Articles | Volume 17, issue 5
https://doi.org/10.5194/acp-17-3401-2017
https://doi.org/10.5194/acp-17-3401-2017
Research article
 | 
09 Mar 2017
Research article |  | 09 Mar 2017

Bromine atom production and chain propagation during springtime Arctic ozone depletion events in Barrow, Alaska

Chelsea R. Thompson, Paul B. Shepson, Jin Liao, L. Greg Huey, Chris Cantrell, Frank Flocke, and John Orlando

Related authors

A new production-based model for estimating emissions and banks of ODSs: Application to HCFC-141b
Helen Walter-Terrinoni, John S. Daniel, Chelsea R. Thompson, and Luke M. Western
EGUsphere, https://doi.org/10.5194/egusphere-2025-297,https://doi.org/10.5194/egusphere-2025-297, 2025
Short summary
Observational ozone data over the global oceans and polar regions: The TOAR-II Oceans data set version 2024
Yugo Kanaya, Roberto Sommariva, Alfonso Saiz-Lopez, Andrea Mazzeo, Theodore K. Koenig, Kaori Kawana, James E. Johnson, Aurélie Colomb, Pierre Tulet, Suzie Molloy, Ian E. Galbally, Rainer Volkamer, Anoop Mahajan, John W. Halfacre, Paul B. Shepson, Julia Schmale, Hélène Angot, Byron Blomquist, Matthew D. Shupe, Detlev Helmig, Junsu Gil, Meehye Lee, Sean C. Coburn, Ivan Ortega, Gao Chen, James Lee, Kenneth C. Aikin, David D. Parrish, John S. Holloway, Thomas B. Ryerson, Ilana B. Pollack, Eric J. Williams, Brian M. Lerner, Andrew J. Weinheimer, Teresa Campos, Frank M. Flocke, J. Ryan Spackman, Ilann Bourgeois, Jeff Peischl, Chelsea R. Thompson, Ralf M. Staebler, Amir A. Aliabadi, Wanmin Gong, Roeland Van Malderen, Anne M. Thompson, Ryan M. Stauffer, Debra E. Kollonige, Juan Carlos Gómez Martin, Masatomo Fujiwara, Katie Read, Matthew Rowlinson, Keiichi Sato, Junichi Kurokawa, Yoko Iwamoto, Fumikazu Taketani, Hisahiro Takashima, Monica Navarro Comas, Marios Panagi, and Martin G. Schultz
Earth Syst. Sci. Data Discuss., https://doi.org/10.5194/essd-2024-566,https://doi.org/10.5194/essd-2024-566, 2025
Revised manuscript accepted for ESSD
Short summary
Widespread trace bromine and iodine in remote tropospheric non-sea-salt aerosols
Gregory P. Schill, Karl D. Froyd, Daniel M. Murphy, Christina J. Williamson, Charles A. Brock, Tomás Sherwen, Mat J. Evans, Eric A. Ray, Eric C. Apel, Rebecca S. Hornbrook, Alan J. Hills, Jeff Peischl, Thomas B. Ryerson, Chelsea R. Thompson, Ilann Bourgeois, Donald R. Blake, Joshua P. DiGangi, and Glenn S. Diskin
Atmos. Chem. Phys., 25, 45–71, https://doi.org/10.5194/acp-25-45-2025,https://doi.org/10.5194/acp-25-45-2025, 2025
Short summary
Natural and anthropogenic influence on tropospheric ozone variability over the Tropical Atlantic unveiled by satellite and in situ observations
Sachiko Okamoto, Juan Cuesta, Gaëlle Dufour, Maxmim Eremenko, Kazuyuki Miyazaki, Cathy Boonne, Hiroshi Tanimoto, Jeff Peischl, and Chelsea Thompson
EGUsphere, https://doi.org/10.5194/egusphere-2024-3758,https://doi.org/10.5194/egusphere-2024-3758, 2024
Short summary
Tropical tropospheric ozone distribution and trends from in situ and satellite data
Audrey Gaudel, Ilann Bourgeois, Meng Li, Kai-Lan Chang, Jerald Ziemke, Bastien Sauvage, Ryan M. Stauffer, Anne M. Thompson, Debra E. Kollonige, Nadia Smith, Daan Hubert, Arno Keppens, Juan Cuesta, Klaus-Peter Heue, Pepijn Veefkind, Kenneth Aikin, Jeff Peischl, Chelsea R. Thompson, Thomas B. Ryerson, Gregory J. Frost, Brian C. McDonald, and Owen R. Cooper
Atmos. Chem. Phys., 24, 9975–10000, https://doi.org/10.5194/acp-24-9975-2024,https://doi.org/10.5194/acp-24-9975-2024, 2024
Short summary

Related subject area

Subject: Gases | Research Activity: Atmospheric Modelling and Data Analysis | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
Constraining the budget of NOx and volatile organic compounds at a remote tropical island using multi-platform observations and WRF-Chem model simulations
Catalina Poraicu, Jean-François Müller, Trissevgeni Stavrakou, Crist Amelynck, Bert W. D. Verreyken, Niels Schoon, Corinne Vigouroux, Nicolas Kumps, Jérôme Brioude, Pierre Tulet, and Camille Mouchel-Vallon
Atmos. Chem. Phys., 25, 6903–6941, https://doi.org/10.5194/acp-25-6903-2025,https://doi.org/10.5194/acp-25-6903-2025, 2025
Short summary
Multi-observational estimation of regional and sectoral emission contributions to the persistent high growth rate of atmospheric CH4 for 2020–2022
Yosuke Niwa, Yasunori Tohjima, Yukio Terao, Tazu Saeki, Akihiko Ito, Taku Umezawa, Kyohei Yamada, Motoki Sasakawa, Toshinobu Machida, Shin-Ichiro Nakaoka, Hideki Nara, Hiroshi Tanimoto, Hitoshi Mukai, Yukio Yoshida, Shinji Morimoto, Shinya Takatsuji, Kazuhiro Tsuboi, Yousuke Sawa, Hidekazu Matsueda, Kentaro Ishijima, Ryo Fujita, Daisuke Goto, Xin Lan, Kenneth Schuldt, Michal Heliasz, Tobias Biermann, Lukasz Chmura, Jarsolaw Necki, Irène Xueref-Remy, and Damiano Sferlazzo
Atmos. Chem. Phys., 25, 6757–6785, https://doi.org/10.5194/acp-25-6757-2025,https://doi.org/10.5194/acp-25-6757-2025, 2025
Short summary
Representing improved tropospheric ozone distribution over the Northern Hemisphere by including lightning NOx emissions in CHIMERE
Sanhita Ghosh, Arineh Cholakian, Sylvain Mailler, and Laurent Menut
Atmos. Chem. Phys., 25, 6273–6297, https://doi.org/10.5194/acp-25-6273-2025,https://doi.org/10.5194/acp-25-6273-2025, 2025
Short summary
Assessing the ability to quantify the decrease in NOx anthropogenic emissions in 2019 compared to 2005 using OMI and TROPOMI satellite observations
Audrey Fortems-Cheiney, Grégoire Broquet, Elise Potier, Antoine Berchet, Isabelle Pison, Adrien Martinez, Robin Plauchu, Rimal Abeed, Aurélien Sicsik-Paré, Gaelle Dufour, Adriana Coman, Dilek Savas, Guillaume Siour, Henk Eskes, Hugo A. C. Denier van der Gon, and Stijn N. C. Dellaert
Atmos. Chem. Phys., 25, 6047–6068, https://doi.org/10.5194/acp-25-6047-2025,https://doi.org/10.5194/acp-25-6047-2025, 2025
Short summary
Tracking daily NOx emissions from an urban agglomeration based on TROPOMI NO2 and a local ensemble transform Kalman filter
Yawen Kong, Bo Zheng, and Yuxi Liu
Atmos. Chem. Phys., 25, 5959–5976, https://doi.org/10.5194/acp-25-5959-2025,https://doi.org/10.5194/acp-25-5959-2025, 2025
Short summary

Cited articles

Abbatt, J., Oldridge, N., Symington, A., Chukalovskiy, V., McWhinney, R. D., Sjostedt, S., and Cox, R. A.: Release of Gas-Phase Halogens by Photolytic Generation of OH in Frozen Halide–Nitrate Solutions: An Active Halogen Formation Mechanism?, J. Phys. Chem. A, 114, 6527–6533, https://doi.org/10.1021/jp102072t, 2010.
Abbatt, J. P. D., Thomas, J. L., Abrahamsson, K., Boxe, C., Granfors, A., Jones, A. E., King, M. D., Saiz-Lopez, A., Shepson, P. B., Sodeau, J., Toohey, D. W., Toubin, C., von Glasow, R., Wren, S. N., and Yang, X.: Halogen activation via interactions with environmental ice and snow in the polar lower troposphere and other regions, Atmos. Chem. Phys., 12, 6237–6271, https://doi.org/10.5194/acp-12-6237-2012, 2012.
Adams, J. W., Holmes, N. S., and Crowley, J. N.: Uptake and reaction of HOBr on frozen and dry NaCl/NaBr surfaces between 253 and 233 K, Atmos. Chem. Phys., 2, 79–91, https://doi.org/10.5194/acp-2-79-2002, 2002.
Apel, E., Emmons, L., Karl, T., Flocke, F., Hills, A., Madronich, S., Lee-Taylor, J., Fried, A., Weibring, P., and Walega, J.: Chemical evolution of volatile organic compounds in the outflow of the Mexico City metropolitan area, Atmos. Chem. Phys., 10, 2353–2375, https://doi.org/10.5194/acp-10-2353-2010, 2010.
Aranda, A., Le Bras, G., La Verdet, G., and Poulet, G.: The BrO+ CH3O2 reaction: Kinetics and role in the atmospheric ozone budget, Geophys. Res. Lett., 24, 2745–2748, https://doi.org/10.1029/97GJ02686, 1997.
Download
Short summary
The generally accepted mechanism leading to ozone depletion events in the Arctic assumes efficient gas-phase recycling of bromine atoms, such that the rate of ozone depletion has often been estimated as the rate that Br atoms regenerate through gas-phase BrO + BrO and BrO + ClO reactions. Using a large suite of data from the OASIS2009 campaign, our modeling results show that the gas-phase regeneration of Br is less efficient than expected and that heterogeneous recycling on surfaces is critical.
Share
Altmetrics
Final-revised paper
Preprint