Articles | Volume 14, issue 9
https://doi.org/10.5194/acp-14-4503-2014
https://doi.org/10.5194/acp-14-4503-2014
Research article
 | 
07 May 2014
Research article |  | 07 May 2014

Kinetic measurements of the reactivity of hydrogen peroxide and ozone towards small atmospherically relevant aldehydes, ketones and organic acids in aqueous solutions

L. Schöne and H. Herrmann

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Cited articles

Andreozzi, R., Caprio, V., Insola, A., Marotta, R., and Tufano, V.: The ozonation of pyruvic acid in aqueous solutions catalyzed by suspended and dissolved manganese, Water Res., 32, 1492–1496, https://doi.org/10.1016/S0043-1354(97)00367-9, 1998.
Beeby, A., Mohammed, D., and Sodeau, J. R.: Photochemistry and photophysics of glycolaldehyde in solution, J. Am. Chem. Soc., 109, 857–861, 1987.
Betterton, E. A., and Hoffmann, M. R.: Henry's law constants of some environmentally important aldehydes, Environ. Sci. Technol., 22, 1415–1418, https://doi.org/10.1021/es00177a004, 1988.
Buxton, G. V., Greenstock, C. L., Helman, W. P., and Ross, A. B.: Critical Review of rate constants for reactions of hydrated electrons, hydrogen atoms and hydroxyl radicals (•OH / •O-) in Aqueous Solution, J. Phys. Chem. Ref. Data, 17, 513–886, 1988.
Calvert, J. G.: The mechanisms of atmospheric oxidation of the alkenes, Oxford University Press, 3–22, 2000.
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