Articles | Volume 23, issue 9
https://doi.org/10.5194/acp-23-5177-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-23-5177-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Impact of aerosol optics on vertical distribution of ozone in autumn over Yangtze River Delta
Shuqi Yan
Key Laboratory of Transportation Meteorology of China Meteorological Administration, Nanjing Joint Institute for Atmospheric Sciences, Nanjing 210041, China
Bin Zhu
CORRESPONDING AUTHOR
Collaborative Innovation Center on Forecast and Evaluation of
Meteorological Disasters, Key Laboratory for Aerosol-Cloud-Precipitation of
China Meteorological Administration, Key Laboratory of Meteorological
Disaster, Ministry of Education (KLME), Special Test Field of National
Integrated Meteorological Observation, Nanjing University of Information
Science and Technology, Nanjing 210044, China
Shuangshuang Shi
Collaborative Innovation Center on Forecast and Evaluation of
Meteorological Disasters, Key Laboratory for Aerosol-Cloud-Precipitation of
China Meteorological Administration, Key Laboratory of Meteorological
Disaster, Ministry of Education (KLME), Special Test Field of National
Integrated Meteorological Observation, Nanjing University of Information
Science and Technology, Nanjing 210044, China
Wen Lu
Collaborative Innovation Center on Forecast and Evaluation of
Meteorological Disasters, Key Laboratory for Aerosol-Cloud-Precipitation of
China Meteorological Administration, Key Laboratory of Meteorological
Disaster, Ministry of Education (KLME), Special Test Field of National
Integrated Meteorological Observation, Nanjing University of Information
Science and Technology, Nanjing 210044, China
Jinhui Gao
Plateau Atmosphere and Environment Key Laboratory of Sichuan Province, School of Atmospheric Sciences, Chengdu University of Information
Technology, Chengdu 610225, China
Hanqing Kang
Collaborative Innovation Center on Forecast and Evaluation of
Meteorological Disasters, Key Laboratory for Aerosol-Cloud-Precipitation of
China Meteorological Administration, Key Laboratory of Meteorological
Disaster, Ministry of Education (KLME), Special Test Field of National
Integrated Meteorological Observation, Nanjing University of Information
Science and Technology, Nanjing 210044, China
Duanyang Liu
Key Laboratory of Transportation Meteorology of China Meteorological Administration, Nanjing Joint Institute for Atmospheric Sciences, Nanjing 210041, China
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Light extinction of aerosols can decease surface ozone mainly via reducing photochemical production of ozone. However, it also leads to high levels of ozone aloft being entrained down to the surface which partly counteracts the reduction in surface ozone. The impact of aerosols is more sensitive to local ozone, which suggests that while controlling the levels of aerosols, controlling the local ozone precursors is an effective way to suppress the increase of ozone over China at present.
Cited articles
Ackerman, T. P. and Toon, O. B.: Absorption of visible radiation in
atmosphere containing mixtures of absorbing and non-absorbing particles,
Appl. Optics, 20, 3661–3662, https://doi.org/10.1364/AO.21.000758, 1981.
Atmospheric Chemistry Observations and Modeling/National Center for Atmospheric Research/University Corporation for Atmospheric Research: Whole Atmosphere Community Climate Model (WACCM) Model Output, Research Data Archive at the National Center for Atmospheric Research, Computational and Information Systems Laboratory [data set], https://doi.org/10.5065/G643-Z138, 2020.
Bond, T. C., Habib, G., and Bergstrom, R. W.: Limitations in the enhancement
of visible light absorption due to mixing state, J. Geophys. Res., 111, D20211,
https://doi.org/10.1029/2006JD007315, 2006.
Cappa, C. D., Onasch, T. B., Massoli, P., Worsnop, D. R., Bates, T. S., Cross, E. S., and Zaveri, R. A.: Radiative absorption enhancements due to the mixing state of atmospheric black carbon, Science, 337, 1078–1081, https://doi.org/10.1126/science.1223447, 2012.
Chen, S. H. and Sun, W. Y.: A one-dimensional time dependent cloud model, J. Meteor. Soc. Japan, 80, 99–118, https://doi.org/10.2151/jmsj.80.99, 2002.
Chen, Y., Fung, J. C., Huang, Y., Lu, X., Wang, Z., Louie, P. K., & Lau,
A. K.:Temporal source apportionment of PM2.5 over the Pearl River Delta
region in southern China, J. Geophys. Res.-Atmos., 127, e2021JD035271,
https://doi.org/10.1029/2021JD035271, 2022.
China National Environmental Monitoring Center:
National Air Quality Monitoring Data, China National Environmental Monitoring Center [data set], https://www.aqistudy.cn/ (last access: 22 April 2023), 2014.
Dickerson, R. R., Kondragunta, S., Stenchikov, G., Civerolo, K. L.,
Doddridge, B. G., and Holben, B. N.: The impact of aerosols on solar
ultraviolet radiation and photochemical smog, Science, 278, 827–830,
https://doi.org/10.1126/science.278.5339.827, 1997.
Ding, A. J., Huang, X., Nie, W., Sun, J. N., Kerminen, V. M., Petaja, T., Su,
H., Cheng, Y. F., Yang, X. Q., Wang, M. H., Chi, X. G., Wang, J. P.,
Virkkula, A., Guo, W. D., Yuan, J., Wang, S. Y., Zhang, R. J., Wu, Y. F.,
Song, Y., Zhu, T., Zilitinkevich, S., Kulmala, M., and Fu, C. B.: Enhanced
haze pollution by black carbon in megacities in China, Geophys. Res. Lett.,
43, 2873–2879, https://doi.org/10.1002/2016GL067745, 2016.
Emery, C., Tai, E., and Yarwood, G.: Enhanced meteorological modeling and performance evaluation for two Texas ozone episodes, in: Prepared for the Texas Natural Resource Conservation Commission, Environ International Corporation, Novato, CA, USA, 2001.
Fast, J. D., Gustafson, W. I., Easter, R. C., Zaveri, R. A., Barnard, J. C.,
Chapman, E. G., Grell, G. A., and Peckham, S. E.: Evolution of ozone,
particulates, and aerosol direct radiative forcing in the vicinity of
Houston using a fully coupled meteorology-chemistry-aerosol model, J.
Geophys. Res., 111, D21305, https://doi.org/10.1029/2005jd006721, 2006.
Fu, Y., Liao, H., and Yang, Y.: Interannual and decadal changes in
tropospheric ozone in China and the associated chemistry–climate
interactions: A review, Adv. Atmos. Sci., 36, 975–993,
https://doi.org/10.1007/s00376-019-8216-9, 2019.
Gao, J., Zhu, B., Xiao, H., Kang, H., Pan, C., Wang, D., and Wang, H.: Effects of black carbon and boundary layer interaction on surface ozone in Nanjing, China, Atmos. Chem. Phys., 18, 7081–7094, https://doi.org/10.5194/acp-18-7081-2018, 2018.
Gao, J., Li, Y., Zhu, B., Hu, B., Wang, L., and Bao, F.: What have we missed when studying the impact of aerosols on surface ozone via changing photolysis rates?, Atmos. Chem. Phys., 20, 10831–10844, https://doi.org/10.5194/acp-20-10831-2020, 2020.
Gao, J., Li, Y., Xie, Z., Wang, L., Hu, B., and Bao, F.: Do Absorbing
Aerosols or Scattering Aerosols Dominate the Impact of Aerosols on Ozone via
Influencing Photolysis Rates?, Earth and Space Science Open Archive,
https://doi.org/10.1002/essoar.10508565.1, 2021.
Gao, M., Yang, Y., Liao, H., Zhu, B., Zhang, Y., Liu, Z., Lu, X., Wang, C., Zhou, Q., Wang, Y., Zhang, Q., Carmichael, G. R., and Hu, J.: Reduced light absorption of black carbon (BC) and its influence on BC-boundary-layer interactions during “APEC Blue”, Atmos. Chem. Phys., 21, 11405–11421, https://doi.org/10.5194/acp-21-11405-2021, 2021.
Grell, G. A., Peckham, S. E., Schmitz, R., McKeen, S. A., Frost, G.,
Skamarock, W. C., and Eder, B.: Fully coupled “online” chemistry within the
WRF model, Atmos. Environ., 39, 6957–6975,
https://doi.org/10.1016/j.atmosenv.2005.04.027, 2005.
Hersbach, H., Bell, B., Berrisford, P., Biavati, G., Horányi, A., Muñoz Sabater, J., Nicolas, J., Peubey, C., Radu, R., Rozum, I., Schepers, D., Simmons, A., Soci, C., Dee, D., Thépaut, J.-N.: ERA5 hourly data on pressure levels from 1940 to present, Copernicus Climate Change Service (C3S) Climate Data Store (CDS) [data set], https://doi.org/10.24381/cds.bd0915c6, 2018.
Hong, S. Y., Noh, Y., and Dudhia, J.: A new vertical diffusion package with an explicit treatment of entrainment processes, Mon. Weather Rev., 134, 2318–2341, https://doi.org/10.1175/MWR3199.1, 2006.
Hu, J., Chen, J., Ying, Q., and Zhang, H.: One-year simulation of ozone and particulate matter in China using WRF/CMAQ modeling system, Atmos. Chem. Phys., 16, 10333–10350, https://doi.org/10.5194/acp-16-10333-2016, 2016.
Jacob, D. J.: Heterogeneous chemistry and tropospheric ozone, Atmos.
Environ., 34, 2131–2159, https://doi.org/10.1016/S1352-2310(99)00462-8,
2000.
Jacobson, M. Z.: Studying the effects of aerosols on vertical photolysis rate
coefficient and temperature profiles over an urban airshed, J. Geophys.
Res.-Atmos., 103, 10593, https://doi.org/10.1029/98JD00287, 1998.
Jacobson, M. Z.: Strong radiative heating due to the mixing state of black
carbon in atmospheric aerosols, Nature, https://doi.org/10.1038/35055518,
2001.
Jia, W. and Zhang, X.: The role of the planetary boundary layer
parameterization schemes on the meteorological and aerosol pollution
simulations: a review, Atmos. Res., 239, 104890,
https://doi.org/10.1016/j.atmosres.2020.104890, 2020.
Jia, W. and Zhang, X.: Impact of modified turbulent diffusion of PM2.5 aerosol in WRF-Chem simulations in eastern China, Atmos. Chem. Phys., 21, 16827–16841, https://doi.org/10.5194/acp-21-16827-2021, 2021.
Jiménez, P. A. and Dudhia, J.: Improving the representation of resolved
and unresolved topographic effects on surface wind in the WRF model, J.
Appl. Meteorol. Climatol., 51, 300–316,
https://doi.org/10.1175/JAMC-D-11-084.1, 2012.
Kwok, R. H. F., Fung, J. C. H., Lau, A. K. H., and Fu, J. S.: Numerical
study on seasonal variations of gaseous pollutants and particulate matters
in Hong Kong and Pearl River Delta Region, J. Geophys. Res., 115, D16308,
https://doi.org/10.1029/2009JD012809, 2010.
Li, J., Wang, Z., Wang, X., Yamaji, K., Takigawa, M., and Kanaya, Y.: Impacts of
aerosols on summertime tropospheric photolysis frequencies and
photochemistry over central eastern china, Atmos. Environ., 45,
1817–1829, https://doi.org/10.1016/j.atmosenv.2011.01.016, 2011.
Li, K., Jacob, D. J., Liao, H., Zhu, J., Shah, V., Shen, L., Bates, K.,
Zhang, Q., and Zhai, S.: A two-pollutant strategy for improving ozone and
particulate matter air quality in China, Nat. Geosci., 12, 906–910,
https://doi.org/10.1038/s41561-019-0464-x, 2019.
Li, K., Jacob, D. J., Shen, L., Lu, X., De Smedt, I., and Liao, H.: Increases in surface ozone pollution in China from 2013 to 2019: anthropogenic and meteorological influences, Atmos. Chem. Phys., 20, 11423–11433, https://doi.org/10.5194/acp-20-11423-2020, 2020.
Li, Y., Cao, L., Gao, S., and Luo, B.: The Current Stage and Development of
MICAPS, Meteorological Monthly, 36, 50–55, 2010 (in Chinese).
Li, Z. Q., Guo, J. P., Ding, A. J., Liao, H., Liu, J. J., Sun, Y. L., Wang,
T. J., Xue, H. W., Zhang, H. S., and Zhu, B.: Aerosol and boundary-layer
interactions and impact on air quality, Natl. Sci. Rev., 4, 810–833,
https://doi.org/10.1093/nsr/nwx117, 2017.
Liu, C., Xu, X., Yin, Y., Schnaiter, M., and Yung, Y. L.: Black carbon
aggregates: A database for optical properties, J. Quant. Spectrosc. Ra., 222, 170–179, https://doi.org/10.1016/j.jqsrt.2018.10.021, 2019.
Liu, D., Whitehead, J., Alfarra, M. R., Reyes-Villegas, E., Spracklen, D.
V., Reddington, C. L., and Allan, J. D.: Black-carbon absorption
enhancement in the atmosphere determined by particle mixing state, Nat.
Geosci., 10, 184–188, https://doi.org/10.1038/ngeo2901, 2017.
Lou, S., Liao, H., and Zhu, B.: Impacts of aerosols on surface-layer ozone
concentrations in China through heterogeneous reactions and changes in
photolysis rates, Atmos. Environ., 85, 123–138,
https://doi.org/10.1016/j.atmosenv.2013.12.004, 2014.
Lu, R., Turco, R. P., and Jacobson, M. Z.: An integrated pollution modeling
system for urban and regional scales: 2. Simulations for SCAQS 1987, J.
Geophys. Res., 102, 6081–6098, https://doi.org/10.1029/96JD03502, 1997.
Matsui, H., Koike, M., Kondo, Y., Moteki, N., Fast, J. D., and Zaveri, R.
A.: Development and validation of a black carbon mixing state resolved
three-dimensional model: Aging processes and radiative impact, J. Geophys.
Res.-Atmos., 118, 2304–2326, https://doi.org/10.1029/2012JD018446, 2013.
MEIC Team: The Multi-resolution Emission Inventory Model for Climate and Air Pollution Research, MEICModel [data set], http://www.meicmodel.org/ (last access: 22 April 2023), 2012.
Qu, Y., Voulgarakis, A., Wang, T., Kasoar, M., Wells, C., Yuan, C., Varma, S., and Mansfield, L.: A study of the effect of aerosols on surface ozone through meteorology feedbacks over China, Atmos. Chem. Phys., 21, 5705–5718, https://doi.org/10.5194/acp-21-5705-2021, 2021.
Riemer, N. and West, M.: Quantifying aerosol mixing state with entropy and diversity measures, Atmos. Chem. Phys., 13, 11423–11439, https://doi.org/10.5194/acp-13-11423-2013, 2013.
Riemer, N., Ault, A. P., West, M., Craig, R. L., and Curtis, J. H.: Aerosol
mixing state: Measurements, modeling, and impacts, Rev. Geophys., 57, 187–249, https://doi.org/10.1029/2018RG000615, 2019.
Shi, S., Zhu, B., Lu, W., Yan, S., Fang, C., Liu, H., Liu, D., Liu, C.:
Estimation of radiative forcing and heating rate based on vertical
observation of black carbon in Nanjing, China, Sci. Total Environ., 756, 144135,
https://doi.org/10.1016/j.scitotenv.2020.144135, 2020.
Shi, S., Zhu, B., Tang, G., Liu, C., An, J., Liu, D., Xu, J., Xu, H., Liao,
H., and Zhang, Y.: Observational evidence of aerosol radiation modifying
photochemical ozone profiles in the lower troposphere, Geophys. Res. Lett.,
49, e2022GL099274, https://doi.org/10.1029/2022GL099274, 2022.
Singh, H. B., Cai, C., Kaduwela, A., Weinheimer, A., and Wisthaler, A.:
Interactions of fire emissions and urban pollution over California: Ozone
formation and air quality simulations, Atmos. Environ., 56, 45–51,
https://doi.org/10.1016/j.atmosenv.2012.03.046, 2012.
Skamarock, W. C., Klemp, J. B., Dudhia, J., Gill, D. O., Barker, D. M., Duda, M. G., Huang, X., Wang, W., and Powers, J. G.: A description of the advanced research WRF Version 3 (NCAR Technical Note NCAR/TN-475+STR), National Center for Atmospheric Research: Boulder, CO, USA, https://doi.org/10.5065/D68S4MVH, 2008 (data available at: https://www2.mmm.ucar.edu/wrf/users/download/get_source.html, last access: 22 April 2023).
Tan, Y., Wang, H., Shi, S., Shen, L., Zhang, C., Zhu, B., and Liu, A.:
Annual variations of black carbon over the Yang-tze River Delta from 2015 to
2018, J. Environ. Sci., 96, 72–84,
https://doi.org/10.1016/j.jes.2020.04.019, 2020.
Tan, Y., Wang, H., Zhu, B., Zhao, T., Shi, S., Liu, A., and Cao, L.: The
interaction between black carbon and plane-tary boundary layer in the
Yangtze River Delta from 2015 to 2020: Why O3 didn't decline so
significantly as PM2.5, Environ. Res., 214, 114095,
https://doi.org/10.1016/j.envres.2022.114095, 2022.
Tian, P., Wang, G., Zhang, R., Wu, Y., and Yan, P.: Impacts of aerosol
chemical compositions on optical properties in urban Beijing, China,
Particuology, 18, 155–164, https://doi.org/10.1016/j.partic.2014.03.014,
2015.
U.S. Environmental Protection Agency (U.S. EPA): Guidance on the Use of Models and Other Analyses in ttainment
Demonstrations for the 8-hour Ozone NAAQS, EPA- 54/R-05-002, https://www3.epa.gov/ttn/naaqs/aqmguide/collection/cp2_old/20051001_oaqps_epa-454_r-05-002_guide_modeling_ozone_attain_demo.pdf (last access: 22 April 2023), 2005.
U.S. Environmental Protection Agency (U.S. EPA): Guidance on the Use of Models and Other Analyses or Demonstrating
Attainment of Air Quality Goals for Ozone, PM2.5, and Regional Haze,
EPA-454/B-07-002, https://www.epa.gov/sites/default/files/2020-10/documents/final-03-pm-rh-guidance.pdf (last access: 22 April 2023), 2007.
Wu, J., Bei, N., Hu, B., Liu, S., Wang, Y., Shen, Z., Li, X., Liu, L., Wang,
R., Liu, Z., Cao, J., Tie, X., Molina, L. T., and Li, G.: Aerosol-photolysis
interaction reduces particulate matter during wintertime haze events, P.
Natl. Acad. Sci. USA, 117, 9755–9761,
https://doi.org/10.1073/pnas.1916775117, 2020.
Yang, F., Tan, J., Zhao, Q., Du, Z., He, K., Ma, Y., Duan, F., Chen, G., and Zhao, Q.: Characteristics of PM2.5 speciation in representative megacities and across China, Atmos. Chem. Phys., 11, 5207–5219, https://doi.org/10.5194/acp-11-5207-2011, 2011.
Yang, H., Chen, L., Liao, H., Zhu, J., Wang, W., and Li, X.: Impacts of aerosol–photolysis interaction and aerosol–radiation feedback on surface-layer ozone in North China during multi-pollutant air pollution episodes, Atmos. Chem. Phys., 22, 4101–4116, https://doi.org/10.5194/acp-22-4101-2022, 2022.
Yang, M., Howell, S. G., Zhuang, J., and Huebert, B. J.: Attribution of aerosol light absorption to black carbon, brown carbon, and dust in China – interpretations of atmospheric measurements during EAST-AIRE, Atmos. Chem. Phys., 9, 2035–2050, https://doi.org/10.5194/acp-9-2035-2009, 2009.
Zaveri, R. A. and Peters, L. K.: A new lumped structure photochemical
mechanism for large-scale applications, J. Geophys. Res., 104,
30387–30415, https://doi.org/10.1029/1999JD900876, 1999.
Zaveri, R. A., Easter, R. C., Fast, J. D., and Peters, L. K.: Model for
simulating aerosol interactions and chemistry (MOSAIC), J. Geophys. Res.,
113, D13204, https://doi.org/10.1029/2007JD008782, 2008.
Zeng, C., Liu, C., Li, J., Zhu, B., Yin, Y., and Wang, Y.: Optical
Properties and Radiative Forcing of Aged BC due to Hygroscopic Growth:
Effects of the Aggregate Structure, J. Geophys. Res. Atmos., 124,
4620–4633, https://doi.org/10.1029/2018JD029809, 2019.
Zhang, H., Chen, G., Hu, J., Chen, S. H., Wiedinmyer, C., Kleeman, M., and
Ying, Q.: Evaluation of a seven-year air quality simulation using the Weather
Research and Forecasting (WRF)/Community Multiscale Air Quality (CMAQ)
models in the eastern United States, Sci. Total Environ., 473, 275–285,
https://doi.org/10.1016/j.scitotenv.2013.11.121, 2014a.
Zhang, H., DeNero, S. P., Joe, D. K., Lee, H.-H., Chen, S.-H., Michalakes, J., and Kleeman, M. J.: Development of a source oriented version of the WRF/Chem model and its application to the California regional PM PM2.5 air quality study, Atmos. Chem. Phys., 14, 485–503, https://doi.org/10.5194/acp-14-485-2014, 2014b.
Zhao, S., Hu, B., Liu, H., Du, C., Xia, X., and Wang, Y.: The influence of
aerosols on the NO2 photolysis rate in a suburban site in North China, Sci.
Total Environ., 767, 144788,
https://doi.org/10.1016/j.scitotenv.2020.144788, 2021.
Zheng, B., Tong, D., Li, M., Liu, F., Hong, C., Geng, G., Li, H., Li, X., Peng, L., Qi, J., Yan, L., Zhang, Y., Zhao, H., Zheng, Y., He, K., and Zhang, Q.: Trends in China's anthropogenic emissions since 2010 as the consequence of clean air actions, Atmos. Chem. Phys., 18, 14095–14111, https://doi.org/10.5194/acp-18-14095-2018, 2018.
Zhu, B., Kang, H. Q., Zhu, T., Su, J. F., Hou, X. W., and Gao, J. H.: Impact
of Shanghai urban land surface forcing on downstream city ozone chemistry,
J. Geophys. Res.-Atmos., 120, 4340–4351,
https://doi.org/10.1002/2014JD022859, 2015.
Short summary
We analyze ozone response to aerosol mixing states in the vertical direction by WRF-Chem simulations. Aerosols generally lead to turbulent suppression, precursor accumulation, low-level photolysis reduction, and upper-level photolysis enhancement under different underlying surface and pollution conditions. Thus, ozone decreases within the entire boundary layer during the daytime, and the decrease is the least in aerosol external mixing states compared to internal and core shell mixing states.
We analyze ozone response to aerosol mixing states in the vertical direction by WRF-Chem...
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