Atmospheric Chemistry and Physics
Atmospheric Chemistry and Physics
ACP
Articles | Volume 22, issue 13
Articles | Volume 22, issue 13
https://doi.org/10.5194/acp-22-9017-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-22-9017-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
Articles | Volume 22, issue 13
Research article
 | 
13 Jul 2022
Research article |  | 13 Jul 2022

Observations of gas-phase products from the nitrate-radical-initiated oxidation of four monoterpenes

Michelia Dam, Danielle C. Draper, Andrey Marsavin, Juliane L. Fry, and James N. Smith

Related authors

Gas-particle partitioning, molecular weight, and yield of organic nitrate under different urban VOC, NOx, and oxidation conditions during SAPHIR-CHANEL campaign
Farhan R. Nursanto, Quanfu He, Sophia van de Wouw, Annika Zanders, Thorsten Hohaus, Willem S. J. Kroese, Robert Wegener, Max Gerrit Adam, Benjamin Winter, René Dubus, Lukas Kesper, Franz Rohrer, Yuwei Wang, Emily Matthews, Aristeidis Voliotis, Thomas J. Bannan, Gordon McFiggans, Hugh Coe, Yizhen Wu, Milan Roska, Manjula Canagaratna, Mitch Alton, Matthew M. Coggon, Chelsea E. Stockwell, Kelvin H. Bates, Eva Y. Pfannerstill, Sören R. Zorn, Hui Wang, Matthieu Riva, Sebastien Perrier, Boxing Yang, Lu Liu, Anna Novelli, Michelle Färber, Hendrik Fuchs, Andrea Carolina Marcillo Lara, Achim Grasse, Christian Wesolek, Ralf Tillmann, Rupert Holzinger, Maarten C. Krol, Georgios I. Gkatzelis, and Juliane L. Fry
EGUsphere, https://doi.org/10.5194/egusphere-2025-6310,https://doi.org/10.5194/egusphere-2025-6310, 2026
This preprint is open for discussion and under review for Atmospheric Chemistry and Physics (ACP).
Short summary
Development and validation of a NOx+ ratio method for the quantitative separation of inorganic and organic nitrate aerosol using a unit-mass-resolution time-of-flight aerosol chemical speciation monitor equipped with a capture vaporizer (CV-UMR-ToF-ACSM)
Farhan R. Nursanto, Douglas A. Day, Roy Meinen, Rupert Holzinger, Harald Saathoff, Jinglan Fu, Jan Mulder, Ulrike Dusek, and Juliane L. Fry
Atmos. Meas. Tech., 18, 3051–3072, https://doi.org/10.5194/amt-18-3051-2025,https://doi.org/10.5194/amt-18-3051-2025, 2025
Short summary
Seasonal investigation of ultrafine-particle organic composition in an eastern Amazonian rainforest
Adam E. Thomas, Hayley S. Glicker, Alex B. Guenther, Roger Seco, Oscar Vega Bustillos, Julio Tota, Rodrigo A. F. Souza, and James N. Smith
Atmos. Chem. Phys., 25, 959–977, https://doi.org/10.5194/acp-25-959-2025,https://doi.org/10.5194/acp-25-959-2025, 2025
Short summary
Seasonal variations in composition and sources of atmospheric ultrafine particles in urban Beijing based on near-continuous measurements
Xiaoxiao Li, Yijing Chen, Yuyang Li, Runlong Cai, Yiran Li, Chenjuan Deng, Jin Wu, Chao Yan, Hairong Cheng, Yongchun Liu, Markku Kulmala, Jiming Hao, James N. Smith, and Jingkun Jiang
Atmos. Chem. Phys., 23, 14801–14812, https://doi.org/10.5194/acp-23-14801-2023,https://doi.org/10.5194/acp-23-14801-2023, 2023
Short summary
What chemical species are responsible for new particle formation and growth in the Netherlands? A hybrid positive matrix factorization (PMF) analysis using aerosol composition (ACSM) and size (SMPS)
Farhan R. Nursanto, Roy Meinen, Rupert Holzinger, Maarten C. Krol, Xinya Liu, Ulrike Dusek, Bas Henzing, and Juliane L. Fry
Atmos. Chem. Phys., 23, 10015–10034, https://doi.org/10.5194/acp-23-10015-2023,https://doi.org/10.5194/acp-23-10015-2023, 2023
Short summary
More articles (4)

Cited articles

Acosta Navarro, J. C., Smolander, S., Struthers, H., Zorita, E., Ekman, A. M. L., Kaplan, J. O., Guenther, A., Arneth, A., and Riipinen, I.: Global emissions of terpenoid VOCs from terrestrial vegetation in the last millennium, J. Geophys. Res.-Atmos., 119, 6867–6885, https://doi.org/10.1002/2013JD021238, 2014. a
Aljawhary, D., Lee, A. K. Y., and Abbatt, J. P. D.: High-resolution chemical ionization mass spectrometry (ToF-CIMS): application to study SOA composition and processing, Atmos. Meas. Tech., 6, 3211–3224, https://doi.org/10.5194/amt-6-3211-2013, 2013. a
Atkinson, R. and Arey, J.: Gas-phase tropospheric chemistry of biogenic volatile organic compounds: a review, Atmos. Environ., 37, Special Issue: The 1997 Southern California Ozone Study (SCOS97-NARSTO). Dedicated to the Memory of Dr. Glen Cass (1947–2001), 197–219, https://doi.org/10.1016/S1352-2310(03)00391-1, 2003. a, b
Ayres, B. R., Allen, H. M., Draper, D. C., Brown, S. S., Wild, R. J., Jimenez, J. L., Day, D. A., Campuzano-Jost, P., Hu, W., de Gouw, J., Koss, A., Cohen, R. C., Duffey, K. C., Romer, P., Baumann, K., Edgerton, E., Takahama, S., Thornton, J. A., Lee, B. H., Lopez-Hilfiker, F. D., Mohr, C., Wennberg, P. O., Nguyen, T. B., Teng, A., Goldstein, A. H., Olson, K., and Fry, J. L.: Organic nitrate aerosol formation via NO3 + biogenic volatile organic compounds in the southeastern United States, Atmos. Chem. Phys., 15, 13377–13392, https://doi.org/10.5194/acp-15-13377-2015, 2015. a, b
Berndt, T. and Böge, O.: Products and mechanism of the reaction of NO3 with selected acyclic monoalkenes, J. Atmos. Chem., 21, 275–291, https://doi.org/10.1007/BF00696759, 1995. a, b
More articles (39)
Download
Short summary
We performed chamber experiments to measure the composition of the gas-phase reaction products of nitrate-radical-initiated oxidation of four monoterpenes. The total organic yield, effective oxygen-to-carbon ratio, and dimer-to-monomer ratio were correlated with the observed particle formation for the monoterpene systems with some exceptions. The Δ-carene system produced the most particles, followed by β-pinene, with the α-pinene and α-thujene systems producing no particles.
Read more
Share
Altmetrics
Final-revised paper
Preprint