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ACP | Articles | Volume 20, issue 10
Atmos. Chem. Phys., 20, 6147–6158, 2020
https://doi.org/10.5194/acp-20-6147-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
Atmos. Chem. Phys., 20, 6147–6158, 2020
https://doi.org/10.5194/acp-20-6147-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.

Research article 26 May 2020

Research article | 26 May 2020

Significant production of ClNO2 and possible source of Cl2 from N2O5 uptake at a suburban site in eastern China

Men Xia et al.

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Cited articles

Ammann, M., Cox, R. A., Crowley, J. N., Jenkin, M. E., Mellouki, A., Rossi, M. J., Troe, J., and Wallington, T. J.: Evaluated kinetic and photochemical data for atmospheric chemistry: Volume VI – heterogeneous reactions with liquid substrates, Atmos. Chem. Phys., 13, 8045–8228, https://doi.org/10.5194/acp-13-8045-2013, 2013. 
Baird, N. C. and Taylor, K. F.: The stabilizing effect of d orbitals on the central nitrogen atom in nitrogen-oxygen molecules and ions, Chem. Phys. Lett., 80, 83–86, https://doi.org/10.1016/0009-2614(81)80062-0, 1981. 
Behnke, W., George, C., Scheer, V., and Zetzsch, C.: Production and decay of ClNO2 from the reaction of gaseous N2O5 with NaCl solution: Bulk and aerosol experiments, J. Geophys. Res.-Atmos., 102, 3795–3804, 1997. 
Bertram, T. H. and Thornton, J. A.: Toward a general parameterization of N2O5 reactivity on aqueous particles: the competing effects of particle liquid water, nitrate and chloride, Atmos. Chem. Phys., 9, 8351–8363, https://doi.org/10.5194/acp-9-8351-2009, 2009. 
Custard, K. D., Pratt, K. A., Wang, S., and Shepson, P. B.: Constraints on Arctic Atmospheric Chlorine Production through Measurements and Simulations of Cl2 and ClO, Environ. Sci. Technol., 50, 12394–12400, https://doi.org/10.1021/acs.est.6b03909, 2016. 
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ClNO2 and Cl2 can be photolyzed by sunlight to produce a highly reactive Cl atom which affects air quality and climate. We observed high ClNO2 and Cl2 concentrations during a recent field study in east China. We analyzed the data and proposed a new hypothesis on the Cl2 production mechanism. Yields of ClNO2 and Cl2 from N2O2 uptake were parameterized using observational constraints, and they can be used in air quality models to improve simulations of atmospheric photochemistry and air quality.
ClNO2 and Cl2 can be photolyzed by sunlight to produce a highly reactive Cl atom which affects...
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