Articles | Volume 20, issue 13
https://doi.org/10.5194/acp-20-7843-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-20-7843-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
06 Jul 2020
Research article |
| 06 Jul 2020
| 06 Jul 2020
Attributing ozone and its precursors to land transport emissions in Europe and Germany
Deutsches Zentrum für Luft- und Raumfahrt, Institut für Physik
der Atmosphäre, Oberpfaffenhofen, Germany
Astrid Kerkweg
Institut für Geowissenschaften und Meteorologie, Rheinische Friedrich-Wilhelms-Universität Bonn, Bonn, Germany
now at: IEK-8, Forschungszentrum Jülich, Jülich, Germany
Volker Grewe
Deutsches Zentrum für Luft- und Raumfahrt, Institut für Physik
der Atmosphäre, Oberpfaffenhofen, Germany
Delft University of Technology, Aerospace Engineering, Section Aircraft Noise and Climate Effects, Delft, the Netherlands
Patrick Jöckel
Deutsches Zentrum für Luft- und Raumfahrt, Institut für Physik
der Atmosphäre, Oberpfaffenhofen, Germany
Robert Sausen
Deutsches Zentrum für Luft- und Raumfahrt, Institut für Physik
der Atmosphäre, Oberpfaffenhofen, Germany
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Earth system models are important tools to improve our understanding of current climate and to project climate change. For this, it is crucial to understand possible shortcomings in the models. New features of the software package ESMValTool allow for comparing and visualizing a model's performance in reproducing observations within the context of other climate models in an easy and user-friendly way. The aim is to help model developers to assess and monitor climate simulations more efficiently.
Federica Castino, Feijia Yin, Volker Grewe, Hiroshi Yamashita, Sigrun Matthes, Simone Dietmüller, Sabine Baumann, Manuel Soler, Abolfazl Simorgh, Maximilian Mendiguchia Meuser, Florian Linke, and Benjamin Lührs
Geosci. Model Dev., 17, 4031–4052, https://doi.org/10.5194/gmd-17-4031-2024, https://doi.org/10.5194/gmd-17-4031-2024, 2024
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We introduce SolFinder 1.0, a decision-making tool to select trade-offs between different objective functions for optimal aircraft trajectories, including fuel use, flight time, NOx emissions, contrail distance, and climate impact. The module is included in the AirTraf 3.0 submodel and uses weather conditions simulated by the EMAC atmospheric model. This paper focuses on the ability of SolFinder to identify eco-efficient trajectories, reducing a flight's climate impact at limited cost penalties.
Simon Rosanka, Holger Tost, Rolf Sander, Patrick Jöckel, Astrid Kerkweg, and Domenico Taraborrelli
Geosci. Model Dev., 17, 2597–2615, https://doi.org/10.5194/gmd-17-2597-2024, https://doi.org/10.5194/gmd-17-2597-2024, 2024
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The capabilities of the Modular Earth Submodel System (MESSy) are extended to account for non-equilibrium aqueous-phase chemistry in the representation of deliquescent aerosols. When applying the new development in a global simulation, we find that MESSy's bias in modelling routinely observed reduced inorganic aerosol mass concentrations, especially in the United States. Furthermore, the representation of fine-aerosol pH is particularly improved in the marine boundary layer.
Francisco J. Pérez-Invernón, Francisco J. Gordillo-Vázquez, Alejandro Malagón-Romero, and Patrick Jöckel
Atmos. Chem. Phys., 24, 3577–3592, https://doi.org/10.5194/acp-24-3577-2024, https://doi.org/10.5194/acp-24-3577-2024, 2024
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Sprites are electrical discharges that occur in the upper atmosphere. Recent modelling and observational data suggest that they may have a measurable impact on atmospheric chemistry. We incorporate both the occurrence rate of sprites and their production of chemical species into a chemistry–climate model. While our results indicate that sprites have a minimal global influence on atmospheric chemistry, they underscore their noteworthy importance at a regional scale.
Xiaodan Ma, Jianping Huang, Michaela Hegglin, Patrick Joeckel, and Tianliang Zhao
EGUsphere, https://doi.org/10.5194/egusphere-2023-2411, https://doi.org/10.5194/egusphere-2023-2411, 2024
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Our study examines 30 years of tropospheric ozone changes in the Northwest Pacific region. We found a significant increase in ozone levels during spring and summer in the middle-upper troposphere. This change is driven by a complex interplay between stratospheric and tropospheric ozone, with implications for climate and air quality in East Asia. Further research into these mechanisms is needed.
Johannes Pletzer and Volker Grewe
Atmos. Chem. Phys., 24, 1743–1775, https://doi.org/10.5194/acp-24-1743-2024, https://doi.org/10.5194/acp-24-1743-2024, 2024
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Very fast aircraft can travel at 30–40 km altitude and are designed to use liquid hydrogen as fuel instead of kerosene. Depending on their flight altitude, the impact of these aircraft on the atmosphere and climate can change very much. Our results show that a variation inflight latitude can have a considerably higher change in impact compared to a variation in flight altitude. Atmospheric air transport and polar stratospheric clouds play an important role in hypersonic aircraft emissions.
Ryan S. Williams, Michaela I. Hegglin, Patrick Jöckel, Hella Garny, and Keith P. Shine
Atmos. Chem. Phys., 24, 1389–1413, https://doi.org/10.5194/acp-24-1389-2024, https://doi.org/10.5194/acp-24-1389-2024, 2024
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During winter, a brief but abrupt reversal of the mean stratospheric westerly flow (~30 km high) around the Arctic occurs ~6 times a decade. Using a chemistry–climate model, about half of these events are shown to induce large anomalies in Arctic ozone (>25 %) and water vapour (>±25 %) around ~8–12 km altitude for up to 2–3 months, important for weather forecasting. We also calculate a doubling to trebling of the risk in breaches of mid-latitude surface air quality (ozone) standards (~60 ppbv).
Sigrun Matthes, Simone Dietmüller, Katrin Dahlmann, Christine Frömming, Patrick Peter, Hiroshi Yamashita, Volker Grewe, Feijia Yin, and Federica Castino
Geosci. Model Dev. Discuss., https://doi.org/10.5194/gmd-2023-92, https://doi.org/10.5194/gmd-2023-92, 2023
Revised manuscript not accepted
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Aviation aims to reduce its climate effect by identifying alternative climate-optimized aircraft trajectories. Such routing strategies requires a dedicated meteorological service in order to inform on regions of the atmosphere where aviation non-CO2 emissions have a large climate effect, e.g. by contrail formation or nitrogen-oxide (NOx)-induced ozone formation. This study presents calibration factors for individual non-CO2 effects by comparing with the climate response model AirClim.
Elena De La Torre Castro, Tina Jurkat-Witschas, Armin Afchine, Volker Grewe, Valerian Hahn, Simon Kirschler, Martina Krämer, Johannes Lucke, Nicole Spelten, Heini Wernli, Martin Zöger, and Christiane Voigt
Atmos. Chem. Phys., 23, 13167–13189, https://doi.org/10.5194/acp-23-13167-2023, https://doi.org/10.5194/acp-23-13167-2023, 2023
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In this study, we show the differences in the microphysical properties between high-latitude (HL) cirrus and mid-latitude (ML) cirrus over the Arctic, North Atlantic, and central Europe during summer. The in situ measurements are combined with backward trajectories to investigate the influence of the region on cloud formation. We show that HL cirrus are characterized by a lower concentration of larger ice crystals when compared to ML cirrus.
Roland Eichinger, Sebastian Rhode, Hella Garny, Peter Preusse, Petr Pisoft, Aleš Kuchař, Patrick Jöckel, Astrid Kerkweg, and Bastian Kern
Geosci. Model Dev., 16, 5561–5583, https://doi.org/10.5194/gmd-16-5561-2023, https://doi.org/10.5194/gmd-16-5561-2023, 2023
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The columnar approach of gravity wave (GW) schemes results in dynamical model biases, but parallel decomposition makes horizontal GW propagation computationally unfeasible. In the global model EMAC, we approximate it by GW redistribution at one altitude using tailor-made redistribution maps generated with a ray tracer. More spread-out GW drag helps reconcile the model with observations and close the 60°S GW gap. Polar vortex dynamics are improved, enhancing climate model credibility.
Marina Friedel, Gabriel Chiodo, Timofei Sukhodolov, James Keeble, Thomas Peter, Svenja Seeber, Andrea Stenke, Hideharu Akiyoshi, Eugene Rozanov, David Plummer, Patrick Jöckel, Guang Zeng, Olaf Morgenstern, and Béatrice Josse
Atmos. Chem. Phys., 23, 10235–10254, https://doi.org/10.5194/acp-23-10235-2023, https://doi.org/10.5194/acp-23-10235-2023, 2023
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Previously, it has been suggested that springtime Arctic ozone depletion might worsen in the coming decades due to climate change, which might counteract the effect of reduced ozone-depleting substances. Here, we show with different chemistry–climate models that springtime Arctic ozone depletion will likely decrease in the future. Further, we explain why models show a large spread in the projected development of Arctic ozone depletion and use the model spread to constrain future projections.
Simone Dietmüller, Sigrun Matthes, Katrin Dahlmann, Hiroshi Yamashita, Abolfazl Simorgh, Manuel Soler, Florian Linke, Benjamin Lührs, Maximilian M. Meuser, Christian Weder, Volker Grewe, Feijia Yin, and Federica Castino
Geosci. Model Dev., 16, 4405–4425, https://doi.org/10.5194/gmd-16-4405-2023, https://doi.org/10.5194/gmd-16-4405-2023, 2023
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Climate-optimized aircraft trajectories avoid atmospheric regions with a large climate impact due to aviation emissions. This requires spatially and temporally resolved information on aviation's climate impact. We propose using algorithmic climate change functions (aCCFs) for CO2 and non-CO2 effects (ozone, methane, water vapor, contrail cirrus). Merged aCCFs combine individual aCCFs by assuming aircraft-specific parameters and climate metrics. Technically this is done with a Python library.
Abolfazl Simorgh, Manuel Soler, Daniel González-Arribas, Florian Linke, Benjamin Lührs, Maximilian M. Meuser, Simone Dietmüller, Sigrun Matthes, Hiroshi Yamashita, Feijia Yin, Federica Castino, Volker Grewe, and Sabine Baumann
Geosci. Model Dev., 16, 3723–3748, https://doi.org/10.5194/gmd-16-3723-2023, https://doi.org/10.5194/gmd-16-3723-2023, 2023
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This paper addresses the robust climate optimal trajectory planning problem under uncertain meteorological conditions within the structured airspace. Based on the optimization methodology, a Python library has been developed, which can be accessed using the following DOI: https://doi.org/10.5281/zenodo.7121862. The developed tool is capable of providing robust trajectories taking into account all probable realizations of meteorological conditions provided by an EPS computationally very fast.
Markus Kilian, Volker Grewe, Patrick Jöckel, Astrid Kerkweg, Mariano Mertens, Andreas Zahn, and Helmut Ziereis
EGUsphere, https://doi.org/10.5194/egusphere-2023-528, https://doi.org/10.5194/egusphere-2023-528, 2023
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Anthropogenic emissions are a major source of precursors for tropospheric ozone formation. As ozone formation is highly non-linear, we apply a global-regional chemistry-climate model with a source attribution method (tagging) to quantify the contribution of anthropogenic emissions to ozone. We focus on two major polluted areas in Europe, the Po Valley and the Benelux region. Our analysis shows that in particular anthropogenic emissions from Europe contribute largely to ground-level ozone.
Robin N. Thor, Malte Niklaß, Katrin Dahlmann, Florian Linke, Volker Grewe, and Sigrun Matthes
Geosci. Model Dev. Discuss., https://doi.org/10.5194/gmd-2023-126, https://doi.org/10.5194/gmd-2023-126, 2023
Preprint withdrawn
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We develop a simplied method to estimate the climate effects of single flights through CO2 and non-CO2 effects, exclusively based on the aircraft seat category as well as the origin and destination airports. The derived climate effect functions exhibit a mean relative error of only 15 % with respect to results from a climate response model. The method is designed for climate footprint assessments and covers most commerical airlines with seat capacities starting from 101 passengers.
Feijia Yin, Volker Grewe, Federica Castino, Pratik Rao, Sigrun Matthes, Katrin Dahlmann, Simone Dietmüller, Christine Frömming, Hiroshi Yamashita, Patrick Peter, Emma Klingaman, Keith P. Shine, Benjamin Lührs, and Florian Linke
Geosci. Model Dev., 16, 3313–3334, https://doi.org/10.5194/gmd-16-3313-2023, https://doi.org/10.5194/gmd-16-3313-2023, 2023
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This paper describes a newly developed submodel ACCF V1.0 based on the MESSy 2.53.0 infrastructure. The ACCF V1.0 is based on the prototype algorithmic climate change functions (aCCFs) v1.0 to enable climate-optimized flight trajectories. One highlight of this paper is that we describe a consistent full set of aCCFs formulas with respect to fuel scenario and metrics. We demonstrate the usage of the ACCF submodel using AirTraf V2.0 to optimize trajectories for cost and climate impact.
Robin N. Thor, Mariano Mertens, Sigrun Matthes, Mattia Righi, Johannes Hendricks, Sabine Brinkop, Phoebe Graf, Volker Grewe, Patrick Jöckel, and Steven Smith
Geosci. Model Dev., 16, 1459–1466, https://doi.org/10.5194/gmd-16-1459-2023, https://doi.org/10.5194/gmd-16-1459-2023, 2023
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We report on an inconsistency in the latitudinal distribution of aviation emissions between two versions of a data product which is widely used by researchers. From the available documentation, we do not expect such an inconsistency. We run a chemistry–climate model to compute the effect of the inconsistency in emissions on atmospheric chemistry and radiation and find that the radiative forcing associated with aviation ozone is 7.6 % higher when using the less recent version of the data.
Dominik Brunner, Gerrit Kuhlmann, Stephan Henne, Erik Koene, Bastian Kern, Sebastian Wolff, Christiane Voigt, Patrick Jöckel, Christoph Kiemle, Anke Roiger, Alina Fiehn, Sven Krautwurst, Konstantin Gerilowski, Heinrich Bovensmann, Jakob Borchardt, Michal Galkowski, Christoph Gerbig, Julia Marshall, Andrzej Klonecki, Pascal Prunet, Robert Hanfland, Margit Pattantyús-Ábrahám, Andrzej Wyszogrodzki, and Andreas Fix
Atmos. Chem. Phys., 23, 2699–2728, https://doi.org/10.5194/acp-23-2699-2023, https://doi.org/10.5194/acp-23-2699-2023, 2023
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We evaluated six atmospheric transport models for their capability to simulate the CO2 plumes from two of the largest power plants in Europe by comparing the models against aircraft observations collected during the CoMet (Carbon Dioxide and Methane Mission) campaign in 2018. The study analyzed how realistically such plumes can be simulated at different model resolutions and how well the planned European satellite mission CO2M will be able to quantify emissions from power plants.
Manuel Schlund, Birgit Hassler, Axel Lauer, Bouwe Andela, Patrick Jöckel, Rémi Kazeroni, Saskia Loosveldt Tomas, Brian Medeiros, Valeriu Predoi, Stéphane Sénési, Jérôme Servonnat, Tobias Stacke, Javier Vegas-Regidor, Klaus Zimmermann, and Veronika Eyring
Geosci. Model Dev., 16, 315–333, https://doi.org/10.5194/gmd-16-315-2023, https://doi.org/10.5194/gmd-16-315-2023, 2023
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The Earth System Model Evaluation Tool (ESMValTool) is a community diagnostics and performance metrics tool for routine evaluation of Earth system models. Originally, ESMValTool was designed to process reformatted output provided by large model intercomparison projects like the Coupled Model Intercomparison Project (CMIP). Here, we describe a new extension of ESMValTool that allows for reading and processing native climate model output, i.e., data that have not been reformatted before.
Matthias Nützel, Sabine Brinkop, Martin Dameris, Hella Garny, Patrick Jöckel, Laura L. Pan, and Mijeong Park
Atmos. Chem. Phys., 22, 15659–15683, https://doi.org/10.5194/acp-22-15659-2022, https://doi.org/10.5194/acp-22-15659-2022, 2022
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During the Asian summer monsoon season, a large high-pressure system is present at levels close to the tropopause above Asia. We analyse how air masses are transported from surface levels to this high-pressure system, which shows distinct features from the surrounding air masses. To this end, we employ multiannual data from two complementary models that allow us to analyse the climatology as well as the interannual and intraseasonal variability of these transport pathways.
Johannes Pletzer, Didier Hauglustaine, Yann Cohen, Patrick Jöckel, and Volker Grewe
Atmos. Chem. Phys., 22, 14323–14354, https://doi.org/10.5194/acp-22-14323-2022, https://doi.org/10.5194/acp-22-14323-2022, 2022
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Very fast aircraft can travel long distances in extremely short times and can fly at high altitudes (15 to 35 km). These aircraft emit water vapour, nitrogen oxides, and hydrogen. Water vapour emissions remain for months to several years at these altitudes and have an important impact on temperature. We investigate two aircraft fleets flying at 26 and 35 km. Ozone is depleted more, and the water vapour perturbation and temperature change are larger for the aircraft flying at 35 km.
Jin Maruhashi, Volker Grewe, Christine Frömming, Patrick Jöckel, and Irene C. Dedoussi
Atmos. Chem. Phys., 22, 14253–14282, https://doi.org/10.5194/acp-22-14253-2022, https://doi.org/10.5194/acp-22-14253-2022, 2022
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Aviation NOx emissions lead to the formation of ozone in the atmosphere in the short term, which has a climate warming effect. This study uses global-scale simulations to characterize the transport patterns between NOx emissions at an altitude of ~ 10.4 km and the resulting ozone. Results show a strong spatial and temporal dependence of NOx in disturbing atmospheric O3 concentrations, with the location that is most impacted in terms of warming not necessarily coinciding with the emission region.
Kostas Eleftheratos, John Kapsomenakis, Ilias Fountoulakis, Christos S. Zerefos, Patrick Jöckel, Martin Dameris, Alkiviadis F. Bais, Germar Bernhard, Dimitra Kouklaki, Kleareti Tourpali, Scott Stierle, J. Ben Liley, Colette Brogniez, Frédérique Auriol, Henri Diémoz, Stana Simic, Irina Petropavlovskikh, Kaisa Lakkala, and Kostas Douvis
Atmos. Chem. Phys., 22, 12827–12855, https://doi.org/10.5194/acp-22-12827-2022, https://doi.org/10.5194/acp-22-12827-2022, 2022
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We present the future evolution of DNA-active ultraviolet (UV) radiation in view of increasing greenhouse gases (GHGs) and decreasing ozone depleting substances (ODSs). It is shown that DNA-active UV radiation might increase after 2050 between 50° N–50° S due to GHG-induced reductions in clouds and ozone, something that is likely not to happen at high latitudes, where DNA-active UV radiation will continue its downward trend mainly due to stratospheric ozone recovery from the reduction in ODSs.
Simon F. Reifenberg, Anna Martin, Matthias Kohl, Sara Bacer, Zaneta Hamryszczak, Ivan Tadic, Lenard Röder, Daniel J. Crowley, Horst Fischer, Katharina Kaiser, Johannes Schneider, Raphael Dörich, John N. Crowley, Laura Tomsche, Andreas Marsing, Christiane Voigt, Andreas Zahn, Christopher Pöhlker, Bruna A. Holanda, Ovid Krüger, Ulrich Pöschl, Mira Pöhlker, Patrick Jöckel, Marcel Dorf, Ulrich Schumann, Jonathan Williams, Birger Bohn, Joachim Curtius, Hardwig Harder, Hans Schlager, Jos Lelieveld, and Andrea Pozzer
Atmos. Chem. Phys., 22, 10901–10917, https://doi.org/10.5194/acp-22-10901-2022, https://doi.org/10.5194/acp-22-10901-2022, 2022
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In this work we use a combination of observational data from an aircraft campaign and model results to investigate the effect of the European lockdown due to COVID-19 in spring 2020. Using model results, we show that the largest relative changes to the atmospheric composition caused by the reduced emissions are located in the upper troposphere around aircraft cruise altitude, while the largest absolute changes are present at the surface.
Vanessa Simone Rieger and Volker Grewe
Geosci. Model Dev., 15, 5883–5903, https://doi.org/10.5194/gmd-15-5883-2022, https://doi.org/10.5194/gmd-15-5883-2022, 2022
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Road traffic emissions of nitrogen oxides, volatile organic compounds and carbon monoxide produce ozone in the troposphere and thus influence Earth's climate. To assess the ozone response to a broad range of mitigation strategies for road traffic, we developed a new chemistry–climate response model called TransClim. It is based on lookup tables containing climate–response relations and thus is able to quickly determine the climate response of a mitigation option.
Francisco J. Pérez-Invernón, Heidi Huntrieser, Thilo Erbertseder, Diego Loyola, Pieter Valks, Song Liu, Dale J. Allen, Kenneth E. Pickering, Eric J. Bucsela, Patrick Jöckel, Jos van Geffen, Henk Eskes, Sergio Soler, Francisco J. Gordillo-Vázquez, and Jeff Lapierre
Atmos. Meas. Tech., 15, 3329–3351, https://doi.org/10.5194/amt-15-3329-2022, https://doi.org/10.5194/amt-15-3329-2022, 2022
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Lightning, one of the major sources of nitrogen oxides in the atmosphere, contributes to the tropospheric concentration of ozone and to the oxidizing capacity of the atmosphere. In this work, we contribute to improving the estimation of lightning-produced nitrogen oxides in the Ebro Valley and the Pyrenees by using two different TROPOMI products and comparing the results.
M. Dolores Andrés Hernández, Andreas Hilboll, Helmut Ziereis, Eric Förster, Ovid O. Krüger, Katharina Kaiser, Johannes Schneider, Francesca Barnaba, Mihalis Vrekoussis, Jörg Schmidt, Heidi Huntrieser, Anne-Marlene Blechschmidt, Midhun George, Vladyslav Nenakhov, Theresa Harlass, Bruna A. Holanda, Jennifer Wolf, Lisa Eirenschmalz, Marc Krebsbach, Mira L. Pöhlker, Anna B. Kalisz Hedegaard, Linlu Mei, Klaus Pfeilsticker, Yangzhuoran Liu, Ralf Koppmann, Hans Schlager, Birger Bohn, Ulrich Schumann, Andreas Richter, Benjamin Schreiner, Daniel Sauer, Robert Baumann, Mariano Mertens, Patrick Jöckel, Markus Kilian, Greta Stratmann, Christopher Pöhlker, Monica Campanelli, Marco Pandolfi, Michael Sicard, José L. Gómez-Amo, Manuel Pujadas, Katja Bigge, Flora Kluge, Anja Schwarz, Nikos Daskalakis, David Walter, Andreas Zahn, Ulrich Pöschl, Harald Bönisch, Stephan Borrmann, Ulrich Platt, and John P. Burrows
Atmos. Chem. Phys., 22, 5877–5924, https://doi.org/10.5194/acp-22-5877-2022, https://doi.org/10.5194/acp-22-5877-2022, 2022
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EMeRGe provides a unique set of in situ and remote sensing airborne measurements of trace gases and aerosol particles along selected flight routes in the lower troposphere over Europe. The interpretation uses also complementary collocated ground-based and satellite measurements. The collected data help to improve the current understanding of the complex spatial distribution of trace gases and aerosol particles resulting from mixing, transport, and transformation of pollution plumes over Europe.
Andrea Pozzer, Simon F. Reifenberg, Vinod Kumar, Bruno Franco, Matthias Kohl, Domenico Taraborrelli, Sergey Gromov, Sebastian Ehrhart, Patrick Jöckel, Rolf Sander, Veronica Fall, Simon Rosanka, Vlassis Karydis, Dimitris Akritidis, Tamara Emmerichs, Monica Crippa, Diego Guizzardi, Johannes W. Kaiser, Lieven Clarisse, Astrid Kiendler-Scharr, Holger Tost, and Alexandra Tsimpidi
Geosci. Model Dev., 15, 2673–2710, https://doi.org/10.5194/gmd-15-2673-2022, https://doi.org/10.5194/gmd-15-2673-2022, 2022
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A newly developed setup of the chemistry general circulation model EMAC (ECHAM5/MESSy for Atmospheric Chemistry) is evaluated here. A comprehensive organic degradation mechanism is used and coupled with a volatility base model.
The results show that the model reproduces most of the tracers and aerosols satisfactorily but shows discrepancies for oxygenated organic gases. It is also shown that this model configuration can be used for further research in atmospheric chemistry.
Francisco J. Pérez-Invernón, Heidi Huntrieser, Patrick Jöckel, and Francisco J. Gordillo-Vázquez
Geosci. Model Dev., 15, 1545–1565, https://doi.org/10.5194/gmd-15-1545-2022, https://doi.org/10.5194/gmd-15-1545-2022, 2022
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This study reports the first parameterization of long-continuing-current lightning in a climate model. Long-continuing-current lightning is proposed to be the main precursor of lightning-ignited wildfires and sprites, a type of transient luminous event taking place in the mesosphere. This parameterization can significantly contribute to improving the implementation of wildfires in climate models.
Vinod Kumar, Julia Remmers, Steffen Beirle, Joachim Fallmann, Astrid Kerkweg, Jos Lelieveld, Mariano Mertens, Andrea Pozzer, Benedikt Steil, Marc Barra, Holger Tost, and Thomas Wagner
Atmos. Meas. Tech., 14, 5241–5269, https://doi.org/10.5194/amt-14-5241-2021, https://doi.org/10.5194/amt-14-5241-2021, 2021
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We present high-resolution regional atmospheric chemistry model simulations focused around Germany. We highlight the importance of spatial resolution of the model itself as well as the input emissions inventory and short-scale temporal variability of emissions for simulations. We propose a consistent approach for evaluating the simulated vertical distribution of NO2 using MAX-DOAS measurements while also considering its spatial sensitivity volume and change in sensitivity within this volume.
Christine Frömming, Volker Grewe, Sabine Brinkop, Patrick Jöckel, Amund S. Haslerud, Simon Rosanka, Jesper van Manen, and Sigrun Matthes
Atmos. Chem. Phys., 21, 9151–9172, https://doi.org/10.5194/acp-21-9151-2021, https://doi.org/10.5194/acp-21-9151-2021, 2021
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The influence of weather situations on non-CO2 aviation climate impact is investigated to identify systematic weather-related sensitivities. If aircraft avoid the most sensitive areas, climate impact might be reduced. Enhanced significance is found for emission in relation to high-pressure systems, jet stream, polar night, and tropopause altitude. The results represent a comprehensive data set for studies aiming at weather-dependent flight trajectory optimization to reduce total climate impact.
Chaim I. Garfinkel, Ohad Harari, Shlomi Ziskin Ziv, Jian Rao, Olaf Morgenstern, Guang Zeng, Simone Tilmes, Douglas Kinnison, Fiona M. O'Connor, Neal Butchart, Makoto Deushi, Patrick Jöckel, Andrea Pozzer, and Sean Davis
Atmos. Chem. Phys., 21, 3725–3740, https://doi.org/10.5194/acp-21-3725-2021, https://doi.org/10.5194/acp-21-3725-2021, 2021
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Water vapor is the dominant greenhouse gas in the atmosphere, and El Niño is the dominant mode of variability in the ocean–atmosphere system. The connection between El Niño and water vapor above ~ 17 km is unclear, with single-model studies reaching a range of conclusions. This study examines this connection in 12 different models. While there are substantial differences among the models, all models appear to capture the fundamental physical processes correctly.
Patrick E. Sheese, Kaley A. Walker, Chris D. Boone, Doug A. Degenstein, Felicia Kolonjari, David Plummer, Douglas E. Kinnison, Patrick Jöckel, and Thomas von Clarmann
Atmos. Meas. Tech., 14, 1425–1438, https://doi.org/10.5194/amt-14-1425-2021, https://doi.org/10.5194/amt-14-1425-2021, 2021
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Output from climate chemistry models (CMAM, EMAC, and WACCM) is used to estimate the expected geophysical variability of ozone concentrations between coincident satellite instrument measurement times and geolocations. We use the Canadian ACE-FTS and OSIRIS instruments as a case study. Ensemble mean estimates are used to optimize coincidence criteria between the two instruments, allowing for the use of more coincident profiles while providing an estimate of the geophysical variation.
Trang Van Pham, Christian Steger, Burkhardt Rockel, Klaus Keuler, Ingo Kirchner, Mariano Mertens, Daniel Rieger, Günther Zängl, and Barbara Früh
Geosci. Model Dev., 14, 985–1005, https://doi.org/10.5194/gmd-14-985-2021, https://doi.org/10.5194/gmd-14-985-2021, 2021
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A new regional climate model was prepared based on a weather forecast model. Slow processes of the climate system such as ocean state development and greenhouse gas emissions were implemented. A model infrastructure and evaluation tools were also prepared to facilitate long-term simulations and model evalution. The first ICON-CLM results were close to observations and comparable to those from COSMO-CLM, the recommended model being used at the Deutscher Wetterdienst and CLM Community.
Franziska Winterstein and Patrick Jöckel
Geosci. Model Dev., 14, 661–674, https://doi.org/10.5194/gmd-14-661-2021, https://doi.org/10.5194/gmd-14-661-2021, 2021
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Atmospheric methane is currently a hot topic in climate research. This is partly due to its chemically active nature. We introduce a simplified approach to simulate methane in climate models to enable large sensitivity studies by reducing computational cost but including the crucial feedback of methane on stratospheric water vapour. We further provide options to simulate the isotopic content of methane and to generate output for an inverse optimization technique for emission estimation.
Tamara Emmerichs, Astrid Kerkweg, Huug Ouwersloot, Silvano Fares, Ivan Mammarella, and Domenico Taraborrelli
Geosci. Model Dev., 14, 495–519, https://doi.org/10.5194/gmd-14-495-2021, https://doi.org/10.5194/gmd-14-495-2021, 2021
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Dry deposition to vegetation is a major sink of ground-level ozone. Its parameterization in atmospheric chemistry models represents a significant source of uncertainty for global tropospheric ozone. We extended the current model parameterization with a relevant pathway and important meteorological adjustment factors. The comparison with measurements shows that this enables a more realistic model representation of ozone dry deposition velocity. Globally, annual dry deposition loss increases.
Laura Stecher, Franziska Winterstein, Martin Dameris, Patrick Jöckel, Michael Ponater, and Markus Kunze
Atmos. Chem. Phys., 21, 731–754, https://doi.org/10.5194/acp-21-731-2021, https://doi.org/10.5194/acp-21-731-2021, 2021
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This study investigates the impact of strongly increased atmospheric methane mixing ratios on the Earth's climate. An interactive model system including atmospheric dynamics, chemistry, and a mixed-layer ocean model is used to analyse the effect of doubled and quintupled methane mixing ratios. We assess feedbacks on atmospheric chemistry and changes in the stratospheric circulation, focusing on the impact of tropospheric warming, and their relevance for the model's climate sensitivity.
Arseniy Karagodin-Doyennel, Eugene Rozanov, Ales Kuchar, William Ball, Pavle Arsenovic, Ellis Remsberg, Patrick Jöckel, Markus Kunze, David A. Plummer, Andrea Stenke, Daniel Marsh, Doug Kinnison, and Thomas Peter
Atmos. Chem. Phys., 21, 201–216, https://doi.org/10.5194/acp-21-201-2021, https://doi.org/10.5194/acp-21-201-2021, 2021
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The solar signal in the mesospheric H2O and CO was extracted from the CCMI-1 model simulations and satellite observations using multiple linear regression (MLR) analysis. MLR analysis shows a pronounced and statistically robust solar signal in both H2O and CO. The model results show a general agreement with observations reproducing a negative/positive solar signal in H2O/CO. The pattern of the solar signal varies among the considered models, reflecting some differences in the model setup.
Edward J. Charlesworth, Ann-Kristin Dugstad, Frauke Fritsch, Patrick Jöckel, and Felix Plöger
Atmos. Chem. Phys., 20, 15227–15245, https://doi.org/10.5194/acp-20-15227-2020, https://doi.org/10.5194/acp-20-15227-2020, 2020
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Modeling the stratosphere requires models with good representations of chemical transport. To do this, nearly all models divide the atmosphere into boxes. This creates some unwanted problems. However, the only other option is to divide the atmosphere into balloons, and this method is very complicated. Here, we use a model which uses this balloon-like method to estimate the impacts of this method on chemical transport. We find significant differences in sensitive regions of the stratosphere.
Yuanhong Zhao, Marielle Saunois, Philippe Bousquet, Xin Lin, Antoine Berchet, Michaela I. Hegglin, Josep G. Canadell, Robert B. Jackson, Makoto Deushi, Patrick Jöckel, Douglas Kinnison, Ole Kirner, Sarah Strode, Simone Tilmes, Edward J. Dlugokencky, and Bo Zheng
Atmos. Chem. Phys., 20, 13011–13022, https://doi.org/10.5194/acp-20-13011-2020, https://doi.org/10.5194/acp-20-13011-2020, 2020
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Decadal trends and variations in OH are critical for understanding atmospheric CH4 evolution. We quantify the impacts of OH trends and variations on the CH4 budget by conducting CH4 inversions on a decadal scale with an ensemble of OH fields. We find the negative OH anomalies due to enhanced fires can reduce the optimized CH4 emissions by up to 10 Tg yr−1 during El Niño years and the positive OH trend from 1986 to 2010 results in a ∼ 23 Tg yr−1 additional increase in optimized CH4 emissions.
Alina Fiehn, Julian Kostinek, Maximilian Eckl, Theresa Klausner, Michał Gałkowski, Jinxuan Chen, Christoph Gerbig, Thomas Röckmann, Hossein Maazallahi, Martina Schmidt, Piotr Korbeń, Jarosław Neçki, Pawel Jagoda, Norman Wildmann, Christian Mallaun, Rostyslav Bun, Anna-Leah Nickl, Patrick Jöckel, Andreas Fix, and Anke Roiger
Atmos. Chem. Phys., 20, 12675–12695, https://doi.org/10.5194/acp-20-12675-2020, https://doi.org/10.5194/acp-20-12675-2020, 2020
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A severe reduction of greenhouse gas emissions is necessary to fulfill the Paris Agreement. We use aircraft- and ground-based in situ observations of trace gases and wind speed from two flights over the Upper Silesian Coal Basin, Poland, for independent emission estimation. The derived methane emission estimates are within the range of emission inventories, carbon dioxide estimates are in the lower range and carbon monoxide emission estimates are slightly higher than emission inventory values.
Simon Rosanka, Christine Frömming, and Volker Grewe
Atmos. Chem. Phys., 20, 12347–12361, https://doi.org/10.5194/acp-20-12347-2020, https://doi.org/10.5194/acp-20-12347-2020, 2020
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Aviation-attributed nitrogen oxide (NOx) emissions lead to an increase in ozone and a depletion of methane. We investigate the impact of weather-related transport processes on these induced composition changes. Subsidence in high-pressure systems leads to earlier ozone maxima due to an enhanced chemical activity. Background NOx and hydroperoxyl radicals limit the total ozone change during summer and winter, respectively. High water vapour concentrations lead to a high methane depletion.
Markus Kilian, Sabine Brinkop, and Patrick Jöckel
Atmos. Chem. Phys., 20, 11697–11715, https://doi.org/10.5194/acp-20-11697-2020, https://doi.org/10.5194/acp-20-11697-2020, 2020
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After the volcanic eruption of Mt Pinatubo in 1991, ozone decreased in the tropics and increased in the midlatitudes and polar regions for 1 year. The change in the ozone column is solely a result of the volcanic heating, followed by an ozone decrease in the higher latitudes. This is caused by the volcanic aerosol, which changes the heterogeneous chemistry and thus the catalytic ozone loss cycles. Vertical transport of water vapour is enhanced by volcanic heating and increases methane.
Hiroshi Yamashita, Feijia Yin, Volker Grewe, Patrick Jöckel, Sigrun Matthes, Bastian Kern, Katrin Dahlmann, and Christine Frömming
Geosci. Model Dev., 13, 4869–4890, https://doi.org/10.5194/gmd-13-4869-2020, https://doi.org/10.5194/gmd-13-4869-2020, 2020
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This paper describes the updated submodel AirTraf 2.0 which simulates global air traffic in the ECHAM/MESSy Atmospheric Chemistry (EMAC) model. Nine aircraft routing options have been integrated, including contrail avoidance, minimum economic costs, and minimum climate impact. Example simulations reveal characteristics of different routing options on air traffic performances. The consistency of the AirTraf simulations is verified with literature data.
Matt Amos, Paul J. Young, J. Scott Hosking, Jean-François Lamarque, N. Luke Abraham, Hideharu Akiyoshi, Alexander T. Archibald, Slimane Bekki, Makoto Deushi, Patrick Jöckel, Douglas Kinnison, Ole Kirner, Markus Kunze, Marion Marchand, David A. Plummer, David Saint-Martin, Kengo Sudo, Simone Tilmes, and Yousuke Yamashita
Atmos. Chem. Phys., 20, 9961–9977, https://doi.org/10.5194/acp-20-9961-2020, https://doi.org/10.5194/acp-20-9961-2020, 2020
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We present an updated projection of Antarctic ozone hole recovery using an ensemble of chemistry–climate models. To do so, we employ a method, more advanced and skilful than the current multi-model mean standard, which is applicable to other ensemble analyses. It calculates the performance and similarity of the models, which we then use to weight the model. Calculating model similarity allows us to account for models which are constructed from similar components.
Daniele Visioni, Giovanni Pitari, Vincenzo Rizi, Marco Iarlori, Irene Cionni, Ilaria Quaglia, Hideharu Akiyoshi, Slimane Bekki, Neal Butchart, Martin Chipperfield, Makoto Deushi, Sandip S. Dhomse, Rolando Garcia, Patrick Joeckel, Douglas Kinnison, Jean-François Lamarque, Marion Marchand, Martine Michou, Olaf Morgenstern, Tatsuya Nagashima, Fiona M. O'Connor, Luke D. Oman, David Plummer, Eugene Rozanov, David Saint-Martin, Robyn Schofield, John Scinocca, Andrea Stenke, Kane Stone, Kengo Sudo, Taichu Y. Tanaka, Simone Tilmes, Holger Tost, Yousuke Yamashita, and Guang Zeng
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2020-525, https://doi.org/10.5194/acp-2020-525, 2020
Preprint withdrawn
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In this work we analyse the trend in ozone profiles taken at L'Aquila (Italy, 42.4° N) for seventeen years, between 2000 and 2016 and compare them against already available measured ozone trends. We try to understand and explain the observed trends at various heights in light of the simulations from seventeen different model, highlighting the contribution of changes in circulation and chemical ozone loss during this time period.
Marta Abalos, Clara Orbe, Douglas E. Kinnison, David Plummer, Luke D. Oman, Patrick Jöckel, Olaf Morgenstern, Rolando R. Garcia, Guang Zeng, Kane A. Stone, and Martin Dameris
Atmos. Chem. Phys., 20, 6883–6901, https://doi.org/10.5194/acp-20-6883-2020, https://doi.org/10.5194/acp-20-6883-2020, 2020
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A set of state-of-the art chemistry–climate models is used to examine future changes in downward transport from the stratosphere, a key contributor to tropospheric ozone. The acceleration of the stratospheric circulation results in increased stratosphere-to-troposphere transport. In the subtropics, downward advection into the troposphere is enhanced due to climate change. At higher latitudes, the ozone reservoir above the tropopause is enlarged due to the stronger circulation and ozone recovery.
Peter H. Zimmermann, Carl A. M. Brenninkmeijer, Andrea Pozzer, Patrick Jöckel, Franziska Winterstein, Andreas Zahn, Sander Houweling, and Jos Lelieveld
Atmos. Chem. Phys., 20, 5787–5809, https://doi.org/10.5194/acp-20-5787-2020, https://doi.org/10.5194/acp-20-5787-2020, 2020
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The atmospheric abundance of the greenhouse gas methane is determined by interacting emission sources and sinks in a dynamic global environment. In this study, its global budget from 1997 to 2016 is simulated with a general circulation model using emission estimates of 11 source categories. The model results are evaluated against 17 ground station and 320 intercontinental flight observation series. Deviations are used to re-scale the emission quantities with the aim of matching observations.
Anna-Leah Nickl, Mariano Mertens, Anke Roiger, Andreas Fix, Axel Amediek, Alina Fiehn, Christoph Gerbig, Michal Galkowski, Astrid Kerkweg, Theresa Klausner, Maximilian Eckl, and Patrick Jöckel
Geosci. Model Dev., 13, 1925–1943, https://doi.org/10.5194/gmd-13-1925-2020, https://doi.org/10.5194/gmd-13-1925-2020, 2020
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Based on the global and regional chemistry–climate model system MECO(n), we implemented a forecast system to support the planning of measurement campaign research flights with chemical weather forecasts. We applied this system for the first time to provide 6 d forecasts in support of the CoMet 1.0
campaign targeting methane emitted from coal mining ventilation shafts in the Upper Silesian Coal Basin in Poland. We describe the new forecast system and evaluate its forecast skill.
Timo Keber, Harald Bönisch, Carl Hartick, Marius Hauck, Fides Lefrancois, Florian Obersteiner, Akima Ringsdorf, Nils Schohl, Tanja Schuck, Ryan Hossaini, Phoebe Graf, Patrick Jöckel, and Andreas Engel
Atmos. Chem. Phys., 20, 4105–4132, https://doi.org/10.5194/acp-20-4105-2020, https://doi.org/10.5194/acp-20-4105-2020, 2020
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In this paper we summarize observations of short-lived halocarbons in the tropopause region. We show that, especially during winter, the levels of short-lived bromine gases at the extratropical tropopause are higher than at the tropical tropopause. We discuss the impact of the distributions on stratospheric bromine levels and compare our observations to two models with four different emission scenarios.
Clara Orbe, David A. Plummer, Darryn W. Waugh, Huang Yang, Patrick Jöckel, Douglas E. Kinnison, Beatrice Josse, Virginie Marecal, Makoto Deushi, Nathan Luke Abraham, Alexander T. Archibald, Martyn P. Chipperfield, Sandip Dhomse, Wuhu Feng, and Slimane Bekki
Atmos. Chem. Phys., 20, 3809–3840, https://doi.org/10.5194/acp-20-3809-2020, https://doi.org/10.5194/acp-20-3809-2020, 2020
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Atmospheric composition is strongly influenced by global-scale winds that are not always properly simulated in computer models. A common approach to correct for this bias is to relax or
nudgeto the observed winds. Here we systematically evaluate how well this technique performs across a large suite of chemistry–climate models in terms of its ability to reproduce key aspects of both the tropospheric and stratospheric circulations.
Julie M. Nicely, Bryan N. Duncan, Thomas F. Hanisco, Glenn M. Wolfe, Ross J. Salawitch, Makoto Deushi, Amund S. Haslerud, Patrick Jöckel, Béatrice Josse, Douglas E. Kinnison, Andrew Klekociuk, Michael E. Manyin, Virginie Marécal, Olaf Morgenstern, Lee T. Murray, Gunnar Myhre, Luke D. Oman, Giovanni Pitari, Andrea Pozzer, Ilaria Quaglia, Laura E. Revell, Eugene Rozanov, Andrea Stenke, Kane Stone, Susan Strahan, Simone Tilmes, Holger Tost, Daniel M. Westervelt, and Guang Zeng
Atmos. Chem. Phys., 20, 1341–1361, https://doi.org/10.5194/acp-20-1341-2020, https://doi.org/10.5194/acp-20-1341-2020, 2020
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Differences in methane lifetime among global models are large and poorly understood. We use a neural network method and simulations from the Chemistry Climate Model Initiative to quantify the factors influencing methane lifetime spread among models and variations over time. UV photolysis, tropospheric ozone, and nitrogen oxides drive large model differences, while the same factors plus specific humidity contribute to a decreasing trend in methane lifetime between 1980 and 2015.
Mariano Mertens, Astrid Kerkweg, Volker Grewe, Patrick Jöckel, and Robert Sausen
Geosci. Model Dev., 13, 363–383, https://doi.org/10.5194/gmd-13-363-2020, https://doi.org/10.5194/gmd-13-363-2020, 2020
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This study investigates if ozone source apportionment results using a tagged tracer approach depend on the resolutions of the applied model and/or emission inventory. For this we apply a global to regional atmospheric chemistry model, which allows us to compare the results on global and regional scales. Our results show that differences on the continental scale (e.g. Europe) are rather small (10 %); on the regional scale, however, differences of up to 30 % were found.
Le Kuai, Kevin W. Bowman, Kazuyuki Miyazaki, Makoto Deushi, Laura Revell, Eugene Rozanov, Fabien Paulot, Sarah Strode, Andrew Conley, Jean-François Lamarque, Patrick Jöckel, David A. Plummer, Luke D. Oman, Helen Worden, Susan Kulawik, David Paynter, Andrea Stenke, and Markus Kunze
Atmos. Chem. Phys., 20, 281–301, https://doi.org/10.5194/acp-20-281-2020, https://doi.org/10.5194/acp-20-281-2020, 2020
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The tropospheric ozone increase from pre-industrial to the present day leads to a radiative forcing. The top-of-atmosphere outgoing fluxes at the ozone band are controlled by ozone, water vapor, and temperature. We demonstrate a method to attribute the models’ flux biases to these key players using satellite-constrained instantaneous radiative kernels. The largest spread between models is found in the tropics, mainly driven by ozone and then water vapor.
Martin Dameris, Patrick Jöckel, and Matthias Nützel
Atmos. Chem. Phys., 19, 13759–13771, https://doi.org/10.5194/acp-19-13759-2019, https://doi.org/10.5194/acp-19-13759-2019, 2019
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A chemistry–climate model (CCM) study is performed, investigating the consequences of a constant CFC-11 surface mixing ratio for stratospheric ozone in the future. The total column ozone is particularly affected in both polar regions in winter and spring. It turns out that the calculated ozone changes, especially in the upper stratosphere, are smaller than expected. In this attitudinal region the additional ozone depletion due to the catalysis by reactive chlorine is partly compensated for.
Yuanhong Zhao, Marielle Saunois, Philippe Bousquet, Xin Lin, Antoine Berchet, Michaela I. Hegglin, Josep G. Canadell, Robert B. Jackson, Didier A. Hauglustaine, Sophie Szopa, Ann R. Stavert, Nathan Luke Abraham, Alex T. Archibald, Slimane Bekki, Makoto Deushi, Patrick Jöckel, Béatrice Josse, Douglas Kinnison, Ole Kirner, Virginie Marécal, Fiona M. O'Connor, David A. Plummer, Laura E. Revell, Eugene Rozanov, Andrea Stenke, Sarah Strode, Simone Tilmes, Edward J. Dlugokencky, and Bo Zheng
Atmos. Chem. Phys., 19, 13701–13723, https://doi.org/10.5194/acp-19-13701-2019, https://doi.org/10.5194/acp-19-13701-2019, 2019
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The role of hydroxyl radical changes in methane trends is debated, hindering our understanding of the methane cycle. This study quantifies how uncertainties in the hydroxyl radical may influence methane abundance in the atmosphere based on the inter-model comparison of hydroxyl radical fields and model simulations of CH4 abundance with different hydroxyl radical scenarios during 2000–2016. We show that hydroxyl radical changes could contribute up to 54 % of model-simulated methane biases.
Andreas Luther, Ralph Kleinschek, Leon Scheidweiler, Sara Defratyka, Mila Stanisavljevic, Andreas Forstmaier, Alexandru Dandocsi, Sebastian Wolff, Darko Dubravica, Norman Wildmann, Julian Kostinek, Patrick Jöckel, Anna-Leah Nickl, Theresa Klausner, Frank Hase, Matthias Frey, Jia Chen, Florian Dietrich, Jarosław Nȩcki, Justyna Swolkień, Andreas Fix, Anke Roiger, and André Butz
Atmos. Meas. Tech., 12, 5217–5230, https://doi.org/10.5194/amt-12-5217-2019, https://doi.org/10.5194/amt-12-5217-2019, 2019
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Methane ventilated from hard coal mines in the Upper Silesian
Coal Basin in Poland is measured with a mobile Fourier transform spectrometer EM27/SUN. The instrument was mounted on a truck driving in stop-and-go patterns downwind of the methane sources. The emissions are estimated with the cross-sectional flux method. Calculated emissions are in broad agreement with the E-PRTR database. Wind-related errors on the methane estimates dominate the error budget and typically amount to 20 %.
Andreas Chrysanthou, Amanda C. Maycock, Martyn P. Chipperfield, Sandip Dhomse, Hella Garny, Douglas Kinnison, Hideharu Akiyoshi, Makoto Deushi, Rolando R. Garcia, Patrick Jöckel, Oliver Kirner, Giovanni Pitari, David A. Plummer, Laura Revell, Eugene Rozanov, Andrea Stenke, Taichu Y. Tanaka, Daniele Visioni, and Yousuke Yamashita
Atmos. Chem. Phys., 19, 11559–11586, https://doi.org/10.5194/acp-19-11559-2019, https://doi.org/10.5194/acp-19-11559-2019, 2019
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We perform the first multi-model comparison of the impact of nudged meteorology on the stratospheric residual circulation (RC) in chemistry–climate models. Nudging meteorology does not constrain the mean strength of RC compared to free-running simulations, and despite the lack of agreement in the mean circulation, nudging tightly constrains the inter-annual variability in the tropical upward mass flux in the lower stratosphere. In summary, nudging strongly affects the representation of RC.
Kévin Lamy, Thierry Portafaix, Béatrice Josse, Colette Brogniez, Sophie Godin-Beekmann, Hassan Bencherif, Laura Revell, Hideharu Akiyoshi, Slimane Bekki, Michaela I. Hegglin, Patrick Jöckel, Oliver Kirner, Ben Liley, Virginie Marecal, Olaf Morgenstern, Andrea Stenke, Guang Zeng, N. Luke Abraham, Alexander T. Archibald, Neil Butchart, Martyn P. Chipperfield, Glauco Di Genova, Makoto Deushi, Sandip S. Dhomse, Rong-Ming Hu, Douglas Kinnison, Michael Kotkamp, Richard McKenzie, Martine Michou, Fiona M. O'Connor, Luke D. Oman, Giovanni Pitari, David A. Plummer, John A. Pyle, Eugene Rozanov, David Saint-Martin, Kengo Sudo, Taichu Y. Tanaka, Daniele Visioni, and Kohei Yoshida
Atmos. Chem. Phys., 19, 10087–10110, https://doi.org/10.5194/acp-19-10087-2019, https://doi.org/10.5194/acp-19-10087-2019, 2019
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In this study, we simulate the ultraviolet radiation evolution during the 21st century on Earth's surface using the output from several numerical models which participated in the Chemistry-Climate Model Initiative. We present four possible futures which depend on greenhouse gases emissions. The role of ozone-depleting substances, greenhouse gases and aerosols are investigated. Our results emphasize the important role of aerosols for future ultraviolet radiation in the Northern Hemisphere.
Ohad Harari, Chaim I. Garfinkel, Shlomi Ziskin Ziv, Olaf Morgenstern, Guang Zeng, Simone Tilmes, Douglas Kinnison, Makoto Deushi, Patrick Jöckel, Andrea Pozzer, Fiona M. O'Connor, and Sean Davis
Atmos. Chem. Phys., 19, 9253–9268, https://doi.org/10.5194/acp-19-9253-2019, https://doi.org/10.5194/acp-19-9253-2019, 2019
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Ozone depletion in the Antarctic has been shown to influence surface conditions, but the effects of ozone depletion in the Arctic on surface climate are unclear. We show that Arctic ozone does influence surface climate in both polar regions and tropical regions, though the proximate cause of these surface impacts is not yet clear.
Petr Šácha, Roland Eichinger, Hella Garny, Petr Pišoft, Simone Dietmüller, Laura de la Torre, David A. Plummer, Patrick Jöckel, Olaf Morgenstern, Guang Zeng, Neal Butchart, and Juan A. Añel
Atmos. Chem. Phys., 19, 7627–7647, https://doi.org/10.5194/acp-19-7627-2019, https://doi.org/10.5194/acp-19-7627-2019, 2019
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Climate models robustly project a Brewer–Dobson circulation (BDC) acceleration in the course of climate change. Analyzing mean age of stratospheric air (AoA) from a subset of climate projection simulations, we find a remarkable agreement in simulating the largest AoA trends in the extratropical stratosphere. This is shown to be related with the upward shift of the circulation, resulting in a so-called stratospheric shrinkage, which could be one of the so-far-omitted BDC acceleration drivers.
Franziska Winterstein, Fabian Tanalski, Patrick Jöckel, Martin Dameris, and Michael Ponater
Atmos. Chem. Phys., 19, 7151–7163, https://doi.org/10.5194/acp-19-7151-2019, https://doi.org/10.5194/acp-19-7151-2019, 2019
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The atmospheric concentrations of the anthropogenic greenhouse gas methane are predicted to rise in the future. In this paper we investigate how very strong methane concentrations will impact the atmosphere. We analyse two experiments, one with doubled and one with quintupled methane concentrations and focus on the rapid atmospheric changes before the ocean adjusts to the induced
forcing. In particular these are changes in temperature, ozone, the hydroxyl radical and stratospheric water vapour.
Sabine Brinkop and Patrick Jöckel
Geosci. Model Dev., 12, 1991–2008, https://doi.org/10.5194/gmd-12-1991-2019, https://doi.org/10.5194/gmd-12-1991-2019, 2019
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We have extended ATTILA (Atmospheric Tracer Transport in a LAgrangian model), a Lagrangian tracer transport scheme which is online coupled to the global ECHAM/MESSy Atmospheric Chemistry (EMAC) model, with a combination of newly developed and modified physical routines and new diagnostic and infrastructure submodels. The results show an improvement of the tracer transport into and within the stratosphere due to the newly implemented diabatic vertical velocity.
Huang Yang, Darryn W. Waugh, Clara Orbe, Guang Zeng, Olaf Morgenstern, Douglas E. Kinnison, Jean-Francois Lamarque, Simone Tilmes, David A. Plummer, Patrick Jöckel, Susan E. Strahan, Kane A. Stone, and Robyn Schofield
Atmos. Chem. Phys., 19, 5511–5528, https://doi.org/10.5194/acp-19-5511-2019, https://doi.org/10.5194/acp-19-5511-2019, 2019
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We evaluate the performance of a suite of models in simulating the large-scale transport from the northern midlatitudes to the Arctic using a CO-like idealized tracer. We find a large multi-model spread of the Arctic concentration of this CO-like tracer that is well correlated with the differences in the location of the midlatitude jet as well as the northern Hadley Cell edge. Our results suggest the Hadley Cell is key and zonal-mean transport by surface meridional flow needs better constraint.
Rolf Sander, Andreas Baumgaertner, David Cabrera-Perez, Franziska Frank, Sergey Gromov, Jens-Uwe Grooß, Hartwig Harder, Vincent Huijnen, Patrick Jöckel, Vlassis A. Karydis, Kyle E. Niemeyer, Andrea Pozzer, Hella Riede, Martin G. Schultz, Domenico Taraborrelli, and Sebastian Tauer
Geosci. Model Dev., 12, 1365–1385, https://doi.org/10.5194/gmd-12-1365-2019, https://doi.org/10.5194/gmd-12-1365-2019, 2019
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We present the atmospheric chemistry box model CAABA/MECCA which
now includes a number of new features: skeletal mechanism
reduction, the MOM chemical mechanism for volatile organic
compounds, an option to include reactions from the Master
Chemical Mechanism (MCM) and other chemical mechanisms, updated
isotope tagging, improved and new photolysis modules, and the new
feature of coexisting multiple chemistry mechanisms.
CAABA/MECCA is a community model published under the GPL.
Ryan S. Williams, Michaela I. Hegglin, Brian J. Kerridge, Patrick Jöckel, Barry G. Latter, and David A. Plummer
Atmos. Chem. Phys., 19, 3589–3620, https://doi.org/10.5194/acp-19-3589-2019, https://doi.org/10.5194/acp-19-3589-2019, 2019
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Tropospheric ozone has important implications for air quality and climate change but is poorly understood at a regional and seasonal level. Analysis of model simulations indicates that downward transport of ozone from the stratosphere has a larger influence than previously thought (as much as ~50 % even near the surface). Recent estimated changes in tropospheric ozone (1980–89 to 2001–10) are generally positive, with substantial attribution from the stratosphere identified over some regions.
J. Christopher Kaiser, Johannes Hendricks, Mattia Righi, Patrick Jöckel, Holger Tost, Konrad Kandler, Bernadett Weinzierl, Daniel Sauer, Katharina Heimerl, Joshua P. Schwarz, Anne E. Perring, and Thomas Popp
Geosci. Model Dev., 12, 541–579, https://doi.org/10.5194/gmd-12-541-2019, https://doi.org/10.5194/gmd-12-541-2019, 2019
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The implementation of the aerosol microphysics submodel MADE3 into the global atmospheric chemistry model EMAC is described and evaluated against an extensive pool of observational data, focusing on aerosol mass and number concentrations, size distributions, composition, and optical properties. EMAC (MADE3) is able to reproduce main aerosol properties reasonably well, in line with the performance of other global aerosol models.
Roland Eichinger, Simone Dietmüller, Hella Garny, Petr Šácha, Thomas Birner, Harald Bönisch, Giovanni Pitari, Daniele Visioni, Andrea Stenke, Eugene Rozanov, Laura Revell, David A. Plummer, Patrick Jöckel, Luke Oman, Makoto Deushi, Douglas E. Kinnison, Rolando Garcia, Olaf Morgenstern, Guang Zeng, Kane Adam Stone, and Robyn Schofield
Atmos. Chem. Phys., 19, 921–940, https://doi.org/10.5194/acp-19-921-2019, https://doi.org/10.5194/acp-19-921-2019, 2019
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To shed more light upon the changes in stratospheric circulation in the 21st century, climate projection simulations of 10 state-of-the-art global climate models, spanning from 1960 to 2100, are analyzed. The study shows that in addition to changes in transport, mixing also plays an important role in stratospheric circulation and that the properties of mixing vary over time. Furthermore, the influence of mixing is quantified and a dynamical framework is provided to understand the changes.
Laura E. Revell, Andrea Stenke, Fiona Tummon, Aryeh Feinberg, Eugene Rozanov, Thomas Peter, N. Luke Abraham, Hideharu Akiyoshi, Alexander T. Archibald, Neal Butchart, Makoto Deushi, Patrick Jöckel, Douglas Kinnison, Martine Michou, Olaf Morgenstern, Fiona M. O'Connor, Luke D. Oman, Giovanni Pitari, David A. Plummer, Robyn Schofield, Kane Stone, Simone Tilmes, Daniele Visioni, Yousuke Yamashita, and Guang Zeng
Atmos. Chem. Phys., 18, 16155–16172, https://doi.org/10.5194/acp-18-16155-2018, https://doi.org/10.5194/acp-18-16155-2018, 2018
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Global models such as those participating in the Chemistry-Climate Model Initiative (CCMI) consistently simulate biases in tropospheric ozone compared with observations. We performed an advanced statistical analysis with one of the CCMI models to understand the cause of the bias. We found that emissions of ozone precursor gases are the dominant driver of the bias, implying either that the emissions are too large, or that the way in which the model handles emissions needs to be improved.
Amanda C. Maycock, Katja Matthes, Susann Tegtmeier, Hauke Schmidt, Rémi Thiéblemont, Lon Hood, Hideharu Akiyoshi, Slimane Bekki, Makoto Deushi, Patrick Jöckel, Oliver Kirner, Markus Kunze, Marion Marchand, Daniel R. Marsh, Martine Michou, David Plummer, Laura E. Revell, Eugene Rozanov, Andrea Stenke, Yousuke Yamashita, and Kohei Yoshida
Atmos. Chem. Phys., 18, 11323–11343, https://doi.org/10.5194/acp-18-11323-2018, https://doi.org/10.5194/acp-18-11323-2018, 2018
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The 11-year solar cycle is an important driver of climate variability. Changes in incoming solar ultraviolet radiation affect atmospheric ozone, which in turn influences atmospheric temperatures. Constraining the impact of the solar cycle on ozone is therefore important for understanding climate variability. This study examines the representation of the solar influence on ozone in numerical models used to simulate past and future climate. We highlight important differences among model datasets.
Blanca Ayarzagüena, Lorenzo M. Polvani, Ulrike Langematz, Hideharu Akiyoshi, Slimane Bekki, Neal Butchart, Martin Dameris, Makoto Deushi, Steven C. Hardiman, Patrick Jöckel, Andrew Klekociuk, Marion Marchand, Martine Michou, Olaf Morgenstern, Fiona M. O'Connor, Luke D. Oman, David A. Plummer, Laura Revell, Eugene Rozanov, David Saint-Martin, John Scinocca, Andrea Stenke, Kane Stone, Yousuke Yamashita, Kohei Yoshida, and Guang Zeng
Atmos. Chem. Phys., 18, 11277–11287, https://doi.org/10.5194/acp-18-11277-2018, https://doi.org/10.5194/acp-18-11277-2018, 2018
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Stratospheric sudden warmings (SSWs) are natural major disruptions of the polar stratospheric circulation that also affect surface weather. In the literature there are conflicting claims as to whether SSWs will change in the future. The confusion comes from studies using different models and methods. Here we settle the question by analysing 12 models with a consistent methodology, to show that no robust changes in frequency and other features are expected over the 21st century.
Franziska Frank, Patrick Jöckel, Sergey Gromov, and Martin Dameris
Atmos. Chem. Phys., 18, 9955–9973, https://doi.org/10.5194/acp-18-9955-2018, https://doi.org/10.5194/acp-18-9955-2018, 2018
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It is frequently assumed that one methane molecule produces two water molecules. Applying various modeling concepts, we find that the yield of water from methane is vertically not constantly 2. In the upper stratosphere and lower mesosphere, transport of intermediate H2 molecules even led to a yield greater than 2. We conclude that for a realistic chemical source of stratospheric water vapor, one must also take other sources (H2), intermediates and the chemical removal of water into account.
Sergey Gromov, Carl A. M. Brenninkmeijer, and Patrick Jöckel
Atmos. Chem. Phys., 18, 9831–9843, https://doi.org/10.5194/acp-18-9831-2018, https://doi.org/10.5194/acp-18-9831-2018, 2018
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Using the observational data on 13C (CO) and 13C (CH4) from the extra-tropical Southern Hemisphere (ETSH) and EMAC model we (1) provide an independent, observation-based evaluation of Cl atom concentration variations in the ETSH throughout 1994–2000, (2) show that the role of tropospheric Cl as a sink of CH4 is seriously overestimated in the literature, (3) demonstrate that the 13C/12C ratio of CO is a sensitive indicator for the isotopic composition of reacted CH4 and therefore for its sources.
Sandip S. Dhomse, Douglas Kinnison, Martyn P. Chipperfield, Ross J. Salawitch, Irene Cionni, Michaela I. Hegglin, N. Luke Abraham, Hideharu Akiyoshi, Alex T. Archibald, Ewa M. Bednarz, Slimane Bekki, Peter Braesicke, Neal Butchart, Martin Dameris, Makoto Deushi, Stacey Frith, Steven C. Hardiman, Birgit Hassler, Larry W. Horowitz, Rong-Ming Hu, Patrick Jöckel, Beatrice Josse, Oliver Kirner, Stefanie Kremser, Ulrike Langematz, Jared Lewis, Marion Marchand, Meiyun Lin, Eva Mancini, Virginie Marécal, Martine Michou, Olaf Morgenstern, Fiona M. O'Connor, Luke Oman, Giovanni Pitari, David A. Plummer, John A. Pyle, Laura E. Revell, Eugene Rozanov, Robyn Schofield, Andrea Stenke, Kane Stone, Kengo Sudo, Simone Tilmes, Daniele Visioni, Yousuke Yamashita, and Guang Zeng
Atmos. Chem. Phys., 18, 8409–8438, https://doi.org/10.5194/acp-18-8409-2018, https://doi.org/10.5194/acp-18-8409-2018, 2018
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We analyse simulations from the Chemistry-Climate Model Initiative (CCMI) to estimate the return dates of the stratospheric ozone layer from depletion by anthropogenic chlorine and bromine. The simulations from 20 models project that global column ozone will return to 1980 values in 2047 (uncertainty range 2042–2052). Return dates in other regions vary depending on factors related to climate change and importance of chlorine and bromine. Column ozone in the tropics may continue to decline.
Stefan Lossow, Dale F. Hurst, Karen H. Rosenlof, Gabriele P. Stiller, Thomas von Clarmann, Sabine Brinkop, Martin Dameris, Patrick Jöckel, Doug E. Kinnison, Johannes Plieninger, David A. Plummer, Felix Ploeger, William G. Read, Ellis E. Remsberg, James M. Russell, and Mengchu Tao
Atmos. Chem. Phys., 18, 8331–8351, https://doi.org/10.5194/acp-18-8331-2018, https://doi.org/10.5194/acp-18-8331-2018, 2018
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Trend estimates of lower stratospheric H2O derived from the FPH observations at Boulder and a merged zonal mean satellite data set clearly differ for the time period from the late 1980s to 2010. We investigate if a sampling bias between Boulder and the zonal mean around the Boulder latitude can explain these trend discrepancies. Typically they are small and not sufficient to explain the trend discrepancies in the observational database.
Vanessa S. Rieger, Mariano Mertens, and Volker Grewe
Geosci. Model Dev., 11, 2049–2066, https://doi.org/10.5194/gmd-11-2049-2018, https://doi.org/10.5194/gmd-11-2049-2018, 2018
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To reduce the climate impact of human activities, it is crucial to attribute changes in atmospheric gases to anthropogenic emissions. We present an advanced method to determine the contribution of emissions to OH and HO2 concentrations. Compared to the former version, it contains the main reactions of the OH and HO2 chemistry in the troposphere and stratosphere, introduces the tagging of the H radical and closes the budget of the sum of all contributions and the total concentration.
Stefanie Meul, Ulrike Langematz, Philipp Kröger, Sophie Oberländer-Hayn, and Patrick Jöckel
Atmos. Chem. Phys., 18, 7721–7738, https://doi.org/10.5194/acp-18-7721-2018, https://doi.org/10.5194/acp-18-7721-2018, 2018
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Using a chemistry--climate model future changes in the stratosphere-to-troposphere ozone mass flux, their drivers, and the future distribution of stratospheric ozone in the troposphere are investigated. In an extreme greenhouse gas (GHG) scenario, the global influx of stratospheric ozone into the troposphere is projected to grow between 2000 and 2100 by 53%. The increase is due to the recovery of stratospheric ozone owing to declining halogens and GHG induced circulation and temperature changes.
Clara Orbe, Huang Yang, Darryn W. Waugh, Guang Zeng, Olaf Morgenstern, Douglas E. Kinnison, Jean-Francois Lamarque, Simone Tilmes, David A. Plummer, John F. Scinocca, Beatrice Josse, Virginie Marecal, Patrick Jöckel, Luke D. Oman, Susan E. Strahan, Makoto Deushi, Taichu Y. Tanaka, Kohei Yoshida, Hideharu Akiyoshi, Yousuke Yamashita, Andreas Stenke, Laura Revell, Timofei Sukhodolov, Eugene Rozanov, Giovanni Pitari, Daniele Visioni, Kane A. Stone, Robyn Schofield, and Antara Banerjee
Atmos. Chem. Phys., 18, 7217–7235, https://doi.org/10.5194/acp-18-7217-2018, https://doi.org/10.5194/acp-18-7217-2018, 2018
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In this study we compare a few atmospheric transport properties among several numerical models that are used to study the influence of atmospheric chemistry on climate. We show that there are large differences among models in terms of the timescales that connect the Northern Hemisphere midlatitudes, where greenhouse gases and ozone-depleting substances are emitted, to the Southern Hemisphere. Our results may have important implications for how models represent atmospheric composition.
Simone Dietmüller, Roland Eichinger, Hella Garny, Thomas Birner, Harald Boenisch, Giovanni Pitari, Eva Mancini, Daniele Visioni, Andrea Stenke, Laura Revell, Eugene Rozanov, David A. Plummer, John Scinocca, Patrick Jöckel, Luke Oman, Makoto Deushi, Shibata Kiyotaka, Douglas E. Kinnison, Rolando Garcia, Olaf Morgenstern, Guang Zeng, Kane Adam Stone, and Robyn Schofield
Atmos. Chem. Phys., 18, 6699–6720, https://doi.org/10.5194/acp-18-6699-2018, https://doi.org/10.5194/acp-18-6699-2018, 2018
Klaus-Dirk Gottschaldt, Hans Schlager, Robert Baumann, Duy Sinh Cai, Veronika Eyring, Phoebe Graf, Volker Grewe, Patrick Jöckel, Tina Jurkat-Witschas, Christiane Voigt, Andreas Zahn, and Helmut Ziereis
Atmos. Chem. Phys., 18, 5655–5675, https://doi.org/10.5194/acp-18-5655-2018, https://doi.org/10.5194/acp-18-5655-2018, 2018
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This study places aircraft trace gas measurements from within the Asian summer monsoon anticyclone into the context of regional, intra- and interannual variability. We find that the processes reflected in the measurements are present throughout multiple simulated monsoon seasons. Dynamical instabilities, photochemical ozone production, lightning and entrainments from the lower troposphere and from the tropopause region determine the distinct composition of the anticyclone and its outflow.
Mariano Mertens, Volker Grewe, Vanessa S. Rieger, and Patrick Jöckel
Atmos. Chem. Phys., 18, 5567–5588, https://doi.org/10.5194/acp-18-5567-2018, https://doi.org/10.5194/acp-18-5567-2018, 2018
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We quantified the contribution of land transport and shipping emissions to tropospheric ozone using a global chemistry–climate model. Our results indicate a contribution to ground-level ozone from land transport emissions of up to 18 % in North America and Southern Europe as well as a contribution from shipping emissions of up to 30 % in the Pacific. Our estimates of the radiative ozone forcing due to land transport and shipping emissions are 92 mW m−2 and 62 mW m−2, respectively.
Astrid Kerkweg, Christiane Hofmann, Patrick Jöckel, Mariano Mertens, and Gregor Pante
Geosci. Model Dev., 11, 1059–1076, https://doi.org/10.5194/gmd-11-1059-2018, https://doi.org/10.5194/gmd-11-1059-2018, 2018
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As part of the model documentation of the MECO(n) system, this article documents the basics of the Multi-Model-Driver expansion (MMD v2.0) to two-way coupling and the newly developed generic MESSy submodel GRID (v1.0), which is used by MMD v2.0 for the generalised definition of arbitrary grids and for the
transformation of data between them.
Klaus Gierens, Kostas Eleftheratos, and Robert Sausen
Atmos. Meas. Tech., 11, 939–948, https://doi.org/10.5194/amt-11-939-2018, https://doi.org/10.5194/amt-11-939-2018, 2018
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HIRS channel 12 on the series of NOAA weathersatellites is sensitive to humidity in the upper troposphere. A change in its central wavelength between NOAA 14 and 15 made it necessary to perform an intercalibration to retain a homogeneous time series. Here we show that the intercalibration of Shi and Bates (2011), which is based on statistical methods, can be underpinned by physical arguments using results of radiative transfer calculations.
Andreas Engel, Harald Bönisch, Jennifer Ostermöller, Martyn P. Chipperfield, Sandip Dhomse, and Patrick Jöckel
Atmos. Chem. Phys., 18, 601–619, https://doi.org/10.5194/acp-18-601-2018, https://doi.org/10.5194/acp-18-601-2018, 2018
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We present a new method to derive equivalent effective stratospheric chlorine (EESC), which is based on an improved formulation of the propagation of trends of species with chemical loss from the troposphere to the stratosphere. EESC calculated with the new method shows much better agreement with model-derived ESC. Based on this new formulation, we expect the halogen impact on midlatitude stratospheric ozone to return to 1980 values about 10 years later, then using the current formulation.
Tilman Hüneke, Oliver-Alex Aderhold, Jannik Bounin, Marcel Dorf, Eric Gentry, Katja Grossmann, Jens-Uwe Grooß, Peter Hoor, Patrick Jöckel, Mareike Kenntner, Marvin Knapp, Matthias Knecht, Dominique Lörks, Sabrina Ludmann, Sigrun Matthes, Rasmus Raecke, Marcel Reichert, Jannis Weimar, Bodo Werner, Andreas Zahn, Helmut Ziereis, and Klaus Pfeilsticker
Atmos. Meas. Tech., 10, 4209–4234, https://doi.org/10.5194/amt-10-4209-2017, https://doi.org/10.5194/amt-10-4209-2017, 2017
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This paper describes a novel instrument for the aircraft-borne remote sensing of trace gases and liquid and solid water. Until recently, such measurements could only be evaluated under clear-sky conditions. We present a characterization and error assessment of the novel "scaling method", which allows for the retrieval of absolute trace gas concentrations under all sky conditions, significantly expanding the applicability of such measurements to study atmospheric photochemistry.
Stefan Lossow, Hella Garny, and Patrick Jöckel
Atmos. Chem. Phys., 17, 11521–11539, https://doi.org/10.5194/acp-17-11521-2017, https://doi.org/10.5194/acp-17-11521-2017, 2017
Stefanie Falk, Björn-Martin Sinnhuber, Gisèle Krysztofiak, Patrick Jöckel, Phoebe Graf, and Sinikka T. Lennartz
Atmos. Chem. Phys., 17, 11313–11329, https://doi.org/10.5194/acp-17-11313-2017, https://doi.org/10.5194/acp-17-11313-2017, 2017
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Brominated very short-lived source gases (VSLS) contribute significantly to the tropospheric and stratospheric bromine loading. We find an increase of future ocean–atmosphere flux of brominated VSLS of 8–10 % compared to present day. A decrease in the tropospheric mixing ratios of VSLS and an increase in the lower stratosphere are attributed to changes in atmospheric chemistry and transport. Bromine impact on stratospheric ozone at the end of the 21st century is reduced compared to present day.
Sergey Gromov, Carl A. M. Brenninkmeijer, and Patrick Jöckel
Atmos. Chem. Phys., 17, 8525–8552, https://doi.org/10.5194/acp-17-8525-2017, https://doi.org/10.5194/acp-17-8525-2017, 2017
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We revisit the proxies/uncertainties for the 13C/12C ratios of emissions of reactive C into the atmosphere. Our main findings are (i) a factor of 2 less uncertain estimate of tropospheric CO surface sources δ13C, (ii) a confirmed disagreement between the bottom-up and top-down 13CO-inclusive emission estimates, and (iii) a novel estimate of the δ13C signatures of a range of NMHCs/VOCs to be used in modelling studies. Results are based on the EMAC model emission set-up evaluated for 2000.
Volker Grewe, Eleni Tsati, Mariano Mertens, Christine Frömming, and Patrick Jöckel
Geosci. Model Dev., 10, 2615–2633, https://doi.org/10.5194/gmd-10-2615-2017, https://doi.org/10.5194/gmd-10-2615-2017, 2017
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We present a diagnostics, implemented in an Earth system model, which keeps track of the contribution of source categories (mainly emission sectors) to various concentrations (O3 and HOx). For the first time, it takes into account chemically competing effects, e.g., the competition between ozone precursors in the production of ozone. We show that the results are in-line with results from other tagging schemes and provide plausibility checks for OH and HO2, which have not previously been tagged.
Simone Dietmüller, Hella Garny, Felix Plöger, Patrick Jöckel, and Duy Cai
Atmos. Chem. Phys., 17, 7703–7719, https://doi.org/10.5194/acp-17-7703-2017, https://doi.org/10.5194/acp-17-7703-2017, 2017
Klaus-D. Gottschaldt, Hans Schlager, Robert Baumann, Heiko Bozem, Veronika Eyring, Peter Hoor, Patrick Jöckel, Tina Jurkat, Christiane Voigt, Andreas Zahn, and Helmut Ziereis
Atmos. Chem. Phys., 17, 6091–6111, https://doi.org/10.5194/acp-17-6091-2017, https://doi.org/10.5194/acp-17-6091-2017, 2017
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We present upper-tropospheric trace gas measurements in the Asian summer monsoon anticyclone, obtained with the HALO research aircraft in September 2012. The anticyclone is one of the largest atmospheric features on Earth, but many aspects of it are not well understood. With the help of model simulations we find that entrainments from the tropopause region and the lower troposphere, combined with photochemistry and dynamical instabilities, can explain the observations.
Jennifer Ostermöller, Harald Bönisch, Patrick Jöckel, and Andreas Engel
Atmos. Chem. Phys., 17, 3785–3797, https://doi.org/10.5194/acp-17-3785-2017, https://doi.org/10.5194/acp-17-3785-2017, 2017
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We analysed the temporal evolution of fractional release factors (FRFs) from EMAC model simulations for several halocarbons and nitrous oxide. The current formulation of FRFs yields values that depend on the tropospheric trend of the species. This is a problematic issue for the application of FRF in the calculation of steady-state quantities (e.g. ODP). Including a loss term in the calculation, we develop a new formulation of FRF and find that the time dependence can almost be compensated.
Olaf Morgenstern, Michaela I. Hegglin, Eugene Rozanov, Fiona M. O'Connor, N. Luke Abraham, Hideharu Akiyoshi, Alexander T. Archibald, Slimane Bekki, Neal Butchart, Martyn P. Chipperfield, Makoto Deushi, Sandip S. Dhomse, Rolando R. Garcia, Steven C. Hardiman, Larry W. Horowitz, Patrick Jöckel, Beatrice Josse, Douglas Kinnison, Meiyun Lin, Eva Mancini, Michael E. Manyin, Marion Marchand, Virginie Marécal, Martine Michou, Luke D. Oman, Giovanni Pitari, David A. Plummer, Laura E. Revell, David Saint-Martin, Robyn Schofield, Andrea Stenke, Kane Stone, Kengo Sudo, Taichu Y. Tanaka, Simone Tilmes, Yousuke Yamashita, Kohei Yoshida, and Guang Zeng
Geosci. Model Dev., 10, 639–671, https://doi.org/10.5194/gmd-10-639-2017, https://doi.org/10.5194/gmd-10-639-2017, 2017
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We present a review of the make-up of 20 models participating in the Chemistry–Climate Model Initiative (CCMI). In comparison to earlier such activities, most of these models comprise a whole-atmosphere chemistry, and several of them include an interactive ocean module. This makes them suitable for studying the interactions of tropospheric air quality, stratospheric ozone, and climate. The paper lays the foundation for other studies using the CCMI simulations for scientific analysis.
Duy Cai, Martin Dameris, Hella Garny, Felix Bunzel, Patrick Jöckel, and Phoebe Graf
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2016-870, https://doi.org/10.5194/acp-2016-870, 2016
Revised manuscript not accepted
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Reliable information on weather and climate are of increasing interest for economy, politics and society.
In particular decadal timescales become more and more important. This study focuses on stratospheric processes relevant for the dynamical variability on intra decadal timescale. We apply a so called power spectra analysis. With this method and further analyses we could determine a minimum vertical resolution for numerical models, which is required to capture these processes.
Bastian Kern and Patrick Jöckel
Geosci. Model Dev., 9, 3639–3654, https://doi.org/10.5194/gmd-9-3639-2016, https://doi.org/10.5194/gmd-9-3639-2016, 2016
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Input and output of large data limit the performance of numerical models on supercomputers. We present an interface for the calculation of online diagnostics in a weather and climate model. These diagnostics are calculated online during the simulation instead of as subsequent post-processing. Depending on the diagnostic, we can reduce the amount of model output.
Mariano Mertens, Astrid Kerkweg, Patrick Jöckel, Holger Tost, and Christiane Hofmann
Geosci. Model Dev., 9, 3545–3567, https://doi.org/10.5194/gmd-9-3545-2016, https://doi.org/10.5194/gmd-9-3545-2016, 2016
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This fourth part in a series of publications describing the newly developed regional chemistry–climate system MECO(n) is dedicated to the evaluation of MECO(n) with respect to tropospheric gas-phase chemistry. For this, a simulation incorporating two regional instances, one over Europe with 50 km resolution and one over Germany with 12 km resolution, is conducted. The model results are compared with satellite, ground-based and aircraft in situ observations.
Hiroshi Yamashita, Volker Grewe, Patrick Jöckel, Florian Linke, Martin Schaefer, and Daisuke Sasaki
Geosci. Model Dev., 9, 3363–3392, https://doi.org/10.5194/gmd-9-3363-2016, https://doi.org/10.5194/gmd-9-3363-2016, 2016
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This study introduces AirTraf v1.0 for climate impact evaluations, which performs global air traffic simulations in the ECHAM5/MESSy Atmospheric Chemistry model. AirTraf simulations were demonstrated with great circle and flight time routing options for a specific winter day, assuming an Airbus A330 aircraft. The results confirmed that AirTraf simulates the air traffic properly for the two options. Calculated flight time, fuel consumption and NOx emission index are comparable to reference data.
Sabine Brinkop, Martin Dameris, Patrick Jöckel, Hella Garny, Stefan Lossow, and Gabriele Stiller
Atmos. Chem. Phys., 16, 8125–8140, https://doi.org/10.5194/acp-16-8125-2016, https://doi.org/10.5194/acp-16-8125-2016, 2016
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This study investigates the water vapour decline in the stratosphere beginning in the year 2000 and other similarly strong stratospheric water vapour reductions. The driving forces are tropical sea surface temperature (SST) changes due to coincidence with a preceding ENSO event and supported by the west to east change of the QBO.
There are indications that both SSTs and the specific dynamical state of the atmosphere contribute to the long period of low water vapour values from 2001 to 2006.
Steffen Beirle, Christoph Hörmann, Patrick Jöckel, Song Liu, Marloes Penning de Vries, Andrea Pozzer, Holger Sihler, Pieter Valks, and Thomas Wagner
Atmos. Meas. Tech., 9, 2753–2779, https://doi.org/10.5194/amt-9-2753-2016, https://doi.org/10.5194/amt-9-2753-2016, 2016
Simone Dietmüller, Patrick Jöckel, Holger Tost, Markus Kunze, Catrin Gellhorn, Sabine Brinkop, Christine Frömming, Michael Ponater, Benedikt Steil, Axel Lauer, and Johannes Hendricks
Geosci. Model Dev., 9, 2209–2222, https://doi.org/10.5194/gmd-9-2209-2016, https://doi.org/10.5194/gmd-9-2209-2016, 2016
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Four new radiation related submodels (RAD, AEROPT, CLOUDOPT, and ORBIT) are available within the MESSy framework now. They are largely based on the original radiation scheme of ECHAM5. RAD simulates radiative transfer, AEROPT calculates aerosol optical properties, CLOUDOPT calculates cloud optical properties, and ORBIT is responsible for Earth orbit calculations. Multiple diagnostic calls of the radiation routine are possible, so radiative forcing can be calculated during the model simulation.
Michael Löffler, Sabine Brinkop, and Patrick Jöckel
Atmos. Chem. Phys., 16, 6547–6562, https://doi.org/10.5194/acp-16-6547-2016, https://doi.org/10.5194/acp-16-6547-2016, 2016
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After the two major volcanic eruptions of El Chichón in Mexico in 1982 and Mount Pinatubo on the Philippines in 1991, stratospheric water vapour is significantly increased. This results from increased stratospheric heating rates due to volcanic aerosol and the subsequent changes in stratospheric and tropopause temperatures in the tropics. The tropical vertical advection and the South Asian summer monsoon are identified as important sources for the additional water vapour in the stratosphere.
Marje Prank, Mikhail Sofiev, Svetlana Tsyro, Carlijn Hendriks, Valiyaveetil Semeena, Xavier Vazhappilly Francis, Tim Butler, Hugo Denier van der Gon, Rainer Friedrich, Johannes Hendricks, Xin Kong, Mark Lawrence, Mattia Righi, Zissis Samaras, Robert Sausen, Jaakko Kukkonen, and Ranjeet Sokhi
Atmos. Chem. Phys., 16, 6041–6070, https://doi.org/10.5194/acp-16-6041-2016, https://doi.org/10.5194/acp-16-6041-2016, 2016
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Aerosol composition in Europe was simulated by four chemistry transport models and compared to observations to identify the most prominent areas for model improvement. Notable differences were found between the models' predictions, attributable to different treatment or omission of aerosol sources and processes. All models underestimated the observed concentrations by 10–60 %, mostly due to under-predicting the carbonaceous and mineral particles and omitting the aerosol-bound water.
Mattia Righi, Johannes Hendricks, and Robert Sausen
Atmos. Chem. Phys., 16, 4481–4495, https://doi.org/10.5194/acp-16-4481-2016, https://doi.org/10.5194/acp-16-4481-2016, 2016
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Using a global aerosol model, we estimate the impact of aviation emissions on aerosol and climate in 2030 for different scenarios. The aviation impacts on particle number are found to be much more important than the impact on aerosol mass and significantly contribute to the overall increase in particle number concentration between 2000 and 2030. This leads to a large aviation-induced climate effect (mostly driven by aerosol-cloud interactions), a factor of 2 to 4 larger than in the year 2000.
Patrick Jöckel, Holger Tost, Andrea Pozzer, Markus Kunze, Oliver Kirner, Carl A. M. Brenninkmeijer, Sabine Brinkop, Duy S. Cai, Christoph Dyroff, Johannes Eckstein, Franziska Frank, Hella Garny, Klaus-Dirk Gottschaldt, Phoebe Graf, Volker Grewe, Astrid Kerkweg, Bastian Kern, Sigrun Matthes, Mariano Mertens, Stefanie Meul, Marco Neumaier, Matthias Nützel, Sophie Oberländer-Hayn, Roland Ruhnke, Theresa Runde, Rolf Sander, Dieter Scharffe, and Andreas Zahn
Geosci. Model Dev., 9, 1153–1200, https://doi.org/10.5194/gmd-9-1153-2016, https://doi.org/10.5194/gmd-9-1153-2016, 2016
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With an advanced numerical global chemistry climate model (CCM) we performed several detailed
combined hind-cast and projection simulations of the period 1950 to 2100 to assess the
past, present, and potential future dynamical and chemical state of the Earth atmosphere.
The manuscript documents the model and the various applied model set-ups and provides
a first evaluation of the simulation results from a global perspective as a quality check of the data.
A. J. G. Baumgaertner, P. Jöckel, A. Kerkweg, R. Sander, and H. Tost
Geosci. Model Dev., 9, 125–135, https://doi.org/10.5194/gmd-9-125-2016, https://doi.org/10.5194/gmd-9-125-2016, 2016
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The Community Earth System Model (CESM1) is connected to the the Modular Earth Submodel System (MESSy) as a new base model. This allows MESSy users the option to utilize either the state-of-the art spectral element atmosphere dynamical core or the finite volume core of CESM1. Additionally, this makes several other component models available to MESSy users.
Christiane Hofmann, Astrid Kerkweg, Peter Hoor, and Patrick Jöckel
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2015-949, https://doi.org/10.5194/acp-2015-949, 2016
Revised manuscript not accepted
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Ozone enhancements at the surface, caused by descending stratospheric air masses along deep tropopause folds, can be reproduced using the model system MECO(n). It is shown that stratosphere-troposphere-exchange (STE) in the vicinity of a tropopause fold occurs in regions of turbulence and diabatic processes. The efficiency of mixing is quantified, showing that almost all of the air masses originating in the tropopause fold are transported into the troposphere during the following two days.
A. Kerkweg and P. Jöckel
Geosci. Model Dev. Discuss., https://doi.org/10.5194/gmdd-8-8607-2015, https://doi.org/10.5194/gmdd-8-8607-2015, 2015
Revised manuscript not accepted
R. Eichinger, P. Jöckel, and S. Lossow
Atmos. Chem. Phys., 15, 7003–7015, https://doi.org/10.5194/acp-15-7003-2015, https://doi.org/10.5194/acp-15-7003-2015, 2015
H. Fischer, A. Pozzer, T. Schmitt, P. Jöckel, T. Klippel, D. Taraborrelli, and J. Lelieveld
Atmos. Chem. Phys., 15, 6971–6980, https://doi.org/10.5194/acp-15-6971-2015, https://doi.org/10.5194/acp-15-6971-2015, 2015
L. E. Revell, F. Tummon, A. Stenke, T. Sukhodolov, A. Coulon, E. Rozanov, H. Garny, V. Grewe, and T. Peter
Atmos. Chem. Phys., 15, 5887–5902, https://doi.org/10.5194/acp-15-5887-2015, https://doi.org/10.5194/acp-15-5887-2015, 2015
Short summary
Short summary
We have examined the effects of ozone precursor emissions and climate change on the tropospheric ozone budget. Under RCP 6.0, ozone in the future is governed primarily by changes in nitrogen oxides (NOx). Methane is also important, and induces an increase in tropospheric ozone that is approximately one-third of that caused by NOx. This study highlights the critical role that emission policies globally have to play in determining tropospheric ozone evolution through the 21st century.
R. Eichinger, P. Jöckel, S. Brinkop, M. Werner, and S. Lossow
Atmos. Chem. Phys., 15, 5537–5555, https://doi.org/10.5194/acp-15-5537-2015, https://doi.org/10.5194/acp-15-5537-2015, 2015
M. Righi, V. Eyring, K.-D. Gottschaldt, C. Klinger, F. Frank, P. Jöckel, and I. Cionni
Geosci. Model Dev., 8, 733–768, https://doi.org/10.5194/gmd-8-733-2015, https://doi.org/10.5194/gmd-8-733-2015, 2015
M. Righi, J. Hendricks, and R. Sausen
Atmos. Chem. Phys., 15, 633–651, https://doi.org/10.5194/acp-15-633-2015, https://doi.org/10.5194/acp-15-633-2015, 2015
R. Sander, P. Jöckel, O. Kirner, A. T. Kunert, J. Landgraf, and A. Pozzer
Geosci. Model Dev., 7, 2653–2662, https://doi.org/10.5194/gmd-7-2653-2014, https://doi.org/10.5194/gmd-7-2653-2014, 2014
C. M. Hoppe, L. Hoffmann, P. Konopka, J.-U. Grooß, F. Ploeger, G. Günther, P. Jöckel, and R. Müller
Geosci. Model Dev., 7, 2639–2651, https://doi.org/10.5194/gmd-7-2639-2014, https://doi.org/10.5194/gmd-7-2639-2014, 2014
P. Valks, N. Hao, S. Gimeno Garcia, D. Loyola, M. Dameris, P. Jöckel, and A. Delcloo
Atmos. Meas. Tech., 7, 2513–2530, https://doi.org/10.5194/amt-7-2513-2014, https://doi.org/10.5194/amt-7-2513-2014, 2014
R. Eichinger and P. Jöckel
Geosci. Model Dev., 7, 1573–1582, https://doi.org/10.5194/gmd-7-1573-2014, https://doi.org/10.5194/gmd-7-1573-2014, 2014
M. S. Long, W. C. Keene, R. C. Easter, R. Sander, X. Liu, A. Kerkweg, and D. Erickson
Atmos. Chem. Phys., 14, 3397–3425, https://doi.org/10.5194/acp-14-3397-2014, https://doi.org/10.5194/acp-14-3397-2014, 2014
S. Meul, U. Langematz, S. Oberländer, H. Garny, and P. Jöckel
Atmos. Chem. Phys., 14, 2959–2971, https://doi.org/10.5194/acp-14-2959-2014, https://doi.org/10.5194/acp-14-2959-2014, 2014
C. Liu, S. Beirle, T. Butler, P. Hoor, C. Frankenberg, P. Jöckel, M. Penning de Vries, U. Platt, A. Pozzer, M. G. Lawrence, J. Lelieveld, H. Tost, and T. Wagner
Atmos. Chem. Phys., 14, 1717–1732, https://doi.org/10.5194/acp-14-1717-2014, https://doi.org/10.5194/acp-14-1717-2014, 2014
V. Grewe, C. Frömming, S. Matthes, S. Brinkop, M. Ponater, S. Dietmüller, P. Jöckel, H. Garny, E. Tsati, K. Dahlmann, O. A. Søvde, J. Fuglestvedt, T. K. Berntsen, K. P. Shine, E. A. Irvine, T. Champougny, and P. Hullah
Geosci. Model Dev., 7, 175–201, https://doi.org/10.5194/gmd-7-175-2014, https://doi.org/10.5194/gmd-7-175-2014, 2014
E. Regelin, H. Harder, M. Martinez, D. Kubistin, C. Tatum Ernest, H. Bozem, T. Klippel, Z. Hosaynali-Beygi, H. Fischer, R. Sander, P. Jöckel, R. Königstedt, and J. Lelieveld
Atmos. Chem. Phys., 13, 10703–10720, https://doi.org/10.5194/acp-13-10703-2013, https://doi.org/10.5194/acp-13-10703-2013, 2013
M. Righi, J. Hendricks, and R. Sausen
Atmos. Chem. Phys., 13, 9939–9970, https://doi.org/10.5194/acp-13-9939-2013, https://doi.org/10.5194/acp-13-9939-2013, 2013
H. Garny, G. E. Bodeker, D. Smale, M. Dameris, and V. Grewe
Atmos. Chem. Phys., 13, 7279–7300, https://doi.org/10.5194/acp-13-7279-2013, https://doi.org/10.5194/acp-13-7279-2013, 2013
V. Grewe
Geosci. Model Dev., 6, 417–427, https://doi.org/10.5194/gmd-6-417-2013, https://doi.org/10.5194/gmd-6-417-2013, 2013
K. Gottschaldt, C. Voigt, P. Jöckel, M. Righi, R. Deckert, and S. Dietmüller
Atmos. Chem. Phys., 13, 3003–3025, https://doi.org/10.5194/acp-13-3003-2013, https://doi.org/10.5194/acp-13-3003-2013, 2013
V. Grewe
Geosci. Model Dev., 6, 247–253, https://doi.org/10.5194/gmd-6-247-2013, https://doi.org/10.5194/gmd-6-247-2013, 2013
Ø. Hodnebrog, T. K. Berntsen, O. Dessens, M. Gauss, V. Grewe, I. S. A. Isaksen, B. Koffi, G. Myhre, D. Olivié, M. J. Prather, F. Stordal, S. Szopa, Q. Tang, P. van Velthoven, and J. E. Williams
Atmos. Chem. Phys., 12, 12211–12225, https://doi.org/10.5194/acp-12-12211-2012, https://doi.org/10.5194/acp-12-12211-2012, 2012
Related subject area
Subject: Gases | Research Activity: Atmospheric Modelling and Data Analysis | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
Interpreting summertime hourly variation of NO2 columns with implications for geostationary satellite applications
An investigation into atmospheric nitrous acid (HONO) processes in South Korea
Performance evaluation of UKESM1 for surface ozone across the pan-tropics
Constraining light dependency in modeled emissions through comparison to observed biogenic volatile organic compound (BVOC) concentrations in a southeastern US forest
A global re-analysis of regionally resolved emissions and atmospheric mole fractions of SF6 for the period 2005–2021
Tropospheric ozone precursors: global and regional distributions, trends, and variability
The contribution of transport emissions to ozone mixing ratios and methane lifetime in 2015 and 2050 in the Shared Socioeconomic Pathways (SSPs)
Ether and ester formation from peroxy radical recombination: a qualitative reaction channel analysis
ACEIC: a comprehensive anthropogenic chlorine emission inventory for China
Impact of methane and other precursor emission reductions on surface ozone in Europe: scenario analysis using the European Monitoring and Evaluation Programme (EMEP) Meteorological Synthesizing Centre – West (MSC-W) model
Verifying national inventory-based combustion emissions of CO2 across the UK and mainland Europe using satellite observations of atmospheric CO and CO2
An improved estimate of inorganic iodine emissions from the ocean using a coupled surface microlayer box model
Impact of improved representation of volatile organic compound emissions and production of NOx reservoirs on modeled urban ozone production
The effect of different climate and air quality policies in China on in situ ozone production in Beijing
Enhancing long-term trend simulation of the global tropospheric hydroxyl (TOH) and its drivers from 2005 to 2019: a synergistic integration of model simulations and satellite observations
Intercomparison of GEOS-Chem and CAM-chem tropospheric oxidant chemistry within the Community Earth System Model version 2 (CESM2)
Development of a detailed gaseous oxidation scheme of naphthalene for secondary organic aerosol (SOA) formation and speciation
Large contributions of soil emissions to the atmospheric nitrogen budget and their impacts on air quality and temperature rise in North China
Why did ozone concentrations remain high during Shanghai's static management? A statistical and radical-chemistry perspective
Revising VOC emissions speciation improves the simulation of global background ethane and propane
Changes in South American surface ozone trends: exploring the influences of precursors and extreme events
Evaluating NOx stack plume emissions using a high-resolution atmospheric chemistry model and satellite-derived NO2 columns
NOx emissions in France in 2019–2021 as estimated by the high-spatial-resolution assimilation of TROPOMI NO2 observations
Aggravated surface O3 pollution primarily driven by meteorological variations in China during the 2020 COVID-19 pandemic lockdown period
Identifying decadal trends in deweathered concentrations of criteria air pollutants in Canadian urban atmospheres with machine learning approaches
Evaluation of modelled versus observed non-methane volatile organic compounds at European Monitoring and Evaluation Programme sites in Europe
Constraining non-methane VOC emissions with TROPOMI HCHO observations: impact on summertime ozone simulation in August 2022 in China
Revealing the significant acceleration of hydrofluorocarbon (HFC) emissions in eastern Asia through long-term atmospheric observations
Role of chemical production and depositional losses on formaldehyde in the Community Regional Atmospheric Chemistry Multiphase Mechanism (CRACMM)
Interpreting Geostationary Environment Monitoring Spectrometer (GEMS) geostationary satellite observations of the diurnal variation in nitrogen dioxide (NO2) over East Asia
An intercomparison of satellite, airborne, and ground-level observations with WRF–CAMx simulations of NO2 columns over Houston, Texas, during the September 2021 TRACER-AQ campaign
Investigating processes influencing simulation of local Arctic wintertime anthropogenic pollution in Fairbanks, Alaska during ALPACA-2022
Interannual variability of summertime formaldehyde (HCHO) vertical column density and its main drivers at northern high latitudes
The impact of multi-decadal changes in VOC speciation on urban ozone chemistry: a case study in Birmingham, United Kingdom
Technical note: Challenges in detecting free tropospheric ozone trends in a sparsely sampled environment
Combined assimilation of NOAA surface and MIPAS satellite observations to constrain the global budget of carbonyl sulfide
The impact of gaseous degradation on the gas–particle partitioning of methylated polycyclic aromatic hydrocarbons
Technical note: An assessment of the performance of statistical bias correction techniques for global chemistry–climate model surface ozone fields
Opinion: Challenges and needs of tropospheric chemical mechanism development
A better representation of volatile organic compound chemistry in WRF-Chem and its impact on ozone over Los Angeles
High-resolution US methane emissions inferred from an inversion of 2019 TROPOMI satellite data: contributions from individual states, urban areas, and landfills
Summertime tropospheric ozone source apportionment study in the Madrid region (Spain)
CO anthropogenic emissions in Europe from 2011 to 2021: insights from Measurement of Pollution in the Troposphere (MOPITT) satellite data
Constraining long-term NOx emissions over the United States and Europe using nitrate wet deposition monitoring networks
Analysis of an intense O3 pollution episode on the Atlantic coast of the Iberian Peninsula using photochemical modeling: characterization of transport pathways and accumulation processes
Atmospheric oxygen as a tracer for fossil fuel carbon dioxide: a sensitivity study in the UK
Source analyses of ambient VOCs considering reactive losses: methods of reducing loss effects, impacts of losses, and sources
MIXv2: a long-term mosaic emission inventory for Asia (2010–2017)
The Atmospheric Oxidizing Capacity in China: Part 2. Sensitivity to emissions of primary pollutants
Process Analysis of Elevated Concentrations of Organic Acids at Whiteface Mountain, New York
Deepangsu Chatterjee, Randall V. Martin, Chi Li, Dandan Zhang, Haihui Zhu, Daven K. Henze, James H. Crawford, Ronald C. Cohen, Lok N. Lamsal, and Alexander M. Cede
Atmos. Chem. Phys., 24, 12687–12706, https://doi.org/10.5194/acp-24-12687-2024, https://doi.org/10.5194/acp-24-12687-2024, 2024
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We investigate the hourly variation of NO2 columns and surface concentrations by applying the GEOS-Chem model to interpret aircraft and ground-based measurements over the US and Pandora sun photometer measurements over the US, Europe, and Asia. Corrections to the Pandora columns and finer model resolution improve the modeled representation of the summertime hourly variation of total NO2 columns to explain the weaker hourly variation in NO2 columns than at the surface.
Kiyeon Kim, Kyung Man Han, Chul Han Song, Hyojun Lee, Ross Beardsley, Jinhyeok Yu, Greg Yarwood, Bonyoung Koo, Jasper Madalipay, Jung-Hun Woo, and Seogju Cho
Atmos. Chem. Phys., 24, 12575–12593, https://doi.org/10.5194/acp-24-12575-2024, https://doi.org/10.5194/acp-24-12575-2024, 2024
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We incorporated each HONO process into the current CMAQ modeling framework to enhance the accuracy of HONO mixing ratio predictions. These results expand our understanding of HONO photochemistry and identify crucial sources of HONO that impact the total HONO budget in Seoul, South Korea. Through this investigation, we contribute to resolving discrepancies in understanding chemical transport models, with implications for better air quality management and environmental protection in the region.
Flossie Brown, Gerd Folberth, Stephen Sitch, Paulo Artaxo, Marijn Bauters, Pascal Boeckx, Alexander W. Cheesman, Matteo Detto, Ninong Komala, Luciana Rizzo, Nestor Rojas, Ines dos Santos Vieira, Steven Turnock, Hans Verbeeck, and Alfonso Zambrano
Atmos. Chem. Phys., 24, 12537–12555, https://doi.org/10.5194/acp-24-12537-2024, https://doi.org/10.5194/acp-24-12537-2024, 2024
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Ozone is a pollutant that is detrimental to human and plant health. Ozone monitoring sites in the tropics are limited, so models are often used to understand ozone exposure. We use measurements from the tropics to evaluate ozone from the UK Earth system model, UKESM1. UKESM1 is able to capture the pattern of ozone in the tropics, except in southeast Asia, although it systematically overestimates it at all sites. This work highlights that UKESM1 can capture seasonal and hourly variability.
Namrata Shanmukh Panji, Deborah F. McGlynn, Laura E. R. Barry, Todd M. Scanlon, Manuel T. Lerdau, Sally E. Pusede, and Gabriel Isaacman-VanWertz
Atmos. Chem. Phys., 24, 12495–12507, https://doi.org/10.5194/acp-24-12495-2024, https://doi.org/10.5194/acp-24-12495-2024, 2024
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Climate change will bring about changes in parameters that are currently used in global-scale models to calculate biogenic emissions. This study seeks to understand the factors driving these models by comparing long-term datasets of biogenic compounds to modeled emissions. We note that the light-dependent fractions currently used in models do not accurately represent regional observations. We provide evidence for the time-dependent variation in this parameter for future modifications to models.
Martin Vojta, Andreas Plach, Saurabh Annadate, Sunyoung Park, Gawon Lee, Pallav Purohit, Florian Lindl, Xin Lan, Jens Mühle, Rona L. Thompson, and Andreas Stohl
Atmos. Chem. Phys., 24, 12465–12493, https://doi.org/10.5194/acp-24-12465-2024, https://doi.org/10.5194/acp-24-12465-2024, 2024
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We constrain the global emissions of the very potent greenhouse gas sulfur hexafluoride (SF6) between 2005 and 2021. We show that SF6 emissions are decreasing in the USA and in the EU, while they are substantially growing in China, leading overall to an increasing global emission trend. The national reports for the USA, EU, and China all underestimated their SF6 emissions. However, stringent mitigation measures can successfully reduce SF6 emissions, as can be seen in the EU emission trend.
Yasin Elshorbany, Jerald R. Ziemke, Sarah Strode, Hervé Petetin, Kazuyuki Miyazaki, Isabelle De Smedt, Kenneth Pickering, Rodrigo J. Seguel, Helen Worden, Tamara Emmerichs, Domenico Taraborrelli, Maria Cazorla, Suvarna Fadnavis, Rebecca R. Buchholz, Benjamin Gaubert, Néstor Y. Rojas, Thiago Nogueira, Thérèse Salameh, and Min Huang
Atmos. Chem. Phys., 24, 12225–12257, https://doi.org/10.5194/acp-24-12225-2024, https://doi.org/10.5194/acp-24-12225-2024, 2024
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We investigated tropospheric ozone spatial variability and trends from 2005 to 2019 and related those to ozone precursors on global and regional scales. We also investigate the spatiotemporal characteristics of the ozone formation regime in relation to ozone chemical sources and sinks. Our analysis is based on remote sensing products of the tropospheric column of ozone and its precursors, nitrogen dioxide, formaldehyde, and total column CO, as well as ozonesonde data and model simulations.
Mariano Mertens, Sabine Brinkop, Phoebe Graf, Volker Grewe, Johannes Hendricks, Patrick Jöckel, Anna Lanteri, Sigrun Matthes, Vanessa S. Rieger, Mattia Righi, and Robin N. Thor
Atmos. Chem. Phys., 24, 12079–12106, https://doi.org/10.5194/acp-24-12079-2024, https://doi.org/10.5194/acp-24-12079-2024, 2024
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We quantified the contributions of land transport, shipping, and aviation emissions to tropospheric ozone; its radiative forcing; and the reductions of the methane lifetime using chemistry-climate model simulations. The contributions were analysed for the conditions of 2015 and for three projections for the year 2050. The results highlight the challenges of mitigating ozone formed by emissions of the transport sector, caused by the non-linearitiy of the ozone chemistry and the long lifetime.
Lauri Franzon, Marie Camredon, Richard Valorso, Bernard Aumont, and Theo Kurtén
Atmos. Chem. Phys., 24, 11679–11699, https://doi.org/10.5194/acp-24-11679-2024, https://doi.org/10.5194/acp-24-11679-2024, 2024
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In this article we investigate the formation of large, sticky molecules from various organic compounds entering the atmosphere as primary emissions and the degree to which these processes may contribute to organic aerosol particle mass. More specifically, we qualitatively investigate a recently discovered chemical reaction channel for one of the most important short-lived radical compounds, peroxy radicals, and discover which of these reactions are most atmospherically important.
Siting Li, Yiming Liu, Yuqi Zhu, Yinbao Jin, Yingying Hong, Ao Shen, Yifei Xu, Haofan Wang, Haichao Wang, Xiao Lu, Shaojia Fan, and Qi Fan
Atmos. Chem. Phys., 24, 11521–11544, https://doi.org/10.5194/acp-24-11521-2024, https://doi.org/10.5194/acp-24-11521-2024, 2024
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This study establishes an inventory of anthropogenic chlorine emissions in China in 2019 with expanded species (HCl, Cl-, Cl2, HOCl) and sources (41 specific sources). The inventory is validated by a modeling study against the observations. This study enhances the understanding of anthropogenic chlorine emissions in the atmosphere, identifies key sources, and provides scientific support for pollution control and climate change.
Willem E. van Caspel, Zbigniew Klimont, Chris Heyes, and Hilde Fagerli
Atmos. Chem. Phys., 24, 11545–11563, https://doi.org/10.5194/acp-24-11545-2024, https://doi.org/10.5194/acp-24-11545-2024, 2024
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Methane in the atmosphere contributes to the production of ozone gas – an air pollutant and greenhouse gas. Our results highlight that simultaneous reductions in methane emissions help avoid offsetting the air pollution benefits already achieved by the already-approved precursor emission reductions by 2050 in the European Monitoring and Evaluation Programme region, while also playing an important role in bringing air pollution further down towards World Health Organization guideline limits.
Tia R. Scarpelli, Paul I. Palmer, Mark Lunt, Ingrid Super, and Arjan Droste
Atmos. Chem. Phys., 24, 10773–10791, https://doi.org/10.5194/acp-24-10773-2024, https://doi.org/10.5194/acp-24-10773-2024, 2024
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Under the Paris Agreement, countries must track their anthropogenic greenhouse gas emissions. This study describes a method to determine self-consistent estimates for combustion emissions and natural fluxes of CO2 from atmospheric data. We report consistent estimates inferred using this approach from satellite data and ground-based data over Europe, suggesting that satellite data can be used to determine national anthropogenic CO2 emissions for countries where ground-based CO2 data are absent.
Ryan J. Pound, Lucy V. Brown, Mat J. Evans, and Lucy J. Carpenter
Atmos. Chem. Phys., 24, 9899–9921, https://doi.org/10.5194/acp-24-9899-2024, https://doi.org/10.5194/acp-24-9899-2024, 2024
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Iodine-mediated loss of ozone to the ocean surface and the subsequent emission of iodine species has a large effect on the troposphere. Here we combine recent experimental insights to develop a box model of the process, which we then parameterize and incorporate into the GEOS-Chem transport model. We find that these new insights have a small impact on the total emission of iodine but significantly change its distribution.
Katherine R. Travis, Benjamin A. Nault, James H. Crawford, Kelvin H. Bates, Donald R. Blake, Ronald C. Cohen, Alan Fried, Samuel R. Hall, L. Gregory Huey, Young Ro Lee, Simone Meinardi, Kyung-Eun Min, Isobel J. Simpson, and Kirk Ullman
Atmos. Chem. Phys., 24, 9555–9572, https://doi.org/10.5194/acp-24-9555-2024, https://doi.org/10.5194/acp-24-9555-2024, 2024
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Human activities result in the emission of volatile organic compounds (VOCs) that contribute to air pollution. Detailed VOC measurements were taken during a field study in South Korea. When compared to VOC inventories, large discrepancies showed underestimates from chemical products, liquefied petroleum gas, and long-range transport. Improved emissions and chemistry of these VOCs better described urban pollution. The new chemical scheme is relevant to urban areas and other VOC sources.
Beth S. Nelson, Zhenze Liu, Freya A. Squires, Marvin Shaw, James R. Hopkins, Jacqueline F. Hamilton, Andrew R. Rickard, Alastair C. Lewis, Zongbo Shi, and James D. Lee
Atmos. Chem. Phys., 24, 9031–9044, https://doi.org/10.5194/acp-24-9031-2024, https://doi.org/10.5194/acp-24-9031-2024, 2024
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The impact of combined air quality and carbon neutrality policies on O3 formation in Beijing was investigated. Emissions inventory data were used to estimate future pollutant mixing ratios relative to ground-level observations. O3 production was found to be most sensitive to changes in alkenes, but large reductions in less reactive compounds led to larger reductions in future O3 production. This study highlights the importance of understanding the emissions of organic pollutants.
Amir H. Souri, Bryan N. Duncan, Sarah A. Strode, Daniel C. Anderson, Michael E. Manyin, Junhua Liu, Luke D. Oman, Zhen Zhang, and Brad Weir
Atmos. Chem. Phys., 24, 8677–8701, https://doi.org/10.5194/acp-24-8677-2024, https://doi.org/10.5194/acp-24-8677-2024, 2024
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We explore a new method of using the wealth of information obtained from satellite observations of Aura OMI NO2, HCHO, and MERRA-2 reanalysis in NASA’s GEOS model equipped with an efficient tropospheric OH (TOH) estimator to enhance the representation of TOH spatial distribution and its long-term trends. This new framework helps us pinpoint regional inaccuracies in TOH and differentiate between established prior knowledge and newly acquired information from satellites on TOH trends.
Haipeng Lin, Louisa K. Emmons, Elizabeth W. Lundgren, Laura Hyesung Yang, Xu Feng, Ruijun Dang, Shixian Zhai, Yunxiao Tang, Makoto M. Kelp, Nadia K. Colombi, Sebastian D. Eastham, Thibaud M. Fritz, and Daniel J. Jacob
Atmos. Chem. Phys., 24, 8607–8624, https://doi.org/10.5194/acp-24-8607-2024, https://doi.org/10.5194/acp-24-8607-2024, 2024
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Tropospheric ozone is a major air pollutant, a greenhouse gas, and a major indicator of model skill. Global atmospheric chemistry models show large differences in simulations of tropospheric ozone, but isolating sources of differences is complicated by different model environments. By implementing the GEOS-Chem model side by side to CAM-chem within a common Earth system model, we identify and evaluate specific differences between the two models and their impacts on key chemical species.
Victor Lannuque and Karine Sartelet
Atmos. Chem. Phys., 24, 8589–8606, https://doi.org/10.5194/acp-24-8589-2024, https://doi.org/10.5194/acp-24-8589-2024, 2024
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Large uncertainties remain in understanding secondary organic aerosol (SOA) formation and speciation from naphthalene oxidation. This study details the development of the first near-explicit chemical scheme for naphthalene oxidation by OH, which includes kinetic and mechanistic data, and is able to reproduce most of the experimentally identified products in both gas and particle phases.
Tong Sha, Siyu Yang, Qingcai Chen, Liangqing Li, Xiaoyan Ma, Yan-Lin Zhang, Zhaozhong Feng, K. Folkert Boersma, and Jun Wang
Atmos. Chem. Phys., 24, 8441–8455, https://doi.org/10.5194/acp-24-8441-2024, https://doi.org/10.5194/acp-24-8441-2024, 2024
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Using an updated soil reactive nitrogen emission scheme in the Unified Inputs for Weather Research and Forecasting coupled with Chemistry (UI-WRF-Chem) model, we investigate the role of soil NO and HONO (Nr) emissions in air quality and temperature in North China. Contributions of soil Nr emissions to O3 and secondary pollutants are revealed, exceeding effects of soil NOx or HONO emission. Soil Nr emissions play an important role in mitigating O3 pollution and addressing climate change.
Jian Zhu, Shanshan Wang, Chuanqi Gu, Zhiwen Jiang, Sanbao Zhang, Ruibin Xue, Yuhao Yan, and Bin Zhou
Atmos. Chem. Phys., 24, 8383–8395, https://doi.org/10.5194/acp-24-8383-2024, https://doi.org/10.5194/acp-24-8383-2024, 2024
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In 2022, Shanghai implemented city-wide static management measures during the high-ozone season in April and May, providing a chance to study ozone pollution control. Despite significant emissions reductions, ozone levels increased by 23 %. Statistically, the number of days with higher ozone diurnal variation types increased during the lockdown period. The uneven decline in VOC and NO2 emissions led to heightened photochemical processes, resulting in the observed ozone level rise.
Matthew J. Rowlinson, Mat J. Evans, Lucy J. Carpenter, Katie A. Read, Shalini Punjabi, Adedayo Adedeji, Luke Fakes, Ally Lewis, Ben Richmond, Neil Passant, Tim Murrells, Barron Henderson, Kelvin H. Bates, and Detlev Helmig
Atmos. Chem. Phys., 24, 8317–8342, https://doi.org/10.5194/acp-24-8317-2024, https://doi.org/10.5194/acp-24-8317-2024, 2024
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Ethane and propane are volatile organic compounds emitted from human activities which help to form ozone, a pollutant and greenhouse gas, and also affect the chemistry of the lower atmosphere. Atmospheric models tend to do a poor job of reproducing the abundance of these compounds in the atmosphere. By using regional estimates of their emissions, rather than globally consistent estimates, we can significantly improve the simulation of ethane in the model and make some improvement for propane.
Rodrigo J. Seguel, Lucas Castillo, Charlie Opazo, Néstor Y. Rojas, Thiago Nogueira, María Cazorla, Mario Gavidia-Calderón, Laura Gallardo, René Garreaud, Tomás Carrasco-Escaff, and Yasin Elshorbany
Atmos. Chem. Phys., 24, 8225–8242, https://doi.org/10.5194/acp-24-8225-2024, https://doi.org/10.5194/acp-24-8225-2024, 2024
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Trends of surface ozone were examined across South America. Our findings indicate that ozone trends in major South American cities either increase or remain steady, with no signs of decline. The upward trends can be attributed to chemical regimes that efficiently convert nitric oxide into nitrogen dioxide. Additionally, our results suggest a climate penalty for ozone driven by meteorological conditions that favor wildfire propagation in Chile and extensive heat waves in southern Brazil.
Maarten Krol, Bart van Stratum, Isidora Anglou, and Klaas Folkert Boersma
Atmos. Chem. Phys., 24, 8243–8262, https://doi.org/10.5194/acp-24-8243-2024, https://doi.org/10.5194/acp-24-8243-2024, 2024
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This paper presents detailed plume simulations of nitrogen oxides and carbon dioxide that are emitted from four large industrial facilities world-wide. Results from the high-resolution simulations that include atmospheric chemistry are compared to nitrogen dioxide observations from satellites. We find good performance of the model and show that common assumptions that are used in simplified models need revision. This work is important for the monitoring of emissions using satellite data.
Robin Plauchu, Audrey Fortems-Cheiney, Grégoire Broquet, Isabelle Pison, Antoine Berchet, Elise Potier, Gaëlle Dufour, Adriana Coman, Dilek Savas, Guillaume Siour, and Henk Eskes
Atmos. Chem. Phys., 24, 8139–8163, https://doi.org/10.5194/acp-24-8139-2024, https://doi.org/10.5194/acp-24-8139-2024, 2024
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This study uses the Community Inversion Framework and CHIMERE model to assess the potential of TROPOMI-S5P PAL NO2 tropospheric column data to estimate NOx emissions in France (2019–2021). Results show a 3 % decrease in average emissions compared to the 2016 CAMS-REG/INS, lower than the 14 % decrease from CITEPA. The study highlights challenges in capturing emission anomalies due to limited data coverage and error levels but shows promise for local inventory improvements.
Zhendong Lu, Jun Wang, Yi Wang, Daven K. Henze, Xi Chen, Tong Sha, and Kang Sun
Atmos. Chem. Phys., 24, 7793–7813, https://doi.org/10.5194/acp-24-7793-2024, https://doi.org/10.5194/acp-24-7793-2024, 2024
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In contrast with past work showing that the reduction of emissions was the dominant factor for the nationwide increase of surface O3 during the lockdown in China, this study finds that the variation in meteorology (temperature and other parameters) plays a more important role. This result is obtained through sensitivity simulations using a chemical transport model constrained by satellite (TROPOMI) data and calibrated with surface observations.
Xiaohong Yao and Leiming Zhang
Atmos. Chem. Phys., 24, 7773–7791, https://doi.org/10.5194/acp-24-7773-2024, https://doi.org/10.5194/acp-24-7773-2024, 2024
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This study investigates long-term trends of criteria air pollutants, including NO2, CO, SO2, O3 and PM2.5, and NO2+O3 measured in 10 Canadian cities during the last 2 to 3 decades. We also investigate associated driving forces in terms of emission reductions, perturbations from varying weather conditions and large-scale wildfires, as well as changes in O3 sources and sinks.
Yao Ge, Sverre Solberg, Mathew R. Heal, Stefan Reimann, Willem van Caspel, Bryan Hellack, Thérèse Salameh, and David Simpson
Atmos. Chem. Phys., 24, 7699–7729, https://doi.org/10.5194/acp-24-7699-2024, https://doi.org/10.5194/acp-24-7699-2024, 2024
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Atmospheric volatile organic compounds (VOCs) constitute many species, acting as precursors to ozone and aerosol. Given the uncertainties in VOC emissions, lack of evaluation studies, and recent changes in emissions, this work adapts the EMEP MSC-W to evaluate emission inventories in Europe. We focus on the varying agreement between modelled and measured VOCs across different species and underscore potential inaccuracies in total and sector-specific emission estimates.
Shuzhuang Feng, Fei Jiang, Tianlu Qian, Nan Wang, Mengwei Jia, Songci Zheng, Jiansong Chen, Fang Ying, and Weimin Ju
Atmos. Chem. Phys., 24, 7481–7498, https://doi.org/10.5194/acp-24-7481-2024, https://doi.org/10.5194/acp-24-7481-2024, 2024
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We developed a multi-air-pollutant inversion system to estimate non-methane volatile organic compound (NMVOC) emissions using TROPOMI formaldehyde retrievals. We found that the inversion significantly improved formaldehyde simulations and reduced NMVOC emission uncertainties. The optimized NMVOC emissions effectively corrected the overestimation of O3 levels, mainly by decreasing the rate of the RO2 + NO reaction and increasing the rate of the NO2 + OH reaction.
Haklim Choi, Alison L. Redington, Hyeri Park, Jooil Kim, Rona L. Thompson, Jens Mühle, Peter K. Salameh, Christina M. Harth, Ray F. Weiss, Alistair J. Manning, and Sunyoung Park
Atmos. Chem. Phys., 24, 7309–7330, https://doi.org/10.5194/acp-24-7309-2024, https://doi.org/10.5194/acp-24-7309-2024, 2024
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We analyzed with an inversion model the atmospheric abundance of hydrofluorocarbons (HFCs), potent greenhouse gases, from 2008 to 2020 at Gosan station in South Korea and revealed a significant increase in emissions, especially from eastern China and Japan. This increase contradicts reported data, underscoring the need for accurate monitoring and reporting. Our findings are crucial for understanding and managing global HFCs emissions, highlighting the importance of efforts to reduce HFCs.
T. Nash Skipper, Emma L. D'Ambro, Forwood C. Wiser, V. Faye McNeill, Rebecca H. Schwantes, Barron H. Henderson, Ivan R. Piletic, Colleen B. Baublitz, Jesse O. Bash, Andrew R. Whitehill, Lukas C. Valin, Asher P. Mouat, Jennifer Kaiser, Glenn M. Wolfe, Jason M. St. Clair, Thomas F. Hanisco, Alan Fried, Bryan K. Place, and Havala O. T. Pye
EGUsphere, https://doi.org/10.5194/egusphere-2024-1680, https://doi.org/10.5194/egusphere-2024-1680, 2024
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Here, we develop the Community Regional Atmospheric Chemistry Multiphase Mechanism (CRACMM) version 2 to improve predictions of formaldehyde in ambient air compared to satellite-, aircraft-, and ground-based observations. With the updated chemistry representation, we then estimate the cancer risk in the contiguous US from exposure to ambient formaldehyde and estimate 40 % of this risk is controllable through reductions in anthropogenic emissions of nitrogen oxides and reactive organic carbon.
Laura Hyesung Yang, Daniel J. Jacob, Ruijun Dang, Yujin J. Oak, Haipeng Lin, Jhoon Kim, Shixian Zhai, Nadia K. Colombi, Drew C. Pendergrass, Ellie Beaudry, Viral Shah, Xu Feng, Robert M. Yantosca, Heesung Chong, Junsung Park, Hanlim Lee, Won-Jin Lee, Soontae Kim, Eunhye Kim, Katherine R. Travis, James H. Crawford, and Hong Liao
Atmos. Chem. Phys., 24, 7027–7039, https://doi.org/10.5194/acp-24-7027-2024, https://doi.org/10.5194/acp-24-7027-2024, 2024
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The Geostationary Environment Monitoring Spectrometer (GEMS) provides hourly measurements of NO2. We use the chemical transport model to find how emissions, chemistry, and transport drive the changes in NO2 observed by GEMS at different times of the day. In winter, the chemistry plays a minor role, and high daytime emissions dominate the diurnal variation in NO2, balanced by transport. In summer, emissions, chemistry, and transport play an important role in shaping the diurnal variation in NO2.
M. Omar Nawaz, Jeremiah Johnson, Greg Yarwood, Benjamin de Foy, Laura Judd, and Daniel L. Goldberg
Atmos. Chem. Phys., 24, 6719–6741, https://doi.org/10.5194/acp-24-6719-2024, https://doi.org/10.5194/acp-24-6719-2024, 2024
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NO2 is a gas with implications for air pollution. A campaign conducted in Houston provided an opportunity to compare NO2 from different instruments and a model. Aircraft and satellite observations agreed well with measurements on the ground; however, the latter estimated lower values. We find that model-simulated NO2 was lower than observations, especially downtown, suggesting that NO2 sources associated with the urban core of Houston, such as vehicle emissions, may be underestimated.
Natalie Brett, Kathy S. Law, Steve R. Arnold, Javier G. Fochesatto, Jean-Christophe Raut, Tatsuo Onishi, Robert Gilliam, Kathleen Fahey, Deanna Huff, George Pouliot, Brice Barret, Elsa Dieudonne, Roman Pohorsky, Julia Schmale, Andrea Baccarini, Slimane Bekki, Gianluca Pappaccogli, Federico Scoto, Stefano Decesari, Antonio Donateo, Meeta Cesler-Maloney, William Simpson, Patrice Medina, Barbara D'Anna, Brice Temime-Roussel, Joel Savarino, Sarah Albertin, Jingqiu Mao, Becky Alexander, Allison Moon, Peter F. DeCarlo, Vanessa Selimovic, Robert Yokelson, and Ellis S. Robinson
EGUsphere, https://doi.org/10.5194/egusphere-2024-1450, https://doi.org/10.5194/egusphere-2024-1450, 2024
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Processes influencing dispersion of local anthropogenic emissions in Arctic wintertime are investigated with dispersion model simulations. Modelled power plant plume rise that considers surface and elevated temperature inversions improves results compared to observations. Modelled near-surface concentrations are improved by representation of vertical mixing and emission estimates. Large increases in diesel vehicle emissions at temperatures reaching -35 °C are required to reproduce observed NOx.
Tianlang Zhao, Jingqiu Mao, Zolal Ayazpour, Gonzalo González Abad, Caroline R. Nowlan, and Yiqi Zheng
Atmos. Chem. Phys., 24, 6105–6121, https://doi.org/10.5194/acp-24-6105-2024, https://doi.org/10.5194/acp-24-6105-2024, 2024
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HCHO variability is a key tracer in understanding VOC emissions in response to climate change. We investigate the role of methane oxidation and biogenic and wildfire emissions in HCHO interannual variability over northern high latitudes in summer, emphasizing wildfires as a key driver of HCHO interannual variability in Alaska, Siberia and northern Canada using satellite HCHO and SIF retrievals and then GEOS-Chem model. We show SIF is a tool to understand biogenic HCHO variability in this region.
Jianghao Li, Alastair C. Lewis, Jim R. Hopkins, Stephen J. Andrews, Tim Murrells, Neil Passant, Ben Richmond, Siqi Hou, William J. Bloss, Roy M. Harrison, and Zongbo Shi
Atmos. Chem. Phys., 24, 6219–6231, https://doi.org/10.5194/acp-24-6219-2024, https://doi.org/10.5194/acp-24-6219-2024, 2024
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A summertime ozone event at an urban site in Birmingham is sensitive to volatile organic compounds (VOCs) – particularly those of oxygenated VOCs. The roles of anthropogenic VOC sources in urban ozone chemistry are examined by integrating the 1990–2019 national atmospheric emission inventory into model scenarios. Road transport remains the most powerful means of further reducing ozone in this case study, but the benefits may be offset if solvent emissions of VOCs continue to increase.
Kai-Lan Chang, Owen R. Cooper, Audrey Gaudel, Irina Petropavlovskikh, Peter Effertz, Gary Morris, and Brian C. McDonald
Atmos. Chem. Phys., 24, 6197–6218, https://doi.org/10.5194/acp-24-6197-2024, https://doi.org/10.5194/acp-24-6197-2024, 2024
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A great majority of observational trend studies of free tropospheric ozone use sparsely sampled ozonesonde and aircraft measurements as reference data sets. A ubiquitous assumption is that trends are accurate and reliable so long as long-term records are available. We show that sampling bias due to sparse samples can persistently reduce the trend accuracy, and we highlight the importance of maintaining adequate frequency and continuity of observations.
Jin Ma, Linda M. J. Kooijmans, Norbert Glatthor, Stephen A. Montzka, Marc von Hobe, Thomas Röckmann, and Maarten C. Krol
Atmos. Chem. Phys., 24, 6047–6070, https://doi.org/10.5194/acp-24-6047-2024, https://doi.org/10.5194/acp-24-6047-2024, 2024
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The global budget of atmospheric COS can be optimised by inverse modelling using TM5-4DVAR, with the co-constraints of NOAA surface observations and MIPAS satellite data. We found reduced COS biosphere uptake from inversions and improved land and ocean separation using MIPAS satellite data assimilation. Further improvements are expected from better quantification of COS ocean and biosphere fluxes.
Fu-Jie Zhu, Zi-Feng Zhang, Li-Yan Liu, Pu-Fei Yang, Peng-Tuan Hu, Geng-Bo Ren, Meng Qin, and Wan-Li Ma
Atmos. Chem. Phys., 24, 6095–6103, https://doi.org/10.5194/acp-24-6095-2024, https://doi.org/10.5194/acp-24-6095-2024, 2024
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Gas–particle (G–P) partitioning is an important atmospheric behavior for semi-volatile organic compounds (SVOCs). Diurnal variation in G–P partitioning of methylated polycyclic aromatic hydrocarbons (Me-PAHs) demonstrates the possible influence of gaseous degradation; the enhancement of gaseous degradation (1.10–5.58 times) on G–P partitioning is verified by a steady-state G–P partitioning model. The effect of gaseous degradation on G–P partitioning of (especially light) SVOCs is important.
Christoph Staehle, Harald E. Rieder, Arlene M. Fiore, and Jordan L. Schnell
Atmos. Chem. Phys., 24, 5953–5969, https://doi.org/10.5194/acp-24-5953-2024, https://doi.org/10.5194/acp-24-5953-2024, 2024
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Chemistry–climate models show biases compared to surface ozone observations and thus require bias correction for impact studies and the assessment of air quality changes. We compare the performance of commonly used correction techniques for model outputs available via CMIP6. While all methods can reduce model biases, better results are obtained from more complex approaches. Thus, our study suggests broader use of these techniques in studies seeking to inform air quality management and policy.
Barbara Ervens, Andrew Rickard, Bernard Aumont, William P. L. Carter, Max McGillen, Abdelwahid Mellouki, John Orlando, Bénédicte Picquet-Varrault, Paul Seakins, William Stockwell, Luc Vereecken, and Tim Wallington
EGUsphere, https://doi.org/10.5194/egusphere-2024-1316, https://doi.org/10.5194/egusphere-2024-1316, 2024
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Chemical mechanisms describe the chemical processes in atmospheric models that are used to describe the changes of the atmospheric composition. Therefore, accurate chemical mechanisms are necessary to predict the evolution of air pollution and climate change. The article describes all steps that are needed to build chemical mechanisms and discusses advances and needs of experimental and theoretical research activities needed to build reliable chemical mechanisms.
Qindan Zhu, Rebecca H. Schwantes, Matthew Coggon, Colin Harkins, Jordan Schnell, Jian He, Havala O. T. Pye, Meng Li, Barry Baker, Zachary Moon, Ravan Ahmadov, Eva Y. Pfannerstill, Bryan Place, Paul Wooldridge, Benjamin C. Schulze, Caleb Arata, Anthony Bucholtz, John H. Seinfeld, Carsten Warneke, Chelsea E. Stockwell, Lu Xu, Kristen Zuraski, Michael A. Robinson, J. Andrew Neuman, Patrick R. Veres, Jeff Peischl, Steven S. Brown, Allen H. Goldstein, Ronald C. Cohen, and Brian C. McDonald
Atmos. Chem. Phys., 24, 5265–5286, https://doi.org/10.5194/acp-24-5265-2024, https://doi.org/10.5194/acp-24-5265-2024, 2024
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Volatile organic compounds (VOCs) fuel the production of air pollutants like ozone and particulate matter. The representation of VOC chemistry remains challenging due to its complexity in speciation and reactions. Here, we develop a chemical mechanism, RACM2B-VCP, that better represents VOC chemistry in urban areas such as Los Angeles. We also discuss the contribution of VOCs emitted from volatile chemical products and other anthropogenic sources to total VOC reactivity and O3.
Hannah Nesser, Daniel J. Jacob, Joannes D. Maasakkers, Alba Lorente, Zichong Chen, Xiao Lu, Lu Shen, Zhen Qu, Melissa P. Sulprizio, Margaux Winter, Shuang Ma, A. Anthony Bloom, John R. Worden, Robert N. Stavins, and Cynthia A. Randles
Atmos. Chem. Phys., 24, 5069–5091, https://doi.org/10.5194/acp-24-5069-2024, https://doi.org/10.5194/acp-24-5069-2024, 2024
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We quantify 2019 methane emissions in the contiguous US (CONUS) at a ≈ 25 km × 25 km resolution using satellite methane observations. We find a 13 % upward correction to the 2023 US Environmental Protection Agency (EPA) Greenhouse Gas Emissions Inventory (GHGI) for 2019, with large corrections to individual states, urban areas, and landfills. This may present a challenge for US climate policies and goals, many of which target significant reductions in methane emissions.
David de la Paz, Rafael Borge, Juan Manuel de Andrés, Luis Tovar, Golam Sarwar, and Sergey L. Napelenok
Atmos. Chem. Phys., 24, 4949–4972, https://doi.org/10.5194/acp-24-4949-2024, https://doi.org/10.5194/acp-24-4949-2024, 2024
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This source apportionment modeling study shows that around 70 % of ground-level O3 in Madrid (Spain) is transported from other regions. Nonetheless, emissions from local sources, mainly road traffic, play a significant role, especially under atmospheric stagnation. Local measures during those conditions may be able to reduce O3 peaks by up to 30 % and, thus, lessen impacts from high-O3 episodes in the Madrid metropolitan area.
Audrey Fortems-Cheiney, Gregoire Broquet, Elise Potier, Robin Plauchu, Antoine Berchet, Isabelle Pison, Hugo Denier van der Gon, and Stijn Dellaert
Atmos. Chem. Phys., 24, 4635–4649, https://doi.org/10.5194/acp-24-4635-2024, https://doi.org/10.5194/acp-24-4635-2024, 2024
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We have estimated the carbon monixide (CO) European emissions from satellite observations of the MOPITT instrument at the relatively high resolution of 0.5° for a period of over 10 years from 2011 to 2021. The analysis of the inversion results reveals the challenges associated with the inversion of CO emissions at the regional scale over Europe.
Amy Christiansen, Loretta J. Mickley, and Lu Hu
Atmos. Chem. Phys., 24, 4569–4589, https://doi.org/10.5194/acp-24-4569-2024, https://doi.org/10.5194/acp-24-4569-2024, 2024
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In this work, we provide an additional constraint on emissions and trends of nitrogen oxides using nitrate wet deposition (NWD) fluxes over the United States and Europe from 1980–2020. We find that NWD measurements constrain total NOx emissions well. We also find evidence of NOx emission overestimates in both domains, but especially over Europe, where NOx emissions are overestimated by a factor of 2. Reducing NOx emissions over Europe improves model representation of ozone at the surface.
Eduardo Torre-Pascual, Gotzon Gangoiti, Ana Rodríguez-García, Estibaliz Sáez de Cámara, Joana Ferreira, Carla Gama, María Carmen Gómez, Iñaki Zuazo, Jose Antonio García, and Maite de Blas
Atmos. Chem. Phys., 24, 4305–4329, https://doi.org/10.5194/acp-24-4305-2024, https://doi.org/10.5194/acp-24-4305-2024, 2024
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We present an analysis of an intense air pollution episode of tropospheric ozone (O3) along the Atlantic coast of the Iberian Peninsula, incorporating both measured and simulated parameters. Our study extends beyond surface-level factors to include altitude-related parameters. These episodes stem from upper-atmosphere O3 accumulation in preceding days, transported to surface layers, causing rapid O3 concentration increase.
Hannah Chawner, Eric Saboya, Karina E. Adcock, Tim Arnold, Yuri Artioli, Caroline Dylag, Grant L. Forster, Anita Ganesan, Heather Graven, Gennadi Lessin, Peter Levy, Ingrid T. Luijkx, Alistair Manning, Penelope A. Pickers, Chris Rennick, Christian Rödenbeck, and Matthew Rigby
Atmos. Chem. Phys., 24, 4231–4252, https://doi.org/10.5194/acp-24-4231-2024, https://doi.org/10.5194/acp-24-4231-2024, 2024
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The quantity of atmospheric potential oxygen (APO), derived from coincident measurements of carbon dioxide (CO2) and oxygen (O2), has been proposed as a tracer for fossil fuel CO2 emissions. In this model sensitivity study, we examine the use of APO for this purpose in the UK and compare our model to observations. We find that our model simulations are most sensitive to uncertainties relating to ocean fluxes and boundary conditions.
Baoshuang Liu, Yao Gu, Yutong Wu, Qili Dai, Shaojie Song, Yinchang Feng, and Philip K. Hopke
EGUsphere, https://doi.org/10.5194/egusphere-2024-916, https://doi.org/10.5194/egusphere-2024-916, 2024
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Reactive loss of VOCs is a long-term issue yet to be resolved in VOC source analyses. This review assesses the common methods and existing issues of reducing losses, impacts of losses, and sources in current source analyses. We provided a potential supporting role in solving the issues of VOC conversion. Source analyses of consumed VOCs produced by reactions for O3 and secondary organic aerosols can play an important role in effective prevention and control of atmospheric secondary pollution.
Meng Li, Junichi Kurokawa, Qiang Zhang, Jung-Hun Woo, Tazuko Morikawa, Satoru Chatani, Zifeng Lu, Yu Song, Guannan Geng, Hanwen Hu, Jinseok Kim, Owen R. Cooper, and Brian C. McDonald
Atmos. Chem. Phys., 24, 3925–3952, https://doi.org/10.5194/acp-24-3925-2024, https://doi.org/10.5194/acp-24-3925-2024, 2024
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In this work, we developed MIXv2, a mosaic Asian emission inventory for 2010–2017. With high spatial (0.1°) and monthly temporal resolution, MIXv2 integrates anthropogenic and open biomass burning emissions across seven sectors following a mosaic methodology. It provides CO2 emissions data alongside nine key pollutants and three chemical mechanisms. Our publicly accessible gridded monthly emissions data can facilitate long-term atmospheric and climate model analyses.
Jianing Dai, Guy P. Brasseur, Mihalis Vrekoussis, Maria Kanakidou, Kun Qu, Yijuan Zhang, Hongliang Zhang, and Tao Wang
EGUsphere, https://doi.org/10.5194/egusphere-2024-693, https://doi.org/10.5194/egusphere-2024-693, 2024
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This paper employs a regional chemical transport model to quantify the sensitivity of air pollutants and photochemical parameters to specified emission reductions in China for conditions of winter and summer as representative. The study provides insights into the further air quality control in China with reduced primary emissions.
Christopher Lawrence, Mary Barth, John Orlando, Paul Casson, Richard Brandt, Daniel Kelting, Elizabeth Yerger, and Sara Lance
EGUsphere, https://doi.org/10.5194/egusphere-2024-715, https://doi.org/10.5194/egusphere-2024-715, 2024
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This work uses WRF-Chem and chemical box modeling to study the gas and aqueous phase production of organic acid concentrations measured in cloud water the summit of Whiteface Mountain on July 1st, 2018. Isoprene was the major source of formic, acetic, and oxalic acid. Gas phase chemistry greatly underestimated formic and acetic acid, indicating missing sources, while cloud chemistry was a key source of oxalic acid. More studies of organic acids are required to better constrain their sources.
Cited articles
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Short summary
We investigate the contribution of land transport emissions to ozone and ozone precursors in Europe and Germany. Our results show that land transport emissions are one of the most important contributors to reactive nitrogen in Europe. The contribution to ozone is in the range of 8 % to 16 % and varies strongly for different seasons. The hots-pots with the largest ozone concentrations are the Po Valley, while the largest concentration to reactive nitrogen is located mainly in western Europe.
We investigate the contribution of land transport emissions to ozone and ozone precursors in...
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