Articles | Volume 24, issue 13
https://doi.org/10.5194/acp-24-7699-2024
© Author(s) 2024. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-24-7699-2024
© Author(s) 2024. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
09 Jul 2024
Research article |
| 09 Jul 2024
| 09 Jul 2024
Evaluation of modelled versus observed non-methane volatile organic compounds at European Monitoring and Evaluation Programme sites in Europe
Division for Climate Modelling and Air Pollution, Norwegian Meteorological Institute, 0313 Oslo, Norway
UK Centre for Ecology & Hydrology, Bush Estate, Penicuik, EH26 0QB, UK
now at: Yusuf Hamied Department of Chemistry, University of Cambridge, Cambridge, CB2 1EW, UK
Sverre Solberg
NILU, 2027 Kjeller, Norway
Mathew R. Heal
School of Chemistry, University of Edinburgh, Joseph Black Building, Edinburgh, EH9 3FJ, UK
Stefan Reimann
Empa – Laboratory for Air Pollution/Environmental Technology, Swiss Federal Laboratories for Materials Science and Technology, 8600 Dübendorf, Switzerland
Willem van Caspel
Division for Climate Modelling and Air Pollution, Norwegian Meteorological Institute, 0313 Oslo, Norway
Bryan Hellack
German Environment Agency, Dessau, Germany
Thérèse Salameh
IMT Nord Europe, Institut Mines-Télécom, Univ. Lille, Centre for Energy and Environment, 59000, Lille, France
Division for Climate Modelling and Air Pollution, Norwegian Meteorological Institute, 0313 Oslo, Norway
Department of Space, Earth and Environment, Chalmers University of Technology, 412 96 Gothenburg, Sweden
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Karl Espen Yttri, Are Bäcklund, Franz Conen, Sabine Eckhardt, Nikolaos Evangeliou, Markus Fiebig, Anne Kasper-Giebl, Avram Gold, Hans Gundersen, Cathrine Lund Myhre, Stephen Matthew Platt, David Simpson, Jason D. Surratt, Sönke Szidat, Martin Rauber, Kjetil Tørseth, Martin Album Ytre-Eide, Zhenfa Zhang, and Wenche Aas
Atmos. Chem. Phys., 24, 2731–2758, https://doi.org/10.5194/acp-24-2731-2024, https://doi.org/10.5194/acp-24-2731-2024, 2024
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Prerita Agarwal, David S. Stevenson, and Mathew R. Heal
Atmos. Chem. Phys., 24, 2239–2266, https://doi.org/10.5194/acp-24-2239-2024, https://doi.org/10.5194/acp-24-2239-2024, 2024
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Rona L. Thompson, Stephen A. Montzka, Martin K. Vollmer, Jgor Arduini, Molly Crotwell, Paul B. Krummel, Chris Lunder, Jens Mühle, Simon O'Doherty, Ronald G. Prinn, Stefan Reimann, Isaac Vimont, Hsiang Wang, Ray F. Weiss, and Dickon Young
Atmos. Chem. Phys., 24, 1415–1427, https://doi.org/10.5194/acp-24-1415-2024, https://doi.org/10.5194/acp-24-1415-2024, 2024
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The hydroxyl radical determines the atmospheric lifetimes of numerous species including methane. Since OH is very short-lived, it is not possible to directly measure its concentration on scales relevant for understanding its effect on other species. Here, OH is inferred by looking at changes in hydrofluorocarbons (HFCs). We find that OH levels have been fairly stable over our study period (2004 to 2021), suggesting that OH is not the main driver of the recent increase in atmospheric methane.
Heidi Hellén, Toni Tykkä, Simon Schallhart, Evdokia Stratigou, Thérèse Salameh, and Maitane Iturrate-Garcia
Atmos. Meas. Tech., 17, 315–333, https://doi.org/10.5194/amt-17-315-2024, https://doi.org/10.5194/amt-17-315-2024, 2024
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Even though online measurements of biogenic volatile organic compounds (BVOCs) are becoming more common, the use of sorbent tubes is expected to continue because they offer greater spatial coverage and no infrastructure is required for sampling. In this study the sorbent tube sampling method was optimized and evaluated for the determination of BVOCs in gas-phase samples. Tenax TA sorbent tubes were found to be suitable for the quantitative measurements of C10–C15 BVOCs.
Willem E. van Caspel, David Simpson, Jan Eiof Jonson, Anna M. K. Benedictow, Yao Ge, Alcide di Sarra, Giandomenico Pace, Massimo Vieno, Hannah L. Walker, and Mathew R. Heal
Geosci. Model Dev., 16, 7433–7459, https://doi.org/10.5194/gmd-16-7433-2023, https://doi.org/10.5194/gmd-16-7433-2023, 2023
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Radiation coming from the sun is essential to atmospheric chemistry, driving the breakup, or photodissociation, of atmospheric molecules. This in turn affects the chemical composition and reactivity of the atmosphere. The representation of photodissociation effects is therefore essential in atmospheric chemistry modeling. One such model is the EMEP MSC-W model, for which a new way of calculating the photodissociation rates is tested and evaluated in this paper.
Ioannis Katharopoulos, Dominique Rust, Martin K. Vollmer, Dominik Brunner, Stefan Reimann, Simon J. O'Doherty, Dickon Young, Kieran M. Stanley, Tanja Schuck, Jgor Arduini, Lukas Emmenegger, and Stephan Henne
Atmos. Chem. Phys., 23, 14159–14186, https://doi.org/10.5194/acp-23-14159-2023, https://doi.org/10.5194/acp-23-14159-2023, 2023
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The effectiveness of climate change mitigation needs to be scrutinized by monitoring greenhouse gas (GHG) emissions. Countries report their emissions to the UN in a bottom-up manner. By combining atmospheric observations and transport models someone can independently validate emission estimates in a top-down fashion. We report Swiss emissions of synthetic GHGs based on kilometer-scale transport and inverse modeling, highlighting the role of appropriate resolution in complex terrain.
Gemma Purser, Mathew R. Heal, Edward J. Carnell, Stephen Bathgate, Julia Drewer, James I. L. Morison, and Massimo Vieno
Atmos. Chem. Phys., 23, 13713–13733, https://doi.org/10.5194/acp-23-13713-2023, https://doi.org/10.5194/acp-23-13713-2023, 2023
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Forest expansion is a ″net-zero“ pathway, but change in land cover alters air quality in many ways. This study combines tree planting suitability data with UK measured emissions of biogenic volatile organic compounds to simulate spatial and temporal changes in atmospheric composition for planting scenarios of four species. Decreases in fine particulate matter are relatively larger than increases in ozone, which may indicate a net benefit of tree planting on human health aspects of air quality.
Alison L. Redington, Alistair J. Manning, Stephan Henne, Francesco Graziosi, Luke M. Western, Jgor Arduini, Anita L. Ganesan, Christina M. Harth, Michela Maione, Jens Mühle, Simon O'Doherty, Joseph Pitt, Stefan Reimann, Matthew Rigby, Peter K. Salameh, Peter G. Simmonds, T. Gerard Spain, Kieran Stanley, Martin K. Vollmer, Ray F. Weiss, and Dickon Young
Atmos. Chem. Phys., 23, 7383–7398, https://doi.org/10.5194/acp-23-7383-2023, https://doi.org/10.5194/acp-23-7383-2023, 2023
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Chlorofluorocarbons (CFCs) were used in Europe pre-1990, damaging the stratospheric ozone layer. Legislation has controlled production and use, and global emissions have decreased sharply. The global rate of decline in CFC-11 recently slowed and was partly attributed to illegal emission in eastern China. This study concludes that emissions of CFC-11 in western Europe have not contributed to the unexplained part of the global increase in CFC-11 observed in the last decade.
Yao Ge, Massimo Vieno, David S. Stevenson, Peter Wind, and Mathew R. Heal
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The sensitivity of fine particles and reactive N and S species to reductions in precursor emissions is investigated using the EMEP MSC-W (European Monitoring and Evaluation Programme Meteorological Synthesizing Centre – West) atmospheric chemistry transport model. This study reveals that the individual emissions reduction has multiple and geographically varying co-benefits and small disbenefits on different species, demonstrating the importance of prioritizing regional emissions controls.
Antje Hoheisel, Cedric Couret, Bryan Hellack, and Martina Schmidt
Atmos. Meas. Tech., 16, 2399–2413, https://doi.org/10.5194/amt-16-2399-2023, https://doi.org/10.5194/amt-16-2399-2023, 2023
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High-precision CO2, CH4 and CO measurements have been carried out at Zugspitze for decades. New technologies make it possible to analyse these gases with high temporal resolution. This allows the detection of local pollution. To this end, measurements have been performed on the mountain ridge (ZGR) and are compared to routine measurements at the Schneefernerhaus (ZSF). Careful manual flagging of pollution events in the ZSF data leads to consistency with the little influenced ZGR time series.
Sam-Erik Walker, Sverre Solberg, Philipp Schneider, and Cristina Guerreiro
Geosci. Model Dev., 16, 573–595, https://doi.org/10.5194/gmd-16-573-2023, https://doi.org/10.5194/gmd-16-573-2023, 2023
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We have developed a statistical model for estimating trends in the daily air quality observations of NO2, O3, PM10 and PM2.5, adjusting for trends and short-term variations in meteorology. The model is general and may also be used for prediction purposes, including forecasting. It has been applied in a recent comprehensive study in Europe. Significant declines are shown for the pollutants from 2005 to 2019, mainly due to reductions in emissions not attributable to changes in meteorology.
Cynthia H. Whaley, Kathy S. Law, Jens Liengaard Hjorth, Henrik Skov, Stephen R. Arnold, Joakim Langner, Jakob Boyd Pernov, Garance Bergeron, Ilann Bourgeois, Jesper H. Christensen, Rong-You Chien, Makoto Deushi, Xinyi Dong, Peter Effertz, Gregory Faluvegi, Mark Flanner, Joshua S. Fu, Michael Gauss, Greg Huey, Ulas Im, Rigel Kivi, Louis Marelle, Tatsuo Onishi, Naga Oshima, Irina Petropavlovskikh, Jeff Peischl, David A. Plummer, Luca Pozzoli, Jean-Christophe Raut, Tom Ryerson, Ragnhild Skeie, Sverre Solberg, Manu A. Thomas, Chelsea Thompson, Kostas Tsigaridis, Svetlana Tsyro, Steven T. Turnock, Knut von Salzen, and David W. Tarasick
Atmos. Chem. Phys., 23, 637–661, https://doi.org/10.5194/acp-23-637-2023, https://doi.org/10.5194/acp-23-637-2023, 2023
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This study summarizes recent research on ozone in the Arctic, a sensitive and rapidly warming region. We find that the seasonal cycles of near-surface atmospheric ozone are variable depending on whether they are near the coast, inland, or at high altitude. Several global model simulations were evaluated, and we found that because models lack some of the ozone chemistry that is important for the coastal Arctic locations, they do not accurately simulate ozone there.
Megan Jeramaz Lickley, John S. Daniel, Eric L. Fleming, Stefan Reimann, and Susan Solomon
Atmos. Chem. Phys., 22, 11125–11136, https://doi.org/10.5194/acp-22-11125-2022, https://doi.org/10.5194/acp-22-11125-2022, 2022
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Halocarbons contained in equipment continue to be emitted after production has ceased. These
banksmust be carefully accounted for in evaluating compliance with the Montreal Protocol. We extend a Bayesian model to the suite of regulated chemicals subject to banking. We find that banks are substantially larger than previous estimates, and we identify banks by chemical and equipment type whose future emissions will contribute to global warming and delay ozone-hole recovery if left unrecovered.
Luke M. Western, Alison L. Redington, Alistair J. Manning, Cathy M. Trudinger, Lei Hu, Stephan Henne, Xuekun Fang, Lambert J. M. Kuijpers, Christina Theodoridi, David S. Godwin, Jgor Arduini, Bronwyn Dunse, Andreas Engel, Paul J. Fraser, Christina M. Harth, Paul B. Krummel, Michela Maione, Jens Mühle, Simon O'Doherty, Hyeri Park, Sunyoung Park, Stefan Reimann, Peter K. Salameh, Daniel Say, Roland Schmidt, Tanja Schuck, Carolina Siso, Kieran M. Stanley, Isaac Vimont, Martin K. Vollmer, Dickon Young, Ronald G. Prinn, Ray F. Weiss, Stephen A. Montzka, and Matthew Rigby
Atmos. Chem. Phys., 22, 9601–9616, https://doi.org/10.5194/acp-22-9601-2022, https://doi.org/10.5194/acp-22-9601-2022, 2022
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The production of ozone-destroying gases is being phased out. Even though production of one of the main ozone-depleting gases, called HCFC-141b, has been declining for many years, the amount that is being released to the atmosphere has been increasing since 2017. We do not know for sure why this is. A possible explanation is that HCFC-141b that was used to make insulating foams many years ago is only now escaping to the atmosphere, or a large part of its production is not being reported.
Yao Ge, Massimo Vieno, David S. Stevenson, Peter Wind, and Mathew R. Heal
Atmos. Chem. Phys., 22, 8343–8368, https://doi.org/10.5194/acp-22-8343-2022, https://doi.org/10.5194/acp-22-8343-2022, 2022
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Reactive N and S gases and aerosols are critical determinants of air quality. We report a comprehensive analysis of the concentrations, wet and dry deposition, fluxes, and lifetimes of these species globally as well as for 10 world regions. We used the EMEP MSC-W model coupled with WRF meteorology and 2015 global emissions. Our work demonstrates the substantial regional variation in these quantities and the need for modelling to simulate atmospheric responses to precursor emissions.
Fanlei Meng, Yibo Zhang, Jiahui Kang, Mathew R. Heal, Stefan Reis, Mengru Wang, Lei Liu, Kai Wang, Shaocai Yu, Pengfei Li, Jing Wei, Yong Hou, Ying Zhang, Xuejun Liu, Zhenling Cui, Wen Xu, and Fusuo Zhang
Atmos. Chem. Phys., 22, 6291–6308, https://doi.org/10.5194/acp-22-6291-2022, https://doi.org/10.5194/acp-22-6291-2022, 2022
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PM2.5 pollution is a pressing environmental issue threatening human health and food security globally. We combined a meta-analysis of nationwide measurements and air quality modeling to identify efficiency gains by striking a balance between controlling NH3 and acid gas emissions. Persistent secondary inorganic aerosol pollution in China is limited by acid gas emissions, while an additional control on NH3 emissions would become more important as reductions in SO2 and NOx emissions progress.
Stephen M. Platt, Øystein Hov, Torunn Berg, Knut Breivik, Sabine Eckhardt, Konstantinos Eleftheriadis, Nikolaos Evangeliou, Markus Fiebig, Rebecca Fisher, Georg Hansen, Hans-Christen Hansson, Jost Heintzenberg, Ove Hermansen, Dominic Heslin-Rees, Kim Holmén, Stephen Hudson, Roland Kallenborn, Radovan Krejci, Terje Krognes, Steinar Larssen, David Lowry, Cathrine Lund Myhre, Chris Lunder, Euan Nisbet, Pernilla B. Nizzetto, Ki-Tae Park, Christina A. Pedersen, Katrine Aspmo Pfaffhuber, Thomas Röckmann, Norbert Schmidbauer, Sverre Solberg, Andreas Stohl, Johan Ström, Tove Svendby, Peter Tunved, Kjersti Tørnkvist, Carina van der Veen, Stergios Vratolis, Young Jun Yoon, Karl Espen Yttri, Paul Zieger, Wenche Aas, and Kjetil Tørseth
Atmos. Chem. Phys., 22, 3321–3369, https://doi.org/10.5194/acp-22-3321-2022, https://doi.org/10.5194/acp-22-3321-2022, 2022
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Here we detail the history of the Zeppelin Observatory, a unique global background site and one of only a few in the high Arctic. We present long-term time series of up to 30 years of atmospheric components and atmospheric transport phenomena. Many of these time series are important to our understanding of Arctic and global atmospheric composition change. Finally, we discuss the future of the Zeppelin Observatory and emerging areas of future research on the Arctic atmosphere.
Dominique Rust, Ioannis Katharopoulos, Martin K. Vollmer, Stephan Henne, Simon O'Doherty, Daniel Say, Lukas Emmenegger, Renato Zenobi, and Stefan Reimann
Atmos. Chem. Phys., 22, 2447–2466, https://doi.org/10.5194/acp-22-2447-2022, https://doi.org/10.5194/acp-22-2447-2022, 2022
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Artificial halocarbons contribute to ozone layer depletion and to global warming. We measured the atmospheric concentrations of halocarbons at the Beromünster tower, modelled the Swiss emissions, and compared the results to the internationally reported Swiss emissions inventory. For most of the halocarbons, we found good agreement, whereas one refrigerant might be overestimated in the inventory. In addition, we present first emission estimates of the newest types of halocarbons.
Katerina Sindelarova, Jana Markova, David Simpson, Peter Huszar, Jan Karlicky, Sabine Darras, and Claire Granier
Earth Syst. Sci. Data, 14, 251–270, https://doi.org/10.5194/essd-14-251-2022, https://doi.org/10.5194/essd-14-251-2022, 2022
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Three new datasets of global emissions of biogenic volatile organic compounds (BVOCs) emitted into the atmosphere from terrestrial vegetation were developed for air quality modelling using the Model of Emissions of Gases and Aerosols from Nature (MEGANv2.1) driven by European Centre for Medium-Range Weather Forecasts meteorological reanalyses for the years 2000–2019. The datasets include updates of the isoprene emission factors in Europe and study the impact of land cover change on emissions.
Yao Ge, Mathew R. Heal, David S. Stevenson, Peter Wind, and Massimo Vieno
Geosci. Model Dev., 14, 7021–7046, https://doi.org/10.5194/gmd-14-7021-2021, https://doi.org/10.5194/gmd-14-7021-2021, 2021
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This study reports the first evaluation of the global EMEP MSC-W ACTM driven by WRF meteorology, with a focus on surface concentrations and wet deposition of reactive N and S species. The model–measurement comparison is conducted both spatially and temporally, covering 10 monitoring networks worldwide. The statistics from the comprehensive evaluations presented in this study support the application of this model framework for global analysis of the budgets and fluxes of reactive N and SIA.
Alistair J. Manning, Alison L. Redington, Daniel Say, Simon O'Doherty, Dickon Young, Peter G. Simmonds, Martin K. Vollmer, Jens Mühle, Jgor Arduini, Gerard Spain, Adam Wisher, Michela Maione, Tanja J. Schuck, Kieran Stanley, Stefan Reimann, Andreas Engel, Paul B. Krummel, Paul J. Fraser, Christina M. Harth, Peter K. Salameh, Ray F. Weiss, Ray Gluckman, Peter N. Brown, John D. Watterson, and Tim Arnold
Atmos. Chem. Phys., 21, 12739–12755, https://doi.org/10.5194/acp-21-12739-2021, https://doi.org/10.5194/acp-21-12739-2021, 2021
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This paper estimates UK emissions of important greenhouse gases (hydrofluorocarbons (HFCs)) using high-quality atmospheric observations and atmospheric modelling. We compare these estimates with those submitted by the UK to the United Nations. We conclude that global concentrations of these gases are still increasing. Our estimates for the UK are 73 % of those reported and that the UK emissions are now falling, demonstrating an impact of UK government policy.
Ernesto Reyes-Villegas, Upasana Panda, Eoghan Darbyshire, James M. Cash, Rutambhara Joshi, Ben Langford, Chiara F. Di Marco, Neil J. Mullinger, Mohammed S. Alam, Leigh R. Crilley, Daniel J. Rooney, W. Joe F. Acton, Will Drysdale, Eiko Nemitz, Michael Flynn, Aristeidis Voliotis, Gordon McFiggans, Hugh Coe, James Lee, C. Nicholas Hewitt, Mathew R. Heal, Sachin S. Gunthe, Tuhin K. Mandal, Bhola R. Gurjar, Shivani, Ranu Gadi, Siddhartha Singh, Vijay Soni, and James D. Allan
Atmos. Chem. Phys., 21, 11655–11667, https://doi.org/10.5194/acp-21-11655-2021, https://doi.org/10.5194/acp-21-11655-2021, 2021
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This paper shows the first multisite online measurements of PM1 in Delhi, India, with measurements over different seasons in Old Delhi and New Delhi in 2018. Organic aerosol (OA) source apportionment was performed using positive matrix factorisation (PMF). Traffic was the main primary aerosol source for both OAs and black carbon, seen with PMF and Aethalometer model analysis, indicating that control of primary traffic exhaust emissions would make a significant reduction to Delhi air pollution.
David Simpson and Sabine Darras
Earth Syst. Sci. Data Discuss., https://doi.org/10.5194/essd-2021-221, https://doi.org/10.5194/essd-2021-221, 2021
Manuscript not accepted for further review
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We present a dataset of global soil NO emissions suitable for atmospheric chemistry modelling. Data are provided globally at 0.5° × 0.5° degrees horizontal resolution, and with monthly time resolution over the period 2000–2018. This paper presents the emission algorithms and their data-sources, some comments on the availability of soil NO emissions in other inventories (and how to avoid double-counting), and finally some preliminary modelling results and comparison with observed data.
James M. Cash, Ben Langford, Chiara Di Marco, Neil J. Mullinger, James Allan, Ernesto Reyes-Villegas, Ruthambara Joshi, Mathew R. Heal, W. Joe F. Acton, C. Nicholas Hewitt, Pawel K. Misztal, Will Drysdale, Tuhin K. Mandal, Shivani, Ranu Gadi, Bhola Ram Gurjar, and Eiko Nemitz
Atmos. Chem. Phys., 21, 10133–10158, https://doi.org/10.5194/acp-21-10133-2021, https://doi.org/10.5194/acp-21-10133-2021, 2021
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We present the first real-time composition of submicron particulate matter (PM1) in Old Delhi using high-resolution aerosol mass spectrometry. Seasonal analysis shows peak concentrations occur during the post-monsoon, and novel-tracers reveal the largest sources are a combination of local open and regional crop residue burning. Strong links between increased chloride aerosol concentrations and burning sources of PM1 suggest burning sources are responsible for the post-monsoon chloride peak.
Karl Espen Yttri, Francesco Canonaco, Sabine Eckhardt, Nikolaos Evangeliou, Markus Fiebig, Hans Gundersen, Anne-Gunn Hjellbrekke, Cathrine Lund Myhre, Stephen Matthew Platt, André S. H. Prévôt, David Simpson, Sverre Solberg, Jason Surratt, Kjetil Tørseth, Hilde Uggerud, Marit Vadset, Xin Wan, and Wenche Aas
Atmos. Chem. Phys., 21, 7149–7170, https://doi.org/10.5194/acp-21-7149-2021, https://doi.org/10.5194/acp-21-7149-2021, 2021
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Carbonaceous aerosol sources and trends were studied at the Birkenes Observatory. A large decrease in elemental carbon (EC; 2001–2018) and a smaller decline in levoglucosan (2008–2018) suggest that organic carbon (OC)/EC from traffic/industry is decreasing, whereas the abatement of OC/EC from biomass burning has been less successful. Positive matrix factorization apportioned 72 % of EC to fossil fuel sources and 53 % (PM2.5) and 78 % (PM10–2.5) of OC to biogenic sources.
Robbie Ramsay, Chiara F. Di Marco, Mathew R. Heal, Matthias Sörgel, Paulo Artaxo, Meinrat O. Andreae, and Eiko Nemitz
Biogeosciences, 18, 2809–2825, https://doi.org/10.5194/bg-18-2809-2021, https://doi.org/10.5194/bg-18-2809-2021, 2021
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The exchange of the gas ammonia between the atmosphere and the surface is an important biogeochemical process, but little is known of this exchange for certain ecosystems, such as the Amazon rainforest. This study took measurements of ammonia exchange over an Amazon rainforest site and subsequently modelled the observed deposition and emission patterns. We observed emissions of ammonia from the rainforest, which can be simulated accurately by using a canopy resistance modelling approach.
Gemma Purser, Julia Drewer, Mathew R. Heal, Robert A. S. Sircus, Lara K. Dunn, and James I. L. Morison
Biogeosciences, 18, 2487–2510, https://doi.org/10.5194/bg-18-2487-2021, https://doi.org/10.5194/bg-18-2487-2021, 2021
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Short-rotation forest plantations could help reduce greenhouse gases but can emit biogenic volatile organic compounds. Emissions were measured at a plantation trial in Scotland. Standardised emissions of isoprene from foliage were higher from hybrid aspen than from Sitka spruce and low from Italian alder. Emissions of total monoterpene were lower. The forest floor was only a small source. Model estimates suggest an SRF expansion of 0.7 Mha could increase total UK emissions between < 1 %–35 %.
Daniel Say, Alistair J. Manning, Luke M. Western, Dickon Young, Adam Wisher, Matthew Rigby, Stefan Reimann, Martin K. Vollmer, Michela Maione, Jgor Arduini, Paul B. Krummel, Jens Mühle, Christina M. Harth, Brendan Evans, Ray F. Weiss, Ronald G. Prinn, and Simon O'Doherty
Atmos. Chem. Phys., 21, 2149–2164, https://doi.org/10.5194/acp-21-2149-2021, https://doi.org/10.5194/acp-21-2149-2021, 2021
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Perfluorocarbons (PFCs) are potent greenhouse gases with exceedingly long lifetimes. We used atmospheric measurements from a global monitoring network to track the accumulation of these gases in the atmosphere. In the case of the two most abundant PFCs, recent measurements indicate that global emissions are increasing. In Europe, we used a model to estimate regional PFC emissions. Our results show that there was no significant decline in northwest European PFC emissions between 2010 and 2019.
Cécile Debevec, Stéphane Sauvage, Valérie Gros, Thérèse Salameh, Jean Sciare, François Dulac, and Nadine Locoge
Atmos. Chem. Phys., 21, 1449–1484, https://doi.org/10.5194/acp-21-1449-2021, https://doi.org/10.5194/acp-21-1449-2021, 2021
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This study provides a better characterization of the seasonal variations in VOC sources impacting the western Mediterranean region, based on a comprehensive chemical composition measured over 25 months at a representative receptor site (Ersa) and by determining factors controlling their temporal variations. Some insights into dominant drivers for VOC concentration variations in Europe are also provided, built on comparisons of Ersa observations with the concomitant ones of 17 European sites.
Y. Sim Tang, Chris R. Flechard, Ulrich Dämmgen, Sonja Vidic, Vesna Djuricic, Marta Mitosinkova, Hilde T. Uggerud, Maria J. Sanz, Ivan Simmons, Ulrike Dragosits, Eiko Nemitz, Marsailidh Twigg, Netty van Dijk, Yannick Fauvel, Francisco Sanz, Martin Ferm, Cinzia Perrino, Maria Catrambone, David Leaver, Christine F. Braban, J. Neil Cape, Mathew R. Heal, and Mark A. Sutton
Atmos. Chem. Phys., 21, 875–914, https://doi.org/10.5194/acp-21-875-2021, https://doi.org/10.5194/acp-21-875-2021, 2021
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The DELTA® approach provided speciated, monthly data on reactive gases (NH3, HNO3, SO2, HCl) and aerosols (NH4+, NO3−, SO42−, Cl−, Na+) across Europe (2006–2010). Differences in spatial and temporal concentrations and patterns between geographic regions and four ecosystem types were captured. NH3 and NH4NO3 were dominant components, highlighting their growing relative importance in ecosystem impacts (acidification, eutrophication) and human health effects (NH3 as a precursor to PM2.5) in Europe.
David Simpson, Robert Bergström, Alan Briolat, Hannah Imhof, John Johansson, Michael Priestley, and Alvaro Valdebenito
Geosci. Model Dev., 13, 6447–6465, https://doi.org/10.5194/gmd-13-6447-2020, https://doi.org/10.5194/gmd-13-6447-2020, 2020
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This paper outlines the structure and usage of the GenChem system, which includes a chemical pre-processor (GenChem.py) and a simple box model (boxChem). GenChem provides scripts and input files for converting chemical equations into differential form for use in atmospheric chemical transport models (CTMs) and/or the boxChem system. Although GenChem is primarily intended for users of the EMEP MSC-W CTM and related systems, boxChem can be run as a stand-alone chemical solver.
Robbie Ramsay, Chiara F. Di Marco, Matthias Sörgel, Mathew R. Heal, Samara Carbone, Paulo Artaxo, Alessandro C. de Araùjo, Marta Sá, Christopher Pöhlker, Jost Lavric, Meinrat O. Andreae, and Eiko Nemitz
Atmos. Chem. Phys., 20, 15551–15584, https://doi.org/10.5194/acp-20-15551-2020, https://doi.org/10.5194/acp-20-15551-2020, 2020
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The Amazon rainforest is a unique
laboratoryto study the processes which govern the exchange of gases and aerosols to and from the atmosphere. This study investigated these processes by measuring the atmospheric concentrations of trace gases and particles at the Amazon Tall Tower Observatory. We found that the long-range transport of pollutants can affect the atmospheric composition above the Amazon rainforest and that the gases ammonia and nitrous acid can be emitted from the rainforest.
Jost Heintzenberg, Wolfram Birmili, Bryan Hellack, Gerald Spindler, Thomas Tuch, and Alfred Wiedensohler
Atmos. Chem. Phys., 20, 10967–10984, https://doi.org/10.5194/acp-20-10967-2020, https://doi.org/10.5194/acp-20-10967-2020, 2020
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A total of 10 years of hourly aerosol and gas data at four rural German stations have been combined with hourly back trajectories to the stations and inventories of the European Emissions Database for Global Atmospheric Research (EDGAR), yielding emission maps and trends over Germany for PM10, particle number concentrations, and equivalent black carbon (eBC). The maps reflect aerosol emissions modified with atmospheric processes during transport between sources and receptor sites.
Cited articles
AeroCom: metno/pyaerocom, Zenodo [code], https://doi.org/10.5281/zenodo.10374181, 2023. a
Ait-Helal, W., Borbon, A., Sauvage, S., de Gouw, J. A., Colomb, A., Gros, V., Freutel, F., Crippa, M., Afif, C., Baltensperger, U., Beekmann, M., Doussin, J.-F., Durand-Jolibois, R., Fronval, I., Grand, N., Leonardis, T., Lopez, M., Michoud, V., Miet, K., Perrier, S., Prévôt, A. S. H., Schneider, J., Siour, G., Zapf, P., and Locoge, N.: Volatile and intermediate volatility organic compounds in suburban Paris: variability, origin and importance for SOA formation, Atmos. Chem. Phys., 14, 10439–10464, https://doi.org/10.5194/acp-14-10439-2014, 2014. a
Andersson-Sköld, Y. and Simpson, D.: Comparison of the chemical schemes of the EMEP MSC-W and the IVL photochemical trajectory models, Atmos. Environ., 33, 1111–1129, 1999. a
Andersson-Sköld, Y., Grennfelt, P., and Pleijel, K.: Photochemical Ozone Creation Potentials: A study of Different Concepts, J. Air Waste Manage., 42, 1152–1158, https://doi.org/10.1080/10473289.1992.10467060, 1992. a
Andreae, M. O.: Emission of trace gases and aerosols from biomass burning – an updated assessment, Atmos. Chem. Phys., 19, 8523–8546, https://doi.org/10.5194/acp-19-8523-2019, 2019. a, b, c
Apel, E. C., Calvert, J. G., Gilpin, T. M., Fehsenfeld, F., and Lonneman, W. A.: Nonmethane Hydrocarbon Intercomparison Experiment (NOMHICE): Task 4, ambient air, J. Geophys. Res.-Atmos., 108, 4300, https://doi.org/10.1029/2002JD002936, 2003. a
Aydin, M., Verhulst, K. R., Saltzman, E. S., Battle, M. O., Montzka, S. A., Blake, D. R., Tang, Q., and Prather, M. J.: Recent decreases in fossil-fuel emissions of ethane and methane derived from firn air, Nature, 476, 198–201, https://doi.org/10.1038/nature10352, 2011. a
Badol, C., Borbon, A., Locoge, N., Léonardis, T., and Galloo, J.-C.: An automated monitoring system for VOC ozone precursors in ambient air: development, implementation and data analysis, Anal. Bioanal. Chem., 378, 1815–1827, https://doi.org/10.1007/s00216-003-2474-0, 2004. a
Badol, C., Locoge, N., Léonardis, T., and Galloo, J.-C.: Using a source–receptor approach to characterise VOC behaviour in a French urban area influenced by industrial emissions Part I: Study area description, data set acquisition and qualitative data analysis of the data set, Sci. Total Environ., 389, 441–452, https://doi.org/10.1016/j.scitotenv.2007.09.003, 2008. a
Ballesta, P., Field, R., and De Saeger, E.: Interlaboratory exercises for volatile organic compound determination, Atmos. Environ., 35, 5729–5740, https://doi.org/10.1016/S1352-2310(01)00372-7, 2001. a
Bergström, R., Hayman, G. D., Jenkin, M. E., and Simpson, D.: Update and comparison of atmospheric chemistry mechanisms for the EMEP MSC-W model system – EmChem19a, EmChem19X, CRIv2R5Em, CB6r2Em, and MCMv3.3Em, EMEP Technical Report 1/2022, The Norwegian Meteorological Institute, Oslo, Norway, https://emep.int/publ/reports/2022/MSCW_technical_1_2022.pdf (last access: 1 July 2024), 2022. a, b, c, d, e, f, g, h
Borbon, A., Fontaine, H., Veillerot, M., Locoge, N., Galloo, J. C., and Guillermo, R.: An investigation into the traffic-related fraction of isoprene at an urban location, Atmos. Environ., 35, 3749–3760, https://doi.org/10.1016/S1352-2310(01)00170-4, 2001. a
Borbon, A., Locoge, N., Veillerot, M., Galloo, J., and Guillermo, R.: Characterisation of NMHCs in a French urban atmosphere: overview of the main sources, Sci. Total Environ., 292, 177–191, https://doi.org/10.1016/S0048-9697(01)01106-8, 2002. a
Borbon, A., Gilman, J. B., Kuster, W. C., Grand, N., Chevaillier, S., Colomb, A., Dolgorouky, C., Gros, V., Lopez, M., Sarda-Esteve, R., Holloway, J., Stutz, J., Petetin, H., McKeen, S., Beekmann, M., Warneke, C., Parrish, D. D., and de Gouw, J. A.: Emission ratios of anthropogenic volatile organic compounds in northern mid-latitude megacities: Observations versus emission inventories in Los Angeles and Paris, J. Geophys. Res.-Atmos., 118, 2041–2057, https://doi.org/10.1002/jgrd.50059, 2013. a
Borbon, A., Dominutti, P., Panopoulou, A., Gros, V., Sauvage, S., Farhat, M., Afif, C., Elguindi, N., Fornaro, A., Granier, C., Hopkins, J. R., Liakakou, E., Nogueira, T., Corrêa dos Santos, T., Salameh, T., Armangaud, A., Piga, D., and Perrussel, O.: Ubiquity of Anthropogenic Terpenoids in Cities Worldwide: Emission Ratios, Emission Quantification and Implications for Urban Atmospheric Chemistry, J. Geophys. Res.-Atmos., 128, e2022JD037566, https://doi.org/10.1029/2022JD037566, 2023. a
Bourtsoukidis, E., Ernle, L., Crowley, J. N., Lelieveld, J., Paris, J.-D., Pozzer, A., Walter, D., and Williams, J.: Non-methane hydrocarbon (C2–C8) sources and sinks around the Arabian Peninsula, Atmos. Chem. Phys., 19, 7209–7232, https://doi.org/10.5194/acp-19-7209-2019, 2019. a
Boynard, A., Borbon, A., Leonardis, T., Barletta, B., Meinardi, S., Blake, D. R., and Locoge, N.: Spatial and seasonal variability of measured anthropogenic non-methane hydrocarbons in urban atmospheres: Implication on emission ratios, Atmos. Environ., 82, 258–267, https://doi.org/10.1016/j.atmosenv.2013.09.039, 2014. a, b
Bray, C. D., Strum, M., Simon, H., Riddick, L., Kosusko, M., Menetrez, M., Hays, M. D., and Rao, V.: An assessment of important SPECIATE profiles in the EPA emissions modeling platform and current data gaps, Atmos. Environ., 207, 93–104, https://doi.org/10.1016/j.atmosenv.2019.03.013, 2019. a
Broadgate, W. J., Liss, P. S., and Penkett, S. A.: Seasonal emissions of isoprene and other reactive hydrocarbon gases from the ocean, Geophys. Res. Lett., 24, 2675–2678, https://doi.org/10.1029/97GL02736, 1997. a
Chen, Y., Wang, W., and Zhu, L.: Wavelength-dependent photolysis of methylglyoxal in the 290–440 nm region, J. Phys. Chem. A, 104, 11126–11131, https://doi.org/10.1021/jp002262t, 2000. a
Coggon, M. M., Gkatzelis, G. I., McDonald, B. C., Gilman, J. B., Schwantes, R. H., Abuhassan, N., Aikin, K. C., Arend, M. F., Berkoff, T. A., Brown, S. S., Campos, T. L., Dickerson, R. R., Gronoff, G., Hurley, J. F., Isaacman-VanWertz, G., Koss, A. R., Li, M., McKeen, S. A., Moshary, F., Peischl, J., Pospisilova, V., Ren, X., Wilson, A., Wu, Y., Trainer, M., and Warneke, C.: Volatile chemical product emissions enhance ozone and modulate urban chemistry, P. Natl. Acad. Sci. USA, 118, e2026653118, https://doi.org/10.1073/pnas.2026653118, 2021. a
Coll, I., Rousseau, C., Barletta, B., Meinardi, S., and Blake, D. R.: Evaluation of an urban NMHC emission inventory by measurements and impact on CTM results, Atmos. Environ., 44, 3843–3855, https://doi.org/10.1016/j.atmosenv.2010.05.042, 2010. a
Dalsøren, S. B., Myhre, G., Hodnebrog, Ø., Myhre, C. L., Stohl, A., Pisso, I., Schwietzke, S., Höglund-Isaksson, L., Helmig, D., Reimann, S., Sauvage, S., Schmidbauer, N., Read, K. A., Carpenter, L. J., Lewis, A. C., Punjabi, S., and Wallasch, M.: Discrepancy between simulated and observed ethane and propane levels explained by underestimated fossil emissions, Nat. Geosci., 11, 178–184, https://doi.org/10.1038/s41561-018-0073-0, 2018. a, b
Denier van der Gon, H., Gauss, M., Granier, C., Arellano, S., Benedictow, A., Darras, S., Dellaert, S., Guevara, M., Jalkanen, J.-P., Krueger, K., Kuenen, J., Liaskoni, M., Liousse, C., Markova, J., Perez, A. P., Quack, B., Simpson, D., Sindelarova, K., and Soulie, A.: CAMS2_61 – Global and European emission inventories. Documentation of CAMS emission inventory products, Copernicus Atmosphere Monitoring Service [data set], https://doi.org/10.24380/q2si-ti6i, 2023. a
Dollard, G., Dumitrean, P., Telling, S., Dixon, J., and Derwent, R.: Observed trends in ambient concentrations of C2–C8 hydrocarbons in the United Kingdom over the period from 1993 to 2004, Atmos. Environ., 41, 2559–2569, https://doi.org/10.1016/j.atmosenv.2006.11.020, 2007. a, b
Dominutti, P., Nogueira, T., Fornaro, A., and Borbon, A.: One decade of VOCs measurements in São Paulo megacity: Composition, variability, and emission evaluation in a biofuel usage context, Sci. Total Environ., 738, 139790, https://doi.org/10.1016/j.scitotenv.2020.139790, 2020. a
Dunmore, R. E., Whalley, L. K., Sherwen, T., Evans, M. J., Heard, D. E., Hopkins, J. R., Lee, J. D., Lewis, A. C., Lidster, R. T., Rickard, A. R., and Hamilton, J. F.: Atmospheric ethanol in London and the potential impacts of future fuel formulations, Faraday Discuss., 189, 105–120, https://doi.org/10.1039/C5FD00190K, 2016. a
EBAS: EBAS databse infrastructure, https://ebas-data.nilu.no/Default.aspx (last access: 1 July 2024), 2023. a
Emberson, L.: Effects of ozone on agriculture, forests and grasslands, Philos. T. R. Soc. A, 378, 20190327, https://doi.org/10.1098/rsta.2019.0327, 2020. a
EMEP MSC-W: Open Source GenChem 1.0.0 documentation, https://genchem.readthedocs.io/en/latest/index.html (last access: 1 July 2024), 2020b. a
EMEP MSC-W: Open Source EMEP/MSC-W model v5.0 (202310), Zenodo [code], https://doi.org/10.5281/zenodo.8431553, 2023. a
Filleul, L., Cassadou, S., Médina, S., Fabres, P., Lefranc, A., Eilstein, D., Tertre, A. L., Pascal, L., Chardon, B., Blanchard, M., Declercq, C., Jusot, J.-F., Prouvost, H., and Ledrans, M.: The Relation Between Temperature, Ozone, and Mortality in Nine French Cities During the Heat Wave of 2003, Environ. Health Persp., 114, 1344–1347, https://doi.org/10.1289/ehp.8328, 2006. a
Franco, B., Bader, W., Toon, G., Bray, C., Perrin, A., Fischer, E., Sudo, K., Boone, C., Bovy, B., Lejeune, B., Servais, C., and Mahieu, E.: Retrieval of ethane from ground-based FTIR solar spectra using improved spectroscopy: Recent burden increase above Jungfraujoch, J. Quant. Spectrosc. Ra., 160, 36–49, https://doi.org/10.1016/j.jqsrt.2015.03.017, 2015. a
Gaimoz, C., Stéphane, S., Valérie, G., Frank, H., Jonathan, W., Nadine, L., Olivier, P., Bernard, B., d’Argouges Odile, Roland, S.-E., and Jean, S.: Volatile organic compounds sources in Paris in spring 2007. Part II: source apportionment using positive matrix factorisation, Environ. Chem., 8, 91–103, https://doi.org/10.1071/EN10067, 2011. a
Ge, Y.: Data for evaluation of modelled versus observed NMVOC compounds at EMEP sites in Europe, Zenodo [data set], https://doi.org/10.5281/zenodo.10417827, 2023. a
Ge, Y., Heal, M. R., Stevenson, D. S., Wind, P., and Vieno, M.: Evaluation of global EMEP MSC-W (rv4.34) WRF (v3.9.1.1) model surface concentrations and wet deposition of reactive N and S with measurements, Geosci. Model Dev., 14, 7021–7046, https://doi.org/10.5194/gmd-14-7021-2021, 2021. a
Ge, Y., Simpson, D., and Solberg, S.: Comparisons of modelled versus observed NMVOC, 2018 and IMP periods, EMEP Technical Report 1/2023, The Norwegian Meteorological Institute, Oslo, Norway, https://emep.int/publ/reports/2023/EMEP_Status_Report_1_2023.pdf (last access: 1 July 2024), 2023a. a
Ge, Y., Vieno, M., Stevenson, D. S., Wind, P., and Heal, M. R.: Global sensitivities of reactive N and S gas and particle concentrations and deposition to precursor emissions reductions, Atmos. Chem. Phys., 23, 6083–6112, https://doi.org/10.5194/acp-23-6083-2023, 2023b. a
Gilman, J. B., Lerner, B. M., Kuster, W. C., and de Gouw, J. A.: Source Signature of Volatile Organic Compounds from Oil and Natural Gas Operations in Northeastern Colorado, Environ. Sci. Technol., 47, 1297–1305, https://doi.org/10.1021/es304119a, 2013. a
Gkatzelis, G. I., Coggon, M. M., McDonald, B. C., Peischl, J., Gilman, J. B., Aikin, K. C., Robinson, M. A., Canonaco, F., Prevot, A. S. H., Trainer, M., and Warneke, C.: Observations Confirm that Volatile Chemical Products Are a Major Source of Petrochemical Emissions in U.S. Cities, Environ. Sci. Technol., 55, 4332–4343, https://doi.org/10.1021/acs.est.0c05471, 2021. a
Grant, A., Yates, E. L., Simmonds, P. G., Derwent, R. G., Manning, A. J., Young, D., Shallcross, D. E., and O'Doherty, S.: A five year record of high-frequency in situ measurements of non-methane hydrocarbons at Mace Head, Ireland, Atmos. Meas. Tech., 4, 955–964, https://doi.org/10.5194/amt-4-955-2011, 2011. a, b, c
Guenther, A. B., Jiang, X., Heald, C. L., Sakulyanontvittaya, T., Duhl, T., Emmons, L. K., and Wang, X.: The Model of Emissions of Gases and Aerosols from Nature version 2.1 (MEGAN2.1): an extended and updated framework for modeling biogenic emissions, Geosci. Model Dev., 5, 1471–1492, https://doi.org/10.5194/gmd-5-1471-2012, 2012. a, b
Guevara, M.: The CAMS anthropogenic temporal profiles: CAMS-TEMPO, in: CAMS2_61 – Global and European emission inventories. Documentation of CAMS emission inventory products, cams261_2022sc1 – product documentation 6, 32–47, Copernicus Atmosphere Monitoring Service [data set], https://doi.org/10.24380/q2si-ti6i, 2023. a
Guevara, M., Jorba, O., Tena, C., Denier van der Gon, H., Kuenen, J., Elguindi, N., Darras, S., Granier, C., and Pérez García-Pando, C.: Copernicus Atmosphere Monitoring Service TEMPOral profiles (CAMS-TEMPO): global and European emission temporal profile maps for atmospheric chemistry modelling, Earth Syst. Sci. Data, 13, 367–404, https://doi.org/10.5194/essd-13-367-2021, 2021. a
Hallquist, M., Wenger, J. C., Baltensperger, U., Rudich, Y., Simpson, D., Claeys, M., Dommen, J., Donahue, N. M., George, C., Goldstein, A. H., Hamilton, J. F., Herrmann, H., Hoffmann, T., Iinuma, Y., Jang, M., Jenkin, M. E., Jimenez, J. L., Kiendler-Scharr, A., Maenhaut, W., McFiggans, G., Mentel, Th. F., Monod, A., Prévôt, A. S. H., Seinfeld, J. H., Surratt, J. D., Szmigielski, R., and Wildt, J.: The formation, properties and impact of secondary organic aerosol: current and emerging issues, Atmos. Chem. Phys., 9, 5155–5236, https://doi.org/10.5194/acp-9-5155-2009, 2009. a
Helmig, D., Petrenko, V., Martinerie, P., Witrant, E., Röckmann, T., Zuiderweg, A., Holzinger, R., Hueber, J., Thompson, C., White, J. W. C., Sturges, W., Baker, A., Blunier, T., Etheridge, D., Rubino, M., and Tans, P.: Reconstruction of Northern Hemisphere 1950–2010 atmospheric non-methane hydrocarbons, Atmos. Chem. Phys., 14, 1463–1483, https://doi.org/10.5194/acp-14-1463-2014, 2014. a, b
Helmig, D., Rossabi, S., Hueber, J., Tans, P., Montzka, S. A., Masarie, K., Thoning, K. Plass-Duelmer, C., Claude, A., Carpenter, L. J., Lewis, A. C., Punjabi, S., Reimann, S. Vollmer, M. K., Steinbrecher, R., Hannigan, J. W., Emmons, L. K., Mahieu, E., Franco, B. Smale, D., and Pozzer, A.: Reversal of global atmospheric ethane and propane trends largely due to US oil and natural gas production, Nat. Geosci., 9, 490–495, https://doi.org/10.1038/ngeo2721, 2016. a
Hobbs, P., Webb, J., Mottram, T., Grant, B., and Misselbrook, T.: Emissions of volatile organic compounds originating from UK livestock agriculture, J. Sci. Food Agr., 84, 1414–1420, https://doi.org/10.1002/jsfa.1810, 2004. a, b
Hoerger, C. C., Claude, A., Plass-Duelmer, C., Reimann, S., Eckart, E., Steinbrecher, R., Aalto, J., Arduini, J., Bonnaire, N., Cape, J. N., Colomb, A., Connolly, R., Diskova, J., Dumitrean, P., Ehlers, C., Gros, V., Hakola, H., Hill, M., Hopkins, J. R., Jäger, J., Junek, R., Kajos, M. K., Klemp, D., Leuchner, M., Lewis, A. C., Locoge, N., Maione, M., Martin, D., Michl, K., Nemitz, E., O'Doherty, S., Pérez Ballesta, P., Ruuskanen, T. M., Sauvage, S., Schmidbauer, N., Spain, T. G., Straube, E., Vana, M., Vollmer, M. K., Wegener, R., and Wenger, A.: ACTRIS non-methane hydrocarbon intercomparison experiment in Europe to support WMO GAW and EMEP observation networks, Atmos. Meas. Tech., 8, 2715–2736, https://doi.org/10.5194/amt-8-2715-2015, 2015. a, b, c, d
Hoesly, R. M., Smith, S. J., Feng, L., Klimont, Z., Janssens-Maenhout, G., Pitkanen, T., Seibert, J. J., Vu, L., Andres, R. J., Bolt, R. M., Bond, T. C., Dawidowski, L., Kholod, N., Kurokawa, J.-I., Li, M., Liu, L., Lu, Z., Moura, M. C. P., O'Rourke, P. R., and Zhang, Q.: Historical (1750–2014) anthropogenic emissions of reactive gases and aerosols from the Community Emissions Data System (CEDS), Geosci. Model Dev., 11, 369–408, https://doi.org/10.5194/gmd-11-369-2018, 2018. a
Hoor, P., Borken-Kleefeld, J., Caro, D., Dessens, O., Endresen, O., Gauss, M., Grewe, V., Hauglustaine, D., Isaksen, I. S. A., Jöckel, P., Lelieveld, J., Myhre, G., Meijer, E., Olivie, D., Prather, M., Schnadt Poberaj, C., Shine, K. P., Staehelin, J., Tang, Q., van Aardenne, J., van Velthoven, P., and Sausen, R.: The impact of traffic emissions on atmospheric ozone and OH: results from QUANTIFY, Atmos. Chem. Phys., 9, 3113–3136, https://doi.org/10.5194/acp-9-3113-2009, 2009. a
Hov, Ø., Sorteberg, A., Schmidbauer, N., Solberg, S., Stordal, F., Simpson, D., Lindskog, A., Areskoug, H., Pedro, O., Lätilä, H., and Heidam, N. Z.: European VOC Emission Estimates Evaluated by Measurements and Model Calculations, J. Atmos. Chem., 28, 173–193, 1997. a
Huang, G., Brook, R., Crippa, M., Janssens-Maenhout, G., Schieberle, C., Dore, C., Guizzardi, D., Muntean, M., Schaaf, E., and Friedrich, R.: Speciation of anthropogenic emissions of non-methane volatile organic compounds: a global gridded data set for 1970–2012, Atmos. Chem. Phys., 17, 7683–7701, https://doi.org/10.5194/acp-17-7683-2017, 2017. a, b, c
Jenkin, M., Derwent, R., and Wallington, T.: Photochemical ozone creation potentials for volatile organic compounds: Rationalization and estimation, Atmos. Environ., 163, 128–137, https://doi.org/10.1016/j.atmosenv.2017.05.024, 2017. a
Jenkin, M., Khan, M., Shallcross, D., Bergström, R., Simpson, D., Murphy, K., and Rickard, A.: The CRI v2.2 reduced degradation scheme for isoprene, Atmos. Environ., 212, 172–182, https://doi.org/10.1016/j.atmosenv.2019.05.055, 2019. a
Jenkin, M. E., Watson, L. A., Utembe, S. R., and Shallcross, D. E.: A Common Representative Intermediates (CRI) mechanism for VOC degradation. Part 1: Gas phase mechanism development, Atmos. Environ., 42, 7185–7195, https://doi.org/10.1016/j.atmosenv.2008.07.028, 2008. a, b
Jonson, J. E., Simpson, D., Fagerli, H., and Solberg, S.: Can we explain the trends in European ozone levels?, Atmos. Chem. Phys., 6, 51–66, https://doi.org/10.5194/acp-6-51-2006, 2006. a
Jonson, J. E., Borken-Kleefeld, J., Simpson, D., Nyíri, A., Posch, M., and Heyes, C.: Impact of excess NOx emissions from diesel cars on air quality, public health and eutrophication in Europe, Environ. Res. Lett., 12, 094017, https://doi.org/10.1088/1748-9326/aa8850, 2017. a
Kanakidou, M., Seinfeld, J. H., Pandis, S. N., Barnes, I., Dentener, F. J., Facchini, M. C., Van Dingenen, R., Ervens, B., Nenes, A., Nielsen, C. J., Swietlicki, E., Putaud, J. P., Balkanski, Y., Fuzzi, S., Horth, J., Moortgat, G. K., Winterhalter, R., Myhre, C. E. L., Tsigaridis, K., Vignati, E., Stephanou, E. G., and Wilson, J.: Organic aerosol and global climate modelling: a review, Atmos. Chem. Phys., 5, 1053–1123, https://doi.org/10.5194/acp-5-1053-2005, 2005. a
Keenan, T., Niinemets, U., Sabate, S., Gracia, C., and Penuelas, J.: Process based inventory of isoprenoid emissions from European forests: model comparisons, current knowledge and uncertainties, Atmos. Chem. Phys., 9, 4053–4076, 2009. a
Kroll, J. H. and Seinfeld, J. H.: Chemistry of secondary organic aerosol: Formation and evolution of low-volatility organics in the atmosphere, Atmos. Environ., 42, 3593–3624, https://doi.org/10.1016/j.atmosenv.2008.01.003, 2008. a
Kuenen, J., Dellaert, S., Visschedijk, A., Jalkanen, J.-P., Super, I., and Denier van der Gon, H.: CAMS-REG-v4: a state-of-the-art high-resolution European emission inventory for air quality modelling, Earth Syst. Sci. Data, 14, 491–515, https://doi.org/10.5194/essd-14-491-2022, 2022. a, b
Lanz, V. A., Hueglin, C., Buchmann, B., Hill, M., Locher, R., Staehelin, J., and Reimann, S.: Receptor modeling of C2–C7 hydrocarbon sources at an urban background site in Zurich, Switzerland: changes between 1993–1994 and 2005–2006, Atmos. Chem. Phys., 8, 2313–2332, https://doi.org/10.5194/acp-8-2313-2008, 2008. a
Lewis, A. C., Carpenter, L. J., and Pilling, M. J.: Nonmethane hydrocarbons in Southern Ocean boundary layer air, J. Geophys. Res.-Atmos., 106, 4987–4994, https://doi.org/10.1029/2000JD900634, 2001. a
Lewis, A. C., Hopkins, J. R., Carslaw, D. C., Hamilton, J. F., Nelson, B. S., Stewart, G., Dernie, J., Passant, N., and Murrells, T.: An increasing role for solvent emissions and implications for future measurements of volatile organic compounds, Philos. T. R. Soc. A, 378, 20190328, https://doi.org/10.1098/rsta.2019.0328, 2020. a, b
Li, B., Ho, S. S. H., Xue, Y., Huang, Y., Wang, L., Cheng, Y., Dai, W., Zhong, H., Cao, J., and Lee, S.: Characterizations of volatile organic compounds (VOCs) from vehicular emissions at roadside environment: The first comprehensive study in Northwestern China, Atmos. Environ., 161, 1–12, https://doi.org/10.1016/j.atmosenv.2017.04.029, 2017. a
Li, B., Ho, S. S. H., Gong, S., Ni, J., Li, H., Han, L., Yang, Y., Qi, Y., and Zhao, D.: Characterization of VOCs and their related atmospheric processes in a central Chinese city during severe ozone pollution periods, Atmos. Chem. Phys., 19, 617–638, https://doi.org/10.5194/acp-19-617-2019, 2019. a
Li, C., Li, Q., Tong, D., Wang, Q., Wu, M., Sun, B., Su, G., and Tan, L.: Environmental impact and health risk assessment of volatile organic compound emissions during different seasons in Beijing, J. Environ. Sci., 93, 1–12, https://doi.org/10.1016/j.jes.2019.11.006, 2020. a
Li, Q., Gong, D., Wang, H., Wang, Y., Han, S., Wu, G., Deng, S., Yu, P., Wang, W., and Wang, B.: Rapid increase in atmospheric glyoxal and methylglyoxal concentrations in Lhasa, Tibetan Plateau: Potential sources and implications, Sci. Total Environ., 824, 153782, https://doi.org/10.1016/j.scitotenv.2022.153782, 2022. a
Malley, C. S., Braban, C. F., Dumitrean, P., Cape, J. N., and Heal, M. R.: The impact of speciated VOCs on regional ozone increment derived from measurements at the UK EMEP supersites between 1999 and 2012, Atmos. Chem. Phys., 15, 8361–8380, https://doi.org/10.5194/acp-15-8361-2015, 2015. a
Matthews, B. and Wankmüller, R.: Methodologies applied to the CEIP GNFR gap-filling 2021 Part I: Main Pollutants (NOx, NMVOCs, SOx, NH3, CO), Particulate Matter (PM2.5, PM10, PMcoarse) and Black Carbon (BC) for the years 2000 to 2019., EMEP/CEIP Technical Report 2/2021, CEIP Vienna, https://www.ceip.at/fileadmin/inhalte/ceip/00_pdf_other/ 2021/main_pm_bc_gap-filling_documentation_2021_final.pdf (last access: 1 July 2024), 2021. a
McDonald, B. C., Gentner, D. R., Goldstein, A. H., and Harley, R. A.: Long-Term Trends in Motor Vehicle Emissions in U.S. Urban Areas, Environ. Sci. Technol., 47, 10022–10031, https://doi.org/10.1021/es401034z, 2013. a
Mills, G., Sharps, K., Simpson, D., Pleijel, H., Broberg, M., Uddling, J., Jaramillo, F., Davies, William, J., Dentener, F., Berg, M., Agrawal, M., Agrawal, S. B., Ainsworth, E. A., Büker, P., Emberson, L., Feng, Z., Harmens, H., Hayes, F., Kobayashi, K., Paoletti, E., and Dingenen, R.: Ozone pollution will compromise efforts to increase global wheat production, Glob. Change Biol., 24, 3560–3574, https://doi.org/10.1111/gcb.14157, 2018. a
Mo, Z., Cui, R., Yuan, B., Cai, H., McDonald, B. C., Li, M., Zheng, J., and Shao, M.: A mass-balance-based emission inventory of non-methane volatile organic compounds (NMVOCs) for solvent use in China, Atmos. Chem. Phys., 21, 13655–13666, https://doi.org/10.5194/acp-21-13655-2021, 2021. a, b
Möllmann-Coers, M., Klemp, D., Mannschreck, K., and Slemr, F.: Statistical study of the diurnal variation of modeled and measured NMHC contributions, Atmos. Environ., 36, 109–122, https://doi.org/10.1016/S1352-2310(02)00217-0, 2002. a
Niedojadlo, A., Becker, K. H., Kurtenbach, R., and Wiesen, P.: The contribution of traffic and solvent use to the total NMVOC emission in a German city derived from measurements and CMB modelling, Atmos. Environ., 41, 7108–7126, https://doi.org/10.1016/j.atmosenv.2007.04.056, 2007. a
Oliveira, K., Guevara, M., Jorba, O., Querol, X., and García-Pando, C. P.: A new NMVOC speciated inventory for a reactivity-based approach to support ozone control strategies in Spain, Sci. Total Environ., 867, 161449, https://doi.org/10.1016/j.scitotenv.2023.161449, 2023. a, b
Parrish, D. D., Trainer, M., Young, V., Goldan, P. D., Kuster, W. C., Jobson, B. T., Fehsenfeld, F. C., Lonneman, W. A., Zika, R. D., Farmer, C. T., Riemer, D. D., and Rodgers, M. O.: Internal consistency tests for evaluation of measurements of anthropogenic hydrocarbons in the troposphere, J. Geophys. Res.-Atmos., 103, 22339–22359, https://doi.org/10.1029/98JD01364, 1998. a
Passant, N.: Speciation of UK emissions of non-methane volatile organic compounds, Report ENV-0545 ENV-0545, AEA Technology, Culham, Abingdon, United Kingdom, https://uk-air.defra.gov.uk/assets/documents/reports/empire/AEAT_ENV_0545_final_v2.pdf (last access: 1 July 2024), 2002. a
Peischl, J., Ryerson, T. B., Brioude, J., Aikin, K. C., Andrews, A. E., Atlas, E., Blake, D., Daube, B. C., de Gouw, J. A., Dlugokencky, E., Frost, G. J., Gentner, D. R., Gilman, J. B., Goldstein, A. H., Harley, R. A., Holloway, J. S., Kofler, J., Kuster, W. C., Lang, P. M., Novelli, P. C., Santoni, G. W., Trainer, M., Wofsy, S. C., and Parrish, D. D.: Quantifying sources of methane using light alkanes in the Los Angeles basin, California, J. Geophys. Res.-Atmos., 118, 4974–4990, https://doi.org/10.1002/jgrd.50413, 2013. a
Pfister, G. G., Emmons, L. K., Hess, P. G., Lamarque, J. F., Orlando, J. J., Walters, S., Guenther, A., Palmer, P. I., and Lawrence, P. J.: Contribution of isoprene to chemical budgets: A model tracer study with the NCAR CTM MOZART-4, J. Geophys. Res., 113, D05308, https://doi.org/10.1029/2007JD008948, 2008. a
Plass-Dülmer, C., Michl, K., Ruf, R., and Berresheim, H.: C2–C8 Hydrocarbon measurement and quality control procedures at the Global Atmosphere Watch Observatory Hohenpeissenberg, Jo. Chromatogr. A, 953, 175–197, https://doi.org/10.1016/S0021-9673(02)00128-0, 2002. a
Plass-Dülmer, C., Schmidbauer, N., Slemr, J., Slemr, F., and D'Souza, H.: European hydrocarbon intercomparison experiment AMOHA part 4: Canister sampling of ambient air, J. Geophys. Res.-Atmos., 111, D04306, https://doi.org/10.1029/2005JD006351, 2006. a, b, c
Pye, H. O. T., Appel, K. W., Seltzer, K. M., Ward-Caviness, C. K., and Murphy, B. N.: Human-Health Impacts of Controlling Secondary Air Pollution Precursors, Environ. Sci. Tech. Lett., 9, 96–101, https://doi.org/10.1021/acs.estlett.1c00798, 2022. a
Rappenglück, B., Apel, E., Bauerfeind, M., Bottenheim, J., Brickell, P., Čavolka, P., Cech, J., Gatti, L., Hakola, H., Honzak, J., Junek, R., Martin, D., Noone, C., Plass-Dülmer, C., Travers, D., and Wang, D.: The first VOC intercomparison exercise within the Global Atmosphere Watch (GAW), Atmos. Environ., 40, 7508–7527, https://doi.org/10.1016/j.atmosenv.2006.07.016, 2006. a
Read, K. A., Carpenter, L. J., Arnold, S. R., Beale, R., Nightingale, P. D., Hopkins, J. R., Lewis, A. C., Lee, J. D., Mendes, L., and Pickering, S. J.: Multiannual Observations of Acetone, Methanol, and Acetaldehyde in Remote Tropical Atlantic Air: Implications for Atmospheric OVOC Budgets and Oxidative Capacity, Environ. Sci. Technol., 46, 11028–11039, https://doi.org/10.1021/es302082p, 2012. a
Reimann, S., Calanca, P., and Hofer, P.: The anthropogenic contribution to isoprene concentrations in a rural atmosphere, Atmos. Environ., 34, 109–115, https://doi.org/10.1016/S1352-2310(99)00285-X, 2000. a
Reimann, S., Wegener, R., Claude, A., and Sauvage, S.: Updated Measurement Guideline for NOx and VOCs (deliverable 3.17 of ACTRIS-2), https://www.actris.eu/sites/default/files/inline-files/WP3_D3.17_M42_0.pdf (last access: 1 July 2024), 2018. a
Rodigast, M., Mutzel, A., Schindelka, J., and Herrmann, H.: A new source of methylglyoxal in the aqueous phase, Atmos. Chem. Phys., 16, 2689–2702, https://doi.org/10.5194/acp-16-2689-2016, 2016. a
Russo, R. S., Zhou, Y., White, M. L., Mao, H., Talbot, R., and Sive, B. C.: Multi-year (2004–2008) record of nonmethane hydrocarbons and halocarbons in New England: seasonal variations and regional sources, Atmos. Chem. Phys., 10, 4909–4929, https://doi.org/10.5194/acp-10-4909-2010, 2010. a
Salameh, T., Borbon, A., Afif, C., Sauvage, S., Leonardis, T., Gaimoz, C., and Locoge, N.: Composition of gaseous organic carbon during ECOCEM in Beirut, Lebanon: new observational constraints for VOC anthropogenic emission evaluation in the Middle East, Atmos. Chem. Phys., 17, 193–209, https://doi.org/10.5194/acp-17-193-2017, 2017. a
aunders, S. M., Jenkin, M. E., Derwent, R. G., and Pilling, M. J.: Protocol for the development of the Master Chemical Mechanism, MCM v3 (Part A): tropospheric degradation of non-aromatic volatile organic compounds, Atmos. Chem. Phys., 3, 161–180, https://doi.org/10.5194/acp-3-161-2003, 2003. a, b
Sauvage, S., Plaisance, H., Locoge, N., Wroblewski, A., Coddeville, P., and Galloo, J.: Long term measurement and source apportionment of non-methane hydrocarbons in three French rural areas, Atmos. Environ., 43, 2430–2441, https://doi.org/10.1016/j.atmosenv.2009.02.001, 2009. a
Seinfeld, J. and Pandis, S.: Atmospheric chemistry and physics. From air pollution to climate change, John Wiley and Sons, inc., New York, ISBN 9781118947401, 1998. a
Simpson, D.: Hydrocarbon reactivity and ozone formation in Europe, J. Atmos. Chem., 20, 163–177, https://doi.org/10.1007/BF00696556, 1995. a
Simpson, D., Winiwarter, W., Börjesson, G., Cinderby, S., Ferreiro, A., Guenther, A., Hewitt, C. N., Janson, R., Khalil, M. A. K., Owen, S., Pierce, T. E., Puxbaum, H., Shearer, M., Skiba, U., Steinbrecher, R., Tarrasón, L., and Öquist, M. G.: Inventorying emissions from Nature in Europe, J. Geophys. Res., 104, 8113–8152, 1999. a, b, c
Simpson, D., Benedictow, A., Berge, H., Bergström, R., Emberson, L. D., Fagerli, H., Flechard, C. R., Hayman, G. D., Gauss, M., Jonson, J. E., Jenkin, M. E., Nyíri, A., Richter, C., Semeena, V. S., Tsyro, S., Tuovinen, J.-P., Valdebenito, Á., and Wind, P.: The EMEP MSC-W chemical transport model – technical description, Atmos. Chem. Phys., 12, 7825–7865, https://doi.org/10.5194/acp-12-7825-2012, 2012. a, b, c, d, e
Simpson, D., Tsyro, S., and Wind, P.: Updates to the EMEP/MSC-W model, in: Transboundary particulate matter, photo-oxidants, acidifying and eutrophying components. EMEP Status Report 1/2015, 129–138, https://emep.int/publ/reports/2015/EMEP_Status_Report_1_2015.pdf (last access: 1 July 2024), 2015. a
Simpson, D., Bergström, R., Briolat, A., Imhof, H., Johansson, J., Priestley, M., and Valdebenito, A.: GenChem v1.0 – a chemical pre-processing and testing system for atmospheric modelling, Geosci. Model Dev., 13, 6447–6465, https://doi.org/10.5194/gmd-13-6447-2020, 2020. a, b, c, d
Simpson, D., van Caspel, W., Benedictow, A., Fagerli, H., Jonson, J., Tsyro, S., Valdebento, A., and Wind, P.: Updates to the EMEP/MSC-W model, 2022–2023, in: Transboundary particulate matter, photo-oxidants, acidifying and eutrophying components. EMEP Status Report 1/2023, 159–179, https://emep.int/publ/reports/2023/EMEP_Status_Report_1_2023.pdf (last access: 1 July 2024), 2023. a, b, c, d
Slemr, J., Slemr, F., Partridge, R., D'Souza, H., and Schmidbauer, N.: Accurate Measurements of Hydrocarbons in the Atmosphere (AMOHA): Three European intercomparisons, J. Geophys. Res.-Atmos., 107, ACH 15-1–ACH 15–25, https://doi.org/10.1029/2001JD001357, 2002. a
Solberg, S., Claude, A., Reimann, S., Sauvage, S., and Walker, S.-E.: VOC measurements 2020, EMEP/CCC-Report 4/2022, Norwegian Institute for Air Research, ISBN 978-82-425-3099-8, https://projects.nilu.no/ccc/reports/EMEP_CCC-Report_4_2022_VOC_measurements_2020.pdf (last access: 1 July 2024), 2022. a
tavrakou, T., Müller, J.-F., De Smedt, I., Van Roozendael, M., Kanakidou, M., Vrekoussis, M., Wittrock, F., Richter, A., and Burrows, J. P.: The continental source of glyoxal estimated by the synergistic use of spaceborne measurements and inverse modelling, Atmos. Chem. Phys., 9, 8431–8446, https://doi.org/10.5194/acp-9-8431-2009, 2009. a
Stockwell, W. R., Geiger, H., and Becker, K. H.: Estimation of incremental reactivities for multiple day scenarios: an application to ethane and dimethyoxymethane, Atmos. Environ., 35, 929–939, 2001. a
Swarthout, R. F., Russo, R. S., Zhou, Y., Hart, A. H., and Sive, B. C.: Volatile organic compound distributions during the NACHTT campaign at the Boulder Atmospheric Observatory: Influence of urban and natural gas sources, J. Geophys. Res.-Atmos., 118, 10614–10637, https://doi.org/10.1002/jgrd.50722, 2013. a
van Caspel, W. E., Simpson, D., Jonson, J. E., Benedictow, A. M. K., Ge, Y., di Sarra, A., Pace, G., Vieno, M., Walker, H. L., and Heal, M. R.: Implementation and evaluation of updated photolysis rates in the EMEP MSC-W chemistry-transport model using Cloud-J v7.3e, Geosci. Model Dev., 16, 7433–7459, https://doi.org/10.5194/gmd-16-7433-2023, 2023. a, b, c
Veefkind, J., Aben, I., McMullan, K., Förster, H., de Vries, J., Otter, G., Claas, J., Eskes, H., de Haan, J., Kleipool, Q., van Weele, M., Hasekamp, O., Hoogeveen, R., Landgraf, J., Snel, R., Tol, P., Ingmann, P., Voors, R., Kruizinga, B., Vink, R., Visser, H., and Levelt, P.: TROPOMI on the ESA Sentinel-5 Precursor: A GMES mission for global observations of the atmospheric composition for climate, air quality and ozone layer applications, Remote Sens. Environ., 120, 70–83, https://doi.org/10.1016/j.rse.2011.09.027, 2012. a
von Schneidemesser, E., Monks, P. S., and Plass-Duelmer, C.: Global comparison of VOC and CO observations in urban areas, Atmos. Environ., 44, 5053–5064, https://doi.org/10.1016/j.atmosenv.2010.09.010, 2010. a
von Schneidemesser, E., Coates, J., Denier van der Gon, H., Visschedijk, A., and Butler, T.: Variation of the NMVOC speciation in the solvent sector and the sensitivity of modelled tropospheric ozone, Atmos. Environ., 135, 59–72, https://doi.org/10.1016/j.atmosenv.2016.03.057, 2016. a
von Schneidemesser, E., McDonald, B. C., Denier van der Gon, H., Crippa, M., Guizzardi, D., Borbon, A., Dominutti, P., Huang, G., Jansens-Maenhout, G., Li, M., Ou-Yang, C.-F., Tisinai, S., and Wang, J.-L.: Comparing Urban Anthropogenic NMVOC Measurements With Representation in Emission Inventories – A Global Perspective, J. Geophys. Res., 128, e2022JD037906, https://doi.org/10.1029/2022JD037906, 2023. a, b, c, d
Waked, A., Sauvage, S., Borbon, A., Gauduin, J., Pallares, C., Vagnot, M.-P., Léonardis, T., and Locoge, N.: Multi-year levels and trends of non-methane hydrocarbon concentrations observed in ambient air in France, Atmos. Environ., 141, 263–275, https://doi.org/10.1016/j.atmosenv.2016.06.059, 2016. a, b, c
Watson, L. A., Shallcross, D. E., Utembe, S. R., and Jenkin, M. E.: A Common Representative Intermediates (CRI) mechanism for VOC degradation. Part 2: Gas phase mechanism reduction, Atmos. Environ., 42, 7196–7204, https://doi.org/10.1016/j.atmosenv.2008.07.034, 2008. a, b, c
Whalley, L. K., Stone, D., Dunmore, R., Hamilton, J., Hopkins, J. R., Lee, J. D., Lewis, A. C., Williams, P., Kleffmann, J., Laufs, S., Woodward-Massey, R., and Heard, D. E.: Understanding in situ ozone production in the summertime through radical observations and modelling studies during the Clean air for London project (ClearfLo), Atmos. Chem. Phys., 18, 2547–2571, https://doi.org/10.5194/acp-18-2547-2018, 2018. a
Wiedinmyer, C., Tie, X., Guenther, A., Neilson, R., and Granier, C.: Future Changes in Biogenic Isoprene Emissions: How Might They Affect Regional and Global Atmospheric Chemistry?, Earth Interact., 10, 1–19, https://doi.org/10.1175/EI174.1, 2006. a
Wiedinmyer, C., Kimura, Y., McDonald-Buller, E. C., Emmons, L. K., Buchholz, R. R., Tang, W., Seto, K., Joseph, M. B., Barsanti, K. C., Carlton, A. G., and Yokelson, R.: The Fire Inventory from NCAR version 2.5: an updated global fire emissions model for climate and chemistry applications, Geosci. Model Dev., 16, 3873–3891, https://doi.org/10.5194/gmd-16-3873-2023, 2023. a
Wilde, S. E., Dominutti, P. A., Allen, G., Andrews, S. J., Bateson, P., Bauguitte, S. J.-B., Burton, R. R., Colfescu, I., France, J., Hopkins, J. R., Huang, L., Jones, A. E., Lachlan-Cope, T., Lee, J. D., Lewis, A. C., Mobbs, S. D., Weiss, A., Young, S., and Purvis, R. M.: Speciation of VOC emissions related to offshore North Sea oil and gas production, Atmos. Chem. Phys., 21, 3741–3762, https://doi.org/10.5194/acp-21-3741-2021, 2021. a
Zhang, Y., Wang, X., Zhang, Z., Lü, S., Shao, M., Lee, F. S., and Yu, J.: Species profiles and normalized reactivity of volatile organic compounds from gasoline evaporation in China, Atmos. Environ., 79, 110–118, https://doi.org/10.1016/j.atmosenv.2013.06.029, 2013. a
Short summary
Atmospheric volatile organic compounds (VOCs) constitute many species, acting as precursors to ozone and aerosol. Given the uncertainties in VOC emissions, lack of evaluation studies, and recent changes in emissions, this work adapts the EMEP MSC-W to evaluate emission inventories in Europe. We focus on the varying agreement between modelled and measured VOCs across different species and underscore potential inaccuracies in total and sector-specific emission estimates.
Atmospheric volatile organic compounds (VOCs) constitute many species, acting as precursors to...
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