Articles | Volume 22, issue 21
https://doi.org/10.5194/acp-22-14377-2022
https://doi.org/10.5194/acp-22-14377-2022
Research article
 | 
09 Nov 2022
Research article |  | 09 Nov 2022

Ammonium adduct chemical ionization to investigate anthropogenic oxygenated gas-phase organic compounds in urban air

Peeyush Khare, Jordan E. Krechmer, Jo E. Machesky, Tori Hass-Mitchell, Cong Cao, Junqi Wang, Francesca Majluf, Felipe Lopez-Hilfiker, Sonja Malek, Will Wang, Karl Seltzer, Havala O. T. Pye, Roisin Commane, Brian C. McDonald, Ricardo Toledo-Crow, John E. Mak, and Drew R. Gentner

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Subject: Gases | Research Activity: Field Measurements | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
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Cited articles

Abbatt, J. P. D. and Wang, C.: The atmospheric chemistry of indoor environments, Environ. Sci. Process. Impacts, 22, 25–48, https://doi.org/10.1039/C9EM00386J, 2020. 
Asaf, D., Tas, E., Pedersen, D., Peleg, M., and Luria, M.: Long-Term Measurements of NO3 Radical at a Semiarid Urban Site: 2. Seasonal Trends and Loss Mechanisms, Environ. Sci. Technol., 44, 5901–5907, https://doi.org/10.1021/es100967z, 2010. 
Aschmann, S. M., Martin, P., Tuazon, E. C., Arey, J., and Atkinson, R.: Kinetic and product studies of the reactions of selected glycol ethers with OH radicals, Environ. Sci. Technol., 35, 4080–4088, https://doi.org/10.1021/es010831k, 2001. 
Bennet, F., Hart-Smith, G., Gruendling, T., Davis, T. P., Barker, P. J., and Barner-Kowollik, C.: Degradation of poly(methyl methacrylate) model compounds under extreme environmental conditions, Macromol. Chem. Phys., 211, 1083–1097, 2010. 
Bi, C., Liang, Y., and Xu, Y.: Fate and Transport of Phthalates in Indoor Environments and the Influence of Temperature: A Case Study in a Test House, Environ. Sci. Technol., 49, 9674–9681, https://doi.org/10.1021/acs.est.5b02787, 2015. 
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Ammonium adduct chemical ionization is used to examine the atmospheric abundances of oxygenated volatile organic compounds associated with emissions from volatile chemical products, which are now key contributors of reactive precursors to ozone and secondary organic aerosols in urban areas. The application of this valuable measurement approach in densely populated New York City enables the evaluation of emissions inventories and thus the role these oxygenated compounds play in urban air quality.
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