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ACP | Articles | Volume 20, issue 3
Atmos. Chem. Phys., 20, 1469–1481, 2020
https://doi.org/10.5194/acp-20-1469-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
Atmos. Chem. Phys., 20, 1469–1481, 2020
https://doi.org/10.5194/acp-20-1469-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.

Research article 06 Feb 2020

Research article | 06 Feb 2020

High secondary formation of nitrogen-containing organics (NOCs) and its possible link to oxidized organics and ammonium

Guohua Zhang et al.

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Cited articles

Altieri, K. E., Turpin, B. J., and Seitzinger, S. P.: Composition of Dissolved Organic Nitrogen in Continental Precipitation Investigated by Ultra-High Resolution FT-ICR Mass Spectrometry, Environ. Sci. Technol., 43, 6950–6955, https://doi.org/10.1021/es9007849, 2009. 
Andreae, M. O. and Gelencsér, A.: Black carbon or brown carbon? The nature of light-absorbing carbonaceous aerosols, Atmos. Chem. Phys., 6, 3131–3148, https://doi.org/10.5194/acp-6-3131-2006, 2006. 
Bones, D. L., Henricksen, D. K., Mang, S. A., Gonsior, M., Bateman, A. P., Nguyen, T. B., Cooper, W. J., and Nizkorodov, S. A.: Appearance of strong absorbers and fluorophores in limonene-O3 secondary organic aerosol due to NH4+-mediated chemical aging over long time scales, J. Geophys. Res.-Atmos., 115, D05203, https://doi.org/10.1029/2009jd012864, 2010. 
Cape, J. N., Cornell, S. E., Jickells, T. D., and Nemitz, E.: Organic nitrogen in the atmosphere – Where does it come from? A review of sources and methods, Atmos. Res., 102, 30–48, https://doi.org/10.1016/j.atmosres.2011.07.009, 2011. 
Chen, Y. F., Ge, X. L., Chen, H., Xie, X. C., Chen, Y. T., Wang, J. F., Ye, Z. L., Bao, M. Y., Zhang, Y. L., and Chen, M. D.: Seasonal light absorption properties of water-soluble brown carbon in atmospheric fine particles in Nanjing, China, Atmos. Environ., 187, 230–240, https://doi.org/10.1016/j.atmosenv.2018.06.002, 2018. 
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Seasonal atmospheric processing of NOCs was investigated using single-particle mass spectrometry in urban Guangzhou. The abundance of NOCs was found to be strongly enhanced by internal mixing with photochemically produced secondary oxidized organics. A multiple linear regression analysis and a positive matrix factorization analysis were performed to predict the relative abundance of NOCs. More than 70 % of observed NOCs could be well explained by oxidized organics and ammonium.
Seasonal atmospheric processing of NOCs was investigated using single-particle mass spectrometry...
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