Articles | Volume 16, issue 14
https://doi.org/10.5194/acp-16-9361-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-16-9361-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Influence of seed aerosol surface area and oxidation rate on vapor wall deposition and SOA mass yields: a case study with α-pinene ozonolysis
Theodora Nah
School of Chemical and Biomolecular Engineering, Georgia Institute of Technology, Atlanta, GA, USA
Renee C. McVay
Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, CA, USA
Xuan Zhang
Division of Engineering and Applied Science, California Institute of Technology, Pasadena, CA, USA
now at: Center for Aerosol and Cloud Chemistry, Aerodyne Research, Billerica, MA, USA
Christopher M. Boyd
School of Chemical and Biomolecular Engineering, Georgia Institute of Technology, Atlanta, GA, USA
John H. Seinfeld
Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, CA, USA
Division of Engineering and Applied Science, California Institute of Technology, Pasadena, CA, USA
School of Chemical and Biomolecular Engineering, Georgia Institute of Technology, Atlanta, GA, USA
School of Earth and Atmospheric Sciences, Georgia Institute of Technology, Atlanta, GA, USA
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Cited
63 citations as recorded by crossref.
- Role of Aerosol Liquid Water in Secondary Organic Aerosol Formation from Volatile Organic Compounds J. Faust et al. 10.1021/acs.est.6b04700
- Modelling organic aerosol concentrations and properties during ChArMEx summer campaigns of 2012 and 2013 in the western Mediterranean region M. Chrit et al. 10.5194/acp-17-12509-2017
- Unified Theory of Vapor–Wall Mass Transport in Teflon-Walled Environmental Chambers Y. Huang et al. 10.1021/acs.est.7b05575
- Temperature and acidity dependence of secondary organic aerosol formation from <i>α</i>-pinene ozonolysis with a compact chamber system Y. Deng et al. 10.5194/acp-21-5983-2021
- Atmospheric Processing of Nitrophenols and Nitrocresols From Biomass Burning Emissions H. Wang et al. 10.1029/2020JD033401
- Southeast Atmosphere Studies: learning from model-observation syntheses J. Mao et al. 10.5194/acp-18-2615-2018
- Functional Group Composition of Secondary Organic Aerosol Formed from Ozonolysis of α-Pinene Under High VOC and Autoxidation Conditions M. Claflin et al. 10.1021/acsearthspacechem.8b00117
- Reactions of C12–C14 n-Alkylcyclohexanes with Cl Atoms: Kinetics and Secondary Organic Aerosol Formation K. Wang et al. 10.1021/acs.est.1c08958
- Nitrate radicals and biogenic volatile organic compounds: oxidation, mechanisms, and organic aerosol N. Ng et al. 10.5194/acp-17-2103-2017
- Kinetic modeling of formation and evaporation of secondary organic aerosol from NO<sub>3</sub> oxidation of pure and mixed monoterpenes T. Berkemeier et al. 10.5194/acp-20-15513-2020
- Secondary organic aerosol formation in biomass-burning plumes: theoretical analysis of lab studies and ambient plumes Q. Bian et al. 10.5194/acp-17-5459-2017
- NOx enhances secondary organic aerosol formation from nighttime γ-terpinene ozonolysis L. Xu et al. 10.1016/j.atmosenv.2020.117375
- Impacts of α-pinene ozonolysis products on the morphology and optical properties of black carbon C. Yuan et al. 10.1016/j.atmosenv.2024.120337
- Secondary organic aerosol formation from in situ OH, O<sub>3</sub>, and NO<sub>3</sub> oxidation of ambient forest air in an oxidation flow reactor B. Palm et al. 10.5194/acp-17-5331-2017
- Chemical evolution of atmospheric organic carbon over multiple generations of oxidation G. Isaacman-VanWertz et al. 10.1038/s41557-018-0002-2
- Multi-generation chemical aging of <i>α</i>-pinene ozonolysis products by reactions with OH N. Wang et al. 10.5194/acp-18-3589-2018
- Compositional Evolution of Secondary Organic Aerosol as Temperature and Relative Humidity Cycle in Atmospherically Relevant Ranges Z. Zhao et al. 10.1021/acsearthspacechem.9b00232
- Effects of NO<sub><i>x</i></sub> and SO<sub>2</sub> on the secondary organic aerosol formation from photooxidation of <i>α</i>-pinene and limonene D. Zhao et al. 10.5194/acp-18-1611-2018
- Challenges in determining atmospheric organic aerosol volatility distributions using thermal evaporation techniques K. Cain et al. 10.1080/02786826.2020.1748172
- Computational Simulation of Secondary Organic Aerosol Formation in Laboratory Chambers S. Charan et al. 10.1021/acs.chemrev.9b00358
- Anthropogenic–Biogenic Interactions at Night: Enhanced Formation of Secondary Aerosols and Particulate Nitrogen- and Sulfur-Containing Organics from β-Pinene Oxidation L. Xu et al. 10.1021/acs.est.0c07879
- Particle Size Distribution Dynamics Can Help Constrain the Phase State of Secondary Organic Aerosol Y. He et al. 10.1021/acs.est.0c05796
- Atmospheric Processes of Aromatic Hydrocarbons in the Presence of Mineral Dust Particles in an Urban Environment Z. Yu & M. Jang 10.1021/acsearthspacechem.9b00195
- Influence of Particle Surface Area Concentration on the Production of Organic Particulate Matter in a Continuously Mixed Flow Reactor Y. Han et al. 10.1021/acs.est.8b07302
- A steady-state continuous flow chamber for the study of daytime and nighttime chemistry under atmospherically relevant NO levels X. Zhang et al. 10.5194/amt-11-2537-2018
- Effects of inorganic seed aerosols on the particulate products of aged 1,3,5-trimethylbenzene secondary organic aerosol M. Huang et al. 10.1016/j.atmosenv.2017.01.010
- Using GECKO-A to derive mechanistic understanding of secondary organic aerosol formation from the ubiquitous but understudied camphene I. Afreh et al. 10.5194/acp-21-11467-2021
- Computational simulation of the dynamics of secondary organic aerosol formation in an environmental chamber A. Sunol et al. 10.1080/02786826.2018.1427209
- Vapors Are Lost to Walls, Not to Particles on the Wall: Artifact-Corrected Parameters from Chamber Experiments and Implications for Global Secondary Organic Aerosol K. Bilsback et al. 10.1021/acs.est.2c03967
- Secondary organic aerosol formation from ambient air in an oxidation flow reactor in central Amazonia B. Palm et al. 10.5194/acp-18-467-2018
- Effect of NOx and SO2 on the photooxidation of methylglyoxal: Implications in secondary aerosol formation S. Wang et al. 10.1016/j.jes.2020.02.011
- Wall losses of oxygenated volatile organic compounds from oxidation of toluene: Effects of chamber volume and relative humidity S. Yu et al. 10.1016/j.jes.2021.09.026
- The Caltech Photooxidation Flow Tube reactor: design, fluid dynamics and characterization Y. Huang et al. 10.5194/amt-10-839-2017
- Primary emissions and secondary aerosol production potential from woodstoves for residential heating: Influence of the stove technology and combustion efficiency A. Bertrand et al. 10.1016/j.atmosenv.2017.09.005
- Secondary Organic Aerosol Formation from Healthy and Aphid-Stressed Scots Pine Emissions C. Faiola et al. 10.1021/acsearthspacechem.9b00118
- Nitrate radical oxidation of <i>γ</i>-terpinene: hydroxy nitrate, total organic nitrate, and secondary organic aerosol yields J. Slade et al. 10.5194/acp-17-8635-2017
- Secondary organic aerosol formation from α-methylstyrene atmospheric degradation: Role of NO level, relative humidity and inorganic seed aerosol M. Tajuelo et al. 10.1016/j.atmosres.2019.104631
- Efficient HOx Radical Production from Isoprene Nighttime Chemistry Z. Moo et al. 10.1021/acsearthspacechem.3c00323
- Collection of Nitrogen Dioxide for Nitrogen and Oxygen Isotope Determination─Laboratory and Environmental Chamber Evaluation D. Blum et al. 10.1021/acs.analchem.2c04672
- Water vapour effects on secondary organic aerosol formation in isoprene ozonolysis Y. Sakamoto et al. 10.1039/C6CP04521A
- Semivolatile POA and parameterized total combustion SOA in CMAQv5.2: impacts on source strength and partitioning B. Murphy et al. 10.5194/acp-17-11107-2017
- Characterization of organic nitrate constituents of secondary organic aerosol (SOA) from nitrate-radical-initiated oxidation of limonene using high-resolution chemical ionization mass spectrometry C. Faxon et al. 10.5194/acp-18-5467-2018
- Assessing the influence of NO<sub><i>x</i></sub> concentrations and relative humidity on secondary organic aerosol yields from <i>α</i>-pinene photo-oxidation through smog chamber experiments and modelling calculations L. Stirnweis et al. 10.5194/acp-17-5035-2017
- Review of Smog Chamber Experiments for Secondary Organic Aerosol Formation H. Kim et al. 10.3390/atmos15010115
- Modeling biogenic secondary organic aerosol (BSOA) formation from monoterpene reactions with NO3: A case study of the SOAS campaign using CMAQ M. Qin et al. 10.1016/j.atmosenv.2018.03.042
- Quantification of the role of stabilized Criegee intermediates in the formation of aerosols in limonene ozonolysis Y. Gong & Z. Chen 10.5194/acp-21-813-2021
- A computationally efficient model to represent the chemistry, thermodynamics, and microphysics of secondary organic aerosols (simpleSOM): model development and application to α-pinene SOA S. Jathar et al. 10.1039/D1EA00014D
- Constraining uncertainties in particle-wall deposition correction during SOA formation in chamber experiments T. Nah et al. 10.5194/acp-17-2297-2017
- Multi-day photochemical evolution of organic aerosol from biomass burning emissions A. Dearden et al. 10.1039/D3EA00111C
- Molecular characterization of alkyl nitrates in atmospheric aerosols by ion mobility mass spectrometry X. Zhang et al. 10.5194/amt-12-5535-2019
- Molecular composition of secondary organic aerosol from styrene under different NO and humidity conditions S. Yu et al. 10.1016/j.atmosres.2021.105950
- NH3 Weakens the Enhancing Effect of SO2 on Biogenic Secondary Organic Aerosol Formation L. Du et al. 10.1021/acs.estlett.2c00959
- Comparison of OH reactivity measurements in the atmospheric simulation chamber SAPHIR H. Fuchs et al. 10.5194/amt-10-4023-2017
- Variability in Aromatic Aerosol Yields under Very Low NOxConditions at Different HO2/RO2Regimes W. Peng et al. 10.1021/acs.est.1c04392
- Lability of secondary organic particulate matter P. Liu et al. 10.1073/pnas.1603138113
- Parameterized Yields of Semivolatile Products from Isoprene Oxidation under Different NOx Levels: Impacts of Chemical Aging and Wall-Loss of Reactive Gases L. Xing et al. 10.1021/acs.est.8b00373
- Secondary organic aerosol formation from OH-initiated oxidation of <i>m</i>-xylene: effects of relative humidity on yield and chemical composition Q. Zhang et al. 10.5194/acp-19-15007-2019
- Secondary Organic Aerosol Formation from Reaction of 3-Methylfuran with Nitrate Radicals T. Joo et al. 10.1021/acsearthspacechem.9b00068
- Direct Measurements of Gas/Particle Partitioning and Mass Accommodation Coefficients in Environmental Chambers J. Krechmer et al. 10.1021/acs.est.7b02144
- Secondary Organic Aerosol (SOA) from Nitrate Radical Oxidation of Monoterpenes: Effects of Temperature, Dilution, and Humidity on Aerosol Formation, Mixing, and Evaporation C. Boyd et al. 10.1021/acs.est.7b01460
- Simulating the impact of gas-wall partitioning on SOA formation using the explicit gas mechanism integrated with aqueous reactions containing electrolytes S. Han & M. Jang 10.1016/j.scitotenv.2020.141360
- Rebounding hygroscopic inorganic aerosol particles: Liquids, gels, and hydrates Y. Li et al. 10.1080/02786826.2016.1263384
- Recent advances in understanding secondary organic aerosol: Implications for global climate forcing M. Shrivastava et al. 10.1002/2016RG000540
63 citations as recorded by crossref.
- Role of Aerosol Liquid Water in Secondary Organic Aerosol Formation from Volatile Organic Compounds J. Faust et al. 10.1021/acs.est.6b04700
- Modelling organic aerosol concentrations and properties during ChArMEx summer campaigns of 2012 and 2013 in the western Mediterranean region M. Chrit et al. 10.5194/acp-17-12509-2017
- Unified Theory of Vapor–Wall Mass Transport in Teflon-Walled Environmental Chambers Y. Huang et al. 10.1021/acs.est.7b05575
- Temperature and acidity dependence of secondary organic aerosol formation from <i>α</i>-pinene ozonolysis with a compact chamber system Y. Deng et al. 10.5194/acp-21-5983-2021
- Atmospheric Processing of Nitrophenols and Nitrocresols From Biomass Burning Emissions H. Wang et al. 10.1029/2020JD033401
- Southeast Atmosphere Studies: learning from model-observation syntheses J. Mao et al. 10.5194/acp-18-2615-2018
- Functional Group Composition of Secondary Organic Aerosol Formed from Ozonolysis of α-Pinene Under High VOC and Autoxidation Conditions M. Claflin et al. 10.1021/acsearthspacechem.8b00117
- Reactions of C12–C14 n-Alkylcyclohexanes with Cl Atoms: Kinetics and Secondary Organic Aerosol Formation K. Wang et al. 10.1021/acs.est.1c08958
- Nitrate radicals and biogenic volatile organic compounds: oxidation, mechanisms, and organic aerosol N. Ng et al. 10.5194/acp-17-2103-2017
- Kinetic modeling of formation and evaporation of secondary organic aerosol from NO<sub>3</sub> oxidation of pure and mixed monoterpenes T. Berkemeier et al. 10.5194/acp-20-15513-2020
- Secondary organic aerosol formation in biomass-burning plumes: theoretical analysis of lab studies and ambient plumes Q. Bian et al. 10.5194/acp-17-5459-2017
- NOx enhances secondary organic aerosol formation from nighttime γ-terpinene ozonolysis L. Xu et al. 10.1016/j.atmosenv.2020.117375
- Impacts of α-pinene ozonolysis products on the morphology and optical properties of black carbon C. Yuan et al. 10.1016/j.atmosenv.2024.120337
- Secondary organic aerosol formation from in situ OH, O<sub>3</sub>, and NO<sub>3</sub> oxidation of ambient forest air in an oxidation flow reactor B. Palm et al. 10.5194/acp-17-5331-2017
- Chemical evolution of atmospheric organic carbon over multiple generations of oxidation G. Isaacman-VanWertz et al. 10.1038/s41557-018-0002-2
- Multi-generation chemical aging of <i>α</i>-pinene ozonolysis products by reactions with OH N. Wang et al. 10.5194/acp-18-3589-2018
- Compositional Evolution of Secondary Organic Aerosol as Temperature and Relative Humidity Cycle in Atmospherically Relevant Ranges Z. Zhao et al. 10.1021/acsearthspacechem.9b00232
- Effects of NO<sub><i>x</i></sub> and SO<sub>2</sub> on the secondary organic aerosol formation from photooxidation of <i>α</i>-pinene and limonene D. Zhao et al. 10.5194/acp-18-1611-2018
- Challenges in determining atmospheric organic aerosol volatility distributions using thermal evaporation techniques K. Cain et al. 10.1080/02786826.2020.1748172
- Computational Simulation of Secondary Organic Aerosol Formation in Laboratory Chambers S. Charan et al. 10.1021/acs.chemrev.9b00358
- Anthropogenic–Biogenic Interactions at Night: Enhanced Formation of Secondary Aerosols and Particulate Nitrogen- and Sulfur-Containing Organics from β-Pinene Oxidation L. Xu et al. 10.1021/acs.est.0c07879
- Particle Size Distribution Dynamics Can Help Constrain the Phase State of Secondary Organic Aerosol Y. He et al. 10.1021/acs.est.0c05796
- Atmospheric Processes of Aromatic Hydrocarbons in the Presence of Mineral Dust Particles in an Urban Environment Z. Yu & M. Jang 10.1021/acsearthspacechem.9b00195
- Influence of Particle Surface Area Concentration on the Production of Organic Particulate Matter in a Continuously Mixed Flow Reactor Y. Han et al. 10.1021/acs.est.8b07302
- A steady-state continuous flow chamber for the study of daytime and nighttime chemistry under atmospherically relevant NO levels X. Zhang et al. 10.5194/amt-11-2537-2018
- Effects of inorganic seed aerosols on the particulate products of aged 1,3,5-trimethylbenzene secondary organic aerosol M. Huang et al. 10.1016/j.atmosenv.2017.01.010
- Using GECKO-A to derive mechanistic understanding of secondary organic aerosol formation from the ubiquitous but understudied camphene I. Afreh et al. 10.5194/acp-21-11467-2021
- Computational simulation of the dynamics of secondary organic aerosol formation in an environmental chamber A. Sunol et al. 10.1080/02786826.2018.1427209
- Vapors Are Lost to Walls, Not to Particles on the Wall: Artifact-Corrected Parameters from Chamber Experiments and Implications for Global Secondary Organic Aerosol K. Bilsback et al. 10.1021/acs.est.2c03967
- Secondary organic aerosol formation from ambient air in an oxidation flow reactor in central Amazonia B. Palm et al. 10.5194/acp-18-467-2018
- Effect of NOx and SO2 on the photooxidation of methylglyoxal: Implications in secondary aerosol formation S. Wang et al. 10.1016/j.jes.2020.02.011
- Wall losses of oxygenated volatile organic compounds from oxidation of toluene: Effects of chamber volume and relative humidity S. Yu et al. 10.1016/j.jes.2021.09.026
- The Caltech Photooxidation Flow Tube reactor: design, fluid dynamics and characterization Y. Huang et al. 10.5194/amt-10-839-2017
- Primary emissions and secondary aerosol production potential from woodstoves for residential heating: Influence of the stove technology and combustion efficiency A. Bertrand et al. 10.1016/j.atmosenv.2017.09.005
- Secondary Organic Aerosol Formation from Healthy and Aphid-Stressed Scots Pine Emissions C. Faiola et al. 10.1021/acsearthspacechem.9b00118
- Nitrate radical oxidation of <i>γ</i>-terpinene: hydroxy nitrate, total organic nitrate, and secondary organic aerosol yields J. Slade et al. 10.5194/acp-17-8635-2017
- Secondary organic aerosol formation from α-methylstyrene atmospheric degradation: Role of NO level, relative humidity and inorganic seed aerosol M. Tajuelo et al. 10.1016/j.atmosres.2019.104631
- Efficient HOx Radical Production from Isoprene Nighttime Chemistry Z. Moo et al. 10.1021/acsearthspacechem.3c00323
- Collection of Nitrogen Dioxide for Nitrogen and Oxygen Isotope Determination─Laboratory and Environmental Chamber Evaluation D. Blum et al. 10.1021/acs.analchem.2c04672
- Water vapour effects on secondary organic aerosol formation in isoprene ozonolysis Y. Sakamoto et al. 10.1039/C6CP04521A
- Semivolatile POA and parameterized total combustion SOA in CMAQv5.2: impacts on source strength and partitioning B. Murphy et al. 10.5194/acp-17-11107-2017
- Characterization of organic nitrate constituents of secondary organic aerosol (SOA) from nitrate-radical-initiated oxidation of limonene using high-resolution chemical ionization mass spectrometry C. Faxon et al. 10.5194/acp-18-5467-2018
- Assessing the influence of NO<sub><i>x</i></sub> concentrations and relative humidity on secondary organic aerosol yields from <i>α</i>-pinene photo-oxidation through smog chamber experiments and modelling calculations L. Stirnweis et al. 10.5194/acp-17-5035-2017
- Review of Smog Chamber Experiments for Secondary Organic Aerosol Formation H. Kim et al. 10.3390/atmos15010115
- Modeling biogenic secondary organic aerosol (BSOA) formation from monoterpene reactions with NO3: A case study of the SOAS campaign using CMAQ M. Qin et al. 10.1016/j.atmosenv.2018.03.042
- Quantification of the role of stabilized Criegee intermediates in the formation of aerosols in limonene ozonolysis Y. Gong & Z. Chen 10.5194/acp-21-813-2021
- A computationally efficient model to represent the chemistry, thermodynamics, and microphysics of secondary organic aerosols (simpleSOM): model development and application to α-pinene SOA S. Jathar et al. 10.1039/D1EA00014D
- Constraining uncertainties in particle-wall deposition correction during SOA formation in chamber experiments T. Nah et al. 10.5194/acp-17-2297-2017
- Multi-day photochemical evolution of organic aerosol from biomass burning emissions A. Dearden et al. 10.1039/D3EA00111C
- Molecular characterization of alkyl nitrates in atmospheric aerosols by ion mobility mass spectrometry X. Zhang et al. 10.5194/amt-12-5535-2019
- Molecular composition of secondary organic aerosol from styrene under different NO and humidity conditions S. Yu et al. 10.1016/j.atmosres.2021.105950
- NH3 Weakens the Enhancing Effect of SO2 on Biogenic Secondary Organic Aerosol Formation L. Du et al. 10.1021/acs.estlett.2c00959
- Comparison of OH reactivity measurements in the atmospheric simulation chamber SAPHIR H. Fuchs et al. 10.5194/amt-10-4023-2017
- Variability in Aromatic Aerosol Yields under Very Low NOxConditions at Different HO2/RO2Regimes W. Peng et al. 10.1021/acs.est.1c04392
- Lability of secondary organic particulate matter P. Liu et al. 10.1073/pnas.1603138113
- Parameterized Yields of Semivolatile Products from Isoprene Oxidation under Different NOx Levels: Impacts of Chemical Aging and Wall-Loss of Reactive Gases L. Xing et al. 10.1021/acs.est.8b00373
- Secondary organic aerosol formation from OH-initiated oxidation of <i>m</i>-xylene: effects of relative humidity on yield and chemical composition Q. Zhang et al. 10.5194/acp-19-15007-2019
- Secondary Organic Aerosol Formation from Reaction of 3-Methylfuran with Nitrate Radicals T. Joo et al. 10.1021/acsearthspacechem.9b00068
- Direct Measurements of Gas/Particle Partitioning and Mass Accommodation Coefficients in Environmental Chambers J. Krechmer et al. 10.1021/acs.est.7b02144
- Secondary Organic Aerosol (SOA) from Nitrate Radical Oxidation of Monoterpenes: Effects of Temperature, Dilution, and Humidity on Aerosol Formation, Mixing, and Evaporation C. Boyd et al. 10.1021/acs.est.7b01460
- Simulating the impact of gas-wall partitioning on SOA formation using the explicit gas mechanism integrated with aqueous reactions containing electrolytes S. Han & M. Jang 10.1016/j.scitotenv.2020.141360
- Rebounding hygroscopic inorganic aerosol particles: Liquids, gels, and hydrates Y. Li et al. 10.1080/02786826.2016.1263384
- Recent advances in understanding secondary organic aerosol: Implications for global climate forcing M. Shrivastava et al. 10.1002/2016RG000540
Saved (preprint)
Latest update: 23 Nov 2024
Short summary
The influence of seed aerosol surface area and oxidation rate on SOA formation in α-pinene ozonolysis is studied. SOA growth rate and mass yields are independent of seed surface area, consistent with the condensation of SOA-forming vapors being dominated by quasi-equilibrium growth. Faster α-pinene oxidation rates and higher SOA mass yields are observed at increasing O3 concentrations, indicating that a faster α-pinene oxidation rate leads to rapidly produced SOA-forming oxidation products.
The influence of seed aerosol surface area and oxidation rate on SOA formation in α-pinene...
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