Articles | Volume 20, issue 10
https://doi.org/10.5194/acp-20-6115-2020
https://doi.org/10.5194/acp-20-6115-2020
Research article
 | 
26 May 2020
Research article |  | 26 May 2020

Molecular composition and photochemical evolution of water-soluble organic carbon (WSOC) extracted from field biomass burning aerosols using high-resolution mass spectrometry

Jing Cai, Xiangying Zeng, Guorui Zhi, Sasho Gligorovski, Guoying Sheng, Zhiqiang Yu, Xinming Wang, and Ping'an Peng

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Cited articles

Altieri, K. E., Seitzinger, S. P., Carlton, A. G., Turpin, B. J., Klein, G. C., and Marshall, A. G.: Oligomers formed through in-cloud methylglyoxal reactions: Chemical composition, properties, and mechanisms investigated by ultra-high resolution FT-ICR mass spectrometry, Atmos. Environ., 42, 1476–1490, 2008. 
Altieri, K. E., Turpin, B. J., and Seitzinger, S. P.: Oligomers, organosulfates, and nitrooxy organosulfates in rainwater identified by ultra-high resolution electrospray ionization FT-ICR mass spectrometry, Atmos. Chem. Phys., 9, 2533–2542, https://doi.org/10.5194/acp-9-2533-2009, 2009a. 
Altieri, K. E., Turpin, B. J., and Seitzinger, S. P.: Composition of Dissolved Organic Nitrogen in Continental Precipitation Investigated by Ultra-High Resolution FT-ICR Mass Spectrometry, Environ. Sci. Technol., 43, 6950–6955, https://doi.org/10.1021/es9007849, 2009b. 
Anastasio, C., Faust, B. C., and Rao, C. J.: Aromatic carbonyl compounds as aqueous-phase photochemical sources of hydrogen peroxide in acidic sulfate aerosols, fogs, and clouds. 1. Non-phenolic methoxybenzaldehydes and methoxyacetophenones with reductants (phenols), Environ. Sci. Technol., 31, 218–232, 1997. 
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The composition and light-induced evolution of a water-soluble organic carbon mixture from fresh biomass burning aerosols was investigated with direct infusion electrospray ionisation high-resolution mass spectrometry (HRMS) and liquid chromatography coupled with HRMS. Our findings indicate that the water-soluble organic fraction of combustion-derived aerosols has the potential to form more oxidised organic matter, contributing to the highly oxygenated nature of atmospheric organic aerosols.
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