Articles | Volume 16, issue 14
https://doi.org/10.5194/acp-16-9361-2016
https://doi.org/10.5194/acp-16-9361-2016
Research article
 | 
28 Jul 2016
Research article |  | 28 Jul 2016

Influence of seed aerosol surface area and oxidation rate on vapor wall deposition and SOA mass yields: a case study with α-pinene ozonolysis

Theodora Nah, Renee C. McVay, Xuan Zhang, Christopher M. Boyd, John H. Seinfeld, and Nga L. Ng

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Cited articles

Abramson, E., Imre, D., Beranek, J., Wilson, J., and Zelenyuk, A.: Experimental determination of chemical diffusion within secondary organic aerosol particles, Phys. Chem. Chem. Phys., 15, 2983–2991, https://doi.org/10.1039/c2cp44013j, 2013.
Bahreini, R., Keywood, M. D., Ng, N. L., Varutbangkul, V., Gao, S., Flagan, R. C., Seinfeld, J. H., Worsnop, D. R., and Jimenez, J. L.: Measurements of Secondary Organic Aerosol from Oxidation of Cycloalkenes, Terpenes, and m-Xylene Using an Aerodyne Aerosol Mass Spectrometer, Environ. Sci. Technol., 39, 5674–5688, https://doi.org/10.1021/es048061a, 2005.
Boyd, C. M., Sanchez, J., Xu, L., Eugene, A. J., Nah, T., Tuet, W. Y., Guzman, M. I., and Ng, N. L.: Secondary organic aerosol formation from the β-pinene + NO3 system: effect of humidity and peroxy radical fate, Atmos. Chem. Phys., 15, 7497–7522, https://doi.org/10.5194/acp-15-7497-2015, 2015.
Canagaratna, M. R., Jimenez, J. L., Kroll, J. H., Chen, Q., Kessler, S. H., Massoli, P., Hildebrandt Ruiz, L., Fortner, E., Williams, L. R., Wilson, K. R., Surratt, J. D., Donahue, N. M., Jayne, J. T., and Worsnop, D. R.: Elemental ratio measurements of organic compounds using aerosol mass spectrometry: characterization, improved calibration, and implications, Atmos. Chem. Phys., 15, 253–272, https://doi.org/10.5194/acp-15-253-2015, 2015.
Capouet, M., Müller, J. F., Ceulemans, K., Compernolle, S., Vereecken, L., and Peeters, J.: Modeling aerosol formation in alpha-pinene photo-oxidation experiments, J. Geophys. Res.-Atmos., 113, D02308, https://doi.org/10.1029/2007JD008995, 2008.
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Short summary
The influence of seed aerosol surface area and oxidation rate on SOA formation in α-pinene ozonolysis is studied. SOA growth rate and mass yields are independent of seed surface area, consistent with the condensation of SOA-forming vapors being dominated by quasi-equilibrium growth. Faster α-pinene oxidation rates and higher SOA mass yields are observed at increasing O3 concentrations, indicating that a faster α-pinene oxidation rate leads to rapidly produced SOA-forming oxidation products.
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