Articles | Volume 19, issue 15
https://doi.org/10.5194/acp-19-10335-2019
https://doi.org/10.5194/acp-19-10335-2019
Research article
 | 
14 Aug 2019
Research article |  | 14 Aug 2019

Perfluorocyclobutane (PFC-318, c-C4F8) in the global atmosphere

Jens Mühle, Cathy M. Trudinger, Luke M. Western, Matthew Rigby, Martin K. Vollmer, Sunyoung Park, Alistair J. Manning, Daniel Say, Anita Ganesan, L. Paul Steele, Diane J. Ivy, Tim Arnold, Shanlan Li, Andreas Stohl, Christina M. Harth, Peter K. Salameh, Archie McCulloch, Simon O'Doherty, Mi-Kyung Park, Chun Ok Jo, Dickon Young, Kieran M. Stanley, Paul B. Krummel, Blagoj Mitrevski, Ove Hermansen, Chris Lunder, Nikolaos Evangeliou, Bo Yao, Jooil Kim, Benjamin Hmiel, Christo Buizert, Vasilii V. Petrenko, Jgor Arduini, Michela Maione, David M. Etheridge, Eleni Michalopoulou, Mike Czerniak, Jeffrey P. Severinghaus, Stefan Reimann, Peter G. Simmonds, Paul J. Fraser, Ronald G. Prinn, and Ray F. Weiss

Related authors

Global Emissions and Abundances of Chemically and Radiatively Important Trace Gases from the AGAGE Network
Luke M. Western, Matthew Rigby, Jens Mühle, Paul B. Krummel, Chris R. Lunder, Simon O'Doherty, Stefan Reimann, Martin K. Vollmer, Dickon Young, Ben Adam, Paul J. Fraser, Anita L. Ganesan, Christina M. Harth, Ove Hermansen, Jooil Kim, Ray L. Langenfelds, Zoë M. Loh, Blagoj Mitrevski, Joseph R. Pitt, Peter K. Salameh, Roland Schmidt, Kieran Stanley, Ann R. Stavert, Hsiang-Jui Wang, Ray F. Weiss, and Ronald G. Prinn
Earth Syst. Sci. Data Discuss., https://doi.org/10.5194/essd-2025-348,https://doi.org/10.5194/essd-2025-348, 2025
Preprint under review for ESSD
Short summary
Indicators of Global Climate Change 2024: annual update of key indicators of the state of the climate system and human influence
Piers M. Forster, Chris Smith, Tristram Walsh, William F. Lamb, Robin Lamboll, Christophe Cassou, Mathias Hauser, Zeke Hausfather, June-Yi Lee, Matthew D. Palmer, Karina von Schuckmann, Aimée B. A. Slangen, Sophie Szopa, Blair Trewin, Jeongeun Yun, Nathan P. Gillett, Stuart Jenkins, H. Damon Matthews, Krishnan Raghavan, Aurélien Ribes, Joeri Rogelj, Debbie Rosen, Xuebin Zhang, Myles Allen, Lara Aleluia Reis, Robbie M. Andrew, Richard A. Betts, Alex Borger, Jiddu A. Broersma, Samantha N. Burgess, Lijing Cheng, Pierre Friedlingstein, Catia M. Domingues, Marco Gambarini, Thomas Gasser, Johannes Gütschow, Masayoshi Ishii, Christopher Kadow, John Kennedy, Rachel E. Killick, Paul B. Krummel, Aurélien Liné, Didier P. Monselesan, Colin Morice, Jens Mühle, Vaishali Naik, Glen P. Peters, Anna Pirani, Julia Pongratz, Jan C. Minx, Matthew Rigby, Robert Rohde, Abhishek Savita, Sonia I. Seneviratne, Peter Thorne, Christopher Wells, Luke M. Western, Guido R. van der Werf, Susan E. Wijffels, Valérie Masson-Delmotte, and Panmao Zhai
Earth Syst. Sci. Data, 17, 2641–2680, https://doi.org/10.5194/essd-17-2641-2025,https://doi.org/10.5194/essd-17-2641-2025, 2025
Short summary
Global Methane Budget 2000–2020
Marielle Saunois, Adrien Martinez, Benjamin Poulter, Zhen Zhang, Peter A. Raymond, Pierre Regnier, Josep G. Canadell, Robert B. Jackson, Prabir K. Patra, Philippe Bousquet, Philippe Ciais, Edward J. Dlugokencky, Xin Lan, George H. Allen, David Bastviken, David J. Beerling, Dmitry A. Belikov, Donald R. Blake, Simona Castaldi, Monica Crippa, Bridget R. Deemer, Fraser Dennison, Giuseppe Etiope, Nicola Gedney, Lena Höglund-Isaksson, Meredith A. Holgerson, Peter O. Hopcroft, Gustaf Hugelius, Akihiko Ito, Atul K. Jain, Rajesh Janardanan, Matthew S. Johnson, Thomas Kleinen, Paul B. Krummel, Ronny Lauerwald, Tingting Li, Xiangyu Liu, Kyle C. McDonald, Joe R. Melton, Jens Mühle, Jurek Müller, Fabiola Murguia-Flores, Yosuke Niwa, Sergio Noce, Shufen Pan, Robert J. Parker, Changhui Peng, Michel Ramonet, William J. Riley, Gerard Rocher-Ros, Judith A. Rosentreter, Motoki Sasakawa, Arjo Segers, Steven J. Smith, Emily H. Stanley, Joël Thanwerdas, Hanqin Tian, Aki Tsuruta, Francesco N. Tubiello, Thomas S. Weber, Guido R. van der Werf, Douglas E. J. Worthy, Yi Xi, Yukio Yoshida, Wenxin Zhang, Bo Zheng, Qing Zhu, Qiuan Zhu, and Qianlai Zhuang
Earth Syst. Sci. Data, 17, 1873–1958, https://doi.org/10.5194/essd-17-1873-2025,https://doi.org/10.5194/essd-17-1873-2025, 2025
Short summary
A global re-analysis of regionally resolved emissions and atmospheric mole fractions of SF6 for the period 2005–2021
Martin Vojta, Andreas Plach, Saurabh Annadate, Sunyoung Park, Gawon Lee, Pallav Purohit, Florian Lindl, Xin Lan, Jens Mühle, Rona L. Thompson, and Andreas Stohl
Atmos. Chem. Phys., 24, 12465–12493, https://doi.org/10.5194/acp-24-12465-2024,https://doi.org/10.5194/acp-24-12465-2024, 2024
Short summary
Revealing the significant acceleration of hydrofluorocarbon (HFC) emissions in eastern Asia through long-term atmospheric observations
Haklim Choi, Alison L. Redington, Hyeri Park, Jooil Kim, Rona L. Thompson, Jens Mühle, Peter K. Salameh, Christina M. Harth, Ray F. Weiss, Alistair J. Manning, and Sunyoung Park
Atmos. Chem. Phys., 24, 7309–7330, https://doi.org/10.5194/acp-24-7309-2024,https://doi.org/10.5194/acp-24-7309-2024, 2024
Short summary

Related subject area

Subject: Gases | Research Activity: Field Measurements | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
Volatile organic compound sources and impacts in an urban Mediterranean area (Marseille, France)
Marvin Dufresne, Thérèse Salameh, Thierry Leonardis, Grégory Gille, Alexandre Armengaud, and Stéphane Sauvage
Atmos. Chem. Phys., 25, 5977–5999, https://doi.org/10.5194/acp-25-5977-2025,https://doi.org/10.5194/acp-25-5977-2025, 2025
Short summary
Short-lived organic nitrates in a suburban temperate forest: an indication of efficient assimilation of reactive nitrogen by the biosphere?
Simone T. Andersen, Rolf Sander, Patrick Dewald, Laura Wüst, Tobias Seubert, Gunther N. T. E. Türk, Jan Schuladen, Max R. McGillen, Chaoyang Xue, Abdelwahid Mellouki, Alexandre Kukui, Vincent Michoud, Manuela Cirtog, Mathieu Cazaunau, Astrid Bauville, Hichem Bouzidi, Paola Formenti, Cyrielle Denjean, Jean-Claude Etienne, Olivier Garrouste, Christopher Cantrell, Jos Lelieveld, and John N. Crowley
Atmos. Chem. Phys., 25, 5893–5909, https://doi.org/10.5194/acp-25-5893-2025,https://doi.org/10.5194/acp-25-5893-2025, 2025
Short summary
Spatiotemporal variations in atmospheric CH4 concentrations and enhancements in northern China based on a comprehensive dataset: ground-based observations, TROPOMI data, inventory data, and inversions
Pengfei Han, Ning Zeng, Bo Yao, Wen Zhang, Weijun Quan, Pucai Wang, Ting Wang, Minqiang Zhou, Qixiang Cai, Yuzhong Zhang, Ruosi Liang, Wanqi Sun, and Shengxiang Liu
Atmos. Chem. Phys., 25, 4965–4988, https://doi.org/10.5194/acp-25-4965-2025,https://doi.org/10.5194/acp-25-4965-2025, 2025
Short summary
Marine emissions and trade winds control the atmospheric nitrous oxide in the Galapagos Islands
Timur Cinay, Dickon Young, Nazaret Narváez Jimenez, Cristina Vintimilla-Palacios, Ariel Pila Alonso, Paul B. Krummel, William Vizuete, and Andrew R. Babbin
Atmos. Chem. Phys., 25, 4703–4718, https://doi.org/10.5194/acp-25-4703-2025,https://doi.org/10.5194/acp-25-4703-2025, 2025
Short summary
Measurement report: A complex street-level air quality observation campaign in a heavy-traffic area utilizing the multivariate adaptive regression splines method for field calibration of low-cost sensors
Petra Bauerová, Josef Keder, Adriana Šindelářová, Ondřej Vlček, William Patiño, Pavel Krč, Jan Geletič, Hynek Řezníček, Martin Bureš, Kryštof Eben, Michal Belda, Jelena Radović, Vladimír Fuka, Radek Jareš, Igor Esau, and Jaroslav Resler
Atmos. Chem. Phys., 25, 4477–4504, https://doi.org/10.5194/acp-25-4477-2025,https://doi.org/10.5194/acp-25-4477-2025, 2025
Short summary

Cited articles

Acerboni, G., Beukes, J. A., Jensen, N. R., Hjorth, J., Myhre, G., Nielsen, C. J., and Sundet, J. K.: Atmospheric degradation and global warming potentials of three perfluoroalkenes, Atmos. Environ., 35, 4113–4123, https://doi.org/10.1016/S1352-2310(01)00209-6, 2001. 
Adolph, A. C. and Albert, M. R.: Gas diffusivity and permeability through the firn column at Summit, Greenland: measurements and comparison to microstructural properties, The Cryosphere, 8, 319–328, https://doi.org/10.5194/tc-8-319-2014, 2014. 
Arnold, T., Mühle, J., Salameh, P. K., Harth, C. M., Ivy, D. J., and Weiss, R. F.: Automated measurement of nitrogen trifluoride in ambient air, Anal. Chem., 84, 4798–4804, https://doi.org/10.1021/ac300373e, 2012. 
Arnold, T., Manning, A. J., Kim, J., Li, S., Webster, H., Thomson, D., Mühle, J., Weiss, R. F., Park, S., and O'Doherty, S.: Inverse modelling of CF4 and NF3 emissions in East Asia, Atmos. Chem. Phys., 18, 13305–13320, https://doi.org/10.5194/acp-18-13305-2018, 2018. 
Aydin, M., Saltzman, E. S., De Bruyn, W. J., Montzka, S. A., Butler, J. H., and Battle, M.: Atmospheric variability of methyl chloride during the last 300 years from an Antarctic ice core and firn air, Geophys. Res. Lett., 31, L02109, https://doi.org/10.1029/2003GL018750, 2004. 
Download
Short summary
We discuss atmospheric concentrations and emissions of the strong greenhouse gas perfluorocyclobutane. A large fraction of recent emissions stem from China, India, and Russia, probably as a by-product from the production of fluoropolymers and fluorochemicals. Most historic emissions likely stem from developed countries. Total emissions are higher than what is being reported. Clearly, more measurements and better reporting are needed to understand emissions of this and other greenhouse gases.
Share
Altmetrics
Final-revised paper
Preprint