Articles | Volume 21, issue 23
https://doi.org/10.5194/acp-21-17995-2021
https://doi.org/10.5194/acp-21-17995-2021
Measurement report
 | 
09 Dec 2021
Measurement report |  | 09 Dec 2021

Measurement report: Fast photochemical production of peroxyacetyl nitrate (PAN) over the rural North China Plain during haze events in autumn

Yulu Qiu, Zhiqiang Ma, Ke Li, Mengyu Huang, Jiujiang Sheng, Ping Tian, Jia Zhu, Weiwei Pu, Yingxiao Tang, Tingting Han, Huaigang Zhou, and Hong Liao

Data sets

Replication Data for: Measurement report: Fast photochemical production of peroxyacetyl nitrate (PAN) over the rural North China Plain during haze events in autumn Yulu Qiu and Zhiqiang Ma https://doi.org/10.7910/DVN/EPAGNB

ERA5 hourly data on single levels from 1979 to present H. Hersbach, B. Bell, P. Berrisford, G. Biavati, A. Horányi, J. Muñoz Sabater, J. Nicolas, C. Peubey, R. Radu, I. Rozum, D. Schepers, A. Simmons, C. Soci, D. Dee, and J.-N. Thépaut https://doi.org/10.24381/cds.adbb2d47

ERA5 hourly data on pressure levels from 1979 to present H. Hersbach, B. Bell, P. Berrisford, G. Biavati, A. Horányi, J. Muñoz Sabater, J. Nicolas, C. Peubey, R. Radu, I. Rozum, D. Schepers, A. Simmons, C. Soci, D. Dee, and J.-N. Thépaut https://doi.org/10.24381/cds.bd0915c6

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Short summary
Photochemical pollution over the North China Plain (NCP) is attracting much concern. Our observations at a rural site in the NCP identified high peroxyacetyl nitrate (PAN) concentrations, even on cold days. Increased acetaldehyde concentration and hydroxyl radical production rates drive fast PAN formation. Moreover, our study emphasizes the importance of formaldehyde photolysis in PAN formation and calls for implementing strict volatile organic compound controls after summer over the NCP.
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