Articles | Volume 15, issue 14
https://doi.org/10.5194/acp-15-8101-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Special issue:
https://doi.org/10.5194/acp-15-8101-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
23 Jul 2015
Research article |
| 23 Jul 2015
Peroxynitric acid (HO2NO2) measurements during the UBWOS 2013 and 2014 studies using iodide ion chemical ionization mass spectrometry
Cooperative Institute for Research in Environmental Sciences, University of Colorado, Boulder, CO, USA
Chemical Sciences Division, NOAA Earth System Research Laboratory, Boulder, CO, USA
J. M. Roberts
Chemical Sciences Division, NOAA Earth System Research Laboratory, Boulder, CO, USA
R. J. Wild
Cooperative Institute for Research in Environmental Sciences, University of Colorado, Boulder, CO, USA
Chemical Sciences Division, NOAA Earth System Research Laboratory, Boulder, CO, USA
P. M. Edwards
Cooperative Institute for Research in Environmental Sciences, University of Colorado, Boulder, CO, USA
Chemical Sciences Division, NOAA Earth System Research Laboratory, Boulder, CO, USA
now at: Department of Chemistry, University of York, York, YO10 5DD, UK
S. S. Brown
Chemical Sciences Division, NOAA Earth System Research Laboratory, Boulder, CO, USA
T. S. Bates
Joint Institute for the Study of the Oceans and Atmosphere, University of Washington, Seattle, WA, USA
Pacific Marine Environmental Laboratory, National Oceanic and Atmospheric Administration, Seattle, Washington 98115, USA
P. K. Quinn
Pacific Marine Environmental Laboratory, National Oceanic and Atmospheric Administration, Seattle, Washington 98115, USA
J. E. Johnson
Joint Institute for the Study of the Oceans and Atmosphere, University of Washington, Seattle, WA, USA
R. J. Zamora
Physical Sciences Division, NOAA Earth System Research Laboratory, Boulder, CO, USA
J. de Gouw
Cooperative Institute for Research in Environmental Sciences, University of Colorado, Boulder, CO, USA
Chemical Sciences Division, NOAA Earth System Research Laboratory, Boulder, CO, USA
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35 citations as recorded by crossref.
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- Modification of a conventional photolytic converter for improving aircraft measurements of NO2 via chemiluminescence C. Nussbaumer et al. 10.5194/amt-14-6759-2021
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- Intercomparison of nitrous acid (HONO) measurement techniques in a megacity (Beijing) L. Crilley et al. 10.5194/amt-12-6449-2019
- A three-channel thermal dissociation cavity ring-down spectrometer for simultaneous measurement of ambient total peroxy nitrates, total alkyl nitrates, and NO2 C. Lin et al. 10.1016/j.talanta.2023.125524
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- Direct Constraints on Secondary HONO Production in Aged Wildfire Smoke From Airborne Measurements Over the Western US Q. Peng et al. 10.1029/2022GL098704
- Derivation of Hydroperoxyl Radical Levels at an Urban Site via Measurement of Pernitric Acid by Iodide Chemical Ionization Mass Spectrometry D. Chen et al. 10.1021/acs.est.6b05169
- A perspective on the reactions of organic peroxy radicals with HO2 N. Illmann 10.1039/D5EA00023H
- Advances on Atmospheric Oxidation Mechanism of Typical Aromatic Hydrocarbons M. Song et al. 10.6023/A21050224
- Comparison of two photolytic calibration methods for nitrous acid A. Lindsay & E. Wood 10.5194/amt-15-5455-2022
- Quantification of peroxynitric acid and peroxyacyl nitrates using an ethane-based thermal dissociation peroxy radical chemical amplification cavity ring-down spectrometer Y. Taha et al. 10.5194/amt-11-4109-2018
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- Computational and Experimental Investigation of the Detection of HO2 Radical and the Products of Its Reaction with Cyclohexene Ozonolysis Derived RO2 Radicals by an Iodide-Based Chemical Ionization Mass Spectrometer S. Iyer et al. 10.1021/acs.jpca.7b01588
- Investigation on heterogeneous reactions of reactive oxidized nitrogen species with urban particles using iodide-chemical ionization mass spectrometry S. Inomata et al. 10.1007/s44273-025-00061-4
- Development of a laser-photofragmentation laser-induced fluorescence instrument for the detection of nitrous acid and hydroxyl radicals in the atmosphere B. Bottorff et al. 10.5194/amt-14-6039-2021
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- Computational Comparison of Different Reagent Ions in the Chemical Ionization of Oxidized Multifunctional Compounds N. Hyttinen et al. 10.1021/acs.jpca.7b10015
- Optimizing the iodide-adduct chemical ionization mass spectrometry (CIMS) quantitative method for toluene oxidation intermediates: experimental insights into functional-group differences M. Song et al. 10.5194/amt-17-5113-2024
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- Ground and Airborne U.K. Measurements of Nitryl Chloride: An Investigation of the Role of Cl Atom Oxidation at Weybourne Atmospheric Observatory T. Bannan et al. 10.1002/2017JD026624
- Investigation of the oxidation of methyl vinyl ketone (MVK) by OH radicals in the atmospheric simulation chamber SAPHIR H. Fuchs et al. 10.5194/acp-18-8001-2018
- Online Calibration of a Chemical Ionization Mass Spectrometer for Multifunctional Biogenic Organic Nitrates M. Robinson et al. 10.1021/acsestair.4c00056
35 citations as recorded by crossref.
- Measurements of hydroperoxy radicals (HO2) at atmospheric concentrations using bromide chemical ionisation mass spectrometry S. Albrecht et al. 10.5194/amt-12-891-2019
- Characterization of nitrous acid and its potential effects on secondary pollution in the warm season in Beijing urban areas J. Li et al. 10.5194/acp-25-2551-2025
- A broadband cavity enhanced absorption spectrometer for aircraft measurements of glyoxal, methylglyoxal, nitrous acid, nitrogen dioxide, and water vapor K. Min et al. 10.5194/amt-9-423-2016
- Modification of a conventional photolytic converter for improving aircraft measurements of NO2 via chemiluminescence C. Nussbaumer et al. 10.5194/amt-14-6759-2021
- A new technique for the direct detection of HO2 radicals using bromide chemical ionization mass spectrometry (Br-CIMS): initial characterization J. Sanchez et al. 10.5194/amt-9-3851-2016
- Chlorine-initiated oxidation of n-alkanes under high-NOx conditions: insights into secondary organic aerosol composition and volatility using a FIGAERO–CIMS D. Wang & L. Hildebrandt Ruiz 10.5194/acp-18-15535-2018
- Intercomparison of nitrous acid (HONO) measurement techniques in a megacity (Beijing) L. Crilley et al. 10.5194/amt-12-6449-2019
- A three-channel thermal dissociation cavity ring-down spectrometer for simultaneous measurement of ambient total peroxy nitrates, total alkyl nitrates, and NO2 C. Lin et al. 10.1016/j.talanta.2023.125524
- Technical note: Gas-phase nitrate radical generation via irradiation of aerated ceric ammonium nitrate mixtures A. Lambe et al. 10.5194/acp-23-13869-2023
- HONO Measurement by Catalytic Conversion to NO on Nafion Surfaces Z. Payne et al. 10.1021/acs.est.2c05944
- Observations of Isocyanate, Amide, Nitrate, and Nitro Compounds From an Anthropogenic Biomass Burning Event Using a ToF‐CIMS M. Priestley et al. 10.1002/2017JD027316
- Springtime Nitrogen Oxide-Influenced Chlorine Chemistry in the Coastal Arctic S. McNamara et al. 10.1021/acs.est.9b01797
- Direct Constraints on Secondary HONO Production in Aged Wildfire Smoke From Airborne Measurements Over the Western US Q. Peng et al. 10.1029/2022GL098704
- Derivation of Hydroperoxyl Radical Levels at an Urban Site via Measurement of Pernitric Acid by Iodide Chemical Ionization Mass Spectrometry D. Chen et al. 10.1021/acs.est.6b05169
- A perspective on the reactions of organic peroxy radicals with HO2 N. Illmann 10.1039/D5EA00023H
- Advances on Atmospheric Oxidation Mechanism of Typical Aromatic Hydrocarbons M. Song et al. 10.6023/A21050224
- Comparison of two photolytic calibration methods for nitrous acid A. Lindsay & E. Wood 10.5194/amt-15-5455-2022
- Quantification of peroxynitric acid and peroxyacyl nitrates using an ethane-based thermal dissociation peroxy radical chemical amplification cavity ring-down spectrometer Y. Taha et al. 10.5194/amt-11-4109-2018
- Development of an incoherent broadband cavity-enhanced absorption spectrometer for in situ measurements of HONO and NO2 J. Duan et al. 10.5194/amt-11-4531-2018
- Cl2− chemical ionization mass spectrometry (Cl2-CIMS) for the measurement of acyl peroxy radicals T. Berg et al. 10.1039/D5EA00043B
- Computational and Experimental Investigation of the Detection of HO2 Radical and the Products of Its Reaction with Cyclohexene Ozonolysis Derived RO2 Radicals by an Iodide-Based Chemical Ionization Mass Spectrometer S. Iyer et al. 10.1021/acs.jpca.7b01588
- Investigation on heterogeneous reactions of reactive oxidized nitrogen species with urban particles using iodide-chemical ionization mass spectrometry S. Inomata et al. 10.1007/s44273-025-00061-4
- Development of a laser-photofragmentation laser-induced fluorescence instrument for the detection of nitrous acid and hydroxyl radicals in the atmosphere B. Bottorff et al. 10.5194/amt-14-6039-2021
- Measurements of Atmospheric HO2 Radicals Using Br-CIMS with Elimination of Potential Interferences from Ambient Peroxynitric Acid L. Wang et al. 10.1021/acs.analchem.4c01184
- Reactive nitrogen partitioning and its relationship to winter ozone events in Utah R. Wild et al. 10.5194/acp-16-573-2016
- Performance of a new coaxial ion–molecule reaction region for low-pressure chemical ionization mass spectrometry with reduced instrument wall interactions B. Palm et al. 10.5194/amt-12-5829-2019
- Evaluation of the accuracy of thermal dissociation CRDS and LIF techniques for atmospheric measurement of reactive nitrogen species C. Womack et al. 10.5194/amt-10-1911-2017
- Computational Comparison of Different Reagent Ions in the Chemical Ionization of Oxidized Multifunctional Compounds N. Hyttinen et al. 10.1021/acs.jpca.7b10015
- Optimizing the iodide-adduct chemical ionization mass spectrometry (CIMS) quantitative method for toluene oxidation intermediates: experimental insights into functional-group differences M. Song et al. 10.5194/amt-17-5113-2024
- Impact of Nonthermal Plasma on Lipid Oxidation from the Perspective of Plasma Treatment Parameters and Plasma Species: Identification of Key Reactive Species D. Liu et al. 10.1021/acs.jafc.3c03706
- The magnitude of the snow-sourced reactive nitrogen flux to the boundary layer in the Uintah Basin, Utah, USA M. Zatko et al. 10.5194/acp-16-13837-2016
- Chemical ionization quadrupole mass spectrometer with an electrical discharge ion source for atmospheric trace gas measurement P. Eger et al. 10.5194/amt-12-1935-2019
- Ground and Airborne U.K. Measurements of Nitryl Chloride: An Investigation of the Role of Cl Atom Oxidation at Weybourne Atmospheric Observatory T. Bannan et al. 10.1002/2017JD026624
- Investigation of the oxidation of methyl vinyl ketone (MVK) by OH radicals in the atmospheric simulation chamber SAPHIR H. Fuchs et al. 10.5194/acp-18-8001-2018
- Online Calibration of a Chemical Ionization Mass Spectrometer for Multifunctional Biogenic Organic Nitrates M. Robinson et al. 10.1021/acsestair.4c00056
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Latest update: 30 Jul 2025
Short summary
In this paper laboratory work is documented establishing iodide ion chemical ionization mass spectrometry (I- CIMS) as a sensitive method for the unambiguous detection of peroxynitric acid (HO2NO2; PNA). A dynamic calibration source for HO2NO2, HO2, and HONO was developed and calibrated using a novel total NOy detector (NOy CaRDS). The ambient observations of HO2NO2 using I- CIMS made during the 2013 and 2014 Uintah Basin Wintertime Ozone Study (UBWOS) are presented.
In this paper laboratory work is documented establishing iodide ion chemical ionization mass...
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