Articles | Volume 24, issue 10
https://doi.org/10.5194/acp-24-5887-2024
https://doi.org/10.5194/acp-24-5887-2024
Measurement report
 | 
23 May 2024
Measurement report |  | 23 May 2024

Measurement report: Optical characterization, seasonality, and sources of brown carbon in fine aerosols from Tianjin, North China: year-round observations

Zhichao Dong, Chandra Mouli Pavuluri, Peisen Li, Zhanjie Xu, Junjun Deng, Xueyan Zhao, Xiaomai Zhao, Pingqing Fu, and Cong-Qiang Liu

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Cited articles

Andreae, M. O. and Gelencsér, A.: Black carbon or brown carbon? The nature of light-absorbing carbonaceous aerosols, Atmos. Chem. Phys., 6, 3131–3148, https://doi.org/10.5194/acp-6-3131-2006, 2006. 
Baduel, C., Voisin, D., and Jaffrezo, J. L.: Comparison of analytical methods for Humic Like Substances (HULIS) measurements in atmospheric particles, Atmos. Chem. Phys., 9, 5949–5962, https://doi.org/10.5194/acp-9-5949-2009, 2009. 
Battin, T. J.: Dissolved organic matter and its optical properties in a blackwater tributary of the upper Orinoco river, Venezuela, Org. Geochem., 28, 561–569, https://doi.org/10.1016/S0146-6380(98)00028-X, 1998. 
Birdwell, J. E. and Engel, A. S.: Characterization of dissolved organic matter in cave and spring waters using UV-Vis absorbance and fluorescence spectroscopy, Org. Geochem., 41, 270–280, https://doi.org/10.1016/j.orggeochem.2009.11.002, 2010. 
Bond, T. C. and Bergstrom, R. W.: Light absorption by carbonaceous particles: An investigative review, Aerosol Sci. Tech., 40, 27–67, https://doi.org/10.1080/02786820500421521, 2006. 
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Short summary
Comprehensive study of optical properties of brown carbon (BrC) in fine aerosols from Tianjin, China, implied that biological emissions are major sources of BrC in summer, whereas fossil fuel combustion and biomass burning emissions are in cold periods. The direct radiation absorption caused by BrC in short wavelengths contributed about 40 % to that caused by BrC in 300–700 nm. Water-insoluble but methanol-soluble BrC contains more protein-like chromophores (PLOM) than that of water-soluble BrC.
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