Articles | Volume 21, issue 10
https://doi.org/10.5194/acp-21-7917-2021
https://doi.org/10.5194/acp-21-7917-2021
Measurement report
 | 
25 May 2021
Measurement report |  | 25 May 2021

Measurement report: Online measurement of gas-phase nitrated phenols utilizing a CI-LToF-MS: primary sources and secondary formation

Kai Song, Song Guo, Haichao Wang, Ying Yu, Hui Wang, Rongzhi Tang, Shiyong Xia, Yuanzheng Gong, Zichao Wan, Daqi Lv, Rui Tan, Wenfei Zhu, Ruizhe Shen, Xin Li, Xuena Yu, Shiyi Chen, Liming Zeng, and Xiaofeng Huang

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Cited articles

Bean, J. K. and Hildebrandt Ruiz, L.: Gas–particle partitioning and hydrolysis of organic nitrates formed from the oxidation of α-pinene in environmental chamber experiments, Atmos. Chem. Phys., 16, 2175–2184, https://doi.org/10.5194/acp-16-2175-2016, 2016. 
Belloli, R., Barletta, B., Bolzacchini, E., Meinardi, S., Orlandi, M., and Rindone, B.: Determination of toxic nitrophenols in the atmosphere by high-performance liquid chromatography, J. Chromatogr. A, 846, 277–281, https://doi.org/10.1016/S0021-9673(99)00030-8, 1999. 
Berndt, T. and Böge, O.: Gas-phase reaction of OH radicals with phenol, Phys. Chem. Chem. Phys., 5, 342–350, https://doi.org/10.1039/b208187c, 2003. 
Brunet, J. P., Tamayo, P., Golub, T. R., and Mesirov, J. P.: Metagenes and molecular pattern discovery using matrix factorization, P. Natl. Acad. Sci. USA, 101, 4164–4169, https://doi.org/10.1073/pnas.0308531101, 2004. 
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Short summary
Nitrated phenols (NPs) are crucial components of brown carbon. To comprehend the constitutes and sources of NPs in winter of Beijing, their concentrations were measured by a CI-LToF-MS. The secondary formation process was simulated by a box model. NPs were mainly influenced by primary emissions and regional transport. Primary emitted phenol rather than benzene oxidation was crucial in the heavy pollution episode in Beijing. This provides more insight into pollution control strategies of NPs.
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