Articles | Volume 17, issue 13
https://doi.org/10.5194/acp-17-8509-2017
https://doi.org/10.5194/acp-17-8509-2017
Research article
 | 
13 Jul 2017
Research article |  | 13 Jul 2017

The effect of hydroxyl functional groups and molar mass on the viscosity of non-crystalline organic and organic–water particles

James W. Grayson, Erin Evoy, Mijung Song, Yangxi Chu, Adrian Maclean, Allena Nguyen, Mary Alice Upshur, Marzieh Ebrahimi, Chak K. Chan, Franz M. Geiger, Regan J. Thomson, and Allan K. Bertram

Related authors

Viscosities, diffusion coefficients, and mixing times of intrinsic fluorescent organic molecules in brown limonene secondary organic aerosol and tests of the Stokes–Einstein equation
Dagny A. Ullmann, Mallory L. Hinks, Adrian M. Maclean, Christopher L. Butenhoff, James W. Grayson, Kelley Barsanti, Jose L. Jimenez, Sergey A. Nizkorodov, Saeid Kamal, and Allan K. Bertram
Atmos. Chem. Phys., 19, 1491–1503, https://doi.org/10.5194/acp-19-1491-2019,https://doi.org/10.5194/acp-19-1491-2019, 2019
Short summary
Mixing times of organic molecules within secondary organic aerosol particles: a global planetary boundary layer perspective
Adrian M. Maclean, Christopher L. Butenhoff, James W. Grayson, Kelley Barsanti, Jose L. Jimenez, and Allan K. Bertram
Atmos. Chem. Phys., 17, 13037–13048, https://doi.org/10.5194/acp-17-13037-2017,https://doi.org/10.5194/acp-17-13037-2017, 2017
Short summary
Observations and implications of liquid–liquid phase separation at high relative humidities in secondary organic material produced by α-pinene ozonolysis without inorganic salts
Lindsay Renbaum-Wolff, Mijung Song, Claudia Marcolli, Yue Zhang, Pengfei F. Liu, James W. Grayson, Franz M. Geiger, Scot T. Martin, and Allan K. Bertram
Atmos. Chem. Phys., 16, 7969–7979, https://doi.org/10.5194/acp-16-7969-2016,https://doi.org/10.5194/acp-16-7969-2016, 2016
Effect of varying experimental conditions on the viscosity of α-pinene derived secondary organic material
James W. Grayson, Yue Zhang, Anke Mutzel, Lindsay Renbaum-Wolff, Olaf Böge, Saeid Kamal, Hartmut Herrmann, Scot T. Martin, and Allan K. Bertram
Atmos. Chem. Phys., 16, 6027–6040, https://doi.org/10.5194/acp-16-6027-2016,https://doi.org/10.5194/acp-16-6027-2016, 2016
Short summary

Related subject area

Subject: Aerosols | Research Activity: Laboratory Studies | Altitude Range: Troposphere | Science Focus: Physics (physical properties and processes)
Role of sea spray aerosol at the air–sea interface in transporting aromatic acids to the atmosphere
Yaru Song, Jianlong Li, Narcisse Tsona Tchinda, Kun Li, and Lin Du
Atmos. Chem. Phys., 24, 5847–5862, https://doi.org/10.5194/acp-24-5847-2024,https://doi.org/10.5194/acp-24-5847-2024, 2024
Short summary
Modeling the influence of carbon branching structure on secondary organic aerosol formation via multiphase reactions of alkanes
Azad Madhu, Myoseon Jang, and Yujin Jo
Atmos. Chem. Phys., 24, 5585–5602, https://doi.org/10.5194/acp-24-5585-2024,https://doi.org/10.5194/acp-24-5585-2024, 2024
Short summary
Technical note: Characterization of a single-beam gradient force aerosol optical tweezer for droplet trapping, phase transition monitoring, and morphology studies
Xiangyu Pei, Yikan Meng, Yueling Chen, Huichao Liu, Yao Song, Zhengning Xu, Fei Zhang, Thomas C. Preston, and Zhibin Wang
Atmos. Chem. Phys., 24, 5235–5246, https://doi.org/10.5194/acp-24-5235-2024,https://doi.org/10.5194/acp-24-5235-2024, 2024
Short summary
Soot aerosols from commercial aviation engines are poor ice-nucleating particles at cirrus cloud temperatures
Baptiste Testa, Lukas Durdina, Peter A. Alpert, Fabian Mahrt, Christopher H. Dreimol, Jacinta Edebeli, Curdin Spirig, Zachary C. J. Decker, Julien Anet, and Zamin A. Kanji
Atmos. Chem. Phys., 24, 4537–4567, https://doi.org/10.5194/acp-24-4537-2024,https://doi.org/10.5194/acp-24-4537-2024, 2024
Short summary
Contribution of brown carbon to light absorption in emissions of European residential biomass combustion appliances
Satish Basnet, Anni Hartikainen, Aki Virkkula, Pasi Yli-Pirilä, Miika Kortelainen, Heikki Suhonen, Laura Kilpeläinen, Mika Ihalainen, Sampsa Väätäinen, Juho Louhisalmi, Markus Somero, Jarkko Tissari, Gert Jakobi, Ralf Zimmermann, Antti Kilpeläinen, and Olli Sippula
Atmos. Chem. Phys., 24, 3197–3215, https://doi.org/10.5194/acp-24-3197-2024,https://doi.org/10.5194/acp-24-3197-2024, 2024
Short summary

Cited articles

Achard, C., Dussap, C. G., and Gros, J.-B.: Prédiction de l'activité de l'eau, des températures d'ébullition et de congélation de solutions aqueuses de sucres par un modèle UNIFAC, Ind. Aliment. Agric., 109, 93–101, 1992.
Baltensperger, U., Kalberer, M., Dommen, J., Paulsen, D., Alfarra, M. R., Coe, H., Fisseha, R., Gascho, A., Gysel, M., Nyeki, S., Sax, M., Steinbacher, M., Prevot, A. S. H., Sjögren, S., Weingartner, E., and Zenobi, R.: Secondary organic aerosols from anthropogenic and biogenic precursors, Faraday Discuss., 130, 265–278, https://doi.org/10.1039/b417367h, 2005.
Baltensperger, U., Dommen, J., Alfarra, M. R., Duplissy, J., Gaeggler, K., Metzger, A., Facchini, M. C., Decesari, S., Finessi, E., Reinnig, C., Schott, M., Warnke, J., Hoffmann, T., Klatzer, B., Puxbaum, H., Geiser, M., Savi, M., Lang, D., Kalberer, M., and Geiser, T.: Combined determination of the chemical composition and of health effects of secondary organic aerosols: The POLYSOA project, J. Aerosol Med. Pulm. Deliv., 21, 145–154, https://doi.org/10.1089/jamp.2007.0655, 2008.
Barbosa-Canovas, G. V.: Water activity in foods: Fundamentals and applications, Wiley-Blackwell, Hoboken, NJ, 2007.
Baudry, J., Charlaix, E., Tonck, A., and Mazuyer, D.: Experimental evidence for a large slip effect at a nonwetting fluid-solid interface, Langmuir, 17, 5232–5236, https://doi.org/10.1021/la0009994, 2001.
Download
Short summary
The viscosities of four polyols and three saccharides mixed with water were determined. The results from the polyol studies suggest viscosity increases by 1–2 orders of magnitude with the addition of an OH functional group to a carbon backbone. The results from the saccharide studies suggest that the viscosity of highly oxidized compounds is strongly dependent on molar mass and oligomerization of highly oxidized compounds in atmospheric SOM could lead to large increases in viscosity.
Altmetrics
Final-revised paper
Preprint