Articles | Volume 15, issue 24
https://doi.org/10.5194/acp-15-13993-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-15-13993-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
18 Dec 2015
Research article |
| 18 Dec 2015
Spring and summer contrast in new particle formation over nine forest areas in North America
Atmospheric Sciences Research Center, State University of New York, 251 Fuller Road, Albany, NY 12203, USA
Atmospheric Sciences Research Center, State University of New York, 251 Fuller Road, Albany, NY 12203, USA
S. C. Pryor
Department of Earth and Atmospheric Sciences, Cornell University, Ithaca, NY 14853, USA
P. R. Pillai
Department of Marine, Earth, and Atmospheric Sciences, North Carolina State University, Raleigh, NC 27695, USA
S. H. Lee
College of Public Health, Kent State University, Kent, OH, USA
J. Ortega
National Center for Atmospheric Research, P.O. Box 3000, Boulder, CO 80307, USA
J. J. Schwab
Atmospheric Sciences Research Center, State University of New York, 251 Fuller Road, Albany, NY 12203, USA
A. G. Hallar
Desert Research Institute, Storm Peak Laboratory, Steamboat Springs, CO 80488, USA
W. R. Leaitch
Environment Canada, Science and Technology Branch, Toronto, ON, Canada
V. P. Aneja
Department of Marine, Earth, and Atmospheric Sciences, North Carolina State University, Raleigh, NC 27695, USA
J. N. Smith
National Center for Atmospheric Research, P.O. Box 3000, Boulder, CO 80307, USA
Applied Physics Dept., University of Eastern Finland, P.O. Box 1627, Kuopio 70211, Finland
J. T. Walker
Department of Marine, Earth, and Atmospheric Sciences, North Carolina State University, Raleigh, NC 27695, USA
US Environmental Protection Agency, Office of Research and Development, Durham, NC 27711, USA
O. Hogrefe
Atmospheric Sciences Research Center, State University of New York, 251 Fuller Road, Albany, NY 12203, USA
currently at: Durham Technical Community College, Durham, NC 27703, USA
K. L. Demerjian
Atmospheric Sciences Research Center, State University of New York, 251 Fuller Road, Albany, NY 12203, USA
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Fangqun Yu, Alexey B. Nadykto, Jason Herb, Gan Luo, Kirill M. Nazarenko, and Lyudmila A. Uvarova
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Jingbo Mao, Fangqun Yu, Yan Zhang, Jingyu An, Lin Wang, Jun Zheng, Lei Yao, Gan Luo, Weichun Ma, Qi Yu, Cheng Huang, Li Li, and Limin Chen
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Fangqun Yu, Gan Luo, Alexey B. Nadykto, and Jason Herb
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Zachary Watson, Can Li, Fei Liu, Sean W. Freeman, Huanxin Zhang, Jun Wang, and Shan-Hu Lee
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Wind turbines in offshore lease areas (LA) along the eastern U.S. may be impacted by hurricanes. Regional simulations with atmosphere-only and coupled atmosphere-ocean-wave regional models well reproduce historical hurricanes and indicate no exceedance of 50 m s-1 wind speeds in the LA and only brief periods with low power production. Coupled simulations lead to more intense hurricanes possibly indicating that previous atmosphere-only simulations underestimate the risk to offshore wind turbines.
Tyler R. Elgiar, Lynne Gratz, A. Gannet Hallar, Rainer Volkamer, and Seth N. Lyman
EGUsphere, https://doi.org/10.5194/egusphere-2025-977, https://doi.org/10.5194/egusphere-2025-977, 2025
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This manuscript compares verified atmospheric mercury measurements against output from the GEOS-Chem 3D photochemical transport model. It shows that the model is unable to reproduce measured atmospheric oxidized mercury concentrations, even in several cases where oxidation rates in the model are enhanced.
Hongyu Liu, Bo Zhang, Richard H. Moore, Luke D. Ziemba, Richard A. Ferrare, Hyundeok Choi, Armin Sorooshian, David Painemal, Hailong Wang, Michael A. Shook, Amy Jo Scarino, Johnathan W. Hair, Ewan C. Crosbie, Marta A. Fenn, Taylor J. Shingler, Chris A. Hostetler, Gao Chen, Mary M. Kleb, Gan Luo, Fangqun Yu, Mark A. Vaughan, Yongxiang Hu, Glenn S. Diskin, John B. Nowak, Joshua P. DiGangi, Yonghoon Choi, Christoph A. Keller, and Matthew S. Johnson
Atmos. Chem. Phys., 25, 2087–2121, https://doi.org/10.5194/acp-25-2087-2025, https://doi.org/10.5194/acp-25-2087-2025, 2025
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We use the GEOS-Chem model to simulate aerosol distributions and properties over the western North Atlantic Ocean (WNAO) during the winter and summer deployments in 2020 of the NASA ACTIVATE mission. Model results are evaluated against aircraft, ground-based, and satellite observations. The improved understanding of life cycle, composition, transport pathways, and distribution of aerosols has important implications for characterizing aerosol–cloud–meteorology interactions over WNAO.
Paul J. DeMott, Jessica A. Mirrielees, Sarah Suda Petters, Daniel J. Cziczo, Markus D. Petters, Heinz G. Bingemer, Thomas C. J. Hill, Karl Froyd, Sarvesh Garimella, A. Gannet Hallar, Ezra J. T. Levin, Ian B. McCubbin, Anne E. Perring, Christopher N. Rapp, Thea Schiebel, Jann Schrod, Kaitlyn J. Suski, Daniel Weber, Martin J. Wolf, Maria Zawadowicz, Jake Zenker, Ottmar Möhler, and Sarah D. Brooks
Atmos. Meas. Tech., 18, 639–672, https://doi.org/10.5194/amt-18-639-2025, https://doi.org/10.5194/amt-18-639-2025, 2025
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The Fifth International Ice Nucleation Workshop Phase 3 (FIN-03) compared the ambient atmospheric performance of ice-nucleating particle (INP) measuring systems and explored general methods for discerning atmospheric INP compositions. Mirroring laboratory results, INP concentrations agreed within 5–10 factors. Measurements of total aerosol properties and investigations of INP compositions supported a dominant role of soil and plant organic aerosol elements as INPs during the study.
Adam E. Thomas, Hayley S. Glicker, Alex B. Guenther, Roger Seco, Oscar Vega Bustillos, Julio Tota, Rodrigo A. F. Souza, and James N. Smith
Atmos. Chem. Phys., 25, 959–977, https://doi.org/10.5194/acp-25-959-2025, https://doi.org/10.5194/acp-25-959-2025, 2025
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We present measurements of the organic composition of ultrafine particles collected from the eastern Amazon, an understudied region that is subjected to increasing human influence. We find that while isoprene chemistry is likely significant for ultrafine-particle growth throughout the year, compounds related to other sources, such as biological-spore emissions and biomass burning, exhibit striking seasonal differences, implying extensive variation in regional ultrafine-particle sources.
Tristan Shepherd, Frederick Letson, Rebecca J. Barthelmie, and Sara C. Pryor
Nat. Hazards Earth Syst. Sci., 24, 4473–4505, https://doi.org/10.5194/nhess-24-4473-2024, https://doi.org/10.5194/nhess-24-4473-2024, 2024
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A historic derecho in the USA is presented. The 29 June 2012 derecho caused more than 20 deaths and millions of US dollars of damage. We use a regional climate model to understand how model fidelity changes under different initial conditions. We find changes drive different convective conditions, resulting in large variation in the simulated hazards. The variation using different reanalysis data shows that framing these results in the context of contemporary and future climate is a challenge.
Jie Zhang, Tianyu Zhu, Alexandra Catena, Yaowei Li, Margaret J. Schwab, Pengfei Liu, Akua Asa-Awuku, and James Schwab
Atmos. Chem. Phys., 24, 13445–13456, https://doi.org/10.5194/acp-24-13445-2024, https://doi.org/10.5194/acp-24-13445-2024, 2024
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This study shows the derived organic aerosol hygroscopicity under high-humidity conditions based on a simple optical scatter monitor system, including two nephelometric monitors (pDR-1500), when the aerosol chemical composition is already known.
Lee Tiszenkel, James H. Flynn, and Shan-Hu Lee
Atmos. Chem. Phys., 24, 11351–11363, https://doi.org/10.5194/acp-24-11351-2024, https://doi.org/10.5194/acp-24-11351-2024, 2024
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Ammonia and amines are important ingredients for aerosol formation in urban environments, but the measurements of these compounds are extremely challenging. Our observations show that urban ammonia and amines in Houston are emitted from urban sources, and diurnal variations in their concentrations are likely governed by gas-to-particle conversion and emissions.
Naveed Ahmad, Changqing Lin, Alexis K. H. Lau, Jhoon Kim, Tianshu Zhang, Fangqun Yu, Chengcai Li, Ying Li, Jimmy C. H. Fung, and Xiang Qian Lao
Atmos. Chem. Phys., 24, 9645–9665, https://doi.org/10.5194/acp-24-9645-2024, https://doi.org/10.5194/acp-24-9645-2024, 2024
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This study developed a nested machine learning model to convert the GEMS NO2 column measurements into ground-level concentrations across China. The model directly incorporates the NO2 mixing height (NMH) into the methodological framework. The study underscores the importance of considering NMH when estimating ground-level NO2 from satellite column measurements and highlights the significant advantages of new-generation geostationary satellites in air quality monitoring.
Eleanor J. Derry, Tyler R. Elgiar, Taylor Y. Wilmot, Nicholas W. Hoch, Noah S. Hirshorn, Peter Weiss-Penzias, Christopher F. Lee, John C. Lin, A. Gannet Hallar, Rainer Volkamer, Seth N. Lyman, and Lynne E. Gratz
Atmos. Chem. Phys., 24, 9615–9643, https://doi.org/10.5194/acp-24-9615-2024, https://doi.org/10.5194/acp-24-9615-2024, 2024
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Mercury (Hg) is a globally distributed neurotoxic pollutant. Atmospheric deposition is the main source of Hg in ecosystems. However, measurement biases hinder understanding of the origins and abundance of the more bioavailable oxidized form. We used an improved, calibrated measurement system to study air mass composition and transport of atmospheric Hg at a remote mountaintop site in the central US. Oxidized Hg originated upwind in the low to middle free troposphere under clean, dry conditions.
Vignesh Vasudevan-Geetha, Lee Tiszenkel, Zhizhao Wang, Robin Russo, Daniel Bryant, Julia Lee-Taylor, Kelley Barsanti, and Shan-Hu Lee
EGUsphere, https://doi.org/10.5194/egusphere-2024-2454, https://doi.org/10.5194/egusphere-2024-2454, 2024
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Our laboratory experiments using two high-resolution mass spectrometers show that these OOMs can also form within the particle phase, in addition to gas-to-particle conversion processes. Our results demonstrate that particle-phase formation processes can contribute to the formation and growth of new particles in biogenic environments.
Christoffer Hallgren, Jeanie A. Aird, Stefan Ivanell, Heiner Körnich, Ville Vakkari, Rebecca J. Barthelmie, Sara C. Pryor, and Erik Sahlée
Wind Energ. Sci., 9, 821–840, https://doi.org/10.5194/wes-9-821-2024, https://doi.org/10.5194/wes-9-821-2024, 2024
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Knowing the wind speed across the rotor of a wind turbine is key in making good predictions of the power production. However, models struggle to capture both the speed and the shape of the wind profile. Using machine learning methods based on the model data, we show that the predictions can be improved drastically. The work focuses on three coastal sites, spread over the Northern Hemisphere (the Baltic Sea, the North Sea, and the US Atlantic coast) with similar results for all sites.
Rebecca Foody, Jacob Coburn, Jeanie A. Aird, Rebecca J. Barthelmie, and Sara C. Pryor
Wind Energ. Sci., 9, 263–280, https://doi.org/10.5194/wes-9-263-2024, https://doi.org/10.5194/wes-9-263-2024, 2024
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Using lidar-derived wind speed measurements at approx. 150 m height at onshore and offshore locations, we quantify the advantages of deploying wind turbines offshore in terms of the amount of electrical power produced and the higher reliability and predictability of the electrical power.
Xiaoxiao Li, Yijing Chen, Yuyang Li, Runlong Cai, Yiran Li, Chenjuan Deng, Jin Wu, Chao Yan, Hairong Cheng, Yongchun Liu, Markku Kulmala, Jiming Hao, James N. Smith, and Jingkun Jiang
Atmos. Chem. Phys., 23, 14801–14812, https://doi.org/10.5194/acp-23-14801-2023, https://doi.org/10.5194/acp-23-14801-2023, 2023
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Near-continuous measurements show the composition, sources, and seasonal variations of ultrafine particles (UFPs) in urban Beijing. Vehicle and cooking emissions and new particle formation are the main sources of UFPs, and aqueous/heterogeneous processes increase UFP mode diameters. UFPs are the highest in winter due to the highest primary particle emission rates and new particle formation rates, and CHO fractions are the highest in summer due to the strongest photooxidation.
Christoffer Hallgren, Jeanie A. Aird, Stefan Ivanell, Heiner Körnich, Rebecca J. Barthelmie, Sara C. Pryor, and Erik Sahlée
Wind Energ. Sci., 8, 1651–1658, https://doi.org/10.5194/wes-8-1651-2023, https://doi.org/10.5194/wes-8-1651-2023, 2023
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Low-level jets (LLJs) are special types of non-ideal wind profiles affecting both wind energy production and loads on a wind turbine. However, among LLJ researchers, there is no consensus regarding which definition to use to identify these profiles. In this work, we compare two different ways of identifying the LLJ – the falloff definition and the shear definition – and argue why the shear definition is better suited to wind energy applications.
Shixian Zhai, Daniel J. Jacob, Drew C. Pendergrass, Nadia K. Colombi, Viral Shah, Laura Hyesung Yang, Qiang Zhang, Shuxiao Wang, Hwajin Kim, Yele Sun, Jin-Soo Choi, Jin-Soo Park, Gan Luo, Fangqun Yu, Jung-Hun Woo, Younha Kim, Jack E. Dibb, Taehyoung Lee, Jin-Seok Han, Bruce E. Anderson, Ke Li, and Hong Liao
Atmos. Chem. Phys., 23, 4271–4281, https://doi.org/10.5194/acp-23-4271-2023, https://doi.org/10.5194/acp-23-4271-2023, 2023
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Anthropogenic fugitive dust in East Asia not only causes severe coarse particulate matter air pollution problems, but also affects fine particulate nitrate. Due to emission control efforts, coarse PM decreased steadily. We find that the decrease of coarse PM is a major driver for a lack of decrease of fine particulate nitrate, as it allows more nitric acid to form fine particulate nitrate. The continuing decrease of coarse PM requires more stringent ammonia and nitrogen oxides emission controls.
Jun-Wei Xu, Jintai Lin, Gan Luo, Jamiu Adeniran, and Hao Kong
Atmos. Chem. Phys., 23, 4149–4163, https://doi.org/10.5194/acp-23-4149-2023, https://doi.org/10.5194/acp-23-4149-2023, 2023
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Research on the sources of Chinese PM2.5 pollution has focused on the contributions of China’s domestic emissions. However, the impact of foreign anthropogenic emissions has typically been simplified or neglected. Here we find that foreign anthropogenic emissions play an important role in Chinese PM2.5 pollution through chemical interactions between foreign-transported pollutants and China’s local emissions. Thus, foreign emission reductions are essential for improving Chinese air quality.
Kun Wang, Xiaoyan Ma, Rong Tian, and Fangqun Yu
Atmos. Chem. Phys., 23, 4091–4104, https://doi.org/10.5194/acp-23-4091-2023, https://doi.org/10.5194/acp-23-4091-2023, 2023
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From 12 March to 6 April 2016 in Beijing, there were 11 typical new particle formation days, 13 non-event days, and 2 undefined days. We first analyzed the favorable background of new particle formation in Beijing and then conducted the simulations using four nucleation schemes based on a global chemistry transport model (GEOS-Chem) to understand the nucleation mechanism.
John T. Walker, Xi Chen, Zhiyong Wu, Donna Schwede, Ryan Daly, Aleksandra Djurkovic, A. Christopher Oishi, Eric Edgerton, Jesse Bash, Jennifer Knoepp, Melissa Puchalski, John Iiames, and Chelcy F. Miniat
Biogeosciences, 20, 971–995, https://doi.org/10.5194/bg-20-971-2023, https://doi.org/10.5194/bg-20-971-2023, 2023
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Better estimates of atmospheric nitrogen (N) deposition are needed to accurately assess ecosystem risk and impacts from deposition of nutrients and acidity. Using measurements and modeling, we estimate total N deposition of 6.7 kg N ha−1 yr−1 at a forest site in the southern Appalachian Mountains, a region sensitive to atmospheric deposition. Reductions in deposition of reduced forms of N (ammonia and ammonium) will be needed to meet the lowest estimates of N critical loads for the region.
Fangqun Yu, Gan Luo, Arshad Arjunan Nair, Sebastian Eastham, Christina J. Williamson, Agnieszka Kupc, and Charles A. Brock
Atmos. Chem. Phys., 23, 1863–1877, https://doi.org/10.5194/acp-23-1863-2023, https://doi.org/10.5194/acp-23-1863-2023, 2023
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Particle number concentrations and size distributions in the stratosphere are studied through model simulations and comparisons with measurements. The nucleation scheme used in most of the solar geoengineering modeling studies overpredicts the nucleation rates and particle number concentrations in the stratosphere. The model based on updated nucleation schemes captures reasonably well some aspects of particle size distributions but misses some features. The possible reasons are discussed.
Christopher E. Lawrence, Paul Casson, Richard Brandt, James J. Schwab, James E. Dukett, Phil Snyder, Elizabeth Yerger, Daniel Kelting, Trevor C. VandenBoer, and Sara Lance
Atmos. Chem. Phys., 23, 1619–1639, https://doi.org/10.5194/acp-23-1619-2023, https://doi.org/10.5194/acp-23-1619-2023, 2023
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Atmospheric aqueous chemistry can have profound effects on our environment, as illustrated by historical data from Whiteface Mountain (WFM) that were critical for uncovering the process of acid rain. The current study updates the long-term trends in cloud water composition at WFM for the period 1994 to 2021. We highlight the emergence of a new chemical regime at WFM dominated by organics and ammonium, quite different from the highly acidic regime observed in the past but not necessarily
clean.
Noah S. Hirshorn, Lauren M. Zuromski, Christopher Rapp, Ian McCubbin, Gerardo Carrillo-Cardenas, Fangqun Yu, and A. Gannet Hallar
Atmos. Chem. Phys., 22, 15909–15924, https://doi.org/10.5194/acp-22-15909-2022, https://doi.org/10.5194/acp-22-15909-2022, 2022
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New particle formation (NPF) is a source of atmospheric aerosol number concentration that can impact climate by growing to larger sizes and under proper conditions form cloud condensation nuclei (CCN). Using novel methods, we find that at Storm Peak Laboratory, a remote, mountaintop site in Colorado, NPF is observed to enhance CCN concentrations in the spring by a factor of 1.54 and in the winter by a factor of 1.36 which can occur on a regional scale having important climate implications.
Deanna C. Myers, Saewung Kim, Steven Sjostedt, Alex B. Guenther, Roger Seco, Oscar Vega Bustillos, Julio Tota, Rodrigo A. F. Souza, and James N. Smith
Atmos. Chem. Phys., 22, 10061–10076, https://doi.org/10.5194/acp-22-10061-2022, https://doi.org/10.5194/acp-22-10061-2022, 2022
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We present the first measurements of gas-phase sulfuric acid from the Amazon basin and evaluate the efficacy of existing sulfuric acid parameterizations in this understudied region. Sulfuric acid is produced during the daytime and nighttime, though current proxies underestimate nighttime production. These results illustrate the need for better parameterizations of sulfuric acid and its precursors that are informed by measurements across a broad range of locations.
Anna L. Hodshire, Ezra J. T. Levin, A. Gannet Hallar, Christopher N. Rapp, Dan R. Gilchrist, Ian McCubbin, and Gavin R. McMeeking
Atmos. Meas. Tech. Discuss., https://doi.org/10.5194/amt-2022-216, https://doi.org/10.5194/amt-2022-216, 2022
Publication in AMT not foreseen
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The new Continuous Flow Diffusion Chamber-Ice Activation Spectrometer collected 4 months of ice nucleating particle (INP) measurements at a 5-minute resolution at the mountainside Storm Peak Laboratory. Most long-term INP measurements are at a time resolution of a day or longer: our instrument is a promising advance towards high-resolution long-term INP measurements. We observe higher peak INP concentrations than previous mountain studies, possibly due to the higher time resolution of our data.
Michelia Dam, Danielle C. Draper, Andrey Marsavin, Juliane L. Fry, and James N. Smith
Atmos. Chem. Phys., 22, 9017–9031, https://doi.org/10.5194/acp-22-9017-2022, https://doi.org/10.5194/acp-22-9017-2022, 2022
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We performed chamber experiments to measure the composition of the gas-phase reaction products of nitrate-radical-initiated oxidation of four monoterpenes. The total organic yield, effective oxygen-to-carbon ratio, and dimer-to-monomer ratio were correlated with the observed particle formation for the monoterpene systems with some exceptions. The Δ-carene system produced the most particles, followed by β-pinene, with the α-pinene and α-thujene systems producing no particles.
Katherine R. Travis, James H. Crawford, Gao Chen, Carolyn E. Jordan, Benjamin A. Nault, Hwajin Kim, Jose L. Jimenez, Pedro Campuzano-Jost, Jack E. Dibb, Jung-Hun Woo, Younha Kim, Shixian Zhai, Xuan Wang, Erin E. McDuffie, Gan Luo, Fangqun Yu, Saewung Kim, Isobel J. Simpson, Donald R. Blake, Limseok Chang, and Michelle J. Kim
Atmos. Chem. Phys., 22, 7933–7958, https://doi.org/10.5194/acp-22-7933-2022, https://doi.org/10.5194/acp-22-7933-2022, 2022
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The 2016 Korea–United States Air Quality (KORUS-AQ) field campaign provided a unique set of observations to improve our understanding of PM2.5 pollution in South Korea. Models typically have errors in simulating PM2.5 in this region, which is of concern for the development of control measures. We use KORUS-AQ observations to improve our understanding of the mechanisms driving PM2.5 and the implications of model errors for determining PM2.5 that is attributable to local or foreign sources.
Libby Koolik, Michael Roesch, Carmen Dameto de Espana, Christopher Nathan Rapp, Lesly J. Franco Deloya, Chuanyang Shen, A. Gannet Hallar, Ian B. McCubbin, and Daniel J. Cziczo
Atmos. Meas. Tech., 15, 3213–3222, https://doi.org/10.5194/amt-15-3213-2022, https://doi.org/10.5194/amt-15-3213-2022, 2022
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A new inlet for studying the small particles, droplets, and ice crystals that constitute mixed-phase clouds has been constructed and is described here. This new inlet was tested in the laboratory. We present the performance of the new inlet to demonstrate its capability of separating ice, droplets, and small particles.
Anna L. Hodshire, Ezra J. T. Levin, A. Gannet Hallar, Christopher N. Rapp, Dan R. Gilchrist, Ian McCubbin, and Gavin R. McMeeking
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2022-29, https://doi.org/10.5194/acp-2022-29, 2022
Preprint withdrawn
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The new Continuous Flow Diffusion Chamber-Ice Activation Spectrometer collected 4 months of ice nucleating particle (INP) measurements at a 5-minute resolution at the mountainside Storm Peak Laboratory. Most long-term INP measurements are at a time resolution of a day or longer: our instrument is a promising advance towards high-resolution long-term INP measurements. We observe higher peak INP concentrations than previous mountain studies, possibly due to the higher time resolution of our data.
Yanda Zhang, Fangqun Yu, Gan Luo, Jiwen Fan, and Shuai Liu
Atmos. Chem. Phys., 21, 17433–17451, https://doi.org/10.5194/acp-21-17433-2021, https://doi.org/10.5194/acp-21-17433-2021, 2021
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This paper explores the impacts of dust on summertime convective cloud and precipitation through a numerical experiment. The result indicates that the long-range-transported dust can notably affect the properties of convective cloud and precipitation by enhancing immersion freezing and invigorating convection. We also analyze the different dust effects predicted by the Morrison and SBM schemes, which are partially attributed to the saturation adjustment approach utilized in the bulk schemes.
Clémence Rose, Martine Collaud Coen, Elisabeth Andrews, Yong Lin, Isaline Bossert, Cathrine Lund Myhre, Thomas Tuch, Alfred Wiedensohler, Markus Fiebig, Pasi Aalto, Andrés Alastuey, Elisabeth Alonso-Blanco, Marcos Andrade, Begoña Artíñano, Todor Arsov, Urs Baltensperger, Susanne Bastian, Olaf Bath, Johan Paul Beukes, Benjamin T. Brem, Nicolas Bukowiecki, Juan Andrés Casquero-Vera, Sébastien Conil, Konstantinos Eleftheriadis, Olivier Favez, Harald Flentje, Maria I. Gini, Francisco Javier Gómez-Moreno, Martin Gysel-Beer, Anna Gannet Hallar, Ivo Kalapov, Nikos Kalivitis, Anne Kasper-Giebl, Melita Keywood, Jeong Eun Kim, Sang-Woo Kim, Adam Kristensson, Markku Kulmala, Heikki Lihavainen, Neng-Huei Lin, Hassan Lyamani, Angela Marinoni, Sebastiao Martins Dos Santos, Olga L. Mayol-Bracero, Frank Meinhardt, Maik Merkel, Jean-Marc Metzger, Nikolaos Mihalopoulos, Jakub Ondracek, Marco Pandolfi, Noemi Pérez, Tuukka Petäjä, Jean-Eudes Petit, David Picard, Jean-Marc Pichon, Veronique Pont, Jean-Philippe Putaud, Fabienne Reisen, Karine Sellegri, Sangeeta Sharma, Gerhard Schauer, Patrick Sheridan, James Patrick Sherman, Andreas Schwerin, Ralf Sohmer, Mar Sorribas, Junying Sun, Pierre Tulet, Ville Vakkari, Pieter Gideon van Zyl, Fernando Velarde, Paolo Villani, Stergios Vratolis, Zdenek Wagner, Sheng-Hsiang Wang, Kay Weinhold, Rolf Weller, Margarita Yela, Vladimir Zdimal, and Paolo Laj
Atmos. Chem. Phys., 21, 17185–17223, https://doi.org/10.5194/acp-21-17185-2021, https://doi.org/10.5194/acp-21-17185-2021, 2021
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Aerosol particles are a complex component of the atmospheric system the effects of which are among the most uncertain in climate change projections. Using data collected at 62 stations, this study provides the most up-to-date picture of the spatial distribution of particle number concentration and size distribution worldwide, with the aim of contributing to better representation of aerosols and their interactions with clouds in models and, therefore, better evaluation of their impact on climate.
Shixian Zhai, Daniel J. Jacob, Jared F. Brewer, Ke Li, Jonathan M. Moch, Jhoon Kim, Seoyoung Lee, Hyunkwang Lim, Hyun Chul Lee, Su Keun Kuk, Rokjin J. Park, Jaein I. Jeong, Xuan Wang, Pengfei Liu, Gan Luo, Fangqun Yu, Jun Meng, Randall V. Martin, Katherine R. Travis, Johnathan W. Hair, Bruce E. Anderson, Jack E. Dibb, Jose L. Jimenez, Pedro Campuzano-Jost, Benjamin A. Nault, Jung-Hun Woo, Younha Kim, Qiang Zhang, and Hong Liao
Atmos. Chem. Phys., 21, 16775–16791, https://doi.org/10.5194/acp-21-16775-2021, https://doi.org/10.5194/acp-21-16775-2021, 2021
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Geostationary satellite aerosol optical depth (AOD) has tremendous potential for monitoring surface fine particulate matter (PM2.5). Our study explored the physical relationship between AOD and PM2.5 by integrating data from surface networks, aircraft, and satellites with the GEOS-Chem chemical transport model. We quantitatively showed that accurate simulation of aerosol size distributions, boundary layer depths, relative humidity, coarse particles, and diurnal variations in PM2.5 are essential.
Sarah Waldo, Jake J. Beaulieu, William Barnett, D. Adam Balz, Michael J. Vanni, Tanner Williamson, and John T. Walker
Biogeosciences, 18, 5291–5311, https://doi.org/10.5194/bg-18-5291-2021, https://doi.org/10.5194/bg-18-5291-2021, 2021
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Human-made reservoirs impact the carbon cycle. In particular, the breakdown of organic matter in reservoir sediments can result in large emissions of greenhouse gases (especially methane) to the atmosphere. This study takes an intensive look at the patterns in greenhouse gas emissions from a single reservoir in Ohio (United States) and the role of water temperature, precipitation, and algal blooms in emissions. We saw a "spring burst" of elevated emissions that challenged our assumptions.
Zhiyong Wu, Leiming Zhang, John T. Walker, Paul A. Makar, Judith A. Perlinger, and Xuemei Wang
Geosci. Model Dev., 14, 5093–5105, https://doi.org/10.5194/gmd-14-5093-2021, https://doi.org/10.5194/gmd-14-5093-2021, 2021
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A community dry deposition algorithm for modeling the gaseous dry deposition process in chemistry transport models was extended to include an additional 12 oxidized volatile organic compounds and hydrogen cyanide based on their physicochemical properties and was then evaluated using field flux measurements over a mixed forest. This study provides a useful tool that is needed in chemistry transport models with increasing complexity for simulating an important atmospheric process.
Sabrina Chee, Kelley Barsanti, James N. Smith, and Nanna Myllys
Atmos. Chem. Phys., 21, 11637–11654, https://doi.org/10.5194/acp-21-11637-2021, https://doi.org/10.5194/acp-21-11637-2021, 2021
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We explored molecular properties affecting atmospheric particle formation efficiency and derived a parameterization between particle formation rate and heterodimer concentration, which showed good agreement to previously reported experimental data. Considering the simplicity of calculating heterodimer concentration, this approach has potential to improve estimates of global cloud condensation nuclei in models that are limited by the computational expense of calculating particle formation rate.
Gongda Lu, Eloise A. Marais, Tuan V. Vu, Jingsha Xu, Zongbo Shi, James D. Lee, Qiang Zhang, Lu Shen, Gan Luo, and Fangqun Yu
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2021-428, https://doi.org/10.5194/acp-2021-428, 2021
Revised manuscript not accepted
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Emission controls were imposed in Beijing-Tianjin-Hebei in northern China in autumn-winter 2017. We find that regional PM2.5 targets (15 % decrease relative to previous year) were exceeded. Our analysis shows that decline in precursor emissions only leads to less than half (43 %) the improved air quality. Most of the change (57 %) is due to interannual variability in meteorology. Stricter emission controls may be necessary in years with unfavourable meteorology.
Jeanie A. Aird, Rebecca J. Barthelmie, Tristan J. Shepherd, and Sara C. Pryor
Wind Energ. Sci., 6, 1015–1030, https://doi.org/10.5194/wes-6-1015-2021, https://doi.org/10.5194/wes-6-1015-2021, 2021
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Low-level jets (LLJs) are pronounced maxima in wind speed profiles affecting wind turbine performance and longevity. We present a climatology of LLJs over Iowa using output from the Weather Research and Forecasting (WRF) model and determine the rotor plane conditions when they occur. LLJ characteristics are highly sensitive to the identification criteria applied, and different (unique) LLJs are extracted with each criterion. LLJ characteristics also vary with different model output resolution.
Frederick W. Letson, Rebecca J. Barthelmie, Kevin I. Hodges, and Sara C. Pryor
Nat. Hazards Earth Syst. Sci., 21, 2001–2020, https://doi.org/10.5194/nhess-21-2001-2021, https://doi.org/10.5194/nhess-21-2001-2021, 2021
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Windstorms during the last 40 years in the US Northeast are identified and characterized using the spatial extent of extreme wind speeds at 100 m height from the ERA5 reanalysis. During all of the top 10 windstorms, wind speeds exceeding the local 99.9th percentile cover at least one-third of the land area in this high-population-density region. These 10 storms followed frequently observed cyclone tracks but have intensities 5–10 times the mean values for cyclones affecting this region.
Xueshun Chen, Fangqun Yu, Wenyi Yang, Yele Sun, Huansheng Chen, Wei Du, Jian Zhao, Ying Wei, Lianfang Wei, Huiyun Du, Zhe Wang, Qizhong Wu, Jie Li, Junling An, and Zifa Wang
Atmos. Chem. Phys., 21, 9343–9366, https://doi.org/10.5194/acp-21-9343-2021, https://doi.org/10.5194/acp-21-9343-2021, 2021
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Atmospheric aerosol particles have significant climate and health effects that depend on aerosol size, composition, and mixing state. A new global-regional nested aerosol model with an advanced particle microphysics module and a volatility basis set organic aerosol module was developed to simulate aerosol microphysical processes. Simulations strongly suggest the important role of anthropogenic organic species in particle formation over the areas influenced by anthropogenic sources.
Amy Hrdina, Jennifer G. Murphy, Anna Gannet Hallar, John C. Lin, Alexander Moravek, Ryan Bares, Ross C. Petersen, Alessandro Franchin, Ann M. Middlebrook, Lexie Goldberger, Ben H. Lee, Munkh Baasandorj, and Steven S. Brown
Atmos. Chem. Phys., 21, 8111–8126, https://doi.org/10.5194/acp-21-8111-2021, https://doi.org/10.5194/acp-21-8111-2021, 2021
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Wintertime air pollution in the Salt Lake Valley is primarily composed of ammonium nitrate, which is formed when gas-phase ammonia and nitric acid react. The major point in this work is that the chemical composition of snow tells a very different story to what we measured in the atmosphere. With the dust–sea salt cations observed in PM2.5 and particle sizing data, we can estimate how much nitric acid may be lost to dust–sea salt that is not accounted for and how much more PM2.5 this could form.
Xiaojing Shen, Junying Sun, Fangqun Yu, Ying Wang, Junting Zhong, Yangmei Zhang, Xinyao Hu, Can Xia, Sinan Zhang, and Xiaoye Zhang
Atmos. Chem. Phys., 21, 7039–7052, https://doi.org/10.5194/acp-21-7039-2021, https://doi.org/10.5194/acp-21-7039-2021, 2021
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In this work, we revealed the changes of PNSD and NPF events during the COVID-19 lockdown period in Beijing, China, to illustrate the impact of reduced primary emission and elavated atmospheric oxidized capicity on the nucleation and growth processes. The subsequent growth of nucleated particles and their contribution to the aerosol pollution formation were also explored, to highlight the necessity of controlling the nanoparticles in the future air quality management.
Franziska Köllner, Johannes Schneider, Megan D. Willis, Hannes Schulz, Daniel Kunkel, Heiko Bozem, Peter Hoor, Thomas Klimach, Frank Helleis, Julia Burkart, W. Richard Leaitch, Amir A. Aliabadi, Jonathan P. D. Abbatt, Andreas B. Herber, and Stephan Borrmann
Atmos. Chem. Phys., 21, 6509–6539, https://doi.org/10.5194/acp-21-6509-2021, https://doi.org/10.5194/acp-21-6509-2021, 2021
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We present in situ observations of vertically resolved particle chemical composition in the summertime Arctic lower troposphere. Our analysis demonstrates the strong vertical contrast between particle properties within the boundary layer and aloft. Emissions from vegetation fires and anthropogenic sources in northern Canada, Europe, and East Asia influenced particle composition in the free troposphere. Organics detected in Arctic aerosol particles can partly be identified as dicarboxylic acids.
Ling Liu, Fangqun Yu, Kaipeng Tu, Zhi Yang, and Xiuhui Zhang
Atmos. Chem. Phys., 21, 6221–6230, https://doi.org/10.5194/acp-21-6221-2021, https://doi.org/10.5194/acp-21-6221-2021, 2021
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Trifluoroacetic acid (TFA) was previously proved to participate in sulfuric acid (SA)–dimethylamine (DMA) nucleation in Shanghai, China. However, complex atmospheric environments can influence the nucleation of aerosol significantly. We show the influence of different atmospheric conditions on the SA-DMA-TFA nucleation and find the enhancement by TFA can be significant in cold and polluted areas, which provides the perspective of the realistic role of TFA in different atmospheric environments.
Arshad Arjunan Nair and Fangqun Yu
Atmos. Chem. Phys., 20, 12853–12869, https://doi.org/10.5194/acp-20-12853-2020, https://doi.org/10.5194/acp-20-12853-2020, 2020
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Small particles in the atmosphere can affect cloud formation and properties and thus Earth's energy budget. These cloud condensation nuclei (CCN) contribute the largest uncertainties in climate change modeling. To reduce these uncertainties, it is important to quantify CCN numbers accurately, measurements of which are sparse. We propose and evaluate a machine learning method to estimate CCN, in the absence of their direct measurements, using more common measurements of weather and air quality.
W. Richard Leaitch, John K. Kodros, Megan D. Willis, Sarah Hanna, Hannes Schulz, Elisabeth Andrews, Heiko Bozem, Julia Burkart, Peter Hoor, Felicia Kolonjari, John A. Ogren, Sangeeta Sharma, Meng Si, Knut von Salzen, Allan K. Bertram, Andreas Herber, Jonathan P. D. Abbatt, and Jeffrey R. Pierce
Atmos. Chem. Phys., 20, 10545–10563, https://doi.org/10.5194/acp-20-10545-2020, https://doi.org/10.5194/acp-20-10545-2020, 2020
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Black carbon is a factor in the warming of the Arctic atmosphere due to its ability to absorb light, but the uncertainty is high and few observations have been made in the high Arctic above 80° N. We combine airborne and ground-based observations in the springtime Arctic, at and above 80° N, with simulations from a global model to show that light absorption by black carbon may be much larger than modelled. However, the uncertainty remains high.
Paolo Laj, Alessandro Bigi, Clémence Rose, Elisabeth Andrews, Cathrine Lund Myhre, Martine Collaud Coen, Yong Lin, Alfred Wiedensohler, Michael Schulz, John A. Ogren, Markus Fiebig, Jonas Gliß, Augustin Mortier, Marco Pandolfi, Tuukka Petäja, Sang-Woo Kim, Wenche Aas, Jean-Philippe Putaud, Olga Mayol-Bracero, Melita Keywood, Lorenzo Labrador, Pasi Aalto, Erik Ahlberg, Lucas Alados Arboledas, Andrés Alastuey, Marcos Andrade, Begoña Artíñano, Stina Ausmeel, Todor Arsov, Eija Asmi, John Backman, Urs Baltensperger, Susanne Bastian, Olaf Bath, Johan Paul Beukes, Benjamin T. Brem, Nicolas Bukowiecki, Sébastien Conil, Cedric Couret, Derek Day, Wan Dayantolis, Anna Degorska, Konstantinos Eleftheriadis, Prodromos Fetfatzis, Olivier Favez, Harald Flentje, Maria I. Gini, Asta Gregorič, Martin Gysel-Beer, A. Gannet Hallar, Jenny Hand, Andras Hoffer, Christoph Hueglin, Rakesh K. Hooda, Antti Hyvärinen, Ivo Kalapov, Nikos Kalivitis, Anne Kasper-Giebl, Jeong Eun Kim, Giorgos Kouvarakis, Irena Kranjc, Radovan Krejci, Markku Kulmala, Casper Labuschagne, Hae-Jung Lee, Heikki Lihavainen, Neng-Huei Lin, Gunter Löschau, Krista Luoma, Angela Marinoni, Sebastiao Martins Dos Santos, Frank Meinhardt, Maik Merkel, Jean-Marc Metzger, Nikolaos Mihalopoulos, Nhat Anh Nguyen, Jakub Ondracek, Noemi Pérez, Maria Rita Perrone, Jean-Eudes Petit, David Picard, Jean-Marc Pichon, Veronique Pont, Natalia Prats, Anthony Prenni, Fabienne Reisen, Salvatore Romano, Karine Sellegri, Sangeeta Sharma, Gerhard Schauer, Patrick Sheridan, James Patrick Sherman, Maik Schütze, Andreas Schwerin, Ralf Sohmer, Mar Sorribas, Martin Steinbacher, Junying Sun, Gloria Titos, Barbara Toczko, Thomas Tuch, Pierre Tulet, Peter Tunved, Ville Vakkari, Fernando Velarde, Patricio Velasquez, Paolo Villani, Sterios Vratolis, Sheng-Hsiang Wang, Kay Weinhold, Rolf Weller, Margarita Yela, Jesus Yus-Diez, Vladimir Zdimal, Paul Zieger, and Nadezda Zikova
Atmos. Meas. Tech., 13, 4353–4392, https://doi.org/10.5194/amt-13-4353-2020, https://doi.org/10.5194/amt-13-4353-2020, 2020
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The paper establishes the fiducial reference of the GAW aerosol network providing the fully characterized value chain to the provision of four climate-relevant aerosol properties from ground-based sites. Data from almost 90 stations worldwide are reported for a reference year, 2017, providing a unique and very robust view of the variability of these variables worldwide. Current gaps in the GAW network are analysed and requirements for the Global Climate Monitoring System are proposed.
Katherine R. Travis, Colette L. Heald, Hannah M. Allen, Eric C. Apel, Stephen R. Arnold, Donald R. Blake, William H. Brune, Xin Chen, Róisín Commane, John D. Crounse, Bruce C. Daube, Glenn S. Diskin, James W. Elkins, Mathew J. Evans, Samuel R. Hall, Eric J. Hintsa, Rebecca S. Hornbrook, Prasad S. Kasibhatla, Michelle J. Kim, Gan Luo, Kathryn McKain, Dylan B. Millet, Fred L. Moore, Jeffrey Peischl, Thomas B. Ryerson, Tomás Sherwen, Alexander B. Thames, Kirk Ullmann, Xuan Wang, Paul O. Wennberg, Glenn M. Wolfe, and Fangqun Yu
Atmos. Chem. Phys., 20, 7753–7781, https://doi.org/10.5194/acp-20-7753-2020, https://doi.org/10.5194/acp-20-7753-2020, 2020
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Atmospheric models overestimate the rate of removal of trace gases by the hydroxyl radical (OH). This is a concern for studies of the climate and air quality impacts of human activities. Here, we evaluate the performance of a commonly used model of atmospheric chemistry against data from the NASA Atmospheric Tomography Mission (ATom) over the remote oceans where models have received little validation. The model is generally successful, suggesting that biases in OH may be a concern over land.
Gan Luo, Fangqun Yu, and Jonathan M. Moch
Geosci. Model Dev., 13, 2879–2903, https://doi.org/10.5194/gmd-13-2879-2020, https://doi.org/10.5194/gmd-13-2879-2020, 2020
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This work improved pH calculation for cloud, rain, and wet surfaces, fraction of cloud available for aqueous-phase chemistry, rainout efficiencies for various types of cloud, empirical washout by rain and snow, and wet surface uptake in GEOS-Chem v12.6.0. We compared simulated mass concentrations of aerosol precursors and aerosols with surface monitoring networks, Arctic sites, and ATom observations, and showed that the model results with the updated wet processes agree better for most species.
Jian Xu, Jia Chen, Na Zhao, Guochen Wang, Guangyuan Yu, Hao Li, Juntao Huo, Yanfen Lin, Qingyan Fu, Hongyu Guo, Congrui Deng, Shan-Hu Lee, Jianmin Chen, and Kan Huang
Atmos. Chem. Phys., 20, 7259–7269, https://doi.org/10.5194/acp-20-7259-2020, https://doi.org/10.5194/acp-20-7259-2020, 2020
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This study provided evidence that gas-particle partitioning of ammonia, as opposed to ammonia concentration, plays a critical role in the haze formation. A reduction in ammonia emissions alone may not reduce air pollution effectively, at least at rural agricultural sites in China.
Chinmoy Sarkar, Alex B. Guenther, Jeong-Hoo Park, Roger Seco, Eliane Alves, Sarah Batalha, Raoni Santana, Saewung Kim, James Smith, Julio Tóta, and Oscar Vega
Atmos. Chem. Phys., 20, 7179–7191, https://doi.org/10.5194/acp-20-7179-2020, https://doi.org/10.5194/acp-20-7179-2020, 2020
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Biogenic volatile organic compounds (BVOCs) are important components of the atmosphere due to their contribution to atmospheric chemistry and biogeochemical cycles. In this study, we report major BVOCs, e.g. isoprene and total monoterpene flux measurements with a proton transfer reaction time-of-flight mass spectrometer (PTR-TOF-MS) using the eddy covariance (EC) method at a primary rainforest in eastern Amazonia. We used the measured data to evaluate the MEGAN2.1 model for the emission site.
Fangqun Yu, Alexey B. Nadykto, Gan Luo, and Jason Herb
Geosci. Model Dev., 13, 2663–2670, https://doi.org/10.5194/gmd-13-2663-2020, https://doi.org/10.5194/gmd-13-2663-2020, 2020
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Secondary particles formed via nucleation have important implications for air quality and climate. Here we describe nucleation rate lookup tables for four different nucleation mechanisms that can be readily used in chemistry transport and climate models. The nucleation rates predicted have been assessed against state-of-the-art laboratory measurements. The lookup tables cover a wide range of key parameters controlling binary, ternary, and ion-mediated nucleation in the Earth's atmosphere.
Havala O. T. Pye, Athanasios Nenes, Becky Alexander, Andrew P. Ault, Mary C. Barth, Simon L. Clegg, Jeffrey L. Collett Jr., Kathleen M. Fahey, Christopher J. Hennigan, Hartmut Herrmann, Maria Kanakidou, James T. Kelly, I-Ting Ku, V. Faye McNeill, Nicole Riemer, Thomas Schaefer, Guoliang Shi, Andreas Tilgner, John T. Walker, Tao Wang, Rodney Weber, Jia Xing, Rahul A. Zaveri, and Andreas Zuend
Atmos. Chem. Phys., 20, 4809–4888, https://doi.org/10.5194/acp-20-4809-2020, https://doi.org/10.5194/acp-20-4809-2020, 2020
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Acid rain is recognized for its impacts on human health and ecosystems, and programs to mitigate these effects have had implications for atmospheric acidity. Historical measurements indicate that cloud and fog droplet acidity has changed in recent decades in response to controls on emissions from human activity, while the limited trend data for suspended particles indicate acidity may be relatively constant. This review synthesizes knowledge on the acidity of atmospheric particles and clouds.
Libby Koolik, Michael Roesch, Lesly J. Franco Deloya, Chuanyang Shen, A. Gannet Hallar, Ian B. McCubbin, and Daniel J. Cziczo
Atmos. Meas. Tech. Discuss., https://doi.org/10.5194/amt-2020-42, https://doi.org/10.5194/amt-2020-42, 2020
Revised manuscript not accepted
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The phaSe seParation Inlet for Droplets icE residuals and inteRstitial aerosols (SPIDER) combines an omni-directional inlet, a Large-Pumped Counterflow Virtual Impactor, a flow tube evaporation chamber, and a Pumped Counterflow Virtual Impactor to separate droplets, ice crystals, and interstitial aerosols for simultaneous sampling. This new inlet for studying mixed-phase clouds is described here, with laboratory verification tests and a deployment at a mountain-top research facility.
Frederick Letson, Rebecca J. Barthelmie, and Sara C. Pryor
Wind Energ. Sci., 5, 331–347, https://doi.org/10.5194/wes-5-331-2020, https://doi.org/10.5194/wes-5-331-2020, 2020
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Wind turbine blade leading edge erosion (LEE) is potentially a significant source of energy loss and expense for wind farm operators. This study presents a novel approach to characterizing LEE potential from precipitation across the contiguous USA based on publicly available National Weather Service dual-polarization RADAR data. The approach is described in detail and illustrated using six locations distributed across parts of the USA that have substantial wind turbine deployments.
Fangqun Yu, Gan Luo, Arshad Arjunan Nair, James J. Schwab, James P. Sherman, and Yanda Zhang
Atmos. Chem. Phys., 20, 2591–2601, https://doi.org/10.5194/acp-20-2591-2020, https://doi.org/10.5194/acp-20-2591-2020, 2020
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Particle number concentration (PNC) is a key parameter important for the health and climate impacts of atmospheric aerosols. We show that, even during wintertime, regional nucleation occurs and contributes significantly to number concentrations of ultrafine particles and cloud condensation nuclei. Due to low biogenic emissions, wintertime regional nucleation is solely controlled by inorganic species, and ternary ion-mediated nucleation is able to capture the observed variations in PNC.
Xiaoyan Ma, Hailing Jia, Rong Tian, Fangqun Yu, and Jiagnan Li
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2020-54, https://doi.org/10.5194/acp-2020-54, 2020
Preprint withdrawn
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BC Mixing state, is one of critical microphysical properties to modulate optical properties, radiative forcing (RF), and climatic effect. However, it has been simply assumed previously as either external or internal mixing. In this study, by employing a nested GEOS-Chem-APM with predicted BC mixing state, we examined the effect of mixing state on aerosol optical properties, RF, and heating rate over East Asia. This will improve the predictions of aerosol climatic effect in the future.
Joelle Dionne, Knut von Salzen, Jason Cole, Rashed Mahmood, W. Richard Leaitch, Glen Lesins, Ian Folkins, and Rachel Y.-W. Chang
Atmos. Chem. Phys., 20, 29–43, https://doi.org/10.5194/acp-20-29-2020, https://doi.org/10.5194/acp-20-29-2020, 2020
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Low clouds persist in the summer Arctic, with important consequences for the radiation budget. We found that the ability of precipitation parameterizations to reproduce observed cloud properties was more variable than their ability to represent radiative effects. Our results show that cloud properties and their parameterizations affect the radiative effects of clouds.
Heiko Bozem, Peter Hoor, Daniel Kunkel, Franziska Köllner, Johannes Schneider, Andreas Herber, Hannes Schulz, W. Richard Leaitch, Amir A. Aliabadi, Megan D. Willis, Julia Burkart, and Jonathan P. D. Abbatt
Atmos. Chem. Phys., 19, 15049–15071, https://doi.org/10.5194/acp-19-15049-2019, https://doi.org/10.5194/acp-19-15049-2019, 2019
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We present airborne trace gas measurements in the European and Canadian Arctic for July 2014 and April 2015. Based on CO and CO2 in situ data as well as 10 d kinematic back trajectories, we characterize the prevailing transport regimes and derive a tracer-based diagnostic for the determination of the polar dome boundary. Using the tracer-derived boundary, an analysis of the recent transport history of air masses within the polar dome reveals significant differences between spring and summer.
Roya Ghahreman, Wanmin Gong, Martí Galí, Ann-Lise Norman, Stephen R. Beagley, Ayodeji Akingunola, Qiong Zheng, Alexandru Lupu, Martine Lizotte, Maurice Levasseur, and W. Richard Leaitch
Atmos. Chem. Phys., 19, 14455–14476, https://doi.org/10.5194/acp-19-14455-2019, https://doi.org/10.5194/acp-19-14455-2019, 2019
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Atmospheric DMS(g) is a climatically important compound and the main source of biogenic sulfate in the Arctic. Its abundance in the Arctic increases during summer due to greater ice-free sea surface and higher biological activity. In this study, we implemented DMS(g) in a regional air quality forecast model configured for the Arctic. The study showed a significant impact from DMS(g) on sulfate aerosols, particularly in the 50–100 nm size range, in the Arctic marine boundary layer during summer.
Hayley S. Glicker, Michael J. Lawler, John Ortega, Suzane S. de Sá, Scot T. Martin, Paulo Artaxo, Oscar Vega Bustillos, Rodrigo de Souza, Julio Tota, Annmarie Carlton, and James N. Smith
Atmos. Chem. Phys., 19, 13053–13066, https://doi.org/10.5194/acp-19-13053-2019, https://doi.org/10.5194/acp-19-13053-2019, 2019
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An understanding of the chemical composition of the smallest particles in the air over the Amazon Basin provides insights into the natural and human-caused influences on particle production in this sensitive region. We present measurements of the composition of sub-100 nm diameter particles performed during the wet season and identify unique constituents that point to both natural and human-caused sources and processes.
Gan Luo, Fangqun Yu, and James Schwab
Geosci. Model Dev., 12, 3439–3447, https://doi.org/10.5194/gmd-12-3439-2019, https://doi.org/10.5194/gmd-12-3439-2019, 2019
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GEOS-Chem 12.0.0 has been recognized to significantly overestimate the concentrations of gaseous nitric acid, aerosol nitrate, and aerosol ammonium over the United States. In this study, we show that most or all of the overestimation issue appears to be associated with wet scavenging processes. With the updated wet scavenging scheme in this work, we successfully improve the skill of the model in predicting the three species concentrations, which are important for air quality and climate studies.
Nanna Myllys, Jakub Kubečka, Vitus Besel, Dina Alfaouri, Tinja Olenius, James Norman Smith, and Monica Passananti
Atmos. Chem. Phys., 19, 9753–9768, https://doi.org/10.5194/acp-19-9753-2019, https://doi.org/10.5194/acp-19-9753-2019, 2019
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In atmospheric sulfuric-acid-driven particle formation, bases are able to stabilize the initial molecular clusters and thus enhance particle formation. We have investigated the enhancing potential of different bases in atmospheric particle formation. We show that strong bases with low abundance are likely to dominate electrically neutral particle formation, whereas weak bases with high abundance have a larger role in ion-mediated particle formation.
Lee Tiszenkel, Chris Stangl, Justin Krasnomowitz, Qi Ouyang, Huan Yu, Michael J. Apsokardu, Murray V. Johnston, and Shan-Hu Lee
Atmos. Chem. Phys., 19, 8915–8929, https://doi.org/10.5194/acp-19-8915-2019, https://doi.org/10.5194/acp-19-8915-2019, 2019
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Understanding the processes surrounding the formation and growth of atmospheric aerosol particles is essential for understanding their effects on air quality, human health and cloud formation. Current atmospheric models neglect many essential variables that influence these processes. This study investigates temperature effects on new particle formation and the formation of clusters and their subsequent growth in differing temperature conditions.
George S. Fanourgakis, Maria Kanakidou, Athanasios Nenes, Susanne E. Bauer, Tommi Bergman, Ken S. Carslaw, Alf Grini, Douglas S. Hamilton, Jill S. Johnson, Vlassis A. Karydis, Alf Kirkevåg, John K. Kodros, Ulrike Lohmann, Gan Luo, Risto Makkonen, Hitoshi Matsui, David Neubauer, Jeffrey R. Pierce, Julia Schmale, Philip Stier, Kostas Tsigaridis, Twan van Noije, Hailong Wang, Duncan Watson-Parris, Daniel M. Westervelt, Yang Yang, Masaru Yoshioka, Nikos Daskalakis, Stefano Decesari, Martin Gysel-Beer, Nikos Kalivitis, Xiaohong Liu, Natalie M. Mahowald, Stelios Myriokefalitakis, Roland Schrödner, Maria Sfakianaki, Alexandra P. Tsimpidi, Mingxuan Wu, and Fangqun Yu
Atmos. Chem. Phys., 19, 8591–8617, https://doi.org/10.5194/acp-19-8591-2019, https://doi.org/10.5194/acp-19-8591-2019, 2019
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Effects of aerosols on clouds are important for climate studies but are among the largest uncertainties in climate projections. This study evaluates the skill of global models to simulate aerosol, cloud condensation nuclei (CCN) and cloud droplet number concentrations (CDNCs). Model results show reduced spread in CDNC compared to CCN due to the negative correlation between the sensitivities of CDNC to aerosol number concentration (air pollution) and updraft velocity (atmospheric dynamics).
Rebecca J. Barthelmie and Sara C. Pryor
Atmos. Meas. Tech., 12, 3463–3484, https://doi.org/10.5194/amt-12-3463-2019, https://doi.org/10.5194/amt-12-3463-2019, 2019
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Wakes are volumes of air with low wind speed that form downwind of wind turbines. Their properties and behaviour determine optimal turbine spacing in wind farms. We use scanning Doppler lidar to accurately and precisely measure wake characteristics at a complex terrain site in Portugal. We develop and apply an automatic processing algorithm to detect wakes and quantify their characteristics. In higher wind speeds, the wake centres are lower. Wake centres are also lower in convective conditions.
Samantha Tremblay, Jean-Christophe Picard, Jill O. Bachelder, Erik Lutsch, Kimberly Strong, Pierre Fogal, W. Richard Leaitch, Sangeeta Sharma, Felicia Kolonjari, Christopher J. Cox, Rachel Y.-W. Chang, and Patrick L. Hayes
Atmos. Chem. Phys., 19, 5589–5604, https://doi.org/10.5194/acp-19-5589-2019, https://doi.org/10.5194/acp-19-5589-2019, 2019
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Atmospheric aerosols, tiny airborne particles, have an important impact on climate. However, a lack of understanding of the chemistry of aerosols is one of the largest contributors to uncertainty in predictions of climate change. Measurements of aerosols were carried out in the Arctic at Eureka Station, Canada, to better understand what role aerosols play in this fragile environment. It is found that organic aerosols, possibly originating from marine emissions, are ubiquitous during summertime.
Douglas H. Lowenthal, A. Gannet Hallar, Robert O. David, Ian B. McCubbin, Randolph D. Borys, and Gerald G. Mace
Atmos. Chem. Phys., 19, 5387–5401, https://doi.org/10.5194/acp-19-5387-2019, https://doi.org/10.5194/acp-19-5387-2019, 2019
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Snow and liquid cloud particles were measured during the StormVEx and IFRACS programs at Storm Peak Lab to better understand snow formation in wintertime mountain clouds. We found significant interactions between the ice and liquid phases of the cloud. A relationship between large droplet and small ice crystal concentrations suggested snow formation by droplet freezing. Blowing snow can bias surface measurements, but its effect was ambiguous, calling for further work on this issue.
Frederick Letson, Rebecca J. Barthelmie, Weifei Hu, and Sara C. Pryor
Atmos. Chem. Phys., 19, 3797–3819, https://doi.org/10.5194/acp-19-3797-2019, https://doi.org/10.5194/acp-19-3797-2019, 2019
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Wind gusts are a key driver of aerodynamic loading, and common approximations used to describe wind gust behavior may not be appropriate in complex terrain at heights relevant to wind turbines and other structures. High-resolution observations from sonic anemometers and vertically pointing Doppler lidars collected in the Perdigão experiment are analyzed to provide a foundation for improved wind gust characterization in complex terrain.
Meng Si, Erin Evoy, Jingwei Yun, Yu Xi, Sarah J. Hanna, Alina Chivulescu, Kevin Rawlings, Daniel Veber, Andrew Platt, Daniel Kunkel, Peter Hoor, Sangeeta Sharma, W. Richard Leaitch, and Allan K. Bertram
Atmos. Chem. Phys., 19, 3007–3024, https://doi.org/10.5194/acp-19-3007-2019, https://doi.org/10.5194/acp-19-3007-2019, 2019
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We investigated the importance of mineral dust, sea spray aerosol, and anthropogenic aerosol to the ice-nucleating particle (INP) population in the Canadian Arctic during spring 2016. The results suggest that mineral dust transported from the Gobi Desert was a major source of the INP population studied, and that sea spray aerosol decreased the ice-nucleating ability of mineral dust. The results should be useful for testing and improving models used to predict INPs and climate in the Arctic.
Betty Croft, Randall V. Martin, W. Richard Leaitch, Julia Burkart, Rachel Y.-W. Chang, Douglas B. Collins, Patrick L. Hayes, Anna L. Hodshire, Lin Huang, John K. Kodros, Alexander Moravek, Emma L. Mungall, Jennifer G. Murphy, Sangeeta Sharma, Samantha Tremblay, Gregory R. Wentworth, Megan D. Willis, Jonathan P. D. Abbatt, and Jeffrey R. Pierce
Atmos. Chem. Phys., 19, 2787–2812, https://doi.org/10.5194/acp-19-2787-2019, https://doi.org/10.5194/acp-19-2787-2019, 2019
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Summertime Arctic atmospheric aerosols are strongly controlled by processes related to natural regional sources. We use a chemical transport model with size-resolved aerosol microphysics to interpret measurements made during summertime 2016 in the Canadian Arctic Archipelago. Our results explore the processes that control summertime aerosol size distributions and support a climate-relevant role for Arctic marine secondary organic aerosol formed from precursor vapors with Arctic marine sources.
Jonathan P. D. Abbatt, W. Richard Leaitch, Amir A. Aliabadi, Allan K. Bertram, Jean-Pierre Blanchet, Aude Boivin-Rioux, Heiko Bozem, Julia Burkart, Rachel Y. W. Chang, Joannie Charette, Jai P. Chaubey, Robert J. Christensen, Ana Cirisan, Douglas B. Collins, Betty Croft, Joelle Dionne, Greg J. Evans, Christopher G. Fletcher, Martí Galí, Roya Ghahreman, Eric Girard, Wanmin Gong, Michel Gosselin, Margaux Gourdal, Sarah J. Hanna, Hakase Hayashida, Andreas B. Herber, Sareh Hesaraki, Peter Hoor, Lin Huang, Rachel Hussherr, Victoria E. Irish, Setigui A. Keita, John K. Kodros, Franziska Köllner, Felicia Kolonjari, Daniel Kunkel, Luis A. Ladino, Kathy Law, Maurice Levasseur, Quentin Libois, John Liggio, Martine Lizotte, Katrina M. Macdonald, Rashed Mahmood, Randall V. Martin, Ryan H. Mason, Lisa A. Miller, Alexander Moravek, Eric Mortenson, Emma L. Mungall, Jennifer G. Murphy, Maryam Namazi, Ann-Lise Norman, Norman T. O'Neill, Jeffrey R. Pierce, Lynn M. Russell, Johannes Schneider, Hannes Schulz, Sangeeta Sharma, Meng Si, Ralf M. Staebler, Nadja S. Steiner, Jennie L. Thomas, Knut von Salzen, Jeremy J. B. Wentzell, Megan D. Willis, Gregory R. Wentworth, Jun-Wei Xu, and Jacqueline D. Yakobi-Hancock
Atmos. Chem. Phys., 19, 2527–2560, https://doi.org/10.5194/acp-19-2527-2019, https://doi.org/10.5194/acp-19-2527-2019, 2019
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The Arctic is experiencing considerable environmental change with climate warming, illustrated by the dramatic decrease in sea-ice extent. It is important to understand both the natural and perturbed Arctic systems to gain a better understanding of how they will change in the future. This paper summarizes new insights into the relationships between Arctic aerosol particles and climate, as learned over the past five or so years by a large Canadian research consortium, NETCARE.
Hannes Schulz, Marco Zanatta, Heiko Bozem, W. Richard Leaitch, Andreas B. Herber, Julia Burkart, Megan D. Willis, Daniel Kunkel, Peter M. Hoor, Jonathan P. D. Abbatt, and Rüdiger Gerdes
Atmos. Chem. Phys., 19, 2361–2384, https://doi.org/10.5194/acp-19-2361-2019, https://doi.org/10.5194/acp-19-2361-2019, 2019
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Aircraft vertical profiles of black carbon (BC) aerosol from the High Canadian Arctic have shown systematic variability in different levels of the cold, stably stratified polar dome. During spring and summer, efficiencies of BC supply by transport (often from gas flaring and wildfire-affected regions) were different in the lower dome than at higher levels, as apparent from changes in mean particle size and mixing ratios with CO. Summer BC concentrations were a factor of 10 lower than in spring.
Xiaoxiao Li, Sabrina Chee, Jiming Hao, Jonathan P. D. Abbatt, Jingkun Jiang, and James N. Smith
Atmos. Chem. Phys., 19, 1555–1570, https://doi.org/10.5194/acp-19-1555-2019, https://doi.org/10.5194/acp-19-1555-2019, 2019
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We performed lab experiments to explore the role of relative humidity, RH, in atmospheric monoterpene oxidation and new particle formation. These studies will provide insights into the most important steps in the process, while also more accurately representing the real atmosphere. We found that the detected compounds did not change with RH, and in fact could mostly be fully explained by the autoxidation of organic peroxy radicals followed by bimolecular reactions with other peroxy radicals.
Victoria E. Irish, Sarah J. Hanna, Megan D. Willis, Swarup China, Jennie L. Thomas, Jeremy J. B. Wentzell, Ana Cirisan, Meng Si, W. Richard Leaitch, Jennifer G. Murphy, Jonathan P. D. Abbatt, Alexander Laskin, Eric Girard, and Allan K. Bertram
Atmos. Chem. Phys., 19, 1027–1039, https://doi.org/10.5194/acp-19-1027-2019, https://doi.org/10.5194/acp-19-1027-2019, 2019
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Ice nucleating particles (INPs) are atmospheric particles that catalyse the formation of ice crystals in clouds. INPs influence the Earth's radiative balance and hydrological cycle. In this study we measured the concentrations of INPs in the Canadian Arctic marine boundary layer. Average INP concentrations fell within the range measured in other marine boundary layer locations. We also found that mineral dust is a more important contributor to the INP population than sea spray aerosol.
Megan D. Willis, Heiko Bozem, Daniel Kunkel, Alex K. Y. Lee, Hannes Schulz, Julia Burkart, Amir A. Aliabadi, Andreas B. Herber, W. Richard Leaitch, and Jonathan P. D. Abbatt
Atmos. Chem. Phys., 19, 57–76, https://doi.org/10.5194/acp-19-57-2019, https://doi.org/10.5194/acp-19-57-2019, 2019
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The vertical distribution of Arctic aerosol is an important driver of its climate impacts. We present vertically resolved measurements of aerosol composition and properties made in the High Arctic during spring on an aircraft platform. We explore how aerosol properties are related to transport history and show evidence of vertical trends in aerosol sources, transport mechanisms and composition. These results will help us to better understand aerosol–climate interactions in the Arctic.
Fangqun Yu, Alexey B. Nadykto, Jason Herb, Gan Luo, Kirill M. Nazarenko, and Lyudmila A. Uvarova
Atmos. Chem. Phys., 18, 17451–17474, https://doi.org/10.5194/acp-18-17451-2018, https://doi.org/10.5194/acp-18-17451-2018, 2018
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Aerosol nucleation exerts important influences on the climate, hydrological cycle, and air quality. We have developed an advanced physical–chemical model that describes ion-induced and neutral nucleation involving ammonia, sulfuric acid, and water vapors. The model is shown to reproduce laboratory measurements taken under a wide range of conditions, offers physiochemical insights into the ternary nucleation process, and provides an accurate approach to calculate ternary rate in the atmosphere.
Tuomo Nieminen, Veli-Matti Kerminen, Tuukka Petäjä, Pasi P. Aalto, Mikhail Arshinov, Eija Asmi, Urs Baltensperger, David C. S. Beddows, Johan Paul Beukes, Don Collins, Aijun Ding, Roy M. Harrison, Bas Henzing, Rakesh Hooda, Min Hu, Urmas Hõrrak, Niku Kivekäs, Kaupo Komsaare, Radovan Krejci, Adam Kristensson, Lauri Laakso, Ari Laaksonen, W. Richard Leaitch, Heikki Lihavainen, Nikolaos Mihalopoulos, Zoltán Németh, Wei Nie, Colin O'Dowd, Imre Salma, Karine Sellegri, Birgitta Svenningsson, Erik Swietlicki, Peter Tunved, Vidmantas Ulevicius, Ville Vakkari, Marko Vana, Alfred Wiedensohler, Zhijun Wu, Annele Virtanen, and Markku Kulmala
Atmos. Chem. Phys., 18, 14737–14756, https://doi.org/10.5194/acp-18-14737-2018, https://doi.org/10.5194/acp-18-14737-2018, 2018
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Atmospheric aerosols have diverse effects on air quality, human health, and global climate. One important source of aerosols is their formation via nucleation and growth in the atmosphere. We have analyzed long-term observations of regional new particle formation events around the globe and provide a comprehensive view on the characteristics of this phenomenon in diverse environments. The results are useful in developing more realistic representation of atmospheric aerosols in global models.
Sara C. Pryor, Tristan J. Shepherd, and Rebecca J. Barthelmie
Wind Energ. Sci., 3, 651–665, https://doi.org/10.5194/wes-3-651-2018, https://doi.org/10.5194/wes-3-651-2018, 2018
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The interannual variability (IAV) of annual energy production (AEP) from wind turbines due to IAV in wind speeds from proposed wind farms plays a key role in dictating project financing but is only poorly constrained. This study provides improved quantification of IAV over eastern N. America using purpose-performed long-term numerical simulations. It may be appropriate to reduce the IAV applied to preconstruction AEP estimates, which would decrease the cost of capital for wind farm developments.
Anna L. Hodshire, Brett B. Palm, M. Lizabeth Alexander, Qijing Bian, Pedro Campuzano-Jost, Eben S. Cross, Douglas A. Day, Suzane S. de Sá, Alex B. Guenther, Armin Hansel, James F. Hunter, Werner Jud, Thomas Karl, Saewung Kim, Jesse H. Kroll, Jeong-Hoo Park, Zhe Peng, Roger Seco, James N. Smith, Jose L. Jimenez, and Jeffrey R. Pierce
Atmos. Chem. Phys., 18, 12433–12460, https://doi.org/10.5194/acp-18-12433-2018, https://doi.org/10.5194/acp-18-12433-2018, 2018
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We investigate the nucleation and growth processes that shape the aerosol size distribution inside oxidation flow reactors (OFRs) that sampled ambient air from Colorado and the Amazon rainforest. Results indicate that organics are important for both nucleation and growth, vapor uptake was limited to accumulation-mode particles, fragmentation reactions were important to limit particle growth at higher OH exposures, and an H2SO4-organics nucleation mechanism captured new particle formation well.
Martine Collaud Coen, Elisabeth Andrews, Diego Aliaga, Marcos Andrade, Hristo Angelov, Nicolas Bukowiecki, Marina Ealo, Paulo Fialho, Harald Flentje, A. Gannet Hallar, Rakesh Hooda, Ivo Kalapov, Radovan Krejci, Neng-Huei Lin, Angela Marinoni, Jing Ming, Nhat Anh Nguyen, Marco Pandolfi, Véronique Pont, Ludwig Ries, Sergio Rodríguez, Gerhard Schauer, Karine Sellegri, Sangeeta Sharma, Junying Sun, Peter Tunved, Patricio Velasquez, and Dominique Ruffieux
Atmos. Chem. Phys., 18, 12289–12313, https://doi.org/10.5194/acp-18-12289-2018, https://doi.org/10.5194/acp-18-12289-2018, 2018
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High altitude stations are often emphasized as free tropospheric measuring sites but they remain influenced by atmospheric boundary layer. An ABL-TopoIndex is defined from a topography analysis around the stations. This new index allows ranking stations as a function of the ABL influence due to topography or help to choose a new site to sample FT. The ABL-TopoIndex is validated by aerosol optical properties and number concentration measured at 29 high altitude stations of five continents.
John K. Kodros, Sarah J. Hanna, Allan K. Bertram, W. Richard Leaitch, Hannes Schulz, Andreas B. Herber, Marco Zanatta, Julia Burkart, Megan D. Willis, Jonathan P. D. Abbatt, and Jeffrey R. Pierce
Atmos. Chem. Phys., 18, 11345–11361, https://doi.org/10.5194/acp-18-11345-2018, https://doi.org/10.5194/acp-18-11345-2018, 2018
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The mixing state of black carbon is one of the key uncertainties limiting the ability of models to estimate the direct radiative effect. In this work, we present aircraft measurements from the Canadian Arctic of coating thickness as a function of black carbon core diameter and black-carbon-containing particle number fractions. We use these measurements to inform estimates of the direct radiative effect in Arctic aerosol simulations.
Chunxiang Ye, Xianliang Zhou, Dennis Pu, Jochen Stutz, James Festa, Max Spolaor, Catalina Tsai, Christopher Cantrell, Roy L. Mauldin III, Andrew Weinheimer, Rebecca S. Hornbrook, Eric C. Apel, Alex Guenther, Lisa Kaser, Bin Yuan, Thomas Karl, Julie Haggerty, Samuel Hall, Kirk Ullmann, James Smith, and John Ortega
Atmos. Chem. Phys., 18, 9107–9120, https://doi.org/10.5194/acp-18-9107-2018, https://doi.org/10.5194/acp-18-9107-2018, 2018
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Substantial levels of HONO existed during the day throughout the troposphere over the southeastern US during NOMADSS 2013. Particulate nitrate photolysis appeared to be the major volume HONO source, while NOx was an important HONO precursor only in industrial and urban plumes. HONO was not a significant OH radical precursor in the rural troposphere away from the ground surface; however, its production from particulate nitrate photolysis was an important renoxification pathway.
Jun Liu, Jeramy Dedrick, Lynn M. Russell, Gunnar I. Senum, Janek Uin, Chongai Kuang, Stephen R. Springston, W. Richard Leaitch, Allison C. Aiken, and Dan Lubin
Atmos. Chem. Phys., 18, 8571–8587, https://doi.org/10.5194/acp-18-8571-2018, https://doi.org/10.5194/acp-18-8571-2018, 2018
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Observations of the organic components of the natural aerosol are scarce in Antarctica, which limits our understanding of natural aerosols and their connection to cloud albedo. We took yearlong measurements of organic aerosols at McMurdo Station. The natural organic aerosol was 150 times higher in summer than in winter. We showed the natural sources of OM were characterized by amide, which may be from seabird populations. Acid was high in summer and likely formed by secondary reactions.
Jingbo Mao, Fangqun Yu, Yan Zhang, Jingyu An, Lin Wang, Jun Zheng, Lei Yao, Gan Luo, Weichun Ma, Qi Yu, Cheng Huang, Li Li, and Limin Chen
Atmos. Chem. Phys., 18, 7933–7950, https://doi.org/10.5194/acp-18-7933-2018, https://doi.org/10.5194/acp-18-7933-2018, 2018
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A few pptv of gaseous amines have been observed to affect particle nucleation and growth, and it is necessary to understand the sources and concentrations of atmospheric amines. This study presents the source-dependent amines to ammonia emission ratios and simulates methylamines concentrations in a polluted region in China with WRF-Chem. The performance of simulations based on source-dependent ratios is much better than those based on fixed ratios that have been assumed in all previous studies.
Jie Zhang, Sara Lance, Jeffrey M. Freedman, Yele Sun, Brian A. Crandall, Xiuli Wei, and James J. Schwab
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2018-529, https://doi.org/10.5194/acp-2018-529, 2018
Preprint retracted
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The impact of fireworks (FW) events on air quality was studied using a High-Resolution Time-of-Flight Aerosol Mass Spectrometer (HR-ToF-AMS) and collocated instruments during the Independence Day (July 4) holiday. The Independence Day FW events resulted in significant increases in both organic and inorganic (potassium, sulfate, chloride) chemical components, and the contribution from different aerosol sources was discussed.
Jie Zhang, Joseph P. Marto, and James J. Schwab
Atmos. Meas. Tech., 11, 2995–3005, https://doi.org/10.5194/amt-11-2995-2018, https://doi.org/10.5194/amt-11-2995-2018, 2018
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The performance of two kinds of optical instruments for aerosol mass measurements was explained by a Mie scattering theory. At the same time, the response of optical instruments for ambient aerosol with different size, chemical composition, and refractive index were also studied. These would help evaluate the applicability and limitations of these optical scattering instruments.
Xi Chen, Mingjie Xie, Michael D. Hays, Eric Edgerton, Donna Schwede, and John T. Walker
Atmos. Chem. Phys., 18, 6829–6846, https://doi.org/10.5194/acp-18-6829-2018, https://doi.org/10.5194/acp-18-6829-2018, 2018
Katrina M. Macdonald, Sangeeta Sharma, Desiree Toom, Alina Chivulescu, Andrew Platt, Mike Elsasser, Lin Huang, Richard Leaitch, Nathan Chellman, Joseph R. McConnell, Heiko Bozem, Daniel Kunkel, Ying Duan Lei, Cheol-Heon Jeong, Jonathan P. D. Abbatt, and Greg J. Evans
Atmos. Chem. Phys., 18, 3485–3503, https://doi.org/10.5194/acp-18-3485-2018, https://doi.org/10.5194/acp-18-3485-2018, 2018
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The sources of key contaminants in Arctic snow may be an important factor in understanding the rapid climate changes observed in the Arctic. Fresh snow samples collected frequently through the winter season were analyzed for major constituents. Temporally refined source apportionment via positive matrix factorization in conjunction with FLEXPART suggested potential source characteristics and locations. The identity of these sources and their relative contribution to key analytes is discussed.
W. Richard Leaitch, Lynn M. Russell, Jun Liu, Felicia Kolonjari, Desiree Toom, Lin Huang, Sangeeta Sharma, Alina Chivulescu, Dan Veber, and Wendy Zhang
Atmos. Chem. Phys., 18, 3269–3287, https://doi.org/10.5194/acp-18-3269-2018, https://doi.org/10.5194/acp-18-3269-2018, 2018
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Over 2 years of atmospheric aerosol organic functional group and microphysics measurements at the world's northernmost land observatory offer a unique high-latitude dataset. Lower organic mass (OM) concentrations and higher OM fractions accompany smaller particles during summer, with opposite results during winter to spring. Seasonally, the OM oxidation level is highest in winter, associated with primary marine alcohol groups. In summer, secondary processes dominate the marine influence on OM.
Nina Sarnela, Tuija Jokinen, Jonathan Duplissy, Chao Yan, Tuomo Nieminen, Mikael Ehn, Siegfried Schobesberger, Martin Heinritzi, Sebastian Ehrhart, Katrianne Lehtipalo, Jasmin Tröstl, Mario Simon, Andreas Kürten, Markus Leiminger, Michael J. Lawler, Matti P. Rissanen, Federico Bianchi, Arnaud P. Praplan, Jani Hakala, Antonio Amorim, Marc Gonin, Armin Hansel, Jasper Kirkby, Josef Dommen, Joachim Curtius, James N. Smith, Tuukka Petäjä, Douglas R. Worsnop, Markku Kulmala, Neil M. Donahue, and Mikko Sipilä
Atmos. Chem. Phys., 18, 2363–2380, https://doi.org/10.5194/acp-18-2363-2018, https://doi.org/10.5194/acp-18-2363-2018, 2018
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Atmospheric trace gases can form small molecular clusters, which can grow to larger sizes through the condensation of vapours. This process is called new particle formation. In this paper we studied the formation of sulfuric acid and highly oxygenated molecules, the key compounds in atmospheric new particle formation, in chamber experiments and introduced a way to simulate these ozonolysis products of α-pinene in a simple manner.
Lukas Pichelstorfer, Dominik Stolzenburg, John Ortega, Thomas Karl, Harri Kokkola, Anton Laakso, Kari E. J. Lehtinen, James N. Smith, Peter H. McMurry, and Paul M. Winkler
Atmos. Chem. Phys., 18, 1307–1323, https://doi.org/10.5194/acp-18-1307-2018, https://doi.org/10.5194/acp-18-1307-2018, 2018
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Quantification of new particle formation as a source of atmospheric aerosol is clearly of importance for climate and health aspects. In our new study we developed two analysis methods that allow retrieval of nanoparticle growth dynamics at much higher precision than it was possible so far. Our results clearly demonstrate that growth rates show much more variation than is currently known and suggest that the Kelvin effect governs growth in the sub-10 nm size range.
Paula Doubrawa, Alex Montornès, Rebecca J. Barthelmie, Sara C. Pryor, and Pau Casso
Wind Energ. Sci. Discuss., https://doi.org/10.5194/wes-2017-61, https://doi.org/10.5194/wes-2017-61, 2018
Preprint withdrawn
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We perform time-resolved, high-resolution simulations of the atmospheric boundary layer with a numerical weather prediction model. The downscaling is done within the model by defining nested domains, and we investigate different ways of treating turbulence modeling at intermediate spatial scales in which traditional turbulence parameterizations are inadequate. We focus on quantities of interest to wind energy and compare the simulations with measurements collected at a complex-terrain site.
Haihan Chen, Anna L. Hodshire, John Ortega, James Greenberg, Peter H. McMurry, Annmarie G. Carlton, Jeffrey R. Pierce, Dave R. Hanson, and James N. Smith
Atmos. Chem. Phys., 18, 311–326, https://doi.org/10.5194/acp-18-311-2018, https://doi.org/10.5194/acp-18-311-2018, 2018
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Much of what we know about atmospheric new particle formation (NPF) is based on ground-level measurements. We used tethered balloon measurements and remote sensing to study the location in the boundary layer in which NPF events are initiated, the degree to which the boundary layer is well-mixed during NPF, and the potential role that water may play in aerosol particle chemical evolution. This information will improve the representativeness of process level models and laboratory experiments.
Sangeeta Sharma, W. Richard Leaitch, Lin Huang, Daniel Veber, Felicia Kolonjari, Wendy Zhang, Sarah J. Hanna, Allan K. Bertram, and John A. Ogren
Atmos. Chem. Phys., 17, 15225–15243, https://doi.org/10.5194/acp-17-15225-2017, https://doi.org/10.5194/acp-17-15225-2017, 2017
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A new and unique data set on BC properties at the highest latitude observatory in the world, at Alert, Canada, evaluates three techniques for estimating black carbon (BC) and gives seasonal best estimates of the BC mass concentrations and BC mass absorption coefficients (MAC) for 2.5 years of data. As a short-lived climate forcer, better estimates of the properties of BC are necessary to ensure accurate modelling of aerosol climate forcing of the Arctic atmosphere for mitigation purposes.
Robert Wagner, Chao Yan, Katrianne Lehtipalo, Jonathan Duplissy, Tuomo Nieminen, Juha Kangasluoma, Lauri R. Ahonen, Lubna Dada, Jenni Kontkanen, Hanna E. Manninen, Antonio Dias, Antonio Amorim, Paulus S. Bauer, Anton Bergen, Anne-Kathrin Bernhammer, Federico Bianchi, Sophia Brilke, Stephany Buenrostro Mazon, Xuemeng Chen, Danielle C. Draper, Lukas Fischer, Carla Frege, Claudia Fuchs, Olga Garmash, Hamish Gordon, Jani Hakala, Liine Heikkinen, Martin Heinritzi, Victoria Hofbauer, Christopher R. Hoyle, Jasper Kirkby, Andreas Kürten, Alexander N. Kvashnin, Tiia Laurila, Michael J. Lawler, Huajun Mai, Vladimir Makhmutov, Roy L. Mauldin III, Ugo Molteni, Leonid Nichman, Wei Nie, Andrea Ojdanic, Antti Onnela, Felix Piel, Lauriane L. J. Quéléver, Matti P. Rissanen, Nina Sarnela, Simon Schallhart, Kamalika Sengupta, Mario Simon, Dominik Stolzenburg, Yuri Stozhkov, Jasmin Tröstl, Yrjö Viisanen, Alexander L. Vogel, Andrea C. Wagner, Mao Xiao, Penglin Ye, Urs Baltensperger, Joachim Curtius, Neil M. Donahue, Richard C. Flagan, Martin Gallagher, Armin Hansel, James N. Smith, António Tomé, Paul M. Winkler, Douglas Worsnop, Mikael Ehn, Mikko Sipilä, Veli-Matti Kerminen, Tuukka Petäjä, and Markku Kulmala
Atmos. Chem. Phys., 17, 15181–15197, https://doi.org/10.5194/acp-17-15181-2017, https://doi.org/10.5194/acp-17-15181-2017, 2017
Sara C. Pryor, Ryan C. Sullivan, and Justin T. Schoof
Atmos. Chem. Phys., 17, 14457–14471, https://doi.org/10.5194/acp-17-14457-2017, https://doi.org/10.5194/acp-17-14457-2017, 2017
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The air temperature and water vapor content are increasing globally due to the increased concentration of "heat-trapping" (greenhouse) gases. But not all regions are warming at the same rate. This analysis is designed to improve understanding of the causes of recent trends and year-to-year variability in summertime heat indices over the eastern US and to present a new model that can be used to make projections of future events that may cause loss of life and/or decreased human well-being.
Franziska Köllner, Johannes Schneider, Megan D. Willis, Thomas Klimach, Frank Helleis, Heiko Bozem, Daniel Kunkel, Peter Hoor, Julia Burkart, W. Richard Leaitch, Amir A. Aliabadi, Jonathan P. D. Abbatt, Andreas B. Herber, and Stephan Borrmann
Atmos. Chem. Phys., 17, 13747–13766, https://doi.org/10.5194/acp-17-13747-2017, https://doi.org/10.5194/acp-17-13747-2017, 2017
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We conducted aircraft-based single particle chemical composition measurements in the Canadian high Arctic during summer. Our results provide evidence for a marine-biogenic influence on secondary formation of particulate trimethylamine in the Arctic boundary layer. Understanding emission sources and further processes controlling aerosol number concentration and chemical composition in the pristine Arctic summer is crucial for modeling future climate in the area.
Robert C. Rhew, Malte Julian Deventer, Andrew A. Turnipseed, Carsten Warneke, John Ortega, Steve Shen, Luis Martinez, Abigail Koss, Brian M. Lerner, Jessica B. Gilman, James N. Smith, Alex B. Guenther, and Joost A. de Gouw
Atmos. Chem. Phys., 17, 13417–13438, https://doi.org/10.5194/acp-17-13417-2017, https://doi.org/10.5194/acp-17-13417-2017, 2017
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Alkenes emanate from both natural and anthropogenic sources and can contribute to atmospheric ozone production. This study measured
lightalkene (ethene, propene and butene) fluxes from a ponderosa pine forest using a novel relaxed eddy accumulation method, revealing much larger emissions than previously estimated and accounting for a significant fraction of OH reactivity. Emissions have a diurnal cycle related to sunlight and temperature, and the forest canopy appears to be the source.
Xi Chen, John T. Walker, and Chris Geron
Atmos. Meas. Tech., 10, 3893–3908, https://doi.org/10.5194/amt-10-3893-2017, https://doi.org/10.5194/amt-10-3893-2017, 2017
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The MARGA instrument is a powerful research tool for investigating atmospheric chemistry and the exchange of gases and particles between the atmosphere and biosphere. Our study examines the operating characteristics of the instrument with a focus on the software used to calculate air concentrations. We show that more accurate measurements may be obtained by calibrating the instrument with a range of standards in addition to the single internal standard used in online concentration calculations.
Maria Sand, Bjørn H. Samset, Yves Balkanski, Susanne Bauer, Nicolas Bellouin, Terje K. Berntsen, Huisheng Bian, Mian Chin, Thomas Diehl, Richard Easter, Steven J. Ghan, Trond Iversen, Alf Kirkevåg, Jean-François Lamarque, Guangxing Lin, Xiaohong Liu, Gan Luo, Gunnar Myhre, Twan van Noije, Joyce E. Penner, Michael Schulz, Øyvind Seland, Ragnhild B. Skeie, Philip Stier, Toshihiko Takemura, Kostas Tsigaridis, Fangqun Yu, Kai Zhang, and Hua Zhang
Atmos. Chem. Phys., 17, 12197–12218, https://doi.org/10.5194/acp-17-12197-2017, https://doi.org/10.5194/acp-17-12197-2017, 2017
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The role of aerosols in the changing polar climate is not well understood and the aerosols are poorly constrained in the models. In this study we have compared output from 16 different aerosol models with available observations at both poles. We show that the model median is representative of the observations, but the model spread is large. The Arctic direct aerosol radiative effect over the industrial area is positive during spring due to black carbon and negative during summer due to sulfate.
K. Max Zhang, George Allen, Bo Yang, Geng Chen, Jiajun Gu, James Schwab, Dirk Felton, and Oliver Rattigan
Atmos. Chem. Phys., 17, 11441–11452, https://doi.org/10.5194/acp-17-11441-2017, https://doi.org/10.5194/acp-17-11441-2017, 2017
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Woodsmoke is a worldwide public health concern. A reliable marker for woodsmoke will be very useful in air-quality management. DC (Delta-C) has been proposed as a woodsmoke marker in previous studies. However, several researchers raised concerns of whether it is reliable. Our study took advantage of aerosol light absorption and PM2.5 data collected at three US cities/towns dominated by woodsmoke. We showed that DC can be a good qualitative and semi-quantitive marker, but with limitations.
Roya Ghahreman, Ann-Lise Norman, Betty Croft, Randall V. Martin, Jeffrey R. Pierce, Julia Burkart, Ofelia Rempillo, Heiko Bozem, Daniel Kunkel, Jennie L. Thomas, Amir A. Aliabadi, Gregory R. Wentworth, Maurice Levasseur, Ralf M. Staebler, Sangeeta Sharma, and W. Richard Leaitch
Atmos. Chem. Phys., 17, 8757–8770, https://doi.org/10.5194/acp-17-8757-2017, https://doi.org/10.5194/acp-17-8757-2017, 2017
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We present spring and summertime vertical profile measurements of Arctic dimethyl sulfide (DMS), together with model simulations to consider what these profiles indicate about DMS sources and lifetimes in the Arctic. Our results highlight the role of local open water as the source of DMS(g) during July 2014 and the influence of long-range transport of DMS(g) from further afield in the Arctic during April 2015.
Julia Burkart, Megan D. Willis, Heiko Bozem, Jennie L. Thomas, Kathy Law, Peter Hoor, Amir A. Aliabadi, Franziska Köllner, Johannes Schneider, Andreas Herber, Jonathan P. D. Abbatt, and W. Richard Leaitch
Atmos. Chem. Phys., 17, 5515–5535, https://doi.org/10.5194/acp-17-5515-2017, https://doi.org/10.5194/acp-17-5515-2017, 2017
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Our aircraft study for the first time systematically investigates aerosol size distributions, including ultrafine particles (5–20 nm in diameter), in the Arctic summertime atmosphere. We find that ultrafine particles occur very frequently in the boundary layer and not aloft, suggesting a surface source of these particles. Understanding aerosol properties and sources is crucial to predict climate and especially important in the Arctic as this region responds extremely fast to climate change.
Fangqun Yu, Gan Luo, Alexey B. Nadykto, and Jason Herb
Atmos. Chem. Phys., 17, 4997–5005, https://doi.org/10.5194/acp-17-4997-2017, https://doi.org/10.5194/acp-17-4997-2017, 2017
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H2SO4–organics clustering thermodynamics from quantum studies has been employed to develop a scheme to include temperature dependence in an H2SO4–organics nucleation parameterization. We show that temperature has a strong impact on nucleation rates, particle number concentrations, and aerosol first indirect radiative forcing in summer. To our knowledge, the study represents the first attempt to study the temperature effect on organics-mediated nucleation in the global atmosphere.
Andrew D. Teakles, Rita So, Bruce Ainslie, Robert Nissen, Corinne Schiller, Roxanne Vingarzan, Ian McKendry, Anne Marie Macdonald, Daniel A. Jaffe, Allan K. Bertram, Kevin B. Strawbridge, W. Richard Leaitch, Sarah Hanna, Desiree Toom, Jonathan Baik, and Lin Huang
Atmos. Chem. Phys., 17, 2593–2611, https://doi.org/10.5194/acp-17-2593-2017, https://doi.org/10.5194/acp-17-2593-2017, 2017
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We present a case study of an intense wildfire smoke plume from Siberia that affected the air quality across the Pacific Northwest on 6–10 July 2012. The transport, entrainment, and chemical composition of the plume are examined to characterize the event. Ambient O3 and PM2.5 from surface monitoring is contrast to modelled baseline air quality estimates to show the overall contribution of the plume to exceedances in O3 and PM2.5 air quality standards and objectives that occurred.
Nathan F. Taylor, Don R. Collins, Douglas H. Lowenthal, Ian B. McCubbin, A. Gannet Hallar, Vera Samburova, Barbara Zielinska, Naresh Kumar, and Lynn R. Mazzoleni
Atmos. Chem. Phys., 17, 2555–2571, https://doi.org/10.5194/acp-17-2555-2017, https://doi.org/10.5194/acp-17-2555-2017, 2017
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The impacts of aerosols on health, visibility, and climate are very sensitive to their ability to take up water under subsaturated conditions and to serve as cloud condensation nuclei. These hydration properties are tightly linked to aerosol composition. This report finds that water soluble organic compounds contribute significantly to atmospheric aerosol hydration both as an independent fraction of aerosol mass and through complementary interactions with common inorganic aerosol constituents.
Jenni Kontkanen, Katrianne Lehtipalo, Lauri Ahonen, Juha Kangasluoma, Hanna E. Manninen, Jani Hakala, Clémence Rose, Karine Sellegri, Shan Xiao, Lin Wang, Ximeng Qi, Wei Nie, Aijun Ding, Huan Yu, Shanhu Lee, Veli-Matti Kerminen, Tuukka Petäjä, and Markku Kulmala
Atmos. Chem. Phys., 17, 2163–2187, https://doi.org/10.5194/acp-17-2163-2017, https://doi.org/10.5194/acp-17-2163-2017, 2017
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The concentrations of ~1–3 nm particles were investigated at nine sites around the world. Sub-3 nm particle concentrations were highest at the sites with strong anthropogenic influence. Electrically neutral particles dominated sub-3 nm particle concentrations in polluted environments and in boreal forest during spring and summer. Sub-3 nm particle concentrations were observed to be determined by the availability of precursor vapors rather than the sink caused by preexisting aerosol particles.
Paola Crippa, Ryan C. Sullivan, Abhinav Thota, and Sara C. Pryor
Atmos. Chem. Phys., 17, 1511–1528, https://doi.org/10.5194/acp-17-1511-2017, https://doi.org/10.5194/acp-17-1511-2017, 2017
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Here we quantify WRF-CHEM sensitivity in simulating meteorological, chemical and aerosol properties as a function of spatial resolution.
We demonstrate that WRF-Chem at high resolution improves model performance of meteorological and gas-phase parameters and of mean and extreme aerosol properties over North America. A dry bias in specific humidity and precipitation in the coarse simulations is identified as cause of the better performance of the high-resolution simulations.
Quentin Libois, Liviu Ivanescu, Jean-Pierre Blanchet, Hannes Schulz, Heiko Bozem, W. Richard Leaitch, Julia Burkart, Jonathan P. D. Abbatt, Andreas B. Herber, Amir A. Aliabadi, and Éric Girard
Atmos. Chem. Phys., 16, 15689–15707, https://doi.org/10.5194/acp-16-15689-2016, https://doi.org/10.5194/acp-16-15689-2016, 2016
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The first airborne measurements performed with the FIRR are presented. Vertical profiles of upwelling spectral radiance in the far-infrared are measured in the Arctic atmosphere for the first time. They show the impact of the temperature inversion on the radiative budget of the atmosphere, especially in the far-infrared. The presence of ice clouds also significantly alters the far-infrared budget, highlighting the critical interplay between water vapour and clouds in this very dry region.
Michael J. Lawler, Paul M. Winkler, Jaeseok Kim, Lars Ahlm, Jasmin Tröstl, Arnaud P. Praplan, Siegfried Schobesberger, Andreas Kürten, Jasper Kirkby, Federico Bianchi, Jonathan Duplissy, Armin Hansel, Tuija Jokinen, Helmi Keskinen, Katrianne Lehtipalo, Markus Leiminger, Tuukka Petäjä, Matti Rissanen, Linda Rondo, Mario Simon, Mikko Sipilä, Christina Williamson, Daniela Wimmer, Ilona Riipinen, Annele Virtanen, and James N. Smith
Atmos. Chem. Phys., 16, 13601–13618, https://doi.org/10.5194/acp-16-13601-2016, https://doi.org/10.5194/acp-16-13601-2016, 2016
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We present chemical observations of newly formed particles as small as ~ 10 nm from new particle formation experiments using sulfuric acid, dimethylamine, ammonia, and water vapor as gas phase reactants. The nanoparticles were more acidic than expected based on thermodynamic expectations, particularly at the smallest measured sizes. The results suggest rapid surface conversion of SO2 to sulfate and show a marked composition change between 10 and 15 nm, possibly indicating a phase change.
Ivan Kourtchev, Ricardo H. M. Godoi, Sarah Connors, James G. Levine, Alex T. Archibald, Ana F. L. Godoi, Sarah L. Paralovo, Cybelli G. G. Barbosa, Rodrigo A. F. Souza, Antonio O. Manzi, Roger Seco, Steve Sjostedt, Jeong-Hoo Park, Alex Guenther, Saewung Kim, James Smith, Scot T. Martin, and Markus Kalberer
Atmos. Chem. Phys., 16, 11899–11913, https://doi.org/10.5194/acp-16-11899-2016, https://doi.org/10.5194/acp-16-11899-2016, 2016
W. Richard Leaitch, Alexei Korolev, Amir A. Aliabadi, Julia Burkart, Megan D. Willis, Jonathan P. D. Abbatt, Heiko Bozem, Peter Hoor, Franziska Köllner, Johannes Schneider, Andreas Herber, Christian Konrad, and Ralf Brauner
Atmos. Chem. Phys., 16, 11107–11124, https://doi.org/10.5194/acp-16-11107-2016, https://doi.org/10.5194/acp-16-11107-2016, 2016
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Thought to be mostly unimportant for summertime Arctic liquid-water clouds, airborne observations show that atmospheric aerosol particles 50 nm in diameter or smaller and most likely from natural sources are often involved in cloud formation in the pristine Arctic summer. The result expands the reference for aerosol forcing of climate. Further, for extremely low droplet concentrations, no evidence is found for a connection between cloud liquid water and aerosol particle concentrations.
H. Wang, R. J. Barthelmie, P. Doubrawa, and S. C. Pryor
Atmos. Meas. Tech., 9, 4123–4139, https://doi.org/10.5194/amt-9-4123-2016, https://doi.org/10.5194/amt-9-4123-2016, 2016
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This paper investigates how long a sampling duration of lidar measurements should be in order to accurately estimate radial velocity variance to obtain turbulence statistics. Using observations and statistical simulations, it is demonstrated that large probe volumes in lidar measurements increase the autocorrelation values, and consequently the uncertainty in radial velocity variance estimates. It is further shown that the random error can exceed 10 % for 30–60 min sampling duration.
Anna L. Hodshire, Michael J. Lawler, Jun Zhao, John Ortega, Coty Jen, Taina Yli-Juuti, Jared F. Brewer, Jack K. Kodros, Kelley C. Barsanti, Dave R. Hanson, Peter H. McMurry, James N. Smith, and Jeffery R. Pierce
Atmos. Chem. Phys., 16, 9321–9348, https://doi.org/10.5194/acp-16-9321-2016, https://doi.org/10.5194/acp-16-9321-2016, 2016
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Processes that control the growth of newly formed particles are not well understood and limit predictions of aerosol climate impacts. We combine state-of-the-art measurements at a central-US site with a particle-growth model to investigate the species and processes contributing to growth. Observed growth was dominated by organics, sulfate salts, or a mixture of these two. The model qualitatively captures the variability between different days.
Amir A. Aliabadi, Jennie L. Thomas, Andreas B. Herber, Ralf M. Staebler, W. Richard Leaitch, Hannes Schulz, Kathy S. Law, Louis Marelle, Julia Burkart, Megan D. Willis, Heiko Bozem, Peter M. Hoor, Franziska Köllner, Johannes Schneider, Maurice Levasseur, and Jonathan P. D. Abbatt
Atmos. Chem. Phys., 16, 7899–7916, https://doi.org/10.5194/acp-16-7899-2016, https://doi.org/10.5194/acp-16-7899-2016, 2016
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For the first time, ship emissions of an ice-breaker, the Amundsen, is characterized while breaking ice in the Canadian Arctic using the plume intercepts by the Polar 6 aircraft. The study is novel, estimating lower plume expansion rates over the stable Arctic marine boundary layer and different emissions factors for oxides of nitrogen, black carbon, and carbon monoxide, compared to plume intercept studies in mid latitudes. These results can inform policy making and emission inventory datasets.
Ian C. Rumsey and John T. Walker
Atmos. Meas. Tech., 9, 2581–2592, https://doi.org/10.5194/amt-9-2581-2016, https://doi.org/10.5194/amt-9-2581-2016, 2016
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The performance of the MARGA (Monitor of AeRosols and GAses in ambient air) instrument in measuring speciated nitrogen and sulfur fluxes is evaluated for the first time. The results demonstrate that the MARGA instrument can be used to make accurate measurements of speciated nitrogen and sulfur deposition. These measurements are urgently needed to evaluate chemical transport models and develop risk assessments and mitigation strategies to protect ecosystems from nutrient and acidic deposition.
Alex K. Y. Lee, Jonathan P. D. Abbatt, W. Richard Leaitch, Shao-Meng Li, Steve J. Sjostedt, Jeremy J. B. Wentzell, John Liggio, and Anne Marie Macdonald
Atmos. Chem. Phys., 16, 6721–6733, https://doi.org/10.5194/acp-16-6721-2016, https://doi.org/10.5194/acp-16-6721-2016, 2016
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Substantial biogenic secondary organic aerosol (BSOA) formation was investigated in a coniferous forest mountain region in Whistler, British Columbia. A largely biogenic aerosol growth episode was observed, providing a unique opportunity to investigate BSOA formation chemistry in a forested environment. In particular, our observations provide insights into the relative importance of different oxidation mechanisms between day and night.
S. T. Martin, P. Artaxo, L. A. T. Machado, A. O. Manzi, R. A. F. Souza, C. Schumacher, J. Wang, M. O. Andreae, H. M. J. Barbosa, J. Fan, G. Fisch, A. H. Goldstein, A. Guenther, J. L. Jimenez, U. Pöschl, M. A. Silva Dias, J. N. Smith, and M. Wendisch
Atmos. Chem. Phys., 16, 4785–4797, https://doi.org/10.5194/acp-16-4785-2016, https://doi.org/10.5194/acp-16-4785-2016, 2016
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The Observations and Modeling of the Green Ocean Amazon (GoAmazon2014/5) Experiment took place in central Amazonia throughout 2014 and 2015. The experiment focused on the complex links among vegetation, atmospheric chemistry, and aerosol production on the one hand and their connections to aerosols, clouds, and precipitation on the other, especially when altered by urban pollution. This article serves as an introduction to the special issue of publications presenting findings of this experiment.
Hui Wang, Rebecca J. Barthelmie, Sara C. Pryor, and Gareth. Brown
Atmos. Meas. Tech., 9, 1653–1669, https://doi.org/10.5194/amt-9-1653-2016, https://doi.org/10.5194/amt-9-1653-2016, 2016
Betty Croft, Randall V. Martin, W. Richard Leaitch, Peter Tunved, Thomas J. Breider, Stephen D. D'Andrea, and Jeffrey R. Pierce
Atmos. Chem. Phys., 16, 3665–3682, https://doi.org/10.5194/acp-16-3665-2016, https://doi.org/10.5194/acp-16-3665-2016, 2016
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Measurements at high-Arctic sites show a strong annual cycle in atmospheric particle number and size. Previous studies identified poor scientific understanding related to global model representation of Arctic particle number and size, limiting ability to simulate this environment. Here we evaluate state-of-science ability to simulate Arctic particles using GEOS-Chem-TOMAS model, documenting key roles and interconnections of particle formation, cloud-related processes and remaining uncertainties.
S. Gagné, L. P. MacDonald, W. R. Leaitch, and J. R. Pierce
Atmos. Meas. Tech., 9, 619–630, https://doi.org/10.5194/amt-9-619-2016, https://doi.org/10.5194/amt-9-619-2016, 2016
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Measurements of clouds with an aircraft are essential to understand how clouds form and how they affect the Earth's climate. These measurements are used in climate models to help predict how our climate might develop in the next century. Aircraft measurements are, however, difficult for modellers to interpret because the way they were acquired and analyzed varies from one team of scientists to the next. We present a software platform for scientists to share and compare their analysis tools.
R. H. Mason, M. Si, C. Chou, V. E. Irish, R. Dickie, P. Elizondo, R. Wong, M. Brintnell, M. Elsasser, W. M. Lassar, K. M. Pierce, W. R. Leaitch, A. M. MacDonald, A. Platt, D. Toom-Sauntry, R. Sarda-Estève, C. L. Schiller, K. J. Suski, T. C. J. Hill, J. P. D. Abbatt, J. A. Huffman, P. J. DeMott, and A. K. Bertram
Atmos. Chem. Phys., 16, 1637–1651, https://doi.org/10.5194/acp-16-1637-2016, https://doi.org/10.5194/acp-16-1637-2016, 2016
J. Kim, L. Ahlm, T. Yli-Juuti, M. Lawler, H. Keskinen, J. Tröstl, S. Schobesberger, J. Duplissy, A. Amorim, F. Bianchi, N. M. Donahue, R. C. Flagan, J. Hakala, M. Heinritzi, T. Jokinen, A. Kürten, A. Laaksonen, K. Lehtipalo, P. Miettinen, T. Petäjä, M. P. Rissanen, L. Rondo, K. Sengupta, M. Simon, A. Tomé, C. Williamson, D. Wimmer, P. M. Winkler, S. Ehrhart, P. Ye, J. Kirkby, J. Curtius, U. Baltensperger, M. Kulmala, K. E. J. Lehtinen, J. N. Smith, I. Riipinen, and A. Virtanen
Atmos. Chem. Phys., 16, 293–304, https://doi.org/10.5194/acp-16-293-2016, https://doi.org/10.5194/acp-16-293-2016, 2016
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The hygroscopicity of nucleated nanoparticles was measured in the presence of sulfuric acid, sulfuric acid-dimethylamine, and sulfuric acid-organics derived from α-pinene oxidation during CLOUD7 at CERN in 2012. The hygroscopicity parameter κ decreased with increasing particle size, indicating decreasing acidity of particles.
S. D. D'Andrea, J. Y. Ng, J. K. Kodros, S. A. Atwood, M. J. Wheeler, A. M. Macdonald, W. R. Leaitch, and J. R. Pierce
Atmos. Chem. Phys., 16, 383–396, https://doi.org/10.5194/acp-16-383-2016, https://doi.org/10.5194/acp-16-383-2016, 2016
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We evaluate aerosol size distributions predicted by GEOS-Chem-TOMAS using measurements from the peak of Whistler Mountain. We improve model-measurement comparisons of aerosol number, size, and composition during periods of free-tropospheric and boundary-layer influence by developing simple filtering techniques, and determine the influence of Asian anthropogenic and biomass burning emissions. The low-cost filtering techniques and source apportionment methods can be used for other mountain sites.
P. Crippa, R. C. Sullivan, A. Thota, and S. C. Pryor
Atmos. Chem. Phys., 16, 397–416, https://doi.org/10.5194/acp-16-397-2016, https://doi.org/10.5194/acp-16-397-2016, 2016
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We evaluate the performance of high-resolution simulations of the Weather Research and Forecasting model coupled with Chemistry in capturing spatiotemporal variability of aerosol optical properties by comparison with ground- and space- based remote-sensing observations and investigate causes of model biases. This work contributes to assessing the model's ability to describe drivers of aerosol direct radiative forcing in the contemporary climate and to improving confidence in future projections.
A. G. Hallar, R. Petersen, E. Andrews, J. Michalsky, I. B. McCubbin, and J. A. Ogren
Atmos. Chem. Phys., 15, 13665–13679, https://doi.org/10.5194/acp-15-13665-2015, https://doi.org/10.5194/acp-15-13665-2015, 2015
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The atmospheric seasonal impact of dust and biomass burning is considered for the western United States from 1999 to 2014. Median contributions to spring and summer aerosol optical depth (AOD) from dust and biomass-burning aerosols are comparable, with more frequent and short duration high AOD measurements due to biomass-burning episodes in summer than in spring. This data set highlights the wide scale implications of a warmer, drier climate on visibility in the western US.
R. H. Mason, M. Si, J. Li, C. Chou, R. Dickie, D. Toom-Sauntry, C. Pöhlker, J. D. Yakobi-Hancock, L. A. Ladino, K. Jones, W. R. Leaitch, C. L. Schiller, J. P. D. Abbatt, J. A. Huffman, and A. K. Bertram
Atmos. Chem. Phys., 15, 12547–12566, https://doi.org/10.5194/acp-15-12547-2015, https://doi.org/10.5194/acp-15-12547-2015, 2015
Y. Zhou, H. Mao, K. Demerjian, C. Hogrefe, and J. Liu
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acpd-15-27253-2015, https://doi.org/10.5194/acpd-15-27253-2015, 2015
Revised manuscript not accepted
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Baseline carbon monoxide (CO) and ozone (O3) were studied at seven rural sites in the Northeast U.S. during varying periods over 2001 – 2010. Baseline CO at all sites decreased significantly at a rate between -4.3 – -2.3 ppbv yr-1, while baseline O3 was relatively constant. Interannual and seasonal variations of baseline CO and O3 were related to increasing Asian emissions, NOx emissions reduction in urban areas, global biomass burning emissions, and meteorological conditions.
L. Zhou, R. Gierens, A. Sogachev, D. Mogensen, J. Ortega, J. N. Smith, P. C. Harley, A. J. Prenni, E. J. T. Levin, A. Turnipseed, A. Rusanen, S. Smolander, A. B. Guenther, M. Kulmala, T. Karl, and M. Boy
Atmos. Chem. Phys., 15, 8643–8656, https://doi.org/10.5194/acp-15-8643-2015, https://doi.org/10.5194/acp-15-8643-2015, 2015
H. Guo, L. Xu, A. Bougiatioti, K. M. Cerully, S. L. Capps, J. R. Hite Jr., A. G. Carlton, S.-H. Lee, M. H. Bergin, N. L. Ng, A. Nenes, and R. J. Weber
Atmos. Chem. Phys., 15, 5211–5228, https://doi.org/10.5194/acp-15-5211-2015, https://doi.org/10.5194/acp-15-5211-2015, 2015
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Particle pH can affect many aerosol processes, including gas-particle partitioning, SOA formation, and mobilization of toxic redox metals. pH is challenging to directly measure and often improperly characterized by proxies like ion balances or molar ratios of measured aerosol ionic species. We present a detailed analysis predicting pH with a thermodynamic model, verify the prediction, and test pH sensitivity to model inputs based on data from the SOAS field campaign.
J. C. Schroder, S. J. Hanna, R. L. Modini, A. L. Corrigan, S. M. Kreidenwies, A. M. Macdonald, K. J. Noone, L. M. Russell, W. R. Leaitch, and A. K. Bertram
Atmos. Chem. Phys., 15, 1367–1383, https://doi.org/10.5194/acp-15-1367-2015, https://doi.org/10.5194/acp-15-1367-2015, 2015
B. B. Almand-Hunter, J. T. Walker, N. P. Masson, L. Hafford, and M. P. Hannigan
Atmos. Meas. Tech., 8, 267–280, https://doi.org/10.5194/amt-8-267-2015, https://doi.org/10.5194/amt-8-267-2015, 2015
L. Q. Hao, A. Kortelainen, S. Romakkaniemi, H. Portin, A. Jaatinen, A. Leskinen, M. Komppula, P. Miettinen, D. Sueper, A. Pajunoja, J. N. Smith, K. E. J. Lehtinen, D. R. Worsnop, A. Laaksonen, and A. Virtanen
Atmos. Chem. Phys., 14, 13483–13495, https://doi.org/10.5194/acp-14-13483-2014, https://doi.org/10.5194/acp-14-13483-2014, 2014
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Positive matrix factorization (PMF) was applied to the unified high-resolution mass spectra organic species with NO+ and NO2+ ions from the measurement in a mixed region between the boreal forestland and the urban area. The PMF analysis succeeded in separating the mixed spectra into three distinct organic factors and one inorganic factor. The particulate organic nitrate was distinguished by PMF for the first time, with a contribution of one-third of the total nitrate mass.
F. Yu and G. Luo
Atmos. Chem. Phys., 14, 12455–12464, https://doi.org/10.5194/acp-14-12455-2014, https://doi.org/10.5194/acp-14-12455-2014, 2014
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Global lifetimes and concentrations of gaseous methylamines (MMA, DMA, and TMA) have been simulated.
Oxidation and aerosol uptakes are dominant sinks for these methylamines. The oxidation alone leads to their lifetimes of 5-10h in most parts of low and middle latitude regions. The uptake by secondary species can shorten their lifetime to as low as 1-2h over central Europe, eastern Asia, and the eastern US.
The modeled concentrations are substantially lower than observed values available.
J. D. Yakobi-Hancock, L. A. Ladino, A. K. Bertram, J. A. Huffman, K. Jones, W. R. Leaitch, R. H. Mason, C. L. Schiller, D. Toom-Sauntry, J. P. S. Wong, and J. P. D. Abbatt
Atmos. Chem. Phys., 14, 12307–12317, https://doi.org/10.5194/acp-14-12307-2014, https://doi.org/10.5194/acp-14-12307-2014, 2014
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As one aspect of the NETwork on Climate and Aerosols: addressing key uncertainties in Remote Canadian Environments, measurements of the cloud condensation nucleation properties of 50 nm and 100 nm aerosol particles were conducted at Ucluelet on the west coast of Vancouver Island in August 2013. The most efficient cloud condensation nuclei arose when the organic to sulfate ratio of the aerosol was lowest and when winds arrived from the west after transport through the marine boundary layer.
Y. You, V. P. Kanawade, J. A. de Gouw, A. B. Guenther, S. Madronich, M. R. Sierra-Hernández, M. Lawler, J. N. Smith, S. Takahama, G. Ruggeri, A. Koss, K. Olson, K. Baumann, R. J. Weber, A. Nenes, H. Guo, E. S. Edgerton, L. Porcelli, W. H. Brune, A. H. Goldstein, and S.-H. Lee
Atmos. Chem. Phys., 14, 12181–12194, https://doi.org/10.5194/acp-14-12181-2014, https://doi.org/10.5194/acp-14-12181-2014, 2014
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Amiens play important roles in atmospheric secondary aerosol formation and human health, but the fast response measurements of amines are lacking. Here we show measurements in a southeastern US forest and a moderately polluted midwestern site. Our results show that gas to particle conversion is an important process that controls ambient amine concentrations and that biomass burning is an important source of amines.
S. C. Pryor, K. E. Hornsby, and K. A. Novick
Atmos. Chem. Phys., 14, 11985–11996, https://doi.org/10.5194/acp-14-11985-2014, https://doi.org/10.5194/acp-14-11985-2014, 2014
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What role do forests play in determining the concentration (and composition) of climate-relevant aerosol particles? This study seeks to address two aspects of this question. Firstly, we document high in-canopy removal of recently formed particles. Then we show evidence that growth rates of particles are a function of soil water availability via a reduction in canopy emissions of gases responsible for particle growth to climate-relevant sizes during drought conditions.
M. J. Lawler, J. Whitehead, C. O'Dowd, C. Monahan, G. McFiggans, and J. N. Smith
Atmos. Chem. Phys., 14, 11557–11569, https://doi.org/10.5194/acp-14-11557-2014, https://doi.org/10.5194/acp-14-11557-2014, 2014
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This work describes the chemical and physical characterization of very small (< 100 nm diameter) particles in the marine atmosphere. We show that sea salt is present even at very small sizes and present evidence that organic species are important contributors to apparent new particle formation events over the ocean.
Y. Y. Cui, A. Hodzic, J. N. Smith, J. Ortega, J. Brioude, H. Matsui, E. J. T. Levin, A. Turnipseed, P. Winkler, and B. de Foy
Atmos. Chem. Phys., 14, 11011–11029, https://doi.org/10.5194/acp-14-11011-2014, https://doi.org/10.5194/acp-14-11011-2014, 2014
J. R. Pierce, D. M. Westervelt, S. A. Atwood, E. A. Barnes, and W. R. Leaitch
Atmos. Chem. Phys., 14, 8647–8663, https://doi.org/10.5194/acp-14-8647-2014, https://doi.org/10.5194/acp-14-8647-2014, 2014
J. Ortega, A. Turnipseed, A. B. Guenther, T. G. Karl, D. A. Day, D. Gochis, J. A. Huffman, A. J. Prenni, E. J. T. Levin, S. M. Kreidenweis, P. J. DeMott, Y. Tobo, E. G. Patton, A. Hodzic, Y. Y. Cui, P. C. Harley, R. S. Hornbrook, E. C. Apel, R. K. Monson, A. S. D. Eller, J. P. Greenberg, M. C. Barth, P. Campuzano-Jost, B. B. Palm, J. L. Jimenez, A. C. Aiken, M. K. Dubey, C. Geron, J. Offenberg, M. G. Ryan, P. J. Fornwalt, S. C. Pryor, F. N. Keutsch, J. P. DiGangi, A. W. H. Chan, A. H. Goldstein, G. M. Wolfe, S. Kim, L. Kaser, R. Schnitzhofer, A. Hansel, C. A. Cantrell, R. L. Mauldin, and J. N. Smith
Atmos. Chem. Phys., 14, 6345–6367, https://doi.org/10.5194/acp-14-6345-2014, https://doi.org/10.5194/acp-14-6345-2014, 2014
I. C. Rumsey, K. A. Cowen, J. T. Walker, T. J. Kelly, E. A. Hanft, K. Mishoe, C. Rogers, R. Proost, G. M. Beachley, G. Lear, T. Frelink, and R. P. Otjes
Atmos. Chem. Phys., 14, 5639–5658, https://doi.org/10.5194/acp-14-5639-2014, https://doi.org/10.5194/acp-14-5639-2014, 2014
G. W. Mann, K. S. Carslaw, C. L. Reddington, K. J. Pringle, M. Schulz, A. Asmi, D. V. Spracklen, D. A. Ridley, M. T. Woodhouse, L. A. Lee, K. Zhang, S. J. Ghan, R. C. Easter, X. Liu, P. Stier, Y. H. Lee, P. J. Adams, H. Tost, J. Lelieveld, S. E. Bauer, K. Tsigaridis, T. P. C. van Noije, A. Strunk, E. Vignati, N. Bellouin, M. Dalvi, C. E. Johnson, T. Bergman, H. Kokkola, K. von Salzen, F. Yu, G. Luo, A. Petzold, J. Heintzenberg, A. Clarke, J. A. Ogren, J. Gras, U. Baltensperger, U. Kaminski, S. G. Jennings, C. D. O'Dowd, R. M. Harrison, D. C. S. Beddows, M. Kulmala, Y. Viisanen, V. Ulevicius, N. Mihalopoulos, V. Zdimal, M. Fiebig, H.-C. Hansson, E. Swietlicki, and J. S. Henzing
Atmos. Chem. Phys., 14, 4679–4713, https://doi.org/10.5194/acp-14-4679-2014, https://doi.org/10.5194/acp-14-4679-2014, 2014
E. J. T. Levin, A. J. Prenni, B. B. Palm, D. A. Day, P. Campuzano-Jost, P. M. Winkler, S. M. Kreidenweis, P. J. DeMott, J. L. Jimenez, and J. N. Smith
Atmos. Chem. Phys., 14, 2657–2667, https://doi.org/10.5194/acp-14-2657-2014, https://doi.org/10.5194/acp-14-2657-2014, 2014
A. Steffen, J. Bottenheim, A. Cole, R. Ebinghaus, G. Lawson, and W. R. Leaitch
Atmos. Chem. Phys., 14, 2219–2231, https://doi.org/10.5194/acp-14-2219-2014, https://doi.org/10.5194/acp-14-2219-2014, 2014
Y. Zhao, A. G. Hallar, and L. R. Mazzoleni
Atmos. Chem. Phys., 13, 12343–12362, https://doi.org/10.5194/acp-13-12343-2013, https://doi.org/10.5194/acp-13-12343-2013, 2013
B. Friedman, A. Zelenyuk, J. Beranek, G. Kulkarni, M. Pekour, A. Gannet Hallar, I. B. McCubbin, J. A. Thornton, and D. J Cziczo
Atmos. Chem. Phys., 13, 11839–11851, https://doi.org/10.5194/acp-13-11839-2013, https://doi.org/10.5194/acp-13-11839-2013, 2013
S. D. D'Andrea, S. A. K. Häkkinen, D. M. Westervelt, C. Kuang, E. J. T. Levin, V. P. Kanawade, W. R. Leaitch, D. V. Spracklen, I. Riipinen, and J. R. Pierce
Atmos. Chem. Phys., 13, 11519–11534, https://doi.org/10.5194/acp-13-11519-2013, https://doi.org/10.5194/acp-13-11519-2013, 2013
M. R. Pennington, B. R. Bzdek, J. W. DePalma, J. N. Smith, A.-M. Kortelainen, L. Hildebrandt Ruiz, T. Petäjä, M. Kulmala, D. R. Worsnop, and M. V. Johnston
Atmos. Chem. Phys., 13, 10215–10225, https://doi.org/10.5194/acp-13-10215-2013, https://doi.org/10.5194/acp-13-10215-2013, 2013
X. Ma, K. Bartlett, K. Harmon, and F. Yu
Atmos. Meas. Tech., 6, 2391–2401, https://doi.org/10.5194/amt-6-2391-2013, https://doi.org/10.5194/amt-6-2391-2013, 2013
J. Zhao, J. Ortega, M. Chen, P. H. McMurry, and J. N. Smith
Atmos. Chem. Phys., 13, 7631–7644, https://doi.org/10.5194/acp-13-7631-2013, https://doi.org/10.5194/acp-13-7631-2013, 2013
M. D. Gibson, J. R. Pierce, D. Waugh, J. S. Kuchta, L. Chisholm, T. J. Duck, J. T. Hopper, S. Beauchamp, G. H. King, J. E. Franklin, W. R. Leaitch, A. J. Wheeler, Z. Li, G. A. Gagnon, and P. I. Palmer
Atmos. Chem. Phys., 13, 7199–7213, https://doi.org/10.5194/acp-13-7199-2013, https://doi.org/10.5194/acp-13-7199-2013, 2013
B. Ervens, Y. Wang, J. Eagar, W. R. Leaitch, A. M. Macdonald, K. T. Valsaraj, and P. Herckes
Atmos. Chem. Phys., 13, 5117–5135, https://doi.org/10.5194/acp-13-5117-2013, https://doi.org/10.5194/acp-13-5117-2013, 2013
S. Lance, T. Raatikainen, T. B. Onasch, D. R. Worsnop, X.-Y. Yu, M. L. Alexander, M. R. Stolzenburg, P. H. McMurry, J. N. Smith, and A. Nenes
Atmos. Chem. Phys., 13, 5049–5062, https://doi.org/10.5194/acp-13-5049-2013, https://doi.org/10.5194/acp-13-5049-2013, 2013
L. Ahlm, K. M. Shakya, L. M. Russell, J. C. Schroder, J. P. S. Wong, S. J. Sjostedt, K. L. Hayden, J. Liggio, J. J. B. Wentzell, H. A. Wiebe, C. Mihele, W. R. Leaitch, and A. M. Macdonald
Atmos. Chem. Phys., 13, 3393–3407, https://doi.org/10.5194/acp-13-3393-2013, https://doi.org/10.5194/acp-13-3393-2013, 2013
A. R. Berg, C. L. Heald, K. E. Huff Hartz, A. G. Hallar, A. J. H. Meddens, J. A. Hicke, J.-F. Lamarque, and S. Tilmes
Atmos. Chem. Phys., 13, 3149–3161, https://doi.org/10.5194/acp-13-3149-2013, https://doi.org/10.5194/acp-13-3149-2013, 2013
J. O. Bash, E. J. Cooter, R. L. Dennis, J. T. Walker, and J. E. Pleim
Biogeosciences, 10, 1635–1645, https://doi.org/10.5194/bg-10-1635-2013, https://doi.org/10.5194/bg-10-1635-2013, 2013
J. T. Walker, M. R. Jones, J. O. Bash, L. Myles, T. Meyers, D. Schwede, J. Herrick, E. Nemitz, and W. Robarge
Biogeosciences, 10, 981–998, https://doi.org/10.5194/bg-10-981-2013, https://doi.org/10.5194/bg-10-981-2013, 2013
A. Asmi, M. Collaud Coen, J. A. Ogren, E. Andrews, P. Sheridan, A. Jefferson, E. Weingartner, U. Baltensperger, N. Bukowiecki, H. Lihavainen, N. Kivekäs, E. Asmi, P. P. Aalto, M. Kulmala, A. Wiedensohler, W. Birmili, A. Hamed, C. O'Dowd, S. G Jennings, R. Weller, H. Flentje, A. M. Fjaeraa, M. Fiebig, C. L. Myhre, A. G. Hallar, E. Swietlicki, A. Kristensson, and P. Laj
Atmos. Chem. Phys., 13, 895–916, https://doi.org/10.5194/acp-13-895-2013, https://doi.org/10.5194/acp-13-895-2013, 2013
L.-H. Young, S.-H. Lee, V. P. Kanawade, T.-C. Hsiao, Y. L. Lee, B.-F. Hwang, Y.-J. Liou, H.-T. Hsu, and P.-J. Tsai
Atmos. Chem. Phys., 13, 547–564, https://doi.org/10.5194/acp-13-547-2013, https://doi.org/10.5194/acp-13-547-2013, 2013
Related subject area
Subject: Aerosols | Research Activity: Atmospheric Modelling and Data Analysis | Altitude Range: Troposphere | Science Focus: Physics (physical properties and processes)
Regional variability of aerosol impacts on clouds and radiation in global kilometer-scale simulations
A novel method to quantify the uncertainty contribution of aerosol–radiation interaction factors
Exploring the aerosol activation properties in coastal shallow convection using cloud- and particle-resolving models
Machine-learning-assisted inference of the particle charge fraction and the ion-induced nucleation rates during new particle formation events
Modeling CMAQ dry deposition treatment over the western Pacific: a distinct characteristic of mineral dust and anthropogenic aerosols
Impact of post-monsoon crop residue burning on PM2.5 over northern India: optimizing emissions using a high-density in situ surface observation network
Modeling simulation of aerosol light absorption over the Beijing–Tianjin–Hebei region: the impact of mixing state and aging processes
An investigation of the impact of Canadian wildfires on US air quality using model, satellite, and ground measurements
How to trace the origins of short-lived atmospheric species: an Arctic example
Dust-producing weather patterns of the North American Great Plains
High-resolution air quality maps for Bucharest using a mixed-effects modeling framework
Interdecadal shift in the impact of winter land-sea thermal contrasts on following spring transcontinental dust transport pathways in North Africa
Anthropogenic and Natural Causes for the Interannual Variation of PM2.5 in East Asia During Summer Monsoon Periods From 2008 to 2018
Construction and application of a pollen emissions model based on phenology and random forests
An uncertain future for the climate and health impacts of anthropogenic aerosols in Africa
The impact of uncertainty in black carbon's refractive index on simulated optical depth and radiative forcing
Gas-phase collision rate enhancement factors for acid-base clusters up to 2 nm in diameter from atomistic simulation and the interacting hard sphere model
Characterization of brown carbon absorption in different European environments through source contribution analysis
Accounting for the black carbon aging process in a two-way coupled meteorology–air quality model
The effectiveness of solar radiation management using fine sea spray across multiple climatic regions
A global dust emission dataset for estimating dust radiative forcings in climate models
Tropospheric aerosols over the western North Atlantic Ocean during the winter and summer deployments of ACTIVATE 2020: life cycle, transport, and distribution
Spatial and temporal evolution of future atmospheric reactive nitrogen deposition in China under different climate change mitigation strategies
Steady-state mixing state of black carbon aerosols from a particle-resolved model
Direct radiative forcing of light-absorbing carbonaceous aerosol and the influencing factors over China
Distinctive dust weather intensities in North China resulted from two types of atmospheric circulation anomalies
Biomass burning emission analysis based on MODIS aerosol optical depth and AeroCom multi-model simulations: implications for model constraints and emission inventories
Quasi-weekly oscillation of regional PM2.5 transport over China driven by the synoptic-scale disturbance of the East Asian winter monsoon circulation
Solar radiation estimation in West Africa: impact of dust conditions during the 2021 dry season
Modeling urban pollutant transport at multi-resolutions: Impacts of turbulent mixing
Homogeneous ice nucleation in adsorbed water films: A theoretical approach
Gaps in our understanding of ice-nucleating particle sources exposed by global simulation of the UK Earth System Model
The role of interfacial tension in the size-dependent phase separation of atmospheric aerosol particles
Impact of Topographic Wind Conditions on Dust Particle Size Distribution: Insights from a Regional Dust Reanalysis Dataset
Uncovering the Impact of Urban Functional Zones on Air Quality in China
Seasonal differences in observed versus modeled new particle formation over boreal regions
Warming effects of reduced sulfur emissions from shipping
The key role of atmospheric absorption in the Asian summer monsoon response to dust emissions in CMIP6 models
Multi-model effective radiative forcing of the 2020 sulfur cap for shipping
Representation of iron aerosol size distributions of anthropogenic emissions is critical in evaluating atmospheric soluble iron input to the ocean
Radiative and climate effects of aerosol scattering in long-wave radiation based on global climate modeling
Revealing dominant patterns of aerosol regimes in the lower troposphere and their evolution from preindustrial times to the future in global climate model simulations
Improving estimation of a record-breaking east Asian dust storm emission with lagged aerosol Ångström exponent observations
Impact of biomass burning aerosols (BBA) on the tropical African climate in an ocean–atmosphere–aerosol coupled climate model
Retrieval of refractive index and water content for the coating materials of aged black carbon aerosol based on optical properties: a theoretical analysis
Strong inter-model differences and biases in CMIP6 simulations of PM2.5, aerosol optical depth, and precipitation over Africa
Predicting hygroscopic growth of organosulfur aerosol particles using COSMOtherm
Dust aerosol from the Aralkum Desert influences the radiation budget and atmospheric dynamics of Central Asia
Global modeling of aerosol nucleation with a semi-explicit chemical mechanism for highly oxygenated organic molecules (HOMs)
Synergistic effects of the winter North Atlantic Oscillation (NAO) and El Niño–Southern Oscillation (ENSO) on dust activities in North China during the following spring
Ross J. Herbert, Andrew I. L. Williams, Philipp Weiss, Duncan Watson-Parris, Elisabeth Dingley, Daniel Klocke, and Philip Stier
Atmos. Chem. Phys., 25, 7789–7814, https://doi.org/10.5194/acp-25-7789-2025, https://doi.org/10.5194/acp-25-7789-2025, 2025
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Clouds exist at scales that climate models struggle to represent, limiting our knowledge of how climate change may impact clouds. Here we use a new kilometer-scale global model representing an important step towards the necessary scale. We focus on how aerosol particles modify clouds, radiation, and precipitation. We find the magnitude and manner of responses tend to vary from region to region, highlighting the potential of global kilometer-scale simulations and a need to represent aerosols in climate models.
Bishuo He and Chunsheng Zhao
Atmos. Chem. Phys., 25, 7765–7776, https://doi.org/10.5194/acp-25-7765-2025, https://doi.org/10.5194/acp-25-7765-2025, 2025
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Factor uncertainty analysis helps us understand the impacts of factors on complex systems. Traditional methods have many limitations. This study introduces a new method to measure how each factor contributes to uncertainty. It gains insights into the role of each variable and works for all multi-factor systems. As an application, we analyzed how aerosols affect solar radiation and identified the key factors. These analyses can improve our understanding of the role of aerosols in climate change.
Ge Yu, Yueya Wang, Zhe Wang, and Xiaoming Shi
Atmos. Chem. Phys., 25, 7527–7542, https://doi.org/10.5194/acp-25-7527-2025, https://doi.org/10.5194/acp-25-7527-2025, 2025
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Studying the cloud-forming capacity of aerosols is crucial in climate research. The PartMC model can provide detailed particle information and help these studies. This model is integrated with the ideal meteorological Cloud Model 1 (CM1) to simulate the aerosols at cloud-forming locations. Significant changes are revealed in the hygroscopicity distribution of aerosols within ascending air parcels. Additionally, different ascent times also affect aerosol aging processes.
Pan Wang, Yue Zhao, Jiandong Wang, Veli-Matti Kerminen, Jingkun Jiang, and Chenxi Li
Atmos. Chem. Phys., 25, 7431–7446, https://doi.org/10.5194/acp-25-7431-2025, https://doi.org/10.5194/acp-25-7431-2025, 2025
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We developed a numerical model to investigate the evolution of the charge state of newly formed atmospheric particles. Based on the simulation results, we successfully employed neural networks to predict particle charge states and estimate ion-induced nucleation rates. This study provides new insights into the dynamics of particle charging and introduces advanced methods for evaluating ion-induced nucleation in atmospheric research.
Steven Soon-Kai Kong, Joshua S. Fu, Neng-Huei Lin, Guey-Rong Sheu, and Wei-Syun Huang
Atmos. Chem. Phys., 25, 7245–7268, https://doi.org/10.5194/acp-25-7245-2025, https://doi.org/10.5194/acp-25-7245-2025, 2025
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The accuracy of the chemical transport model, a key focus of our research, is strongly dependent on the dry deposition parameterization. Our findings show that the refined CMAQ dust model correlated well with ground-based and high-altitude in situ measurements by implementing the suggested dry deposition schemes. Furthermore, we reveal the mixing state of two types of aerosols at the upper level, a finding supported by both the optimized model and measurements.
Mizuo Kajino, Kentaro Ishijima, Joseph Ching, Kazuyo Yamaji, Rio Ishikawa, Tomoki Kajikawa, Tanbir Singh, Tomoki Nakayama, Yutaka Matsumi, Koyo Kojima, Taisei Machida, Takashi Maki, Prabir K. Patra, and Sachiko Hayashida
Atmos. Chem. Phys., 25, 7137–7160, https://doi.org/10.5194/acp-25-7137-2025, https://doi.org/10.5194/acp-25-7137-2025, 2025
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Air pollution in Delhi during the post-monsoon period is severe, and association with intensive crop residue burning (CRB) over Punjab state has attracted attention. However, the relationship has been unclear as the CRB emissions conventionally derived from satellites were underestimated due to clouds or thick smoke/haze over the region. We evaluated the impact of CRB on PM2.5 to be about 50 %, based on a combination of numerical modeling and an observation network using low-cost sensors we installed.
Huiyun Du, Jie Li, Xueshun Chen, Gabriele Curci, Fangqun Yu, Yele Sun, Xu Dao, Song Guo, Zhe Wang, Wenyi Yang, Lianfang Wei, and Zifa Wang
Atmos. Chem. Phys., 25, 5665–5681, https://doi.org/10.5194/acp-25-5665-2025, https://doi.org/10.5194/acp-25-5665-2025, 2025
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Inadequate consideration of mixing states and coatings on black carbon (BC) hinders aerosol radiation forcing quantification. Core–shell mixing aligns well with observations, but partial internal mixing is a more realistic representation. We used a microphysics module to determine the fraction of embedded BC and coating aerosols, constraining the mixing state. This reduced absorption enhancement by 30 %–43 % in northern China, offering insights into BC's radiative effects.
Zhixin Xue, Nair Udaysankar, and Sundar A. Christopher
Atmos. Chem. Phys., 25, 5497–5517, https://doi.org/10.5194/acp-25-5497-2025, https://doi.org/10.5194/acp-25-5497-2025, 2025
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Canadian wildfires in August 2018 significantly increased surface air pollution across the United States (US) – by up to 69 % in some areas. Using model, satellite, and ground measurements, the study highlights how weather patterns and long-range smoke transport drive pollution. The northwestern US was most affected by Canadian wildfire smoke, while the northeastern US experienced the least impact. These findings indicate the growing concern that wildfire smoke poses to air quality across the US.
Anderson Da Silva, Louis Marelle, Jean-Christophe Raut, Yvette Gramlich, Karolina Siegel, Sophie L. Haslett, Claudia Mohr, and Jennie L. Thomas
Atmos. Chem. Phys., 25, 5331–5354, https://doi.org/10.5194/acp-25-5331-2025, https://doi.org/10.5194/acp-25-5331-2025, 2025
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Particle sources in polar climates are unclear, affecting climate representation in models. This study introduces an evaluated method for tracking particles with backward modeling. Tests on simulated particles allowed us to show that traditional detection methods often misidentify sources. An improved method that accurately traces the origins of aerosol particles in the Arctic is presented. The study recommends using this enhanced method for better source identification of atmospheric species.
Stuart Evans
Atmos. Chem. Phys., 25, 4833–4845, https://doi.org/10.5194/acp-25-4833-2025, https://doi.org/10.5194/acp-25-4833-2025, 2025
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This study of the North American Great Plains identifies the various weather patterns responsible for blowing dust in all parts of the region using a weather pattern classification. In the southwestern plains passing cold fronts are the primary cause of dust; in the understudied northern plains, summertime patterns and southerly pre-frontal winds are most important in the west and east, respectively. These results are valuable to understanding and forecasting dust in this complex source region.
Camelia Talianu, Jeni Vasilescu, Doina Nicolae, Alexandru Ilie, Andrei Dandocsi, Anca Nemuc, and Livio Belegante
Atmos. Chem. Phys., 25, 4639–4654, https://doi.org/10.5194/acp-25-4639-2025, https://doi.org/10.5194/acp-25-4639-2025, 2025
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For Bucharest, Romania's capital, mobile measurements during two intensive campaigns and mixed-effect LUR (land-use regression) models to derive seasonal maps of near-surface PM10, NO2 and UFPs (ultrafine particles) have successfully been used. The model's performance was evaluated, demonstrating its potential for high-resolution mapping in other cities with well-characterized urban structures and diverse in situ monitoring stations.
Qi Wen, Yan Li, Mengying Du, Wenjun Song, Linbo Wei, Zhilan Wang, and Xu Li
EGUsphere, https://doi.org/10.5194/egusphere-2025-826, https://doi.org/10.5194/egusphere-2025-826, 2025
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We find that, through an interdecadal phase-locking effect of sea-land thermal forcing-North Atlantic Oscillation-Westerly Jet coupling, springtime dust from North Africa is more likely to be transported eastwards (extending into North America) after the late 1990s, whereas before that time westward transport paths for dust were more frequent. Subject to thermal forcing, wind speed and drought contribute to dust emissions in the two periods, respectively.
Danyang Ma, Min Xie, Huan He, Tijian Wang, Mengzhu Xi, Lingyun Feng, Shuxian Zhang, and Shitong Chen
EGUsphere, https://doi.org/10.5194/egusphere-2025-10, https://doi.org/10.5194/egusphere-2025-10, 2025
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The PM2.5 concentration in China underwent significant changes in 2013. We examined the underlying causes from three perspectives: anthropogenic pollutant emissions, meteorological conditions, and CO2 concentration variations. Our study highlighted the importance of considering the role of CO2 on vegetation when predicting PM2.5 concentrations and developing corresponding control strategies.
Jiangtao Li, Xingqin An, Zhaobin Sun, Caihua Ye, Qing Hou, Yuxin Zhao, and Zhe Liu
Atmos. Chem. Phys., 25, 3583–3602, https://doi.org/10.5194/acp-25-3583-2025, https://doi.org/10.5194/acp-25-3583-2025, 2025
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Climate change and pollution have intensified pollen allergies. We developed a pollen emissions model using phenology and random forests. Key factors affecting annual pollen emissions include temperature, relative humidity and sunshine hours. Pollen dispersal starts around 10 August, peaks around 30 August and ends by 25 September, lasting about 45 d. Over time, annual pollen emissions exhibit significant fluctuations and a downward trend.
Joe Adabouk Amooli, Marianne T. Lund, Sourangsu Chowdhury, Gunnar Myhre, Ane N. Johansen, Bjørn H. Samset, and Daniel M. Westervelt
EGUsphere, https://doi.org/10.5194/egusphere-2025-948, https://doi.org/10.5194/egusphere-2025-948, 2025
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We analyze various projections of African aerosol emissions and their potential impacts on climate and public health. We find that future emissions vary widely across emission projections, with differences in sectoral emission distributions. Using the Oslo chemical transport model, we show that air pollution exposure in some regions of Africa could increase significantly by 2050, increasing pollution-related deaths, with most scenarios projecting aerosol-induced warming over sub-Saharan Africa.
Ruth A. R. Digby, Knut von Salzen, Adam H. Monahan, Nathan P. Gillett, and Jiangnan Li
Atmos. Chem. Phys., 25, 3109–3130, https://doi.org/10.5194/acp-25-3109-2025, https://doi.org/10.5194/acp-25-3109-2025, 2025
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The refractive index of black carbon (BCRI), which determines how much energy black carbon absorbs and scatters, is difficult to measure, and different climate models use different values. We show that varying the BCRI across commonly used values can increase absorbing aerosol optical depth by 42 % and the warming effect from interactions between black carbon and radiation by 47 %, an appreciable fraction of the overall spread between models reported in recent literature assessments.
Valtteri Tikkanen, Huan Yang, Hanna Vehkamäki, and Bernhard Reischl
EGUsphere, https://doi.org/10.5194/egusphere-2025-507, https://doi.org/10.5194/egusphere-2025-507, 2025
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Collisions of neutral molecules and clusters is the prevalent pathway in atmospheric new particle formation. In heavily polluted urban areas, where clusters are formed rapidly and in large number, cluster-cluster collisions also become relevant. We calculate cluster-cluster collision rates from atomistic molecular dynamics simulations and an interacting hard sphere model. Not accounting for long-range attractive interactions underestimates collision and particle formation rates significantly.
Hector Navarro-Barboza, Jordi Rovira, Vincenzo Obiso, Andrea Pozzer, Marta Via, Andres Alastuey, Xavier Querol, Noemi Perez, Marjan Savadkoohi, Gang Chen, Jesus Yus-Díez, Matic Ivancic, Martin Rigler, Konstantinos Eleftheriadis, Stergios Vratolis, Olga Zografou, Maria Gini, Benjamin Chazeau, Nicolas Marchand, Andre S. H. Prevot, Kaspar Dallenbach, Mikael Ehn, Krista Luoma, Tuukka Petäjä, Anna Tobler, Jaroslaw Necki, Minna Aurela, Hilkka Timonen, Jarkko Niemi, Olivier Favez, Jean-Eudes Petit, Jean-Philippe Putaud, Christoph Hueglin, Nicolas Pascal, Aurélien Chauvigné, Sébastien Conil, Marco Pandolfi, and Oriol Jorba
Atmos. Chem. Phys., 25, 2667–2694, https://doi.org/10.5194/acp-25-2667-2025, https://doi.org/10.5194/acp-25-2667-2025, 2025
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Brown carbon (BrC) absorbs ultraviolet (UV) and visible light, influencing climate. This study explores BrC's imaginary refractive index (k) using data from 12 European sites. Residential emissions are a major organic aerosol (OA) source in winter, while secondary organic aerosol (SOA) dominates in summer. Source-specific k values were derived, improving model accuracy. The findings highlight BrC's climate impact and emphasize source-specific constraints in atmospheric models.
Yuzhi Jin, Jiandong Wang, Chao Liu, David C. Wong, Golam Sarwar, Kathleen M. Fahey, Shang Wu, Jiaping Wang, Jing Cai, Zeyuan Tian, Zhouyang Zhang, Jia Xing, Aijun Ding, and Shuxiao Wang
Atmos. Chem. Phys., 25, 2613–2630, https://doi.org/10.5194/acp-25-2613-2025, https://doi.org/10.5194/acp-25-2613-2025, 2025
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Black carbon (BC) affects climate and the environment, and its aging process alters its properties. Current models, like WRF-CMAQ, lack full accounting for it. We developed the WRF-CMAQ-BCG model to better represent BC aging by introducing bare and coated BC species and their conversion. The WRF-CMAQ-BCG model introduces the capability to simulate BC mixing states and bare and coated BC wet deposition, and it improves the accuracy of BC mass concentration and aerosol optics.
Zhe Song, Shaocai Yu, Pengfei Li, Ningning Yao, Lang Chen, Yuhai Sun, Boqiong Jiang, and Daniel Rosenfeld
Atmos. Chem. Phys., 25, 2473–2494, https://doi.org/10.5194/acp-25-2473-2025, https://doi.org/10.5194/acp-25-2473-2025, 2025
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Our results with injected sea salt aerosols for five open oceans show that sea salt aerosols with low injection amounts dominate shortwave radiation, mainly through indirect effects. As indirect aerosol effects saturate with increasing injection rates, direct effects exceed indirect effects. This implies that marine cloud brightening is best implemented in areas with extensive cloud cover, while aerosol direct scattering effects remain dominant when clouds are scarce.
Danny M. Leung, Jasper F. Kok, Longlei Li, David M. Lawrence, Natalie M. Mahowald, Simone Tilmes, and Erik Kluzek
Atmos. Chem. Phys., 25, 2311–2331, https://doi.org/10.5194/acp-25-2311-2025, https://doi.org/10.5194/acp-25-2311-2025, 2025
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This study derives a gridded dust emission dataset for 1841–2000 by employing a combination of observed dust from core records and reanalyzed global dust cycle constraints. We evaluate the ability of global models to replicate the observed historical dust variability by using the emission dataset to force a historical simulation in an Earth system model. We show that prescribing our emissions forces the model to better match observations than other mechanistic models.
Hongyu Liu, Bo Zhang, Richard H. Moore, Luke D. Ziemba, Richard A. Ferrare, Hyundeok Choi, Armin Sorooshian, David Painemal, Hailong Wang, Michael A. Shook, Amy Jo Scarino, Johnathan W. Hair, Ewan C. Crosbie, Marta A. Fenn, Taylor J. Shingler, Chris A. Hostetler, Gao Chen, Mary M. Kleb, Gan Luo, Fangqun Yu, Mark A. Vaughan, Yongxiang Hu, Glenn S. Diskin, John B. Nowak, Joshua P. DiGangi, Yonghoon Choi, Christoph A. Keller, and Matthew S. Johnson
Atmos. Chem. Phys., 25, 2087–2121, https://doi.org/10.5194/acp-25-2087-2025, https://doi.org/10.5194/acp-25-2087-2025, 2025
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We use the GEOS-Chem model to simulate aerosol distributions and properties over the western North Atlantic Ocean (WNAO) during the winter and summer deployments in 2020 of the NASA ACTIVATE mission. Model results are evaluated against aircraft, ground-based, and satellite observations. The improved understanding of life cycle, composition, transport pathways, and distribution of aerosols has important implications for characterizing aerosol–cloud–meteorology interactions over WNAO.
Mingrui Ma, Jiachen Cao, Dan Tong, Bo Zheng, and Yu Zhao
Atmos. Chem. Phys., 25, 2147–2166, https://doi.org/10.5194/acp-25-2147-2025, https://doi.org/10.5194/acp-25-2147-2025, 2025
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We combined two global climate change pathways and three national emission control scenarios to analyze the future evolution of reactive nitrogen (Nr) deposition till the 2060s in China with air quality modeling. We show China’s clean air and carbon neutrality policies would overcome the adverse effects of climate change and efficiently reduce Nr deposition. The outflow of Nr fluxes from mainland China to the west Pacific would also be clearly reduced from continuous stringent emission controls.
Zhouyang Zhang, Jiandong Wang, Jiaping Wang, Nicole Riemer, Chao Liu, Yuzhi Jin, Zeyuan Tian, Jing Cai, Yueyue Cheng, Ganzhen Chen, Bin Wang, Shuxiao Wang, and Aijun Ding
Atmos. Chem. Phys., 25, 1869–1881, https://doi.org/10.5194/acp-25-1869-2025, https://doi.org/10.5194/acp-25-1869-2025, 2025
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Black carbon (BC) exerts notable warming effects. We use a particle-resolved model to investigate the long-term behavior of the BC mixing state, revealing its compositions, coating thickness distribution, and optical properties all stabilize with a characteristic time of less than 1 d. This study can effectively simplify the description of the BC mixing state, which facilitates the precise assessment of the optical properties of BC aerosols in global and chemical transport models.
Shuangqin Yang, Yusi Liu, Li Chen, Nan Cao, Jing Wang, and Shuang Gao
EGUsphere, https://doi.org/10.5194/egusphere-2024-3705, https://doi.org/10.5194/egusphere-2024-3705, 2025
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Black carbon, primary brown carbon, and secondary brown carbon are the leading light-absorbing carbonaceous aerosols (LACs) that contribute significantly to climate change. We modified the GEOS-Chem model to simulate the climate change by LACs based on local emission inventory, and explored the impacts of LACs properties and atmospheric variables on the corresponding DRFs in seven regions of China. The study confirms the warming effect of LACs and deepens our knowledge of their climatic effects.
Qianyi Huo, Zhicong Yin, Xiaoqing Ma, and Huijun Wang
Atmos. Chem. Phys., 25, 1711–1724, https://doi.org/10.5194/acp-25-1711-2025, https://doi.org/10.5194/acp-25-1711-2025, 2025
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Dust days during the spring seasons of 2015–2023 in North China were classified into Mongolian cyclone and cold high types depending on the presence of the Mongolian cyclone. The Mongolian cyclone type led to more frequent and severe dust weather, indicated by PM10 concentrations. To comprehensively forecast the two types of dust weather, a common predictor was established based on 500 hPa anomalous circulation systems, offering insights for dust weather forecasting and climate prediction.
Mariya Petrenko, Ralph Kahn, Mian Chin, Susanne E. Bauer, Tommi Bergman, Huisheng Bian, Gabriele Curci, Ben Johnson, Johannes W. Kaiser, Zak Kipling, Harri Kokkola, Xiaohong Liu, Keren Mezuman, Tero Mielonen, Gunnar Myhre, Xiaohua Pan, Anna Protonotariou, Samuel Remy, Ragnhild Bieltvedt Skeie, Philip Stier, Toshihiko Takemura, Kostas Tsigaridis, Hailong Wang, Duncan Watson-Parris, and Kai Zhang
Atmos. Chem. Phys., 25, 1545–1567, https://doi.org/10.5194/acp-25-1545-2025, https://doi.org/10.5194/acp-25-1545-2025, 2025
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We compared smoke plume simulations from 11 global models to each other and to satellite smoke amount observations aimed at constraining smoke source strength. In regions where plumes are thick and background aerosol is low, models and satellites compare well. However, the input emission inventory tends to underestimate in many places, and particle property and loss rate assumptions vary enormously among models, causing uncertainties that require systematic in situ measurements to resolve.
Yongqing Bai, Tianliang Zhao, Kai Meng, Yue Zhou, Jie Xiong, Xiaoyun Sun, Lijuan Shen, Yanyu Yue, Yan Zhu, Weiyang Hu, and Jingyan Yao
Atmos. Chem. Phys., 25, 1273–1287, https://doi.org/10.5194/acp-25-1273-2025, https://doi.org/10.5194/acp-25-1273-2025, 2025
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We proposed a composite statistical method to identify the quasi-weekly oscillation (QWO) of regional PM2.5 transport over China in winter from 2015 to 2019. The QWO of regional PM2.5 transport is constrained by synoptic-scale disturbances of the East Asian winter monsoon circulation with the periodic activities of the Siberian high, providing a new insight into the understanding of regional pollutant transport with meteorological drivers in atmospheric environment changes.
Léo Clauzel, Sandrine Anquetin, Christophe Lavaysse, Gilles Bergametti, Christel Bouet, Guillaume Siour, Rémy Lapere, Béatrice Marticorena, and Jennie Thomas
Atmos. Chem. Phys., 25, 997–1021, https://doi.org/10.5194/acp-25-997-2025, https://doi.org/10.5194/acp-25-997-2025, 2025
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Solar energy production in West Africa is set to rise and needs accurate solar radiation estimates which are affected by desert dust. This work analyses a March 2021 dust event using a modelling strategy incorporating desert dust. Results show that considering desert dust cuts errors in solar radiation estimates by 75 % and reduces surface solar radiation by 18 %. This highlights the importance of incorporating dust aerosols into solar forecasting for better accuracy.
Zining Yang, Qiuyan Du, Qike Yang, Chun Zhao, Gudongze Li, Zihan Xia, Mingyue Xu, Renmin Yuan, Yubin Li, Kaihui Xia, Jun Gu, and Jiawang Feng
EGUsphere, https://doi.org/10.5194/egusphere-2024-3890, https://doi.org/10.5194/egusphere-2024-3890, 2025
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This study investigates the impact of turbulent mixing on black carbon (BC) concentrations in urban areas using WRF-Chem at 25, 5, and 1 km resolutions. Significant variations in BC and turbulent mixing occur mainly at night. Higher resolutions reduce BC overestimation due to enhanced PBL mixing coefficients and vertical wind fluxes. Small-scale eddies at higher resolutions increase BC lifetime and column concentrations. Land use and terrain variations across multi-resolutions affect PBL mixing.
Ari Laaksonen, Golnaz Roudsari, Ana A. Piedehierro, and André Welti
EGUsphere, https://doi.org/10.5194/egusphere-2024-4095, https://doi.org/10.5194/egusphere-2024-4095, 2025
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The mechanisms of ice nucleation at temperatures below 235 K have remained unclear for the past century. We suggest that ice nucleation is caused by the freezing of water adsorbed on aerosol surfaces. To test this hypothesis, we derived theoretical equations to predict the exact atmospheric conditions under which ice nucleation occurs. Our predictions agree well with experiments. The new theory thus provides a basis for an improved description of ice nucleation in the atmosphere.
Ross J. Herbert, Alberto Sanchez-Marroquin, Daniel P. Grosvenor, Kirsty J. Pringle, Stephen R. Arnold, Benjamin J. Murray, and Kenneth S. Carslaw
Atmos. Chem. Phys., 25, 291–325, https://doi.org/10.5194/acp-25-291-2025, https://doi.org/10.5194/acp-25-291-2025, 2025
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Aerosol particles that help form ice in clouds vary in number and type around the world and with time. However, in many weather and climate models cloud ice is not linked to aerosols that are known to nucleate ice. Here we report the first steps towards representing ice-nucleating particles within the UK Earth System Model. We conclude that in addition to ice nucleation by sea spray and mineral components of soil dust, we also need to represent ice nucleation by the organic components of soils.
Ryan Schmedding and Andreas Zuend
Atmos. Chem. Phys., 25, 327–346, https://doi.org/10.5194/acp-25-327-2025, https://doi.org/10.5194/acp-25-327-2025, 2025
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Four different approaches for computing the interfacial tension between liquid phases in aerosol particles were tested for particles with diameters from 10 nm to more than 5 μm. Antonov's rule led to the strongest reductions in the onset relative humidity of liquid–liquid phase separation and reproduced measured interfacial tensions for highly immiscible systems. A modified form of the Butler equation was able to best reproduce measured interfacial tensions in more miscible systems.
Xinyue Huang, Wenyu Gao, and Hosein Foroutan
EGUsphere, https://doi.org/10.5194/egusphere-2024-3076, https://doi.org/10.5194/egusphere-2024-3076, 2024
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This study investigates the relationship between wind-blown dust aerosols size distribution and wind conditions over topography at a regional scale, utilizing 10 years of dust reanalysis data. Linear regression models suggest that higher wind speeds and steeper land slopes, particularly under uphill winds, are associated with increased fractions of coarser dust particles. Moreover, these positive correlations weaken during summer and afternoon events, likely related to the haboob storms.
Lulu Yuan, Wenchao Han, Jiachen Meng, Yang Wang, Haojie Yu, and Wenze Li
EGUsphere, https://doi.org/10.5194/egusphere-2024-3350, https://doi.org/10.5194/egusphere-2024-3350, 2024
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This study utilizes multi-source data to reveal the impact of various urban functional zones in China on the spatial distribution of pollutants. The findings indicate that the residential and commercial zones see notable air quality gains, but the improvement of air quality in the transportation zone is the least considerable. Moreover, the industrial zone has the most seasonal air quality variation. Therefore, air pollution prevention policies should consider differences in functional zones.
Carl Svenhag, Pontus Roldin, Tinja Olenius, Robin Wollesen de Jonge, Sara Blichner, Daniel Yazgi, and Moa Sporre
EGUsphere, https://doi.org/10.5194/egusphere-2024-3626, https://doi.org/10.5194/egusphere-2024-3626, 2024
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This study investigates the model representation of how particles are formed and grow in the atmosphere. Using modeled and observed data from two boreal forest stations in 2018, we identify key factors for NPF to improve particle-climate predictions in the global EC-Earth3 model. Comparisons with the detailed ADCHEM model show that adding ammonia improves particle growth predictions, though EC-Earth3 still highly underestimates the number of particles during warmer months.
Masaru Yoshioka, Daniel P. Grosvenor, Ben B. B. Booth, Colin P. Morice, and Ken S. Carslaw
Atmos. Chem. Phys., 24, 13681–13692, https://doi.org/10.5194/acp-24-13681-2024, https://doi.org/10.5194/acp-24-13681-2024, 2024
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A 2020 regulation has reduced sulfur emissions from shipping by about 80 %, leading to a decrease in atmospheric aerosols that have a cooling effect primarily by affecting cloud properties and amounts. Our climate model simulations predict a global temperature increase of 0.04 K over the next 3 decades as a result, which could contribute to surpassing the Paris Agreement's 1.5 °C target. Reduced aerosols may have also contributed to the recent temperature spikes.
Alcide Zhao, Laura J. Wilcox, and Claire L. Ryder
Atmos. Chem. Phys., 24, 13385–13402, https://doi.org/10.5194/acp-24-13385-2024, https://doi.org/10.5194/acp-24-13385-2024, 2024
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Climate models include desert dust aerosols, which cause atmospheric heating and can change circulation patterns. We assess the effect of dust on the Indian and east Asian summer monsoons through multi-model experiments isolating the effect of dust in current climate models for the first time. Dust atmospheric heating results in a southward shift of western Pacific equatorial rainfall and an enhanced Indian summer monsoon. This shows the importance of accurate dust representation in models.
Ragnhild Bieltvedt Skeie, Rachael Byrom, Øivind Hodnebrog, Caroline Jouan, and Gunnar Myhre
Atmos. Chem. Phys., 24, 13361–13370, https://doi.org/10.5194/acp-24-13361-2024, https://doi.org/10.5194/acp-24-13361-2024, 2024
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In 2020, new regulations by the International Maritime Organization regarding sulfur emissions came into force, reducing emissions of SO2 from the shipping sector by approximately 80 %. In this study, we use multiple models to calculate how much the Earth energy balance changed due to the emission reduction or the so-called effective radiative forcing. The calculated effective radiative forcing is weak, comparable to the effect of the increase in CO2 over the last 2 to 3 years.
Mingxu Liu, Hitoshi Matsui, Douglas S. Hamilton, Sagar D. Rathod, Kara D. Lamb, and Natalie M. Mahowald
Atmos. Chem. Phys., 24, 13115–13127, https://doi.org/10.5194/acp-24-13115-2024, https://doi.org/10.5194/acp-24-13115-2024, 2024
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Atmospheric aerosol deposition provides bioavailable iron to promote marine primary production, yet the estimates of its fluxes remain highly uncertain. This study, by performing global aerosol simulations, demonstrates that iron-containing particle size upon emission is a critical factor in regulating soluble iron input to open oceans. Further observational constraints on this are needed to reduce modeling uncertainties.
Thomas Drugé, Pierre Nabat, Martine Michou, and Marc Mallet
EGUsphere, https://doi.org/10.5194/egusphere-2024-3659, https://doi.org/10.5194/egusphere-2024-3659, 2024
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Aerosol scattering in long-wave radiation is often neglected in climate models. In this study, we analyze its impact through a physical modeling of this process in the CNRM ARPEGE-Climat model. It mainly leads to surface LW radiation increases across Sahara, Sahel and Arabian Peninsula, resulting in daily minimum near-surface temperature rises. Other changes in atmospheric fields are also simulated.
Jingmin Li, Mattia Righi, Johannes Hendricks, Christof G. Beer, Ulrike Burkhardt, and Anja Schmidt
Atmos. Chem. Phys., 24, 12727–12747, https://doi.org/10.5194/acp-24-12727-2024, https://doi.org/10.5194/acp-24-12727-2024, 2024
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Aiming to understand underlying patterns and trends in aerosols, we characterize the spatial patterns and long-term evolution of lower tropospheric aerosols by clustering multiple aerosol properties from preindustrial times to the year 2050 under three Shared
Socioeconomic Pathway scenarios. The results provide a clear and condensed picture of the spatial extent and distribution of aerosols for different time periods and emission scenarios.
Socioeconomic Pathway scenarios. The results provide a clear and condensed picture of the spatial extent and distribution of aerosols for different time periods and emission scenarios.
Yueming Cheng, Tie Dai, Junji Cao, Daisuke Goto, Jianbing Jin, Teruyuki Nakajima, and Guangyu Shi
Atmos. Chem. Phys., 24, 12643–12659, https://doi.org/10.5194/acp-24-12643-2024, https://doi.org/10.5194/acp-24-12643-2024, 2024
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In March 2021, east Asia experienced an outbreak of severe dust storms after an absence of 1.5 decades. Here, we innovatively used the time-lagged ground-based aerosol size information with the fixed-lag ensemble Kalman smoother to optimize dust emission and reproduce the dust storm. This work is valuable for not only the quantification of health damage, aviation risks, and profound impacts on the Earth's system but also revealing the climatic driving force and the process of desertification.
Marc Mallet, Aurore Voldoire, Fabien Solmon, Pierre Nabat, Thomas Drugé, and Romain Roehrig
Atmos. Chem. Phys., 24, 12509–12535, https://doi.org/10.5194/acp-24-12509-2024, https://doi.org/10.5194/acp-24-12509-2024, 2024
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This study investigates the interactions between smoke aerosols and climate in tropical Africa using a coupled ocean–atmosphere–aerosol climate model. The work shows that smoke plumes have a significant impact by increasing the low-cloud fraction, decreasing the ocean and continental surface temperature and reducing the precipitation of coastal western Africa. It also highlights the role of the ocean temperature response and its feedbacks for the September–November season.
Jia Liu, Cancan Zhu, Donghui Zhou, and Jinbao Han
Atmos. Chem. Phys., 24, 12341–12354, https://doi.org/10.5194/acp-24-12341-2024, https://doi.org/10.5194/acp-24-12341-2024, 2024
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The hydrophilic coatings of aged black carbon (BC) particles absorb moisture during the hygroscopic growth process, but it is difficult to characterize how much water is absorbed under different relative humidities (RHs). In this study, we propose a method to obtain the water content in the coatings based on the equivalent complex refractive index retrieved from optical properties. This method is verified from a theoretical perspective, and it performs well for thickly coated BC at high RHs.
Catherine Anne Toolan, Joe Adabouk Amooli, Laura J. Wilcox, Bjørn H. Samset, Andrew G. Turner, and Daniel M. Westervelt
EGUsphere, https://doi.org/10.5194/egusphere-2024-3057, https://doi.org/10.5194/egusphere-2024-3057, 2024
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Our research explores how well air pollution and rainfall patterns in Africa are represented in current climate models, by comparing model data to observations from 1981 to 2023. While most models capture seasonal air quality changes well, they struggle to replicate the distribution of non-dust pollutants and certain rainfall patterns, especially over east Africa. Improving these models is crucial for better climate predictions and preparing for future risks.
Zijun Li, Angela Buchholz, and Noora Hyttinen
Atmos. Chem. Phys., 24, 11717–11725, https://doi.org/10.5194/acp-24-11717-2024, https://doi.org/10.5194/acp-24-11717-2024, 2024
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Evaluating organosulfur (OS) hygroscopicity is important for assessing aerosol–cloud climate interactions in the post-fossil-fuel future, when SO2 emissions decrease and OS compounds become increasingly important. Here a state-of-the-art quantum-chemistry-based method was used to predict the hygroscopic growth factors (HGFs) of a group of atmospherically relevant OS compounds and their mixtures with (NH4)2SO4. A good agreement was observed between their model-estimated and experimental HGFs.
Jamie R. Banks, Bernd Heinold, and Kerstin Schepanski
Atmos. Chem. Phys., 24, 11451–11475, https://doi.org/10.5194/acp-24-11451-2024, https://doi.org/10.5194/acp-24-11451-2024, 2024
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The Aralkum is a new desert in Central Asia formed by the desiccation of the Aral Sea. This has created a source of atmospheric dust, with implications for the balance of solar and thermal radiation. Simulating these effects using a dust transport model, we find that Aralkum dust adds radiative cooling effects to the surface and atmosphere on average but also adds heating events. Increases in surface pressure due to Aralkum dust strengthen the Siberian High and weaken the summer Asian heat low.
Xinyue Shao, Minghuai Wang, Xinyi Dong, Yaman Liu, Wenxiang Shen, Stephen R. Arnold, Leighton A. Regayre, Meinrat O. Andreae, Mira L. Pöhlker, Duseong S. Jo, Man Yue, and Ken S. Carslaw
Atmos. Chem. Phys., 24, 11365–11389, https://doi.org/10.5194/acp-24-11365-2024, https://doi.org/10.5194/acp-24-11365-2024, 2024
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Highly oxygenated organic molecules (HOMs) play an important role in atmospheric new particle formation (NPF). By semi-explicitly coupling the chemical mechanism of HOMs and a comprehensive nucleation scheme in a global climate model, the updated model shows better agreement with measurements of nucleation rate, growth rate, and NPF event frequency. Our results reveal that HOM-driven NPF leads to a considerable increase in particle and cloud condensation nuclei burden globally.
Falei Xu, Shuang Wang, Yan Li, and Juan Feng
Atmos. Chem. Phys., 24, 10689–10705, https://doi.org/10.5194/acp-24-10689-2024, https://doi.org/10.5194/acp-24-10689-2024, 2024
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This study examines how the winter North Atlantic Oscillation (NAO) and El Niño–Southern Oscillation (ENSO) affect dust activities in North China during the following spring. The results show that the NAO and ENSO, particularly in their negative phases, greatly influence dust activities. When both are negative, their combined effect on dust activities is even greater. This research highlights the importance of these climate patterns in predicting spring dust activities in North China.
Cited articles
Bae, M.-S., Schwab, J. J., Hogrefe, O., Frank, B. P., Lala, G. G., and Demerjian, K. L.: Characteristics of size distributions at urban and rural locations in New York, Atmos. Chem. Phys., 10, 4521–4535, https://doi.org/10.5194/acp-10-4521-2010, 2010.
Berndt, T., Sipilä, M., Stratmann, F., Petäjä, T., Vanhanen, J., Mikkilä, J., Patokoski, J., Taipale, R., Mauldin III, R. L., and Kulmala, M.: Enhancement of atmospheric H2SO4 / H2O nucleation: organic oxidation products versus amines, Atmos. Chem. Phys., 14, 751–764, https://doi.org/10.5194/acp-14-751-2014, 2014.
Bey, I., Jacob, D. J., Yantosca, R. M., Logan, J. A., Field, B., Fiore, A. M., Li, Q., Liu, H., Mickley, L. J., and Schultz, M., Global modeling of tropospheric chemistry with assimilated meteorology: Model description and evaluation, J. Geophys. Res., 106, 23073–23096, 2001.
Carslaw, K. S., Lee, L. A., Reddington, C. L., Pringle, K. J., Rap, A. Forster, P. M., Mann, G. W., Spracklen, D. V., Woodhouse, M. T., Regayre, L. A., and Pierce, J. R.: Large contribution of natural aerosols to uncertainty in indirect forcing, Nature, 503, 67–71, https://doi.org/10.1038/nature12674, 2013.
Chen, M., Titcombe, M., Jiang, J., Kuang, Fischer, M. L., Edgerton, E., Eisele, F. L., Siepmann, J. I., Hanson, D. H., Zhao, J., and McMurry, P. H.: Acid-base chemical reaction model for nucleation rates in the polluted boundary layer, Proc. Natl. Aca. Sci., 109, 18713–18718, 2012.
Chung, S. H. and Seinfeld, J. H.: Global distribution and climate forcing of carbonaceous aerosols, J. Geophys. Res., 107, 4407, https://doi.org/10.1029/2001JD001397, 2002.
Dal Maso, M., Kulmala, M., Dal Maso, M., Riipinen, I.,Wagner, R., Hussein, T., Aalto, P., and Lehtinen, K. E. J.: Formation and growth of fresh atmospheric aerosols: eight years of aerosol size distribution data from SMEAR II, Hyytiala, Finland, Boreal Environ. Res., 10, 323–336, 2005.
Dawson, M. L., Varner, M. E., Perraud, V., Ezell, M. J., Gerber, R. B., and Finlayson-Pitts, B. J.: Simplified mechanism for new particle formation from methanesulfonic acid, amines, and water via experiments and ab initio calculations, Proc. Natl. Aca. Sci., 109, 18719–18724, 2012.
Ehn, M., Thornton, J., Kleist, E., Sipilä, M., Junninen, H., Pullinen, I., Springer, M., Rubach, F., Tillmann, R., Lee, B., Lopez-Hilfiker, F., Andres, S., Acir, I.-H., Rissanen, M., Jokinen, T., Schobesberger, S., Kangasluoma, J., Kontkanen, J., Nieminen, T., Kurtén, T., Nielsen, L., Jørgensen, S., Kjaergaard, H., Canagaratna, M., Maso, M., Berndt, T., Petäjä, T., Wahner, A., Kerminen, V.-M., Kulmala, M., Worsnop, D., Wildt, J., and Mentel, T.: A large source of low-volatility secondary organic aerosol, Nature, 506, 476–479, https://doi.org/10.1038/nature13032, 2014.
Erupe, M. E., Viggiano, A. A., and Lee, S.-H.: The effect of trimethylamine on atmospheric nucleation involving H2SO4, Atmos. Chem. Phys., 11, 4767–4775, https://doi.org/10.5194/acp-11-4767-2011, 2011.
Evans, M. J. and Jacob, D. J.: Impact of new laboratory studies of N2O5 hydrolysis on global model budgets of tropospheric nitrogen oxides, ozone, and OH, Geophys. Res. Lett., 32, L09813, https://doi.org/10.1029/2005GL022469, 2005.
Glasoe, W. A., Volz, K., Panta, B., Freshour, N., Bachman, R., Hanson, D. R., McMurry, P. H., and Jen, C.: Sulfuric acid nucleation: An experimental study of the effect of seven bases, J. Geophys. Res.-Atmos., 120, https://doi.org/10.1002/2014JD022730, 2015.
Guenther, A., Karl, T., Harley, P., Wiedinmyer, C., Palmer, P. I., and Geron, C.: Estimates of global terrestrial isoprene emissions using MEGAN (Model of Emissions of Gases and Aerosols from Nature), Atmos. Chem. Phys., 6, 3181–3210, https://doi.org/10.5194/acp-6-3181-2006, 2006.
Hallar, A. G., Lowenthal, D. H., Chirokova, G., Wiedinmyer, C., and Borys, R. D.: Persistent daily new particle formation at a mountain-top location, Atmos. Environ., 45, 4111–4115, https://doi.org/10.1016/j.atmosenv.2011.04.044, 2011.
Henze, D. K., Seinfeld, J. H., Ng, N. L., Kroll, J. H., Fu, T.-M., Jacob, D. J., and Heald, C. L.: Global modeling of secondary organic aerosol formation from aromatic hydrocarbons: high- vs. low-yield pathways, Atmos. Chem. Phys., 8, 2405–2420, https://doi.org/10.5194/acp-8-2405-2008, 2008.
IPCC (Intergovernmental Panel on Climate Change): The Physical Science Basis, Working Group I Contribution to the IPCC 5th Assessment Report – Changes to the Underlying Scientific/Technical Assessment, Cambridge Univ. Press, New York, 2013.
Kanawade, V. P., Jobson, B. T., Guenther, A. B., Erupe, M. E., Pressley, S. N., Tripathi, S. N., and Lee, S.-H.: Isoprene suppression of new particle formation in a mixed deciduous forest, Atmos. Chem. Phys., 11, 6013–6027, https://doi.org/10.5194/acp-11-6013-2011, 2011.
Kazil, J., Stier, P., Zhang, K., Quaas, J., Kinne, S., O'Donnell, D., Rast, S., Esch, M., Ferrachat, S., Lohmann, U., and Feichter, J.: Aerosol nucleation and its role for clouds and Earth's radiative forcing in the aerosol-climate model ECHAM5-HAM, Atmos. Chem. Phys., 10, 10733–10752, https://doi.org/10.5194/acp-10-10733-2010, 2010.
Knibbs, L. D., Cole-Hunter, T., and Morawska, L.: A review of commuter exposure to ultrafine particles and its health effects, Atmos. Environ., 45, 2611–2622, 2011.
Kulmala, M., Vehkamaki, H., Petäjä , T., Dal Maso, M., Lauri, A., Kerminen, V.-M., Birmili, W., and McMurry, P.: Formation and growth rates of ultrafine atmospheric particles: A review of observations, J. Aerosol Sci., 35, 143–176, 2004.
Lee, S. H., et al:, New insights on isoprene suppression of biogenic new particle formation, in preparation, 2015.
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Short summary
The role of low-volatility organics in new particle formation (NPF) in the atmosphere is assessed. An empirical formulation in which formation rate is a function of the concentrations of sulfuric acid and low-volatility organics significantly overpredicts NPF in the summer.
Two different schemes predict quite different nucleation rates (including their spatial patterns), concentrations of cloud condensation nuclei, and aerosol first indirect radiative forcing in North America.
The role of low-volatility organics in new particle formation (NPF) in the atmosphere is...
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