Articles | Volume 23, issue 11
https://doi.org/10.5194/acp-23-6571-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-23-6571-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
15 Jun 2023
Research article |
| 15 Jun 2023
| 15 Jun 2023
Amino acids, carbohydrates, and lipids in the tropical oligotrophic Atlantic Ocean: sea-to-air transfer and atmospheric in situ formation
Manuela van Pinxteren
Atmospheric Chemistry Department (ACD), Leibniz Institute for Tropospheric Research (TROPOS), 04318 Leipzig, Germany
Sebastian Zeppenfeld
Atmospheric Chemistry Department (ACD), Leibniz Institute for Tropospheric Research (TROPOS), 04318 Leipzig, Germany
Khanneh Wadinga Fomba
Atmospheric Chemistry Department (ACD), Leibniz Institute for Tropospheric Research (TROPOS), 04318 Leipzig, Germany
Nadja Triesch
Atmospheric Chemistry Department (ACD), Leibniz Institute for Tropospheric Research (TROPOS), 04318 Leipzig, Germany
now at: Department Safety in the Food Chain, German Federal Institute
for Risk Assessment, 10589 Berlin, Germany
Sanja Frka
Division for Marine and Environmental Research, Ruđer
Bošković Institute, 10000 Zagreb, Croatia
Atmospheric Chemistry Department (ACD), Leibniz Institute for Tropospheric Research (TROPOS), 04318 Leipzig, Germany
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This study represents the primary marine organic aerosol (PMOA) emissions, focusing on their sea–atmosphere transfer. Using the FESOM2.1–REcoM3 model, concentrations of key organic biomolecules were estimated and integrated into the ECHAM6.3–HAM2.3 aerosol–climate model. Results highlight the influence of marine biological activity and surface winds on PMOA emissions, with reasonably good agreement with observations improving aerosol representation in the southern oceans.
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Aerosol particles from sea spray transport inorganic salts and carbohydrates from the ocean into the atmosphere. In this field study conducted in Svalbard, we found that carbohydrates reach elevated altitudes that are relevant for cloud formation and properties.
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This preprint is open for discussion and under review for Biogeosciences (BG).
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We studied how daily cycles affect inorganic carbon variables in the ocean's surface microlayer. Using data from three full days and nights off the Croatian coast, we found that thermohaline properties and key indicators like pH and pCO₂ change significantly from day to night. Ignoring nighttime conditions may lead to global carbon budget errors and highlights the need for continuous ocean observations.
Peng Cheng, Gilles Mailhot, Mohamed Sarakha, Guillaume Voyard, Daniele Scheres Firak, Thomas Schaefer, Hartmut Herrmann, and Marcello Brigante
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Atmos. Chem. Phys., 25, 741–758, https://doi.org/10.5194/acp-25-741-2025, https://doi.org/10.5194/acp-25-741-2025, 2025
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Dimethyl sulfide (DMS) is a crucial natural reactive gas in the global climate system due to its great contribution to aerosols and subsequent impact on clouds over remote oceans. Leveraging machine learning techniques, we constructed a long-term global sea surface DMS gridded dataset with daily resolution. Compared to previous datasets, our new dataset holds promise for improving atmospheric chemistry modeling and advancing our comprehension of the climate effects associated with oceanic DMS.
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An optimized and controlled protocol for generating quasi-adiabatic expansion clouds under simulated dark and light conditions was presented. The irradiated clouds clearly showed a gradual activation of seed particles into droplets. In contrast, non-irradiated clouds faced a flash activation. This paper will lay the foundation for multiphase photochemical studies implying water-soluble volatile organic compounds and particulate matter formation during cloud formation-evaporation cycles.
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Atmos. Chem. Phys., 24, 2583–2605, https://doi.org/10.5194/acp-24-2583-2024, https://doi.org/10.5194/acp-24-2583-2024, 2024
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This study evaluated the air pollution and climate impacts of residential-wood-burning particle emissions from a rural European site. The authors investigate the optical and physical properties that connect the aerosol emissions with climate by evaluating atmospheric radiative impacts via simple-forcing calculations. The study contributes to reducing the lack of information on the understanding of the optical properties of air pollution from anthropogenic sources.
Sebastian Zeppenfeld, Manuela van Pinxteren, Markus Hartmann, Moritz Zeising, Astrid Bracher, and Hartmut Herrmann
Atmos. Chem. Phys., 23, 15561–15587, https://doi.org/10.5194/acp-23-15561-2023, https://doi.org/10.5194/acp-23-15561-2023, 2023
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Marine carbohydrates are produced in the surface of the ocean, enter the atmophere as part of sea spray aerosol particles, and potentially contribute to the formation of fog and clouds. Here, we present the results of a sea–air transfer study of marine carbohydrates conducted in the high Arctic. Besides a chemo-selective transfer, we observed a quick atmospheric aging of carbohydrates, possibly as a result of both biotic and abiotic processes.
Jean-Philippe Putaud, Enrico Pisoni, Alexander Mangold, Christoph Hueglin, Jean Sciare, Michael Pikridas, Chrysanthos Savvides, Jakub Ondracek, Saliou Mbengue, Alfred Wiedensohler, Kay Weinhold, Maik Merkel, Laurent Poulain, Dominik van Pinxteren, Hartmut Herrmann, Andreas Massling, Claus Nordstroem, Andrés Alastuey, Cristina Reche, Noemí Pérez, Sonia Castillo, Mar Sorribas, Jose Antonio Adame, Tuukka Petaja, Katrianne Lehtipalo, Jarkko Niemi, Véronique Riffault, Joel F. de Brito, Augustin Colette, Olivier Favez, Jean-Eudes Petit, Valérie Gros, Maria I. Gini, Stergios Vratolis, Konstantinos Eleftheriadis, Evangelia Diapouli, Hugo Denier van der Gon, Karl Espen Yttri, and Wenche Aas
Atmos. Chem. Phys., 23, 10145–10161, https://doi.org/10.5194/acp-23-10145-2023, https://doi.org/10.5194/acp-23-10145-2023, 2023
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The study focuses on the aerosol chemical variations found in the rural-background station of Melpitz based on ACSM and MAAP measurements. Source apportionment on both organic aerosol (OA) and black carbon (eBC) was performed, and source seasonality was also linked to air mass trajectories. Overall, three anthropogenic sources were identified in OA and eBC plus two additional aged OA. Our results demonstrate the influence of transported coal-combustion-related OA even during summer time.
Yuan Wang, Silvia Henning, Laurent Poulain, Chunsong Lu, Frank Stratmann, Yuying Wang, Shengjie Niu, Mira L. Pöhlker, Hartmut Herrmann, and Alfred Wiedensohler
Atmos. Chem. Phys., 22, 15943–15962, https://doi.org/10.5194/acp-22-15943-2022, https://doi.org/10.5194/acp-22-15943-2022, 2022
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Aerosol particle activation affects cloud, precipitation, radiation, and thus the global climate. Its long-term measurements are important but still scarce. In this study, more than 4 years of measurements at a central European station were analyzed. The overall characteristics and seasonal changes of aerosol particle activation are summarized. The power-law fit between particle hygroscopicity factor and diameter was recommended for predicting cloud
condensation nuclei number concentration.
Christian Tatzelt, Silvia Henning, André Welti, Andrea Baccarini, Markus Hartmann, Martin Gysel-Beer, Manuela van Pinxteren, Robin L. Modini, Julia Schmale, and Frank Stratmann
Atmos. Chem. Phys., 22, 9721–9745, https://doi.org/10.5194/acp-22-9721-2022, https://doi.org/10.5194/acp-22-9721-2022, 2022
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We present the abundance and origin of cloud-relevant aerosol particles in the preindustral-like conditions of the Southern Ocean (SO) during austral summer. Cloud condensation nuclei (CCN) and ice-nucleating particles (INP) were measured during a circum-Antarctic scientific cruise with in situ instrumentation and offline filter measurements, respectively. Transport processes were found to play an equally important role as local sources for both the CCN and INP population of the SO.
Lady Mateus-Fontecha, Angela Vargas-Burbano, Rodrigo Jimenez, Nestor Y. Rojas, German Rueda-Saa, Dominik van Pinxteren, Manuela van Pinxteren, Khanneh Wadinga Fomba, and Hartmut Herrmann
Atmos. Chem. Phys., 22, 8473–8495, https://doi.org/10.5194/acp-22-8473-2022, https://doi.org/10.5194/acp-22-8473-2022, 2022
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This study reports the chemical composition of regionally representative PM2.5 in an area densely populated and substantially industrialized, located in the inter-Andean valley, with the highest sugarcane yield in the world and where sugarcane is burned and harvested year round. We found that sugarcane burning is not portrayed as a distinguishable sample composition component. Instead, the composition analysis revealed multiple associations among sugarcane burning components and other sources.
Manuela van Pinxteren, Tiera-Brandy Robinson, Sebastian Zeppenfeld, Xianda Gong, Enno Bahlmann, Khanneh Wadinga Fomba, Nadja Triesch, Frank Stratmann, Oliver Wurl, Anja Engel, Heike Wex, and Hartmut Herrmann
Atmos. Chem. Phys., 22, 5725–5742, https://doi.org/10.5194/acp-22-5725-2022, https://doi.org/10.5194/acp-22-5725-2022, 2022
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A class of marine particles (transparent exopolymer particles, TEPs) that is ubiquitously found in the world oceans was measured for the first time in ambient marine aerosol particles and marine cloud waters in the tropical Atlantic Ocean. TEPs are likely to have good properties for influencing clouds. We show that TEPs are transferred from the ocean to the marine atmosphere via sea-spray formation and our results suggest that they can also form directly in aerosol particles and in cloud water.
Kristina Glojek, Griša Močnik, Honey Dawn C. Alas, Andrea Cuesta-Mosquera, Luka Drinovec, Asta Gregorič, Matej Ogrin, Kay Weinhold, Irena Ježek, Thomas Müller, Martin Rigler, Maja Remškar, Dominik van Pinxteren, Hartmut Herrmann, Martina Ristorini, Maik Merkel, Miha Markelj, and Alfred Wiedensohler
Atmos. Chem. Phys., 22, 5577–5601, https://doi.org/10.5194/acp-22-5577-2022, https://doi.org/10.5194/acp-22-5577-2022, 2022
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A pilot study to determine the emissions of wood burning under
real-world laboratoryconditions was conducted. We found that measured black carbon (eBC) and particulate matter (PM) in rural shallow terrain depressions with residential wood burning could be much greater than predicted by models. The exceeding levels are a cause for concern since similar conditions can be expected in numerous hilly and mountainous regions across Europe, where approximately 20 % of the total population lives.
Nabil Deabji, Khanneh Wadinga Fomba, Souad El Hajjaji, Abdelwahid Mellouki, Laurent Poulain, Sebastian Zeppenfeld, and Hartmut Herrmann
Atmos. Chem. Phys., 21, 18147–18174, https://doi.org/10.5194/acp-21-18147-2021, https://doi.org/10.5194/acp-21-18147-2021, 2021
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Mountain and high-altitude sites provide representative data for the lower free troposphere, various pathways for aerosol interactions, and changing boundary layer heights useful in understanding atmospheric composition. However, only few studies exist in African regions despite diversity in both natural and anthropogenic emissions. This study provides detailed atmospheric studies in the northern African high-altitude region.
Andreas Tilgner, Thomas Schaefer, Becky Alexander, Mary Barth, Jeffrey L. Collett Jr., Kathleen M. Fahey, Athanasios Nenes, Havala O. T. Pye, Hartmut Herrmann, and V. Faye McNeill
Atmos. Chem. Phys., 21, 13483–13536, https://doi.org/10.5194/acp-21-13483-2021, https://doi.org/10.5194/acp-21-13483-2021, 2021
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Feedbacks of acidity and atmospheric multiphase chemistry in deliquesced particles and clouds are crucial for the tropospheric composition, depositions, climate, and human health. This review synthesizes the current scientific knowledge on these feedbacks using both inorganic and organic aqueous-phase chemistry. Finally, this review outlines atmospheric implications and highlights the need for future investigations with respect to reducing emissions of key acid precursors in a changing world.
R. Anthony Cox, Markus Ammann, John N. Crowley, Paul T. Griffiths, Hartmut Herrmann, Erik H. Hoffmann, Michael E. Jenkin, V. Faye McNeill, Abdelwahid Mellouki, Christopher J. Penkett, Andreas Tilgner, and Timothy J. Wallington
Atmos. Chem. Phys., 21, 13011–13018, https://doi.org/10.5194/acp-21-13011-2021, https://doi.org/10.5194/acp-21-13011-2021, 2021
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The term open-air factor was coined in the 1960s, establishing that rural air had powerful germicidal properties possibly resulting from immediate products of the reaction of ozone with alkenes, unsaturated compounds ubiquitously present in natural and polluted environments. We have re-evaluated those early experiments, applying the recently substantially improved knowledge, and put them into the context of the lifetime of aerosol-borne pathogens that are so important in the Covid-19 pandemic.
Markus Hartmann, Xianda Gong, Simonas Kecorius, Manuela van Pinxteren, Teresa Vogl, André Welti, Heike Wex, Sebastian Zeppenfeld, Hartmut Herrmann, Alfred Wiedensohler, and Frank Stratmann
Atmos. Chem. Phys., 21, 11613–11636, https://doi.org/10.5194/acp-21-11613-2021, https://doi.org/10.5194/acp-21-11613-2021, 2021
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Ice-nucleating particles (INPs) are not well characterized in the Arctic despite their importance for the Arctic energy budget. Little is known about their nature (mineral or biological) and sources (terrestrial or marine, long-range transport or local). We find indications that, at the beginning of the melt season, a local, biogenic, probably marine source is likely, but significant enrichment of INPs has to take place from the ocean to the aerosol phase.
Anke Mutzel, Yanli Zhang, Olaf Böge, Maria Rodigast, Agata Kolodziejczyk, Xinming Wang, and Hartmut Herrmann
Atmos. Chem. Phys., 21, 8479–8498, https://doi.org/10.5194/acp-21-8479-2021, https://doi.org/10.5194/acp-21-8479-2021, 2021
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This study investigates secondary organic aerosol (SOA) formation and particle growth from α-pinene, limonene, and m-cresol oxidation through NO3 and OH radicals and the effect of relative humidity. The formed SOA is comprehensively characterized with respect to the content of OC / EC, WSOC, SOA-bound peroxides, and SOA marker compounds. The findings present new insights and implications of nighttime chemistry, which can form SOA more efficiently than OH radical reaction during daytime.
Abdelwahid Mellouki, Markus Ammann, R. Anthony Cox, John N. Crowley, Hartmut Herrmann, Michael E. Jenkin, V. Faye McNeill, Jürgen Troe, and Timothy J. Wallington
Atmos. Chem. Phys., 21, 4797–4808, https://doi.org/10.5194/acp-21-4797-2021, https://doi.org/10.5194/acp-21-4797-2021, 2021
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Volatile organic compounds play an important role in atmospheric chemistry. This article, the eighth in the series, presents kinetic and photochemical data sheets evaluated by the IUPAC Task Group on Atmospheric Chemical Kinetic Data Evaluation. It covers the gas-phase reactions of organic species with four, or more, carbon atoms (≥ C4) including thermal reactions of closed-shell organic species with HO and NO3 radicals and their photolysis. These data are important for atmospheric models.
Nadja Triesch, Manuela van Pinxteren, Sanja Frka, Christian Stolle, Tobias Spranger, Erik Hans Hoffmann, Xianda Gong, Heike Wex, Detlef Schulz-Bull, Blaženka Gašparović, and Hartmut Herrmann
Atmos. Chem. Phys., 21, 4267–4283, https://doi.org/10.5194/acp-21-4267-2021, https://doi.org/10.5194/acp-21-4267-2021, 2021
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To investigate the source of lipids and their representatives in the marine atmosphere, concerted measurements of seawater and submicrometer aerosol particle sampling were carried out on the Cabo Verde islands. This field study describes the biogenic sources of lipids, their selective transfer from the ocean into the atmosphere and their enrichment as part of organic matter. A strong enrichment of the studied representatives of the lipid classes on submicrometer aerosol particles was observed.
Laurent Poulain, Benjamin Fahlbusch, Gerald Spindler, Konrad Müller, Dominik van Pinxteren, Zhijun Wu, Yoshiteru Iinuma, Wolfram Birmili, Alfred Wiedensohler, and Hartmut Herrmann
Atmos. Chem. Phys., 21, 3667–3684, https://doi.org/10.5194/acp-21-3667-2021, https://doi.org/10.5194/acp-21-3667-2021, 2021
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We present results from source apportionment analysis on the carbonaceous aerosol particles, including organic aerosol (OA) and equivalent black carbon (eBC), allowing us to distinguish local emissions from long-range transport for OA and eBC sources. By merging online chemical measurements and considering particle number size distribution, the different air masses reaching the sampling place were described and discussed, based on their respective chemical composition and size distribution.
Jing Dou, Peter A. Alpert, Pablo Corral Arroyo, Beiping Luo, Frederic Schneider, Jacinta Xto, Thomas Huthwelker, Camelia N. Borca, Katja D. Henzler, Jörg Raabe, Benjamin Watts, Hartmut Herrmann, Thomas Peter, Markus Ammann, and Ulrich K. Krieger
Atmos. Chem. Phys., 21, 315–338, https://doi.org/10.5194/acp-21-315-2021, https://doi.org/10.5194/acp-21-315-2021, 2021
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Photochemistry of iron(III) complexes plays an important role in aerosol aging, especially in the lower troposphere. Ensuing radical chemistry leads to decarboxylation, and the production of peroxides, and oxygenated volatile compounds, resulting in particle mass loss due to release of the volatile products to the gas phase. We investigated kinetic transport limitations due to high particle viscosity under low relative humidity conditions. For quantification a numerical model was developed.
Nadja Triesch, Manuela van Pinxteren, Anja Engel, and Hartmut Herrmann
Atmos. Chem. Phys., 21, 163–181, https://doi.org/10.5194/acp-21-163-2021, https://doi.org/10.5194/acp-21-163-2021, 2021
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To investigate the sources of free amino acids (FAAs) in the marine atmosphere, concerted measurements (the simultaneous investigation of seawater, size-segregated aerosol particles and cloud water) were performed at the Cabo Verde islands. This study describes the transfer of FAAs as part of organic matter from the ocean into the atmosphere on a molecular level. In the investigated marine environment, a high enrichment of FAAs in submicron aerosol particles and in cloud droplets was observed.
André Welti, E. Keith Bigg, Paul J. DeMott, Xianda Gong, Markus Hartmann, Mike Harvey, Silvia Henning, Paul Herenz, Thomas C. J. Hill, Blake Hornblow, Caroline Leck, Mareike Löffler, Christina S. McCluskey, Anne Marie Rauker, Julia Schmale, Christian Tatzelt, Manuela van Pinxteren, and Frank Stratmann
Atmos. Chem. Phys., 20, 15191–15206, https://doi.org/10.5194/acp-20-15191-2020, https://doi.org/10.5194/acp-20-15191-2020, 2020
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Ship-based measurements of maritime ice nuclei concentrations encompassing all oceans are compiled. From this overview it is found that maritime ice nuclei concentrations are typically 10–100 times lower than over continents, while concentrations are surprisingly similar in different oceanic regions. The analysis of the influence of ship emissions shows no effect on the data, making ship-based measurements an efficient strategy for the large-scale exploration of ice nuclei concentrations.
Jiarong Li, Chao Zhu, Hui Chen, Defeng Zhao, Likun Xue, Xinfeng Wang, Hongyong Li, Pengfei Liu, Junfeng Liu, Chenglong Zhang, Yujing Mu, Wenjin Zhang, Luming Zhang, Hartmut Herrmann, Kai Li, Min Liu, and Jianmin Chen
Atmos. Chem. Phys., 20, 13735–13751, https://doi.org/10.5194/acp-20-13735-2020, https://doi.org/10.5194/acp-20-13735-2020, 2020
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Based on a field study at Mt. Tai, China, the simultaneous variations of cloud microphysics, aerosol microphysics and their potential interactions during cloud life cycles were discussed. Results demonstrated that clouds on clean days were more susceptible to the concentrations of particle number, while clouds formed on polluted days might be more sensitive to meteorological parameters. Particles larger than 150 nm played important roles in forming cloud droplets with sizes of 5–10 μm.
R. Anthony Cox, Markus Ammann, John N. Crowley, Hartmut Herrmann, Michael E. Jenkin, V. Faye McNeill, Abdelwahid Mellouki, Jürgen Troe, and Timothy J. Wallington
Atmos. Chem. Phys., 20, 13497–13519, https://doi.org/10.5194/acp-20-13497-2020, https://doi.org/10.5194/acp-20-13497-2020, 2020
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Criegee intermediates, formed from alkene–ozone reactions, play a potentially important role as tropospheric oxidants. Evaluated kinetic data are provided for reactions governing their formation and removal for use in atmospheric models. These include their formation from reactions of simple and complex alkenes and removal by decomposition and reaction with a number of atmospheric species (e.g. H2O, SO2). An overview of the tropospheric chemistry of Criegee intermediates is also provided.
Yangang Ren, Bastian Stieger, Gerald Spindler, Benoit Grosselin, Abdelwahid Mellouki, Thomas Tuch, Alfred Wiedensohler, and Hartmut Herrmann
Atmos. Chem. Phys., 20, 13069–13089, https://doi.org/10.5194/acp-20-13069-2020, https://doi.org/10.5194/acp-20-13069-2020, 2020
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We present HONO measurements from the TROPOS research site in Melpitz, Germany. Investigations of HONO sources and sinks revealed the nighttime formation by heterogeneous conversion of NO2 to HONO followed by a significant surface deposition at night. The evaporation of dew was identified as the main HONO source in the morning. In the following, dew measurements with a self-made dew collector were performed to estimate the amount of evaporated HONO from dew in the atmospheric HONO distribution.
Laurent Poulain, Gerald Spindler, Achim Grüner, Thomas Tuch, Bastian Stieger, Dominik van Pinxteren, Jean-Eudes Petit, Olivier Favez, Hartmut Herrmann, and Alfred Wiedensohler
Atmos. Meas. Tech., 13, 4973–4994, https://doi.org/10.5194/amt-13-4973-2020, https://doi.org/10.5194/amt-13-4973-2020, 2020
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The stability and the comparability between ACSM and collocated filter sampling and MPSS measurements was investigated in order to examine the instruments robustness for year-long measurements. Specific attention was paid to the influence of the upper size cutoff diameter to better understand how it might affect the data validation. Recommendations are provided for better on-site quality assurance and quality control of the ACSM, which would be useful for either long-term or intensive campaigns.
Cited articles
Abbatt, J. P. D., Leaitch, W. R., Aliabadi, A. A., Bertram, A. K., Blanchet, J.-P., Boivin-Rioux, A., Bozem, H., Burkart, J., Chang, R. Y. W., Charette, J., Chaubey, J. P., Christensen, R. J., Cirisan, A., Collins, D. B., Croft, B., Dionne, J., Evans, G. J., Fletcher, C. G., Galí, M., Ghahreman, R., Girard, E., Gong, W., Gosselin, M., Gourdal, M., Hanna, S. J., Hayashida, H., Herber, A. B., Hesaraki, S., Hoor, P., Huang, L., Hussherr, R., Irish, V. E., Keita, S. A., Kodros, J. K., Köllner, F., Kolonjari, F., Kunkel, D., Ladino, L. A., Law, K., Levasseur, M., Libois, Q., Liggio, J., Lizotte, M., Macdonald, K. M., Mahmood, R., Martin, R. V., Mason, R. H., Miller, L. A., Moravek, A., Mortenson, E., Mungall, E. L., Murphy, J. G., Namazi, M., Norman, A.-L., O'Neill, N. T., Pierce, J. R., Russell, L. M., Schneider, J., Schulz, H., Sharma, S., Si, M., Staebler, R. M., Steiner, N. S., Thomas, J. L., von Salzen, K., Wentzell, J. J. B., Willis, M. D., Wentworth, G. R., Xu, J.-W., and Yakobi-Hancock, J. D.: Overview paper: New insights into aerosol and climate in the Arctic, Atmos. Chem. Phys., 19, 2527–2560, https://doi.org/10.5194/acp-19-2527-2019, 2019.
Aller, J. Y., Radway, J. C., Kilthau, W. P., Bothe, D. W., Wilson, T. W.,
Vaillancourt, R. D., Quinn, P. K., Coffman, D. J., Murray, B. J., and Knopf,
D. A.: Size-resolved characterization of the polysaccharidic and
proteinaceous components of sea spray aerosol, Atmos. Environ., 154,
331–347, https://doi.org/10.1016/j.atmosenv.2017.01.053, 2017.
Barbaro, E., Zangrando, R., Vecchiato, M., Piazza, R., Cairns, W. R. L., Capodaglio, G., Barbante, C., and Gambaro, A.: Free amino acids in Antarctic aerosol: potential markers for the evolution and fate of marine aerosol, Atmos. Chem. Phys., 15, 5457–5469, https://doi.org/10.5194/acp-15-5457-2015, 2015.
Beaupre, S. R., Kieber, D. J., Keene, W. C., Long, M. S., Maben, J. R., Lu,
X., Zhu, Y. T., Frossard, A. A., Section, J. D. K., Duplessis, P., Chang, R.
Y. W., and Bisgrove, J.: Oceanic efflux of ancient marine dissolved organic
carbon in primary marine aerosol, Sci. Adv., 5, eaax653,
https://doi.org/10.1126/sciadv.aax6535, 2019.
Bertram, T. H., Cochran, R. E., Grassian, V. H., and Stone, E. A.: Sea spray
aerosol chemical composition: elemental and molecular mimics for laboratory
studies of heterogeneous and multiphase reactions, Chem. Soc. Rev.,
47, 2374–2400, https://doi.org/10.1039/c7cs00008a, 2018.
Bianco, A., Deguillaume, L., Chaumerliac, N., Vaïtilingom, M., Wang,
M., Delort, A.-M., and Bridoux, M. C.: Effect of endogenous microbiota on
the molecular composition of cloud water: a study by Fourier-transform ion
cyclotron resonance mass spectrometry (FT-ICR MS), Sci. Rep., 9,
7663, https://doi.org/10.1038/s41598-019-44149-8, 2019.
Brooks, S. D. and Thornton, D. C. O.: Marine Aerosols and Clouds, in:
Annual Review of Marine Science, Vol. 10, edited by: Carlson, C. A. and
Giovannoni, S. J., Annual Review of Marine Science, Annual Reviews, Palo
Alto, 289–313, https://doi.org/10.1146/annurev-marine-121916-063148, 2018.
Burrows, S. M., Hoose, C., Pöschl, U., and Lawrence, M. G.: Ice nuclei in marine air: biogenic particles or dust?, Atmos. Chem. Phys., 13, 245–267, https://doi.org/10.5194/acp-13-245-2013, 2013.
Burrows, S. M., Ogunro, O., Frossard, A. A., Russell, L. M., Rasch, P. J., and Elliott, S. M.: A physically based framework for modeling the organic fractionation of sea spray aerosol from bubble film Langmuir equilibria, Atmos. Chem. Phys., 14, 13601–13629, https://doi.org/10.5194/acp-14-13601-2014, 2014.
Burrows, S. M., Gobrogge, E., Fu, L., Link, K., Elliott, S. M., Wang, H. F.,
and Walker, R.: OCEANFILMS-2: Representing coadsorption of saccharides in
marine films and potential impacts on modeled marine aerosol chemistry,
Geophys. Res. Lett., 43, 8306–8313, https://doi.org/10.1002/2016gl069070, 2016.
Capone, D. G., Ferrier, M. D., and Carpenter, E. J.: Amino Acid Cycling in
Colonies of the Planktonic Marine Cyanobacterium TRICHODESMIUM-THIEBAUTII,
Appl. Environ. Microb., 60, 3989–3995,
https://doi.org/10.1128/aem.60.11.3989-3995.1994, 1994.
Carpenter, E. J., Bergman, B., Dawson, R., Siddiqui, P. J. A., Soderback,
E., and Capone, D. G.: Glutamine Synthetase and Nitrogen Cycling in Colinies
of the Marine Diazotrophic Cyanobacteria TRICHODESMIUM SPP, Appl.
Environ. Microb., 58, 3122–3129, https://doi.org/10.1128/aem.58.9.3122-3129.1992,
1992.
Carpenter, L. J., Fleming, Z. L., Read, K. A., Lee, J. D., Moller, S. J.,
Hopkins, J. R., Purvis, R. M., Lewis, A. C., Müller, K., Heinold, B.,
Herrmann, H., Fomba, K. W., van Pinxteren, D., Müller, C., Tegen, I.,
Wiedensohler, A., Müller, T., Niedermeier, N., Achterberg, E. P., Patey,
M. D., Kozlova, E. A., Heimann, M., Heard, D. E., Plane, J. M. C., Mahajan,
A., Oetjen, H., Ingham, T., Stone, D., Whalley, L. K., Evans, M. J.,
Pilling, M. J., Leigh, R. J., Monks, P. S., Karunaharan, A., Vaughan, S.,
Arnold, S. R., Tschritter, J., Pohler, D., Friess, U., Holla, R., Mendes, L.
M., Lopez, H., Faria, B., Manning, A. J., and Wallace, D. W. R.: Seasonal
characteristics of tropical marine boundary layer air measured at the Cape
Verde Atmospheric Observatory, J. Atmos. Chem., 67, 87–140,
https://doi.org/10.1007/s10874-011-9206-1, 2010.
Casillo, A., Lanzetta, R., Parrilli, M., and Corsaro, M. M.:
Exopolysaccharides from Marine and Marine Extremophilic Bacteria:
Structures, Properties, Ecological Roles and Applications, Mar. Drugs, 16, 69,
https://doi.org/10.3390/md16020069, 2018.
Cavalli, F., Viana, M., Yttri, K. E., Genberg, J., and Putaud, J.-P.: Toward a standardised thermal-optical protocol for measuring atmospheric organic and elemental carbon: the EUSAAR protocol, Atmos. Meas. Tech., 3, 79–89, https://doi.org/10.5194/amt-3-79-2010, 2010.
Chen, Q., Guo, Z. G., Yu, M., Sachs, J. P., Hou, P. F., Li, L., Jin, G. E.,
Liu, Y. Y., and Zhao, M. X.: Lipid biomarker estimates of seasonal
variations of aerosol organic carbon sources in coastal Qingdao, China,
Org. Geochem., 151, 104148, https://doi.org/10.1016/j.orggeochem.2020.104148, 2021.
Choi, J. H., Jang, E., Yoon, Y. J., Park, J. Y., Kim, T. W., Becagli, S.,
Caiazzo, L., Cappelletti, D., Krejci, R., Eleftheria, K., Park, K. T., and
Jang, K. S.: Influence of Biogenic Organics on the Chemical Composition of
Arctic Aerosols, Global Biogeochem. Cy., 33, 1238–1250,
https://doi.org/10.1029/2019gb006226, 2019.
Cochran, R. E., Ryder, O. S., Grassian, V. H., and Prather, K. A.: Sea Spray
Aerosol: The Chemical Link between the Oceans, Atmosphere, and Climate,
Accounts Chem. Res., 50, 599–604, https://doi.org/10.1021/acs.accounts.6b00603, 2017.
Cravigan, L. T., Mallet, M. D., Vaattovaara, P., Harvey, M. J., Law, C. S., Modini, R. L., Russell, L. M., Stelcer, E., Cohen, D. D., Olsen, G., Safi, K., Burrell, T. J., and Ristovski, Z.: Sea spray aerosol organic enrichment, water uptake and surface tension effects, Atmos. Chem. Phys., 20, 7955–7977, https://doi.org/10.5194/acp-20-7955-2020, 2020.
Cunliffe, M. and Wurl, O.: Guide to best practices to study the ocean's
surface, Occasional Publications of the Marine Biological Association of
the United Kingdom, Plymouth, UK, 118 pp., https://plymsea.ac.uk/id/eprint/6523/ (last access: 24 May 2023),
2014.
Cunliffe, M., Engel, A., Frka, S., Gasparovic, B., Guitart, C., Murrell, J.
C., Salter, M., Stolle, C., Upstill-Goddard, R., and Wurl, O.: Sea surface
microlayers: A unified physicochemical and biological perspective of the
air-ocean interface, Prog. Oceanogr., 109, 104–116,
https://doi.org/10.1016/j.pocean.2012.08.004, 2013.
Decesari, S., Paglione, M., Rinaldi, M., Dall'Osto, M., Simó, R., Zanca, N., Volpi, F., Facchini, M. C., Hoffmann, T., Götz, S., Kampf, C. J., O'Dowd, C., Ceburnis, D., Ovadnevaite, J., and Tagliavini, E.: Shipborne measurements of Antarctic submicron organic aerosols: an NMR perspective linking multiple sources and bioregions, Atmos. Chem. Phys., 20, 4193–4207, https://doi.org/10.5194/acp-20-4193-2020, 2020.
Dominutti, P. A., Renard, P., Vaïtilingom, M., Bianco, A., Baray, J.-L., Borbon, A., Bourianne, T., Burnet, F., Colomb, A., Delort, A.-M., Duflot, V., Houdier, S., Jaffrezo, J.-L., Joly, M., Leremboure, M., Metzger, J.-M., Pichon, J.-M., Ribeiro, M., Rocco, M., Tulet, P., Vella, A., Leriche, M., and Deguillaume, L.: Insights into tropical cloud chemistry in Réunion (Indian Ocean): results from the BIO-MAÏDO campaign, Atmos. Chem. Phys., 22, 505–533, https://doi.org/10.5194/acp-22-505-2022, 2022.
Engel, A. and Galgani, L.: The organic sea-surface microlayer in the upwelling region off the coast of Peru and potential implications for air–sea exchange processes, Biogeosciences, 13, 989–1007, https://doi.org/10.5194/bg-13-989-2016, 2016.
Engel, A., Bange, H., Cunliffe, M., Burrows, S., Friedrichs, G., Galgani,
L., Herrmann, H., Hertkorn, N., Johnson, M., Liss, P., Quinn, P., Schartau,
M., Soloviev, A., Stolle, C., Upstill-Goddard, R., van Pinxteren, M., and
Zäncker, B.: The Ocean's Vital Skin: Toward an Integrated Understanding
of the Sea Surface Microlayer, Front. Mar. Sci., 4, 165, https://doi.org/10.3389/fmars.2017.00165, 2017.
Ervens, B. and Amato, P.: The global impact of bacterial processes on carbon mass, Atmos. Chem. Phys., 20, 1777–1794, https://doi.org/10.5194/acp-20-1777-2020, 2020.
Facchini, M. C., Rinaldi, M., Decesari, S., Carbone, C., Finessi, E.,
Mircea, M., Fuzzi, S., Ceburnis, D., Flanagan, R., Nilsson, E. D., de Leeuw,
G., Martino, M., Woeltjen, J., and O'Dowd, C. D.: Primary submicron marine
aerosol dominated by insoluble organic colloids and aggregates, Geophys.
Res. Lett., 35, L17814, https://doi.org/10.1029/2008gl034210, 2008.
Fomba, K. W., Müller, K., van Pinxteren, D., and Herrmann, H.: Aerosol size-resolved trace metal composition in remote northern tropical Atlantic marine environment: case study Cape Verde islands, Atmos. Chem. Phys., 13, 4801–4814, https://doi.org/10.5194/acp-13-4801-2013, 2013.
Fomba, K. W., Müller, K., van Pinxteren, D., Poulain, L., van Pinxteren, M., and Herrmann, H.: Long-term chemical characterization of tropical and marine aerosols at the Cape Verde Atmospheric Observatory (CVAO) from 2007 to 2011, Atmos. Chem. Phys., 14, 8883–8904, https://doi.org/10.5194/acp-14-8883-2014, 2014.
Franklin, D., Poulton, J. A., Steinke, M., Young, J., Peeken, I., and Malin,
G.: Dimethylsulphide, DMSP-lyase activity and microplankton community
structure inside and outside of the Mauritanian upwelling, Prog.
Oceanogr., 83, 134–142, 2009.
Frka, S., Pogorzelski, S., Kozarac, Z., and Ćosović, B.:
Physicochemical Signatures of Natural Sea Films from Middle Adriatic
Stations, J. Phys. Chem. A, 116, 6552–6559,
https://doi.org/10.1021/jp212430a, 2012.
Frossard, A. A., Russell, L. M., Burrows, S. M., Elliott, S. M., Bates, T.
S., and Quinn, P. K.: Sources and composition of submicron organic mass in
marine aerosol particles, J. Geophys. Res.-Atmos., 119,
12977–13003, https://doi.org/10.1002/2014jd021913, 2014.
Fu, P., Kawamura, K., and Miura, K.: Molecular characterization of marine
organic aerosols collected during a round-the-world cruise, J.
Geophys. Res.-Atmos., 116, D13302, https://doi.org/10.1029/2011jd015604, 2011.
Gantt, B. and Meskhidze, N.: The physical and chemical characteristics of marine primary organic aerosol: a review, Atmos. Chem. Phys., 13, 3979–3996, https://doi.org/10.5194/acp-13-3979-2013, 2013.
Gašparović, B., Kazazić, S. P., Cvitešić, A.,
Penezić, A., and Frka, S.: Improved separation and analysis of
glycolipids by Iatroscan thin-layer chromatography-flame ionization
detection, J. Chromatogr. A, 1409, 259–267,
https://doi.org/10.1016/j.chroma.2015.07.047, 2015.
Gašparović, B., Kazazić, S. P., Cvitešić, A.,
Penezić, A., and Frka, S.: Improved separation and analysis of
glycolipids by Iatroscan thin-layer chromatography-flame ionization
detection (vol 1409, pg 259, 2015), J. Chromatogr. A, 1521,
168–169, https://doi.org/10.1016/j.chroma.2017.09.038, 2017.
Haddrell, A. E. and Thomas, R. J.: Aerobiology: Experimental
Considerations, Observations, and Future Tools, Appl. Environ.
Microb., 83, e00809-17, https://doi.org/10.1128/aem.00809-17, 2017.
Hardy, J. T.: The Sea-Surface Microlayer – Biology, Chemistry and
Antrophogenic Enrichment, Prog. Oceanogr., 11, 307–328,
https://doi.org/10.1016/0079-6611(82)90001-5, 1982.
Hasenecz, E. S., Kaluarachchi, C. P., Lee, H. D., Tivanski, A. V., and
Stone, E. A.: Saccharide Transfer to Sea Spray Aerosol Enhanced by Surface
Activity, Calcium, and Protein Interactions, ACS Earth Space Chem., 3,
2539–2548, https://doi.org/10.1021/acsearthspacechem.9b00197, 2019.
Hepach, H., Quack, B., Ziska, F., Fuhlbrügge, S., Atlas, E. L., Krüger, K., Peeken, I., and Wallace, D. W. R.: Drivers of diel and regional variations of halocarbon emissions from the tropical North East Atlantic, Atmos. Chem. Phys., 14, 1255–1275, https://doi.org/10.5194/acp-14-1255-2014, 2014.
Jaber, S., Joly, M., Brissy, M., Leremboure, M., Khaled, A., Ervens, B., and Delort, A.-M.: Biotic and abiotic transformation of amino acids in cloud water: experimental studies and atmospheric implications, Biogeosciences, 18, 1067–1080, https://doi.org/10.5194/bg-18-1067-2021, 2021.
Kawamura, K., Ishimura, Y., and Yamazaki, K.: Four years' observations of
terrestrial lipid class compounds in marine aerosols from the western North
Pacific, Global Biogeochem. Cy., 17, 3-1–3-19, https://doi.org/10.1029/2001gb001810, 2003.
Keene, W. C., Maring, H., Maben, J. R., Kieber, D. J., Pszenny, A. A. P.,
Dahl, E. E., Izaguirre, M. A., Davis, A. J., Long, M. S., Zhou, X.,
Smoydzin, L., and Sander, R.: Chemical and physical characteristics of
nascent aerosols produced by bursting bubbles at a model air-sea interface,
J. Geophys. Res.-Atmos., 112, D21202, https://doi.org/10.1029/2007jd008464,
2007.
Khaled, A., Zhang, M., Amato, P., Delort, A.-M., and Ervens, B.: Biodegradation by bacteria in clouds: an underestimated sink for some organics in the atmospheric multiphase system, Atmos. Chem. Phys., 21, 3123–3141, https://doi.org/10.5194/acp-21-3123-2021, 2021.
Kieber, D. J., Keene, W. C., Frossard, A. A., Long, M. S., Maben, J. R.,
Russell, L. M., Kinsey, J. D., Tyssebotn, I. M. B., Quinn, P. K., and Bates,
T. S.: Coupled ocean-atmosphere loss of marine refractory dissolved organic
carbon, Geophys. Res. Lett., 43, 2765–2772, https://doi.org/10.1002/2016gl068273,
2016.
Klein, A. M., Bohannan, B. J. M., Jaffe, D. A., Levin, D. A., and Green, J.
L.: Molecular Evidence for Metabolically Active Bacteria in the Atmosphere,
Front. Microbiol., 7, 772, https://doi.org/10.3389/fmicb.2016.00772, 2016.
Krembs, C., Eicken, H., Junge, K., and Deming, J. W.: High concentrations of
exopolymeric substances in Arctic winter sea ice: implications for the polar
ocean carbon cycle and cryoprotection of diatoms, Deep-Sea Res. Pt.
I, 49, 2163–2181,
https://doi.org/10.1016/s0967-0637(02)00122-x, 2002.
Kuznetsova, M. and Lee, C.: Enhanced extracellular enzymatic peptide
hydrolysis in the sea-surface microlayer, Mar. Chem., 73, 319–332,
https://doi.org/10.1016/s0304-4203(00)00116-x, 2001.
Kuznetsova, M. and Lee, C.: Dissolved free and combined amino acids in
nearshore seawater, sea surface microlayers and foams: Influence of
extracellular hydrolysis, Aquat. Sci., 64, 252–268,
https://doi.org/10.1007/s00027-002-8070-0, 2002.
Kuznetsova, M., Lee, C., Aller, J., and Frew, N.: Enrichment of amino acids
in the sea surface microlayer at coastal and open ocean sites in the North
Atlantic Ocean, Limnol. Oceanogr., 49, 1605–1619, 2004.
Kuznetsova, M., Lee, C., and Aller, J.: Characterization of the
proteinaceous matter in marine aerosols, Mar. Chem., 96, 359–377,
https://doi.org/10.1016/j.marchem.2005.03.007, 2005.
Lass, K. and Friedrichs, G.: Revealing structural properties of the marine
nanolayer from vibrational sum frequency generation spectra, J. Geophys.
Res.-Oceans, 116, C08042, https://doi.org/10.1029/2010jc006609, 2011.
Lawler, M. J., Lewis, S. L., Russell, L. M., Quinn, P. K., Bates, T. S., Coffman, D. J., Upchurch, L. M., and Saltzman, E. S.: North Atlantic marine organic aerosol characterized by novel offline thermal desorption mass spectrometry: polysaccharides, recalcitrant material, and secondary organics, Atmos. Chem. Phys., 20, 16007–16022, https://doi.org/10.5194/acp-20-16007-2020, 2020.
Leck, C., Gao, Q., Mashayekhy Rad, F., and Nilsson, U.: Size-resolved atmospheric particulate polysaccharides in the high summer Arctic, Atmos. Chem. Phys., 13, 12573–12588, https://doi.org/10.5194/acp-13-12573-2013, 2013.
Link, K. A., Spurzem, G. N., Tuladhar, A., Chase, Z., Wang, Z. M., Wang, H.
F., and Walker, R. A.: Organic Enrichment at Aqueous Interfaces: Cooperative
Adsorption of Glucuronic Acid to DPPC Monolayers Studied with Vibrational
Sum Frequency Generation, J. Phys. Chem. A, 123, 5621–5632,
https://doi.org/10.1021/acs.jpca.9b02255, 2019.
Liss, P. S. and Duce, R. A.: The sea surface and global change,
Cambridge University Press, Cambridge, https://doi.org/10.1017/CBO9780511525025, 1997.
Malfatti, F., Lee, C., Tinta, T., Pendergraft, M. A., Celussi, M., Zhou, Y.
Y., Sultana, C. M., Rotter, A., Axson, J. L., Collins, D. B., Santander, M.
V., Morales, A. L. A., Aluwihare, L. I., Riemer, N., Grassian, V. H., Azam,
F., and Prather, K. A.: Detection of Active Microbial Enzymes in Nascent Sea
Spray Aerosol: Implications for Atmospheric Chemistry and Climate,
Environ. Sci. Tech. Let., 6, 171–177,
https://doi.org/10.1021/acs.estlett.8b00699, 2019.
Mandalakis, M., Apostolaki, M., and Stephanou, E. G.: Trace analysis of free
and combined amino acids in atmospheric aerosols by gas chromatography-mass
spectrometry, J. Chromatogr. A, 1217, 143–150, https://doi.org/10.1016/j.chroma.2009.11.021,
2010.
Matos, J. T. V., Duarte, R., and Duarte, A. C.: Challenges in the
identification and characterization of free amino acids and proteinaceous
compounds in atmospheric aerosols: A critical review, Trac-Trends in
Anal. Chem., 75, 97–107, https://doi.org/10.1016/j.trac.2015.08.004, 2016.
Matsumoto, K. and Uematsu, M.: Free amino acids in marine aerosols over the
western North Pacific Ocean, Atmos. Environ., 39, 2163–2170,
https://doi.org/10.1016/j.atmosenv.2004.12.022, 2005.
Matulova, M., Husarova, S., Capek, P., Sancelme, M., and Delort, A. M.:
Biotransformation of Various Saccharides and Production of Exopolymeric
Substances by Cloud-Borne Bacillus sp 3B6, Environ. Sci.
Technol., 48, 14238–14247, https://doi.org/10.1021/es501350s, 2014.
McCluskey, C. S., Hill, T. C. J., Humphries, R. S., Rauker, A. M., Moreau,
S., Strutton, P. G., Chambers, S. D., Williams, A. G., McRobert, I., Ward,
J., Keywood, M. D., Harnwell, J., Ponsonby, W., Loh, Z. M., Krummel, P. B.,
Protat, A., Kreidenweis, S. M., and DeMott, P. J.: Observations of Ice
Nucleating Particles Over Southern Ocean Waters, Geophys. Res.
Lett., 45, 11989–11997, https://doi.org/10.1029/2018gl079981, 2018a.
McCluskey, C. S., Ovadnevaite, J., Rinaldi, M., Atkinson, J., Belosi, F.,
Ceburnis, D., Marullo, S., Hill, T. C. J., Lohmann, U., Kanji, Z. A.,
O'Dowd, C., Kreidenweis, S. M., and DeMott, P. J.: Marine and Terrestrial
Organic Ice-Nucleating Particles in Pristine Marine to Continentally
Influenced Northeast Atlantic Air Masses, J. Geophys.
Res.-Atmos., 123, 6196–6212, https://doi.org/10.1029/2017jd028033, 2018b.
Mimura, T. and Romano, J. C.: Muramin acid measurements for bacterial
investigations in marine environments by
high-pressure-liquid-chromatography, Appl. Environ. Microb.,
50, 229–237, https://doi.org/10.1128/aem.50.2.229-237.1985, 1985.
Mochida, M., Kitamori, Y., Kawamura, K., Nojiri, Y., and Suzuki, K.: Fatty
acids in the marine atmosphere: Factors governing their concentrations and
evaluation of organic films on sea-salt particles, J. Geophys.
Res.-Atmos., 107, AAC 1-1–AAC 1-10, https://doi.org/10.1029/2001jd001278, 2002.
Montoya, J. P., Voss, M., and Capone, D. G.: Spatial variation in N2-fixation rate and diazotroph activity in the Tropical Atlantic, Biogeosciences, 4, 369–376, https://doi.org/10.5194/bg-4-369-2007, 2007.
O'Dowd, C. D., Facchini, M. C., Cavalli, F., Ceburnis, D., Mircea, M.,
Decesari, S., Fuzzi, S., Yoon, Y. J., and Putaud, J. P.: Biogenically driven
organic contribution to marine aerosol, Nature, 431, 676–680, https://doi.org/10.1038/Nature02959, 2004.
Pagnone, A., Volker, C., and Ye, Y.: Processes affecting dissolved iron
across the Subtropical North Atlantic: a model study, Ocean Dynam., 69,
989–1007, https://doi.org/10.1007/s10236-019-01288-w, 2019.
Patel, A. and Rastogi, N.: Chemical Composition and Oxidative Potential of
Atmospheric PM10 over the Arabian Sea, ACS Earth Space Chem., 4, 112–121,
https://doi.org/10.1021/acsearthspacechem.9b00285, 2020.
Pena-Izquierdo, J., Pelegri, J. L., Pastor, M. V., Castellanos, P.,
Emelianov, M., Gasser, M., Salvador, J., and Vazquez-Dominguez, E.: The
continental slope current system between Cape Verde and the Canary Islands,
Sci. Mar., 76, 65–78, https://doi.org/10.3989/scimar.03607.18C, 2012.
Penezić, A., Drozdowska, V., Novak, T., and Gasparovic, B.: Distribution and
characterization of organic matter within the sea surface microlayer in the
Gulf of Gdansk, Oceanologia, 64, 631–650, https://doi.org/10.1016/j.oceano.2022.05.003,
2022.
Quinn, P. K., Bates, T. S., Schulz, K. S., Coffman, D. J., Frossard, A. A.,
Russell, L. M., Keene, W. C., and Kieber, D. J.: Contribution of sea surface
carbon pool to organic matter enrichment in sea spray aerosol, Nat.
Geosci., 7, 228–232, https://doi.org/10.1038/ngeo2092, 2014.
Quinn, P. K., Collins, D. B., Grassian, V. H., Prather, K. A., and Bates, T.
S.: Chemistry and Related Properties of Freshly Emitted Sea Spray Aerosol,
Chem. Rev., 115, 4383–4399, https://doi.org/10.1021/cr500713g, 2015.
Rastelli, E., Corinaldesi, C., Dell'Anno, A., Lo Martire, M., Greco, S.,
Facchini, M. C., Rinaldi, M., O'Dowd, C., Ceburnis, D., and Danovaro, R.:
Transfer of labile organic matter and microbes from the ocean surface to the
marine aerosol: an experimental approach, Sci. Rep., 7, 11475,
https://doi.org/10.1038/s41598-017-10563-z, 2017.
Reinthaler, T., Sintes, E., and Herndl, G. J.: Dissolved organic matter and
bacterial production and respiration in the sea-surface microlayer of the
open Atlantic and the western Mediterranean Sea, Limnol. Oceanogr., 53,
122–136, https://doi.org/10.4319/lo.2008.53.1.0122, 2008.
Renard, P., Brissy, M., Rossi, F., Leremboure, M., Jaber, S., Baray, J.-L., Bianco, A., Delort, A.-M., and Deguillaume, L.: Free amino acid quantification in cloud water at the Puy de Dôme station (France), Atmos. Chem. Phys., 22, 2467–2486, https://doi.org/10.5194/acp-22-2467-2022, 2022.
Riebesell, U., Fabry, V. J., Hansson L., and Gattuso J.-P. (Eds.): Guide to
best practices for ocean acidification research and data reporting
[reprinted edition including erratum], Luxembourg, Publications Office of
the European Union, 258 pp., https://doi.org/10.2777/66906, 2011.
Romankevich, E. A.: Geochemistry of Organic Matter in the Ocean, Springer,
https://doi.org/10.1002/aheh.19850130604, 1984.
Russell, L. M., Hawkins, L. N., Frossard, A. A., Quinn, P. K., and Bates, T.
S.: Carbohydrate-like composition of submicron atmospheric particles and
their production from ocean bubble bursting, P. Natl.
Acad. Sci. USA, 107, 6652–6657,
https://doi.org/10.1073/pnas.0908905107, 2010.
Samaké, A., Jaffrezo, J.-L., Favez, O., Weber, S., Jacob, V., Albinet, A., Riffault, V., Perdrix, E., Waked, A., Golly, B., Salameh, D., Chevrier, F., Oliveira, D. M., Bonnaire, N., Besombes, J.-L., Martins, J. M. F., Conil, S., Guillaud, G., Mesbah, B., Rocq, B., Robic, P.-Y., Hulin, A., Le Meur, S., Descheemaecker, M., Chretien, E., Marchand, N., and Uzu, G.: Polyols and glucose particulate species as tracers of primary biogenic organic aerosols at 28 French sites, Atmos. Chem. Phys., 19, 3357–3374, https://doi.org/10.5194/acp-19-3357-2019, 2019.
Sander, R., Keene, W. C., Pszenny, A. A. P., Arimoto, R., Ayers, G. P., Baboukas, E., Cainey, J. M., Crutzen, P. J., Duce, R. A., Hönninger, G., Huebert, B. J., Maenhaut, W., Mihalopoulos, N., Turekian, V. C., and Van Dingenen, R.: Inorganic bromine in the marine boundary layer: a critical review, Atmos. Chem. Phys., 3, 1301–1336, https://doi.org/10.5194/acp-3-1301-2003, 2003.
Schill, S. R., Burrows, S. M., Hasenecz, E. S., Stone, E. A., and Bertram,
T. H.: The Impact of Divalent Cations on the Enrichment of Soluble
Saccharides in Primary Sea Spray Aerosol, Atmosphere, 9, 476,
https://doi.org/10.3390/atmos9120476, 2018.
Schmitt-Kopplin, P., Liger-Belair, G., Koch, B. P., Flerus, R., Kattner, G., Harir, M., Kanawati, B., Lucio, M., Tziotis, D., Hertkorn, N., and Gebefügi, I.: Dissolved organic matter in sea spray: a transfer study from marine surface water to aerosols, Biogeosciences, 9, 1571–1582, https://doi.org/10.5194/bg-9-1571-2012, 2012.
Sieburth, J. M.: Microbiological and organic-chemical processes in the
surface and mixed layers, in: Air-Sea Exchange of Gases and Particles,
edited by: Liss, P. S. and Slinn, W. G. N., Reidel Publishers Co, Hingham, MA,
121–172, 1983.
Stolle, C., Nagel, K., Labrenz, M., and Jürgens, K.: Succession of the sea-surface microlayer in the coastal Baltic Sea under natural and experimentally induced low-wind conditions, Biogeosciences, 7, 2975–2988, https://doi.org/10.5194/bg-7-2975-2010, 2010.
Triesch, N., van Pinxteren, M., Engel, A., and Herrmann, H.: Concerted measurements of free amino acids at the Cabo Verde islands: high enrichments in submicron sea spray aerosol particles and cloud droplets, Atmos. Chem. Phys., 21, 163–181, https://doi.org/10.5194/acp-21-163-2021, 2021a.
Triesch, N., van Pinxteren, M., Frka, S., Stolle, C., Spranger, T., Hoffmann, E. H., Gong, X., Wex, H., Schulz-Bull, D., Gašparović, B., and Herrmann, H.: Concerted measurements of lipids in seawater and on submicrometer aerosol particles at the Cabo Verde islands: biogenic sources, selective transfer and high enrichments, Atmos. Chem. Phys., 21, 4267–4283, https://doi.org/10.5194/acp-21-4267-2021, 2021b.
Triesch, N., van Pinxteren, M., Salter, M., Stolle, C., Pereira, R., Zieger,
P., and Herrmann, H.: Sea Spray Aerosol Chamber Study on Selective Transfer
and Enrichment of Free and Combined Amino Acids, ACS Earth Space Chem., 5,
1564–1574, https://doi.org/10.1021/acsearthspacechem.1c00080, 2021c.
Triesch, N., van Pinxteren, M., Frka, S., Stolle, C., Spranger, T., Hoffmann, E. H., Gong, X., Wex, H., Schulz-Bull, D., Gašparović, B., and Herrmann, H.: Measurements of lipids on submicron aerosol particles at the Cape Verde Islands, PANGAEA [data set], https://doi.org/10.1594/PANGAEA.921832, 2023.
van Pinxteren, M., Müller, C., Iinuma, Y., Stolle, C., and Herrmann, H.:
Chemical Characterization of Dissolved Organic Compounds from Coastal Sea
Surface Micro layers (Baltic Sea, Germany), Environ. Sci.
Technol., 46, 10455–10462, https://doi.org/10.1021/es204492b, 2012.
van Pinxteren, M., Fiedler, B., van Pinxteren, D., Iinuma, Y., Koertzinger,
A., and Herrmann, H.: Chemical characterization of sub-micrometer aerosol
particles in the tropical Atlantic Ocean: marine and biomass burning
influences, J. Atmos. Chem., 72, 105–125,
https://doi.org/10.1007/s10874-015-9307-3, 2015.
van Pinxteren, M., Barthel, S., Fomba, K., Müller, K., von Tümpling,
W., and Herrmann, H.: The influence of environmental drivers on the
enrichment of organic carbon in the sea surface microlayer and in submicron
aerosol particles – measurements from the Atlantic Ocean, Elementa 5, 35,
https://doi.org/10.1525/elementa.225, 2017.
van Pinxteren, M., Fomba, K. W., van Pinxteren, D., Triesch, N., Hoffmann,
E. H., Cree, C. H. L., Fitzsimons, M. F., von Tumpling, W., and Herrmann,
H.: Aliphatic amines at the Cape Verde Atmospheric Observatory: Abundance,
origins and sea-air fluxes, Atmos. Environ., 203, 183–195,
https://doi.org/10.1016/j.atmosenv.2019.02.011, 2019.
van Pinxteren, M., Fomba, K. W., Triesch, N., Stolle, C., Wurl, O., Bahlmann, E., Gong, X., Voigtländer, J., Wex, H., Robinson, T.-B., Barthel, S., Zeppenfeld, S., Hoffmann, E. H., Roveretto, M., Li, C., Grosselin, B., Daële, V., Senf, F., van Pinxteren, D., Manzi, M., Zabalegui, N., Frka, S., Gašparović, B., Pereira, R., Li, T., Wen, L., Li, J., Zhu, C., Chen, H., Chen, J., Fiedler, B., von Tümpling, W., Read, K. A., Punjabi, S., Lewis, A. C., Hopkins, J. R., Carpenter, L. J., Peeken, I., Rixen, T., Schulz-Bull, D., Monge, M. E., Mellouki, A., George, C., Stratmann, F., and Herrmann, H.: Marine organic matter in the remote environment of the Cape Verde islands – an introduction and overview to the MarParCloud campaign, Atmos. Chem. Phys., 20, 6921–6951, https://doi.org/10.5194/acp-20-6921-2020, 2020.
van Pinxteren, M., Robinson, T.-B., Zeppenfeld, S., Gong, X., Bahlmann, E., Fomba, K. W., Triesch, N., Stratmann, F., Wurl, O., Engel, A., Wex, H., and Herrmann, H.: High number concentrations of transparent exopolymer particles in ambient aerosol particles and cloud water – a case study at the tropical Atlantic Ocean, Atmos. Chem. Phys., 22, 5725–5742, https://doi.org/10.5194/acp-22-5725-2022, 2022.
Vazques de Vasquez, M. G., Rogers, M. M., Carter-Fenk, K. A., and Allen, H.
C.: Discerning Poly- and Monosaccharide Enrichment Mechanisms: Alginate and
Glucuronate Adsorption to a Stearic Acid Sea Surface Microlayer, ACS Earth
Space Chem., 6, 1581–1595, https://doi.org/10.1021/acsearthspacechem.2c00066, 2022.
Wang, X., Sultana, C. M., Trueblood, J., Hill, T. C. J., Malfatti, F., Lee,
C., Laskina, O., Moore, K. A., Beall, C. M., McCluskey, C. S., Cornwell, G.
C., Zhou, Y., Cox, J. L., Pendergraft, M. A., Santander, M. V., Bertram, T.
H., Cappa, C. D., Azam, F., DeMott, P. J., Grassian, V. H., and Prather, K.
A.: Microbial Control of Sea Spray Aerosol Composition: A Tale of Two
Blooms, ACS Central Science, 1, 124–131, https://doi.org/10.1021/acscentsci.5b00148, 2015.
Wedyan, M. A. and Preston, M. R.: The coupling of surface seawater organic
nitrogen and the marine aerosol as inferred from enantiomer-specific amino
acid analysis, Atmos. Environ., 42, 8698–8705,
https://doi.org/10.1016/j.atmosenv.2008.04.038, 2008.
Wurl, O.: Sampling and sample treatments, in: Practical Guidelines for the
Analysis of
Seawater, edited by: Wurl, O., CRC Press, Boca Raton, 329 pp., https://doi.org/10.1201/9781420073072, 2009.
Zäncker, B., Bracher, A., Röttgers, R., and Engel, A.: Variations of
the Organic Matter Composition in the Sea Surface Microlayer: A Comparison
between Open Ocean, Coastal, and Upwelling Sites Off the Peruvian Coast,
Front. Microbiol., 8, 2369, https://doi.org/10.3389/fmicb.2017.02369, 2017.
Zehr, J. P.: Nitrogen fixation by marine cyanobacteria, Trend.
Microbiol., 19, 162–173, https://doi.org/10.1016/j.tim.2010.12.004, 2011.
Zeppenfeld, S., van Pinxteren, M., Engel, A., and Herrmann, H.: A protocol for quantifying mono- and polysaccharides in seawater and related saline matrices by electro-dialysis (ED) – combined with HPAEC-PAD, Ocean Sci., 16, 817–830, https://doi.org/10.5194/os-16-817-2020, 2020.
Zeppenfeld, S., van Pinxteren, M., van Pinxteren, D., Wex, H., Berdalet, E.,
Vaqué, D., Dall'Osto, M., and Herrmann, H.: Aerosol Marine Primary
Carbohydrates and Atmospheric Transformation in the Western Antarctic
Peninsula, ACS Earth Space Chem., 5, 1032–1047, https://doi.org/10.1021/acsearthspacechem.0c00351, 2021.
Zhang, M., Khaled, A., Amato, P., Delort, A.-M., and Ervens, B.: Sensitivities to biological aerosol particle properties and ageing processes: potential implications for aerosol–cloud interactions and optical properties, Atmos. Chem. Phys., 21, 3699–3724, https://doi.org/10.5194/acp-21-3699-2021, 2021.
Zhu, R.-G., Xiao, H.-Y., Cheng, L., Zhu, H., Xiao, H., and Gong, Y.: Measurement report: Characterization of sugars and amino acids in atmospheric fine particulates and their relationship to local primary sources, Atmos. Chem. Phys., 22, 14019–14036, https://doi.org/10.5194/acp-22-14019-2022, 2022.
Zindler, C., Peeken, I., Marandino, C. A., and Bange, H. W.: Environmental control on the variability of DMS and DMSP in the Mauritanian upwelling region, Biogeosciences, 9, 1041–1051, https://doi.org/10.5194/bg-9-1041-2012, 2012.
Short summary
Important marine organic carbon compounds were identified in the Atlantic Ocean and marine aerosol particles. These compounds were strongly enriched in the atmosphere. Their enrichment was, however, not solely explained via sea-to-air transfer but also via atmospheric in situ formation. The identified compounds constituted about 50 % of the organic carbon on the aerosol particles, and a pronounced coupling between ocean and atmosphere for this oligotrophic region could be concluded.
Important marine organic carbon compounds were identified in the Atlantic Ocean and marine...
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