Influence of seed aerosol surface area and oxidation rate on vapor wall
deposition and SOA mass yields: a case study with <i>α</i>-pinene
ozonolysis

Nah, Theodora; McVay, Renee C.; Zhang, Xuan; Boyd, Christopher M.; Seinfeld, John H.; Ng, Nga L.

doi:10.5194/acp-16-9361-2016

Articles | Volume 16, issue 14

https://doi.org/10.5194/acp-16-9361-2016

© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.

https://doi.org/10.5194/acp-16-9361-2016

© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.

Articles | Volume 16, issue 14

Research article

|

28 Jul 2016

Research article |

| 28 Jul 2016

Influence of seed aerosol surface area and oxidation rate on vapor wall deposition and SOA mass yields: a case study with α-pinene ozonolysis

Theodora Nah, Renee C. McVay, Xuan Zhang, Christopher M. Boyd, John H. Seinfeld, and Nga L. Ng

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Apr 2016	201	103	3	307
May 2016	51	9	1	61
Jun 2016	15	11	3	29
Jul 2016	97	34	0	131
Aug 2016	75	63	2	140
Sep 2016	21	16	0	37
Oct 2016	22	10	0	32
Nov 2016	10	8	0	18
Dec 2016	9	21	0	30
Jan 2017	24	36	1	61
Feb 2017	16	25	2	43
Mar 2017	23	45	1	69
Apr 2017	26	53	2	81
May 2017	36	16	2	54
Jun 2017	31	11	2	44
Jul 2017	18	17	1	36
Aug 2017	14	9	0	23
Sep 2017	15	8	1	24
Oct 2017	18	20	0	38
Nov 2017	11	10	4	25
Dec 2017	23	15	2	40
Jan 2018	19	12	0	31
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Mar 2018	18	11	0	29
Apr 2018	18	12	0	30
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Jun 2018	11	9	0	20
Jul 2018	8	8	1	17
Aug 2018	20	11	0	31
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Oct 2018	17	20	2	39
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Jan 2021	15	8	0	23
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Jan 2023	18	23	0	41
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Apr 2023	10	11	0	21
May 2023	39	10	0	49
Jun 2023	44	5	2	51
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Oct 2023	47	6	1	54
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Jan 2024	45	5	3	53
Feb 2024	40	14	1	55
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Apr 2024	46	13	6	65
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Jun 2024	21	11	1	33
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Aug 2024	35	19	5	59
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Oct 2024	23	11	2	36
Nov 2024	20	6	4	30
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Jan 2025	20	7	5	32
Feb 2025	39	13	7	59
Mar 2025	20	9	2	31
Apr 2025	26	24	3	53
May 2025	29	8	0	37
Jun 2025	65	12	2	79
Jul 2025	37	16	3	56
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Sep 2025	64	16	1	81
Oct 2025	29	25	0	54
Nov 2025	36	20	4	60
Dec 2025	38	46	1	85
Jan 2026	52	26	8	86
Feb 2026	47	16	5	68
Mar 2026	18	7	2	27

Cumulative views and downloads (calculated since 04 Apr 2016)

Month	HTML	PDF	XML	Total
Apr 2016	201	103	3	307
May 2016	51	9	1	61
Jun 2016	15	11	3	29
Jul 2016	97	34	0	131
Aug 2016	75	63	2	140
Sep 2016	21	16	0	37
Oct 2016	22	10	0	32
Nov 2016	10	8	0	18
Dec 2016	9	21	0	30
Jan 2017	24	36	1	61
Feb 2017	16	25	2	43
Mar 2017	23	45	1	69
Apr 2017	26	53	2	81
May 2017	36	16	2	54
Jun 2017	31	11	2	44
Jul 2017	18	17	1	36
Aug 2017	14	9	0	23
Sep 2017	15	8	1	24
Oct 2017	18	20	0	38
Nov 2017	11	10	4	25
Dec 2017	23	15	2	40
Jan 2018	19	12	0	31
Feb 2018	12	8	0	20
Mar 2018	18	11	0	29
Apr 2018	18	12	0	30
May 2018	15	10	1	26
Jun 2018	11	9	0	20
Jul 2018	8	8	1	17
Aug 2018	20	11	0	31
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Oct 2018	17	20	2	39
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Jan 2023	18	23	0	41
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Apr 2023	10	11	0	21
May 2023	39	10	0	49
Jun 2023	44	5	2	51
Jul 2023	41	10	1	52
Aug 2023	44	11	3	58
Sep 2023	48	5	1	54
Oct 2023	47	6	1	54
Nov 2023	29	4	1	34
Dec 2023	49	14	0	63
Jan 2024	45	5	3	53
Feb 2024	40	14	1	55
Mar 2024	52	17	2	71
Apr 2024	46	13	6	65
May 2024	20	20	1	41
Jun 2024	21	11	1	33
Jul 2024	15	13	5	33
Aug 2024	35	19	5	59
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Oct 2024	23	11	2	36
Nov 2024	20	6	4	30
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Jan 2025	20	7	5	32
Feb 2025	39	13	7	59
Mar 2025	20	9	2	31
Apr 2025	26	24	3	53
May 2025	29	8	0	37
Jun 2025	65	12	2	79
Jul 2025	37	16	3	56
Aug 2025	48	21	1	70
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Oct 2025	29	25	0	54
Nov 2025	36	20	4	60
Dec 2025	38	46	1	85
Jan 2026	52	26	8	86
Feb 2026	47	16	5	68
Mar 2026	18	7	2	27

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Short summary

The influence of seed aerosol surface area and oxidation rate on SOA formation in α-pinene ozonolysis is studied. SOA growth rate and mass yields are independent of seed surface area, consistent with the condensation of SOA-forming vapors being dominated by quasi-equilibrium growth. Faster α-pinene oxidation rates and higher SOA mass yields are observed at increasing O₃ concentrations, indicating that a faster α-pinene oxidation rate leads to rapidly produced SOA-forming oxidation products.