Articles | Volume 17, issue 2
https://doi.org/10.5194/acp-17-1343-2017
https://doi.org/10.5194/acp-17-1343-2017
Research article
 | 
30 Jan 2017
Research article |  | 30 Jan 2017

Qualitative and quantitative analysis of atmospheric organosulfates in Centreville, Alabama

Anusha P. S. Hettiyadura, Thilina Jayarathne, Karsten Baumann, Allen H. Goldstein, Joost A. de Gouw, Abigail Koss, Frank N. Keutsch, Kate Skog, and Elizabeth A. Stone

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Cited articles

Allen, H. M., Draper, D. C., Ayres, B. R., Ault, A., Bondy, A., Takahama, S., Modini, R. L., Baumann, K., Edgerton, E., Knote, C., Laskin, A., Wang, B., and Fry, J. L.: Influence of crustal dust and sea spray supermicron particle concentrations and acidity on inorganic NO3 aerosol during the 2013 Southern Oxidant and Aerosol Study, Atmos. Chem. Phys., 15, 10669–10685, https://doi.org/10.5194/acp-15-10669-2015, 2015.
Altieri, K. E., Turpin, B. J., and Seitzinger, S. P.: Oligomers, organosulfates, and nitrooxy organosulfates in rainwater identified by ultra-high resolution electrospray ionization FT-ICR mass spectrometry, Atmos. Chem. Phys., 9, 2533–2542, https://doi.org/10.5194/acp-9-2533-2009, 2009.
Anderson, J. O., Thundiyil, J. G., and Stolbach, A.: Clearing the Air: A Review of the Effects of Particulate Matter Air Pollution on Human Health, J. Med. Toxicol., 8, 166–175, https://doi.org/10.1007/s13181-011-0203-1, 2011.
Attwood, A. R., Washenfelder, R. A., Brock, C. A., Hu, W., Baumann, K., Campuzano-Jost, P., Day, D. A., Edgerton, E. S., Murphy, D. M., Palm, B. B., McComiskey, A., Wagner, N. L., de Sá, S. S., Ortega, A., Martin, S. T., Jimenez, J. L., and Brown, S. S.: Trends in sulfate and organic aerosol mass in the Southeast U.S.: Impact on aerosol optical depth and radiative forcing, Geophys. Res. Lett., 41, 7701–7709, https://doi.org/10.1002/2014GL061669, 2014.
Budisulistiorini, S. H., Li, X., Bairai, S. T., Renfro, J., Liu, Y., Liu, Y. J., McKinney, K. A., Martin, S. T., McNeill, V. F., Pye, H. O. T., Nenes, A., Neff, M. E., Stone, E. A., Mueller, S., Knote, C., Shaw, S. L., Zhang, Z., Gold, A., and Surratt, J. D.: Examining the effects of anthropogenic emissions on isoprene-derived secondary organic aerosol formation during the 2013 Southern Oxidant and Aerosol Study (SOAS) at the Look Rock, Tennessee ground site, Atmos. Chem. Phys., 15, 8871–8888, https://doi.org/10.5194/acp-15-8871-2015, 2015.
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Short summary
Organosulfates are components of secondary organic aerosol (SOA) formed in the presence of sulfate. Herein, their abundance, identity, and potential to form as sampling artifacts were studied in Centreville, AL, USA. The 10 most abundant signals accounted for 58–78 % of the total, with at least 20–200 other species accounting for the remainder. These major species were largely associated with biogenic gases, like isoprene and monoterpenes, and are proposed targets for future standard development.
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