Articles | Volume 21, issue 23
https://doi.org/10.5194/acp-21-17995-2021
https://doi.org/10.5194/acp-21-17995-2021
Measurement report
 | 
09 Dec 2021
Measurement report |  | 09 Dec 2021

Measurement report: Fast photochemical production of peroxyacetyl nitrate (PAN) over the rural North China Plain during haze events in autumn

Yulu Qiu, Zhiqiang Ma, Ke Li, Mengyu Huang, Jiujiang Sheng, Ping Tian, Jia Zhu, Weiwei Pu, Yingxiao Tang, Tingting Han, Huaigang Zhou, and Hong Liao

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Cited articles

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Chen, Y., Ma, Q., Lin, W., Xu, X., Yao, J., and Gao, W.: Measurement report: Long-term variations in carbon monoxide at a background station in China's Yangtze River Delta region, Atmos. Chem. Phys., 20, 15969–15982, https://doi.org/10.5194/acp-20-15969-2020, 2020. 
Dang, R., Liao, H., and Fu, Y.: Quantifying the anthropogenic and meteorological influences on summertime surface ozone in China over 2012–2017, Sci. Total Environ., 754, 142394, https://doi.org/10.1016/j.scitotenv.2020.142394, 2021. 
Duan, J., Guo, S., Tan, J., Wang, S., and Chai, F.: Characteristics of atmospheric carbonyls during haze days in Beijing, China, Atmos. Res., 114–115, 17–27, https://doi.org/10.1016/j.atmosres.2012.05.010, 2012. 
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Photochemical pollution over the North China Plain (NCP) is attracting much concern. Our observations at a rural site in the NCP identified high peroxyacetyl nitrate (PAN) concentrations, even on cold days. Increased acetaldehyde concentration and hydroxyl radical production rates drive fast PAN formation. Moreover, our study emphasizes the importance of formaldehyde photolysis in PAN formation and calls for implementing strict volatile organic compound controls after summer over the NCP.
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