Articles | Volume 22, issue 13
https://doi.org/10.5194/acp-22-9017-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-22-9017-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Observations of gas-phase products from the nitrate-radical-initiated oxidation of four monoterpenes
Michelia Dam
Department of Chemistry, University of California, Irvine, Irvine, USA
Danielle C. Draper
Department of Chemistry, University of California, Irvine, Irvine, USA
Andrey Marsavin
Chemistry Department, Reed College, Portland, USA
Juliane L. Fry
Chemistry Department, Reed College, Portland, USA
Department of Chemistry, University of California, Irvine, Irvine, USA
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Cited
13 citations as recorded by crossref.
- Identification of highly oxygenated organic molecules and their role in aerosol formation in the reaction of limonene with nitrate radical Y. Guo et al. 10.5194/acp-22-11323-2022
- Secondary Organic Aerosol Mass Yields from NO3 Oxidation of α-Pinene and Δ-Carene: Effect of RO2 Radical Fate D. Day et al. 10.1021/acs.jpca.2c04419
- Unravelling the role of silver in addressing the nitrate radical induced photocatalytic oxidation of olefins to epoxides or carbonyl compounds A. Gottuso et al. 10.1016/j.jphotochem.2024.115871
- Formation and temperature dependence of highly oxygenated organic molecules (HOMs) from Δ3-carene ozonolysis Y. Luo et al. 10.5194/acp-24-9459-2024
- A nitrate ion chemical-ionization atmospheric-pressure-interface time-of-flight mass spectrometer (NO3− ToFCIMS) sensitivity study S. Alage et al. 10.5194/amt-17-4709-2024
- Unpacking the diversity of monoterpene oxidation pathways via nitrooxy–alkyl radical ring-opening reactions and nitrooxy–alkoxyl radical bond scissions D. Draper et al. 10.1016/j.jaerosci.2024.106379
- Formation of Highly Oxidized Organic Compounds and Secondary Organic Aerosol from α-Thujene Ozonolysis M. Dam et al. 10.1021/acs.jpca.3c02584
- Influence of anthropogenic emissions on the composition of highly oxygenated organic molecules in Helsinki: a street canyon and urban background station comparison M. Okuljar et al. 10.5194/acp-23-12965-2023
- Indoor Emission, Oxidation, and New Particle Formation of Personal Care Product Related Volatile Organic Compounds T. Wu et al. 10.1021/acs.estlett.4c00353
- Potential pre-industrial–like new particle formation induced by pure biogenic organic vapors in Finnish peatland W. Huang et al. 10.1126/sciadv.adm9191
- Measuring Biogenic Volatile Organic Compounds from Leaves Exposed to Submicron Black Carbon Using Portable Sensor Q. Liu & Y. Liu 10.3390/pollutants4020012
- Investigation of Gas-Phase Products from the NO3 Radical Oxidation of Δ-3-Carene O. Jenks et al. 10.1021/acsearthspacechem.3c00020
- Volatility and chemical composition of secondary organic aerosol derived from acenaphthylene and acenaphthene under various oxidant conditions W. Xiang et al. 10.1016/j.atmosenv.2024.120563
13 citations as recorded by crossref.
- Identification of highly oxygenated organic molecules and their role in aerosol formation in the reaction of limonene with nitrate radical Y. Guo et al. 10.5194/acp-22-11323-2022
- Secondary Organic Aerosol Mass Yields from NO3 Oxidation of α-Pinene and Δ-Carene: Effect of RO2 Radical Fate D. Day et al. 10.1021/acs.jpca.2c04419
- Unravelling the role of silver in addressing the nitrate radical induced photocatalytic oxidation of olefins to epoxides or carbonyl compounds A. Gottuso et al. 10.1016/j.jphotochem.2024.115871
- Formation and temperature dependence of highly oxygenated organic molecules (HOMs) from Δ3-carene ozonolysis Y. Luo et al. 10.5194/acp-24-9459-2024
- A nitrate ion chemical-ionization atmospheric-pressure-interface time-of-flight mass spectrometer (NO3− ToFCIMS) sensitivity study S. Alage et al. 10.5194/amt-17-4709-2024
- Unpacking the diversity of monoterpene oxidation pathways via nitrooxy–alkyl radical ring-opening reactions and nitrooxy–alkoxyl radical bond scissions D. Draper et al. 10.1016/j.jaerosci.2024.106379
- Formation of Highly Oxidized Organic Compounds and Secondary Organic Aerosol from α-Thujene Ozonolysis M. Dam et al. 10.1021/acs.jpca.3c02584
- Influence of anthropogenic emissions on the composition of highly oxygenated organic molecules in Helsinki: a street canyon and urban background station comparison M. Okuljar et al. 10.5194/acp-23-12965-2023
- Indoor Emission, Oxidation, and New Particle Formation of Personal Care Product Related Volatile Organic Compounds T. Wu et al. 10.1021/acs.estlett.4c00353
- Potential pre-industrial–like new particle formation induced by pure biogenic organic vapors in Finnish peatland W. Huang et al. 10.1126/sciadv.adm9191
- Measuring Biogenic Volatile Organic Compounds from Leaves Exposed to Submicron Black Carbon Using Portable Sensor Q. Liu & Y. Liu 10.3390/pollutants4020012
- Investigation of Gas-Phase Products from the NO3 Radical Oxidation of Δ-3-Carene O. Jenks et al. 10.1021/acsearthspacechem.3c00020
- Volatility and chemical composition of secondary organic aerosol derived from acenaphthylene and acenaphthene under various oxidant conditions W. Xiang et al. 10.1016/j.atmosenv.2024.120563
Latest update: 13 Dec 2024
Short summary
We performed chamber experiments to measure the composition of the gas-phase reaction products of nitrate-radical-initiated oxidation of four monoterpenes. The total organic yield, effective oxygen-to-carbon ratio, and dimer-to-monomer ratio were correlated with the observed particle formation for the monoterpene systems with some exceptions. The Δ-carene system produced the most particles, followed by β-pinene, with the α-pinene and α-thujene systems producing no particles.
We performed chamber experiments to measure the composition of the gas-phase reaction products...
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