Articles | Volume 17, issue 13
https://doi.org/10.5194/acp-17-8509-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-17-8509-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
13 Jul 2017
Research article |
| 13 Jul 2017
The effect of hydroxyl functional groups and molar mass on the viscosity of non-crystalline organic and organic–water particles
James W. Grayson
CORRESPONDING AUTHOR
Department of Chemistry, University of British Columbia, 2036 Main Mall, Vancouver, BC, V6T 1Z1, Canada
Erin Evoy
Department of Chemistry, University of British Columbia, 2036 Main Mall, Vancouver, BC, V6T 1Z1, Canada
Mijung Song
Department of Chemistry, University of British Columbia, 2036 Main Mall, Vancouver, BC, V6T 1Z1, Canada
now at: Department of Earth and Environmental Sciences, Chonbuk National University, Jeollabuk-do, Republic of Korea
Yangxi Chu
Division of Environment and Sustainability, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong, China
Adrian Maclean
Department of Chemistry, University of British Columbia, 2036 Main Mall, Vancouver, BC, V6T 1Z1, Canada
Allena Nguyen
Department of Chemistry, University of British Columbia, 2036 Main Mall, Vancouver, BC, V6T 1Z1, Canada
Mary Alice Upshur
Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, Illinois, 60208, USA
Marzieh Ebrahimi
Department of Chemical and Biological Engineering, University of British Columbia, 2360 East Mall, Vancouver, BC, V6T 1Z3, Canada
Chak K. Chan
Division of Environment and Sustainability, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong, China
Department of Chemical and Biomolecular Engineering, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong, China
School of Energy and Environment, City University of Hong Kong, Tat Chee Avenue, Kowloon, Hong Kong, China
Franz M. Geiger
Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, Illinois, 60208, USA
Regan J. Thomson
Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, Illinois, 60208, USA
Allan K. Bertram
Department of Chemistry, University of British Columbia, 2036 Main Mall, Vancouver, BC, V6T 1Z1, Canada
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Cited
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- Going green: Development of a sustainable lipid-based enteric coating formulation for low-dose aspirin multiparticulate systems S. Schertel et al. 10.1016/j.ijpharm.2022.121453
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- Enhanced Nitrate Fraction: Enabling Urban Aerosol Particles to Remain in a Liquid State at Reduced Relative Humidity Y. Liu et al. 10.1029/2023GL105505
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- Volatility and Viscosity Are Correlated in Terpene Secondary Organic Aerosol Formed in a Flow Reactor W. Champion et al. 10.1021/acs.estlett.9b00412
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40 citations as recorded by crossref.
- Predicting the influence of particle size on the glass transition temperature and viscosity of secondary organic material M. Petters & S. Kasparoglu 10.1038/s41598-020-71490-0
- The effect of functional groups on the glass transition temperature of atmospheric organic compounds: a molecular dynamics study P. Siachouli et al. 10.1039/D4SM00405A
- The interplay between aqueous replacement reaction and the phase state of internally mixed organic/ammonium aerosols H. Yang et al. 10.5194/acp-24-11619-2024
- Observations on the unique phase transitions of inorganics relevant due to gluconic acid in particles Y. Zhu et al. 10.1016/j.atmosenv.2022.119313
- Influence of Relative Humidity and Composition on PM2.5 Phases in Northeast Asia C. Seong et al. 10.1021/acsearthspacechem.4c00019
- A core-shell box model for simulating viscosity dependent secondary organic aerosol (CSVA) and its application L. Jia & Y. Xu 10.1016/j.scitotenv.2021.147954
- High Viscosity and Two Phases Observed over a Range of Relative Humidities in Biomass Burning Organic Aerosol from Canadian Wildfires N. Gerrebos et al. 10.1021/acs.est.4c09148
- Ion-molecule interactions enable unexpected phase transitions in organic-inorganic aerosol D. Richards et al. 10.1126/sciadv.abb5643
- Evaluation of Biogenic Organic Aerosols in the Amazon Rainforest Using WRF‐Chem With MOSAIC J. Mao et al. 10.1029/2021JD034913
- Adsorption of phosphate from wastewater by a ZnO-ZnAl hydrotalcite Z. Liu et al. 10.1080/03067319.2019.1622696
- Quantifying the hygroscopic properties of cyclodextrin containing aerosol for drug delivery to the lungs C. Day et al. 10.1039/D0CP01385D
- Automatic materials characterization from infrared spectra using convolutional neural networks G. Jung et al. 10.1039/D2SC05892H
- Comparison of Approaches for Measuring and Predicting the Viscosity of Ternary Component Aerosol Particles G. Rovelli et al. 10.1021/acs.analchem.8b05353
- Going green: Development of a sustainable lipid-based enteric coating formulation for low-dose aspirin multiparticulate systems S. Schertel et al. 10.1016/j.ijpharm.2022.121453
- A facile method to synthesis of a highly acrylated epoxidized soybean oil with low viscosity: Combined experimental and computational approach S. Baghban et al. 10.1016/j.polymertesting.2022.107727
- Effect of inorganic-to-organic mass ratio on the heterogeneous OH reaction rates of erythritol: implications for atmospheric chemical stability of 2-methyltetrols R. Xu et al. 10.5194/acp-20-3879-2020
- Predicting the glass transition temperature and viscosity of secondary organic material using molecular composition W. DeRieux et al. 10.5194/acp-18-6331-2018
- Estimation of the Volatility and Apparent Activity Coefficient of Levoglucosan in Wood-Burning Organic Aerosols J. Zhang et al. 10.1021/acs.estlett.4c00608
- Predicting secondary organic aerosol phase state and viscosity and its effect on multiphase chemistry in a regional-scale air quality model R. Schmedding et al. 10.5194/acp-20-8201-2020
- The phase state and viscosity of organic aerosol and related impacts on atmospheric physicochemical processes: A review Y. Gou et al. 10.1016/j.atmosenv.2024.120985
- Secondary Organic Aerosol from Biomass Burning Phenolic Compounds and Nitrate Radicals can be Highly Viscous over a Wide Relative Humidity Range S. Nikkho et al. 10.1021/acs.est.4c06235
- Melanoidins from Shanxi aged vinegar: Characterization and behavior after in vitro simulated digestion and colonic fermentation J. Wang et al. 10.1016/j.foodchem.2024.141769
- Relationship between Structure, Functionality, and Viscosity for Aerosol-Mimicking Solutions Containing Ammonium Sulfate, Glyoxal, and a Series of Oxidized C1–C5 Compounds E. Gubbins et al. 10.1021/acsearthspacechem.9b00119
- Secondary organic aerosols derived from intermediate-volatility n-alkanes adopt low-viscous phase state T. Galeazzo et al. 10.5194/acp-24-5549-2024
- Effect of dry or wet substrate deposition on the organic volume fraction of core–shell aerosol particles H. Lee et al. 10.5194/amt-12-2033-2019
- Predictions of diffusion rates of large organic molecules in secondary organic aerosols using the Stokes–Einstein and fractional Stokes–Einstein relations E. Evoy et al. 10.5194/acp-19-10073-2019
- Emerging investigator series: chemical and physical properties of organic mixtures on indoor surfaces during HOMEChem R. O'Brien et al. 10.1039/D1EM00060H
- Amine Structure-Foam Behavior Relationship and Its Predictive Foam Model Used for Amine Selection for Design of Amine-based Carbon Dioxide (CO2) Capture Process P. Muchan et al. 10.2174/2210298101999201002094601
- Secondary Organic Aerosol from OH-Initiated Oxidation of Mixtures of d-Limonene and β-Myrcene S. Liu et al. 10.1021/acs.est.4c04870
- Viscosities, diffusion coefficients, and mixing times of intrinsic fluorescent organic molecules in brown limonene secondary organic aerosol and tests of the Stokes–Einstein equation D. Ullmann et al. 10.5194/acp-19-1491-2019
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- Insect Infestation Increases Viscosity of Biogenic Secondary Organic Aerosol N. Smith et al. 10.1021/acsearthspacechem.3c00007
- The viscosity of atmospherically relevant organic particles J. Reid et al. 10.1038/s41467-018-03027-z
- Liquid–liquid phase separation and viscosity within secondary organic aerosol generated from diesel fuel vapors M. Song et al. 10.5194/acp-19-12515-2019
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- Viscosity, Glass Formation, and Mixing Times within Secondary Organic Aerosol from Biomass Burning Phenolics K. Kiland et al. 10.1021/acsearthspacechem.3c00039
- Enhanced Nitrate Fraction: Enabling Urban Aerosol Particles to Remain in a Liquid State at Reduced Relative Humidity Y. Liu et al. 10.1029/2023GL105505
- Unified Description of Diffusion Coefficients from Small to Large Molecules in Organic–Water Mixtures E. Evoy et al. 10.1021/acs.jpca.9b11271
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Discussed (preprint)
Latest update: 02 Apr 2025
Short summary
The viscosities of four polyols and three saccharides mixed with water were determined. The results from the polyol studies suggest viscosity increases by 1–2 orders of magnitude with the addition of an OH functional group to a carbon backbone. The results from the saccharide studies suggest that the viscosity of highly oxidized compounds is strongly dependent on molar mass and oligomerization of highly oxidized compounds in atmospheric SOM could lead to large increases in viscosity.
The viscosities of four polyols and three saccharides mixed with water were determined. The...
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