Journal cover Journal topic
Atmospheric Chemistry and Physics An interactive open-access journal of the European Geosciences Union
Journal topic

Journal metrics

IF value: 5.414
IF5.414
IF 5-year value: 5.958
IF 5-year
5.958
CiteScore value: 9.7
CiteScore
9.7
SNIP value: 1.517
SNIP1.517
IPP value: 5.61
IPP5.61
SJR value: 2.601
SJR2.601
Scimago H <br class='widget-line-break'>index value: 191
Scimago H
index
191
h5-index value: 89
h5-index89
Volume 16, issue 4
Atmos. Chem. Phys., 16, 2689–2702, 2016
https://doi.org/10.5194/acp-16-2689-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
Atmos. Chem. Phys., 16, 2689–2702, 2016
https://doi.org/10.5194/acp-16-2689-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.

Research article 03 Mar 2016

Research article | 03 Mar 2016

A new source of methylglyoxal in the aqueous phase

Maria Rodigast et al.

Related authors

Evaluated kinetic and photochemical data for atmospheric chemistry: Volume VIII – gas phase reactions of organic species with four, or more, carbon atoms (≥ C4)
Abdelwahid Mellouki, Markus Ammann, R. Anthony Cox, John N. Crowley, Hartmut Herrmann, Michael E. Jenkin, V. Faye McNeill, Jürgen Troe, and Timothy J. Wallington
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2020-940,https://doi.org/10.5194/acp-2020-940, 2020
Preprint under review for ACP
Short summary
Application of TXRF in monitoring trace metals in particulate matter and cloud water
Khanneh Wadinga Fomba, Nabil Deabji, Sayf El Islam Barcha, Ibrahim Ouchen, El Mehdi Elbaramoussi, Rajaa Cherkaoui El Moursli, Mimoun Harnafi, Souad El Hajjaji, Abdelwahid Mellouki, and Hartmut Herrmann
Atmos. Meas. Tech., 13, 4773–4790, https://doi.org/10.5194/amt-13-4773-2020,https://doi.org/10.5194/amt-13-4773-2020, 2020
Short summary
Treatment of non-ideality in the SPACCIM multiphase model – Part 2: Impacts on the multiphase chemical processing in deliquesced aerosol particles
Ahmad Jhony Rusumdar, Andreas Tilgner, Ralf Wolke, and Hartmut Herrmann
Atmos. Chem. Phys., 20, 10351–10377, https://doi.org/10.5194/acp-20-10351-2020,https://doi.org/10.5194/acp-20-10351-2020, 2020
Short summary
Photochemical degradation of iron(III)-citrate/citric acid aerosol quantified with the combination of three complementary experimental techniques and a kinetic process model
Jing Dou, Peter A. Alpert, Pablo Corral Arroyo, Beiping Luo, Frederic Schneider, Jacinta Xto, Thomas Huthwelker, Camelia N. Borca, Katja D. Henzler, Jörg Raabe, Benjamin Watts, Hartmut Herrmann, Thomas Peter, Markus Ammann, and Ulrich K. Krieger
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2020-779,https://doi.org/10.5194/acp-2020-779, 2020
Preprint under review for ACP
A protocol for quantifying mono- and polysaccharides in seawater and related saline matrices by electro-dialysis (ED) – combined with HPAEC-PAD
Sebastian Zeppenfeld, Manuela van Pinxteren, Anja Engel, and Hartmut Herrmann
Ocean Sci., 16, 817–830, https://doi.org/10.5194/os-16-817-2020,https://doi.org/10.5194/os-16-817-2020, 2020
Short summary

Related subject area

Subject: Aerosols | Research Activity: Laboratory Studies | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
Laboratory studies of fresh and aged biomass burning aerosol emitted from east African biomass fuels – Part 2: Chemical properties and characterization
Damon M. Smith, Tianqu Cui, Marc N. Fiddler, Rudra P. Pokhrel, Jason D. Surratt, and Solomon Bililign
Atmos. Chem. Phys., 20, 10169–10191, https://doi.org/10.5194/acp-20-10169-2020,https://doi.org/10.5194/acp-20-10169-2020, 2020
Short summary
Impact of NOx on secondary organic aerosol (SOA) formation from α-pinene and β-pinene photooxidation: the role of highly oxygenated organic nitrates
Iida Pullinen, Sebastian Schmitt, Sungah Kang, Mehrnaz Sarrafzadeh, Patrick Schlag, Stefanie Andres, Einhard Kleist, Thomas F. Mentel, Franz Rohrer, Monika Springer, Ralf Tillmann, Jürgen Wildt, Cheng Wu, Defeng Zhao, Andreas Wahner, and Astrid Kiendler-Scharr
Atmos. Chem. Phys., 20, 10125–10147, https://doi.org/10.5194/acp-20-10125-2020,https://doi.org/10.5194/acp-20-10125-2020, 2020
Short summary
Evaluation of the chemical composition of gas- and particle-phase products of aromatic oxidation
Archit Mehra, Yuwei Wang, Jordan E. Krechmer, Andrew Lambe, Francesca Majluf, Melissa A. Morris, Michael Priestley, Thomas J. Bannan, Daniel J. Bryant, Kelly L. Pereira, Jacqueline F. Hamilton, Andrew R. Rickard, Mike J. Newland, Harald Stark, Philip Croteau, John T. Jayne, Douglas R. Worsnop, Manjula R. Canagaratna, Lin Wang, and Hugh Coe
Atmos. Chem. Phys., 20, 9783–9803, https://doi.org/10.5194/acp-20-9783-2020,https://doi.org/10.5194/acp-20-9783-2020, 2020
Short summary
Glyoxal's impact on dry ammonium salts: fast and reversible surface aerosol browning
David O. De Haan, Lelia N. Hawkins, Kevin Jansen, Hannah G. Welsh, Raunak Pednekar, Alexia de Loera, Natalie G. Jimenez, Margaret A. Tolbert, Mathieu Cazaunau, Aline Gratien, Antonin Bergé, Edouard Pangui, Paola Formenti, and Jean-François Doussin
Atmos. Chem. Phys., 20, 9581–9590, https://doi.org/10.5194/acp-20-9581-2020,https://doi.org/10.5194/acp-20-9581-2020, 2020
Short summary
Oxygenated products formed from OH-initiated reactions of trimethylbenzene: autoxidation and accretion
Yuwei Wang, Archit Mehra, Jordan E. Krechmer, Gan Yang, Xiaoyu Hu, Yiqun Lu, Andrew Lambe, Manjula Canagaratna, Jianmin Chen, Douglas Worsnop, Hugh Coe, and Lin Wang
Atmos. Chem. Phys., 20, 9563–9579, https://doi.org/10.5194/acp-20-9563-2020,https://doi.org/10.5194/acp-20-9563-2020, 2020
Short summary

Cited articles

Akagi, S. K., Yokelson, R. J., Wiedinmyer, C., Alvarado, M. J., Reid, J. S., Karl, T., Crounse, J. D., and Wennberg, P. O.: Emission factors for open and domestic biomass burning for use in atmospheric models, Atmos. Chem. Phys., 11, 4039–4072, https://doi.org/10.5194/acp-11-4039-2011, 2011.
Andreae, M. O. and Merlet, P.: Emission of trace gases and aerosols from biomass burning, Global Biogeochem. Cy., 15, 955–966, https://doi.org/10.1029/2000gb001382, 2001.
Ashworth, R. A., Howe, G. B., Mullins, M. E., and Rogers, T. N.: Air water partitioning coefficients of organics in dilute aqueous-solutions, J. Hazard. Mater., 18, 25–36, https://doi.org/10.1016/0304-3894(88)85057-x, 1988.
Atkinson, R.: Gas-phase tropospheric chemistry of volatile organic compounds .1. Alkanes and alkenes, J. Phys. Chem. Ref. Data, 26, 215–290, 1997.
Betterton, E. A. and Hoffmann, M. R.: Henry's law constants of some environmentally important aldehydes. Environ. Sci. Technol., 22, 1415–1418, 1988.
Publications Copernicus
Download
Short summary
The study highlights methyl ethyl ketone as a new and unknown source for methylglyoxal in the aqueous phase that is important for aqueous secondary organic aerosol (aqSOA) formation. Besides 2,3-butanedione (29.5 %) and hydroxyacetone (3.0 %), methylglyoxal was formed with a molar yield of 9.5 %. According to the detected products a reaction mechanism was developed and evaluated. The comparison of the model and experimental data showed excellent agreements, in particular for methylglyoxal.
The study highlights methyl ethyl ketone as a new and unknown source for methylglyoxal in the...
Citation
Altmetrics
Final-revised paper
Preprint