Articles | Volume 14, issue 22
https://doi.org/10.5194/acp-14-12513-2014
https://doi.org/10.5194/acp-14-12513-2014
Research article
 | 
27 Nov 2014
Research article |  | 27 Nov 2014

Competition between water uptake and ice nucleation by glassy organic aerosol particles

T. Berkemeier, M. Shiraiwa, U. Pöschl, and T. Koop

Related authors

Desorption lifetimes and activation energies influencing gas–surface interactions and multiphase chemical kinetics
Daniel A. Knopf, Markus Ammann, Thomas Berkemeier, Ulrich Pöschl, and Manabu Shiraiwa
Atmos. Chem. Phys., 24, 3445–3528, https://doi.org/10.5194/acp-24-3445-2024,https://doi.org/10.5194/acp-24-3445-2024, 2024
Short summary
Volatile oxidation products and secondary organosiloxane aerosol from D5 + OH at varying OH exposures
Hyun Gu Kang, Yanfang Chen, Yoojin Park, Thomas Berkemeier, and Hwajin Kim
Atmos. Chem. Phys., 23, 14307–14323, https://doi.org/10.5194/acp-23-14307-2023,https://doi.org/10.5194/acp-23-14307-2023, 2023
Short summary
Technical note: In situ measurements and modelling of the oxidation kinetics in films of a cooking aerosol proxy using a quartz crystal microbalance with dissipation monitoring (QCM-D)
Adam Milsom, Shaojun Qi, Ashmi Mishra, Thomas Berkemeier, Zhenyu Zhang, and Christian Pfrang
Atmos. Chem. Phys., 23, 10835–10843, https://doi.org/10.5194/acp-23-10835-2023,https://doi.org/10.5194/acp-23-10835-2023, 2023
Short summary
Accelerating models for multiphase chemical kinetics through machine learning with polynomial chaos expansion and neural networks
Thomas Berkemeier, Matteo Krüger, Aryeh Feinberg, Marcel Müller, Ulrich Pöschl, and Ulrich K. Krieger
Geosci. Model Dev., 16, 2037–2054, https://doi.org/10.5194/gmd-16-2037-2023,https://doi.org/10.5194/gmd-16-2037-2023, 2023
Short summary
Aqueous-phase reactive species formed by fine particulate matter from remote forests and polluted urban air
Haijie Tong, Fobang Liu, Alexander Filippi, Jake Wilson, Andrea M. Arangio, Yun Zhang, Siyao Yue, Steven Lelieveld, Fangxia Shen, Helmi-Marja K. Keskinen, Jing Li, Haoxuan Chen, Ting Zhang, Thorsten Hoffmann, Pingqing Fu, William H. Brune, Tuukka Petäjä, Markku Kulmala, Maosheng Yao, Thomas Berkemeier, Manabu Shiraiwa, and Ulrich Pöschl
Atmos. Chem. Phys., 21, 10439–10455, https://doi.org/10.5194/acp-21-10439-2021,https://doi.org/10.5194/acp-21-10439-2021, 2021
Short summary

Related subject area

Subject: Aerosols | Research Activity: Atmospheric Modelling and Data Analysis | Altitude Range: Troposphere | Science Focus: Physics (physical properties and processes)
Aerosol composition, air quality, and boundary layer dynamics in the urban background of Stuttgart in winter
Hengheng Zhang, Wei Huang, Xiaoli Shen, Ramakrishna Ramisetty, Junwei Song, Olga Kiseleva, Christopher Claus Holst, Basit Khan, Thomas Leisner, and Harald Saathoff
Atmos. Chem. Phys., 24, 10617–10637, https://doi.org/10.5194/acp-24-10617-2024,https://doi.org/10.5194/acp-24-10617-2024, 2024
Short summary
Measurement report: Source attribution and estimation of black carbon levels in an urban hotspot of the central Po Valley – an integrated approach combining high-resolution dispersion modelling and micro-aethalometers
Giorgio Veratti, Alessandro Bigi, Michele Stortini, Sergio Teggi, and Grazia Ghermandi
Atmos. Chem. Phys., 24, 10475–10512, https://doi.org/10.5194/acp-24-10475-2024,https://doi.org/10.5194/acp-24-10475-2024, 2024
Short summary
Microphysical modelling of aerosol scavenging by different types of clouds: description and validation of the approach
Pascal Lemaitre, Arnaud Quérel, Alexis Dépée, Alice Guerra Devigne, Marie Monier, Thibault Hiron, Chloé Soto Minguez, Daniel Hardy, and Andrea Flossmann
Atmos. Chem. Phys., 24, 9713–9732, https://doi.org/10.5194/acp-24-9713-2024,https://doi.org/10.5194/acp-24-9713-2024, 2024
Short summary
Insights into the sources of ultrafine particle numbers at six European urban sites obtained by investigating COVID-19 lockdowns
Alex Rowell, James Brean, David C. S. Beddows, Tuukka Petäjä, Máté Vörösmarty, Imre Salma, Jarkko V. Niemi, Hanna E. Manninen, Dominik van Pinxteren, Thomas Tuch, Kay Weinhold, Zongbo Shi, and Roy M. Harrison
Atmos. Chem. Phys., 24, 9515–9531, https://doi.org/10.5194/acp-24-9515-2024,https://doi.org/10.5194/acp-24-9515-2024, 2024
Short summary
In-plume and out-of-plume analysis of aerosol–cloud interactions derived from the 2014–2015 Holuhraun volcanic eruption
Amy H. Peace, Ying Chen, George Jordan, Daniel G. Partridge, Florent Malavelle, Eliza Duncan, and Jim M. Haywood
Atmos. Chem. Phys., 24, 9533–9553, https://doi.org/10.5194/acp-24-9533-2024,https://doi.org/10.5194/acp-24-9533-2024, 2024
Short summary

Cited articles

Adler, G., Koop, T., Haspel, C., Taraniuk, I., Moise, T., Koren, I., Heiblum, R. H., and Rudich, Y.: Formation of highly porous aerosol particles by atmospheric freeze-drying in ice clouds, P. Natl. Acad. Sci. USA, 110, 20414–20419, https://doi.org/10.1073/pnas.1317209110, 2013.
Andreae, M. O. and Rosenfeld, D.: Aerosol-cloud-precipitation interactions. Part 1. The nature and sources of cloud-active aerosols, Earth Sci. Rev., 89, 13–41, https://doi.org/10.1016/j.earscirev.2008.03.001, 2008.
Angell, C. A.: Strong and fragile liquids, in: Relaxations in Complex Systems, edited by: Ngai, K. and Wright, G. B., National Technical Information Service, I.S. Department of Commerce, Springfield, VA, 1985.
Angell, C. A.: Landscapes with megabasins: polyamorphism in liquids and biopolymers and the role of nucleation in folding and folding diseases, Physica D, 107, 122–142, https://doi.org/10.1016/s0167-2789(97)00077-8, 1997.
Baustian, K. J., Wise, M. E., Jensen, E. J., Schill, G. P., Freedman, M. A., and Tolbert, M. A.: State transformations and ice nucleation in amorphous (semi-)solid organic aerosol, Atmos. Chem. Phys., 13, 5615–5628, 10.5194/acp-13-5615-2013, 2013.
Download
Short summary
Glassy organic particles can serve as ice nuclei at low temperatures. We provide a rationale for these findings using a numerical aerosol diffusion model that describes particle phase state and its kinetics during simulated atmospheric updrafts dependent upon composition, size, updraft velocity, temperature and humidity. Our simulations suggest that aerosols from anthropogenic aromatic organics can be particularly relevant for ice cloud formation.
Altmetrics
Final-revised paper
Preprint