem. Phys., 24, 8569–8587, https://doi.org/10.5194/acp-24-8569-2024, https://doi.org/10.5194/acp-24-8569-2024, 2024
Short summary
Short summary
The nitrous acid (HONO) budget was validated during a COVID-19 lockdown event. The main conclusions are (1) HONO concentrations showed a significant decrease from 0.97 to 0.53 ppb during lockdown; (2) vehicle emissions accounted for 53 % of nighttime sources, with the heterogeneous conversion of NO2 on ground surfaces more important than aerosol; and (3) the dominant daytime source shifted from the homogenous reaction between NO and OH (51 %) to nitrate photolysis (53 %) during lockdown.
Dong Zhang, Xiao Li, Minghao Yuan, Yifei Xu, Qixiang Xu, Fangcheng Su, Shenbo Wang, and Ruiqin Zhang
Atmos. Chem. Phys., 24, 8549–8567, https://doi.org/10.5194/acp-24-8549-2024, https://doi.org/10.5194/acp-24-8549-2024, 2024
Short summary
Short summary
The increasing concentration of O3 precursors and unfavorable meteorological conditions are key factors in the formation of O3 pollution in Zhengzhou. Vehicular exhausts (28 %), solvent usage (27 %), and industrial production (22 %) are identified as the main sources of NMVOCs. Moreover, O3 formation in Zhengzhou is found to be in an anthropogenic volatile organic compound (AVOC)-limited regime. Thus, to reduce O3 formation, a minimum AVOCs / NOx reduction ratio ≥ 3 : 1 is recommended.
Yuening Li, Faqiang Zhan, Chubashini Shunthirasingham, Ying Duan Lei, Jenny Oh, Amina Ben Chaaben, Zhe Lu, Kelsey Lee, Frank A. P. C. Gobas, Hayley Hung, and Frank Wania
EGUsphere, https://doi.org/10.5194/egusphere-2024-1883, https://doi.org/10.5194/egusphere-2024-1883, 2024
Short summary
Short summary
Organophosphate esters are important man-made trace contaminants. Measuring them in the atmospheric gas phase, particles, precipitation and surface water from Canada, we explore seasonal concentration variability, gas/particle partitioning, precipitation scavenging, and air-water equilibrium. Whereas higher concentrations in summer and efficient precipitation scavenging conform with expectations, the lack of a relationship between compound volatility and gas-particle partitioning is puzzling.
Fanhao Meng, Baobin Han, Min Qin, Wu Fang, Ke Tang, Dou Shao, Zhitang Liao, Jun Duan, Yan Feng, Yong Huang, Ting Ni, and Pinhua Xie
EGUsphere, https://doi.org/10.5194/egusphere-2024-2127, https://doi.org/10.5194/egusphere-2024-2127, 2024
Short summary
Short summary
Comprehensive observations of HONO and NOx fluxes were first performed over paddy fields in the Huaihe River Basin. The consecutive peaks in HONO flux and NO flux demonstrated a potentially enhanced release of HONO and NO due to soil tillage, whereas higher WFPS (~80 %) inhibited microbial processes following irrigation. Notably, the biological processes and light-driven NO2 reactions on the surface could both be sources of HONO and influence the local HONO budget during rotary tillage.
Junwei Song, Georgios I. Gkatzelis, Ralf Tillmann, Nicolas Brüggemann, Thomas Leisner, and Harald Saathoff
EGUsphere, https://doi.org/10.5194/egusphere-2024-1768, https://doi.org/10.5194/egusphere-2024-1768, 2024
Short summary
Short summary
VOCs and organic aerosol (OA) particles were measured online at an European stressed pine forest site. Higher temperatures can enhance the forest emissions of biogenic VOCs exceeding their photochemical consumption during daytime. Weakly oxidized monoterpene products dominated the VOCs during nighttime. Moreover, increasing relative humidity can promote the gas-to-particle partitioning of these weakly oxidized monoterpene products, leading to increased OA mass.
Jakob Boyd Pernov, Jens Liengaard Hjorth, Lise Lotte Sørensen, and Henrik Skov
EGUsphere, https://doi.org/10.5194/egusphere-2024-1676, https://doi.org/10.5194/egusphere-2024-1676, 2024
Short summary
Short summary
Arctic ozone depletion events (ODEs) occurs every spring and have vast implications for the oxidizing capacity, radiative balance, and mercury oxidation. In this study, we analyze ozone, ODEs, and their connection to meteorological and air mass history variables through statistical analyses, back-trajectories, and machine learning (ML) at Villum Research Station. ODEs are favorable under sunny, calm conditions with air masses arriving from northerly wind directions with sea ice contact.
Arianna Peron, Martin Graus, Marcus Striednig, Christian Lamprecht, Georg Wohlfahrt, and Thomas Karl
Atmos. Chem. Phys., 24, 7063–7083, https://doi.org/10.5194/acp-24-7063-2024, https://doi.org/10.5194/acp-24-7063-2024, 2024
Short summary
Short summary
The anthropogenic fraction of non-methane volatile organic compound (NMVOC) emissions associated with biogenic sources (e.g., terpenes) is investigated based on eddy covariance observations. The anthropogenic fraction of terpene emissions is strongly dependent on season. When analyzing volatile chemical product (VCP) emissions in urban environments, we caution that observations from short-term campaigns might over-/underestimate their significance depending on local and seasonal circumstances.
Qing Yang, Xiao-Bing Li, Bin Yuan, Xiaoxiao Zhang, Yibo Huangfu, Lei Yang, Xianjun He, Jipeng Qi, and Min Shao
Atmos. Chem. Phys., 24, 6865–6882, https://doi.org/10.5194/acp-24-6865-2024, https://doi.org/10.5194/acp-24-6865-2024, 2024
Short summary
Short summary
Online vertical gradient measurements of formic and isocyanic acids were made based on a 320 m tower in a megacity. Vertical variations and sources of the two acids were analyzed in this study. We find that formic and isocyanic acids exhibited positive vertical gradients and were mainly contributed by photochemical formations. The formation of formic and isocyanic acids was also significantly enhanced in urban regions aloft.
Junwei Song, Harald Saathoff, Feng Jiang, Linyu Gao, Hengheng Zhang, and Thomas Leisner
Atmos. Chem. Phys., 24, 6699–6717, https://doi.org/10.5194/acp-24-6699-2024, https://doi.org/10.5194/acp-24-6699-2024, 2024
Short summary
Short summary
This study presents concurrent online measurements of organic gas and particles (VOCs and OA) at a forested site in summer. Both VOCs and OA were largely contributed by oxygenated organic compounds. Semi-volatile oxygenated OA and organic nitrate formed from monoterpenes and sesquiterpenes contributed significantly to nighttime particle growth. The results help us to understand the causes of nighttime particle growth regularly observed in summer in central European rural forested environments.
Xin Yang, Kimberly Strong, Alison S. Criscitiello, Marta Santos-Garcia, Kristof Bognar, Xiaoyi Zhao, Pierre Fogal, Kaley A. Walker, Sara M. Morris, and Peter Effertz
Atmos. Chem. Phys., 24, 5863–5886, https://doi.org/10.5194/acp-24-5863-2024, https://doi.org/10.5194/acp-24-5863-2024, 2024
Short summary
Short summary
This study uses snow samples collected from a Canadian high Arctic site, Eureka, to demonstrate that surface snow in early spring is a net sink of atmospheric bromine and nitrogen. Surface snow bromide and nitrate are significantly correlated, indicating the oxidation of reactive nitrogen is accelerated by reactive bromine. In addition, we show evidence that snow photochemical release of reactive bromine is very weak, and its emission flux is much smaller than the deposition flux of bromide.
Zhaojin An, Rujing Yin, Xinyan Zhao, Xiaoxiao Li, Yi Yuan, Junchen Guo, Yuyang Li, Xue Li, Dandan Li, Yaowei Li, Dongbin Wang, Chao Yan, Kebin He, Douglas R. Worsnop, Frank N. Keutsch, and Jingkun Jiang
EGUsphere, https://doi.org/10.5194/egusphere-2024-1325, https://doi.org/10.5194/egusphere-2024-1325, 2024
Short summary
Short summary
Online Vocus-PTR measurements show the compositions and seasonal variations of organic vapors in urban Beijing. With enhanced sensitivity and mass resolution, various sub-ppt level species and organics with multiple oxygens (≥3) were discovered. The fast photooxidation process in summer leads to an increase in both concentration and proportion of organics with multiple oxygens. While in other seasons, the variations of them could be influenced by primary emissions.
Rebecca M. Garland, Katye E. Altieri, Laura Dawidowski, Laura Gallardo, Aderiana Mbandi, Nestor Y. Rojas, and N'datchoh E. Touré
Atmos. Chem. Phys., 24, 5757–5764, https://doi.org/10.5194/acp-24-5757-2024, https://doi.org/10.5194/acp-24-5757-2024, 2024
Short summary
Short summary
This opinion piece focuses on two geographical areas in the Global South where the authors are based that are underrepresented in atmospheric science. This opinion provides context on common challenges and constraints, with suggestions on how the community can address these. The focus is on the strengths of atmospheric science research in these regions. It is these strengths, we believe, that highlight the critical role of Global South researchers in the future of atmospheric science research.
Gerard Ancellet, Camille Viatte, Anne Boynard, François Ravetta, Jacques Pelon, Cristelle Cailteau-Fischbach, Pascal Genau, Julie Capo, Axel Roy, and Philippe Nédélec
EGUsphere, https://doi.org/10.5194/egusphere-2024-892, https://doi.org/10.5194/egusphere-2024-892, 2024
Short summary
Short summary
Characterization of ozone pollution in urban areas has benefited from a measurement campaign in summer 2022 in the Paris region. The analysis is based on 21 days of lidar and aircraft observations. The main objective is a sensitivity analysis of ozone pollution to first the micrometeorological processes in the urban atmospheric boundary layer, and second, the transport of regional pollution. The paper also discuss to what extent satellite observations can track the observed ozone plumes.
Heidi Hellén, Rostislav Kouznetsov, Kaisa Kraft, Jukka Seppälä, Mika Vestenius, Jukka-Pekka Jalkanen, Lauri Laakso, and Hannele Hakola
Atmos. Chem. Phys., 24, 4717–4731, https://doi.org/10.5194/acp-24-4717-2024, https://doi.org/10.5194/acp-24-4717-2024, 2024
Short summary
Short summary
Mixing ratios of C2-C5 NMHCs and methanethiol were measured on an island in the Baltic Sea using an in situ gas chromatograph. Shipping emissions were found to be an important source of ethene, ethyne, propene, and benzene. High summertime mixing ratios of methanethiol and dependence of mixing ratios on seawater temperature and height indicated the biogenic origin to possibly be phytoplankton or macroalgae. These emissions may have a strong impact on SO2 production and new particle formation.
Hagninou Elagnon Venance Donnou, Aristide Barthélémy Akpo, Money Ossohou, Claire Delon, Véronique Yoboué, Dungall Laouali, Marie Ouafo-Leumbe, Pieter Gideon Van Zyl, Ousmane Ndiaye, Eric Gardrat, Maria Dias-Alves, and Corinne Galy-Lacaux
EGUsphere, https://doi.org/10.5194/egusphere-2024-284, https://doi.org/10.5194/egusphere-2024-284, 2024
Short summary
Short summary
Ozone is a secondary air pollutant that is detrimental to human and plant health. A better understanding of its chemical evolution is a challenge for Africa, where it is still under-sampled. Out of 14 sites examined (1995–2020), high levels of O3 are reported in southern Africa. The dominant chemical processes leading to O3 formation are identified. A decrease in O3 is observed at Katibougou (Mali) and Banizoumbou (Niger), and an increase at Zoétélé (Cameroon) and Skukuza (South Africa).
Matthew M. Coggon, Chelsea E. Stockwell, Lu Xu, Jeff Peischl, Jessica B. Gilman, Aaron Lamplugh, Henry J. Bowman, Kenneth Aikin, Colin Harkins, Qindan Zhu, Rebecca H. Schwantes, Jian He, Meng Li, Karl Seltzer, Brian McDonald, and Carsten Warneke
Atmos. Chem. Phys., 24, 4289–4304, https://doi.org/10.5194/acp-24-4289-2024, https://doi.org/10.5194/acp-24-4289-2024, 2024
Short summary
Short summary
Residential and commercial cooking emits pollutants that degrade air quality. Here, ambient observations show that cooking is an important contributor to anthropogenic volatile organic compounds (VOCs) emitted in Las Vegas, NV. These emissions are not fully presented in air quality models, and more work may be needed to quantify emissions from important sources, such as commercial restaurants.
Fabien Paulot, Gabrielle Pétron, Andrew M. Crotwell, and Matteo B. Bertagni
Atmos. Chem. Phys., 24, 4217–4229, https://doi.org/10.5194/acp-24-4217-2024, https://doi.org/10.5194/acp-24-4217-2024, 2024
Short summary
Short summary
New data from the National Oceanic and Atmospheric Administration show that hydrogen (H2) concentrations increased from 2010 to 2019, which is consistent with the simulated increase in H2 photochemical production (mainly from methane). But this cannot be reconciled with the expected decrease (increase) in H2 anthropogenic emissions (soil deposition) in the same period. This shows gaps in our knowledge of the H2 biogeochemical cycle that must be resolved to quantify the impact of higher H2 usage.
Wenjie Wang, Bin Yuan, Hang Su, Yafang Cheng, Jipeng Qi, Sihang Wang, Wei Song, Xinming Wang, Chaoyang Xue, Chaoqun Ma, Fengxia Bao, Hongli Wang, Shengrong Lou, and Min Shao
Atmos. Chem. Phys., 24, 4017–4027, https://doi.org/10.5194/acp-24-4017-2024, https://doi.org/10.5194/acp-24-4017-2024, 2024
Short summary
Short summary
This study investigates the important role of unmeasured volatile organic compounds (VOCs) in ozone formation. Based on results in a megacity of China, we show that unmeasured VOCs can contribute significantly to ozone fomation and also influence the determination of ozone control strategy. Our results show that these unmeasured VOCs are mainly from human sources.
Romain Salignat, Matti Rissanen, Siddharth Iyer, Jean-Luc Baray, Pierre Tulet, Jean-Marc Metzger, Jérôme Brioude, Karine Sellegri, and Clémence Rose
Atmos. Chem. Phys., 24, 3785–3812, https://doi.org/10.5194/acp-24-3785-2024, https://doi.org/10.5194/acp-24-3785-2024, 2024
Short summary
Short summary
Using mass spectrometry data collected at the Maïdo Observatory (2160 m a.s.l., Réunion), we provide the first detailed analysis of molecular cluster chemical composition specifically in the marine free troposphere. The abundance of the identified species is related both to in situ meteorological parameters and air mass history, which also provide insight into their origin. Our work makes an important contribution to documenting the chemistry and physics of the marine free troposphere.
Delaney B. Kilgour, Gordon A. Novak, Megan S. Claflin, Brian M. Lerner, and Timothy H. Bertram
Atmos. Chem. Phys., 24, 3729–3742, https://doi.org/10.5194/acp-24-3729-2024, https://doi.org/10.5194/acp-24-3729-2024, 2024
Short summary
Short summary
Laboratory experiments with seawater mimics suggest ozone deposition to the surface ocean can be a source of reactive carbon to the marine atmosphere. We conduct both field and laboratory measurements to assess abiotic VOC composition and yields from ozonolysis of real surface seawater. We show that C5–C11 aldehydes contribute to the observed VOC emission flux. We estimate that VOCs generated by the ozonolysis of surface seawater are competitive with biological VOC production and emission.
Xiangdong Zheng, Wen Yang, Yuting Sun, Chunmei Geng, Yingying Liu, and Xiaobin Xu
Atmos. Chem. Phys., 24, 3759–3768, https://doi.org/10.5194/acp-24-3759-2024, https://doi.org/10.5194/acp-24-3759-2024, 2024
Short summary
Short summary
Chen et al. (2022) attributed the nocturnal ozone enhancement (NOE) during the night of 31 July 2021 in the North China Plain (NCP) to "the direct stratospheric intrusion to reach the surface". We analyzed in situ data from the NCP. Our results do not suggest that there was a significant impact from the stratosphere on surface ozone during the NOE. We argue that the NOE was not caused by stratospheric intrusion but originated from fresh photochemical production in the lower troposphere.
James M. Roberts, Siyuan Wang, Patrick R. Veres, J. Andrew Neuman, Michael A. Robinson, Ilann Bourgeois, Jeff Peischl, Thomas B. Ryerson, Chelsea R. Thompson, Hannah M. Allen, John D. Crounse, Paul O. Wennberg, Samuel R. Hall, Kirk Ullmann, Simone Meinardi, Isobel J. Simpson, and Donald Blake
Atmos. Chem. Phys., 24, 3421–3443, https://doi.org/10.5194/acp-24-3421-2024, https://doi.org/10.5194/acp-24-3421-2024, 2024
Short summary
Short summary
We measured cyanogen bromide (BrCN) in the troposphere for the first time. BrCN is a product of the same active bromine chemistry that destroys ozone and removes mercury in polar surface environments and is a previously unrecognized sink for active Br compounds. BrCN has an apparent lifetime against heterogeneous loss in the range 1–10 d, so it serves as a cumulative marker of Br-radical chemistry. Accounting for BrCN chemistry is an important part of understanding polar Br cycling.
Kai Qin, Wei Hu, Qin He, Fan Lu, and Jason Blake Cohen
Atmos. Chem. Phys., 24, 3009–3028, https://doi.org/10.5194/acp-24-3009-2024, https://doi.org/10.5194/acp-24-3009-2024, 2024
Short summary
Short summary
We compute CH4 emissions and uncertainty on a mine-by-mine basis, including underground, overground, and abandoned mines. Mine-by-mine gas and flux data and 30 min observations from a flux tower located next to a mine shaft are integrated. The observed variability and bias correction are propagated over the emissions dataset, demonstrating that daily observations may not cover the range of variability. Comparisons show both an emissions magnitude and spatial mismatch with current inventories.
Bowen Zhang, Dong Zhang, Zhe Dong, Xinshuai Song, Ruiqin Zhang, and Xiao Li
EGUsphere, https://doi.org/10.5194/egusphere-2024-575, https://doi.org/10.5194/egusphere-2024-575, 2024
Short summary
Short summary
Continuous online VOCs monitoring was carried out at an urban site in a traffic-hub city for two months during the Omicron-infected stage. The characteristics and variations of VOCs in different periods were studied, and their impact on the formation of SOA were evaluated. The work in this manuscript evaluated the influence of the policy variation on VOCs pollution, which will provide some basis for VOCs pollution research and control of pollution sources.
Sachin Mishra, Vinayak Sinha, Haseeb Hakkim, Arpit Awasthi, Sachin D. Ghude, Vijay Kumar Soni, Narendra Nigam, Baerbel Sinha, and Madhavan N. Rajeevan
EGUsphere, https://doi.org/10.5194/egusphere-2024-500, https://doi.org/10.5194/egusphere-2024-500, 2024
Short summary
Short summary
We quantified 111 gases using extended volatility mass spectrometry to understand how changes in seasonality and emissions lead from clean air in monsoon to extremely polluted air in the post-monsoon season in Delhi. Averaged total mass concentrations (260 µgm-3) were >4 times in polluted periods, driven by biomass burning emissions and reduced atmospheric ventilation. Reactive gaseous nitrogen, chlorine and sulphur compounds hitherto un-reported from such a polluted environment were discovered.
Yao Yan Huang and D. James Donaldson
Atmos. Chem. Phys., 24, 2387–2398, https://doi.org/10.5194/acp-24-2387-2024, https://doi.org/10.5194/acp-24-2387-2024, 2024
Short summary
Short summary
Ground-level ozone interacts at the lake–land boundary; this is important to our understanding and modelling of atmospheric chemistry and air pollution in the lower atmosphere. We show that a steep ozone gradient occurs year-round moving inland up to 1 km from the lake and that this gradient is influenced by seasonal factors on the local land environment, where more rural areas are more greatly affected seasonally.
Katrin Müller, Jordis S. Tradowsky, Peter von der Gathen, Christoph Ritter, Sharon Patris, Justus Notholt, and Markus Rex
Atmos. Chem. Phys., 24, 2169–2193, https://doi.org/10.5194/acp-24-2169-2024, https://doi.org/10.5194/acp-24-2169-2024, 2024
Short summary
Short summary
The Palau Atmospheric Observatory is introduced as an ideal site to detect changes in atmospheric composition and dynamics above the remote tropical western Pacific. We focus on the ozone sounding program from 2016–2021, including El Niño 2016. The year-round high convective activity is reflected in dominant low tropospheric ozone and high relative humidity. Their seasonal distributions are unique compared to other tropical sites and are modulated by the Intertropical Convergence Zone.
Ziyan Guo, Keding Lu, Pengxiang Qiu, Mingyi Xu, and Zhaobing Guo
Atmos. Chem. Phys., 24, 2195–2205, https://doi.org/10.5194/acp-24-2195-2024, https://doi.org/10.5194/acp-24-2195-2024, 2024
Short summary
Short summary
The formation of secondary sulfate needs to be further explored. In this work, we simultaneously measured sulfur and oxygen isotopic compositions to gain an increased understanding of specific sulfate formation processes. The results indicated that secondary sulfate was mainly ascribed to SO2 homogeneous oxidation by OH radicals and heterogeneous oxidation by H2O2 and Fe3+ / O2. This study is favourable for deeply investigating the sulfur cycle in the atmosphere.
Imran A. Girach, Narendra Ojha, Prabha R. Nair, Kandula V. Subrahmanyam, Neelakantan Koushik, Mohammed M. Nazeer, Nadimpally Kiran Kumar, Surendran Nair Suresh Babu, Jos Lelieveld, and Andrea Pozzer
Atmos. Chem. Phys., 24, 1979–1995, https://doi.org/10.5194/acp-24-1979-2024, https://doi.org/10.5194/acp-24-1979-2024, 2024
Short summary
Short summary
We investigate surface ozone variability in East Antarctica based on measurements and EMAC global model simulations during austral summer. Nearly half of the surface ozone is found to be of stratospheric origin. The east coast of Antarctica acts as a stronger sink of ozone than surrounding regions. Photochemical loss of ozone is counterbalanced by downward transport of ozone. The study highlights the intertwined role of chemistry and dynamics in governing ozone variations over East Antarctica.
Ying Zhang, Duzitian Li, Xu-Cheng He, Wei Nie, Chenjuan Deng, Runlong Cai, Yuliang Liu, Yishuo Guo, Chong Liu, Yiran Li, Liangduo Chen, Yuanyuan Li, Chenjie Hua, Tingyu Liu, Zongcheng Wang, Jiali Xie, Lei Wang, Tuukka Petäjä, Federico Bianchi, Ximeng Qi, Xuguang Chi, Pauli Paasonen, Yongchun Liu, Chao Yan, Jingkun Jiang, Aijun Ding, and Markku Kulmala
Atmos. Chem. Phys., 24, 1873–1893, https://doi.org/10.5194/acp-24-1873-2024, https://doi.org/10.5194/acp-24-1873-2024, 2024
Short summary
Short summary
This study conducts a long-term observation of gaseous iodine oxoacids in two Chinese megacities, revealing their ubiquitous presence with peak concentrations (up to 0.1 pptv) in summer. Our analysis suggests a mix of terrestrial and marine sources for iodine. Additionally, iodic acid is identified as a notable contributor to sub-3 nm particle growth and particle survival probability.
Guoxian Zhang, Renzhi Hu, Pinhua Xie, Changjin Hu, Xiaoyan Liu, Liujun Zhong, Haotian Cai, Bo Zhu, Shiyong Xia, Xiaofeng Huang, Xin Li, and Wenqing Liu
Atmos. Chem. Phys., 24, 1825–1839, https://doi.org/10.5194/acp-24-1825-2024, https://doi.org/10.5194/acp-24-1825-2024, 2024
Short summary
Short summary
Comprehensive observation of HOx radicals was conducted at a coastal site in the Pearl River Delta. Radical chemistry was influenced by different air masses in a time-dependent way. Land mass promotes a more active photochemical process, with daily averages of 7.1 × 106 and 5.2 × 108 cm−3 for OH and HO2 respectively. The rapid oxidation process was accompanied by a higher diurnal HONO concentration, which influences the ozone-sensitive system and eventually magnifies the background ozone.
Sarah Albertin, Joël Savarino, Slimane Bekki, Albane Barbero, Roberto Grilli, Quentin Fournier, Irène Ventrillard, Nicolas Caillon, and Kathy Law
Atmos. Chem. Phys., 24, 1361–1388, https://doi.org/10.5194/acp-24-1361-2024, https://doi.org/10.5194/acp-24-1361-2024, 2024
Short summary
Short summary
This study reports the first simultaneous records of oxygen (Δ17O) and nitrogen (δ15N) isotopes in nitrogen dioxide (NO2) and nitrate (NO3−). These data are combined with atmospheric observations to explore sub-daily N reactive chemistry and quantify N fractionation effects in an Alpine winter city. The results highlight the necessity of using Δ17O and δ15N in both NO2 and NO3− to avoid biased estimations of NOx sources and fates from NO3− isotopic records in urban winter environments.
Shigeyuki Ishidoya, Kazuhiro Tsuboi, Hiroaki Kondo, Kentaro Ishijima, Nobuyuki Aoki, Hidekazu Matsueda, and Kazuyuki Saito
Atmos. Chem. Phys., 24, 1059–1077, https://doi.org/10.5194/acp-24-1059-2024, https://doi.org/10.5194/acp-24-1059-2024, 2024
Short summary
Short summary
A method evaluating techniques for carbon neutrality, such as carbon capture and storage (CCS), is important. This study presents a method to evaluate CO2 emissions from a cement plant based on atmospheric O2 and CO2 measurements. The method will also be useful for evaluating CO2 capture from flue gas at CCS plants, since the plants remove CO2 from the atmosphere without causing any O2 changes, just as cement plants do, differing only in the direction of CO2 exchange with the atmosphere.
Cited articles
Acton, W. J. F., Schallhart, S., Langford, B., Valach, A., Rantala, P., Fares, S., Carriero, G., Tillmann, R., Tomlinson, S. J., Dragosits, U., Gianelle, D., Hewitt, C. N., and Nemitz, E.: Canopy-scale flux measurements and bottom-up emission estimates of volatile organic compounds from a mixed oak and hornbeam forest in northern Italy, Atmos. Chem. Phys., 16, 7149–7170, https://doi.org/10.5194/acp-16-7149-2016, 2016.
Atkinson, R. and Arey, J.: Atmospheric Degradation of Volatile Organic Compounds, Chem. Rev., 103, 4605–4638, https://doi.org/10.1021/cr0206420, 2003.
Atkinson, R., Baulch, D. L., Cox, R. A., Crowley, J. N., Hampson, R. F., Hynes, R. G., Jenkin, M. E., Rossi, M. J., and Troe, J.: Evaluated kinetic and photochemical data for atmospheric chemistry: Volume I - gas phase reactions of Ox, HOx, NOx and SOx species, Atmos. Chem. Phys., 4, 1461–1738, https://doi.org/10.5194/acp-4-1461-2004, 2004.
Atkinson, R., Baulch, D. L., Cox, R. A., Crowley, J. N., Hampson, R. F., Hynes, R. G., Jenkin, M. E., Rossi, M. J., Troe, J., and IUPAC Subcommittee: Evaluated kinetic and photochemical data for atmospheric chemistry: Volume II – gas phase reactions of organic species, Atmos. Chem. Phys., 6, 3625–4055, https://doi.org/10.5194/acp-6-3625-2006, 2006.
Buhr, K., van Ruth, S., and Delahunty, C.: Analysis of volatile flavour compounds by Proton Transfer Reaction-Mass Spectrometry: fragmentation patterns and discrimination between isobaric and isomeric compounds, Int. J. Mass Spectrom., 221, 1–7, https://doi.org/10.1016/S1387-3806(02)00896-5, 2002.
Cappellin, L., Karl, T., Probst, M., Ismailova, O., Winkler, P. M., Soukoulis, C., Aprea, E., Mark, T. D., Gasperi, F., and Biasioli, F.: On quantitative determination of volatile organic compound concentrations using proton transfer reaction time-of-flight mass spectrometry, Environ. Sci. Technol., 46, 2283–2290, https://doi.org/10.1021/es203985t, 2012.
Carter, W. P.: Development of the SAPRC-07 chemical mechanism, Atmos. Environ., 44, 5324–5335, 2010.
Chang, X., Zhao, B., Zheng, H., Wang, S., Cai, S., Guo, F., Gui, P., Huang, G., Wu, D., Han, L., Xing, J., Man, H., Hu, R., Liang, C., Xu, Q., Qiu, X., Ding, D., Liu, K., Han, R., Robinson, A. L., and Donahue, N. M.: Full-volatility emission framework corrects missing and underestimated secondary organic aerosol sources, One Earth, 5, 403–412, https://doi.org/10.1016/j.oneear.2022.03.015, 2022.
Chen, Y., Yuan, B., Wang, C., Wang, S., He, X., Wu, C., Song, X., Huangfu, Y., Li, X.-B., Liao, Y., and Shao, M.: Online measurements of cycloalkanes based on NO+ chemical ionization in proton transfer reaction time-of-flight mass spectrometry (PTR-ToF-MS), Atmos. Meas. Tech., 15, 6935–6947, https://doi.org/10.5194/amt-15-6935-2022, 2022.
Coggon, M. M., McDonald, B. C., Vlasenko, A., Veres, P. R., Bernard, F., Koss, A. R., Yuan, B., Gilman, J. B., Peischl, J., Aikin, K. C., DuRant, J., Warneke, C., Li, S. M., and de Gouw, J. A.: Diurnal Variability and Emission Pattern of Decamethylcyclopentasiloxane (D5) from the Application of Personal Care Products in Two North American Cities, Environ. Sci. Technol., 52, 5610–5618, https://doi.org/10.1021/acs.est.8b00506, 2018.
Coggon, M. M., Gkatzelis, G. I., McDonald, B. C., Gilman, J. B., Schwantes, R. H., Abuhassan, N., Aikin, K. C., Arend, M. F., Berkoff, T. A., Brown, S. S., Campos, T. L., Dickerson, R. R., Gronoff, G., Hurley, J. F., Isaacman-VanWertz, G., Koss, A. R., Li, M., McKeen, S. A., Moshary, F., Peischl, J., Pospisilova, V., Ren, X., Wilson, A., Wu, Y., Trainer, M., and Warneke, C.: Volatile chemical product emissions enhance ozone and modulate urban chemistry, P. Natl. Acad. Sci. USA, 118, e2026653118, https://doi.org/10.1073/pnas.2026653118, 2021.
Coggon, M. M., Stockwell, C. E., Claflin, M. S., Pfannerstill, E. Y., Xu, L., Gilman, J. B., Marcantonio, J., Cao, C., Bates, K., Gkatzelis, G. I., Lamplugh, A., Katz, E. F., Arata, C., Apel, E. C., Hornbrook, R. S., Piel, F., Majluf, F., Blake, D. R., Wisthaler, A., Canagaratna, M., Lerner, B. M., Goldstein, A. H., Mak, J. E., and Warneke, C.: Identifying and correcting interferences to PTR-ToF-MS measurements of isoprene and other urban volatile organic compounds, Atmos. Meas. Tech., 17, 801–825, https://doi.org/10.5194/amt-17-801-2024, 2024.
de Gouw, J. and Warneke, C.: Measurements of volatile organic compounds in the earth's atmosphere using proton-transfer-reaction mass spectrometry, Mass Spectrom. Rev., 26, 223–257, https://doi.org/10.1002/mas.20119, 2007.
Donahue, N. M., Epstein, S. A., Pandis, S. N., and Robinson, A. L.: A two-dimensional volatility basis set: 1. organic-aerosol mixing thermodynamics, Atmos. Chem. Phys., 11, 3303–3318, https://doi.org/10.5194/acp-11-3303-2011, 2011.
Fang, L., Liu, W., Chen, D., Li, G., Wang, D., Shao, X., and Nie, L.: Source Profiles of Volatile Organic Compounds (VOCs) from Typical Solventbased Industries in Beijing, Environmental Science, 40, 4395–4403, https://doi.org/10.13227/j.hjkx.201901128, 2019 (in Chinese).
Fortner, E. C., Zheng, J., Zhang, R., Berk Knighton, W., Volkamer, R. M., Sheehy, P., Molina, L., and André, M.: Measurements of Volatile Organic Compounds Using Proton Transfer Reaction – Mass Spectrometry during the MILAGRO 2006 Campaign, Atmos. Chem. Phys., 9, 467–481, https://doi.org/10.5194/acp-9-467-2009, 2009.
Gao, Y., Wang, H., Yuan, L., Jing, S., Yuan, B., Shen, G., Zhu, L., Koss, A., Li, Y., Wang, Q., Huang, D. D., Zhu, S., Tao, S., Lou, S., and Huang, C.: Measurement report: Underestimated reactive organic gases from residential combustion – insights from a near-complete speciation, Atmos. Chem. Phys., 23, 6633–6646, https://doi.org/10.5194/acp-23-6633-2023, 2023.
Gkatzelis, G. I., Coggon, M. M., McDonald, B. C., Peischl, J., Aikin, K. C., Gilman, J. B., Trainer, M., and Warneke, C.: Identifying Volatile Chemical Product Tracer Compounds in U.S. Cities, Environ. Sci. Technol., 55, 188–199, https://doi.org/10.1021/acs.est.0c05467, 2021a.
Gkatzelis, G. I., Coggon, M. M., McDonald, B. C., Peischl, J., Gilman, J. B., Aikin, K. C., Robinson, M. A., Canonaco, F., Prevot, A. S. H., Trainer, M., and Warneke, C.: Observations Confirm that Volatile Chemical Products Are a Major Source of Petrochemical Emissions in U.S. Cities, Environ. Sci. Technol., 55, 4332–4343, https://doi.org/10.1021/acs.est.0c05471, 2021b.
Gonzalez-Mendez, R., Watts, P., Olivenza-Leon, D., Reich, D. F., Mullock, S. J., Corlett, C. A., Cairns, S., Hickey, P., Brookes, M., and Mayhew, C. A.: Enhancement of Compound Selectivity Using a Radio Frequency Ion-Funnel Proton Transfer Reaction Mass Spectrometer: Improved Specificity for Explosive Compounds, Anal. Chem., 88, 10624–10630, https://doi.org/10.1021/acs.analchem.6b02982, 2016.
Guenther, A. B., Jiang, X., Heald, C. L., Sakulyanontvittaya, T., Duhl, T., Emmons, L. K., and Wang, X.: The Model of Emissions of Gases and Aerosols from Nature version 2.1 (MEGAN2.1): an extended and updated framework for modeling biogenic emissions, Geosci. Model Dev., 5, 1471–1492, https://doi.org/10.5194/gmd-5-1471-2012, 2012.
Haase, K. B., Keene, W. C., Pszenny, A. A. P., Mayne, H. R., Talbot, R. W., and Sive, B. C.: Calibration and intercomparison of acetic acid measurements using proton-transfer-reaction mass spectrometry (PTR-MS), Atmos. Meas. Tech., 5, 2739–2750, https://doi.org/10.5194/amt-5-2739-2012, 2012.
Han, C., Liu, R., Luo, H., Li, G., Ma, S., Chen, J., and An, T.: Pollution profiles of volatile organic compounds from different urban functional areas in Guangzhou China based on GC/MS and PTR-TOF-MS: Atmospheric environmental implications, Atmos. Environ., 214, 116843, https://doi.org/10.1016/j.atmosenv.2019.116843, 2019.
He, X., Che, X., Gao, S., Chen, X., Pan, M., Jiang, M., Zhang, S., Jia, H., and Duan, Y.: Volatile organic compounds emission inventory of organic chemical raw material industry, Atmos. Pollut. Res., 13, 101276, https://doi.org/10.1016/j.apr.2021.101276, 2022a.
He, X., Yuan, B., Wu, C., Wang, S., Wang, C., Huangfu, Y., Qi, J., Ma, N., Xu, W., Wang, M., Chen, W., Su, H., Cheng, Y., and Shao, M.: Volatile organic compounds in wintertime North China Plain: Insights from measurements of proton transfer reaction time-of-flight mass spectrometer (PTR-ToF-MS), J. Environ. Sci., 114, 98–114, https://doi.org/10.1016/j.jes.2021.08.010, 2022b.
Huang, C., Chen, C. H., Li, L., Cheng, Z., Wang, H. L., Huang, H. Y., Streets, D. G., Wang, Y. J., Zhang, G. F., and Chen, Y. R.: Emission inventory of anthropogenic air pollutants and VOC species in the Yangtze River Delta region, China, Atmos. Chem. Phys., 11, 4105–4120, https://doi.org/10.5194/acp-11-4105-2011, 2011.
Huangfu, Y., Yuan, B., Wang, S., Wu, C., He, X., Qi, J., de Gouw, J., Warneke, C., Gilman, J. B., Wisthaler, A., Karl, T., Graus, M., Jobson, B. T., and Shao, M.: Revisiting Acetonitrile as Tracer of Biomass Burning in Anthropogenic-Influenced Environments, Geophys. Res. Lett., 48, e2020GL092322, https://doi.org/10.1029/2020gl092322, 2021.
Humes, M. B., Wang, M., Kim, S., Machesky, J. E., Gentner, D. R., Robinson, A. L., Donahue, N. M., and Presto, A. A.: Limited Secondary Organic Aerosol Production from Acyclic Oxygenated Volatile Chemical Products, Environ. Sci. Technol., 56, 4806–4815, https://doi.org/10.1021/acs.est.1c07354, 2022.
Inomata, S., Tanimoto, H., and Yamada, H.: Mass Spectrometric Detection of Alkanes Using NO+ Chemical Ionization in Proton-transfer-reaction Plus Switchable Reagent Ion Mass Spectrometry, Chem. Lett., 43, 538–540, https://doi.org/10.1246/cl.131105, 2014.
Ji, Y., Zheng, J., Qin, D., Li, Y., Gao, Y., Yao, M., Chen, X., Li, G., An, T., and Zhang, R.: OH-Initiated Oxidation of Acetylacetone: Implications for Ozone and Secondary Organic Aerosol Formation, Environ. Sci. Technol., 52, 11169–11177, https://doi.org/10.1021/acs.est.8b03972, 2018.
Kamal, M. S., Razzak, S. A., and Hossain, M. M.: Catalytic oxidation of volatile organic compounds (VOCs) – A review, Atmos. Environ., 140, 117–134, https://doi.org/10.1016/j.atmosenv.2016.05.031, 2016.
Khare, P. and Gentner, D. R.: Considering the future of anthropogenic gas-phase organic compound emissions and the increasing influence of non-combustion sources on urban air quality, Atmos. Chem. Phys., 18, 5391–5413, https://doi.org/10.5194/acp-18-5391-2018, 2018.
Khare, P., Krechmer, J. E., Machesky, J. E., Hass-Mitchell, T., Cao, C., Wang, J., Majluf, F., Lopez-Hilfiker, F., Malek, S., Wang, W., Seltzer, K., Pye, H. O. T., Commane, R., McDonald, B. C., Toledo-Crow, R., Mak, J. E., and Gentner, D. R.: Ammonium adduct chemical ionization to investigate anthropogenic oxygenated gas-phase organic compounds in urban air, Atmos. Chem. Phys., 22, 14377–14399, https://doi.org/10.5194/acp-22-14377-2022, 2022.
Koss, A. R., Warneke, C., Yuan, B., Coggon, M. M., Veres, P. R., and de Gouw, J. A.: Evaluation of NO+ reagent ion chemistry for online measurements of atmospheric volatile organic compounds, Atmos. Meas. Tech., 9, 2909–2925, https://doi.org/10.5194/amt-9-2909-2016, 2016.
Koss, A. R., Sekimoto, K., Gilman, J. B., Selimovic, V., Coggon, M. M., Zarzana, K. J., Yuan, B., Lerner, B. M., Brown, S. S., Jimenez, J. L., Krechmer, J., Roberts, J. M., Warneke, C., Yokelson, R. J., and de Gouw, J.: Non-methane organic gas emissions from biomass burning: identification, quantification, and emission factors from PTR-ToF during the FIREX 2016 laboratory experiment, Atmos. Chem. Phys., 18, 3299–3319, https://doi.org/10.5194/acp-18-3299-2018, 2018.
Kostenidou, E., Lee, B.-H., Engelhart, G. J., Pierce, J. R., and Pandis, S. N.: Mass Spectra Deconvolution of Low, Medium, and High Volatility Biogenic Secondary Organic Aerosol, Environ. Sci. Technol., 43, 4884–4889, https://doi.org/10.1021/es803676g, 2009.
Li, C., Cui, M., Zheng, J., Chen, Y., Liu, J., Ou, J., Tang, M., Sha, Q., Yu, F., Liao, S., Zhu, M., Wang, J., Yao, N., and Li, C.: Variability in real-world emissions and fuel consumption by diesel construction vehicles and policy implications, Sci. Total Environ., 786, 147256, https://doi.org/10.1016/j.scitotenv.2021.147256, 2021.
Li, G., Jiang, B., Wang, S., Li, C., Yuan, B., Wang, B., and Zhanyi, Z.: Determination of 118 Volatile Organic Compounds in Source Emission by Canister Sampling-Preconcentration/Gas Chromatography–Mass Spectrometry, Journal of Instrumental Analysis, 39, 1441–1450, 2020 (in Chinese).
Li, L. and Cocker, D. R.: Molecular structure impacts on secondary organic aerosol formation from glycol ethers, Atmos. Environ., 180, 206–215, https://doi.org/10.1016/j.atmosenv.2017.12.025, 2018.
Li, M., Zhang, Q., Zheng, B., Tong, D., Lei, Y., Liu, F., Hong, C., Kang, S., Yan, L., Zhang, Y., Bo, Y., Su, H., Cheng, Y., and He, K.: Persistent growth of anthropogenic non-methane volatile organic compound (NMVOC) emissions in China during 1990–2017: drivers, speciation and ozone formation potential, Atmos. Chem. Phys., 19, 8897–8913, https://doi.org/10.5194/acp-19-8897-2019, 2019.
Li, W., Li, L., Chen, C.-l., Kacarab, M., Peng, W., Price, D., Xu, J., and Cocker, D. R.: Potential of select intermediate-volatility organic compounds and consumer products for secondary organic aerosol and ozone formation under relevant urban conditions, Atmos. Environ., 178, 109–117, https://doi.org/10.1016/j.atmosenv.2017.12.019, 2018.
Li, X.-B., Yuan, B., Wang, S., Wang, C., Lan, J., Liu, Z., Song, Y., He, X., Huangfu, Y., Pei, C., Cheng, P., Yang, S., Qi, J., Wu, C., Huang, S., You, Y., Chang, M., Zheng, H., Yang, W., Wang, X., and Shao, M.: Variations and sources of volatile organic compounds (VOCs) in urban region: insights from measurements on a tall tower, Atmos. Chem. Phys., 22, 10567–10587, https://doi.org/10.5194/acp-22-10567-2022, 2022.
Li, X.-B., Zhang, C., Liu, A., Yuan, B., Yang, H., Liu, C., Wang, S., Huangfu, Y., Qi, J., Liu, Z., He, X., Song, X., Chen, Y., Peng, Y., Zhang, X., Zheng, E., Yang, L., Yang, Q., Qin, G., Zhou, J., and Shao, M.: Assessment of long tubing in measuring atmospheric trace gases: applications on tall towers, Environmental Science: Atmospheres, 3, 506–520, https://doi.org/10.1039/d2ea00110a, 2023.
Li, Y., Pöschl, U., and Shiraiwa, M.: Molecular corridors and parameterizations of volatility in the chemical evolution of organic aerosols, Atmos. Chem. Phys., 16, 3327–3344, https://doi.org/10.5194/acp-16-3327-2016, 2016.
Liang, Z., Chen, L., Alam, M. S., Zeraati Rezaei, S., Stark, C., Xu, H., and Harrison, R. M.: Comprehensive chemical characterization of lubricating oils used in modern vehicular engines utilizing GC × GC-TOFMS, Fuel, 220, 792–799, https://doi.org/10.1016/j.fuel.2017.11.142, 2018.
Liu, Y., Li, Y., Yuan, Z., Wang, H., Sha, Q., Lou, S., Liu, Y., Hao, Y., Duan, L., Ye, P., Zheng, J., Yuan, B., and Shao, M.: Identification of two main origins of intermediate-volatility organic compound emissions from vehicles in China through two-phase simultaneous characterization, Environ. Pollut., 281, 117020, https://doi.org/10.1016/j.envpol.2021.117020, 2021.
Malherbe, L. and Mandin, C.: VOC emissions during outdoor ship painting and health-risk assessment, Atmos. Environ., 41, 6322–6330, https://doi.org/10.1016/j.atmosenv.2007.02.018, 2007.
McDonald, B. C., de Gouw, J. A., Gilman, J. B., Jathar, S. H., Akherati, A., Cappa, C. D., Jimenez, J. L., Lee-Taylor, J., Hayes, P. L., McKeen, S. A., Cui, Y. Y., Kim, S.-W., Gentner, D. R., Isaacman-VanWertz, G., Goldstein, A. H., Harley, R. A., Frost, G. J., Roberts, J. M., Ryerson, T. B., and Trainer, M.: Volatile chemical products emerging as largest petrochemical source of urban organic emissions, Science, 359, 760–764, https://doi.org/10.1126/science.aaq0524, 2018.
Mo, Z., Shao, M., and Lu, S.: Compilation of a source profile database for hydrocarbon and OVOC emissions in China, Atmos. Environ., 143, 209–217, https://doi.org/10.1016/j.atmosenv.2016.08.025, 2016.
Mo, Z., Cui, R., Yuan, B., Cai, H., McDonald, B. C., Li, M., Zheng, J., and Shao, M.: A mass-balance-based emission inventory of non-methane volatile organic compounds (NMVOCs) for solvent use in China, Atmos. Chem. Phys., 21, 13655–13666, https://doi.org/10.5194/acp-21-13655-2021, 2021.
Na, K. and Pyo Kim, Y.: Chemical mass balance receptor model applied to ambient C2–C9 VOC concentration in Seoul, Korea: Effect of chemical reaction losses, Atmos. Environ., 41, 6715–6728, https://doi.org/10.1016/j.atmosenv.2007.04.054, 2007.
Ou, J., Zheng, J., Li, R., Huang, X., Zhong, Z., Zhong, L., and Lin, H.: Speciated OVOC and VOC emission inventories and their implications for reactivity-based ozone control strategy in the Pearl River Delta region, China, Sci. Total Environ., 530–531, 393–402, https://doi.org/10.1016/j.scitotenv.2015.05.062, 2015.
Qin, M., Murphy, B. N., Isaacs, K. K., McDonald, B. C., Lu, Q., McKeen, S. A., Koval, L., Robinson, A. L., Efstathiou, C., Allen, C., and Pye, H. O. T.: Criteria pollutant impacts of volatile chemical products informed by near-field modelling, Nature Sustainability, 4, 129–137, https://doi.org/10.1038/s41893-020-00614-1, 2021.
Rogers, T. M., Grimsrud, E. P., Herndon, S. C., Jayne, J. T., Kolb, C. E., Allwine, E., Westberg, H., Lamb, B. K., Zavala, M., Molina, L. T., Molina, M. J., and Knighton, W. B.: On-road measurements of volatile organic compounds in the Mexico City metropolitan area using proton transfer reaction mass spectrometry, Int. J. Mass Spectrom., 252, 26–37, https://doi.org/10.1016/j.ijms.2006.01.027, 2006.
Sasidharan, S., He, Y., Akherati, A., Li, Q., Li, W., Cocker, D., McDonald, B. C., Coggon, M. M., Seltzer, K. M., Pye, H. O. T., Pierce, J. R., and Jathar, S. H.: Secondary Organic Aerosol Formation from Volatile Chemical Product Emissions: Model Parameters and Contributions to Anthropogenic Aerosol, Environ. Sci. Technol., 57, 11891–11902, https://doi.org/10.1021/acs.est.3c00683, 2023.
Seco, R., Peñuelas, J., Filella, I., Llusià, J., Molowny-Horas, R., Schallhart, S., Metzger, A., Müller, M., and Hansel, A.: Contrasting winter and summer VOC mixing ratios at a forest site in the Western Mediterranean Basin: the effect of local biogenic emissions, Atmos. Chem. Phys., 11, 13161–13179, https://doi.org/10.5194/acp-11-13161-2011, 2011.
Sekimoto, K., Li, S.-M., Yuan, B., Koss, A., Coggon, M., Warneke, C., and de Gouw, J.: Calculation of the sensitivity of proton-transfer-reaction mass spectrometry (PTR-MS) for organic trace gases using molecular properties, Int. J. Mass Spectrom., 421, 71–94, https://doi.org/10.1016/j.ijms.2017.04.006, 2017.
Seltzer, K. M., Pennington, E., Rao, V., Murphy, B. N., Strum, M., Isaacs, K. K., and Pye, H. O. T.: Reactive organic carbon emissions from volatile chemical products, Atmos. Chem. Phys., 21, 5079–5100, https://doi.org/10.5194/acp-21-5079-2021, 2021.
Seltzer, K. M., Murphy, B. N., Pennington, E. A., Allen, C., Talgo, K., and Pye, H. O. T.: Volatile Chemical Product Enhancements to Criteria Pollutants in the United States, Environ. Sci. Technol., 56, 6905–6913, https://doi.org/10.1021/acs.est.1c04298, 2022.
Sha, Q., Zhu, M., Huang, H., Wang, Y., Huang, Z., Zhang, X., Tang, M., Lu, M., Chen, C., Shi, B., Chen, Z., Wu, L., Zhong, Z., Li, C., Xu, Y., Yu, F., Jia, G., Liao, S., Cui, X., Liu, J., and Zheng, J.: A newly integrated dataset of volatile organic compounds (VOCs) source profiles and implications for the future development of VOCs profiles in China, Sci. Total Environ., 793, 148348, https://doi.org/10.1016/j.scitotenv.2021.148348, 2021.
Shi, Y., Xi, Z., Lv, D., Simayi, M., Liang, Y., Ren, J., and Xie, S.: Sector-based volatile organic compound emission characteristics and reduction perspectives for coating materials manufacturing in China, J. Clean. Prod., 394, 136407, https://doi.org/10.1016/j.jclepro.2023.136407, 2023.
Song, X., Yuan, B., Wang, S., He, X., Li, X., Peng, Y., Chen, Y., Qi, J., Cai, J., Huang, S., Hu, D., Wei, W., Liu, K., and Shao, M.: Compositional Characteristics of Volatile Organic Compounds in Typical Industrial Areas of the Pearl River Delta: Importance of Oxygenated Volatile Organic Compounds, Environmental Science, 44, 1336–1345, https://doi.org/10.13227/j.hjkx.202204104, 2023 (in Chinese).
Stark, H., Yatavelli, R. L. N., Thompson, S. L., Kimmel, J. R., Cubison, M. J., Chhabra, P. S., Canagaratna, M. R., Jayne, J. T., Worsnop, D. R., and Jimenez, J. L.: Methods to extract molecular and bulk chemical information from series of complex mass spectra with limited mass resolution, Int. J. Mass Spectrom., 389, 26–38, https://doi.org/10.1016/j.ijms.2015.08.011, 2015.
Stockwell, C. E., Coggon, M. M., Gkatzelis, G. I., Ortega, J., McDonald, B. C., Peischl, J., Aikin, K., Gilman, J. B., Trainer, M., and Warneke, C.: Volatile organic compound emissions from solvent- and water-borne coatings – compositional differences and tracer compound identifications, Atmos. Chem. Phys., 21, 6005–6022, https://doi.org/10.5194/acp-21-6005-2021, 2021.
Sulzer, P., Hartungen, E., Hanel, G., Feil, S., Winkler, K., Mutschlechner, P., Haidacher, S., Schottkowsky, R., Gunsch, D., Seehauser, H., Striednig, M., Jürschik, S., Breiev, K., Lanza, M., Herbig, J., Märk, L., Märk, T. D., and Jordan, A.: A Proton Transfer Reaction-Quadrupole interface Time-Of-Flight Mass Spectrometer (PTR-QiTOF): High speed due to extreme sensitivity, Int. J. Mass Spectrom., 368, 1–5, https://doi.org/10.1016/j.ijms.2014.05.004, 2014.
Sun, W., Shao, M., Granier, C., Liu, Y., Ye, C. S., and Zheng, J. Y.: Long-Term Trends of Anthropogenic SO2, NOx, CO, and NMVOCs Emissions in China, Earth's Future, 6, 1112–1133, https://doi.org/10.1029/2018ef000822, 2018.
Tan, Y., Han, S., Chen, Y., Zhang, Z., Li, H., Li, W., Yuan, Q., Li, X., Wang, T., and Lee, S.-c.: Characteristics and source apportionment of volatile organic compounds (VOCs) at a coastal site in Hong Kong, Sci. Total Environ., 777, 146241, https://doi.org/10.1016/j.scitotenv.2021.146241, 2021.
Ulbrich, I. M., Canagaratna, M. R., Zhang, Q., Worsnop, D. R., and Jimenez, J. L.: Interpretation of organic components from Positive Matrix Factorization of aerosol mass spectrometric data, Atmos. Chem. Phys., 9, 2891–2918, https://doi.org/10.5194/acp-9-2891-2009, 2009.
Wang, C., Yuan, B., Wu, C., Wang, S., Qi, J., Wang, B., Wang, Z., Hu, W., Chen, W., Ye, C., Wang, W., Sun, Y., Wang, C., Huang, S., Song, W., Wang, X., Yang, S., Zhang, S., Xu, W., Ma, N., Zhang, Z., Jiang, B., Su, H., Cheng, Y., Wang, X., and Shao, M.: Measurements of higher alkanes using NO+ chemical ionization in PTR-ToF-MS: important contributions of higher alkanes to secondary organic aerosols in China, Atmos. Chem. Phys., 20, 14123–14138, https://doi.org/10.5194/acp-20-14123-2020, 2020.
Wang, H., Qiao, Y., Chen, C., Lu, J., Dai, H., Qiao, L., Lou, S., Huang, C., Li, L., Jing, S., and Wu, J.: Source Profiles and Chemical Reactivity of Volatile Organic Compounds from Solvent Use in Shanghai, China, Aerosol Air Qual. Res., 14, 301–310, https://doi.org/10.4209/aaqr.2013.03.0064, 2014.
Wang, H., Sun, S., Nie, L., Zhang, Z., Li, W., and Hao, Z.: A review of whole-process control of industrial volatile organic compounds in China, J. Environ. Sci., 123, 127–139, https://doi.org/10.1016/j.jes.2022.02.037, 2023.
Wang, R., Zhang, C., Ding, H., LV, S., Ding, Y., Wang, H., and Wang, B.: Emission characteristics of volatile organic compounds (VOCs) from the production processes of plastic parts in electronic manufacturing industry, Acta Scientiae Circumstantiae, 39, 4–12, https://doi.org/10.13671/j.hjkxxb.2018.0243, 2019 (in Chinese).
Wang, S., Yuan, B., Wu, C., Wang, C., Li, T., He, X., Huangfu, Y., Qi, J., Li, X.-B., Sha, Q., Zhu, M., Lou, S., Wang, H., Karl, T., Graus, M., Yuan, Z., and Shao, M.: Oxygenated volatile organic compounds (VOCs) as significant but varied contributors to VOC emissions from vehicles, Atmos. Chem. Phys., 22, 9703–9720, https://doi.org/10.5194/acp-22-9703-2022, 2022.
Wei, W., Wang, S., Hao, J., and Cheng, S.: Projection of anthropogenic volatile organic compounds (VOCs) emissions in China for the period 2010–2020, Atmos. Environ., 45, 6863–6871, https://doi.org/10.1016/j.atmosenv.2011.01.013, 2011.
Wu, C., Wang, C., Wang, S., Wang, W., Yuan, B., Qi, J., Wang, B., Wang, H., Wang, C., Song, W., Wang, X., Hu, W., Lou, S., Ye, C., Peng, Y., Wang, Z., Huangfu, Y., Xie, Y., Zhu, M., Zheng, J., Wang, X., Jiang, B., Zhang, Z., and Shao, M.: Measurement report: Important contributions of oxygenated compounds to emissions and chemistry of volatile organic compounds in urban air, Atmos. Chem. Phys., 20, 14769–14785, https://doi.org/10.5194/acp-20-14769-2020, 2020a.
Wu, J., Gao, S., Chen, X., Yang, Y., Fu, Q.-y., Che, X., and Jiao, Z.: Source Profiles and Impact of Volatile Organic Compounds in the Coating Manufacturing Industry, Environmental Science, 41, 1582–1588, https://doi.org/10.13227/j.hjkx.201908203, 2020b (in Chinese).
Yang, G., Huo, J., Wang, L., Wang, Y., Wu, S., Yao, L., Fu, Q., and Wang, L.: Total OH Reactivity Measurements in a Suburban Site of Shanghai, J. Geophys. Res.-Atmos., 127, e2021JD035981, https://doi.org/10.1029/2021JD035981, 2022.
Yang, Y., Shao, M., Wang, X., Nölscher, A. C., Kessel, S., Guenther, A., and Williams, J.: Towards a quantitative understanding of total OH reactivity: A review, Atmos. Environ., 134, 147–161, https://doi.org/10.1016/j.atmosenv.2016.03.010, 2016.
Yuan, B., Shao, M., Lu, S., and Wang, B.: Source profiles of volatile organic compounds associated with solvent use in Beijing, China, Atmos. Environ., 44, 1919–1926, https://doi.org/10.1016/j.atmosenv.2010.02.014, 2010.
Yuan, B., Shao, M., Gouw, J. D., Parrish, D. D., Lu, S., Wang, M., Zeng, L., Zhang, Q., Song, Y., and Zhang, J.: Volatile organic compounds (VOCs) in urban air: How chemistry affects the interpretation of positive matrix factorization (PMF) analysis, J. Geophys. Res.-Atmos., 117, D24302, https://doi.org/10.1029/2012JD018236, 2012.
Yuan, B., Koss, A. R., Warneke, C., Coggon, M., Sekimoto, K., and de Gouw, J. A.: Proton-Transfer-Reaction Mass Spectrometry: Applications in Atmospheric Sciences, Chem. Rev., 117, 13187–13229, https://doi.org/10.1021/acs.chemrev.7b00325, 2017.
Zhao, J., Yao, X., Sun, M., Xu, Y., Wang, S., Cao, D., and Liu, J.: Emission characteristics of volatile organic compounds from typical solvent use industries in Tianjin, Environmental Pollution & Control, 43, 539–545, https://doi.org/10.15985/j.cnki.1001-3865.2021.05.002, 2021 (in Chinese).
Zhao, R., Huang, L., Zhang, J., and Ouyang, F.: Emissions characteristics of volatile organic compounds (VOCs) from typical industries of solvent use in Chengdu City, Acta Scientiae Circumstantiae, 38, 1147–1154, https://doi.org/10.13671/j.hjkxxb.2017.0362, 2018a (in Chinese).
Zhao, Y., Hennigan, C. J., May, A. A., Tkacik, D. S., de Gouw, J. A., Gilman, J. B., Kuster, W. C., Borbon, A., and Robinson, A. L.: Intermediate-volatility organic compounds: a large source of secondary organic aerosol, Environ. Sci. Technol., 48, 13743–13750, https://doi.org/10.1021/es5035188, 2014.
Zhao, Y., Nguyen, N. T., Presto, A. A., Hennigan, C. J., May, A. A., and Robinson, A. L.: Intermediate Volatility Organic Compound Emissions from On-Road Gasoline Vehicles and Small Off-Road Gasoline Engines, Environ. Sci. Technol., 50, 4554–4563, https://doi.org/10.1021/acs.est.5b06247, 2016.
Zhao, Y., Lambe, A. T., Saleh, R., Saliba, G., and Robinson, A. L.: Secondary Organic Aerosol Production from Gasoline Vehicle Exhaust: Effects of Engine Technology, Cold Start, and Emission Certification Standard, Environ. Sci. Technol., 52, 1253–1261, https://doi.org/10.1021/acs.est.7b05045, 2018b.
Zheng, J., Yu, Y., Mo, Z., Zhang, Z., Wang, X., Yin, S., Peng, K., Yang, Y., Feng, X., and Cai, H.: Industrial sector-based volatile organic compound (VOC) source profiles measured in manufacturing facilities in the Pearl River Delta, China, Sci. Total Environ., 456–457, 127–136, https://doi.org/10.1016/j.scitotenv.2013.03.055, 2013.
Zhong, Z., Sha, Q., Zheng, J., Yuan, Z., Gao, Z., Ou, J., Zheng, Z., Li, C., and Huang, Z.: Sector-based VOCs emission factors and source profiles for the surface coating industry in the Pearl River Delta region of China, Sci. Total Environ., 583, 19–28, https://doi.org/10.1016/j.scitotenv.2016.12.172, 2017.
Zhong, Z., Zheng, J., Zhu, M., Huang, Z., Zhang, Z., Jia, G., Wang, X., Bian, Y., Wang, Y., and Li, N.: Recent developments of anthropogenic air pollutant emission inventories in Guangdong province, China, Sci. Total Environ., 627, 1080–1092, https://doi.org/10.1016/j.scitotenv.2018.01.268, 2018.
Zhou, Z., Deng, Y., Zhou, X., Wu, K., Tan, Q., Yin, D., Song, D., Chen, Q., and Zeng, W.: Source Profiles of Industrial Emission-Based VOCs in Chengdu, Environmental Science, 41, 3042–3055, https://doi.org/10.13227/j.hjkx.201912203, 2020a (in Chinese).
Zhou, Z., Tan, Q., Deng, Y., Song, D., Wu, K., Zhou, X., Huang, F., Zeng, W., and Lu, C.: Compilation of emission inventory and source profile database for volatile organic compounds: A case study for Sichuan, China, Atmos. Pollut. Res., 11, 105–116, https://doi.org/10.1016/j.apr.2019.09.020, 2020b.
Zhu, W., Guo, S., Zhang, Z., Wang, H., Yu, Y., Chen, Z., Shen, R., Tan, R., Song, K., Liu, K., Tang, R., Liu, Y., Lou, S., Li, Y., Zhang, W., Zhang, Z., Shuai, S., Xu, H., Li, S., Chen, Y., Hu, M., Canonaco, F., and Prévôt, A. S. H.: Mass spectral characterization of secondary organic aerosol from urban cooking and vehicular sources, Atmos. Chem. Phys., 21, 15065–15079, https://doi.org/10.5194/acp-21-15065-2021, 2021.
Short summary
Emissions of reactive organic gases from industrial volatile chemical product sources are measured. There are large differences among these industrial sources. We show that oxygenated species account for significant contributions to reactive organic gas emissions, especially for industrial sources utilizing water-borne chemicals.
Emissions of reactive organic gases from industrial volatile chemical product sources are...
Altmetrics
Final-revised paper
Preprint