Articles | Volume 17, issue 2
https://doi.org/10.5194/acp-17-1343-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-17-1343-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Qualitative and quantitative analysis of atmospheric organosulfates in Centreville, Alabama
Anusha P. S. Hettiyadura
Department of Chemistry, University of Iowa, Iowa City, IA, USA
Thilina Jayarathne
Department of Chemistry, University of Iowa, Iowa City, IA, USA
Karsten Baumann
Atmospheric Research & Analysis, Inc., Cary, NC, USA
Allen H. Goldstein
Department of Environmental Science, Policy, and Management,
University of California, Berkeley, CA, USA
Department of Civil and Environmental Engineering, University of
California, Berkeley, CA, USA
Joost A. de Gouw
Chemical Sciences Division, Earth System Research Laboratory, National
Oceanic & Atmospheric Administration, Boulder, CO, USA
Abigail Koss
Chemical Sciences Division, Earth System Research Laboratory, National
Oceanic & Atmospheric Administration, Boulder, CO, USA
Frank N. Keutsch
Department of Chemistry, University of Wisconsin-Madison, Madison, WI,
USA
now at: School of Engineering and Applied Sciences and
Department of Chemistry & Chemical Biology, Harvard University,
Cambridge, MA, USA
Kate Skog
Department of Chemistry, University of Wisconsin-Madison, Madison, WI,
USA
now at: Department of Chemical & Environmental Engineering, Yale
University, New Haven, CT, USA
Elizabeth A. Stone
CORRESPONDING AUTHOR
Department of Chemistry, University of Iowa, Iowa City, IA, USA
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- Molecular Characterization of Organosulfates in Highly Polluted Atmosphere Using Ultra‐High‐Resolution Mass Spectrometry D. Cai et al. 10.1029/2019JD032253
- Anthropogenic–Biogenic Interactions at Night: Enhanced Formation of Secondary Aerosols and Particulate Nitrogen- and Sulfur-Containing Organics from β-Pinene Oxidation L. Xu et al. 10.1021/acs.est.0c07879
- Direct target and non-target analysis of urban aerosol sample extracts using atmospheric pressure photoionisation high-resolution mass spectrometry C. Giorio et al. 10.1016/j.chemosphere.2019.02.151
- Organic synthesis in the study of terpene-derived oxidation products in the atmosphere M. Upshur et al. 10.1039/D2NP00064D
- The secondary formation of organosulfates under interactions between biogenic emissions and anthropogenic pollutants in summer in Beijing Y. Wang et al. 10.5194/acp-18-10693-2018
- Accurate Computational Model for the Hydration Extent of Atmospherically Relevant Carbonyls on Aqueous Atmospheric Particles M. Elrod et al. 10.1021/acsearthspacechem.0c00322
- Molecular characteristics, sources, and formation pathways of organosulfur compounds in ambient aerosol in Guangzhou, South China H. Jiang et al. 10.5194/acp-22-6919-2022
- Chemical transformation of <i>α</i>-pinene-derived organosulfate via heterogeneous OH oxidation: implications for sources and environmental fates of atmospheric organosulfates R. Xu et al. 10.5194/acp-22-5685-2022
- Decreases in Epoxide-Driven Secondary Organic Aerosol Production under Highly Acidic Conditions: The Importance of Acid–Base Equilibria M. Cooke et al. 10.1021/acs.est.3c10851
- Molecular characterization of atmospheric organic aerosols: Contemporary applications of high-resolution mass spectrometry Q. Xie & A. Laskin 10.1016/j.trac.2024.117986
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Short summary
Organosulfates are components of secondary organic aerosol (SOA) formed in the presence of sulfate. Herein, their abundance, identity, and potential to form as sampling artifacts were studied in Centreville, AL, USA. The 10 most abundant signals accounted for 58–78 % of the total, with at least 20–200 other species accounting for the remainder. These major species were largely associated with biogenic gases, like isoprene and monoterpenes, and are proposed targets for future standard development.
Organosulfates are components of secondary organic aerosol (SOA) formed in the presence of...
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