Articles | Volume 18, issue 23
https://doi.org/10.5194/acp-18-17497-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-18-17497-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
11 Dec 2018
Research article |
| 11 Dec 2018
| 11 Dec 2018
Activation of intact bacteria and bacterial fragments mixed with agar as cloud droplets and ice crystals in cloud chamber experiments
Kaitlyn J. Suski
Pacific Northwest National Laboratory, Richland, WA, USA
David M. Bell
Pacific Northwest National Laboratory, Richland, WA, USA
currently at: Paul Scherrer Institute, Villigen, Switzerland
Naruki Hiranuma
Institute of Meteorology and Climate Research – Atmospheric Aerosol
Research, Karlsruhe Institute of Technology, Karlsruhe, Germany
currently at: Department of Life, Earth and Environmental Sciences,
West Texas A&M University, Canyon, TX, USA
Ottmar Möhler
Institute of Meteorology and Climate Research – Atmospheric Aerosol
Research, Karlsruhe Institute of Technology, Karlsruhe, Germany
Dan Imre
Imre Consulting, Richland, WA, USA
Alla Zelenyuk
CORRESPONDING AUTHOR
Pacific Northwest National Laboratory, Richland, WA, USA
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Guangyu Li, Elise K. Wilbourn, Zezhen Cheng, Jörg Wieder, Allison Fagerson, Jan Henneberger, Ghislain Motos, Rita Traversi, Sarah D. Brooks, Mauro Mazzola, Swarup China, Athanasios Nenes, Ulrike Lohmann, Naruki Hiranuma, and Zamin A. Kanji
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Sophie L. Haslett, David M. Bell, Varun Kumar, Jay G. Slowik, Dongyu S. Wang, Suneeti Mishra, Neeraj Rastogi, Atinderpal Singh, Dilip Ganguly, Joel Thornton, Feixue Zheng, Yuanyuan Li, Wei Nie, Yongchun Liu, Wei Ma, Chao Yan, Markku Kulmala, Kaspar R. Daellenbach, David Hadden, Urs Baltensperger, Andre S. H. Prevot, Sachchida N. Tripathi, and Claudia Mohr
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Emelie L. Graham, Cheng Wu, David M. Bell, Amelie Bertrand, Sophie L. Haslett, Urs Baltensperger, Imad El Haddad, Radovan Krejci, Ilona Riipinen, and Claudia Mohr
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Robert Wagner, Alexander D. James, Victoria L. Frankland, Ottmar Möhler, Benjamin J. Murray, John M. C. Plane, Harald Saathoff, Ralf Weigel, and Martin Schnaiter
Atmos. Chem. Phys., 23, 6789–6811, https://doi.org/10.5194/acp-23-6789-2023, https://doi.org/10.5194/acp-23-6789-2023, 2023
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Lucía Caudillo, Mihnea Surdu, Brandon Lopez, Mingyi Wang, Markus Thoma, Steffen Bräkling, Angela Buchholz, Mario Simon, Andrea C. Wagner, Tatjana Müller, Manuel Granzin, Martin Heinritzi, Antonio Amorim, David M. Bell, Zoé Brasseur, Lubna Dada, Jonathan Duplissy, Henning Finkenzeller, Xu-Cheng He, Houssni Lamkaddam, Naser G. A. Mahfouz, Vladimir Makhmutov, Hanna E. Manninen, Guillaume Marie, Ruby Marten, Roy L. Mauldin, Bernhard Mentler, Antti Onnela, Tuukka Petäjä, Joschka Pfeifer, Maxim Philippov, Ana A. Piedehierro, Birte Rörup, Wiebke Scholz, Jiali Shen, Dominik Stolzenburg, Christian Tauber, Ping Tian, António Tomé, Nsikanabasi Silas Umo, Dongyu S. Wang, Yonghong Wang, Stefan K. Weber, André Welti, Marcel Zauner-Wieczorek, Urs Baltensperger, Richard C. Flagan, Armin Hansel, Jasper Kirkby, Markku Kulmala, Katrianne Lehtipalo, Douglas R. Worsnop, Imad El Haddad, Neil M. Donahue, Alexander L. Vogel, Andreas Kürten, and Joachim Curtius
Atmos. Chem. Phys., 23, 6613–6631, https://doi.org/10.5194/acp-23-6613-2023, https://doi.org/10.5194/acp-23-6613-2023, 2023
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Kara D. Lamb, Jerry Y. Harrington, Benjamin W. Clouser, Elisabeth J. Moyer, Laszlo Sarkozy, Volker Ebert, Ottmar Möhler, and Harald Saathoff
Atmos. Chem. Phys., 23, 6043–6064, https://doi.org/10.5194/acp-23-6043-2023, https://doi.org/10.5194/acp-23-6043-2023, 2023
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Siegfried Schobesberger, Emma L. D'Ambro, Lejish Vettikkat, Ben H. Lee, Qiaoyun Peng, David M. Bell, John E. Shilling, Manish Shrivastava, Mikhail Pekour, Jerome Fast, and Joel A. Thornton
Atmos. Meas. Tech., 16, 247–271, https://doi.org/10.5194/amt-16-247-2023, https://doi.org/10.5194/amt-16-247-2023, 2023
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We present a new, highly sensitive technique for measuring atmospheric ammonia, an important trace gas that is emitted mainly by agriculture. We deployed the instrument on an aircraft during research flights over rural Oklahoma. Due to its fast response, we could analyze correlations with turbulent winds and calculate ammonia emissions from nearby areas at 1 to 2 km resolution. We observed high spatial variability and point sources that are not resolved in the US National Emissions Inventory.
David M. Bell, Cheng Wu, Amelie Bertrand, Emelie Graham, Janne Schoonbaert, Stamatios Giannoukos, Urs Baltensperger, Andre S. H. Prevot, Ilona Riipinen, Imad El Haddad, and Claudia Mohr
Atmos. Chem. Phys., 22, 13167–13182, https://doi.org/10.5194/acp-22-13167-2022, https://doi.org/10.5194/acp-22-13167-2022, 2022
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Outi Meinander, Pavla Dagsson-Waldhauserova, Pavel Amosov, Elena Aseyeva, Cliff Atkins, Alexander Baklanov, Clarissa Baldo, Sarah L. Barr, Barbara Barzycka, Liane G. Benning, Bojan Cvetkovic, Polina Enchilik, Denis Frolov, Santiago Gassó, Konrad Kandler, Nikolay Kasimov, Jan Kavan, James King, Tatyana Koroleva, Viktoria Krupskaya, Markku Kulmala, Monika Kusiak, Hanna K. Lappalainen, Michał Laska, Jerome Lasne, Marek Lewandowski, Bartłomiej Luks, James B. McQuaid, Beatrice Moroni, Benjamin Murray, Ottmar Möhler, Adam Nawrot, Slobodan Nickovic, Norman T. O’Neill, Goran Pejanovic, Olga Popovicheva, Keyvan Ranjbar, Manolis Romanias, Olga Samonova, Alberto Sanchez-Marroquin, Kerstin Schepanski, Ivan Semenkov, Anna Sharapova, Elena Shevnina, Zongbo Shi, Mikhail Sofiev, Frédéric Thevenet, Throstur Thorsteinsson, Mikhail Timofeev, Nsikanabasi Silas Umo, Andreas Uppstu, Darya Urupina, György Varga, Tomasz Werner, Olafur Arnalds, and Ana Vukovic Vimic
Atmos. Chem. Phys., 22, 11889–11930, https://doi.org/10.5194/acp-22-11889-2022, https://doi.org/10.5194/acp-22-11889-2022, 2022
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High-latitude dust (HLD) is a short-lived climate forcer, air pollutant, and nutrient source. Our results suggest a northern HLD belt at 50–58° N in Eurasia and 50–55° N in Canada and at >60° N in Eurasia and >58° N in Canada. Our addition to the previously identified global dust belt (GDB) provides crucially needed information on the extent of active HLD sources with both direct and indirect impacts on climate and environment in remote regions, which are often poorly understood and predicted.
Jerome D. Fast, David M. Bell, Gourihar Kulkarni, Jiumeng Liu, Fan Mei, Georges Saliba, John E. Shilling, Kaitlyn Suski, Jason Tomlinson, Jian Wang, Rahul Zaveri, and Alla Zelenyuk
Atmos. Chem. Phys., 22, 11217–11238, https://doi.org/10.5194/acp-22-11217-2022, https://doi.org/10.5194/acp-22-11217-2022, 2022
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Recent aircraft measurements from the HI-SCALE campaign conducted over the Southern Great Plains (SGP) site in Oklahoma are used to quantify spatial variability of aerosol properties in terms of grid spacings typically used by weather and climate models. Surprisingly large horizontal gradients in aerosol properties were frequently observed in this rural area. This spatial variability can be used as an uncertainty range when comparing surface point measurements with model predictions.
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Real-time detection of both the gas and particle phase is needed to elucidate the sources and chemical reaction pathways of organic vapors and particulate matter. The Dual-EESI was developed to measure gas- and particle-phase species to provide new insights into aerosol sources or formation mechanisms. After characterizing the relative gas and particle response factors of EESI via organic aerosol uptake experiments, the Dual-EESI is more sensitive toward gas-phase analyes.
Varun Kumar, Stamatios Giannoukos, Sophie L. Haslett, Yandong Tong, Atinderpal Singh, Amelie Bertrand, Chuan Ping Lee, Dongyu S. Wang, Deepika Bhattu, Giulia Stefenelli, Jay S. Dave, Joseph V. Puthussery, Lu Qi, Pawan Vats, Pragati Rai, Roberto Casotto, Rangu Satish, Suneeti Mishra, Veronika Pospisilova, Claudia Mohr, David M. Bell, Dilip Ganguly, Vishal Verma, Neeraj Rastogi, Urs Baltensperger, Sachchida N. Tripathi, André S. H. Prévôt, and Jay G. Slowik
Atmos. Chem. Phys., 22, 7739–7761, https://doi.org/10.5194/acp-22-7739-2022, https://doi.org/10.5194/acp-22-7739-2022, 2022
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Here we present source apportionment results from the first field deployment in Delhi of an extractive electrospray ionization time-of-flight mass spectrometer (EESI-TOF). The EESI-TOF is a recently developed instrument capable of providing uniquely detailed online chemical characterization of organic aerosol (OA), in particular the secondary OA (SOA) fraction. Here, we are able to apportion not only primary OA but also SOA to specific sources, which is performed for the first time in Delhi.
Zoé Brasseur, Dimitri Castarède, Erik S. Thomson, Michael P. Adams, Saskia Drossaart van Dusseldorp, Paavo Heikkilä, Kimmo Korhonen, Janne Lampilahti, Mikhail Paramonov, Julia Schneider, Franziska Vogel, Yusheng Wu, Jonathan P. D. Abbatt, Nina S. Atanasova, Dennis H. Bamford, Barbara Bertozzi, Matthew Boyer, David Brus, Martin I. Daily, Romy Fösig, Ellen Gute, Alexander D. Harrison, Paula Hietala, Kristina Höhler, Zamin A. Kanji, Jorma Keskinen, Larissa Lacher, Markus Lampimäki, Janne Levula, Antti Manninen, Jens Nadolny, Maija Peltola, Grace C. E. Porter, Pyry Poutanen, Ulrike Proske, Tobias Schorr, Nsikanabasi Silas Umo, János Stenszky, Annele Virtanen, Dmitri Moisseev, Markku Kulmala, Benjamin J. Murray, Tuukka Petäjä, Ottmar Möhler, and Jonathan Duplissy
Atmos. Chem. Phys., 22, 5117–5145, https://doi.org/10.5194/acp-22-5117-2022, https://doi.org/10.5194/acp-22-5117-2022, 2022
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The present measurement report introduces the ice nucleation campaign organized in Hyytiälä, Finland, in 2018 (HyICE-2018). We provide an overview of the campaign settings, and we describe the measurement infrastructure and operating procedures used. In addition, we use results from ice nucleation instrument inter-comparison to show that the suite of these instruments deployed during the campaign reports consistent results.
Manuel Baumgartner, Christian Rolf, Jens-Uwe Grooß, Julia Schneider, Tobias Schorr, Ottmar Möhler, Peter Spichtinger, and Martina Krämer
Atmos. Chem. Phys., 22, 65–91, https://doi.org/10.5194/acp-22-65-2022, https://doi.org/10.5194/acp-22-65-2022, 2022
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An important mechanism for the appearance of ice particles in the upper troposphere at low temperatures is homogeneous nucleation. This process is commonly described by the
Koop line, predicting the humidity at freezing. However, laboratory measurements suggest that the freezing humidities are above the Koop line, motivating the present study to investigate the influence of different physical parameterizations on the homogeneous freezing with the help of a detailed numerical model.
Lucía Caudillo, Birte Rörup, Martin Heinritzi, Guillaume Marie, Mario Simon, Andrea C. Wagner, Tatjana Müller, Manuel Granzin, Antonio Amorim, Farnoush Ataei, Rima Baalbaki, Barbara Bertozzi, Zoé Brasseur, Randall Chiu, Biwu Chu, Lubna Dada, Jonathan Duplissy, Henning Finkenzeller, Loïc Gonzalez Carracedo, Xu-Cheng He, Victoria Hofbauer, Weimeng Kong, Houssni Lamkaddam, Chuan P. Lee, Brandon Lopez, Naser G. A. Mahfouz, Vladimir Makhmutov, Hanna E. Manninen, Ruby Marten, Dario Massabò, Roy L. Mauldin, Bernhard Mentler, Ugo Molteni, Antti Onnela, Joschka Pfeifer, Maxim Philippov, Ana A. Piedehierro, Meredith Schervish, Wiebke Scholz, Benjamin Schulze, Jiali Shen, Dominik Stolzenburg, Yuri Stozhkov, Mihnea Surdu, Christian Tauber, Yee Jun Tham, Ping Tian, António Tomé, Steffen Vogt, Mingyi Wang, Dongyu S. Wang, Stefan K. Weber, André Welti, Wang Yonghong, Wu Yusheng, Marcel Zauner-Wieczorek, Urs Baltensperger, Imad El Haddad, Richard C. Flagan, Armin Hansel, Kristina Höhler, Jasper Kirkby, Markku Kulmala, Katrianne Lehtipalo, Ottmar Möhler, Harald Saathoff, Rainer Volkamer, Paul M. Winkler, Neil M. Donahue, Andreas Kürten, and Joachim Curtius
Atmos. Chem. Phys., 21, 17099–17114, https://doi.org/10.5194/acp-21-17099-2021, https://doi.org/10.5194/acp-21-17099-2021, 2021
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We performed experiments in the CLOUD chamber at CERN at low temperatures to simulate new particle formation in the upper free troposphere (at −30 ºC and −50 ºC). We measured the particle and gas phase and found that most of the compounds present in the gas phase are detected as well in the particle phase. The major compounds in the particles are C8–10 and C18–20. Specifically, we showed that C5 and C15 compounds are detected in a mixed system with isoprene and α-pinene at −30 ºC, 20 % RH.
Larissa Lacher, Hans-Christian Clemen, Xiaoli Shen, Stephan Mertes, Martin Gysel-Beer, Alireza Moallemi, Martin Steinbacher, Stephan Henne, Harald Saathoff, Ottmar Möhler, Kristina Höhler, Thea Schiebel, Daniel Weber, Jann Schrod, Johannes Schneider, and Zamin A. Kanji
Atmos. Chem. Phys., 21, 16925–16953, https://doi.org/10.5194/acp-21-16925-2021, https://doi.org/10.5194/acp-21-16925-2021, 2021
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We investigate ice-nucleating particle properties at Jungfraujoch during the 2017 joint INUIT/CLACE field campaign, to improve the knowledge about those rare particles in a cloud-relevant environment. By quantifying ice-nucleating particles in parallel to single-particle mass spectrometry measurements, we find that mineral dust and aged sea spray particles are potential candidates for ice-nucleating particles. Our findings are supported by ice residual analysis and source region modeling.
Dongyu S. Wang, Chuan Ping Lee, Jordan E. Krechmer, Francesca Majluf, Yandong Tong, Manjula R. Canagaratna, Julia Schmale, André S. H. Prévôt, Urs Baltensperger, Josef Dommen, Imad El Haddad, Jay G. Slowik, and David M. Bell
Atmos. Meas. Tech., 14, 6955–6972, https://doi.org/10.5194/amt-14-6955-2021, https://doi.org/10.5194/amt-14-6955-2021, 2021
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To understand the sources and fate of particulate matter in the atmosphere, the ability to quantitatively describe its chemical composition is essential. In this work, we developed a calibration method for a state-of-the-art measurement technique without the need for chemical standards. Statistical analyses identified the driving factors behind instrument sensitivity variability towards individual components of particulate matter.
Cheng Wu, David M. Bell, Emelie L. Graham, Sophie Haslett, Ilona Riipinen, Urs Baltensperger, Amelie Bertrand, Stamatios Giannoukos, Janne Schoonbaert, Imad El Haddad, Andre S. H. Prevot, Wei Huang, and Claudia Mohr
Atmos. Chem. Phys., 21, 14907–14925, https://doi.org/10.5194/acp-21-14907-2021, https://doi.org/10.5194/acp-21-14907-2021, 2021
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Night-time reactions of biogenic volatile organic compounds and nitrate radicals can lead to the formation of secondary organic aerosol (BSOANO3). Here, we study the impacts of light exposure on the BSOANO3 from three biogenic precursors. Our results suggest that photolysis causes photodegradation of a substantial fraction of BSOANO3, changes the chemical composition and bulk volatility, and might be a potentially important loss pathway of BSOANO3 during the night-to-day transition.
Matteo Rinaldi, Naruki Hiranuma, Gianni Santachiara, Mauro Mazzola, Karam Mansour, Marco Paglione, Cheyanne A. Rodriguez, Rita Traversi, Silvia Becagli, David Cappelletti, and Franco Belosi
Atmos. Chem. Phys., 21, 14725–14748, https://doi.org/10.5194/acp-21-14725-2021, https://doi.org/10.5194/acp-21-14725-2021, 2021
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This study aims to add to the still scant ice-nucleating particle (INP) observations in the Arctic environment, investigating INP concentrations and potential sources, during spring and summertime, at the ground-level site of GVB. The lack of a clear concentration seasonal trend, in contrast with previous works, shows an important interannual variability of Arctic INP sources, which may be both terrestrial and marine, outside the Arctic haze period.
Haoran Li, Ottmar Möhler, Tuukka Petäjä, and Dmitri Moisseev
Atmos. Chem. Phys., 21, 14671–14686, https://doi.org/10.5194/acp-21-14671-2021, https://doi.org/10.5194/acp-21-14671-2021, 2021
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In natural clouds, ice-nucleating particles are expected to be rare above –10 °C. In the current paper, we found that the formation of ice columns is frequent in stratiform clouds and is associated with increased precipitation intensity and liquid water path. In single-layer shallow clouds, the production of ice columns was attributed to secondary ice production, despite the rime-splintering process not being expected to take place in such clouds.
Julia Schneider, Kristina Höhler, Robert Wagner, Harald Saathoff, Martin Schnaiter, Tobias Schorr, Isabelle Steinke, Stefan Benz, Manuel Baumgartner, Christian Rolf, Martina Krämer, Thomas Leisner, and Ottmar Möhler
Atmos. Chem. Phys., 21, 14403–14425, https://doi.org/10.5194/acp-21-14403-2021, https://doi.org/10.5194/acp-21-14403-2021, 2021
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Homogeneous freezing is a relevant mechanism for the formation of cirrus clouds in the upper troposphere. Based on an extensive set of homogeneous freezing experiments at the AIDA chamber with aqueous sulfuric acid aerosol, we provide a new fit line for homogeneous freezing onset conditions of sulfuric acid aerosol focusing on cirrus temperatures. In the atmosphere, homogeneous freezing thresholds have important implications on the cirrus cloud occurrence and related cloud radiative effects.
Mao Xiao, Christopher R. Hoyle, Lubna Dada, Dominik Stolzenburg, Andreas Kürten, Mingyi Wang, Houssni Lamkaddam, Olga Garmash, Bernhard Mentler, Ugo Molteni, Andrea Baccarini, Mario Simon, Xu-Cheng He, Katrianne Lehtipalo, Lauri R. Ahonen, Rima Baalbaki, Paulus S. Bauer, Lisa Beck, David Bell, Federico Bianchi, Sophia Brilke, Dexian Chen, Randall Chiu, António Dias, Jonathan Duplissy, Henning Finkenzeller, Hamish Gordon, Victoria Hofbauer, Changhyuk Kim, Theodore K. Koenig, Janne Lampilahti, Chuan Ping Lee, Zijun Li, Huajun Mai, Vladimir Makhmutov, Hanna E. Manninen, Ruby Marten, Serge Mathot, Roy L. Mauldin, Wei Nie, Antti Onnela, Eva Partoll, Tuukka Petäjä, Joschka Pfeifer, Veronika Pospisilova, Lauriane L. J. Quéléver, Matti Rissanen, Siegfried Schobesberger, Simone Schuchmann, Yuri Stozhkov, Christian Tauber, Yee Jun Tham, António Tomé, Miguel Vazquez-Pufleau, Andrea C. Wagner, Robert Wagner, Yonghong Wang, Lena Weitz, Daniela Wimmer, Yusheng Wu, Chao Yan, Penglin Ye, Qing Ye, Qiaozhi Zha, Xueqin Zhou, Antonio Amorim, Ken Carslaw, Joachim Curtius, Armin Hansel, Rainer Volkamer, Paul M. Winkler, Richard C. Flagan, Markku Kulmala, Douglas R. Worsnop, Jasper Kirkby, Neil M. Donahue, Urs Baltensperger, Imad El Haddad, and Josef Dommen
Atmos. Chem. Phys., 21, 14275–14291, https://doi.org/10.5194/acp-21-14275-2021, https://doi.org/10.5194/acp-21-14275-2021, 2021
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Experiments at CLOUD show that in polluted environments new particle formation (NPF) is largely driven by the formation of sulfuric acid–base clusters, stabilized by amines, high ammonia concentrations or lower temperatures. While oxidation products of aromatics can nucleate, they play a minor role in urban NPF. Our experiments span 4 orders of magnitude variation of observed NPF rates in ambient conditions. We provide a framework based on NPF and growth rates to interpret ambient observations.
Naruki Hiranuma, Brent W. Auvermann, Franco Belosi, Jack Bush, Kimberly M. Cory, Dimitrios G. Georgakopoulos, Kristina Höhler, Yidi Hou, Larissa Lacher, Harald Saathoff, Gianni Santachiara, Xiaoli Shen, Isabelle Steinke, Romy Ullrich, Nsikanabasi S. Umo, Hemanth S. K. Vepuri, Franziska Vogel, and Ottmar Möhler
Atmos. Chem. Phys., 21, 14215–14234, https://doi.org/10.5194/acp-21-14215-2021, https://doi.org/10.5194/acp-21-14215-2021, 2021
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We present laboratory and field studies showing that an open-lot livestock facility is a substantial source of atmospheric ice-nucleating particles (INPs). The ambient concentration of INPs from livestock facilities in Texas is very high. It is up to several thousand INPs per liter below –20 °C and may impact regional aerosol–cloud interactions. About 50% of feedlot INPs were supermicron in diameter. No notable amount of known ice-nucleating microorganisms was found in our feedlot samples.
Robert Wagner, Luisa Ickes, Allan K. Bertram, Nora Els, Elena Gorokhova, Ottmar Möhler, Benjamin J. Murray, Nsikanabasi Silas Umo, and Matthew E. Salter
Atmos. Chem. Phys., 21, 13903–13930, https://doi.org/10.5194/acp-21-13903-2021, https://doi.org/10.5194/acp-21-13903-2021, 2021
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Sea spray aerosol particles are a mixture of inorganic salts and organic matter from phytoplankton organisms. At low temperatures in the upper troposphere, both inorganic and organic constituents can induce the formation of ice crystals and thereby impact cloud properties and climate. In this study, we performed experiments in a cloud simulation chamber with particles produced from Arctic seawater samples to quantify the relative contribution of inorganic and organic species in ice formation.
Chuan Ping Lee, Mihnea Surdu, David M. Bell, Houssni Lamkaddam, Mingyi Wang, Farnoush Ataei, Victoria Hofbauer, Brandon Lopez, Neil M. Donahue, Josef Dommen, Andre S. H. Prevot, Jay G. Slowik, Dongyu Wang, Urs Baltensperger, and Imad El Haddad
Atmos. Meas. Tech., 14, 5913–5923, https://doi.org/10.5194/amt-14-5913-2021, https://doi.org/10.5194/amt-14-5913-2021, 2021
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Extractive electrospray ionization mass spectrometry (EESI-MS) has been deployed for high throughput online detection of particles with minimal fragmentation. Our study elucidates the extraction mechanism between the particles and electrospray (ES) droplets of different properties. The results show that the extraction rate is likely affected by the coagulation rate between the particles and ES droplets. Once coagulated, the particles undergo complete extraction within the ES droplet.
Barbara Bertozzi, Robert Wagner, Junwei Song, Kristina Höhler, Joschka Pfeifer, Harald Saathoff, Thomas Leisner, and Ottmar Möhler
Atmos. Chem. Phys., 21, 10779–10798, https://doi.org/10.5194/acp-21-10779-2021, https://doi.org/10.5194/acp-21-10779-2021, 2021
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Internally mixed particles composed of sulfate and organics are among the most abundant aerosol types. Their ice nucleation (IN) ability influences the formation of cirrus and, thus, the climate. We show that the presence of a thin organic coating suppresses the heterogeneous IN ability of crystalline ammonium sulfate particles. However, the IN ability of the same particle can substantially change if subjected to atmospheric processing, mainly due to differences in the resulting morphology.
Hemanth S. K. Vepuri, Cheyanne A. Rodriguez, Dimitrios G. Georgakopoulos, Dustin Hume, James Webb, Gregory D. Mayer, and Naruki Hiranuma
Atmos. Chem. Phys., 21, 4503–4520, https://doi.org/10.5194/acp-21-4503-2021, https://doi.org/10.5194/acp-21-4503-2021, 2021
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Due to a high frequency of storm events, West Texas is an ideal location to study ice-nucleating particles (INPs) in severe precipitation. Our results present that cumulative INP concentration in our precipitation samples below −20 °C could be high in the samples collected while observing > 10 mm h−1 precipitation with notably large hydrometeor sizes and an implication of cattle feedyard bacteria inclusion. Marine bacteria were found in a subset of our precipitation and cattle feedyard samples.
Julia Schneider, Kristina Höhler, Paavo Heikkilä, Jorma Keskinen, Barbara Bertozzi, Pia Bogert, Tobias Schorr, Nsikanabasi Silas Umo, Franziska Vogel, Zoé Brasseur, Yusheng Wu, Simo Hakala, Jonathan Duplissy, Dmitri Moisseev, Markku Kulmala, Michael P. Adams, Benjamin J. Murray, Kimmo Korhonen, Liqing Hao, Erik S. Thomson, Dimitri Castarède, Thomas Leisner, Tuukka Petäjä, and Ottmar Möhler
Atmos. Chem. Phys., 21, 3899–3918, https://doi.org/10.5194/acp-21-3899-2021, https://doi.org/10.5194/acp-21-3899-2021, 2021
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By triggering the formation of ice crystals, ice-nucleating particles (INP) strongly influence cloud formation. Continuous, long-term measurements are needed to characterize the atmospheric INP variability. Here, a first long-term time series of INP spectra measured in the boreal forest for more than 1 year is presented, showing a clear seasonal cycle. It is shown that the seasonal dependency of INP concentrations and prevalent INP types is driven by the abundance of biogenic aerosol.
Robert Wagner, Baptiste Testa, Michael Höpfner, Alexei Kiselev, Ottmar Möhler, Harald Saathoff, Jörn Ungermann, and Thomas Leisner
Atmos. Meas. Tech., 14, 1977–1991, https://doi.org/10.5194/amt-14-1977-2021, https://doi.org/10.5194/amt-14-1977-2021, 2021
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During the Asian summer monsoon period, air pollutants are transported from layers near the ground to high altitudes of 13 to 18 km in the atmosphere. Infrared measurements have shown that particles composed of solid ammonium nitrate are a major part of these pollutants. To enable the quantitative analysis of the infrared spectra, we have determined for the first time accurate optical constants of ammonium nitrate for the low-temperature conditions of the upper atmosphere.
Ottmar Möhler, Michael Adams, Larissa Lacher, Franziska Vogel, Jens Nadolny, Romy Ullrich, Cristian Boffo, Tatjana Pfeuffer, Achim Hobl, Maximilian Weiß, Hemanth S. K. Vepuri, Naruki Hiranuma, and Benjamin J. Murray
Atmos. Meas. Tech., 14, 1143–1166, https://doi.org/10.5194/amt-14-1143-2021, https://doi.org/10.5194/amt-14-1143-2021, 2021
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The Earth's climate is influenced by clouds, which are impacted by ice-nucleating particles (INPs), a minor fraction of atmospheric aerosols. INPs induce ice formation in clouds and thus often initiate precipitation formation. The Portable Ice Nucleation Experiment (PINE) is the first fully automated instrument to study cloud ice formation and to obtain long-term records of INPs. This is a timely development, and the capabilities it offers for research and atmospheric monitoring are significant.
Gourihar Kulkarni, Naruki Hiranuma, Ottmar Möhler, Kristina Höhler, Swarup China, Daniel J. Cziczo, and Paul J. DeMott
Atmos. Meas. Tech., 13, 6631–6643, https://doi.org/10.5194/amt-13-6631-2020, https://doi.org/10.5194/amt-13-6631-2020, 2020
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This study presents a new continuous-flow-diffusion-chamber-style operated ice chamber (Modified Compact Ice Chamber, MCIC) to measure the immersion-freezing efficiency of atmospheric particles. MCIC allowed us to obtain maximum droplet-freezing efficiency at higher time resolution without droplet breakthrough ambiguity. Its evaluation was performed by reproducing published data from the recent ice nucleation workshop and past laboratory data for standard and airborne ice-nucleating particles.
Isabelle Steinke, Naruki Hiranuma, Roger Funk, Kristina Höhler, Nadine Tüllmann, Nsikanabasi Silas Umo, Peter G. Weidler, Ottmar Möhler, and Thomas Leisner
Atmos. Chem. Phys., 20, 11387–11397, https://doi.org/10.5194/acp-20-11387-2020, https://doi.org/10.5194/acp-20-11387-2020, 2020
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In this study, we highlight the potential impact of particles from certain terrestrial sources on the formation of ice crystals in clouds. In particular, we focus on biogenic particles consisting of various organic compounds, which makes it very difficult to predict the ice nucleation properties of complex ambient particles. We find that these ambient particles are often more ice active than individual components.
Luisa Ickes, Grace C. E. Porter, Robert Wagner, Michael P. Adams, Sascha Bierbauer, Allan K. Bertram, Merete Bilde, Sigurd Christiansen, Annica M. L. Ekman, Elena Gorokhova, Kristina Höhler, Alexei A. Kiselev, Caroline Leck, Ottmar Möhler, Benjamin J. Murray, Thea Schiebel, Romy Ullrich, and Matthew E. Salter
Atmos. Chem. Phys., 20, 11089–11117, https://doi.org/10.5194/acp-20-11089-2020, https://doi.org/10.5194/acp-20-11089-2020, 2020
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The Arctic is a region where aerosols are scarce. Sea spray might be a potential source of aerosols acting as ice-nucleating particles. We investigate two common phytoplankton species (Melosira arctica and Skeletonema marinoi) and present their ice nucleation activity in comparison with Arctic seawater microlayer samples from different field campaigns. We also aim to understand the aerosolization process of marine biological samples and the potential effect on the ice nucleation activity.
Benjamin W. Clouser, Kara D. Lamb, Laszlo C. Sarkozy, Jan Habig, Volker Ebert, Harald Saathoff, Ottmar Möhler, and Elisabeth J. Moyer
Atmos. Chem. Phys., 20, 1089–1103, https://doi.org/10.5194/acp-20-1089-2020, https://doi.org/10.5194/acp-20-1089-2020, 2020
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Previous measurements of water vapor in the upper troposphere and lower stratosphere (UT/LS) have shown unexpectedly high concentrations of water vapor in ice clouds, which may be due to an incomplete understanding of the structure of ice and the behavior of ice growth in this part of the atmosphere. Water vapor measurements during the 2013 IsoCloud campaign at the AIDA cloud chamber show no evidence of this
anomalous supersaturationin conditions similar to the real atmosphere.
Emma L. D'Ambro, Siegfried Schobesberger, Cassandra J. Gaston, Felipe D. Lopez-Hilfiker, Ben H. Lee, Jiumeng Liu, Alla Zelenyuk, David Bell, Christopher D. Cappa, Taylor Helgestad, Ziyue Li, Alex Guenther, Jian Wang, Matthew Wise, Ryan Caylor, Jason D. Surratt, Theran Riedel, Noora Hyttinen, Vili-Taneli Salo, Galib Hasan, Theo Kurtén, John E. Shilling, and Joel A. Thornton
Atmos. Chem. Phys., 19, 11253–11265, https://doi.org/10.5194/acp-19-11253-2019, https://doi.org/10.5194/acp-19-11253-2019, 2019
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Isoprene is the most abundantly emitted reactive organic gas globally, and thus it is important to understand its fate and role in aerosol formation and growth. A major product of its oxidation is an epoxydiol, IEPOX, which can be efficiently taken up by acidic aerosol to generate substantial amounts of secondary organic aerosol (SOA). We present chamber experiments exploring the properties of IEPOX SOA and reconcile discrepancies between field, laboratory, and model studies of this process.
Xianda Gong, Heike Wex, Thomas Müller, Alfred Wiedensohler, Kristina Höhler, Konrad Kandler, Nan Ma, Barbara Dietel, Thea Schiebel, Ottmar Möhler, and Frank Stratmann
Atmos. Chem. Phys., 19, 10883–10900, https://doi.org/10.5194/acp-19-10883-2019, https://doi.org/10.5194/acp-19-10883-2019, 2019
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For the diverse aerosol on Cyprus, we found the following: new particle formation can be a source of cloud condensation nuclei. Particle hygroscopicity showed that particles ~<100 nm contained mostly organic material, while larger ones were more hygroscopic. Two separate methods obtained similar concentrations of ice-nucleating particles (INP), with mostly no evidence of a local origin. Different parameterizations overestimated INP concentration in this rather polluted region.
Nsikanabasi Silas Umo, Robert Wagner, Romy Ullrich, Alexei Kiselev, Harald Saathoff, Peter G. Weidler, Daniel J. Cziczo, Thomas Leisner, and Ottmar Möhler
Atmos. Chem. Phys., 19, 8783–8800, https://doi.org/10.5194/acp-19-8783-2019, https://doi.org/10.5194/acp-19-8783-2019, 2019
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Annually, over 600 Tg of coal fly ash (CFA) is produced; a significant proportion of this amount is injected into the atmosphere, which could significantly contribute to heterogeneous ice formation in clouds. This study presents an improved understanding of CFA particles' behaviour in forming ice in clouds, especially when exposed to lower temperatures before being re-circulated in the upper troposphere or entrained into the lower troposphere.
Zamin A. Kanji, Ryan C. Sullivan, Monika Niemand, Paul J. DeMott, Anthony J. Prenni, Cédric Chou, Harald Saathoff, and Ottmar Möhler
Atmos. Chem. Phys., 19, 5091–5110, https://doi.org/10.5194/acp-19-5091-2019, https://doi.org/10.5194/acp-19-5091-2019, 2019
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The ice nucleation ability of two natural desert dusts coated with a proxy of secondary organic aerosol is presented for temperatures and relative humidity conditions relevant for mixed-phase clouds. We find that at the tested conditions, there is no effect on the ice nucleation ability of the particles due to the organic coating. Furthermore, the two dust samples do not show variability within measurement uncertainty. Particle size and surface area may play a role in any difference observed.
Naruki Hiranuma, Kouji Adachi, David M. Bell, Franco Belosi, Hassan Beydoun, Bhaskar Bhaduri, Heinz Bingemer, Carsten Budke, Hans-Christian Clemen, Franz Conen, Kimberly M. Cory, Joachim Curtius, Paul J. DeMott, Oliver Eppers, Sarah Grawe, Susan Hartmann, Nadine Hoffmann, Kristina Höhler, Evelyn Jantsch, Alexei Kiselev, Thomas Koop, Gourihar Kulkarni, Amelie Mayer, Masataka Murakami, Benjamin J. Murray, Alessia Nicosia, Markus D. Petters, Matteo Piazza, Michael Polen, Naama Reicher, Yinon Rudich, Atsushi Saito, Gianni Santachiara, Thea Schiebel, Gregg P. Schill, Johannes Schneider, Lior Segev, Emiliano Stopelli, Ryan C. Sullivan, Kaitlyn Suski, Miklós Szakáll, Takuya Tajiri, Hans Taylor, Yutaka Tobo, Romy Ullrich, Daniel Weber, Heike Wex, Thomas F. Whale, Craig L. Whiteside, Katsuya Yamashita, Alla Zelenyuk, and Ottmar Möhler
Atmos. Chem. Phys., 19, 4823–4849, https://doi.org/10.5194/acp-19-4823-2019, https://doi.org/10.5194/acp-19-4823-2019, 2019
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A total of 20 ice nucleation measurement techniques contributed to investigate the immersion freezing behavior of cellulose particles – natural polymers. Our data showed several types of cellulose are able to nucleate ice as efficiently as some mineral dust samples and cellulose has the potential to be an important atmospheric ice-nucleating particle. Continued investigation/collaboration is necessary to obtain further insight into consistency or diversity of ice nucleation measurements.
Nicholas A. Marsden, Romy Ullrich, Ottmar Möhler, Stine Eriksen Hammer, Konrad Kandler, Zhiqiang Cui, Paul I. Williams, Michael J. Flynn, Dantong Liu, James D. Allan, and Hugh Coe
Atmos. Chem. Phys., 19, 2259–2281, https://doi.org/10.5194/acp-19-2259-2019, https://doi.org/10.5194/acp-19-2259-2019, 2019
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The composition of airborne dust influences climate and ecosystems but its measurements presents a huge analytical challenge. Using online single-particle mass spectrometry, we demonstrate differences in mineralogy and mixing state can be detected in real time in both laboratory studies and ambient measurements. The results provide insights into the temporal and spatial evolution of dust properties that will be useful for aerosol–cloud interaction studies and dust cycle modelling.
Jian Wang, John E. Shilling, Jiumeng Liu, Alla Zelenyuk, David M. Bell, Markus D. Petters, Ryan Thalman, Fan Mei, Rahul A. Zaveri, and Guangjie Zheng
Atmos. Chem. Phys., 19, 941–954, https://doi.org/10.5194/acp-19-941-2019, https://doi.org/10.5194/acp-19-941-2019, 2019
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Earlier studies showed organic hygroscopicity increases with oxidation level. Such increases have been attributed to higher water solubility for more oxidized organics. By systematically varying the water content of activating droplets, we show that for secondary organic aerosols, essentially all organics are dissolved at the point of droplet activation. Therefore, the organic hygroscopicity is not limited by solubility but is dictated mainly by the molecular weight of organic species.
Paul J. DeMott, Ottmar Möhler, Daniel J. Cziczo, Naruki Hiranuma, Markus D. Petters, Sarah S. Petters, Franco Belosi, Heinz G. Bingemer, Sarah D. Brooks, Carsten Budke, Monika Burkert-Kohn, Kristen N. Collier, Anja Danielczok, Oliver Eppers, Laura Felgitsch, Sarvesh Garimella, Hinrich Grothe, Paul Herenz, Thomas C. J. Hill, Kristina Höhler, Zamin A. Kanji, Alexei Kiselev, Thomas Koop, Thomas B. Kristensen, Konstantin Krüger, Gourihar Kulkarni, Ezra J. T. Levin, Benjamin J. Murray, Alessia Nicosia, Daniel O'Sullivan, Andreas Peckhaus, Michael J. Polen, Hannah C. Price, Naama Reicher, Daniel A. Rothenberg, Yinon Rudich, Gianni Santachiara, Thea Schiebel, Jann Schrod, Teresa M. Seifried, Frank Stratmann, Ryan C. Sullivan, Kaitlyn J. Suski, Miklós Szakáll, Hans P. Taylor, Romy Ullrich, Jesus Vergara-Temprado, Robert Wagner, Thomas F. Whale, Daniel Weber, André Welti, Theodore W. Wilson, Martin J. Wolf, and Jake Zenker
Atmos. Meas. Tech., 11, 6231–6257, https://doi.org/10.5194/amt-11-6231-2018, https://doi.org/10.5194/amt-11-6231-2018, 2018
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The ability to measure ice nucleating particles is vital to quantifying their role in affecting clouds and precipitation. Methods for measuring droplet freezing were compared while co-sampling relevant particle types. Measurement correspondence was very good for ice nucleating particles of bacterial and natural soil origin, and somewhat more disparate for those of mineral origin. Results reflect recently improved capabilities and provide direction toward addressing remaining measurement issues.
Matthias Hummel, Corinna Hoose, Bernhard Pummer, Caroline Schaupp, Janine Fröhlich-Nowoisky, and Ottmar Möhler
Atmos. Chem. Phys., 18, 15437–15450, https://doi.org/10.5194/acp-18-15437-2018, https://doi.org/10.5194/acp-18-15437-2018, 2018
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How important for clouds is the ability of biological particles to glaciate droplets at little supercooling? In a case study, the regional atmospheric model COSMO–ART is used. Perturbed and control runs are compared.
The number of ice particles that are nucleated by biological particles is highest at around −10 °C. No significant influence on the average state of the cloud ice phase was found. However, the number of ice crystals is slightly enhanced in the absence of other ice nucleators.
Costa D. Christopoulos, Sarvesh Garimella, Maria A. Zawadowicz, Ottmar Möhler, and Daniel J. Cziczo
Atmos. Meas. Tech., 11, 5687–5699, https://doi.org/10.5194/amt-11-5687-2018, https://doi.org/10.5194/amt-11-5687-2018, 2018
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Compositional analysis of atmospheric and laboratory aerosols is often conducted with mass spectrometry. In this study, machine learning is used to automatically differentiate particles on the basis of chemistry and size. The ability of the machine learning algorithm was then tested on a data set for which the particles were not initially known to judge its ability.
Kaitlyn J. Suski, Tom C. J. Hill, Ezra J. T. Levin, Anna Miller, Paul J. DeMott, and Sonia M. Kreidenweis
Atmos. Chem. Phys., 18, 13755–13771, https://doi.org/10.5194/acp-18-13755-2018, https://doi.org/10.5194/acp-18-13755-2018, 2018
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The harvesting of crops emits large amounts of particles into the air. These particles can form and interact with clouds to alter cloud properties and precipitation, but the magnitude of these effects is unknown. This study looked at the ability of harvest particles to form ice in clouds by sampling with an ice nucleation chamber downwind of fields being harvested. Some crops emitted large amounts of ice-nucleating particles, and harvest emissions are mixtures of organics, soil, and minerals.
Jake Zenker, Kristen N. Collier, Guanglang Xu, Ping Yang, Ezra J. T. Levin, Kaitlyn J. Suski, Paul J. DeMott, and Sarah D. Brooks
Atmos. Meas. Tech., 10, 4639–4657, https://doi.org/10.5194/amt-10-4639-2017, https://doi.org/10.5194/amt-10-4639-2017, 2017
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We have developed a new method which employs single particle depolarization to determine ice nucleating particle (INP) concentrations and to differentiate between ice crystals, water droplets, and aerosols. The method is used to interpret measurements collected using the Texas A&M Continuous Flow Diffusion Chamber (TAMU CFDC) coupled to a Cloud and Aerosol Spectrometer with Polarization (CASPOL). This new method extends the range of operating conditions for the CFDC to higher supersaturations.
Leonid Nichman, Emma Järvinen, James Dorsey, Paul Connolly, Jonathan Duplissy, Claudia Fuchs, Karoliina Ignatius, Kamalika Sengupta, Frank Stratmann, Ottmar Möhler, Martin Schnaiter, and Martin Gallagher
Atmos. Meas. Tech., 10, 3231–3248, https://doi.org/10.5194/amt-10-3231-2017, https://doi.org/10.5194/amt-10-3231-2017, 2017
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Optical probes are frequently used for the detection of cloud particles. The detected microphysical properties may affect particle growth and accretion mechanisms and the light scattering properties of cirrus clouds. In the CLOUD chamber study at CERN, we compared four optical measurement techniques. We show that shape derivation alone is not sufficient to determine the phase of the small cloud particles. None of the instruments were able to unambiguously determine the phase of small particles.
Giancarlo Ciarelli, Imad El Haddad, Emily Bruns, Sebnem Aksoyoglu, Ottmar Möhler, Urs Baltensperger, and André S. H. Prévôt
Geosci. Model Dev., 10, 2303–2320, https://doi.org/10.5194/gmd-10-2303-2017, https://doi.org/10.5194/gmd-10-2303-2017, 2017
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In Europe, residential wood-burning emissions constitute one of the main anthropogenic sources of air pollution. Novel wood-burning experiments performed in a state-of-the-art smog chamber provide valuable information on the chemical properties of wood-burning emissions and the transformation in the atmosphere. In this study, these new data were used in a box model to constrain a parameterization suitable for predicting the contribution of wood burning to air pollution with large-scale models.
Naruki Hiranuma, Ottmar Möhler, Gourihar Kulkarni, Martin Schnaiter, Steffen Vogt, Paul Vochezer, Emma Järvinen, Robert Wagner, David M. Bell, Jacqueline Wilson, Alla Zelenyuk, and Daniel J. Cziczo
Atmos. Meas. Tech., 9, 3817–3836, https://doi.org/10.5194/amt-9-3817-2016, https://doi.org/10.5194/amt-9-3817-2016, 2016
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A new pumped counterflow virtual impactor (PCVI) called the ice-selecting PCVI (IS-PCVI) has been developed to collect ice crystal residuals for investigating physico-chemical properties of ice-nucleating particles. The results show that the ice crystals of volume-equivalent diameter ~ 10 to 30 µm can be efficiently separated from the supercooled droplets and interstitial particles. The IS-PCVI is efficient when the counterflow-to-input flow ratio is within 0.09 to 0.18.
Karoliina Ignatius, Thomas B. Kristensen, Emma Järvinen, Leonid Nichman, Claudia Fuchs, Hamish Gordon, Paul Herenz, Christopher R. Hoyle, Jonathan Duplissy, Sarvesh Garimella, Antonio Dias, Carla Frege, Niko Höppel, Jasmin Tröstl, Robert Wagner, Chao Yan, Antonio Amorim, Urs Baltensperger, Joachim Curtius, Neil M. Donahue, Martin W. Gallagher, Jasper Kirkby, Markku Kulmala, Ottmar Möhler, Harald Saathoff, Martin Schnaiter, Antonio Tomé, Annele Virtanen, Douglas Worsnop, and Frank Stratmann
Atmos. Chem. Phys., 16, 6495–6509, https://doi.org/10.5194/acp-16-6495-2016, https://doi.org/10.5194/acp-16-6495-2016, 2016
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Viscous solid or semi-solid secondary organic aerosol (SOA) may influence cloud properties through ice nucleation in the atmosphere. Here, we observed heterogeneous ice nucleation of viscous α-pinene SOA at temperatures between −39 °C and −37.2 °C with ice saturation ratios significantly below the homogeneous freezing limit. Global modelling suggests that viscous biogenic SOA are present in regions where cirrus formation takes place and could contribute to the global ice nuclei budget.
Emma Järvinen, Karoliina Ignatius, Leonid Nichman, Thomas B. Kristensen, Claudia Fuchs, Christopher R. Hoyle, Niko Höppel, Joel C. Corbin, Jill Craven, Jonathan Duplissy, Sebastian Ehrhart, Imad El Haddad, Carla Frege, Hamish Gordon, Tuija Jokinen, Peter Kallinger, Jasper Kirkby, Alexei Kiselev, Karl-Heinz Naumann, Tuukka Petäjä, Tamara Pinterich, Andre S. H. Prevot, Harald Saathoff, Thea Schiebel, Kamalika Sengupta, Mario Simon, Jay G. Slowik, Jasmin Tröstl, Annele Virtanen, Paul Vochezer, Steffen Vogt, Andrea C. Wagner, Robert Wagner, Christina Williamson, Paul M. Winkler, Chao Yan, Urs Baltensperger, Neil M. Donahue, Rick C. Flagan, Martin Gallagher, Armin Hansel, Markku Kulmala, Frank Stratmann, Douglas R. Worsnop, Ottmar Möhler, Thomas Leisner, and Martin Schnaiter
Atmos. Chem. Phys., 16, 4423–4438, https://doi.org/10.5194/acp-16-4423-2016, https://doi.org/10.5194/acp-16-4423-2016, 2016
Leonid Nichman, Claudia Fuchs, Emma Järvinen, Karoliina Ignatius, Niko Florian Höppel, Antonio Dias, Martin Heinritzi, Mario Simon, Jasmin Tröstl, Andrea Christine Wagner, Robert Wagner, Christina Williamson, Chao Yan, Paul James Connolly, James Robert Dorsey, Jonathan Duplissy, Sebastian Ehrhart, Carla Frege, Hamish Gordon, Christopher Robert Hoyle, Thomas Bjerring Kristensen, Gerhard Steiner, Neil McPherson Donahue, Richard Flagan, Martin William Gallagher, Jasper Kirkby, Ottmar Möhler, Harald Saathoff, Martin Schnaiter, Frank Stratmann, and António Tomé
Atmos. Chem. Phys., 16, 3651–3664, https://doi.org/10.5194/acp-16-3651-2016, https://doi.org/10.5194/acp-16-3651-2016, 2016
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Processes in the atmosphere are often governed by the physical and chemical properties of small cloud particles. Ice, water, and mixed clouds, as well as viscous aerosols, were formed under controlled conditions at the CLOUD-CERN facility. The experimental results show a link between cloud particle properties and their unique optical fingerprints. The classification map presented here allows easier discrimination between various particles such as viscous organic aerosol, salt, ice, and liquid.
Robert Wagner, Alexei Kiselev, Ottmar Möhler, Harald Saathoff, and Isabelle Steinke
Atmos. Chem. Phys., 16, 2025–2042, https://doi.org/10.5194/acp-16-2025-2016, https://doi.org/10.5194/acp-16-2025-2016, 2016
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We have investigated the enhancement of the ice nucleation ability of well-known and abundant ice nucleating particles like dust grains due to pre-activation. Temporary exposure to a low temperature (228 K) provokes that pores and surface cracks of the particles are filled with ice, which makes them better nuclei for the growth of macroscopic ice crystals at high temperatures (245–260 K).
C. R. Hoyle, C. Fuchs, E. Järvinen, H. Saathoff, A. Dias, I. El Haddad, M. Gysel, S. C. Coburn, J. Tröstl, A.-K. Bernhammer, F. Bianchi, M. Breitenlechner, J. C. Corbin, J. Craven, N. M. Donahue, J. Duplissy, S. Ehrhart, C. Frege, H. Gordon, N. Höppel, M. Heinritzi, T. B. Kristensen, U. Molteni, L. Nichman, T. Pinterich, A. S. H. Prévôt, M. Simon, J. G. Slowik, G. Steiner, A. Tomé, A. L. Vogel, R. Volkamer, A. C. Wagner, R. Wagner, A. S. Wexler, C. Williamson, P. M. Winkler, C. Yan, A. Amorim, J. Dommen, J. Curtius, M. W. Gallagher, R. C. Flagan, A. Hansel, J. Kirkby, M. Kulmala, O. Möhler, F. Stratmann, D. R. Worsnop, and U. Baltensperger
Atmos. Chem. Phys., 16, 1693–1712, https://doi.org/10.5194/acp-16-1693-2016, https://doi.org/10.5194/acp-16-1693-2016, 2016
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A significant portion of sulphate, an important constituent of atmospheric aerosols, is formed via the aqueous phase oxidation of sulphur dioxide by ozone. The rate of this reaction has previously only been measured over a relatively small temperature range. Here, we use the state of the art CLOUD chamber at CERN to perform the first measurements of this reaction rate in super-cooled droplets, confirming that the existing extrapolation of the reaction rate to sub-zero temperatures is accurate.
R. H. Mason, M. Si, C. Chou, V. E. Irish, R. Dickie, P. Elizondo, R. Wong, M. Brintnell, M. Elsasser, W. M. Lassar, K. M. Pierce, W. R. Leaitch, A. M. MacDonald, A. Platt, D. Toom-Sauntry, R. Sarda-Estève, C. L. Schiller, K. J. Suski, T. C. J. Hill, J. P. D. Abbatt, J. A. Huffman, P. J. DeMott, and A. K. Bertram
Atmos. Chem. Phys., 16, 1637–1651, https://doi.org/10.5194/acp-16-1637-2016, https://doi.org/10.5194/acp-16-1637-2016, 2016
G. Vali, P. J. DeMott, O. Möhler, and T. F. Whale
Atmos. Chem. Phys., 15, 10263–10270, https://doi.org/10.5194/acp-15-10263-2015, https://doi.org/10.5194/acp-15-10263-2015, 2015
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Clarification is needed in the terminology used to discuss ice nucleation in the literature. Conflicting interpretations coupled with uncertainties about the details of the processes have led to difficulties in the clear communication of results and ideas. This paper contains a proposal for future usage. This proposed terminology was arrived at as a result of a year-long exchange of suggestions by a number of scientists.
J. Meyer, C. Rolf, C. Schiller, S. Rohs, N. Spelten, A. Afchine, M. Zöger, N. Sitnikov, T. D. Thornberry, A. W. Rollins, Z. Bozóki, D. Tátrai, V. Ebert, B. Kühnreich, P. Mackrodt, O. Möhler, H. Saathoff, K. H. Rosenlof, and M. Krämer
Atmos. Chem. Phys., 15, 8521–8538, https://doi.org/10.5194/acp-15-8521-2015, https://doi.org/10.5194/acp-15-8521-2015, 2015
P. Amato, M. Joly, C. Schaupp, E. Attard, O. Möhler, C. E. Morris, Y. Brunet, and A.-M. Delort
Atmos. Chem. Phys., 15, 6455–6465, https://doi.org/10.5194/acp-15-6455-2015, https://doi.org/10.5194/acp-15-6455-2015, 2015
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Mortality rate of typical bacterial aerosols (Pseudomonas species) was determined in a cloud simulation chamber. Ice nucleation activity remained unchanged for several hours in aerosolized cells, whether they were viable or not. Cloud increased the specific removal of ice nucleation active cells by precipitation. Survival was negatively impacted by the presence of cloud and by sulfates.
I. Steinke, C. Hoose, O. Möhler, P. Connolly, and T. Leisner
Atmos. Chem. Phys., 15, 3703–3717, https://doi.org/10.5194/acp-15-3703-2015, https://doi.org/10.5194/acp-15-3703-2015, 2015
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Ice nucleation in clouds has a significant influence on the global radiative budget and the hydrological cycle. Several studies have investigated the ice formation in droplets and parameterizations have been developed in order to include immersion freezing in climate models. In contrast, there are fewer studies regarding the conversion of water vapor into ice (so-called deposition nucleation) which is the topic of this paper which investigates deposition nucleation by Arizona Test dust in detail
N. Hiranuma, S. Augustin-Bauditz, H. Bingemer, C. Budke, J. Curtius, A. Danielczok, K. Diehl, K. Dreischmeier, M. Ebert, F. Frank, N. Hoffmann, K. Kandler, A. Kiselev, T. Koop, T. Leisner, O. Möhler, B. Nillius, A. Peckhaus, D. Rose, S. Weinbruch, H. Wex, Y. Boose, P. J. DeMott, J. D. Hader, T. C. J. Hill, Z. A. Kanji, G. Kulkarni, E. J. T. Levin, C. S. McCluskey, M. Murakami, B. J. Murray, D. Niedermeier, M. D. Petters, D. O'Sullivan, A. Saito, G. P. Schill, T. Tajiri, M. A. Tolbert, A. Welti, T. F. Whale, T. P. Wright, and K. Yamashita
Atmos. Chem. Phys., 15, 2489–2518, https://doi.org/10.5194/acp-15-2489-2015, https://doi.org/10.5194/acp-15-2489-2015, 2015
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Seventeen ice nucleation measurement techniques contributed to investigate the immersion freezing behavior of illite NX. All data showed a similar temperature trend, but the measured ice nucleation activity was on average smaller for the wet suspended samples and higher for the dry-dispersed aerosol samples at high temperatures. A continued investigation and collaboration is necessary to obtain further insights into consistency or diversity of ice nucleation measurements.
H. Wex, S. Augustin-Bauditz, Y. Boose, C. Budke, J. Curtius, K. Diehl, A. Dreyer, F. Frank, S. Hartmann, N. Hiranuma, E. Jantsch, Z. A. Kanji, A. Kiselev, T. Koop, O. Möhler, D. Niedermeier, B. Nillius, M. Rösch, D. Rose, C. Schmidt, I. Steinke, and F. Stratmann
Atmos. Chem. Phys., 15, 1463–1485, https://doi.org/10.5194/acp-15-1463-2015, https://doi.org/10.5194/acp-15-1463-2015, 2015
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Immersion freezing measurements from seven different measurement techniques were intercompared using a biological ice nucleating material from bacteria. Although different techniques examined differently concentrated droplets, it was possible to find a uniform description, which showed that results from all experiments were generally in good agreement and were also in agreement with parameterizations published earlier in literature.
P. J. DeMott, A. J. Prenni, G. R. McMeeking, R. C. Sullivan, M. D. Petters, Y. Tobo, M. Niemand, O. Möhler, J. R. Snider, Z. Wang, and S. M. Kreidenweis
Atmos. Chem. Phys., 15, 393–409, https://doi.org/10.5194/acp-15-393-2015, https://doi.org/10.5194/acp-15-393-2015, 2015
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Laboratory and field data are used together to develop an empirical relation between the concentrations of mineral dust particles at sizes above 0.5 microns, approximated as a single compositional type, and ice nucleating particle concentrations measured versus temperature. This should be useful in global modeling of ice cloud formation. The utility of laboratory data for parameterization development is reinforced, and the need for careful interpretation of ice nucleation data is emphasized.
N. Hiranuma, M. Paukert, I. Steinke, K. Zhang, G. Kulkarni, C. Hoose, M. Schnaiter, H. Saathoff, and O. Möhler
Atmos. Chem. Phys., 14, 13145–13158, https://doi.org/10.5194/acp-14-13145-2014, https://doi.org/10.5194/acp-14-13145-2014, 2014
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A new heterogeneous ice nucleation parameterization is developed and implemented in cloud models. The results of our simulations suggest stronger influence of dust particles lifted to the upper troposphere on heterogeneous nucleation and more ice nucleation at temperature and humidity conditions relevant to both mixed-phase and cirrus clouds when compared to the existing parametrical frameworks.
D. W. Fahey, R.-S. Gao, O. Möhler, H. Saathoff, C. Schiller, V. Ebert, M. Krämer, T. Peter, N. Amarouche, L. M. Avallone, R. Bauer, Z. Bozóki, L. E. Christensen, S. M. Davis, G. Durry, C. Dyroff, R. L. Herman, S. Hunsmann, S. M. Khaykin, P. Mackrodt, J. Meyer, J. B. Smith, N. Spelten, R. F. Troy, H. Vömel, S. Wagner, and F. G. Wienhold
Atmos. Meas. Tech., 7, 3177–3213, https://doi.org/10.5194/amt-7-3177-2014, https://doi.org/10.5194/amt-7-3177-2014, 2014
N. Hiranuma, N. Hoffmann, A. Kiselev, A. Dreyer, K. Zhang, G. Kulkarni, T. Koop, and O. Möhler
Atmos. Chem. Phys., 14, 2315–2324, https://doi.org/10.5194/acp-14-2315-2014, https://doi.org/10.5194/acp-14-2315-2014, 2014
S. M. Platt, I. El Haddad, A. A. Zardini, M. Clairotte, C. Astorga, R. Wolf, J. G. Slowik, B. Temime-Roussel, N. Marchand, I. Ježek, L. Drinovec, G. Močnik, O. Möhler, R. Richter, P. Barmet, F. Bianchi, U. Baltensperger, and A. S. H. Prévôt
Atmos. Chem. Phys., 13, 9141–9158, https://doi.org/10.5194/acp-13-9141-2013, https://doi.org/10.5194/acp-13-9141-2013, 2013
H. Saathoff, S. Henin, K. Stelmaszczyk, M. Petrarca, R. Delagrange, Z. Hao, J. Lüder, O. Möhler, Y. Petit, P. Rohwetter, M. Schnaiter, J. Kasparian, T. Leisner, J.-P. Wolf, and L. Wöste
Atmos. Chem. Phys., 13, 4593–4604, https://doi.org/10.5194/acp-13-4593-2013, https://doi.org/10.5194/acp-13-4593-2013, 2013
J. Skrotzki, P. Connolly, M. Schnaiter, H. Saathoff, O. Möhler, R. Wagner, M. Niemand, V. Ebert, and T. Leisner
Atmos. Chem. Phys., 13, 4451–4466, https://doi.org/10.5194/acp-13-4451-2013, https://doi.org/10.5194/acp-13-4451-2013, 2013
M. Laborde, M. Schnaiter, C. Linke, H. Saathoff, K.-H. Naumann, O. Möhler, S. Berlenz, U. Wagner, J. W. Taylor, D. Liu, M. Flynn, J. D. Allan, H. Coe, K. Heimerl, F. Dahlkötter, B. Weinzierl, A. G. Wollny, M. Zanatta, J. Cozic, P. Laj, R. Hitzenberger, J. P. Schwarz, and M. Gysel
Atmos. Meas. Tech., 5, 3077–3097, https://doi.org/10.5194/amt-5-3077-2012, https://doi.org/10.5194/amt-5-3077-2012, 2012
Related subject area
Subject: Clouds and Precipitation | Research Activity: Laboratory Studies | Altitude Range: Troposphere | Science Focus: Physics (physical properties and processes)
Stable and unstable fall motions of plate-like ice crystal analogues
Secondary ice production – no evidence of efficient rime-splintering mechanism
Fragmentation of ice particles: laboratory experiments on graupel–graupel and graupel–snowflake collisions
Molecular simulations reveal that heterogeneous ice nucleation occurs at higher temperatures in water under capillary tension
Measurement of the collision rate coefficients between atmospheric ions and multiply charged aerosol particles in the CERN CLOUD chamber
Re-evaluating cloud chamber constraints on depositional ice growth in cirrus clouds – Part 1: Model description and sensitivity tests
Ice nucleation by smectites: the role of the edges
A single-parameter hygroscopicity model for functionalized insoluble aerosol surfaces
Mexican agricultural soil dust as a source of ice nucleating particles
The impact of (bio-)organic substances on the ice nucleation activity of the K-feldspar microcline in aqueous solutions
Secondary ice production during the break-up of freezing water drops on impact with ice particles
High homogeneous freezing onsets of sulfuric acid aerosol at cirrus temperatures
Laboratory and field studies of ice-nucleating particles from open-lot livestock facilities in Texas
Comment on “Review of experimental studies of secondary ice production” by Korolev and Leisner (2020)
Effect of chemically induced fracturing on the ice nucleation activity of alkali feldspar
Ice nucleation ability of ammonium sulfate aerosol particles internally mixed with secondary organics
Ice-nucleating particles in precipitation samples from the Texas Panhandle
Comparative study on immersion freezing utilizing single-droplet levitation methods
Exploratory experiments on pre-activated freezing nucleation on mercuric iodide
Application of holography and automated image processing for laboratory experiments on mass and fall speed of small cloud ice crystals
Review of experimental studies of secondary ice production
The role of contact angle and pore width on pore condensation and freezing
Technical note: Equilibrium droplet size distributions in a turbulent cloud chamber with uniform supersaturation
Protein aggregates nucleate ice: the example of apoferritin
No anomalous supersaturation in ultracold cirrus laboratory experiments
Lateral facet growth of ice and snow – Part 1: Observations and applications to secondary habits
The ice-nucleating ability of quartz immersed in water and its atmospheric importance compared to K-feldspar
Ice nucleation properties of K-feldspar polymorphs and plagioclase feldspars
Enhanced ice nucleation activity of coal fly ash aerosol particles initiated by ice-filled pores
A comprehensive characterization of ice nucleation by three different types of cellulose particles immersed in water
Anomalous holiday precipitation over southern China
Coal fly ash: linking immersion freezing behavior and physicochemical particle properties
Surface roughness during depositional growth and sublimation of ice crystals
Ice nucleation abilities of soot particles determined with the Horizontal Ice Nucleation Chamber
The efficiency of secondary organic aerosol particles acting as ice-nucleating particles under mixed-phase cloud conditions
Uncertainty in counting ice nucleating particles with continuous flow diffusion chambers
Experimental evidence of the rear capture of aerosol particles by raindrops
Refreeze experiments with water droplets containing different types of ice nuclei interpreted by classical nucleation theory
Pre-activation of aerosol particles by ice preserved in pores
Heterogeneous ice nucleation on dust particles sourced from nine deserts worldwide – Part 1: Immersion freezing
A comparative study of K-rich and Na/Ca-rich feldspar ice-nucleating particles in a nanoliter droplet freezing assay
Ice nucleation efficiency of AgI: review and new insights
The adsorption of fungal ice-nucleating proteins on mineral dusts: a terrestrial reservoir of atmospheric ice-nucleating particles
Exploring an approximation for the homogeneous freezing temperature of water droplets
Cloud chamber experiments on the origin of ice crystal complexity in cirrus clouds
Phase transition observations and discrimination of small cloud particles by light polarization in expansion chamber experiments
Analysis of isothermal and cooling-rate-dependent immersion freezing by a unifying stochastic ice nucleation model
Pre-activation of ice-nucleating particles by the pore condensation and freezing mechanism
Influence of the ambient humidity on the concentration of natural deposition-mode ice-nucleating particles
Comparison of measured and calculated collision efficiencies at low temperatures
Jennifer R. Stout, Christopher D. Westbrook, Thorwald H. M. Stein, and Mark W. McCorquodale
Atmos. Chem. Phys., 24, 11133–11155, https://doi.org/10.5194/acp-24-11133-2024, https://doi.org/10.5194/acp-24-11133-2024, 2024
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This study uses 3D-printed ice crystal analogues falling in a water–glycerine mix and observed with multi-view cameras, simulating atmospheric conditions. Four types of motion are observed: stable, zigzag, transitional, and spiralling. Particle shape strongly influences motion; complex shapes have a wider range of conditions where they fall steadily compared to simple plates. The most common orientation of unstable particles is non-horizontal, contrary to prior assumptions of always horizontal.
Johanna S. Seidel, Alexei A. Kiselev, Alice Keinert, Frank Stratmann, Thomas Leisner, and Susan Hartmann
Atmos. Chem. Phys., 24, 5247–5263, https://doi.org/10.5194/acp-24-5247-2024, https://doi.org/10.5194/acp-24-5247-2024, 2024
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Clouds often contain several thousand times more ice crystals than aerosol particles catalyzing ice formation. This phenomenon, commonly known as ice multiplication, is often explained by secondary ice formation due to the collisions between falling ice particles and droplets. In this study, we mimic this riming process. Contrary to earlier experiments, we found no efficient ice multiplication, which fundamentally questions the importance of the rime-splintering mechanism.
Pierre Grzegorczyk, Sudha Yadav, Florian Zanger, Alexander Theis, Subir K. Mitra, Stephan Borrmann, and Miklós Szakáll
Atmos. Chem. Phys., 23, 13505–13521, https://doi.org/10.5194/acp-23-13505-2023, https://doi.org/10.5194/acp-23-13505-2023, 2023
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Secondary ice production generates high concentrations of ice crystals in clouds. These processes have been poorly understood. We conducted experiments at the wind tunnel laboratory of the Johannes Gutenberg University, Mainz, on graupel–graupel and graupel–snowflake collisions. From these experiments fragment number, size, cross-sectional area, and aspect ratio were determined.
Elise Rosky, Will Cantrell, Tianshu Li, Issei Nakamura, and Raymond A. Shaw
Atmos. Chem. Phys., 23, 10625–10642, https://doi.org/10.5194/acp-23-10625-2023, https://doi.org/10.5194/acp-23-10625-2023, 2023
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Using computer simulations of water, we find that water under tension freezes more easily than under normal conditions. A linear equation describes how freezing temperature increases with tension. Accordingly, simulations show that naturally occurring tension in water capillary bridges leads to higher freezing temperatures. This work is an early step in determining if atmospheric cloud droplets freeze due to naturally occurring tension, for example, during processes such as droplet collisions.
Joschka Pfeifer, Naser G. A. Mahfouz, Benjamin C. Schulze, Serge Mathot, Dominik Stolzenburg, Rima Baalbaki, Zoé Brasseur, Lucia Caudillo, Lubna Dada, Manuel Granzin, Xu-Cheng He, Houssni Lamkaddam, Brandon Lopez, Vladimir Makhmutov, Ruby Marten, Bernhard Mentler, Tatjana Müller, Antti Onnela, Maxim Philippov, Ana A. Piedehierro, Birte Rörup, Meredith Schervish, Ping Tian, Nsikanabasi S. Umo, Dongyu S. Wang, Mingyi Wang, Stefan K. Weber, André Welti, Yusheng Wu, Marcel Zauner-Wieczorek, Antonio Amorim, Imad El Haddad, Markku Kulmala, Katrianne Lehtipalo, Tuukka Petäjä, António Tomé, Sander Mirme, Hanna E. Manninen, Neil M. Donahue, Richard C. Flagan, Andreas Kürten, Joachim Curtius, and Jasper Kirkby
Atmos. Chem. Phys., 23, 6703–6718, https://doi.org/10.5194/acp-23-6703-2023, https://doi.org/10.5194/acp-23-6703-2023, 2023
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Attachment rate coefficients between ions and charged aerosol particles determine their lifetimes and may also influence cloud dynamics and aerosol processing. Here we present novel experiments that measure ion–aerosol attachment rate coefficients for multiply charged aerosol particles under atmospheric conditions in the CERN CLOUD chamber. Our results provide experimental discrimination between various theoretical models.
Kara D. Lamb, Jerry Y. Harrington, Benjamin W. Clouser, Elisabeth J. Moyer, Laszlo Sarkozy, Volker Ebert, Ottmar Möhler, and Harald Saathoff
Atmos. Chem. Phys., 23, 6043–6064, https://doi.org/10.5194/acp-23-6043-2023, https://doi.org/10.5194/acp-23-6043-2023, 2023
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This study investigates how ice grows directly from vapor in cirrus clouds by comparing observations of populations of ice crystals growing in a cloud chamber against models developed in the context of single-crystal laboratory studies. We demonstrate that previous discrepancies between different experimental measurements do not necessarily point to different physical interpretations but are rather due to assumptions that were made in terms of how experiments were modeled in previous studies.
Anand Kumar, Kristian Klumpp, Chen Barak, Giora Rytwo, Michael Plötze, Thomas Peter, and Claudia Marcolli
Atmos. Chem. Phys., 23, 4881–4902, https://doi.org/10.5194/acp-23-4881-2023, https://doi.org/10.5194/acp-23-4881-2023, 2023
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Smectites are a major class of clay minerals that are ice nucleation (IN) active. They form platelets that swell or even delaminate in water by intercalation of water between their layers. We hypothesize that at least three smectite layers need to be stacked together to host a critical ice embryo on clay mineral edges and that the larger the surface edge area is, the higher the freezing temperature. Edge sites on such clay particles play a crucial role in imparting IN ability to such particles.
Chun-Ning Mao, Kanishk Gohil, and Akua A. Asa-Awuku
Atmos. Chem. Phys., 22, 13219–13228, https://doi.org/10.5194/acp-22-13219-2022, https://doi.org/10.5194/acp-22-13219-2022, 2022
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The impact of molecular-level surface chemistry for aerosol water uptake and droplet growth is not well understood. In this work we show changes in water uptake due to molecular-level surface chemistry can be measured and quantified. In addition, we develop a single-parameter model, representing changes in aerosol chemistry that can be used in global climate models to reduce the uncertainty in aerosol-cloud predictions.
Diana L. Pereira, Irma Gavilán, Consuelo Letechipía, Graciela B. Raga, Teresa Pi Puig, Violeta Mugica-Álvarez, Harry Alvarez-Ospina, Irma Rosas, Leticia Martinez, Eva Salinas, Erika T. Quintana, Daniel Rosas, and Luis A. Ladino
Atmos. Chem. Phys., 22, 6435–6447, https://doi.org/10.5194/acp-22-6435-2022, https://doi.org/10.5194/acp-22-6435-2022, 2022
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Airborne particles were i) collected in an agricultural fields and ii) generated in the laboratory from agricultural soil samples to analyze their ice nucleating abilities. It was found that the size and chemical composition of the Mexican agricultural dust particles influence their ice nucleating behavior, where the organic components are likely responsible for their efficiency as INPs. The INP concentrations from the present study are comparable to those from higher latitudes.
Kristian Klumpp, Claudia Marcolli, and Thomas Peter
Atmos. Chem. Phys., 22, 3655–3673, https://doi.org/10.5194/acp-22-3655-2022, https://doi.org/10.5194/acp-22-3655-2022, 2022
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Surface interactions with solutes can significantly alter the ice nucleation activity of mineral dust. Past studies revealed the sensitivity of microcline, one of the most ice-active types of dust in the atmosphere, to inorganic solutes. This study focuses on the interaction of microcline with bio-organic substances and the resulting effects on its ice nucleation activity. We observe strongly hampered ice nucleation activity due to the presence of carboxylic and amino acids but not for polyols.
Rachel L. James, Vaughan T. J. Phillips, and Paul J. Connolly
Atmos. Chem. Phys., 21, 18519–18530, https://doi.org/10.5194/acp-21-18519-2021, https://doi.org/10.5194/acp-21-18519-2021, 2021
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Secondary ice production (SIP) plays an important role in ice formation within mixed-phase clouds. We present a laboratory investigation of a potentially new SIP mechanism involving the collisions of supercooled water drops with ice particles. At impact, the supercooled water drop fragments form smaller secondary drops. Approximately 30 % of the secondary drops formed during the retraction phase of the supercooled water drop impact freeze over a temperature range of −4 °C to −12 °C.
Julia Schneider, Kristina Höhler, Robert Wagner, Harald Saathoff, Martin Schnaiter, Tobias Schorr, Isabelle Steinke, Stefan Benz, Manuel Baumgartner, Christian Rolf, Martina Krämer, Thomas Leisner, and Ottmar Möhler
Atmos. Chem. Phys., 21, 14403–14425, https://doi.org/10.5194/acp-21-14403-2021, https://doi.org/10.5194/acp-21-14403-2021, 2021
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Homogeneous freezing is a relevant mechanism for the formation of cirrus clouds in the upper troposphere. Based on an extensive set of homogeneous freezing experiments at the AIDA chamber with aqueous sulfuric acid aerosol, we provide a new fit line for homogeneous freezing onset conditions of sulfuric acid aerosol focusing on cirrus temperatures. In the atmosphere, homogeneous freezing thresholds have important implications on the cirrus cloud occurrence and related cloud radiative effects.
Naruki Hiranuma, Brent W. Auvermann, Franco Belosi, Jack Bush, Kimberly M. Cory, Dimitrios G. Georgakopoulos, Kristina Höhler, Yidi Hou, Larissa Lacher, Harald Saathoff, Gianni Santachiara, Xiaoli Shen, Isabelle Steinke, Romy Ullrich, Nsikanabasi S. Umo, Hemanth S. K. Vepuri, Franziska Vogel, and Ottmar Möhler
Atmos. Chem. Phys., 21, 14215–14234, https://doi.org/10.5194/acp-21-14215-2021, https://doi.org/10.5194/acp-21-14215-2021, 2021
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We present laboratory and field studies showing that an open-lot livestock facility is a substantial source of atmospheric ice-nucleating particles (INPs). The ambient concentration of INPs from livestock facilities in Texas is very high. It is up to several thousand INPs per liter below –20 °C and may impact regional aerosol–cloud interactions. About 50% of feedlot INPs were supermicron in diameter. No notable amount of known ice-nucleating microorganisms was found in our feedlot samples.
Vaughan T. J. Phillips, Jun-Ichi Yano, Akash Deshmukh, and Deepak Waman
Atmos. Chem. Phys., 21, 11941–11953, https://doi.org/10.5194/acp-21-11941-2021, https://doi.org/10.5194/acp-21-11941-2021, 2021
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For decades, high concentrations of ice observed in precipitating mixed-phase clouds have created an enigma. Such concentrations are higher than can be explained by the action of aerosols or by the spontaneous freezing of most cloud droplets. The controversy has partly persisted due to the lack of laboratory experimentation in ice microphysics, especially regarding fragmentation of ice, a topic reviewed by a recent paper. Our comment attempts to clarify some issues with regards to that review.
Alexei A. Kiselev, Alice Keinert, Tilia Gaedeke, Thomas Leisner, Christoph Sutter, Elena Petrishcheva, and Rainer Abart
Atmos. Chem. Phys., 21, 11801–11814, https://doi.org/10.5194/acp-21-11801-2021, https://doi.org/10.5194/acp-21-11801-2021, 2021
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Alkali feldspar is the most abundant mineral in the Earth's crust and is often present in mineral dust aerosols that are responsible for the formation of rain and snow in clouds. However, the cloud droplets containing pure potassium-rich feldspar would not freeze unless cooled down to a very low temperature. Here we show that partly replacing potassium with sodium would induce fracturing of feldspar, exposing a crystalline surface that could initiate freezing at higher temperature.
Barbara Bertozzi, Robert Wagner, Junwei Song, Kristina Höhler, Joschka Pfeifer, Harald Saathoff, Thomas Leisner, and Ottmar Möhler
Atmos. Chem. Phys., 21, 10779–10798, https://doi.org/10.5194/acp-21-10779-2021, https://doi.org/10.5194/acp-21-10779-2021, 2021
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Internally mixed particles composed of sulfate and organics are among the most abundant aerosol types. Their ice nucleation (IN) ability influences the formation of cirrus and, thus, the climate. We show that the presence of a thin organic coating suppresses the heterogeneous IN ability of crystalline ammonium sulfate particles. However, the IN ability of the same particle can substantially change if subjected to atmospheric processing, mainly due to differences in the resulting morphology.
Hemanth S. K. Vepuri, Cheyanne A. Rodriguez, Dimitrios G. Georgakopoulos, Dustin Hume, James Webb, Gregory D. Mayer, and Naruki Hiranuma
Atmos. Chem. Phys., 21, 4503–4520, https://doi.org/10.5194/acp-21-4503-2021, https://doi.org/10.5194/acp-21-4503-2021, 2021
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Due to a high frequency of storm events, West Texas is an ideal location to study ice-nucleating particles (INPs) in severe precipitation. Our results present that cumulative INP concentration in our precipitation samples below −20 °C could be high in the samples collected while observing > 10 mm h−1 precipitation with notably large hydrometeor sizes and an implication of cattle feedyard bacteria inclusion. Marine bacteria were found in a subset of our precipitation and cattle feedyard samples.
Miklós Szakáll, Michael Debertshäuser, Christian Philipp Lackner, Amelie Mayer, Oliver Eppers, Karoline Diehl, Alexander Theis, Subir Kumar Mitra, and Stephan Borrmann
Atmos. Chem. Phys., 21, 3289–3316, https://doi.org/10.5194/acp-21-3289-2021, https://doi.org/10.5194/acp-21-3289-2021, 2021
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The freezing of cloud drops is promoted by ice-nucleating particles immersed in the drops. This process is essential to understand ice and subsequent precipitation formation in clouds. We investigated the efficiency of several particle types to trigger immersion freezing with two single-drop levitation techniques: a wind tunnel and an acoustic levitator. The evaluation accounted for different conditions during our two series of experiments, which is also applicable to future comparison studies.
Gabor Vali
Atmos. Chem. Phys., 21, 2551–2568, https://doi.org/10.5194/acp-21-2551-2021, https://doi.org/10.5194/acp-21-2551-2021, 2021
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The freezing of water drops in clouds is a prime example for the role of ice-nucleating particles (INPs). Mercuric iodide particles and a few other substances can be conditioned to become very effective INPs after previous ice formation and moderate heating to melt temperatures, opening a new pathway to ice formation in the atmosphere and in other systems like tissue preservation, artificial snow making, and more.
Maximilian Weitzel, Subir K. Mitra, Miklós Szakáll, Jacob P. Fugal, and Stephan Borrmann
Atmos. Chem. Phys., 20, 14889–14901, https://doi.org/10.5194/acp-20-14889-2020, https://doi.org/10.5194/acp-20-14889-2020, 2020
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The properties of ice crystals smaller than 150 µm in diameter were investigated in a cold-room laboratory using digital holography and microscopy. Automated image processing has been used to determine the track of falling ice crystals, and collected crystals were melted and scanned under a microscope to infer particle mass. A parameterization relating particle size and mass was determined which describes ice crystals in this size range more accurately than existing relationships.
Alexei Korolev and Thomas Leisner
Atmos. Chem. Phys., 20, 11767–11797, https://doi.org/10.5194/acp-20-11767-2020, https://doi.org/10.5194/acp-20-11767-2020, 2020
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Secondary ice production (SIP) plays a key role in the formation of ice particles in tropospheric clouds. This work presents a critical review of the laboratory studies related to secondary ice production. It aims to identify gaps in our knowledge of SIP as well as to stimulate further laboratory studies focused on obtaining a quantitative description of efficiencies for each SIP mechanism.
Robert O. David, Jonas Fahrni, Claudia Marcolli, Fabian Mahrt, Dominik Brühwiler, and Zamin A. Kanji
Atmos. Chem. Phys., 20, 9419–9440, https://doi.org/10.5194/acp-20-9419-2020, https://doi.org/10.5194/acp-20-9419-2020, 2020
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Ice crystal formation plays an important role in controlling the Earth's climate. However, the mechanisms responsible for ice formation in the atmosphere are still uncertain. Here we use surrogates for atmospherically relevant porous particles to determine the role of pore diameter and wettability on the ability of porous particles to nucleate ice in the atmosphere. Our results are consistent with the pore condensation and freeing mechanism.
Steven K. Krueger
Atmos. Chem. Phys., 20, 7895–7909, https://doi.org/10.5194/acp-20-7895-2020, https://doi.org/10.5194/acp-20-7895-2020, 2020
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When CCN are injected into a turbulent cloud chamber at a constant rate, and the rate of droplet activation is balanced by the rate of droplet fallout, a steady-state droplet size distribution (DSD) can be achieved. Analytic DSDs and PDFs of droplet radius were derived for such conditions when there is uniform supersaturation. Given the chamber height, the analytic PDF is determined by the supersaturation alone. This could allow one to infer the supersaturation that produced a measured PDF.
María Cascajo-Castresana, Robert O. David, Maiara A. Iriarte-Alonso, Alexander M. Bittner, and Claudia Marcolli
Atmos. Chem. Phys., 20, 3291–3315, https://doi.org/10.5194/acp-20-3291-2020, https://doi.org/10.5194/acp-20-3291-2020, 2020
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Atmospheric ice-nucleating particles are rare but relevant for cloud glaciation. A source of particles that nucleate ice above −15 °C is biological material including some proteins. Here we show that proteins of very diverse functions and structures can nucleate ice. Among these, the iron storage protein apoferritin stands out, with activity up to −4 °C. We show that its activity does not stem from correctly assembled proteins but from misfolded protein monomers or oligomers and aggregates.
Benjamin W. Clouser, Kara D. Lamb, Laszlo C. Sarkozy, Jan Habig, Volker Ebert, Harald Saathoff, Ottmar Möhler, and Elisabeth J. Moyer
Atmos. Chem. Phys., 20, 1089–1103, https://doi.org/10.5194/acp-20-1089-2020, https://doi.org/10.5194/acp-20-1089-2020, 2020
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Previous measurements of water vapor in the upper troposphere and lower stratosphere (UT/LS) have shown unexpectedly high concentrations of water vapor in ice clouds, which may be due to an incomplete understanding of the structure of ice and the behavior of ice growth in this part of the atmosphere. Water vapor measurements during the 2013 IsoCloud campaign at the AIDA cloud chamber show no evidence of this
anomalous supersaturationin conditions similar to the real atmosphere.
Jon Nelson and Brian D. Swanson
Atmos. Chem. Phys., 19, 15285–15320, https://doi.org/10.5194/acp-19-15285-2019, https://doi.org/10.5194/acp-19-15285-2019, 2019
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Ice crystals in clouds have a wide variety. But many crystal forms are inexplicable using the common approach of modeling the growth rates normal to the crystal faces. Instead of using only this normal-growth approach, we suggest including lateral facet growth processes. Using such lateral processes, backed up by new experiments, we give explanations for some of these puzzling forms. The forms include the center droxtal in stellar crystals, scrolls, capped columns, sheath bundles, and trigonals.
Alexander D. Harrison, Katherine Lever, Alberto Sanchez-Marroquin, Mark A. Holden, Thomas F. Whale, Mark D. Tarn, James B. McQuaid, and Benjamin J. Murray
Atmos. Chem. Phys., 19, 11343–11361, https://doi.org/10.5194/acp-19-11343-2019, https://doi.org/10.5194/acp-19-11343-2019, 2019
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Mineral dusts are a source of ice-nucleating particles (INPs) in the atmosphere. Here we present a comprehensive survey of the ice-nucleating ability of naturally occurring quartz. We show the ice-nucleating variability of quartz and its sensitivity to time spent in water and air. We propose four new parameterizations for the minerals quartz, K feldspar, albite and plagioclase to predict INP concentrations in the atmosphere and show that K-feldspar is the dominant INP type in mineral dusts.
André Welti, Ulrike Lohmann, and Zamin A. Kanji
Atmos. Chem. Phys., 19, 10901–10918, https://doi.org/10.5194/acp-19-10901-2019, https://doi.org/10.5194/acp-19-10901-2019, 2019
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The ice nucleation ability of singly immersed feldspar particles in suspended water droplets relevant for ice crystal formation under mixed-phase cloud conditions is presented. The effects of particle size, crystal structure, trace metal and mineralogical composition are discussed by testing up to five different diameters in the submicron range and nine different feldspar samples at conditions relevant for ice nucleation in mixed-phase clouds.
Nsikanabasi Silas Umo, Robert Wagner, Romy Ullrich, Alexei Kiselev, Harald Saathoff, Peter G. Weidler, Daniel J. Cziczo, Thomas Leisner, and Ottmar Möhler
Atmos. Chem. Phys., 19, 8783–8800, https://doi.org/10.5194/acp-19-8783-2019, https://doi.org/10.5194/acp-19-8783-2019, 2019
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Annually, over 600 Tg of coal fly ash (CFA) is produced; a significant proportion of this amount is injected into the atmosphere, which could significantly contribute to heterogeneous ice formation in clouds. This study presents an improved understanding of CFA particles' behaviour in forming ice in clouds, especially when exposed to lower temperatures before being re-circulated in the upper troposphere or entrained into the lower troposphere.
Naruki Hiranuma, Kouji Adachi, David M. Bell, Franco Belosi, Hassan Beydoun, Bhaskar Bhaduri, Heinz Bingemer, Carsten Budke, Hans-Christian Clemen, Franz Conen, Kimberly M. Cory, Joachim Curtius, Paul J. DeMott, Oliver Eppers, Sarah Grawe, Susan Hartmann, Nadine Hoffmann, Kristina Höhler, Evelyn Jantsch, Alexei Kiselev, Thomas Koop, Gourihar Kulkarni, Amelie Mayer, Masataka Murakami, Benjamin J. Murray, Alessia Nicosia, Markus D. Petters, Matteo Piazza, Michael Polen, Naama Reicher, Yinon Rudich, Atsushi Saito, Gianni Santachiara, Thea Schiebel, Gregg P. Schill, Johannes Schneider, Lior Segev, Emiliano Stopelli, Ryan C. Sullivan, Kaitlyn Suski, Miklós Szakáll, Takuya Tajiri, Hans Taylor, Yutaka Tobo, Romy Ullrich, Daniel Weber, Heike Wex, Thomas F. Whale, Craig L. Whiteside, Katsuya Yamashita, Alla Zelenyuk, and Ottmar Möhler
Atmos. Chem. Phys., 19, 4823–4849, https://doi.org/10.5194/acp-19-4823-2019, https://doi.org/10.5194/acp-19-4823-2019, 2019
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A total of 20 ice nucleation measurement techniques contributed to investigate the immersion freezing behavior of cellulose particles – natural polymers. Our data showed several types of cellulose are able to nucleate ice as efficiently as some mineral dust samples and cellulose has the potential to be an important atmospheric ice-nucleating particle. Continued investigation/collaboration is necessary to obtain further insight into consistency or diversity of ice nucleation measurements.
Jiahui Zhang, Dao-Yi Gong, Rui Mao, Jing Yang, Ziyin Zhang, and Yun Qian
Atmos. Chem. Phys., 18, 16775–16791, https://doi.org/10.5194/acp-18-16775-2018, https://doi.org/10.5194/acp-18-16775-2018, 2018
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The Chinese Spring Festival (also known as the Chinese New Year or Lunar New Year) is the most important festival in China. This paper reports that during the Chinese Spring Festival, the precipitation over southern China has been significantly reduced. The precipitation reduction is due to anomalous northerly winds. We suppose that anomalous atmospheric circulation is likely related to the human activity during holidays. It is an interesting phenomenon.
Sarah Grawe, Stefanie Augustin-Bauditz, Hans-Christian Clemen, Martin Ebert, Stine Eriksen Hammer, Jasmin Lubitz, Naama Reicher, Yinon Rudich, Johannes Schneider, Robert Staacke, Frank Stratmann, André Welti, and Heike Wex
Atmos. Chem. Phys., 18, 13903–13923, https://doi.org/10.5194/acp-18-13903-2018, https://doi.org/10.5194/acp-18-13903-2018, 2018
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In this study, coal fly ash particles immersed in supercooled cloud droplets were analyzed concerning their freezing behavior. Additionally, physico-chemical particle properties (morphology, chemical composition, crystallography) were investigated. In combining both aspects, components that potentially contribute to the observed freezing behavior of the ash could be identified. Interactions at the particle-water interface, that depend on suspension time and influence freezing, are discussed.
Jens Voigtländer, Cedric Chou, Henner Bieligk, Tina Clauss, Susan Hartmann, Paul Herenz, Dennis Niedermeier, Georg Ritter, Frank Stratmann, and Zbigniew Ulanowski
Atmos. Chem. Phys., 18, 13687–13702, https://doi.org/10.5194/acp-18-13687-2018, https://doi.org/10.5194/acp-18-13687-2018, 2018
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Surface roughness of ice crystals has recently been acknowledged to strongly influence the radiative properties of cold clouds such as cirrus, but it is unclear how this roughness arises. The study investigates the origins of ice surface roughness under a variety of atmospherically relevant conditions, using a novel method to measure roughness quantitatively. It is found that faster growth leads to stronger roughness. Roughness also increases following repeated growth–sublimation cycles.
Fabian Mahrt, Claudia Marcolli, Robert O. David, Philippe Grönquist, Eszter J. Barthazy Meier, Ulrike Lohmann, and Zamin A. Kanji
Atmos. Chem. Phys., 18, 13363–13392, https://doi.org/10.5194/acp-18-13363-2018, https://doi.org/10.5194/acp-18-13363-2018, 2018
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The ice nucleation ability of different soot particles in the cirrus and mixed-phase cloud temperature regime is presented. The impact of aerosol particle size, particle morphology, organic matter and hydrophilicity on ice nucleation is examined. We propose ice nucleation proceeds via a pore condensation freezing mechanism for soot particles with the necessary physicochemical properties that nucleated ice well below water saturation.
Wiebke Frey, Dawei Hu, James Dorsey, M. Rami Alfarra, Aki Pajunoja, Annele Virtanen, Paul Connolly, and Gordon McFiggans
Atmos. Chem. Phys., 18, 9393–9409, https://doi.org/10.5194/acp-18-9393-2018, https://doi.org/10.5194/acp-18-9393-2018, 2018
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The coupled system of the Manchester Aerosol Chamber and Manchester Ice Cloud Chamber was used to study the ice-forming abilities of secondary
organic aerosol particles under mixed-phase cloud conditions. Given the vast abundance of secondary organic particles in the atmosphere, they
might present an important contribution to ice-nucleating particles. However, we find that in the studied temperature range (20 to 28 °C)
the secondary organic particles do not nucleate ice particles.
Sarvesh Garimella, Daniel A. Rothenberg, Martin J. Wolf, Robert O. David, Zamin A. Kanji, Chien Wang, Michael Rösch, and Daniel J. Cziczo
Atmos. Chem. Phys., 17, 10855–10864, https://doi.org/10.5194/acp-17-10855-2017, https://doi.org/10.5194/acp-17-10855-2017, 2017
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This study investigates systematic and variable low bias in the measurement of ice nucleating particle concentration using continuous flow diffusion chambers. We find that non-ideal instrument behavior exposes particles to different humidities and/or temperatures than predicted from theory. We use a machine learning approach to quantify and minimize the uncertainty associated with this measurement bias.
Pascal Lemaitre, Arnaud Querel, Marie Monier, Thibault Menard, Emmanuel Porcheron, and Andrea I. Flossmann
Atmos. Chem. Phys., 17, 4159–4176, https://doi.org/10.5194/acp-17-4159-2017, https://doi.org/10.5194/acp-17-4159-2017, 2017
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We present new measurements of the efficiency with which aerosol particles are collected by raindrops. These measurements provide the link to reconcile the scavenging coefficients obtained from theoretical approaches with those from experimental studies. We provide proof of the rear capture that is a fundamental effect on submicroscopic particles. Finally, we propose an expression to take into account this mechanism to calculate the collection efficiency for drops within the rain size range.
Lukas Kaufmann, Claudia Marcolli, Beiping Luo, and Thomas Peter
Atmos. Chem. Phys., 17, 3525–3552, https://doi.org/10.5194/acp-17-3525-2017, https://doi.org/10.5194/acp-17-3525-2017, 2017
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To improve the understanding of heterogeneous ice nucleation, we have subjected different ice nuclei to repeated freezing cycles and evaluated the freezing temperatures with different parameterizations of classical nucleation theory. It was found that two fit parameters were necessary to describe the temperature dependence of the nucleation rate.
Claudia Marcolli
Atmos. Chem. Phys., 17, 1595–1622, https://doi.org/10.5194/acp-17-1595-2017, https://doi.org/10.5194/acp-17-1595-2017, 2017
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Laboratory studies from the last century have shown that some types of particles are susceptible to pre-activation, i.e. they are able to develop macroscopic ice at warmer temperatures or lower relative humidities after they had been involved in an ice nucleation event before. This review analyses these works under the presumption that pre-activation occurs by ice preserved in pores, and it discusses atmospheric scenarios for which pre-activation might be important.
Yvonne Boose, André Welti, James Atkinson, Fabiola Ramelli, Anja Danielczok, Heinz G. Bingemer, Michael Plötze, Berko Sierau, Zamin A. Kanji, and Ulrike Lohmann
Atmos. Chem. Phys., 16, 15075–15095, https://doi.org/10.5194/acp-16-15075-2016, https://doi.org/10.5194/acp-16-15075-2016, 2016
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We compare the immersion freezing behavior of four airborne to 11 surface-collected dust samples to investigate the role of different minerals for atmospheric ice nucleation on desert dust. We find that present K-feldspars dominate at T > 253 K, while quartz does at colder temperatures, and surface-collected dust samples are not necessarily representative for airborne dust. For improved ice cloud prediction, modeling of quartz and feldspar emission and transport are key.
Andreas Peckhaus, Alexei Kiselev, Thibault Hiron, Martin Ebert, and Thomas Leisner
Atmos. Chem. Phys., 16, 11477–11496, https://doi.org/10.5194/acp-16-11477-2016, https://doi.org/10.5194/acp-16-11477-2016, 2016
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The precipitation in midlatitude clouds proceeds predominantly via nucleation of ice in the supercooled droplets containing foreign inclusions, like feldspar mineral dust, that have been recently identified as one of the most active ice nucleating agents in the atmosphere. We have built an apparatus to observe the freezing of feldspar immersed in up to 1500 identical droplets simultaneously. With this setup we investigated four feldspar samples and show that it can induce freezing at −5 °C.
Claudia Marcolli, Baban Nagare, André Welti, and Ulrike Lohmann
Atmos. Chem. Phys., 16, 8915–8937, https://doi.org/10.5194/acp-16-8915-2016, https://doi.org/10.5194/acp-16-8915-2016, 2016
Short summary
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Silver iodide is one of the best-investigated ice nuclei. It has relevance for the atmosphere since it is used for glaciogenic cloud seeding. Nevertheless, many open questions remain. This paper gives an overview of silver iodide as an ice nucleus and tries to identify the factors that influence the ice nucleation ability of silver iodide.
Daniel O'Sullivan, Benjamin J. Murray, James F. Ross, and Michael E. Webb
Atmos. Chem. Phys., 16, 7879–7887, https://doi.org/10.5194/acp-16-7879-2016, https://doi.org/10.5194/acp-16-7879-2016, 2016
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In the absence of particles which can trigger freezing, cloud droplets can exist in a supercooled liquid state well below the melting point. However, the sources of efficient ice-nucleating particles in the atmosphere are uncertain. Here we show that ice-nucleating proteins produced by soil fungi can bind to clay particles in soils. Hence, the subsequent dispersion of soil particles into the atmosphere acts as a route through which biological ice nucleators can influence clouds.
Kuan-Ting O and Robert Wood
Atmos. Chem. Phys., 16, 7239–7249, https://doi.org/10.5194/acp-16-7239-2016, https://doi.org/10.5194/acp-16-7239-2016, 2016
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In this work, based on the well-known formulae of classical nucleation theory (CNT), the temperature at which the mean number of critical embryos inside a droplet is unity is derived from the Boltzmann distribution function and explored as a new simplified approximation for homogeneous freezing temperature. It thus appears that the simplicity of this approximation makes it potentially useful for predicting homogeneous freezing temperatures of water droplets in the atmosphere.
Martin Schnaiter, Emma Järvinen, Paul Vochezer, Ahmed Abdelmonem, Robert Wagner, Olivier Jourdan, Guillaume Mioche, Valery N. Shcherbakov, Carl G. Schmitt, Ugo Tricoli, Zbigniew Ulanowski, and Andrew J. Heymsfield
Atmos. Chem. Phys., 16, 5091–5110, https://doi.org/10.5194/acp-16-5091-2016, https://doi.org/10.5194/acp-16-5091-2016, 2016
Leonid Nichman, Claudia Fuchs, Emma Järvinen, Karoliina Ignatius, Niko Florian Höppel, Antonio Dias, Martin Heinritzi, Mario Simon, Jasmin Tröstl, Andrea Christine Wagner, Robert Wagner, Christina Williamson, Chao Yan, Paul James Connolly, James Robert Dorsey, Jonathan Duplissy, Sebastian Ehrhart, Carla Frege, Hamish Gordon, Christopher Robert Hoyle, Thomas Bjerring Kristensen, Gerhard Steiner, Neil McPherson Donahue, Richard Flagan, Martin William Gallagher, Jasper Kirkby, Ottmar Möhler, Harald Saathoff, Martin Schnaiter, Frank Stratmann, and António Tomé
Atmos. Chem. Phys., 16, 3651–3664, https://doi.org/10.5194/acp-16-3651-2016, https://doi.org/10.5194/acp-16-3651-2016, 2016
Short summary
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Processes in the atmosphere are often governed by the physical and chemical properties of small cloud particles. Ice, water, and mixed clouds, as well as viscous aerosols, were formed under controlled conditions at the CLOUD-CERN facility. The experimental results show a link between cloud particle properties and their unique optical fingerprints. The classification map presented here allows easier discrimination between various particles such as viscous organic aerosol, salt, ice, and liquid.
Peter A. Alpert and Daniel A. Knopf
Atmos. Chem. Phys., 16, 2083–2107, https://doi.org/10.5194/acp-16-2083-2016, https://doi.org/10.5194/acp-16-2083-2016, 2016
Short summary
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A stochastic immersion freezing model is introduced capable of reproducing laboratory data for a variety of experimental methods using a time and surface area dependent ice nucleation process. The assumption that droplets contain identical surface area is evaluated. A quantitative uncertainty analysis of the laboratory observed freezing process is presented. Our results imply that ice nuclei surface area assumptions are crucial for interpretation of experimental immersion freezing results.
Robert Wagner, Alexei Kiselev, Ottmar Möhler, Harald Saathoff, and Isabelle Steinke
Atmos. Chem. Phys., 16, 2025–2042, https://doi.org/10.5194/acp-16-2025-2016, https://doi.org/10.5194/acp-16-2025-2016, 2016
Short summary
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We have investigated the enhancement of the ice nucleation ability of well-known and abundant ice nucleating particles like dust grains due to pre-activation. Temporary exposure to a low temperature (228 K) provokes that pores and surface cracks of the particles are filled with ice, which makes them better nuclei for the growth of macroscopic ice crystals at high temperatures (245–260 K).
M. L. López and E. E. Ávila
Atmos. Chem. Phys., 16, 927–932, https://doi.org/10.5194/acp-16-927-2016, https://doi.org/10.5194/acp-16-927-2016, 2016
Short summary
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This work deals with the origin and nature of atmospheric ice-nucleating particles (INPs). An accurate determination of the atmospheric INP concentration is relevant since INPs induce freezing in clouds, thus initiating an efficient mechanism for cloud particles to reach a precipitating size.
The effect of relative humidity on the INP concentration at ground level was analyzed and discussed.
B. Nagare, C. Marcolli, O. Stetzer, and U. Lohmann
Atmos. Chem. Phys., 15, 13759–13776, https://doi.org/10.5194/acp-15-13759-2015, https://doi.org/10.5194/acp-15-13759-2015, 2015
Short summary
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We determined collision efficiencies of cloud droplets with aerosol particles experimentally and found that they were around 1 order of magnitude higher than theoretical formulations that include Brownian diffusion, impaction, interception, thermophoretic, diffusiophoretic and electric forces. This is most probably due to uncertainties and inaccuracies in the theoretical formulations of thermophoretic and diffusiophoretic processes.
Cited articles
Amato, P., Joly, M., Schaupp, C., Attard, E., Möhler, O., Morris, C. E.,
Brunet, Y., and Delort, A.-M.: Survival and ice nucleation activity of
bacteria as aerosols in a cloud simulation chamber, Atmos. Chem. Phys., 15,
6455–6465, https://doi.org/10.5194/acp-15-6455-2015, 2015.
Attard, E., Yang, H., Delort, A.-M., Amato, P., Pöschl, U., Glaux, C.,
Koop, T., and Morris, C. E.: Effects of atmospheric conditions on ice
nucleation activity of Pseudomonas, Atmos. Chem. Phys., 12,
10667–10677, https://doi.org/10.5194/acp-12-10667-2012, 2012.
Augustin, S., Wex, H., Niedermeier, D., Pummer, B., Grothe, H., Hartmann, S.,
Tomsche, L., Clauss, T., Voigtländer, J., Ignatius, K., and Stratmann,
F.: Immersion freezing of birch pollen washing water, Atmos. Chem. Phys., 13,
10989–11003, https://doi.org/10.5194/acp-13-10989-2013, 2013.
Bauer, H., Giebl, H., Hitzenberger, R., Kasper-Giebl, A., Reischl, G.,
Zibuschka, F., and Puxbaum, H.: Airborne bacteria as cloud condensation
nuclei, J. Geophys. Res.-Atmos., 108, 4658, https://doi.org/10.1029/2003jd003545, 2003.
Boulter, J. E., Cziczo, D. J., Middlebrook, A. M., Thomson, D. S., and
Murphy, D. M.: Design and performance of a pumped counterflow virtual
impactor, Aerosol Sci. Tech., 40, 969–976, https://doi.org/10.1080/02786820600840984,
2006.
Burrows, S. M., Hoose, C., Pöschl, U., and Lawrence, M. G.: Ice nuclei in
marine air: biogenic particles or dust?, Atmos. Chem. Phys., 13, 245–267,
https://doi.org/10.5194/acp-13-245-2013, 2013.
Cantrell, W. and Heymsfield, A.: Production of ice in tropospheric clouds –
A review, B. Am. Meteorol. Soc., 86, 795–807, 2005.
Conen, F., Stopelli, E., and Zimmermann, L.: Clues that decaying leaves
enrich Arctic air with ice nucleating particles, Atmos. Environ., 129,
91–94, https://doi.org/10.1016/j.atmosenv.2016.01.027, 2016.
Creamean, J. M., Suski, K. J., Rosenfeld, D., Cazorla, A., DeMott, P. J.,
Sullivan, R. C., White, A. B., Ralph, F. M., Minnis, P., Comstock, J. M.,
Tomlinson, J. M., and Prather, K. A.: Dust and Biological Aerosols from the
Sahara and Asia Influence Precipitation in the Western U.S., Science, 339,
1572–1578, 2013.
Czerwieniec, G. A., Russell, S. C., Tobias, H. J., Pitesky, M. E., Fergenson,
D. P., Steele, P., Srivastava, A., Horn, J. M., Frank, M., Gard, E. E., and
Lebrilla, C. B.: Stable isotope labeling of entire Bacillus atrophaeus spores
and vegetative cells using bioaerosol mass spectrometry, Anal. Chem., 77,
1081–1087, https://doi.org/10.1021/ac0488098, 2005.
DeMott, P. J. and Prenni, A. J.: New Directions: Need for defining the
numbers and sources of biological aerosols acting as ice nuclei, Atmos.
Environ., 44, 1944–1945, 2010.
Despres, V. R., Huffman, J. A., Burrows, S. M., Hoose, C., Safatov, A. S.,
Buryak, G., Fröhlich-Nowoisky, J., Elbert, W., Andreae, M. O.,
Pöschl, U., and Jaenicke, R.: Primary biological aerosol particles in the
atmosphere: a review, Tellus B, 64, 15598, https://doi.org/10.3402/tellusb.v64i0.15598,
2012.
Diehl, K., Quick, C., Matthias-Maser, S., Mitra, S. K., and Jaenicke, R.: The
ice nucleating ability of pollen – Part I: Laboratory studies in deposition
and condensation freezing modes, Atmos. Res., 58, 75–87, 2001.
Fahey, D. W., Gao, R.-S., Möhler, O., Saathoff, H., Schiller, C., Ebert,
V., Krämer, M., Peter, T., Amarouche, N., Avallone, L. M., Bauer, R.,
Bozóki, Z., Christensen, L. E., Davis, S. M., Durry, G., Dyroff, C.,
Herman, R. L., Hunsmann, S., Khaykin, S. M., Mackrodt, P., Meyer, J., Smith,
J. B., Spelten, N., Troy, R. F., Vömel, H., Wagner, S., and Wienhold, F.
G.: The AquaVIT-1 intercomparison of atmospheric water vapor measurement
techniques, Atmos. Meas. Tech., 7, 3177–3213,
https://doi.org/10.5194/amt-7-3177-2014, 2014.
Fergenson, D. P., Pitesky, M. E., Tobias, H. J., Steele, P. T., Czerwieniec,
G. A., Russell, S. C., Lebrilla, C. B., Horn, J. M., Coffee, K. R.,
Srivastava, A., Pillai, S. P., Shih, M. T. P., Hall, H. L., Ramponi, A. J.,
Chang, J. T., Langlois, R. G., Estacio, P. L., Hadley, R. T., Frank, M., and
Gard, E. E.: Reagentless detection and classification of individual
bioaerosol particles in seconds, Anal. Chem., 76, 373–378, 2004.
Franc, G. D. and DeMott, P. J.: Cloud activation characteristics of airborne
Erwinia carotovora cells, J. Appl. Meteorol., 37, 1293–1300,
https://doi.org/10.1175/1520-0450(1998)037<1293:Cacoae>2.0.Co;2, 1998.
Fröhlich-Nowoisky, J., Hill, T. C. J., Pummer, B. G., Yordanova, P.,
Franc, G. D., and Pöschl, U.: Ice nucleation activity in the widespread
soil fungus Mortierella alpina, Biogeosciences, 12, 1057–1071,
https://doi.org/10.5194/bg-12-1057-2015, 2015.
Gallavardin, S. J., Froyd, K. D., Lohmann, U., Moehler, O., Murphy, D. M.,
and Cziczo, D. J.: Single Particle Laser Mass Spectrometry Applied to
Differential Ice Nucleation Experiments at the AIDA Chamber, Aerosol Sci.
Tech., 42, 773–791, 2008.
Govindarajan, A. G. and Lindow, S. E.: Size of bacterial ice-nucleation sites
measured in situ by radiation inactivation analysis, P. Natl. Acad. Sci. USA,
85, 1334–1338, 1988.
Hader, J. D., Wright, T. P., and Petters, M. D.: Contribution of pollen to
atmospheric ice nuclei concentrations, Atmos. Chem. Phys., 14, 5433–5449,
https://doi.org/10.5194/acp-14-5433-2014, 2014.
Hartmann, S., Augustin, S., Clauss, T., Wex, H., Šantl-Temkiv, T.,
Voigtländer, J., Niedermeier, D., and Stratmann, F.: Immersion freezing
of ice nucleation active protein complexes, Atmos. Chem. Phys., 13,
5751–5766, https://doi.org/10.5194/acp-13-5751-2013, 2013.
Hiranuma, N., Möhler, O., Kulkarni, G., Schnaiter, M., Vogt, S.,
Vochezer, P., Järvinen, E., Wagner, R., Bell, D. M., Wilson, J.,
Zelenyuk, A., and Cziczo, D. J.: Development and characterization of an
ice-selecting pumped counterflow virtual impactor (IS-PCVI) to study ice
crystal residuals, Atmos. Meas. Tech., 9, 3817–3836,
https://doi.org/10.5194/amt-9-3817-2016, 2016.
Hoose, C., Kristjansson, J. E., and Burrows, S. M.: How important is
biological ice nucleation in clouds on a global scale?, Environ. Res. Lett.,
5, 7, 2010.
IPCC: Summary for Policymakers, in: Climate Change 2013: The Physical Science
Basis, Contribution of Working Group I to the Fifth Assessment Report of the
Intergovernmental Panel on Climate Change, Cambridge, United Kingdom and New
York, NY, USA, 1–30, 2013.
Lindow, S. E., Arny, D. C., and Upper, C. D.: Bacterial Ice Nucleation – a
Factor in Frost Injury to Plants, Plant. Physiol., 70, 1084–1089, 1982.
Lindow, S. E., Lahue, E., Govindarajan, A. G., Panopoulos, N. J., and Gies,
D.: Localization of Ice Nucleation Activity and the Icec Gene-Product in
Pseudomonas-Syringae and Escherichia-Coli, Mol. Plant. Microbe. In., 2,
262–272, https://doi.org/10.1094/Mpmi-2-262, 1989.
Liu, P. S. K., Deng, R., Smith, K. A., Williams, L. R., Jayne, J. T.,
Canagaratna, M. R., Moore, K., Onasch, T. B., Worsnop, D. R., and Deshler,
T.: Transmission efficiency of an aerodynamic focusing lens system:
Comparison of model calculations and laboratory measurements for the Aerodyne
Aerosol Mass Spectrometer, Aerosol Sci. Tech., 41, 721–733, 2007.
Maki, L. R., Galyan, E. L., Changchi. M., and Caldwell, D. R.: Ice Nucleation
Induced by Pseudomonas-Syringae, Appl. Microbiol., 28, 456–459, 1974.
Maki, L. R. and Willoughby, K. J.: Bacteria as Biogenic Sources of Freezing
Nuclei, J. Appl. Meteorol., 17, 1049–1053,
https://doi.org/10.1175/1520-0450(1978)017<1049:Babsof>2.0.Co;2, 1978.
Möhler, O., Stetzer, O., Schaefers, S., Linke, C., Schnaiter, M., Tiede,
R., Saathoff, H., Krämer, M., Mangold, A., Budz, P., Zink, P., Schreiner,
J., Mauersberger, K., Haag, W., Kärcher, B., and Schurath, U.:
Experimental investigation of homogeneous freezing of sulphuric acid
particles in the aerosol chamber AIDA, Atmos. Chem. Phys., 3, 211–223,
https://doi.org/10.5194/acp-3-211-2003, 2003.
Möhler, O., DeMott, P. J., Vali, G., and Levin, Z.: Microbiology and
atmospheric processes: the role of biological particles in cloud physics,
Biogeosciences, 4, 1059–1071, https://doi.org/10.5194/bg-4-1059-2007, 2007.
Möhler, O., Georgakopoulos, D. G., Morris, C. E., Benz, S., Ebert, V.,
Hunsmann, S., Saathoff, H., Schnaiter, M., and Wagner, R.: Heterogeneous ice
nucleation activity of bacteria: new laboratory experiments at simulated
cloud conditions, Biogeosciences, 5, 1425–1435,
https://doi.org/10.5194/bg-5-1425-2008, 2008.
Morris, C. E., Georgakopoulos, D. G., and Sands, D. C.: Ice nucleation active
bacteria and their potential role in precipitation, J. Phys. Iv., 121, 87–103,
https://doi.org/10.1051/jp4:2004121004, 2004.
Murray, B. J., O'Sullivan, D., Atkinson, J. D., and Webb, M. E.: Ice
nucleation by particles immersed in supercooled cloud droplets, Chem. Soc. Rev.,
41, 6519–6554, https://doi.org/10.1039/c2cs35200a, 2012.
Oehm, C. C., Amato, P., Attard, E., Delort, A.-M., Morris, C., Kiselev, A.,
Stetzer, O., Möhler, O., and Leisner, T.: Laboratory studies with
cloud-derived Bacterial Cells acting as Ice Nuclei in the Immersion and
Deposition Mode, EGU General Assembly 2012, 23–27 April, Vienna, Austria,
2012.
O'Sullivan, D., Murray, B. J., Ross, J. F., and Webb, M. E.: The adsorption
of fungal ice-nucleating proteins on mineral dusts: a terrestrial reservoir
of atmospheric ice-nucleating particles, Atmos. Chem. Phys., 16, 7879–7887,
https://doi.org/10.5194/acp-16-7879-2016, 2016.
Pandey, R., Usui, K., Livingstone, R. A., Fischer, S. A., Pfaendtner, J.,
Backus, E. H. G., Nagata, Y., Fröhlich-Nowoisky, J., Schmuser, L., Mauri,
S., Scheel, J. F., Knopf, D. A., Pöschl, U., Bonn, M., and Weidner, T.:
Ice-nucleating bacteria control the order and dynamics of interfacial water,
Sci Adv, 2, e1501630, https://doi.org/10.1126/sciadv.1501630, 2016.
Peters, T. M., Ott, D., and O'Shaughnessy, P. T.: Comparison of the Grimm
1.108 and 1.109 portable aerosol spectrometer to the TSI 3321 aerodynamic
particle sizer for dry particles, Ann. Occup. Hyg., 50, 843–850, 2006.
Phillips, V. T. J., Andronache, C., Christner, B., Morris, C. E., Sands, D.
C., Bansemer, A., Lauer, A., McNaughton, C., and Seman, C.: Potential impacts
from biological aerosols on ensembles of continental clouds simulated
numerically, Biogeosciences, 6, 987–1014,
https://doi.org/10.5194/bg-6-987-2009, 2009.
Polen, M., Lawlis, E., and Sullivan, R. C.: The unstable ice nucleation
properties of Snomax (R) bacterial particles, J. Geophys. Res.-Atmos., 121,
11666–11678, 2016.
Pratt, K. A., DeMott, P. J., French, J. R., Wang, Z., Westphal, D. L.,
Heymsfield, A. J., Twohy, C. H., Prenni, A. J., and Prather, K. A.: In situ
detection of biological particles in cloud ice-crystals, Nat. Geosci., 2,
398–401, 2009.
Pruppacher, H. R. and Klett, J. D.: Microphysics of Clouds and Precipitation,
Atmospheric and Oceanographic Sciences Library, Springer, Netherlands, 2010.
Pummer, B. G., Bauer, H., Bernardi, J., Bleicher, S., and Grothe, H.:
Suspendable macromolecules are responsible for ice nucleation activity of
birch and conifer pollen, Atmos. Chem. Phys., 12, 2541–2550,
https://doi.org/10.5194/acp-12-2541-2012, 2012.
Šantl-Temkiv, T., Sahyoun, M., Finster, K., Hartmann, S.,
Augustin-Bauditz, S., Stratmann, F., Wex, H., Clauss, T., Nielsen, N. W.,
Sørensen, J. H., Korsholm, U. S., Wick, L. Y., and Karlson, U. G.:
Characterization of airborne ice-nucleation-active bacteria and bacterial
fragments, Atmos. Environ., 109, 105–117,
https://doi.org/10.1016/j.atmosenv.2015.02.060, 2015.
Schnell, R. C. and Vali, G.: Biogenic Ice Nuclei: Part I, Terrestrial and
Marine Sources, J. Atmos. Sci., 33, 1554–1564,
https://doi.org/10.1175/1520-0469(1976)033<1554:BINPIT>2.0.CO;2, 1976.
Sharma, P. K. and Rao, K. H.: Analysis of different approaches for evaluation
of surface energy of microbial cells by contact angle goniometry, Adv.
Colloid. Interfac., 98, 34—463, https://doi.org/10.1016/S0001-8686(02)00004-0, 2002.
Simpson, E. L., Connolly, P. J., and McFiggans, G.: Competition for water
vapour results in suppression of ice formation in mixed-phase clouds, Atmos.
Chem. Phys., 18, 7237–7250, https://doi.org/10.5194/acp-18-7237-2018, 2018.
Spracklen, D. V. and Heald, C. L.: The contribution of fungal spores and
bacteria to regional and global aerosol number and ice nucleation immersion
freezing rates, Atmos. Chem. Phys., 14, 9051–9059,
https://doi.org/10.5194/acp-14-9051-2014, 2014.
Srivastava, A., Pitesky, M. E., Steele, P. T., Tobias, H. J., Fergenson, D.
P., Horn, J. M., Russell, S. C., Czerwieniec, G. A., Lebrilla, C. S., Gard,
E. E., and Frank, M.: Comprehensive assignment of mass spectral signatures
from individual Bacillus atrophaeus spores in matrix-free laser
desorption/ionization bioaerosol mass spectrometry, Anal. Chem., 77,
3315–3323, 2005.
Suski, K. J.: Activation of Intact Bacteria and Bacterial Fragments Mixed
with Agar as Cloud Droplets and Ice Crystals in Cloud Chamber Experiments,
data set, available at:
https://dtn2.pnl.gov/data/release/2018_Suski_et_al_Bacteria_Paper/,
last access: 30 May 2018.
Turner, M. A., Arellano, F., and Kozloff, L. M.: 3 Separate Classes of
Bacterial Ice Nucleation Structures, J. Bacteriol., 172, 2521–2526, 1990.
Turner, M. A., Arellano, F., and Kozloff, L. M.: Components of Ice Nucleation
Structures of Bacteria, J. Bacteriol., 173, 6515–6527, 1991.
Vaden, T. D., Imre, D., Beranek, J., and Zelenyuk, A.: Extending the
Capabilities of Single Particle Mass Spectrometry: I. Measurements of Aerosol
Number Concentration, Size Distribution, and Asphericity, Aerosol Sci.
Technol., 45, 113–124, https://doi.org/10.1080/02786826.2010.526155, 2011a.
Vaden, T. D., Imre, D., Beranek, J., and Zelenyuk, A.: Extending the
Capabilities of Single Particle Mass Spectrometry: II. Measurements of
Aerosol Particle Density without DMA, Aerosol Sci. Technol., 45, 125–135,
https://doi.org/10.1080/02786826.2010.526156, 2011b.
Vali, G., Christensen, M., Fresh, R. W., Galyan, E. L., Maki, L. R., and
Schnell, R. C.: Biogenic Ice Nuclei, 2. Bacterial Sources, J. Atmos. Sci.,
33, 1565–1570, 1976.
Vali, G., Rogers, D. C., Gordon, D., Saunders, C. P. R., Reischel, M., and
Black, R.: Aerosol and Nucleation Research, in: Support of NASA Cloud Physics
Experiments in Space, NASA Final Report, 1–86, 1978.
Vali, G., DeMott, P. J., Möhler, O., and Whale, T. F.: Technical Note: A
proposal for ice nucleation terminology, Atmos. Chem. Phys., 15,
10263–10270, https://doi.org/10.5194/acp-15-10263-2015, 2015.
Wagner, R. and Möhler, O.: Heterogeneous ice nucleation ability of
crystalline sodium chloride dihydrate particles, J. Geophys. Res.-Atmos.,
118, 4610–4622, 2013.
Wex, H., Augustin-Bauditz, S., Boose, Y., Budke, C., Curtius, J., Diehl, K.,
Dreyer, A., Frank, F., Hartmann, S., Hiranuma, N., Jantsch, E., Kanji, Z. A.,
Kiselev, A., Koop, T., Möhler, O., Niedermeier, D., Nillius, B.,
Rösch, M., Rose, D., Schmidt, C., Steinke, I., and Stratmann, F.:
Intercomparing different devices for the investigation of ice nucleating
particles using Snomax® as test substance,
Atmos. Chem. Phys., 15, 1463–1485, https://doi.org/10.5194/acp-15-1463-2015,
2015.
Wolber, P. K., Deininger, C. A., Southworth, M. W., Vandekerckhove, J.,
Vanmontagu, M., and Warren, G. J.: Identification and Purification of a
Bacterial Ice-Nucleation Protein, P. Natl. Acad. Sci. USA, 83, 7256–7260,
https://doi.org/10.1073/pnas.83.19.7256, 1986.
Wolf, R., Slowik, J. G., Schaupp, C., Amato, P., Saathoff, H., Möhler,
O., Prevot, A. S. H., and Baltensperger, U.: Characterization of
ice-nucleating bacteria using on-line electron impact ionization aerosol mass
spectrometry, J. Mass. Spectrom., 50, 662–671, https://doi.org/10.1002/jms.3573, 2015.
Yankofsky, S. A., Levin, Z., Bertold, T., and Sandlerman, N.: Some Basic
Characteristics of Bacterial Freezing Nuclei, J. Appl. Meteorol., 20,
1013–1019, https://doi.org/10.1175/1520-0450(1981)020<1013:Sbcobf>2.0.Co;2, 1981.
Zawadowicz, M. A., Froyd, K. D., Murphy, D. M., and Cziczo, D. J.: Improved
identification of primary biological aerosol particles using single-particle
mass spectrometry, Atmos. Chem. Phys., 17, 7193–7212,
https://doi.org/10.5194/acp-17-7193-2017, 2017.
Zelenyuk, A., Imre, D., Cai, Y., Mueller, K., Han, Y. P., and Imrich, P.:
SpectraMiner, an interactive data mining and visualization software for
single particle mass spectroscopy: A laboratory test case, Int. J. Mass
Spectrom., 258, 58–73, https://doi.org/10.1016/j.ijms.2006.06.015, 2006.
Zelenyuk, A., Imre, D., Nam, E. J., Han, Y. P., and Mueller, K.:
ClusterSculptor: Software for expert-steered classification of single
particle mass spectra, Int. J. Mass Spectrom., 275, 1–10,
https://doi.org/10.1016/j.ijms.2008.04.033, 2008.
Zelenyuk, A., Yang, J., Choi, E., and Imre, D.: SPLAT II: An Aircraft
Compatible, Ultra-Sensitive, High Precision Instrument for In-Situ
Characterization of the Size and Composition of Fine and Ultrafine Particles,
Aerosol Sci. Technol., 43, 411–424, https://doi.org/10.1080/02786820802709243, 2009.
Zelenyuk, A., Imre, D., Wilson, J., Zhang, Z. Y., Wang, J., and Mueller, K.:
Airborne Single Particle Mass Spectrometers (SPLAT II & miniSPLAT) and New
Software for Data Visualization and Analysis in a Geo-Spatial Context, J. Am.
Soc. Mass Spectrom., 26, 257–270, https://doi.org/10.1007/s13361-014-1043-4, 2015.
Short summary
This work investigates the cloud condensation nuclei and ice nucleation activity of bacteria using cloud chamber data and a single particle mass spectrometer. The size and chemical composition of the cloud residuals show that bacterial fragments mixed with agar growth media activate preferentially over intact bacteria cells as cloud condensation nuclei. Intact bacteria cells do not make it into cloud droplets; they thus cannot serve as immersion-mode ice nucleating particles.
This work investigates the cloud condensation nuclei and ice nucleation activity of bacteria...
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