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Volume 15, issue 14
Atmos. Chem. Phys., 15, 8101–8114, 2015
https://doi.org/10.5194/acp-15-8101-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.

Special issue: Uintah Basin Winter Ozone Studies (ACP/AMT inter-journal SI)

Atmos. Chem. Phys., 15, 8101–8114, 2015
https://doi.org/10.5194/acp-15-8101-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.

Research article 23 Jul 2015

Research article | 23 Jul 2015

Peroxynitric acid (HO2NO2) measurements during the UBWOS 2013 and 2014 studies using iodide ion chemical ionization mass spectrometry

P. R. Veres et al.

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Cited articles

Abida, O., Mielke, L. H., and Osthoff, H. D.: Observation of gas-phase peroxynitrous and peroxynitric acid during the photolysis of nitrate in acidified frozen solutions, Chem. Phys. Lett., 511, 187–192, https://doi.org/10.1016/j.cplett.2011.06.055, 2011.
Appelman, E. H. and Gosztola, D. J.: Aqueous Peroxynitric Acid (HOONO2): A Novel Synthesis and Some Chemical and Spectroscopic Properties, Inorganic Chemistry, 34, 4, https://doi.org/10.1021/ic00108a007, 1995.
Atkinson, R., Baulch, D. L., Cox, R. A., Crowley, J. N., Hampson, R. F., Hynes, R. G., Jenkin, M. E., Rossi, M. J., and Troe, J.: Evaluated kinetic and photochemical data for atmospheric chemistry: Volume I – gas phase reactions of Ox, HOx, NOx and SOx species, Atmos. Chem. Phys., 4, 1461–1738, https://doi.org/10.5194/acp-4-1461-2004, 2004.
Behnke, W., George, C., Scheer, V., and Zetzsch, C.: Production and decay of ClNO2, from the reaction of gaseous N2O5 with NaCl solution: Bulk and aerosol experiments, J. Geophys. Res.-Atmos., 102, 3795–3804, https://doi.org/10.1029/96jd03057, 1997.
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In this paper laboratory work is documented establishing iodide ion chemical ionization mass spectrometry (I- CIMS) as a sensitive method for the unambiguous detection of peroxynitric acid (HO2NO2; PNA). A dynamic calibration source for HO2NO2, HO2, and HONO was developed and calibrated using a novel total NOy detector (NOy CaRDS). The ambient observations of HO2NO2 using I- CIMS made during the 2013 and 2014 Uintah Basin Wintertime Ozone Study (UBWOS) are presented.
In this paper laboratory work is documented establishing iodide ion chemical ionization mass...
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