Articles | Volume 21, issue 10
https://doi.org/10.5194/acp-21-7917-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-21-7917-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Measurement report: Online measurement of gas-phase nitrated phenols utilizing a CI-LToF-MS: primary sources and secondary formation
Kai Song
State Key Joint Laboratory of Environmental Simulation and Pollution Control, International Joint Laboratory for Regional Pollution Control, Ministry of Education (IJRC), College of Environmental Sciences and Engineering, Peking University, Beijing, 100871, China
Collaborative Innovation Center of Atmospheric Environment and
Equipment Technology, Nanjing University of Information Science and Technology, Nanjing, 210044, China
State Key Joint Laboratory of Environmental Simulation and Pollution Control, International Joint Laboratory for Regional Pollution Control, Ministry of Education (IJRC), College of Environmental Sciences and Engineering, Peking University, Beijing, 100871, China
Collaborative Innovation Center of Atmospheric Environment and
Equipment Technology, Nanjing University of Information Science and Technology, Nanjing, 210044, China
Haichao Wang
School of Atmospheric Sciences, Sun Yat-sen University, Zhuhai,
519082, China
Ying Yu
State Key Joint Laboratory of Environmental Simulation and Pollution Control, International Joint Laboratory for Regional Pollution Control, Ministry of Education (IJRC), College of Environmental Sciences and Engineering, Peking University, Beijing, 100871, China
Hui Wang
State Key Joint Laboratory of Environmental Simulation and Pollution Control, International Joint Laboratory for Regional Pollution Control, Ministry of Education (IJRC), College of Environmental Sciences and Engineering, Peking University, Beijing, 100871, China
Rongzhi Tang
State Key Joint Laboratory of Environmental Simulation and Pollution Control, International Joint Laboratory for Regional Pollution Control, Ministry of Education (IJRC), College of Environmental Sciences and Engineering, Peking University, Beijing, 100871, China
Shiyong Xia
Key Laboratory for Urban Habitat Environmental Science and Technology,
School of Environment and Energy, Peking University Shenzhen Graduate
School, Shenzhen, 518055, China
Yuanzheng Gong
State Key Joint Laboratory of Environmental Simulation and Pollution Control, International Joint Laboratory for Regional Pollution Control, Ministry of Education (IJRC), College of Environmental Sciences and Engineering, Peking University, Beijing, 100871, China
Zichao Wan
State Key Joint Laboratory of Environmental Simulation and Pollution Control, International Joint Laboratory for Regional Pollution Control, Ministry of Education (IJRC), College of Environmental Sciences and Engineering, Peking University, Beijing, 100871, China
Daqi Lv
State Key Joint Laboratory of Environmental Simulation and Pollution Control, International Joint Laboratory for Regional Pollution Control, Ministry of Education (IJRC), College of Environmental Sciences and Engineering, Peking University, Beijing, 100871, China
Rui Tan
State Key Joint Laboratory of Environmental Simulation and Pollution Control, International Joint Laboratory for Regional Pollution Control, Ministry of Education (IJRC), College of Environmental Sciences and Engineering, Peking University, Beijing, 100871, China
Wenfei Zhu
State Key Joint Laboratory of Environmental Simulation and Pollution Control, International Joint Laboratory for Regional Pollution Control, Ministry of Education (IJRC), College of Environmental Sciences and Engineering, Peking University, Beijing, 100871, China
Ruizhe Shen
State Key Joint Laboratory of Environmental Simulation and Pollution Control, International Joint Laboratory for Regional Pollution Control, Ministry of Education (IJRC), College of Environmental Sciences and Engineering, Peking University, Beijing, 100871, China
State Key Joint Laboratory of Environmental Simulation and Pollution Control, International Joint Laboratory for Regional Pollution Control, Ministry of Education (IJRC), College of Environmental Sciences and Engineering, Peking University, Beijing, 100871, China
Xuena Yu
State Key Joint Laboratory of Environmental Simulation and Pollution Control, International Joint Laboratory for Regional Pollution Control, Ministry of Education (IJRC), College of Environmental Sciences and Engineering, Peking University, Beijing, 100871, China
Shiyi Chen
State Key Joint Laboratory of Environmental Simulation and Pollution Control, International Joint Laboratory for Regional Pollution Control, Ministry of Education (IJRC), College of Environmental Sciences and Engineering, Peking University, Beijing, 100871, China
Liming Zeng
State Key Joint Laboratory of Environmental Simulation and Pollution Control, International Joint Laboratory for Regional Pollution Control, Ministry of Education (IJRC), College of Environmental Sciences and Engineering, Peking University, Beijing, 100871, China
Xiaofeng Huang
Key Laboratory for Urban Habitat Environmental Science and Technology,
School of Environment and Energy, Peking University Shenzhen Graduate
School, Shenzhen, 518055, China
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Cited
19 citations as recorded by crossref.
- Increasing role of phenolic oxidative branch in daytime oxidation process of aromatics in Chinese haze period F. Wang et al. 10.1016/j.scitotenv.2022.159578
- Comprehensive understanding on sources of high levels of fine particulate nitro-aromatic compounds at a coastal rural area in northern China Y. Jiang et al. 10.1016/j.jes.2022.09.033
- Secondary Formation and Impacts of Gaseous Nitro-Phenolic Compounds in the Continental Outflow Observed at a Background Site in South China Y. Chen et al. 10.1021/acs.est.1c04596
- Decomposition of Clusters of Oxygenated Compounds with NO3– by Applying Voltage Scanning to Chemical Ionization Mass Spectrometry in Steady-State Experiments H. Wang et al. 10.1021/acs.estlett.4c00276
- Investigation of partition coefficients and fingerprints of atmospheric gas- and particle-phase intermediate volatility and semi-volatile organic compounds using pixel-based approaches K. Song et al. 10.1016/j.chroma.2022.462808
- Source apportionment of gaseous Nitrophenols and their contribution to HONO formation in an urban area M. Ahmed et al. 10.1016/j.chemosphere.2023.139499
- Exploring condensable organic vapors and their co-occurrence with PM2.5and O3in winter in Eastern China Y. Liu et al. 10.1039/D2EA00143H
- Seasonal variation in oxygenated organic molecules in urban Beijing and their contribution to secondary organic aerosol Y. Guo et al. 10.5194/acp-22-10077-2022
- Field Detection of Highly Oxygenated Organic Molecules in Shanghai by Chemical Ionization–Orbitrap Y. Zhang et al. 10.1021/acs.est.1c08346
- Observations and Modeling of Gaseous Nitrated Phenols in Urban Beijing: Insights From Seasonal Comparison and Budget Analysis M. Xia et al. 10.1029/2023JD039551
- Insights into the nitroaromatic compounds, formation, and light absorption contributing emissions from various geological maturity coals S. Huang et al. 10.1016/j.scitotenv.2023.162033
- Chromophores and chemical composition of brown carbon characterized at an urban kerbside by excitation–emission spectroscopy and mass spectrometry F. Jiang et al. 10.5194/acp-22-14971-2022
- Enigma of Urban Gaseous Oxygenated Organic Molecules: Precursor Type, Role of NOx, and Degree of Oxygenation L. Tian et al. 10.1021/acs.est.2c05047
- Characteristics and source apportionment of water-soluble organic nitrogen (WSON) in PM2.5 in Hong Kong: With focus on amines, urea, and nitroaromatic compounds C. Leung et al. 10.1016/j.jhazmat.2024.133899
- Does community attitude matter? The effects of local community environmental orientation on firms' environmental practices S. Cai et al. 10.1002/csr.2609
- The important contribution of secondary formation and biomass burning to oxidized organic nitrogen (OON) in a polluted urban area: insights from in situ measurements of a chemical ionization mass spectrometer (CIMS) Y. Cai et al. 10.5194/acp-23-8855-2023
- Nitrophenols in the environment: An update on pretreatment and analysis techniques since 2017 M. Qian et al. 10.1016/j.ecoenv.2024.116611
- Nitroaromatic compounds in six major Chinese cities: Influence of different formation mechanisms on light absorption properties S. Huang et al. 10.1016/j.scitotenv.2024.172672
- Application of fuzzy c-means clustering for analysis of chemical ionization mass spectra: insights into the gas phase chemistry of NO3-initiated oxidation of isoprene R. Wu et al. 10.5194/amt-17-1811-2024
19 citations as recorded by crossref.
- Increasing role of phenolic oxidative branch in daytime oxidation process of aromatics in Chinese haze period F. Wang et al. 10.1016/j.scitotenv.2022.159578
- Comprehensive understanding on sources of high levels of fine particulate nitro-aromatic compounds at a coastal rural area in northern China Y. Jiang et al. 10.1016/j.jes.2022.09.033
- Secondary Formation and Impacts of Gaseous Nitro-Phenolic Compounds in the Continental Outflow Observed at a Background Site in South China Y. Chen et al. 10.1021/acs.est.1c04596
- Decomposition of Clusters of Oxygenated Compounds with NO3– by Applying Voltage Scanning to Chemical Ionization Mass Spectrometry in Steady-State Experiments H. Wang et al. 10.1021/acs.estlett.4c00276
- Investigation of partition coefficients and fingerprints of atmospheric gas- and particle-phase intermediate volatility and semi-volatile organic compounds using pixel-based approaches K. Song et al. 10.1016/j.chroma.2022.462808
- Source apportionment of gaseous Nitrophenols and their contribution to HONO formation in an urban area M. Ahmed et al. 10.1016/j.chemosphere.2023.139499
- Exploring condensable organic vapors and their co-occurrence with PM2.5and O3in winter in Eastern China Y. Liu et al. 10.1039/D2EA00143H
- Seasonal variation in oxygenated organic molecules in urban Beijing and their contribution to secondary organic aerosol Y. Guo et al. 10.5194/acp-22-10077-2022
- Field Detection of Highly Oxygenated Organic Molecules in Shanghai by Chemical Ionization–Orbitrap Y. Zhang et al. 10.1021/acs.est.1c08346
- Observations and Modeling of Gaseous Nitrated Phenols in Urban Beijing: Insights From Seasonal Comparison and Budget Analysis M. Xia et al. 10.1029/2023JD039551
- Insights into the nitroaromatic compounds, formation, and light absorption contributing emissions from various geological maturity coals S. Huang et al. 10.1016/j.scitotenv.2023.162033
- Chromophores and chemical composition of brown carbon characterized at an urban kerbside by excitation–emission spectroscopy and mass spectrometry F. Jiang et al. 10.5194/acp-22-14971-2022
- Enigma of Urban Gaseous Oxygenated Organic Molecules: Precursor Type, Role of NOx, and Degree of Oxygenation L. Tian et al. 10.1021/acs.est.2c05047
- Characteristics and source apportionment of water-soluble organic nitrogen (WSON) in PM2.5 in Hong Kong: With focus on amines, urea, and nitroaromatic compounds C. Leung et al. 10.1016/j.jhazmat.2024.133899
- Does community attitude matter? The effects of local community environmental orientation on firms' environmental practices S. Cai et al. 10.1002/csr.2609
- The important contribution of secondary formation and biomass burning to oxidized organic nitrogen (OON) in a polluted urban area: insights from in situ measurements of a chemical ionization mass spectrometer (CIMS) Y. Cai et al. 10.5194/acp-23-8855-2023
- Nitrophenols in the environment: An update on pretreatment and analysis techniques since 2017 M. Qian et al. 10.1016/j.ecoenv.2024.116611
- Nitroaromatic compounds in six major Chinese cities: Influence of different formation mechanisms on light absorption properties S. Huang et al. 10.1016/j.scitotenv.2024.172672
- Application of fuzzy c-means clustering for analysis of chemical ionization mass spectra: insights into the gas phase chemistry of NO3-initiated oxidation of isoprene R. Wu et al. 10.5194/amt-17-1811-2024
Latest update: 12 Oct 2024
Short summary
Nitrated phenols (NPs) are crucial components of brown carbon. To comprehend the constitutes and sources of NPs in winter of Beijing, their concentrations were measured by a CI-LToF-MS. The secondary formation process was simulated by a box model. NPs were mainly influenced by primary emissions and regional transport. Primary emitted phenol rather than benzene oxidation was crucial in the heavy pollution episode in Beijing. This provides more insight into pollution control strategies of NPs.
Nitrated phenols (NPs) are crucial components of brown carbon. To comprehend the constitutes and...
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