Journal cover Journal topic
Atmospheric Chemistry and Physics An interactive open-access journal of the European Geosciences Union
Journal topic

Journal metrics

Journal metrics

  • IF value: 5.414 IF 5.414
  • IF 5-year value: 5.958 IF 5-year
    5.958
  • CiteScore value: 9.7 CiteScore
    9.7
  • SNIP value: 1.517 SNIP 1.517
  • IPP value: 5.61 IPP 5.61
  • SJR value: 2.601 SJR 2.601
  • Scimago H <br class='hide-on-tablet hide-on-mobile'>index value: 191 Scimago H
    index 191
  • h5-index value: 89 h5-index 89
ACP | Articles | Volume 19, issue 1
Atmos. Chem. Phys., 19, 349–362, 2019
https://doi.org/10.5194/acp-19-349-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
Atmos. Chem. Phys., 19, 349–362, 2019
https://doi.org/10.5194/acp-19-349-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.

Research article 10 Jan 2019

Research article | 10 Jan 2019

ROOOH: a missing piece of the puzzle for OH measurements in low-NO environments?

Christa Fittschen et al.

Related authors

Kinetics of dimethyl sulfide (DMS) reactions with isoprene-derived Criegee intermediates studied with direct UV absorption
Mei-Tsan Kuo, Isabelle Weber, Christa Fittschen, Luc Vereecken, and Jim Jr-Min Lin
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2020-484,https://doi.org/10.5194/acp-2020-484, 2020
Preprint under review for ACP
Short summary
Kinetics of dimethyl sulfide (DMS) reactions with isoprene-derived Criegee intermediates studied with direct UV absorption
Mei-Tsan Kuo, Isabelle Weber, Christa Fittschen, and Jim Jr-Min Lin
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2020-326,https://doi.org/10.5194/acp-2020-326, 2020
Preprint withdrawn
Short summary
Comparison of OH reactivity measurements in the atmospheric simulation chamber SAPHIR
Hendrik Fuchs, Anna Novelli, Michael Rolletter, Andreas Hofzumahaus, Eva Y. Pfannerstill, Stephan Kessel, Achim Edtbauer, Jonathan Williams, Vincent Michoud, Sebastien Dusanter, Nadine Locoge, Nora Zannoni, Valerie Gros, Francois Truong, Roland Sarda-Esteve, Danny R. Cryer, Charlotte A. Brumby, Lisa K. Whalley, Daniel Stone, Paul W. Seakins, Dwayne E. Heard, Coralie Schoemaecker, Marion Blocquet, Sebastien Coudert, Sebastien Batut, Christa Fittschen, Alexander B. Thames, William H. Brune, Cheryl Ernest, Hartwig Harder, Jennifer B. A. Muller, Thomas Elste, Dagmar Kubistin, Stefanie Andres, Birger Bohn, Thorsten Hohaus, Frank Holland, Xin Li, Franz Rohrer, Astrid Kiendler-Scharr, Ralf Tillmann, Robert Wegener, Zhujun Yu, Qi Zou, and Andreas Wahner
Atmos. Meas. Tech., 10, 4023–4053, https://doi.org/10.5194/amt-10-4023-2017,https://doi.org/10.5194/amt-10-4023-2017, 2017
Short summary
Intercomparison of the comparative reactivity method (CRM) and pump–probe technique for measuring total OH reactivity in an urban environment
R. F. Hansen, M. Blocquet, C. Schoemaecker, T. Léonardis, N. Locoge, C. Fittschen, B. Hanoune, P. S. Stevens, V. Sinha, and S. Dusanter
Atmos. Meas. Tech., 8, 4243–4264, https://doi.org/10.5194/amt-8-4243-2015,https://doi.org/10.5194/amt-8-4243-2015, 2015
Short summary

Related subject area

Subject: Gases | Research Activity: Laboratory Studies | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
Atmospheric fate of two relevant unsaturated ketoethers: kinetics, products and mechanisms for the reaction of hydroxyl radicals with (E)-4-methoxy-3-buten-2-one and (1E)-1-methoxy-2-methyl-1-penten-3-one
Rodrigo Gastón Gibilisco, Ian Barnes, Iustinian Gabriel Bejan, and Peter Wiesen
Atmos. Chem. Phys., 20, 8939–8951, https://doi.org/10.5194/acp-20-8939-2020,https://doi.org/10.5194/acp-20-8939-2020, 2020
Short summary
The nitrogen budget of laboratory-simulated western US wildfires during the FIREX 2016 Fire Lab study
James M. Roberts, Chelsea E. Stockwell, Robert J. Yokelson, Joost de Gouw, Yong Liu, Vanessa Selimovic, Abigail R. Koss, Kanako Sekimoto, Matthew M. Coggon, Bin Yuan, Kyle J. Zarzana, Steven S. Brown, Cristina Santin, Stefan H. Doerr, and Carsten Warneke
Atmos. Chem. Phys., 20, 8807–8826, https://doi.org/10.5194/acp-20-8807-2020,https://doi.org/10.5194/acp-20-8807-2020, 2020
Short summary
Determination of the absorption cross-sections of higher order iodine oxides at 355 nm and 532 nm
Thomas R. Lewis, Juan Carlos Gómez Martin, Mark A. Blitz, Carlos A. Cuevas, John M. C. Plane, and Alfonso Saiz-Lopez
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2020-456,https://doi.org/10.5194/acp-2020-456, 2020
Revised manuscript accepted for ACP
Short summary
Evolution of NO3 reactivity during the oxidation of isoprene
Patrick Dewald, Jonathan M. Liebmann, Nils Friedrich, Justin Shenolikar, Jan Schuladen, Franz Rohrer, David Reimer, Ralf Tillmann, Anna Novelli, Changmin Cho, Kangming Xu, Rupert Holzinger, François Bernard, Li Zhou, Wahid Mellouki, Steven S. Brown, Hendrik Fuchs, Jos Lelieveld, and John N. Crowley
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2020-360,https://doi.org/10.5194/acp-2020-360, 2020
Revised manuscript accepted for ACP
Short summary
Rate coefficients for reactions of OH with aromatic and aliphatic volatile organic compounds determined by the Multivariate Relative Rate Technique
Jacob T. Shaw, Andrew R. Rickard, Mike J. Newland, and Terry J. Dillon
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2020-281,https://doi.org/10.5194/acp-2020-281, 2020
Revised manuscript accepted for ACP
Short summary

Cited articles

Archibald, A. T., Petit, A. S., Percival, C. J., Harvey, J. N., and Shallcross, D. E.: On the Importance of the Reaction between OH and RO2 Radicals, Atmos. Sci. Lett., 10, 102–108, 2009. 
Archibald, A. T., Cooke, M. C., Utembe, S. R., Shallcross, D. E., Derwent, R. G., and Jenkin, M. E.: Impacts of mechanistic changes on HOx formation and recycling in the oxidation of isoprene, Atmos. Chem. Phys., 10, 8097–8118, https://doi.org/10.5194/acp-10-8097-2010, 2010. 
Assaf, E., Song, B., Tomas, A., Schoemaecker, C., and Fittschen, C.: Rate Constant of the Reaction between CH3O2 Radicals and OH Radicals revisited, J. Phys. Chem. A, 120, 8923–8932, https://doi.org/10.1021/acs.jpca.6b07704, 2016. 
Assaf, E., Sheps, L., Whalley, L., Heard, D., Tomas, A., Schoemaecker, C., and Fittschen, C.: The Reaction between CH3O2 and OH Radicals: Product Yields and Atmospheric Implications, Environ. Sci. Technol., 51, 2170–2177, https://doi.org/10.1021/acs.est.6b06265, 2017a. 
Publications Copernicus
Download
Short summary
Concentrations of OH, the main oxidant in the atmosphere, were measured in biogenic environments up to a factor of 10 higher than predicted by models. This was interpreted as a major lack in our understanding of biogenic volatile organic compound chemistry. But interferences of unknown origin have also been discovered, and we present experimental and modelling evidence that the interference might be due to the unexpected decomposition of a new class of molecule, ROOOH, in the FAGE instruments.
Concentrations of OH, the main oxidant in the atmosphere, were measured in biogenic environments...
Citation
Final-revised paper
Preprint